WO2006022254A1 - 電極用複合粒子およびその製造法、ならびに二次電池 - Google Patents
電極用複合粒子およびその製造法、ならびに二次電池 Download PDFInfo
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- WO2006022254A1 WO2006022254A1 PCT/JP2005/015265 JP2005015265W WO2006022254A1 WO 2006022254 A1 WO2006022254 A1 WO 2006022254A1 JP 2005015265 W JP2005015265 W JP 2005015265W WO 2006022254 A1 WO2006022254 A1 WO 2006022254A1
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- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 150000002641 lithium Chemical group 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000007734 materials engineering Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- HDKLIZDXVUCLHQ-UHFFFAOYSA-N non-3-en-2-one Chemical compound CCCCCC=CC(C)=O HDKLIZDXVUCLHQ-UHFFFAOYSA-N 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000002296 pyrolytic carbon Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002409 silicon-based active material Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/34—Length
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/36—Diameter
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to composite particles obtained by improving active material particles capable of charge / discharge, and more particularly to active material particles in which a single bon nanofiber is bonded to the surface.
- the present invention also relates to a method for efficiently growing carbon nanofibers on the surface of an active material.
- the present invention further relates to a non-aqueous electrolyte secondary battery capacitor having excellent initial charge / discharge characteristics or cycle characteristics.
- the contained metal oxide has been put into practical use.
- Patent Document 1 It has been studied to use fine graphite powder or carbon black as a conductive agent. By using these conductive agents, the initial charge / discharge characteristics of the battery are improved.
- Patent Document 1 Si and its oxides have particularly poor conductivity, it has been proposed to coat the surface thereof with carbon. The carbon coating is performed by a CVD (chemical vapor deposition) method. Carbon coating ensures electronic conductivity and reduces electrode plate resistance before charging (Patent Documents 2 and 3). It has also been proposed to use carbon nanofibers known to exhibit high conductivity as a conductive agent (Patent Document 4).
- Non-patent Document 1 Non-patent Document 1
- Non-patent Document 2 Various carbon types are being investigated for the conductive agent. Studies have also been conducted on the shape of carbon species and the amount of additive (Patent Documents 5, 6, and 7).
- the methods for synthesizing the carbon nanofiber include the following two methods.
- the first method is an arc discharge method in which a fiber is grown by arc discharge between carbon electrodes. It has been reported that single-walled carbon nanotubes (SWNTs) or multi-walled carbon nanotubes (MWNTs), which are a type of carbon nanofiber, are produced by the arc discharge method. At the same time, however, a lot of other carbon soot is generated. Therefore, the production rate (yield) of carbon nanofiber is very small. Furthermore, separation work between carbon nanofibers and carbon soot is required, which is not practical.
- SWNTs single-walled carbon nanotubes
- MWNTs multi-walled carbon nanotubes
- the second method is a method in which a carbon nanofiber is vapor-phase grown by bringing a mixed gas of hydrogen gas and organic gas into contact with a metal catalyst in a high temperature atmosphere.
- the reason why the organic gas is mixed with hydrogen gas is to activate the catalyst.
- the catalytic activity is reduced only with organic gas, and the conversion rate of the raw material gas to carbon nanofibers is reduced. Or, the catalyst becomes inactive and the formation of carbon nanofibers cannot be confirmed (Non-patent Documents 3 and 4, Patent Document 8).
- carbon nanofibers are vapor-phased on the surface of the electrode active material containing metal or metalloid.
- the production rate of carbon nanofibers is low.
- the catalyst is easily detached from the active material surface. Therefore, even if an electrode is fabricated using an active material on which carbon nanofibers are grown, the construction of an electron conduction network is incomplete. Therefore
- Patent Document 9 In electrochemical devices such as capacitors and secondary batteries, the expected cycle characteristics cannot be improved (Patent Document 9).
- Patent Document 1 Japanese Patent Laid-Open No. 4-188560
- Patent Document 2 Japanese Patent Laid-Open No. 2002-42806
- Patent Document 3 Japanese Patent Laid-Open No. 2004-47404
- Patent Document 4 Japanese Patent Laid-Open No. 2003-77476
- Patent Document 5 JP-A-60-65462
- Patent Document 6 Japanese Patent Laid-Open No. 4-190561
- Patent Document 7 Japanese Patent Laid-Open No. 4-215252
- Patent Document 8 Japanese Patent Laid-Open No. 2001-196064
- Patent Document 9 Japanese Unexamined Patent Application Publication No. 2004-349056
- Non-Patent Document 1 “Electrochemistry”, 2003, No. 71, No. 12, p. 1105-1107
- Non-Patent Document 2 Edited by Satoshi Kanamura, “21st Century Lithium Secondary Battery Technology”, CMC Publishing, p. 1 25-128
- Non-Patent Document 3 Michio Inagaki, “Carbon Materials Engineering”, published by Nikkan Kogyo Shimbun, December 1987 23 0, p. 72-76
- Non-Patent Document 4 Sumio Iijima et al., “Carbon Nanotubes”, CMC Publishing, 2001, January 10, p. 1-25
- lithium-containing metal oxides also have poor conductivity
- various carbon species it has been proposed to use various carbon species as a conductive agent.
- the lithium-containing metal oxide repeats the lithium insertion reaction and the elimination reaction during the charge / discharge cycle. Therefore, the active material particles repeat expansion and contraction. For this reason, the electron conduction network between the particles is gradually cut, and it is difficult to realize excellent high power discharge characteristics and cycle characteristics.
- the density difference between the conductive agent and the lithium-containing metal oxide is very large. Therefore, it is extremely difficult to uniformly mix the lithium-containing metal oxide and the conductive agent.
- the active material When carbon nanofibers are grown on the surface of the active material, the active material may be dissolved or altered by heat in the arc discharge method. Also, it is difficult and inefficient to separate carbon soot.
- the active material is impregnated in an aqueous solution or an organic solution containing the catalyst element, and then dried to remove the solvent component.
- the catalyst element sulfate, nitrate, chloride and the like are dissolved in the solution. These salts sublime in a high temperature atmosphere. Therefore, it is necessary to perform heat treatment once in an oxygen-containing atmosphere and convert it into a metal oxide that does not sublime. Furthermore, the metal oxide must be returned to the metallic state using a large amount of hydrogen gas in a high temperature atmosphere before the synthesis of the carbon nanofiber. Therefore, a large amount of hydrogen gas is required, and the conversion rate of the raw material gas to the carbon nanofiber is also reduced. [0020] If the step of converting the salt of the catalytic element into a metal oxide is omitted, the formation of carbon nanofibers is not recognized.
- the conversion rate of the raw material gas into carbon nanofibers becomes extremely small.
- the catalytic element supported on the active material surface tends to be peeled off by the step of converting the salt into a metal oxide or the step of reducing the metal oxide to a metal state.
- carbon nanofibers that are not bonded to the active material are produced. Therefore, even if an electrode is produced using composite particles grown with carbon nanofibers, the construction of the electron conduction network is incomplete. As a result, the charge / discharge characteristics and cycle characteristics of capacitors, secondary batteries, and the like deteriorate.
- a reaction vessel made of stainless steel is inexpensive and easy to increase in size.
- SUS stainless steel
- the carbon reaction vessel has high resistance to hydrogen reduction and is excellent in terms of points. However, under the coexistence of hydrogen gas and catalyst, carbon hydrogenation or gasification reaction proceeds, and the reaction vessel deteriorates.
- the composite particle for an electrode of the present invention includes active material particles, carbon nanofino bonded to the surface of the active material particles, and a catalytic element that promotes the growth of carbon nanofibers.
- the active material particles include an electrochemically active phase.
- the composite particles for electrodes can be obtained by growing carbon nanofibers on the surface of the active material particles in which the catalytic element is present.
- the composite particles for an electrode may further contain other elements in addition to the active material particles, the carbon nanofibers, and the catalytic element within the range of! / ⁇ .
- other elements include conductive polymers.
- the electrode composite particles may be composed of only active material particles, carbon nanofibers, and catalytic elements.
- the catalytic element is preferably at least one selected from the group consisting of Au, Ag, Pt, Ru, Ir, Cu, Fe, Co, Ni, Mo, and Mn.
- the catalyst element has a particle size of Inn! It is preferably present in the state of lOOOnm metal particles or Z and metal oxide particles (catalyst particles). That is, the catalyst particles may be in the form of metal particles or in the form of metal oxide particles.
- the catalyst particles may be particles containing a metal and a metal oxide. Two or more kinds of catalyst particles may be used in combination.
- the particle size of the catalyst particles can be measured by SEM observation, TEM observation or the like.
- the catalyst particles are present on the surface layer of the active material particles and the free ends of the Z or carbon nanofibers. That is, the present invention includes the case where the catalyst element is present at least in the surface layer portion of the active material particles and the case where the catalyst element is supported on the growth end of the carbon nanofiber. In the latter case, the catalyst element may be further present in the surface layer portion of the active material particles. The catalytic element may be further present inside the active material particles.
