WO2006027873A1 - 圧電薄膜共振子 - Google Patents
圧電薄膜共振子 Download PDFInfo
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- WO2006027873A1 WO2006027873A1 PCT/JP2005/008427 JP2005008427W WO2006027873A1 WO 2006027873 A1 WO2006027873 A1 WO 2006027873A1 JP 2005008427 W JP2005008427 W JP 2005008427W WO 2006027873 A1 WO2006027873 A1 WO 2006027873A1
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- Prior art keywords
- thin film
- substrate
- piezoelectric thin
- piezoelectric
- sacrificial layer
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
- H03H9/15—Constructional features of resonators consisting of piezoelectric or electrostrictive material
- H03H9/17—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
- H03H9/171—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator implemented with thin-film techniques, i.e. of the film bulk acoustic resonator [FBAR] type
- H03H9/172—Means for mounting on a substrate, i.e. means constituting the material interface confining the waves to a volume
- H03H9/173—Air-gaps
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
- H03H9/02—Details
- H03H9/02007—Details of bulk acoustic wave devices
- H03H9/02086—Means for compensation or elimination of undesirable effects
- H03H9/02133—Means for compensation or elimination of undesirable effects of stress
Definitions
- the present invention relates to a piezoelectric thin film resonator.
- a piezoelectric thin film resonator it is necessary to acoustically separate from a substrate a vibration part in which a piezoelectric thin film is disposed between a pair of opposing excitation electrodes. For this reason, there is a structure in which the thin film portion (membrane) is partially lifted from the substrate cover via a void layer.
- the thin film portion includes a support portion supported by the substrate and a floating portion that floats on the substrate force, and the floating portion is supported by the support portion. Stress concentrates in the vicinity of the boundary of the part, and cracks are likely to occur. In addition, the floating part is easily bent. Therefore, a structure has been proposed in which a piezoelectric thin film is sandwiched between a pair of excitation electrodes and further sandwiched between a pair of dielectric thin films (see, for example, Patent Document 1).
- Patent Document 1 Japanese Patent Publication No. 6-40611
- the present invention intends to provide a piezoelectric thin film resonator capable of ensuring the strength of the membrane without impairing the resonance characteristics and facilitating handling during mounting. It is.
- the present invention provides a piezoelectric thin film resonator configured as follows.
- the piezoelectric thin film resonator includes a substrate, a thin film portion, and a reinforcing film.
- the thin film portion includes at least two support portions supported by the substrate, and a floating portion that is disposed between the substrate via a gap layer and supported by the support portion.
- the floating portion includes a vibrating portion in which a piezoelectric thin film is disposed between a pair of excitation electrodes.
- the reinforcing film is formed in the vicinity of the boundary between the support portion and the floating portion of the thin film portion.
- the strength of the membrane is improved by the reinforcing film in the vicinity of the boundary between the support portion and the floating portion of the thin film portion (membrane), so that cracks and deflection can be reduced. Monkey.
- the reinforcing film is not formed on the vibrating part of the thin film part, the resonance characteristics are not impaired.
- the vibrating part is dented with respect to the reinforcing film, and it is difficult for a load to be applied to the vibrating part, and handling during mounting becomes easy.
- the present invention also provides a piezoelectric thin film resonator configured as follows.
- the piezoelectric thin film resonator includes a substrate, a thin film portion, a reinforcing film, and a reinforcing film between the resonators.
- the thin film includes at least three support portions supported by the substrate, and a floating portion that is disposed between the substrate via a gap layer and supported by the support portion.
- the floating portion includes at least two vibrating portions in which a piezoelectric thin film is disposed between a pair of excitation electrodes. Each vibration part is arranged in a row in a direction connecting the two support parts.
- the reinforcing film is disposed in the vicinity of the boundary between the two supporting portions and the floating portion of the thin film portion.
- the inter-resonator reinforcing film is disposed so as to extend from the other supporting portion of the thin film portion between the two vibrating portions of the floating portion of the thin film portion.
- the vibrating part is dented with respect to the reinforcing film, and it is difficult for a load to be applied to the vibrating part, and handling during mounting becomes easy.
- the substrate has a flat portion and a tapered portion.
- the support portion of the thin film portion is in contact with both the flat portion and the taper portion of the substrate at a portion in the vicinity of the boundary with the floating portion.
- the taper angle force of the floating portion in the vicinity of the boundary is smaller than the taper angle of the taper portion of the substrate.
- the floating portion extends substantially continuously from the surface where the thin film portion and the substrate are in contact with each other, so that stress concentration near the boundary between the support portion and the floating portion of the thin film portion is reduced.
- the boundary between the support portion and the floating portion of the thin film portion is linear.
- the area occupied by the floating portion can be reduced, and the piezoelectric thin film resonator can be reduced in size.
- a boundary between the support portion and the floating portion of the thin film portion is curved.
- the rigidity of the boundary between the support portion and the floating portion of the thin film portion can be increased, and cracks and deflection can be reduced.
- the configuration is as follows.
- the substrate force is a plane sapphire.
- the piezoelectric thin film is ZnO or A1N.
- the substrate is C-plane sapphire, Z-plane LiTaO, or Z-plane LiNbO. Said
- Piezoelectric thin film force ⁇ or A1N Piezoelectric thin film force ⁇ or A1N.
- the effect of the reinforcing film is greater when the resonance frequency is 1.5 GHz or more.
- the present invention also provides a piezoelectric filter using the piezoelectric thin film resonator having any one of the above-described configurations. Since this piezoelectric filter uses a piezoelectric thin film resonator that can secure the strength of the membrane without impairing the resonance characteristics, it is possible to achieve the desired resonance characteristics with high reliability. [0028] Further, the present invention provides a duplexer using the piezoelectric thin film resonator having any one of the above configurations or the piezoelectric filter having any one of the above configurations.
