WO2008078628A1 - ニッケル水酸化物、非水電解質二次電池用正極活物質の製造方法、非水電解質二次電池用電極および非水電解質二次電池 - Google Patents

ニッケル水酸化物、非水電解質二次電池用正極活物質の製造方法、非水電解質二次電池用電極および非水電解質二次電池 Download PDF

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WO2008078628A1
WO2008078628A1 PCT/JP2007/074445 JP2007074445W WO2008078628A1 WO 2008078628 A1 WO2008078628 A1 WO 2008078628A1 JP 2007074445 W JP2007074445 W JP 2007074445W WO 2008078628 A1 WO2008078628 A1 WO 2008078628A1
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Prior art keywords
nonaqueous electrolyte
electrolyte secondary
secondary battery
active material
positive electrode
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PCT/JP2007/074445
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English (en)
French (fr)
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Hidekazu Hiratsuka
Shigeru Hanaoka
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Panasonic Corporation
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Priority to US12/513,641 priority Critical patent/US8802294B2/en
Priority to CN200780040414.5A priority patent/CN101528607B/zh
Priority to KR1020097010022A priority patent/KR101088255B1/ko
Publication of WO2008078628A1 publication Critical patent/WO2008078628A1/ja

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
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    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Nickelates
    • C01G53/42Nickelates containing alkali metals, e.g. LiNiO2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Nickelates
    • C01G53/42Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/11Powder tap density
    • CCHEMISTRY; METALLURGY
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2006/19Oil-absorption capacity, e.g. DBP values
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    • C01P2006/40Electric properties
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    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

 一次粒子の平均粒子径が1~5μmかつDBP吸収量が10~30mL/100gである水酸化ニッケルと、リチウム化合物とを酸化性雰囲気中で焼成してリチウム複合ニッケル酸化物を含有する非水電解質二次電池用の正極活物質を製造する。このリチウム複合ニッケル酸化物は、充填性、出力特性(特にハイレート特性)に優れ、非水電解質二次電池の正極活物質として有用である。
PCT/JP2007/074445 2006-12-22 2007-12-19 ニッケル水酸化物、非水電解質二次電池用正極活物質の製造方法、非水電解質二次電池用電極および非水電解質二次電池 WO2008078628A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/513,641 US8802294B2 (en) 2006-12-22 2007-12-19 Nickel hydroxide, method for producing positive electrode active material for non-aqueous electrolyte secondary battery, electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery
CN200780040414.5A CN101528607B (zh) 2006-12-22 2007-12-19 镍氢氧化物、非水电解质二次电池用正极活性物质的制造方法、非水电解质二次电池用电极以及非水电解质二次电池
KR1020097010022A KR101088255B1 (ko) 2006-12-22 2007-12-19 니켈수산화물, 비수전해질 이차전지용 양극 활물질의 제조방법, 비수전해질 이차전지용 전극 및 비수전해질 이차전지

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006345502 2006-12-22
JP2006-345502 2006-12-22

Publications (1)

Publication Number Publication Date
WO2008078628A1 true WO2008078628A1 (ja) 2008-07-03

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PCT/JP2007/074445 WO2008078628A1 (ja) 2006-12-22 2007-12-19 ニッケル水酸化物、非水電解質二次電池用正極活物質の製造方法、非水電解質二次電池用電極および非水電解質二次電池

Country Status (5)

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US (1) US8802294B2 (ja)
JP (1) JP4995061B2 (ja)
KR (1) KR101088255B1 (ja)
CN (1) CN101528607B (ja)
WO (1) WO2008078628A1 (ja)

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JP5626614B2 (ja) * 2011-03-03 2014-11-19 トヨタ自動車株式会社 非水電解液二次電池

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KR20110136002A (ko) * 2010-06-13 2011-12-21 삼성에스디아이 주식회사 리튬 이차 전지용 양극 활물질 전구체 및 이를 이용한 리튬 이차 전지용 양극 활물질 및 양극 활물질을 포함하는 리튬 이차 전지
US9225008B2 (en) 2010-10-15 2015-12-29 Toyota Jidosha Kabushiki Kaisha Secondary battery
JP5213989B2 (ja) * 2011-04-27 2013-06-19 住友金属鉱山株式会社 アルカリ二次電池正極活物質用被覆水酸化ニッケル粉末及びその製造方法
JP5553798B2 (ja) * 2011-06-10 2014-07-16 株式会社日立製作所 リチウムイオン二次電池用正極材料
KR101579700B1 (ko) * 2011-10-20 2015-12-22 도요타지도샤가부시키가이샤 비수 전해액 이차 전지 및 그 이용
CN104126238B (zh) * 2012-09-24 2016-02-24 三洋电机株式会社 封闭式二次电池
CN103440997B (zh) * 2013-08-26 2016-06-29 中国科学技术大学 金属双氢氧化物/二硫化钼纳米复合材料及其制备方法和应用
CN105934409B (zh) * 2014-01-31 2018-03-09 住友金属矿山株式会社 镍锰复合氢氧化物粒子及其制造方法、非水电解质二次电池用正极活性物质及其制造方法、以及非水电解质二次电池
KR102172026B1 (ko) * 2014-05-20 2020-10-30 삼성에스디아이 주식회사 활물질 전구체 및 그 제조방법
JP2016062832A (ja) * 2014-09-19 2016-04-25 トヨタ自動車株式会社 二次電池の製造方法
JP5943051B2 (ja) * 2014-09-30 2016-06-29 住友金属鉱山株式会社 ニッケルコバルト複合水酸化物の製造方法
KR101937896B1 (ko) * 2016-03-04 2019-01-14 주식회사 엘지화학 이차전지용 양극활물질의 전구체 및 이를 이용하여 제조된 양극활물질
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CN109803929B (zh) * 2016-07-29 2022-08-26 住友金属矿山株式会社 镍锰复合氢氧化物及其制造方法、非水系电解质二次电池用正极活性物质及其制造方法
US11316155B2 (en) * 2016-12-26 2022-04-26 Sumitomo Metal Mining Co., Ltd. Cathode active material precursor for non-aqueous electrolyte secondary battery
KR101982546B1 (ko) * 2017-12-27 2019-05-27 울산과학기술원 나트륨 이차전지 양극의 제조 방법
KR102231062B1 (ko) 2018-03-09 2021-03-23 주식회사 엘지화학 양극 활물질, 그 제조 방법, 이를 포함하는 양극 및 이차전지
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CN101528607B (zh) 2014-08-27
JP2008174444A (ja) 2008-07-31
CN101528607A (zh) 2009-09-09
KR20090080973A (ko) 2009-07-27
US8802294B2 (en) 2014-08-12
KR101088255B1 (ko) 2011-11-30
US20100068624A1 (en) 2010-03-18
JP4995061B2 (ja) 2012-08-08

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