- At least one end of the carbon nanofiber is bonded to the surface of the active material particle without passing through the resin component.
- the carbon nanofiber is bonded to the active material particle on the surface of the active material particle that is the starting point of the growth.
- the carbon nanofiber is chemically bonded to the surface of the active material particle at least at one end which is the starting point of the growth.
- the growth end of the carbon nanofiber is usually the free end.
- both ends of the carbon nanofiber may be bonded to the surface of the active material particles.
- the catalytic element does not desorb the active material particle force even when the carbon nanofiber grows, the catalytic element is present at the fixed end of the carbon nanofiber. That is, the catalytic element is present at the bonding portion between the force-bonding nanofiber and the active material particles. In this case, composite particles for electrodes in a state where the catalytic element is supported on the active material particles can be obtained.
- the catalytic element When the catalytic element is detached from the active material particle force as the carbon nanofiber grows, the catalytic element is present at the tip of the carbon nanofiber, that is, the free end.
- composite particles for an electrode in which one end of the carbon nanofiber is bonded to the surface of the active material particle and the other end carries a catalytic element can be obtained.
- carbon nanofibers in which the catalytic element is present at the fixed end and carbon nanofibers in which the catalytic element is present at the free end may be mixed.
- One active material particle may be bonded to a carbon nanofiber in which the catalytic element is present at the fixed end and a carbon nanofiber in which the catalytic element is present at the free end.
- the catalytic element Until the growth of the carbon nanofibers is completed, it is desired that the catalytic element exhibits good catalytic action.
- the catalytic element is used for the surface layer portion of the active material particles and
- the fiber length of the carbon nanofiber is, for example, lnm to Lmm.
- Carbon nanofibers have a fiber diameter of Inn! From the viewpoint of improving the electronic conductivity of composite particles. It is more preferable to include a fine fiber having a fiber diameter of 1 nm to 40 nm and a large fiber having a fiber diameter of 40 to 200 nm.
- the fiber length and fiber diameter can be measured by SEM observation, TEM observation, and the like.
- the carbon nanofibers preferably include at least one selected from the group force consisting of tube-shaped carbon, accordion-shaped carbon, plate-shaped carbon, and Hering'bone-shaped carbon.
- the carbon nanofibers may include carbon nanofibers in other states which may be at least one kind of force selected from the group force.
- the composite particles for an electrode of the present invention can be classified into the following categories A to C.
- the electrochemically active phase of the composite particle for electrode of category A is, for example, a compound of at least one metal or metalloid element selected from the group power consisting of Group 3B, 4B and 5B elements of the periodic table, or Including alloy or simple substance.
- the compound is preferably at least one selected from the group consisting of oxides, nitrides, oxynitrides, carbides and sulfides.
- the electrochemically active phase contains at least an oxide, it is desirable that the oxide is amorphous.
- the alloy is preferably a metal alloy of a metalloid element and a transition metal element from the viewpoint of improving the electronic conductivity of the composite particles.
- Examples of the metals or metalloid elements of groups 3B, 4B, and 5B of the periodic table include Al, Si, Ga, Ge, Ir, Sn, Sb, Tl, Pb, and Bi. Of these, Si, Sn, Ge and the like are preferable from the viewpoint of obtaining a material having a high energy density.
- Metal or metalloid elements are Si, Sn and And at least one selected from the group force consisting of Ge, the compound is preferably at least one selected from the group force consisting of oxide, nitride and oxynitride.
- examples of the oxide include SnO, SnO, GeO, GeO, PbO, and SbO.
- Si which is a metalloid element
- Si is promising as a high-capacity active material because it has the ability to occlude lithium.
- the reaction in which a single element of lithium absorbs and releases lithium electrochemically involves a very complicated crystal change.
- the composition and crystal structure of Si are: Si (crystal structure: Fd3m), LiSi (crystal structure: I4lZa), Li Si (crystal structure).
- the volume of Si expands by about 4 times. Therefore, as the charge / discharge cycle is repeated, the destruction of the active material particles proceeds. In addition, the formation of a bond between lithium and cage damages the lithium insertion site that was initially contained in the cage and significantly reduces the cycle life.
- the key atom is covalently bonded to the oxygen atom. Therefore, in order to bond to Si force S lithium, it is necessary to break the covalent bond between the silicon atom and the oxygen atom. Therefore, even when lithium is inserted, the destruction of the oxygen skeleton is likely to be suppressed. In other words, the reaction between lithium oxide and Li is considered to proceed while maintaining the oxide oxide skeleton. Similar effects can be expected for compounds of other metalloid elements.
- oxides, nitrides and sulfides are advantageous in that the catalyst element can be reliably fixed on the surface of the active material particles. This is presumably because oxygen, nitrogen or ion atoms existing on the surface of the active material particles are combined with the catalytic element. In addition, due to the electron withdrawing effect of oxygen, nitrogen or nitrogen atoms on the surface of the active material particles, the catalyst element is converted to metal. Thus, it is considered that high catalytic activity can be obtained even under mild and reducing conditions.
- an oxide layer on the surface of the active material particles. That is, as active material particles, a nucleus composed of at least one metal or metalloid element selected from the group force consisting of Group 3B, 4B and 5B elements of the periodic table, and an acid covering the surface of the nucleus. It is also possible to use particles having a dielectric layer. For example, active material particles having a nucleus that also has a single elemental force and an oxide silicon (SiO or SiO 2) layer covering the surface of the nucleus can be preferably used. Suppresses destruction of active material particles
- the thickness of the oxide layer is preferably 5 to 20 nm.
- an oxide layer having a suitable thickness can be formed by baking acid hikelite in the atmosphere for 0.5 hour or longer.
- the electrochemically active phase of [B] category B electrode composite particles includes at least one metal element selected from the group force consisting of, for example, Cu, Fe, Co, Ni, Mo, and Mn.
- Examples of such an electrochemically active phase include a lithium-containing transition metal oxide having a layered structure (eg, R3m). In lithium-containing transition metal oxides, oxygen preferably has a cubic close-packed arrangement. Examples of lithium-containing transition metal oxides include Li M L O (where 0 ⁇ 1.2, 0 ⁇ y ⁇ , such as LiCoO and LiNiO).
- Element M is at least one selected from the group forces of Co and NU.
- Element L is from the group consisting of Al, Mn, Mg, Ti, Cr, Fe, Nb, Mo, Ta, Zr and Sr. And at least one selected). Also, olivine such as LiFePO and LiCoPO
- the electrochemically active phase of the composite particles for [C] category C electrodes is, for example, RuO, MoO
- Category A composite particles for electrodes are suitable as negative electrode materials for non-aqueous electrolyte secondary batteries.
- Category B electrode composite particles are suitable as cathode materials for non-aqueous electrolyte secondary batteries.
- Category C electrode composite particles are suitable as electrode materials for electrochemical capacitors.
- the present invention also comprises an electrochemically active phase, and at least the surface layer portion has carbon nanofibers.
- Step A for preparing active material particles having a catalytic element for promoting Aiba growth A
- Step B for growing carbon nanofibers on the surface of the active material particles in an atmosphere containing a carbon-containing gas, and an inert gas atmosphere
- the present invention relates to a method for producing composite particles for an electrode, including a step C in which active material particles bonded with carbon nanofibers are fired at 400 ° C to 1600 ° C.
- Step A is, for example, selected from the group consisting of Au, Ag, Pt, Ru, Ir, Cu, Fe, Co, Ni, Mo, and Mn on the surface of the particle that is the electrochemically active phase.
- Step A reduces, for example, the surface of particles composed of an electrochemically active phase containing at least one metal element selected from the group consisting of Cu, Fe, Co, Ni, Mo, and Mn. Process.
- Step A includes, for example, at least one metal or metalloid element selected from the group force consisting of Group 3B, 4B and 5B elements of the periodic table and Cu, Fe, Co, Ni, Mo and Mn.
- the production method of the present invention preferably has a step of heat-treating the composite particles at 100 ° C or higher and 400 ° C or lower in the air after step C.
- the catalytic element can be oxidized. If heat treatment is performed at 100 ° C or more and 400 ° C or less, it is possible to oxidize only metal elements without oxidizing the carbon nanofibers.
- the carbon-containing gas is ethylene
- the carbon nanofino is in the form of a ring-bone 'bone is particularly preferable. -This is because the ring-bone-like carbon is made of low crystalline carbon, so that the flexibility and the expansion and contraction of the active material accompanying charge / discharge are easy to relax.
- the present invention further relates to a nonaqueous electrolyte secondary battery including a positive electrode capable of charging and discharging lithium, a negative electrode including category A composite particles, and a nonaqueous electrolyte.
- the present invention further relates to a non-aqueous electrolyte secondary battery including a positive electrode including composite particles of category B, a negative electrode capable of charging and discharging lithium, and a non-aqueous electrolyte.
- the present invention further relates to a non-aqueous electrolyte secondary battery including a positive electrode including category B composite particles, a negative electrode including category A composite particles, and a non-aqueous electrolyte.