- This duplexer uses a piezoelectric thin film resonator that can secure the strength of the membrane without impairing the resonance characteristics, or a piezoelectric filter using this piezoelectric thin film resonator, so that the desired frequency characteristics with high reliability are achieved. Is possible.
- the present invention provides a communication device using the piezoelectric thin film resonator having any one of the above configurations or the piezoelectric filter having any one of the above configurations.
- This communication device uses a piezoelectric thin film resonator that can secure the strength of the membrane without impairing the resonance characteristics, or a piezoelectric filter using this piezoelectric thin film resonator, so that the desired frequency characteristics with high reliability can be obtained. Is possible.
- the piezoelectric thin film resonator of the present invention can ensure the strength of the membrane without impairing the resonance characteristics, and can facilitate the handling during mounting.
- FIG. 1 is a plan view of a main part of a piezoelectric thin film resonator. (Example 1)
- Example 2 is a cross-sectional view taken along line II II in FIG. (Example 1)
- FIG. 3 is a plan view of an essential part of a piezoelectric thin film resonator. (Modification)
- FIG. 5 is a cross-sectional view taken along line V—V in FIG. (Example 2)
- FIG. 6 is a plan view of the main part of a piezoelectric thin film resonator. (Example 3)
- FIG. 7 is a cross-sectional view of a piezoelectric thin film resonator. (Example 4)
- FIG. 8 is a cross-sectional view of a principal part of a piezoelectric thin film resonator. (Example 4)
- FIG. 9 is a plan view of the main part of a piezoelectric thin film resonator. (Example 7)
- FIG. 10a is a circuit diagram of a ladder filter. (Example 10)
- FIG. 10b is a circuit diagram of a lattice filter. (Example 10)
- FIG. 10c is a circuit diagram of a multimode filter. (Example 10)
- FIG. 11 is a circuit diagram of a duplexer. (Example 11)
- FIG. 12 is a block diagram of a communication device. (Example 12) Explanation of symbols
- FIG. 1 is a principal plan view schematically showing the structure of the piezoelectric thin film resonator 10 of the first embodiment.
- FIG. 2 is a cross-sectional view taken along line II-II in FIG.
- a dielectric film 16, a lower electrode 17a, a piezoelectric thin film 18, an upper electrode 17b, and reinforcing films 19a and 19b are formed on a substrate 11.
- a gap layer 14 (see FIG. 2) formed by removing the sacrificial layer 13 (see FIG. 1) causes the electrodes 17a and 17b to overlap each other in the stacking direction.
- Twelve dielectric films 16, a lower electrode 17 a, a piezoelectric thin film 18, and an upper electrode 17 b, that is, a vibrating part 12 is lifted from the substrate 11.
- the piezoelectric thin film resonator 10 is manufactured as follows.
- a sacrificial layer 13 such as zinc oxide which is easily chemically dissolved is formed on a part of the substrate 11 by using a technique such as sputtering or etching.
- a technique such as sputtering or etching.
- a Si or glass substrate with a flat surface is even better.
- the sacrificial layer 13 is finally removed to form the void layer 14.
- the material of the sacrificial layer 13 is preferably one that can withstand high temperatures that can be reached during the formation of the piezoelectric thin film 18 and can be easily removed.
- metals such as Ge, Sb, Ti, Al, and Cu, phosphate silicate glass (PSG), and polymers. Examples of the polymer include polytetrafluoroethylene or derivatives thereof.
- Conductors polyphenylene sulfide, polyether ether ketone, polyamide, polyamide imide, polyimide, polyimide siloxane, butyl ether, polyphenyl, norylene-n, parylene f, benzocyclobutene and the like are preferable.
- the thickness of the sacrificial layer 13 to be formed must be such that the vibrating portion 12 does not come into contact with the substrate 11 even if the membrane is bent, and the ease of manufacturing is preferably 50 nm to several ⁇ m.
- a dielectric film (not shown) is formed on the sacrificial layer 13 and the substrate 11 by sputtering, CVD, electron beam evaporation, or the like so as to cover the entire surface.
- TCF frequency temperature characteristic
- the lower electrode 17a is formed on the dielectric film (not shown) by using sputtering, CVD, electron beam evaporation, or the like and patterning by photolithography.
- the lower electrode 17a is mainly made of a metal material such as Mo, Pt, Al, Au, Cu, and Ti, and is formed in a strip shape from the sacrificial layer 13 to the substrate 11.
- a piezoelectric thin film 18 such as zinc oxide or aluminum nitride is formed on the lower electrode 17a by using film formation by sputtering or the like and patterning by photolithography technology.
- the aluminum nitride is patterned by lift-off using zinc oxide.
- a dielectric film 16 such as SiO is entirely applied on the sacrificial layer 13.
- the zinc oxide used for the sacrificial layer 13 is etched even when wet etching of the zinc oxide is performed during the lift-off patterning of the zinc oxide for lift-off and the lift-off of the aluminum nitride. None! /
- the upper electrode 17b is formed on the piezoelectric film 18 in the same manner as the lower electrode 17a.