- the present invention further relates to an electrochemical capacitor comprising a pair of polarizable electrodes containing category C composite particles, a separator disposed between both electrodes, and an aqueous solution or non-aqueous electrolyte.
- the present invention also includes a step of supporting a catalytic element that promotes the growth of carbon nanofibers on the surface of the active material, and an active material supporting the catalytic element in contact with a raw material gas, thereby bringing the active material into contact.
- the active material includes an oxide
- the source gas is composed of a carbon-containing gas or a mixed gas of carbon-containing gas and hydrogen gas, and contains carbon.
- the gas is carbon monoxide (CO), saturated carbonization represented by CH (n ⁇ l) n 2n + 2
- the present invention relates to a method for producing composite particles for electrodes in which the content of hydrogen gas in the mixed gas of carbon-containing gas and hydrogen gas is less than 5% by volume.
- the active material contains at least an oxide in the surface layer portion thereof.
- the oxide constituting the active material is mainly a metal oxide.
- the catalyst element may be supported at least on the surface layer portion of the active material.
- a raw material gas and an active material supporting a catalytic element are introduced into the reaction vessel, and the temperature in the reaction vessel is set to 400 to 750 ° C. Hold on. As a result, carbon nanofibers that are bonded to the surface of the active material grow.
- At least one material selected from the group force consisting of pig iron, carbon (for example, graphite or glassy carbon) and alumina can be used.
- pig iron carbon is preferred because of its high workability.
- the production method of the present invention includes, for example, a group consisting of Au, Ag, Pt, Ru, Ir, Cu, Fe, Co, Ni, Mo, and Mn in an active material containing at least an oxide in the surface layer
- a step of supporting at least one selected catalyst element in the form of a salt or a compound, for example, and a raw material gas that may contain less than 5% by volume of hydrogen gas together with an active material supporting the catalyst element, are 400 to 75 introducing into a reaction vessel maintained at o ° C., and growing carbon nanofibers on the surface of the active material.
- the present invention also includes a pair of polarizable electrodes containing an active material produced by any one of the methods described above, a separator disposed between both electrodes, and an aqueous solution or a non-aqueous electrolyte. It relates to electrochemical capacitors. Electrochemical capacitors include electric double layer capacitors, redox capacitors and the like. Polarized electrodes include ruthenium oxide electrodes and manganese oxide electrodes.
- the present invention further includes a positive electrode, a negative electrode, a separator disposed between both electrodes, and a non-aqueous electrolyte, and at least one of the positive electrode and the negative electrode is produced by any one of the methods described above.
- the present invention relates to a secondary battery containing an active material. Secondary batteries include lithium ion secondary batteries
- the active material refers to a material that can electrochemically store electric capacity, that is, a material composed of an electrochemically active phase.
- the active material is usually in the state of powder, granules, flakes, etc.
- the catalytic element refers to an element that is mainly in a metallic state and has activity for the growth of carbon nanofibers.
- the salt or compound of the catalytic element is, for example, sulfate, nitrate, chloride, etc., specifically, nickel nitrate, cobalt nitrate, iron nitrate, nickel chloride, cobalt chloride, iron chloride, nickel sulfate, cobalt sulfate, Examples thereof include iron sulfate, nickel hydroxide, cobalt hydroxide, iron hydroxide, nickel carbonate, cobalt carbonate, iron carbonate, nickel acetate, cobalt acetate, iron acetate, nickel oxide, cobalt oxide, and iron oxide.
- the carbon nanofiber is bonded to the surface of the active material particle. Therefore, an electrode including the composite particles for an electrode provides a battery having excellent initial charge / discharge characteristics with high electron conductivity. Further, even if the active material particles are repeatedly expanded and contracted, the contact between the carbon nanofibers and the active material particles is always maintained. Therefore, if the composite particles for electrodes of the present invention are used, a battery having excellent charge / discharge cycle characteristics can be obtained.
- the carbon nanofiber functions as a buffer layer that absorbs stress accompanying expansion and contraction of the active material particles. Therefore, the positive electrode and the negative electrode are wound through a separator. Even in the electrode group, buckling is suppressed. In addition, cracking of the current collector due to buckling is suppressed.
- the active material is an oxide
- the oxygen element present in the active material and the catalytic element are bonded by intermolecular force, ionic bond, or the like. Therefore, it is possible to suppress the sublimation of catalyst elements such as sulfates, nitrates, and chlorides before starting the growth of carbon nanofibers. Further, the catalytic element is reliably fixed on the active material surface. Therefore, it is possible to omit conversion to metal oxides such as sulfates, nitrates, and salts.
- the catalytic element When the active material is an oxide, the catalytic element is brought into a metal state only by temperature control even in a low hydrogen concentration atmosphere or an atmosphere not containing hydrogen gas due to the electron withdrawing effect of oxygen atoms on the surface of the active material. Can be reduced. As a result, the amount of carbon-containing gas in the source gas can be increased, and the conversion rate of the source gas into carbon nanofibers can be dramatically improved. That is, when the active material is an oxide, the conversion rate of the raw material gas to the carbon nanofiber can be greatly improved by a simple process. In addition, it is possible to use a reaction vessel having a material strength other than stone. Therefore, it is easy to increase the size of the reaction apparatus.
- FIG. 1 is a diagram conceptually showing the structure of a composite particle of the present invention.
- FIG. 2 is a diagram conceptually showing the structure of another composite particle of the present invention.
- FIG. 3 is a 500 times magnified SEM photograph of the composite particle surface obtained in Example 1.
- FIG. 4 is a 50000 times magnified SEM photograph of the main part of the composite particle surface obtained in Example 1.
- FIG. 5 is a 30000 times magnified SEM photograph of the main part of the composite particle surface obtained in Example 1.
- the composite particles for an electrode of the present invention include active material particles, carbon nanofibers bonded to the surface of the active material particles, and a catalytic element that promotes the growth of carbon nanofibers.
- the active material particles are composed of an electrochemically active phase.
- the active material particles preferably have a single particle force rather than a granulated body having a plurality of particle forces. Single particles are charged and discharged Difficult to cause collapse due to expansion and contraction. From the viewpoint of suppressing cracking of the particles as much as possible, the average particle size of the active material particles made of a single particle is preferably 1 to 20 / ⁇ ⁇ . Since a granulated body composed of a plurality of particles has a particle size larger than the above range, it may collapse due to expansion and contraction stress during charge and discharge.
- the catalyst element is not particularly limited, but at least one selected from the group force consisting of Au, Ag, Pt, Ru, Ir, Cu, Fe, Co, Ni, Mo and Mn can be preferably used.
- the catalytic element is preferably in a metal state or an acid state.
- the catalytic element is preferably present in a metallic state.
- the catalyst element has a particle size of Inn! ⁇ Particle size 10 to preferably exist in the form of lOOOnm metal particles or oxide particles (catalyst particles): More preferably, it exists in the form of LOOnm catalyst particles.
- the catalytic element provides an active point for growing carbon nanofibers in the metallic state. That is, when the active material particles whose catalytic elements are exposed in a metallic state are introduced into a high-temperature atmosphere containing a carbon nanofiber source gas, the growth of carbon nanofibers proceeds. When no catalytic element is present on the surface of the active material particles, the growth of carbon nanofibers is not observed.
- the catalytic element may desorb the surface layer force of the active material particles.
- composite particles are obtained in which the catalyst particles are supported on the tips of the carbon nanofibers, that is, the free ends.
- a carbon nanofiber having a catalytic element at the surface layer portion of the active material particle, that is, a fixed end of the carbon nanofiber, and a carbon nanofiber having a catalytic element at the free end may be mixed.
- FIG. 1 conceptually shows the structure of an example of the composite particle for an electrode of the present invention.
- the composite particle 10 includes active material particles 11, catalyst particles 12 existing on the surface of the active material particles 11, and carbon nanofibers 13 grown based on the catalyst particles 12. Such composite particles are obtained when the carbon nanofiber grows but the catalytic element does not desorb from the active material particles. In this case, the catalyst particles are present at the joint between the surface of the active material particles and the carbon nanofibers, that is, at the fixed end.
- FIG. 2 conceptually shows the structure of another example of the composite particle for an electrode of the present invention.
- the composite particle 20 has one end bonded to the surface of the active material particle 21 and the active material particle 21.
- the carbon nanofiber 23 has catalyst particles 22 supported on the other end of the carbon nanofiber 23. Such composite particles are obtained when the catalyst particles are detached from the surface layer of the active material particles as the carbon nanofiber grows. In this case, the catalyst particles are present at the tip of the carbon nanofiber, ie, the free end.
- the catalyst particles 12 and 22 are made of a catalyst element and act as a catalyst for growing carbon nanofibers.
- the average particle diameter of the active material particles 11 and 21 is not particularly limited, but is preferably 1 to 20 ⁇ m.
- the method of providing the catalyst particles on the surface of the active material particles is not particularly limited.
- the method of supporting the catalyst particles on the surface of particles composed of an electrochemically active phase (Method 1), the active material containing the catalyst element.
- a method of reducing the surface of the material particles and generating catalyst particles on the surface of the active material particles (Method 2) is preferable.
- Method 1 can be applied to any particles that are composed of an electrochemically active phase.
- Method 2 can be applied only to active material particles containing a catalytic element.
- nickel nitrate hexahydrate, cobalt nitrate hexahydrate, iron nitrate nonahydrate, copper nitrate trihydrate, manganese nitrate hexahydrate, heptamolybdenum Forces that can include, but are not limited to, acid hexaamonium tetrahydrate.
- the solvent of the solution is selected in consideration of the solubility of the compound and compatibility with the electrochemically active phase.
- a suitable one is selected from water, an organic solvent, and a mixture of water and an organic solvent.
- the organic solvent for example, ethanol, isopropyl alcohol, toluene, benzene, hexane, tetrahydrofuran and the like can be used.
- active material particles containing a catalytic element such as LiCoO, LiNiO, LiMn 2 O
- the lithium-containing metal oxides such as 2 2 2 4 under a reducing gas atmosphere such as hydrogen gas.
- metal particles such as Co, Ni, and Mn can be generated on the particle surface.
- the particle size Inn! ⁇ LOOOnm preferably 10 to 100 nm catalyst particles can be produced.
- alloy particles containing a catalytic element can be synthesized and used as active material particles.
- an alloy of at least one metal or metalloid element and a catalytic element which is selected from the group force consisting of Group 3B, 4B and 5B elements, is synthesized by a normal alloy manufacturing method.
- a metal or metalloid element selected from Group 3B, 4B and 5B elements of the periodic table electrochemically reacts with Li to form a Li alloy, thus forming an electrochemically active phase.
- at least a part of the metal phase composed of the catalytic element is exposed on the surface of the alloy particles in the form of particles having a particle size of lOnm to 100 nm, for example.
- the catalyst particles are 0.01 weight of the active material particles. Desirably, it is 1% to 3% by weight. If the amount of the catalyst particles or catalytic metal power is too small, it takes a long time to grow the carbon nanofiber, which may reduce the production efficiency. On the other hand, if the amount of the catalyst phase or the metal phase serving as the catalytic element force is too large, carbon nanofibers with uneven and thick fiber diameters grow due to aggregation of the catalytic elements. This leads to a decrease in electrode conductivity and active material density. In addition, the proportion of the electrochemically active phase is relatively small, and it may be difficult to make the composite particles into a high-capacity electrode material.
- the fiber length of the carbon nanofiber is preferably from lnm to lmm, more preferably from 500nm to 500 ⁇ m. If the fiber length of the carbon nanofiber is less than 1 nm, the effect of increasing the conductivity of the electrode may be too small. On the other hand, when the fiber length exceeds lmm, the active material density and capacity of the electrode tend to decrease.
- the fiber diameter of the carbon nanofiber is more preferably 50 nm to 300 nm, more preferably In m to 1000 nm.
- a part of the carbon nanofiber is preferably a fine fiber having a fiber diameter of 1 nm to 40 nm from the viewpoint of improving the electronic conductivity of the composite particle.
- a fine fiber having a fiber diameter of 40 nm or less and a large fiber having a fiber diameter of 50 nm or more are included at the same time. More preferably.
- the amount of carbon nanofibers grown on the surface of the active material particles is desirably 5 to 150 parts by weight per 100 parts by weight of the active material particles. 10 to L00 parts by weight Is more preferable. If the amount of carbon nanofibers is too small, the effect of increasing the conductivity of the electrode or the charge / discharge characteristics and cycle characteristics of the battery may not be sufficiently obtained. Even if the amount of carbon nanofibers is large, there is no problem in terms of electrode conductivity, battery charge / discharge characteristics, and sanitary characteristics, but the electrode active material density and capacity are reduced.
- active material particles having a catalytic element at least in the surface layer portion are introduced into a high-temperature atmosphere containing a carbon nanofiber raw material gas
- the growth of the carbon nanofiber proceeds.
- active material particles are put into a ceramic reaction vessel and have inert gas or reducing power.
- the gas is heated to a high temperature of 100 to 1000 ° C, preferably 300 to 600 ° C.
- a carbon nanofiber source gas is introduced into the reaction vessel. If the temperature in the reaction vessel is less than 100 ° C, carbon nanofibers will not grow or grow too slowly, and productivity will be impaired.
- the temperature in the reaction vessel exceeds 1000 ° C, decomposition of the reaction gas is promoted and it becomes difficult to produce carbon nanofibers.
- a mixed gas of carbon-containing gas and hydrogen gas is suitable.
- the carbon-containing gas a gas containing a carbon element such as methane, ethane, ethylene, butane, carbon monoxide, and acetylene can be used.
- the mixing ratio of the carbon-containing gas and the hydrogen gas is preferably 2: 8 to 8: 2 in terms of molar ratio (volume ratio). If the catalyst element in the metallic state is not exposed on the surface of the active material particles, the ratio of hydrogen gas is controlled to be large. As a result, the reduction of the catalytic element and the growth of the carbon nanofiber can proceed in parallel.
- the active material contains an oxide
- a raw material gas containing no hydrogen gas may be used even if the ratio of hydrogen gas is low.
- the active material particles to which the carbon nanofibers are bonded are fired in an inert gas atmosphere at 400 ° C. or higher and 1600 ° C. or lower, for example, for 30 minutes to 2 hours.
- an inert gas atmosphere at 400 ° C. or higher and 1600 ° C. or lower, for example, for 30 minutes to 2 hours.
- the above-described irreversible reaction may not be suppressed, and the charge / discharge efficiency of the battery may decrease.
- the firing temperature exceeds 1600 ° C, the reaction between the electrochemically active phase of the active material particles and the carbon nanofibers proceeds. Therefore, the active phase may be deactivated or the electrochemically active phase may be reduced, causing a decrease in capacity.
- the electrochemically active phase of the active material particles is Si
- Si reacts with carbon nanofibers to generate inactive carbon carbide, which causes a decrease in charge / discharge capacity of the battery.
- lithium-containing oxides known as positive electrode active materials may be thermally reduced at temperatures exceeding 1000 ° C.
- the firing temperature of the lithium-containing oxide is particularly preferably 700 ° C or higher and 1000 ° C or lower.
- the firing temperature of Si is particularly preferably 1000 ° C or higher and 1600 ° C or lower.
- the composite particles after calcination in an inert gas further oxidize at least a part (for example, the surface) of metal particles or metal phases that are catalytic elemental forces in the atmosphere at 100 ° C or higher, Heat treatment is preferably performed at 400 ° C. or lower. When the heat treatment temperature is less than 100 ° C, it is difficult to oxidize the metal. When the heat treatment temperature exceeds 400 ° C, the grown carbon nanofibers may burn.
- the carbon nanofiber may take a catalytic element inside itself during the growth process.
- Carbon nanofibers grown on the surface of the active material particles may include tubes, accordion states, plate states, and herring 'bone states. Of these, carbon nanofibers in a herring 'bone state, which is in an amorphous state, are particularly preferred.
- Hering 'bone-state carbon nanofibers are flexible due to low carbon crystallinity and have a high ability to relieve stress due to expansion of active material particles.
- a copper-nickel alloy (molar ratio of copper to nickel is 3: 7) is used as the catalyst, and the reaction is performed at a temperature of 550 to 650 ° C. It is desirable to do. It is preferable to use ethylene gas or the like as the carbon-containing gas in the raw material gas.
- the mixing ratio of carbon-containing gas and hydrogen gas is a molar ratio (volume ratio), for example, a force in which 2: 8 to 8: 2 is suitable. The suitable range of the mixing ratio is considered to depend on the type of active material. .
- an iron-nickel alloy (molar ratio of iron to nickel: 6: 4) is used as a catalyst, and the reaction is performed at a temperature of 600 to 700 ° C. It is desirable. It is preferable to use carbon monoxide or the like as the carbon-containing gas in the source gas.
- the mixing ratio of the carbon-containing gas and the hydrogen gas is a molar ratio (volume ratio), for example, 2: 8 to 8: 2 Although preferred, the preferred range of the mixing ratio is believed to depend on the type of active material.
- carbon nanofibers in a plate state are grown, for example, it is desirable to use iron as a catalyst and perform the reaction at a temperature of 550 to 650 ° C. It is preferable to use carbon monoxide or the like as the carbon-containing gas in the source gas.
- the mixing ratio of the carbon-containing gas and the hydrogen gas is a molar ratio (volume ratio). For example, a suitable range of force mixing ratio of 2: 8 to 8: 2 is considered to depend on the type of active material.
- a general electrode used in a cylindrical or rectangular nonaqueous electrolyte secondary battery can be obtained by processing an electrode plate having an electrode mixture supported on a current collector into a predetermined shape.
- the electrode mixture usually contains composite particles and a resin binder as essential components.