- reinforcing films 19a and 19b are formed. As shown in FIG. 1, when the lower electrode 17a and the upper electrode 17b are arranged in a straight line, the connecting portion between the membrane and the substrate 11 (that is, the portion near the boundary between the membrane floating portion and the supporting portion). The same applies hereinafter.) Reinforcing films 19a and 19b are formed on the lower electrode 17a and the upper electrode 17b. Further, the reinforcing films 19a and 19b are formed as much as possible on the electrodes 17a and 17b that do not cover the vibration part 12. Reinforcing membrane 19a and 19b are formed by sputtering, CVD, electron beam evaporation, or the like. Reinforcing membrane 1 9a, 19b [For use! /, Materials such as Al, Ag, Au, Co, Cr, Cu, Fe, In, Mo, Nb, Ni, Ti, Pd, Pt, W, Zr, etc. Metal materials (including alloys) containing at least one of these elements.
- sacrificial layer etch holes 13a, 13b and a dielectric film 16 are formed.
- the sacrificial layer etch holes 13a and 13b are portions of the sacrificial layer 13 where the dielectric film 16 force is also exposed.
- Photoresist is patterned by photolithography, and the dielectric film (not shown) on the sacrificial layer etch holes 13a and 13b is removed by reactive ion etching or wet etching. For example, if SiO is used for the dielectric film (not shown), a CF or other
- Reactive ion etching is performed using an elementary gas. Further, wet etching may be performed with a solution such as hydrofluoric acid. After etching, the etch mask such as photoresist is removed with an organic solvent such as gasoline.
- the sacrificial layer 13 is etched from the sacrificial layer etch holes 13 a and 13 b to form the void layer 14.
- Photoresist is patterned by photolithography, and the sacrificial layer 13 is removed by reactive ion etching or wet etching.
- the zinc oxide is removed using an acidic solution such as hydrochloric acid or phosphoric acid.
- the etch mask such as photoresist is removed with an organic solvent such as acetone.
- the solution is one that does not etch the piezoelectric thin film 18, the dielectric film 16, the electrodes 17a and 17b, and the reinforcing films 19a and 19b, the process of patterning by photolithography and the removal of this etch mask can be eliminated.
- the piezoelectric thin film 18 is made of aluminum nitride
- the dielectric film 16 is made of SiO
- the electrodes 17a and 17b are made of Pt, Au, Ti, etc.
- the zinc oxide in the sacrificial layer 13 can be removed with a mixed aqueous solution of acetic acid and phosphoric acid without notching. After the etching, it is sufficiently substituted with a volatile solution such as IPA (isopropyl alcohol) and dried to form the void layer 14.
- IPA isopropyl alcohol
- a dielectric material is formed on the entire surface of the sacrificial layer 13 during patterning of the aluminum nitride. Since the film 16 is formed, the shape of the sacrificial layer 13 is not impaired at the time of aluminum nitride lift-off.
- Etch sacrificial layer 13 into the constituent films other than sacrificial layer 13 If a material resistant to the etching solution is used, the patterning process at the time of sacrificial layer etching can be eliminated, and the cost can be reduced by stabilizing the process and reducing the number of steps. After the sacrificial layer 13 is wet etched, the time required for the drying process after removing the sacrificial layer can be shortened by sufficiently replacing the etchant with a volatile solution such as IPA, thereby reducing the cost.
- metal reinforcing films 19a and 19b are formed at the connection between the membrane and the substrate 11 where the stress of the membrane is concentrated. Strength increases, and it is possible to reduce characteristic defects due to membrane cracks and deflection.
- the metal reinforcing films 19a and 19b are arranged on the lower electrode 17a and the upper electrode 17b, the wiring resistance is reduced and the insertion loss of the filter is reduced, so that good filter characteristics can be obtained. Can do.
- the heat dissipation is further improved, and a resonator having more excellent power durability is obtained.
- FIG. 3 shows a case where the lower electrode 27a and the upper electrode 27b are not linear as a modification of the first embodiment.
- a dielectric film 26, a lower electrode 27a, a piezoelectric thin film 28, an upper electrode 27b, and reinforcing films 29a, 29b, and 29c are formed on the substrate.
- the lower electrode 27a is formed so as to straddle the sacrificial layer 23, the membrane and substrate connecting portions are provided on both sides of the vibrating portion 22, and the reinforcing films 29a and 29b are formed on the lower electrode 27a of these two connecting portions.
- the upper electrode 27b is disposed at a right angle to the lower electrode 27a, and at least one end extends from the sacrificial layer 23 to the substrate.
- a reinforcing film 29c is formed on the upper electrode 27b at at least one connection portion between the membrane and the substrate.
- FIG. 4 is a principal plan view schematically showing the structure of the piezoelectric thin film resonator 30 of the second embodiment.
- FIG. 5 is a cross-sectional view taken along line V—V in FIG.
- a dielectric film 36, a lower electrode 37a, a piezoelectric thin film 38, an upper electrode 37b, and reinforcing films 39a and 39b are formed on a substrate 31 in substantially the same manner as in the first embodiment.
- 37 b that is, a structure in which the vibration part 32 is lifted from the substrate 31.
- the specific structure of the membrane is different from that of Example 1.
- the sacrificial layer 33 is formed in a substantially H shape as shown in FIG. 4, and four connection portions between the membrane and the substrate 31 are provided.
- the reinforcing films 39a and 39b are formed at two positions adjacent to the vibration part 32 other than the parts on the lower electrode 37a and the upper electrode 37b.
- the forming method of the reinforcing films 39a and 39b is sputtering, CVD, electron beam evaporation or the like.
- the material of the reinforcing films 39a and 39b is an insulating material mainly composed of silicon oxide, silicon nitride, alumina, aluminum nitride, titanium oxide, tantalum oxide, etc., and may have a multilayer structure of two or more layers.
- the reinforcing films 19a, 17b are formed so that the lower electrode 17a and the upper electrode 17b are not electrically short-circuited and the parasitic capacitance between the electrodes 17a, 17b does not adversely affect the resonance characteristics. 19b must be placed.
- an insulating material is used for the reinforcing films 39a and 39b as in the second embodiment, it is not necessary to consider the electrical wiring of the resonator, so that the flexibility of the reinforcing material layout is increased.
- the reinforcing films 39a and 39b a multilayer structure using two or more kinds of insulating materials, the stress of the reinforcing films 39a and 39b can be relieved, so that the strength of the membrane is improved.
- aluminum nitride having a good thermal conductivity is used as the reinforcing films 39a and 39b, a heat dissipation can be improved and a resonator excellent in power durability can be obtained.
- the reinforcing films 39a and 39b are formed at the connection portion between the membrane where the stress is concentrated and the substrate 31 after the sacrificial layer 33 is removed, as in the first embodiment, The strength of the membrane increases, and it is possible to reduce characteristic defects due to membrane cracks and deflection.
- the reinforcing films 39a and 39b are arranged in a region where the electrodes 37a and 37b are not formed at the connection portion between the membrane and the substrate 31, and further, the lower electrode 37a and the upper portion at the connection portion between the membrane and the substrate 31 are arranged.
- a reinforcing film made of a metal material or a multilayer reinforcing film made of a metal material and an insulating material may be arranged on the electrode 37b.
- FIG. 6 is a principal plan view schematically showing the structure of the piezoelectric thin film resonator 40 of the third embodiment.
- the piezoelectric thin film resonator 40 of the third embodiment is configured in substantially the same manner as the first embodiment, but is different from the first embodiment and includes two resonator elements. That is, on the substrate, the dielectric film 46, the lower electrode 47a, the piezoelectric thin film 48, the upper electrodes 47b, 47c, and the reinforcing films 49a, 49b, 49c, 49d, 49s.
- the gap layer formed by the sacrificial layer 43 formed between the substrate and the dielectric film 46 causes the lower electrode 47a and the upper electrodes 47b and 47c to overlap each other in the stacking direction 42 2s and 42t.
- the dielectric film 46, the lower electrode 47a, the piezoelectric thin film 48, the upper electrodes 47b and 47c, that is, the two vibrating parts 42s and 42t have a structure in which the substrate force is also raised.
- the reinforcing films 49a, 49b, 49c, and 49d are formed on the lower electrode 47a and the upper electrodes 47b and 47c at the connection portion of the membrane and the substrate, as in the first embodiment.
- the reinforcing film 49s is formed so as to cross over the sacrificial layer 43 in a region other than the vibrating parts 42s and 42t.
- Example 1 In the piezoelectric thin film resonator 40, since the reinforcing films 49a, 49b, 49c, 49d, and 49s are formed at the connection portion between the membrane and the substrate where stress is concentrated after the sacrificial layer 43 is removed, Example 1 In the same way, the strength of the membrane is increased, and it is possible to reduce the defect of characteristics caused by cracks and deflection of the membrane.
- FIG. 7 is a cross-sectional view schematically showing the structure of the piezoelectric thin film resonator 50 of the fourth embodiment.
- Fig. 8 is an enlarged cross-sectional view of the main part.
- a void layer 54 is formed on a convex portion 51x formed on an upper surface 51a of a substrate 51, and a dielectric film 56, a lower electrode 57a, a piezoelectric layer are formed thereon.
- the thin film 58, the upper electrode 57b, and the thin film portions of the reinforcing films 59a and 59b are formed.
- the upper surface 51a of the substrate 51 and the inclined surface 51s of the convex portion 51x are forward tapered. That is, the angle between the upper surface 51a of the substrate 51 and the slope 51s of the convex portion 51x is an obtuse angle (greater than 90 ° and less than 180 °).
- the thin film portion and the substrate 51 are in contact with each other through two surfaces 51a and 53s that intersect at an obtuse angle.
- the piezoelectric thin film resonator 50 is manufactured as follows.
- a sacrificial layer 53 is formed thicker than the final shape on the portion of the substrate 51 where the convex portion 51x is to be formed.
- the sacrificial layer 53 preferably has a trapezoidal cross section, and its inclined surface has a gentle forward taper with the substrate 51 (makes an obtuse angle close to 180 ° with the upper surface of the substrate 51).
- To make the sacrificial layer 53 have a gentle forward taper for example, when using a photoresist for the sacrificial layer 53, patterning is performed using a gray-tone mask that gradually changes the light intensity, and the slope is It is formed in a forward tapered shape.
- the sacrificial layer 53 and the substrate 51 are etched by reactive ion etching or wet etching. For example, reactive ion ethyne using a fluorine-based gas such as CF
- the slope of the slope 53s of the sacrificial layer 53 becomes smaller than the slope of the slope 51s of the convex portion 51x, as shown in FIG. That is, when the substrate is etched using the sacrificial layer 53 having a trapezoidal cross section as a mask, the sacrificial layer 53 is also etched in the thickness direction as the substrate 51 is etched in the thickness direction, and the substrate area covered by the sacrificial layer is reduced. Therefore, a taper having a larger angle than that of the sacrificial layer 53 is formed on the substrate 51.
- the taper angle of the slope 53s of the sacrificial layer 53 is smaller than the taper angle of the slope 51s of the convex part 51x of the substrate 51, the residual stress of the membrane can be reduced and the strength of the membrane can be secured.
- the dielectric film 56 can be formed on the sacrificial layer 53 with good coverage. Then, the electrodes 57a and 57b to be formed thereafter can be formed with good coverage, and device defects due to disconnection of the electrodes 57a and 57b can be reduced.