- the electrode mixture can contain a conductive agent, a thickener and the like as optional components as long as the effects of the present invention are not significantly impaired.
- the binder include fluorine resin such as polyvinylidene fluoride (PVDF), rubbery resin such as styrene butadiene rubber (SBR), and rubbery resin containing acrylic acid, acrylonitrile or acrylate units.
- PVDF polyvinylidene fluoride
- SBR styrene butadiene rubber
- acrylic acid acrylonitrile or acrylate units.
- the conductive agent carbon black or the like is preferably used.
- the thickener carboxymethyl cellulose (CMC) or the like is preferably used.
- the electrode mixture is mixed with a liquid component to form a slurry.
- the resulting slurry is applied to both sides of the current collector and dried. Thereafter, the electrode mixture carried on the current collector is rolled together with the current collector and cut into a predetermined size to obtain an electrode.
- the method described here is merely an example, and the electrode may be manufactured by any other method. Further, the type and shape of the electrode are not limited, and for example, composite particles can be used for the electrode of a coin-type battery.
- An electrode group is constituted by using the obtained electrode, the counter electrode, and the separator.
- a microporous film made of polyolefin resin is preferably used, but is not particularly limited.
- the electrode group is housed in the battery case together with the non-aqueous electrolyte.
- a nonaqueous solvent in which a lithium salt is dissolved is used for the nonaqueous electrolyte.
- the lithium salt is not particularly limited.
- LiPF, LiBF, etc. are preferably used.
- the non-aqueous solvent is not particularly limited.
- carbonic acid esters such as ethylene carbonate, propylene carbonate, dimethylol carbonate, diethyl carbonate, ethylmethyl carbonate and the like are preferably used.
- the conversion rate of the raw material gas to the carbon nanofibers can be greatly improved by reducing the hydrogen gas concentration in the raw material gas.
- the raw material gas does not contain hydrogen gas or is low in concentration, it is possible to use a reaction vessel with excellent material properties other than quartz that has excellent workability and handling properties, and the size of the reaction apparatus is increased. Is also easier.
- the source gas a carbon-containing gas or a mixed gas of carbon-containing gas and hydrogen gas is used.
- the source gas may be used by mixing with an inert carrier gas.
- the hydrogen gas content in the mixed gas should be less than 5% by volume.
- the hydrogenation reaction of carbon proceeds by the catalyst and tends to gasify. Therefore, the production rate of carbon nanofibers decreases.
- the carbon-containing gas is a saturated hydrocarbon gas represented by carbon monoxide (CO), C H (n ⁇ l) n 2n + 2
- Group power consisting of saturated hydrocarbon gas is at least one selected.
- the carbon-containing gas preferably contains at least an unsaturated hydrocarbon gas.
- ethane which is a saturated hydrocarbon, starts a polymerization reaction in a high-temperature atmosphere and generates hydrogen gas simultaneously with the polymerization reaction.
- This hydrogen gas reduces the catalytic element or the catalyst Hydrocracking pie-mouth carbon (pyrolytic carbon) adhering to elements. Therefore, even if the hydrogen concentration in the raw material gas is extremely low or does not contain hydrogen, it is considered that the raw material gas is efficiently decomposed and carbon nanofibers are generated with high efficiency.
- Unsaturated hydrocarbons are considered to act similarly. However, for example, when ethylene, which is an unsaturated hydrocarbon, is polymerized, the resulting polymer contains unsaturated bonds. Therefore, compared to saturated hydrocarbon gas, it is considered that the generation rate of carbon nanofibers, where graphen-sheets are easy to grow, is greatly improved.
- the saturated hydrocarbon represented by C H (n ⁇ l) includes, for example, methane, ethane, propane, bu n 2n + 2
- Tan, pentane, heptane and the like can be used.
- the saturated hydrocarbon n is preferably l ⁇ n ⁇ 5.
- Unsaturated hydrocarbons represented by C H (n ⁇ 2) or C H (n ⁇ 2) include, for example, et n 2n n 2n-2
- ne Lene, acetylene, propene, allene, propyne, butene, methylpropene, butadiene, etc. can be used.
- the n of the unsaturated hydrocarbon is preferably 2 ⁇ n ⁇ 5.
- the active material that is, the material capable of electrochemically storing electric capacity includes an oxide.
- a metal oxide such as SiO, SnO, S ⁇ , GeO, GeO or a semimetal oxide can be used as the oxide.
- the oxide includes, for example, LiCoO, Li
- lithium composite transition metal oxides such as NiO and LiMn O It is not limited to.
- examples of the oxide include RuO,
- transition metal oxides such as MnO are not limited to these.
- the active material as a whole does not need to be made of acid. Only the surface layer portion of the active material may contain an oxide.
- a material for example, Si, Sn, Ge, etc. capable of electrochemically storing electric capacity can be used after being heat-treated in an oxygen atmosphere. By the heat treatment, an active material containing an oxide is generated in the surface layer portion of the material.
- a catalytic element that promotes the growth of carbon nanofibers at least one selected from the group force consisting of Au, Ag, Pt, Ru, Ir, Cu, Fe, Co, Ni, Mo, and Mn should be used. Is preferred.
- the method for supporting the catalyst element on the surface of the active material is not particularly limited, but the impregnation method is suitable.
- an active material is impregnated in an aqueous solution or organic solution in which a salt containing a catalytic element (for example, nitrate, sulfate, chloride, etc.) or a compound containing a catalytic element is dissolved, and then only the solvent component is removed.
- the removal of the solvent component can be performed using an apparatus such as an evaporator.
- the catalyst element can be uniformly supported on the surface of the active material in a state of nitrate, sulfate, salt or the like.
- Examples of the salt or compound containing a catalytic element include nickel nitrate hexahydrate, cobalt nitrate hexahydrate, iron nitrate nonahydrate, copper nitrate trihydrate, manganese nitrate hexahydrate, 7 Hexamolybdate hexaammonium tetrahydrate. Of these, nitrate is preferable.
- the solvent of the solution a suitable one such as water, an organic solvent, a mixture of water and an organic solvent, or the like is selected.
- the organic solvent for example, ethanol, isopropyl alcohol, toluene, benzene, hexane, tetrahydrofuran and the like can be used.
- an active material carrying a catalytic element is introduced into a high temperature atmosphere containing a raw material gas.
- an active material carrying a catalytic element is put into a quartz reaction vessel, and the temperature is raised to 400 to 750 ° C, preferably 500 to 600 ° C in an inert gas.
- the carbon nanofiber source gas is introduced into the reaction vessel, and the temperature in the reaction vessel is maintained at 400 to 750 ° C, preferably 500 to 600 ° C. If the temperature in the reaction vessel is less than 400 ° C, the growth of carbon nanofibers may become too slow and productivity may be impaired.
- the temperature in the reaction vessel exceeds 750 ° C, decomposition of the raw material gas is accelerated, and the production of carbon nanofibers may be hindered.
- the raw material gas is replaced with an inert gas, and the inside of the reaction vessel is cooled to room temperature.
- the amount of carbon nanofibers grown on the surface of the active material is preferably 5 to 150 parts by weight per 100 parts by weight of the active material (a material capable of accumulating electric capacity electrochemically). If the amount of carbon nanofibers is too small, the effect of increasing the conductivity of the electrode or improving the charge / discharge characteristics and cycle characteristics of the battery may not be obtained sufficiently. Even if the amount of carbon nanofibers is large, there is a problem from the viewpoint of electrode conductivity, battery charge / discharge characteristics, and cycle characteristics !, but the electrode active material density and battery capacity are reduced.
- the reaction vessel is preferably made of carbon (for example, graphite or glassy carbon), pig iron, alumina or the like. Quartz can be used as the material for the reaction vessel, but Ishihide has difficulty in workability. If quartz is used, it will be difficult to improve productivity, which makes it difficult to increase the size of the reaction vessel. On the other hand, carbon, pig iron, alumina, etc. have high heat resistance and excellent workability. In addition, even when exposed to high-temperature atmospheres, it hardly reacts with carbon-containing gases.
- Nickel nitrate hexahydrate (special grade) lg produced by Kanto Chemical Co., Ltd. was dissolved in lOOg of ion-exchanged water.
- the obtained solution was mixed with key particle (Si) lOOg manufactured by Kojundo Chemical Laboratory Co., Ltd., pulverized to 10 m or less. After stirring this mixture for 1 hour, remove moisture with an evaporator. Removed.
- an active material particle composed of an electrochemically active phase, ie, a silicon particle and nickel nitrate supported on the surface thereof was obtained.
- the nickel particles supporting nickel nitrate were put into a ceramic reaction vessel and heated to 550 ° C in the presence of helium gas. Thereafter, helium gas was replaced with a mixed gas of 50% by volume of hydrogen gas and 50% by volume of methane gas, and the inside of the reaction vessel was kept at 550 ° C. for 3 hours. As a result, tubular carbon nanofibers with a fiber diameter of about 80 nm and a fiber length of 500 / zm were grown on the surface of the silicon particles. Thereafter, the mixed gas was replaced with helium gas, and the inside of the reaction vessel was cooled to room temperature. The amount of the grown carbon nanofiber was 100 parts by weight per 100 parts by weight of the active material particles.
- the nickel nitrate supported on the silicon particles was reduced to particles having a particle size of about lOOnm.
- the particle size, fiber diameter, and fiber length of the nickel particles were observed by SEM, and the weight of the carbon nanofibers was measured from the change in the weight of the active material particles before and after the growth. SEM observation confirmed the presence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of approximately 80 nm.
- Fig. 3 shows a 500 times magnified photograph of the obtained composite particles.
- Fig. 4 shows a 50 000x magnified photograph of the area surrounded by the circle in Fig. 3.
- Figure 4 confirms that carbon nanofibers are growing in the circle.
- Figure 5 shows a 30000 times magnified photograph of the resulting composite particles. In FIG. 5, the presence of large carbon nanofibers 32 and fine carbon nanofibers 33 can be observed on the surface of the active material particles 31.
- the composite particles were heated to 1000 ° C in argon gas, and the composite particles were calcined at 1000 ° C for 1 hour to obtain an electrode material A for a nonaqueous electrolyte secondary battery.
- Example 1 Similar to Example 1 except that cobalt nitrate hexahydrate (special grade) lg manufactured by Kanto Yigaku Co., Ltd. was dissolved in 100 g of ion-exchanged water instead of nickel nitrate hexahydrate lg. Thus, the electrode material B of the nonaqueous electrolyte secondary battery was obtained.
- the diameters of the coronate particles supported on the silicon particles were almost the same as the nickel particles of Example 1.
- the fiber diameter, fiber length, and weight ratio with respect to the active material particles of the grown carbon fiber having a single ring bone were almost the same as in Example 1.
- SEM observation in addition to fibers with a fiber diameter of about 80 nm, The presence of fine fibers with a diameter of 30 nm or less was confirmed.
- Nickel nitrate hexahydrate As in Example 1, except that 0.5 g of nickel nitrate hexahydrate and 0.5 g of cobalt nitrate hexahydrate were dissolved in 100 g of ion-exchanged water instead of lg. As a result, the electrode material D of the nonaqueous electrolyte secondary battery was obtained. The particle diameters of the cobalt particles and nickel particles supported on the silicon particles were almost the same as those of the nickel particles of Example 1, respectively. The fiber diameter, fiber length, and weight ratio of the grown tubular carbon nanofibers to the active material particles were almost the same as in Example 1. Here again, SEM observation confirmed the presence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of approximately 80 nm.
- Example 2 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar for 5 minutes, the same procedure as in Example 1
- the electrode material E was used for nonaqueous electrolyte secondary batteries.
- the grown carbon nanofibers had a fiber length of about 0.5 nm and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 1 part by weight or less per 100 parts by weight of active material particles.
- Example 6 [0144] in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar to 20 hours, the same procedure as in Example 1 Therefore, electrode material F of non-aqueous electrolyte secondary battery was used.
- the grown carbon nanofibers had a fiber length of 3 mm or more and a fiber diameter of 80 nm.
- the amount of carbon nanofiber grown was 200 parts by weight per 100 parts by weight of active material particles.
- SEM observation confirmed the presence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of approximately 80 nm.
- An electrode material G for a nonaqueous electrolyte secondary battery was obtained by performing the same operation as in Example 1, except that the composite particles after the carbon nanofiber growth were baked at 100 ° C.
- Example 2 The same operation as in Example 1 was performed except that the composite particles after the carbon nanofiber growth were baked at 1700 ° C to obtain an electrode material H for a nonaqueous electrolyte secondary battery.
- Nickel nitrate hexahydrate lg was dissolved in 100 g of ion-exchanged water. The resulting solution was mixed with 5 g of acetylene black (AB). After stirring this mixture for 1 hour, water was removed with an evaporator and nickel particles were supported on acetylene black. Next, acetylene black carrying nickel particles was baked at 300 ° C. in the atmosphere to obtain nickel oxide particles having a particle size of 0: L m or less.
- the obtained nickel oxide particles were put into a ceramic reaction vessel and heated to 550 ° C in the presence of helium gas. Thereafter, helium gas was replaced with a mixed gas of 50% by volume of hydrogen gas and 50% by volume of methane gas, and the inside of the reaction vessel was kept at 550 ° C. for 3 hours. As a result, tubular carbon nanofibers having a fiber diameter of about 80 nm and a fiber length of 500 m were obtained. Thereafter, the mixed gas was replaced with helium gas, and the reaction vessel was cooled to room temperature. [0150] The obtained carbon nanofibers (CNF) were washed with an aqueous hydrochloric acid solution to remove nickel particles, and carbon nanofibers containing no catalyst element were obtained. 100 parts by weight of the carbon nanofibers and 100 parts by weight of the silicon particles pulverized to 10 m or less were dry-mixed to obtain an electrode material J for a non-aqueous electrolyte secondary battery.
- CNF carbon nanofibers
- the silicon particles pulverized to 10 ⁇ m or less were put into a ceramic reaction vessel and heated to 1000 ° C. in the presence of helium gas. Then, helium gas was replaced with benzene gas 50 volume 0/0 and helium gas 50% by volume of the mixed gas, the reaction vessel was held for 1 hour at 1000 ° C. As a result, a carbon layer having a thickness of about 500 nm was formed on the surface of the silicon particles. Thereafter, the mixed gas was replaced with helium gas, and the inside of the reaction vessel was cooled to room temperature to obtain an electrode material K for a nonaqueous electrolyte secondary battery.
- the resulting mixture was mixed for 10 hours using a ball mill to obtain chromium-containing silicon particles. Thereafter, 70 parts by weight of chromium-containing silicon particles and 30 parts by weight of the same carbon nanofiber as used in Comparative Example 2 were mixed by a ball mill and pulverized until the silicon particles became 10 / z m or less.
- the obtained mixture was put into a ceramic reaction vessel and heated to 700 ° C in the presence of helium gas. Thereafter, helium gas was replaced with 100% by volume of methane gas, and the inside of the reaction vessel was kept at 700 ° C. for 6 hours. As a result, a carbon layer having a thickness of about lOOnm was formed on the surface of the silicon particles. Thereafter, the methane gas was replaced with helium gas, and the inside of the reaction vessel was cooled to room temperature to obtain an electrode material L for a nonaqueous electrolyte secondary battery.
- the electrode materials produced in Examples 1 to 8 and Comparative Examples 1 to 4 were mixed with a binder made of vinylidene fluoride resin and N-methyl 2-pyrrolidone (NMP), and combined.
- An agent slurry was prepared. The slurry was cast on a 15 m thick Cu foil, dried, and then the mixture was rolled to obtain an electrode plate. The mixture density of the obtained electrode plate was 0.8 to 1.4 gZcm 3 .
- This electrode plate was sufficiently dried in an oven at 80 ° C to obtain a working electrode. With the counter electrode of the working electrode Then, a coin-type lithium ion battery regulated by the working electrode was fabricated using lithium metal foil.
- a non-aqueous electrolyte a solution in which LiPF was dissolved at a concentration of 1.
- OM (molZL) in a 1: 1 volume mixture of ethylene carbonate and jetyl carbonate was used as the non-aqueous electrolyte.
- the initial charge capacity and the initial discharge capacity were measured at a charge / discharge rate of 0.05C, and the initial discharge capacity per active material weight was determined. Furthermore, the ratio of the initial discharge capacity to the initial charge capacity was obtained as a percentage value and used as the charge / discharge efficiency.
- a B Acetylene black
- a battery using the electrode material of Comparative Example 4 in which a mixture of active material particles containing chromium and carbon nanofibers was mixed with a ball mill and the particle surface was coated with a carbon layer was also used in Examples 1 to Compared to the 8 batteries, a sharp drop in charge / discharge efficiency and cycle efficiency was confirmed. This is also due to the disconnection of the electron conduction network between the active material particles due to the expansion and contraction of the active material due to charge and discharge.
- LiCoO particles with an average particle size of 10 ⁇ m were put into a ceramic reactor and helium gas was present.
- the temperature was raised to 550 ° C in the presence. Thereafter, the helium gas was replaced with a mixed gas of 50% by volume of hydrogen gas and 50% by volume of methane gas, and the inside of the reaction vessel was maintained at 550 ° C. for 3 hours. As a result, a tube-like force with a fiber diameter of about 80 nm and a fiber length of 500 ⁇ m is applied to the surface of the LiCoO particles.
- One bon nanofiber grew. Thereafter, the mixed gas was replaced with helium gas, and the inside of the reaction vessel was cooled to room temperature. The amount of carbon nanofiber grown was 100 parts by weight per 100 parts by weight of the active material particles. SEM observation confirmed the existence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of approximately 80 nm.
- the composite particles were heated to 700 ° C in argon gas, and the composite particles were fired at 700 ° C for 1 hour. Thereafter, the temperature was further raised to 300 ° C. in the atmosphere, and the composite particles were heat-treated for 2 hours to obtain an electrode material M for a nonaqueous electrolyte secondary battery.