- the thickness of the sacrificial layer 53 after the convex portion 5 lx is formed on the substrate 51 must be such that the vibrating portion 52 does not contact the substrate 51 (the upper surface 51b of the convex portion 51x) even if the membrane is bent. In view of ease of production, it is preferably 50 nm or more and tens / zm or less.
- the protrusion height a of the protrusion 51x formed on the substrate 51 is not less than 50 nm, which is more than the thickness of the membrane. And even better. Further, a shown in FIG. 8 is preferably about half of h shown in FIG.
- the slope 53s of the sacrificial layer 53 is inclined rather than the slope 51s of the convex part 51x formed on the substrate 51, and the change in the angle of the membrane is reduced as much as possible (the angle gradually changes).
- the taper angle of the sacrificial layer 53 is smaller than the taper angle of the substrate 51, the strength of the membrane can be ensured, and defects in the membrane due to cracks and deflection of the membrane can be reduced.
- the taper angle of the sacrificial layer 53 is smaller than the taper angle of the convex portion 51x of the substrate 51, the electrodes 57a and 57b to be formed later can be formed with good coverage, and an element failure due to disconnection of the electrodes 57a and 57b, etc. Can be reduced. Removal of sacrificial layer 53 Later, the strength of the membrane can be secured.
- a piezoelectric thin film resonator having the same structure as that of Example 4 is manufactured by a method different from that of Example.
- an etch mask is formed on the sacrificial layer. Thereafter, the sacrificial layer and the substrate are etched by reactive ion etching or wet etching to form a taper on the sacrificial layer and the substrate. Thereafter, the etch mask is removed.
- the etch mask may be a metal such as photoresist A1.
- the sacrificial layer, the substrate etching, and the etch mask removal process may be the same. That is, the sacrificial layer in the etching process
- Etching is performed until all of the substrate and etch mask are etched and at least the etch mask is removed.
- the sacrificial layer is processed in fewer steps, so the process can be stabilized. it can.
- the piezoelectric thin film resonator of Example 6 does not employ a dielectric film as the membrane, and the floating portion has a structure consisting only of a piezoelectric thin film and electrodes sandwiching it.
- At least one dielectric film or metal film is formed on the substrate. That is, before forming the sacrificial layer on the substrate, at least one dielectric film or metal film
- a constituent film such as an organic film is formed. If Si is used for the substrate, thermal oxide may be formed. Alternatively, a dielectric film such as silicon nitride may be formed by sputtering, CVD, electron beam evaporation, or the like.
- FIG. 9 is a principal plan view schematically showing the structure of the piezoelectric thin film resonator 60 of the seventh embodiment.
- a sacrificial layer 63 for forming a void layer is formed on a substrate, and a dielectric film 66, a lower electrode 67a, a piezoelectric thin film 68, an upper electrode 67b, and Reinforcing films 69a and 69b are formed.
- the edges 63s, 63t of the sacrificial layer 63 are curved, and the sacrificial layer 63 is After removal, the substrate force of the membrane also floats, and the shape of the boundary between the floating portion and the support portion supported by the substrate becomes a curve. Further, the shapes of the ends 67s and 67t of the electrodes 67a and 67b forming the vibrating part 62 in the membrane are curved, and the shapes of the edges 63s and 63t of the sacrificial layer 63 adjacent to the electrodes 67a and 67b are the electrodes 67a, It is made substantially parallel to the shape of the ends 67s and 67t of 67b.
- the shape of the membrane floating portion where stress concentrates after removal of the sacrificial layer 63 and the portion in the vicinity of the boundary between the supporting portions are made into a gently curved shape.
- the strength of the membrane is increased, and special defects due to cracks and deflection of the membrane can be reduced.
- the shapes of the ends 67s and 67t of the electrodes 67a and 67b forming the vibrating portion 62 in the membrane are curved, the shapes of the edges 63s and 63t of the sacrificial layer 53 adjacent to the electrodes 67a and 67b are the electrodes 67a, By making the end portions 67s and 67t of the 67b substantially parallel to the shapes of the end portions 67s and 67t, the heat generated in the vibrating portion 62 can be efficiently dissipated to the substrate, and a resonator with better power durability can be obtained.
- a piezoelectric thin film resonator having the same structure as in the other examples is manufactured.
- a sacrificial layer composed mainly of ZnO is formed on a sapphire substrate with a C-face on the substrate.
- the C-plane of ZnO which is a sacrificial layer faces the normal direction of the substrate surface.
- Al, Au, Cu, Ir, Mo, Ni, Pd, Pt, Ta, and W, which have good lattice matching with ZnO, are formed as lower electrodes.
- KNbO, PZT, etc. are formed. At this time, the C surface of the piezoelectric thin film faces the normal direction of the substrate surface.
- the sacrificial layer, the lower electrode, the piezoelectric thin film, and the upper electrode includes sputtering, CVD, and electron beam evaporation. As a notching method, lift-off, etching or the like is used. Thereafter, the sacrificial layer is removed by wet etching or dry etching.
- the substrate may be a SiC substrate having an a-plane and LiTaO or LiNbO having a Z-plane on the surface.
- the vibration mode uses thickness longitudinal vibration.
- Example 9 A piezoelectric thin film resonator having the structure shown in Fig. 4 and utilizing thickness shear vibration is fabricated.
- a sapphire substrate with an R-plane is used.
- the C-plane of ZnO, which is a sacrificial layer, is formed so that it faces perpendicular to the substrate surface normal.
- the C surface of the piezoelectric thin film is formed in a direction perpendicular to the substrate surface normal.