- Nickel nitrate hexahydrate lg was dissolved in 100 g of ion-exchanged water. The resulting solution was mixed with 100 g of LiCoO particles having an average particle size m. The mixture is stirred for 1 hour and then evaporated.
- Active material particles such as nickel nitrate were obtained.
- the active material particles thus obtained were put into a ceramic reaction vessel, and the same operation as in Example 9 was performed except that carbon nanofibers were grown on the surface thereof. Thus, a nonaqueous electrolyte secondary battery was manufactured. Electrode material N.
- the grown tubular carbon nanofibers had a fiber diameter of approximately 80 nm and a fiber length of 500 m. The weight ratio of the grown carbon nanofibers to the active material particles was almost the same as in Example 1. Nitric acid supported on LiCoO particles
- Nickel was reduced to nickel particles with a particle size of about lOOnm.
- SEM observation in addition to fibers with a fiber diameter of about 80 nm, the presence of fine fibers with a fiber diameter of 30 nm or less is confirmed. Recognized,
- the electrode material for non-aqueous electrolyte secondary batteries was O. Nickel supported on LiMn O particles
- the particle size of the particles was almost the same as the nickel particles of Example 10, and the fiber diameter, fiber length, and weight ratio of the grown carbon nanofibers to the active material particles were almost the same as those of Example 10. SEM observation confirmed the presence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of approximately 80 nm.
- Example 13 The particle diameters of the particles and the nickel particles were almost the same as the nickel particles of Example 10, respectively.
- Example 13 SEM observation confirmed the presence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of about 80 ⁇ m.
- Example 10 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar for 5 minutes, the procedure of Example 10
- the electrode material Q for non-aqueous electrolyte secondary batteries was used.
- the grown carbon nanofibers had a fiber length of about 0.5 nm and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was less than 1 part by weight per 100 parts by weight of active material particles.
- SEM observation in addition to fibers with a fiber diameter of about 80 nm, the presence of fine fibers with a fiber diameter of 30 nm or less was confirmed.
- Example 10 Electrode material R for non-aqueous electrolyte secondary battery.
- Grown carbon nanofibers are roughly fibers The length was 3 mm or more and the fiber diameter was 80 nm.
- the amount of the grown carbon nanofiber was 200 parts by weight per 100 parts by weight of the active material particles.
- SEM observation in addition to fibers with a fiber diameter of about 80 nm, the presence of fine fibers with a fiber diameter of 30 nm or less was confirmed.
- An electrode material S for a non-aqueous electrolyte secondary battery was prepared in the same manner as in Example 10, except that the composite particles after the carbon nanofiber growth were baked at 100 ° C.
- An electrode material T for a non-aqueous electrolyte secondary battery was prepared in the same manner as in Example 10 except that the composite particles after the carbon nanofiber growth were baked at 1500 ° C.
- the electrode materials manufactured in Examples 9 to 16 and Comparative Examples 5 and 6 were mixed with a binder made of vinylidene fluoride resin and NMP to prepare a mixture slurry.
- the slurry was cast on an A1 foil having a thickness of 15 m, and after drying, the mixture was rolled to obtain an electrode plate.
- the mixture density of the obtained electrode plate was 3.3 gZcm 3 .
- This electrode plate was sufficiently dried in an oven at 80 ° C to obtain a working electrode.
- a lithium metal foil as the counter electrode of the working electrode, a coin-type lithium ion battery regulated by the working electrode was fabricated.
- a non-aqueous electrolyte a solution obtained by dissolving LiPF at a concentration of 1.0 M in a mixed solvent of ethylene carbonate and jetyl carbonate in a volume of 1: 1 was used.
- the obtained coin-type lithium ion battery was charged and discharged at a rate of 0.2 C to determine the initial discharge capacity per active material weight.
- the battery was charged at a speed of 0.2C and discharged at a speed of 1. OC or 2. OC.
- the ratio of 2. OC discharge capacity to 1. OC discharge capacity was calculated as a percentage value and used as discharge efficiency.
- the initial discharge capacity was determined at the charge / discharge rate of OC.
- 1. Charge / discharge was repeated 200 cycles at the OC charge / discharge rate. After that, the ratio of the discharge capacity after 200 cycles to the initial discharge capacity was obtained as a percentage value and used as the cycle efficiency. The results are shown in Table 2.
- a B Acetylene black
- Example 14 Conversely, in the battery using the composite particles of Example 14 in which the carbon nanofibers were grown for a long time, the initial discharge capacity per unit weight of the active material, the discharge efficiency, and the cycle efficiency were the same level as in Example 10. Met. However, it was confirmed that the discharge capacity per electrode plate was reduced. This is because the proportion of carbon nanofibers in the electrode plate increased relative to the amount of active material.
- Example 10 Compared with Example 10, the discharge efficiency of the battery using the composite particles of Example 15 in which the firing treatment after carbon nanofiber growth was performed at 100 ° C was reduced. This is because, when firing at 100 ° C, functional groups such as hydrogen ions, methyl groups, and hydroxyl groups attached to the carbon nanofiber surface were not removed, resulting in an irreversible reaction with the electrolyte.
- Example 10 Compared with Example 10, the initial discharge capacity per active material weight of the battery using the composite particles of Example 16 in which the firing treatment after carbon nanofiber growth was performed at 1500 ° C was reduced. In this case, it is considered that functional groups such as hydrogen ions, methyl groups, and hydroxyl groups attached to the carbon nanofiber surface are completely removed. However, LiCoO is reduced and decomposed,
- Co-chemically inert cobalt oxide such as Co 2 O was generated and the initial discharge capacity was reduced.
- Example 1 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar to 10 minutes, the procedure of Example 1 , Non-hydroelectric
- the electrode material was W for a denatured secondary battery.
- the grown carbon nanofibers had a fiber length of approximately 500 nm and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 5 parts by weight or less per 100 parts by weight of active material particles.
- Example 1 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar for 30 minutes, the procedure of Example 1
- the electrode material X for non-aqueous electrolyte secondary batteries was used.
- the grown carbon nanofibers had a fiber length of 10 ⁇ m and a fiber diameter of 80 nm.
- the amount of carbon nanofiber grown was 10 parts by weight per 100 parts by weight of the active material particles.
- Example 1 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar to 60 minutes, the procedure of Example 1
- the electrode material Y for non-aqueous electrolyte secondary batteries was used.
- the grown carbon nanofibers had a fiber length of 50 ⁇ m and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 30 parts by weight per 100 parts by weight of the active material particles.
- Example 1 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar for 90 minutes, the procedure of Example 1
- the electrode material Z for nonaqueous electrolyte secondary batteries was used.
- the grown carbon nanofibers had a fiber length of 100 m and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 50 parts by weight per 100 parts by weight of the active material particles.
- Example 17 Using the electrode materials produced in Examples 17 to 20, coin-type lithium ion batteries similar to Example 1 were produced and evaluated in the same manner as Example 1. The initial discharge capacity per active material weight, charge / discharge efficiency, and cycle efficiency were determined. The results are shown in Table 3.
- Example 10 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar to 10 minutes, the procedure of Example 10
- the electrode material ⁇ of the non-aqueous electrolyte secondary battery was used.
- the grown carbon nanofibers had a fiber length of approximately 500 nm and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 5 parts by weight per 100 parts by weight of active material particles.
- Example 10 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar for 30 minutes, the procedure of Example 10
- the electrode material was j8 for non-aqueous electrolyte secondary batteries.
- the grown carbon nanofibers had a fiber length of about 10 m and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 10 parts by weight per 100 parts by weight of active material particles.
- Example 10 in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar to 60 minutes, the procedure of Example 10
- the electrode material ⁇ of the non-aqueous electrolyte secondary battery was used.
- the grown carbon nanofibers had a fiber length of 50 ⁇ m and a fiber diameter of 80 nm.
- the amount of carbon nanofibers grown was 30 parts by weight per 100 parts by weight of active material particles.
- Example 24 [0199] in a mixed gas of hydrogen gas 50 vol 0/0 and methane 50 volume 0/0, except for changing the growth time of the carbon nano Huai bar for 90 minutes, the procedure of Example 10
- the electrode material ⁇ of the non-aqueous electrolyte secondary battery was used.
- the grown carbon nanofibers had a fiber length of 100 / ⁇ ⁇ and a fiber diameter of 80 nm.
- the amount of the grown carbon nanofiber was 50 parts by weight per 100 parts by weight of the active material particles.
- Example 9 coin-type lithium ion batteries similar to Example 9 were produced and evaluated in the same manner as Example 9. The initial discharge capacity per active material weight, discharge efficiency, and cycle efficiency were determined. The results are shown in Table 4.
- Nickel nitrate hexahydrate (special grade) lg produced by Kanto Chemical Co., Ltd. was dissolved in lOOg of ion-exchanged water.