- ZnO or A1N is formed on the substrate with C-plane sapphire, Z-plane LiTaO, or Z-plane LiNbO
- a piezoelectric thin film having a C-axis perpendicular to the substrate surface is obtained, and the thickness longitudinal mode can be excited by sandwiching the piezoelectric thin film with a pair of electrodes parallel to the substrate surface. Even in the longitudinal thickness mode, the thickness becomes thin inversely proportional to the resonance frequency, and it tends to break. Therefore, the effect of the reinforcing film is greater at resonance frequencies of 1.5 GHz and above.
- 10a to 10c are circuit diagrams of the piezoelectric filter of the tenth embodiment.
- the piezoelectric filter of Example 10 is configured using the piezoelectric thin film resonators of Examples 1 to 9.
- the piezoelectric filter 70 shown in FIG. 10a is an L-type ladder filter in which one series piezoelectric thin film resonator 72 and one parallel piezoelectric thin film resonator 74 are ladder-connected in an L shape.
- the piezoelectric filter 100 shown in FIG. 10b is a lattice type filter in which piezoelectric thin film resonators are connected in a lattice shape. In this case, a balanced-balanced filter is created.
- the piezoelectric filter 110 shown in FIG. 10c is a multimode filter. In this case, a highly selective filter can be obtained.
- piezoelectric filters 70, 100, and 110 use piezoelectric thin film resonators that can ensure the strength of the membrane without impairing the resonance characteristics, so that the desired frequency characteristics with high reliability as a piezoelectric filter are obtained. Is possible.
- FIG. 11 is a circuit diagram of the duplexer 80 of the eleventh embodiment.
- the duplexer 80 is provided with an antenna terminal 82, a reception side terminal 84, and a transmission side terminal 86.
- the duplexer 80 includes a piezoelectric filter that passes only the reception frequency band and attenuates the transmission frequency band between the reception-side terminal 84 and the antenna terminal 82.
- a piezoelectric filter is provided between the transmission side terminal 86 and the antenna terminal 82 to pass only the transmission frequency band and attenuate the reception frequency band.
- These piezoelectric filters included in the duplexer 80 are constituted by the piezoelectric thin film resonators according to any one of the first to ninth embodiments.
- the piezoelectric filter included in the duplexer 80 is composed of a piezoelectric thin film resonator that can secure the strength of the membrane without impairing the resonance characteristics. Therefore, the duplexer 80 has a desired frequency characteristic with high reliability. Is possible.
- FIG. 12 is a principal block diagram of the communication device 90 according to the twelfth embodiment.
- the communication device 90 supports different systems such as a multi-band mobile phone, and can switch the reception frequency by using a switch SW.
- a duplexer 92 is connected to the antenna 91.
- the duplexer 92 is connected to two receiving circuits via the switch SW. That is, the reception-side RF piezoelectric filters 94 and 94a, the amplifiers 95 and 95a, and the reception-side mixers 93 and 93a are connected between the switch SW and the IF stage piezoelectric filters 99 and 99a, respectively.
- An amplifier 97 and a transmission side piezoelectric filter 98 constituting an RF stage are connected between the duplexer 92 and the transmission side mixer 96.
- This communication device 90 uses a piezoelectric filter duplexer constituted by a piezoelectric thin film resonator that can ensure the strength of the membrane without impairing the resonance characteristics, and thereby achieves a desired reliability with high reliability. It is possible to have frequency characteristics.
- the multi-band RF filter module for mobile phones is a communication device in which circuit elements including at least the reception-side RF piezoelectric filters 94 and 94a are modularized.
- the piezoelectric thin film resonator of each of the above embodiments includes a substrate and a piezoelectric body sandwiched between electrodes so that a sacrificial layer is formed between the substrates.
- the resonator is the main constituent element, and a reinforcing film is formed at the connection between the membrane and the substrate.
- the membrane is deformed.
- the stress is concentrated at this time. This is the connection between the substrate and the substrate (the vicinity of the boundary between the support portion and the floating portion).
- the reinforcing film is not formed in the vibrating portion of the piezoelectric thin film resonator, but is provided only in the region where the stress is concentrated, so that the strength of the membrane can be ensured without impairing the resonance characteristics.
- the resonator power is improved in heat dissipation to the substrate, and the resonator is excellent in power durability.
- the sacrificial layer type is preferred for device miniaturization.
- the number of steps is smaller in the sacrificial layer type, and the device can be manufactured at a lower cost.
- a metal film is formed as a part of the reinforcing film on the lower electrode and the upper electrode at the connection portion of the membrane and the substrate. Since the reinforcing film can reduce the wiring resistance of the piezoelectric thin film resonator, the insertion loss of the filter can be reduced and good filter characteristics can be obtained. By using a metal film having a high thermal conductivity, the heat dissipation is further improved, and a resonator with better power durability is obtained.
- the thickness of the reinforcing film be in the range in which notching can be easily formed for both the metal film and the insulating film.
- the thicker the reinforcing film the greater the reinforcing effect.
- the reinforcing film is too thick, the membrane will be destroyed by stress.
- a recess may be provided in the substrate.
- the taper angle of the floating portion be smaller than the taper angle of the concave portion with which the support portion is in contact in the vicinity of the boundary between the support portion and the floating portion of the thin film portion.
Landscapes
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
Abstract
Description
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006535033A JP4432972B2 (ja) | 2004-09-10 | 2005-05-09 | 圧電薄膜共振子 |
| US11/715,359 US7327209B2 (en) | 2004-09-10 | 2007-03-08 | Piezoelectric thin film resonator |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004-264281 | 2004-09-10 | ||
| JP2004264281 | 2004-09-10 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/715,359 Continuation US7327209B2 (en) | 2004-09-10 | 2007-03-08 | Piezoelectric thin film resonator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2006027873A1 true WO2006027873A1 (ja) | 2006-03-16 |
Family
ID=36036167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2005/008427 Ceased WO2006027873A1 (ja) | 2004-09-10 | 2005-05-09 | 圧電薄膜共振子 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7327209B2 (ja) |
| JP (1) | JP4432972B2 (ja) |
| CN (1) | CN100578928C (ja) |
| WO (1) | WO2006027873A1 (ja) |
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| EP2003775A4 (en) * | 2006-04-05 | 2011-04-27 | Murata Manufacturing Co | PIEZOELECTRIC RESONATOR AND PIEZOELECTRIC FILTER |
| WO2011048910A1 (ja) * | 2009-10-22 | 2011-04-28 | 太陽誘電株式会社 | 圧電薄膜共振子 |
| JP2011167021A (ja) * | 2010-02-14 | 2011-08-25 | Canon Inc | 静電容量型電気機械変換装置 |
| JP2015008509A (ja) * | 2011-02-25 | 2015-01-15 | 株式会社村田製作所 | 可変容量素子及びチューナブルフィルタ |
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| US11431318B2 (en) * | 2018-12-14 | 2022-08-30 | Samsung Electro-Mechanics Co., Ltd. | Acoustic resonator and method of manufacturing thereof |
| CN113285685B (zh) * | 2021-03-05 | 2022-12-09 | 广州乐仪投资有限公司 | 石英薄膜体声波谐振器及其加工方法、电子设备 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61127216A (ja) * | 1984-11-26 | 1986-06-14 | Toshiba Corp | 圧電薄膜共振子 |
| JPS63305608A (ja) * | 1987-06-06 | 1988-12-13 | Kazuhiko Yamanouchi | 弾性振動を用いた圧電性薄膜複合共振子及びフィルタ |
| JPS6473782A (en) * | 1987-09-16 | 1989-03-20 | Canon Kk | Manufacture of non-ferroelectric piezoelectric thin film and method of searching piezoelectric axis sign |
| JPH0418806A (ja) * | 1990-05-14 | 1992-01-23 | Toshiba Corp | 圧電薄膜デバイス |
| JP2001168674A (ja) * | 1999-12-09 | 2001-06-22 | Murata Mfg Co Ltd | 圧電共振子及び電子機器 |
| JP2003017973A (ja) * | 2001-07-02 | 2003-01-17 | Murata Mfg Co Ltd | 圧電共振子、フィルタ、電子通信機器、圧電共振子の製造方法 |
| JP2003163566A (ja) * | 2001-11-22 | 2003-06-06 | Toshiba Corp | 薄膜圧電共振器及びその製造方法 |
| JP2003238292A (ja) * | 2002-02-14 | 2003-08-27 | Canon Inc | 蛍石結晶の製造方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60189307A (ja) * | 1984-03-09 | 1985-09-26 | Toshiba Corp | 圧電薄膜共振器およびその製造方法 |
| JPS61127217A (ja) | 1984-11-26 | 1986-06-14 | Toshiba Corp | 圧電薄膜共振子 |
| JPS61218214A (ja) | 1985-03-25 | 1986-09-27 | Toshiba Corp | 圧電薄膜共振子 |
| JPH0640611B2 (ja) | 1985-03-25 | 1994-05-25 | 株式会社東芝 | 圧電薄膜共振子 |
| JPS6294008A (ja) | 1985-10-19 | 1987-04-30 | Murata Mfg Co Ltd | 圧電薄膜共振子 |
| JPS62200813A (ja) | 1986-02-28 | 1987-09-04 | Toshiba Corp | 圧電薄膜共振子 |
| JPH0640611A (ja) | 1992-07-22 | 1994-02-15 | Konica Corp | 記録紙手差し装置 |
| JPH06204776A (ja) | 1992-12-28 | 1994-07-22 | Oki Electric Ind Co Ltd | 圧電薄膜振動子の製造方法 |
| JPH0878995A (ja) | 1994-09-02 | 1996-03-22 | Murata Mfg Co Ltd | 圧電部品 |
| JPH0878997A (ja) | 1994-09-02 | 1996-03-22 | Murata Mfg Co Ltd | 圧電共振子及びその製造方法 |
| JPH10200369A (ja) | 1997-01-13 | 1998-07-31 | Mitsubishi Materials Corp | 圧電薄膜共振子 |
| JPH11205062A (ja) | 1998-01-09 | 1999-07-30 | Toyo Commun Equip Co Ltd | 高周波二重モード圧電フィルタの製造法 |
| JP4759117B2 (ja) | 2000-06-22 | 2011-08-31 | 日本特殊陶業株式会社 | 金属酸化物膜付き基板及び金属酸化物膜付き基板の製造方法 |
| KR100413589B1 (ko) | 2000-07-04 | 2003-12-31 | (주)레드폭스아이 | 실시간 경제 변수 지표를 도입한 복권 구입 및 판매 시스템 |
| KR100398363B1 (ko) | 2000-12-05 | 2003-09-19 | 삼성전기주식회사 | Fbar 소자 및 그 제조방법 |
| JP3903848B2 (ja) * | 2001-07-02 | 2007-04-11 | 株式会社村田製作所 | 圧電共振子、圧電共振子の製造方法、圧電フィルタ、圧電フィルタの製造方法、デュプレクサおよび電子通信機器 |
| JP2003283292A (ja) | 2002-01-15 | 2003-10-03 | Murata Mfg Co Ltd | 圧電共振子およびそれを用いたフィルタ・デュプレクサ・通信装置 |
| US20030141946A1 (en) | 2002-01-31 | 2003-07-31 | Ruby Richard C. | Film bulk acoustic resonator (FBAR) and the method of making the same |
| JP2004072715A (ja) | 2002-06-11 | 2004-03-04 | Murata Mfg Co Ltd | 圧電薄膜共振子、圧電フィルタ、およびそれを有する電子部品 |
| JP3879643B2 (ja) | 2002-09-25 | 2007-02-14 | 株式会社村田製作所 | 圧電共振子、圧電フィルタ、通信装置 |
| JP2005033262A (ja) | 2003-07-07 | 2005-02-03 | Murata Mfg Co Ltd | 圧電共振子、圧電フィルタおよびそれを有する電子機器 |
| JP3945486B2 (ja) * | 2004-02-18 | 2007-07-18 | ソニー株式会社 | 薄膜バルク音響共振子およびその製造方法 |
-
2005
- 2005-05-09 JP JP2006535033A patent/JP4432972B2/ja not_active Expired - Fee Related
- 2005-05-09 WO PCT/JP2005/008427 patent/WO2006027873A1/ja not_active Ceased
- 2005-05-09 CN CN200580029867A patent/CN100578928C/zh not_active Expired - Fee Related
-
2007
- 2007-03-08 US US11/715,359 patent/US7327209B2/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61127216A (ja) * | 1984-11-26 | 1986-06-14 | Toshiba Corp | 圧電薄膜共振子 |
| JPS63305608A (ja) * | 1987-06-06 | 1988-12-13 | Kazuhiko Yamanouchi | 弾性振動を用いた圧電性薄膜複合共振子及びフィルタ |
| JPS6473782A (en) * | 1987-09-16 | 1989-03-20 | Canon Kk | Manufacture of non-ferroelectric piezoelectric thin film and method of searching piezoelectric axis sign |
| JPH0418806A (ja) * | 1990-05-14 | 1992-01-23 | Toshiba Corp | 圧電薄膜デバイス |
| JP2001168674A (ja) * | 1999-12-09 | 2001-06-22 | Murata Mfg Co Ltd | 圧電共振子及び電子機器 |
| JP2003017973A (ja) * | 2001-07-02 | 2003-01-17 | Murata Mfg Co Ltd | 圧電共振子、フィルタ、電子通信機器、圧電共振子の製造方法 |
| JP2003163566A (ja) * | 2001-11-22 | 2003-06-06 | Toshiba Corp | 薄膜圧電共振器及びその製造方法 |
| JP2003238292A (ja) * | 2002-02-14 | 2003-08-27 | Canon Inc | 蛍石結晶の製造方法 |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2003775A4 (en) * | 2006-04-05 | 2011-04-27 | Murata Manufacturing Co | PIEZOELECTRIC RESONATOR AND PIEZOELECTRIC FILTER |
| KR101238360B1 (ko) * | 2006-08-16 | 2013-03-04 | 삼성전자주식회사 | 공진기 및 그 제조 방법 |
| JP2008048380A (ja) * | 2006-08-16 | 2008-02-28 | Samsung Electronics Co Ltd | 共振器およびその製造方法 |
| US7795692B2 (en) | 2006-08-16 | 2010-09-14 | Samsung Electronics Co., Ltd. | Resonator and fabrication method thereof |
| JP5018788B2 (ja) * | 2007-01-24 | 2012-09-05 | 株式会社村田製作所 | 圧電共振子及び圧電フィルタ |
| US7924120B2 (en) | 2007-01-24 | 2011-04-12 | Murata Manufacturing Co., Ltd. | Piezoelectric resonator and piezoelectric filter having a heat-radiating film |
| JPWO2008090651A1 (ja) * | 2007-01-24 | 2010-05-13 | 株式会社村田製作所 | 圧電共振子及び圧電フィルタ |
| WO2008090651A1 (ja) * | 2007-01-24 | 2008-07-31 | Murata Manufacturing Co., Ltd. | 圧電共振子及び圧電フィルタ |
| WO2011048910A1 (ja) * | 2009-10-22 | 2011-04-28 | 太陽誘電株式会社 | 圧電薄膜共振子 |
| US8450906B2 (en) | 2009-10-22 | 2013-05-28 | Taiyo Yuden Co., Ltd. | Piezoelectric thin-film resonator |
| JP2011167021A (ja) * | 2010-02-14 | 2011-08-25 | Canon Inc | 静電容量型電気機械変換装置 |
| JP2015008509A (ja) * | 2011-02-25 | 2015-01-15 | 株式会社村田製作所 | 可変容量素子及びチューナブルフィルタ |
| US11050409B2 (en) | 2019-04-16 | 2021-06-29 | Samsung Electro-Mechanics Co., Ltd. | Acoustic resonator and acoustic resonator filter |
| JP2021150724A (ja) * | 2020-03-17 | 2021-09-27 | 太陽誘電株式会社 | 弾性波デバイスおよびフィルタ |
| JP7485479B2 (ja) | 2020-03-17 | 2024-05-16 | 太陽誘電株式会社 | フィルタ |
| US12255604B2 (en) | 2020-03-17 | 2025-03-18 | Taiyo Yuden Co., Ltd. | Acoustic wave device and filter |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2006027873A1 (ja) | 2008-05-08 |
| CN101010875A (zh) | 2007-08-01 |
| JP4432972B2 (ja) | 2010-03-17 |
| US20070152775A1 (en) | 2007-07-05 |
| US7327209B2 (en) | 2008-02-05 |
| CN100578928C (zh) | 2010-01-06 |
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