- the obtained solution was mixed with key particle lOOg manufactured by Kojundo Chemical Laboratory Co., Ltd., pulverized to 10 m or less. After the mixture was stirred for 1 hour, moisture was removed by an evaporator device, thereby obtaining silicon particles and active material particles made of nickel nitrate supported on the surface thereof.
- the nickel particles supporting nickel nitrate were put into a ceramic reaction vessel and heated to 550 ° C in the presence of helium gas. Then, helium gas was replaced with hydrogen gas 20 vol 0/0 and E Ji Rengasu 80% by volume of the mixed gas, the reaction vessel was held for 3 hours at 540 ° C. So As a result, a carbon nanofiber with a ⁇ ring with a fiber diameter of about 80 nm and a fiber length of 500 m was grown on the surface of the key particle. Thereafter, the mixed gas was replaced with helium gas, and the reaction vessel was cooled to room temperature. The amount of the grown carbon nanofiber was 100 parts by weight per 100 parts by weight of the active material particles.
- SEM observation confirmed the presence of fine fibers with a fiber diameter of 30 nm or less in addition to fibers with a fiber diameter of approximately 80 nm.
- Example 25 Using the electrode material produced in Example 25, a negative electrode similar to Example 1 was produced. Lithium corresponding to an irreversible capacity was imparted to the obtained negative electrode using a lithium vapor deposition apparatus by resistance heating.
- a battery was prepared in the same manner as in Example 1 except that a positive electrode containing 0.8 0.17 0.o was used.
- the method for introducing lithium into the negative electrode is not limited to the above.
- a battery may be assembled by attaching a lithium foil to the negative electrode, or lithium powder may be introduced into the battery.
- An electrode material was obtained in the same manner as in Example 1 except that the obtained silicon particles having a silicon oxide layer were used.
- tubular carbon nanofibers having a fiber diameter of about 80 nm and a fiber length of 500 m were grown on the surface of the key particle having an oxide layer.
- the amount of the grown carbon nanofiber was 100 parts by weight per 100 parts by weight of the active material particles.
- SEM observation in addition to fibers with a fiber diameter of about 80 nm, The presence of fine fibers with a diameter of 30 nm or less was confirmed.
- Example 2 Using the obtained electrode material, a battery was produced in the same manner as in Example 1, and evaluated in the same manner as in Example 1. As a result, the initial discharge capacity per active material weight was 3800 mAhZg, the discharge efficiency was 90%, and the cycle efficiency was 95%.
- an oxygen silicate (SiO) was used as an active material
- Ni was used as a catalytic element
- an ethylene gas was used as a carbon-containing gas, and the following procedure was followed.
- a composite active material containing fiber was prepared.
- Nickel nitrate hexahydrate (special grade) lg manufactured by Kanto Chemical Co., Ltd. was dissolved in 100 g of ion-exchanged water.
- the resulting solution was mixed with 20 g of acid silicate produced by Kojundo Chemical Laboratory Co., Ltd., pulverized to an average particle size of 10 ⁇ m or less. After the mixture was stirred for 1 hour, the water content was removed with an evaporator device, so that nickel nitrate was supported on the surface of the oxide silica particles.
- the silicon oxide carrying nickel nitrate was put into a quartz reaction vessel and heated to 550 ° C in the presence of helium gas. Then, the helium gas is replaced with a mixed gas of 2 vol 0/0 and Echire Ngasu 98 vol% hydrogen gas, the reaction vessel was held for 1 hour at 550 ° C.
- the obtained composite particles can be used, for example, as a negative electrode material for a nonaqueous electrolyte secondary battery.
- the composite particles contained about 101 parts by weight of carbon nanofibers per 100 parts by weight of oxygen.
- the weight of the carbon nanofibers was measured by the weight change force of the oxygen silicate before and after the growth.
- Example 27 The same operation was carried out to prepare composite particles containing oxygenated carbon and carbon nanofibers.
- Example 30
- Example 31 The same procedure as in Example 27 was performed, except that a carbon reaction vessel was used instead of the quartz reaction vessel, and composite particles containing acid silicate and carbon nanofibers were prepared.
- a carbon reaction vessel was used instead of the quartz reaction vessel, and composite particles containing acid silicate and carbon nanofibers were prepared.
- Example 32 By performing the same operation as in Example 27, except that a reaction vessel made of pig iron was used instead of the reaction vessel made of quartz, composite particles containing an acid chain and carbon nanofibers were prepared.
- a reaction vessel made of pig iron was used instead of the reaction vessel made of quartz, composite particles containing an acid chain and carbon nanofibers were prepared.
- Example 27 The same procedure as in Example 27 was performed, except that an alumina reaction vessel was used instead of the quartz reaction vessel, to prepare composite particles containing oxygenated carbon and carbon nanofibers Reference Example 1
- Example 2 instead of a gas mixture of hydrogen gas 2 vol 0/0 and ethylene gas 98v 0/0, except for using a mixed gas of 10 body volume% of hydrogen gas and ethylene gas 90 vol%, Example The same operation as in No. 27 was performed to prepare composite particles containing oxygenated carbon and carbon nanofibers.
- Example 2 instead of a gas mixture of hydrogen gas 2 vol 0/0 and ethylene gas 98v 0/0, except for using a mixed gas of hydrogen gas 50 body volume% of ethylene gas 50 vol%, Example The same operation as in No. 27 was performed to prepare composite particles containing oxygenated carbon and carbon nanofibers.
- Table 5 shows the production rate of carbon nanofibers and problems in Examples 27 to 32 and Reference Examples 1 to 5.
- Nickel nitrate hexahydrate Similar to Example 27 except that 1 g of iron nitrate nonahydrate (special grade) manufactured by Kanto Chemical Co., Ltd. was dissolved in lOOg of ion-exchanged water instead of lg. The operation was carried out to prepare composite particles containing oxygen and carbon nanofibers.
- Nickel nitrate hexahydrate In place of lg, except that hexamolybdenum hexamolybdate tetrahydrate (special grade) manufactured by Kanto Yigaku Co., Ltd. was dissolved in lOOg ion-exchanged water. Then, the same operation as in Example 27 was carried out, and composite particles containing acid silicate and carbon nanofiber were prepared.
- Example 36 hexamolybdenum hexamolybdate tetrahydrate (special grade) manufactured by Kanto Yigaku Co., Ltd. was dissolved in lOOg ion-exchanged water. Then, the same operation as in Example 27 was carried out, and composite particles containing acid silicate and carbon nanofiber were prepared.
- Nickel nitrate hexahydrate instead of lg, nickel nitrate hexahydrate produced by Kanto Chemical Co., Ltd.
- Example 2 Except that 5 g and 0.5 g of cobalt nitrate hexahydrate were dissolved in lOOg of ion-exchanged water, the same operation as in Example 1 was performed to prepare composite particles containing acid and carbon nanofibers. Made.
- Example 27 The same operation as in Example 27 was performed, except that nickel nitrate hexahydrate was not dissolved.
- An active material containing silicon oxide was prepared.
- Example 27 Except that ethane gas was used in place of ethylene gas as the carbon-containing gas, the same operation as in Example 27 was performed to prepare composite particles containing oxygenated carbon and carbon nanofibers.
- Example 27 The same operation as in Example 27 was performed, except that acetylene gas was used as the carbon-containing gas instead of ethylene gas, to prepare composite particles containing oxygenated carbon and carbon nanofibers.
- Example 27 Except that propane gas was used instead of ethylene gas as the carbon-containing gas, the same operation as in Example 27 was carried out to prepare composite particles containing an oxygen carrier and carbon nanofibers.
- a composite particle containing an oxygen atom and carbon nanofibers was prepared in the same manner as in Example 27 except that propene gas was used as the carbon-containing gas instead of ethylene gas. Made.
- Example 27 Except that propyne gas was used instead of ethylene gas as the carbon-containing gas, the same operation as in Example 27 was performed to prepare composite particles containing an oxygen silicate and carbon nanofibers.
- a composite particle containing an oxygen atom and carbon nanofibers was prepared in the same manner as in Example 27 except that methane gas was used instead of ethylene gas as the carbon-containing gas.
- Composite particles containing silicon oxide were prepared in the same manner as in Example 27 except that a mixed gas of hexane and helium was used instead of ethylene gas. Helium gas was mixed as a hexane carrier gas that is liquid at room temperature.
- Composite particles containing silicon oxide were prepared in the same manner as in Example 27 except that a mixed gas of benzene and helium was used instead of ethylene gas. Helium gas was mixed as a carrier gas for benzene, which is liquid at room temperature.
- the compounds containing 6 carbon atoms used in Comparative Examples 8 and 9 have high polymerizability.
- benzene is prone to undergo polycondensation without a catalyst. Therefore, carbon fiber is not formed from the catalyst as a starting point, but a carbon film or carbide is formed on the active material surface. Therefore, the generation of carbon nanofibers was not recognized.
- Oxidation treatment was performed at 1000 ° C for 1 hour on Si manufactured by Kojundo Chemical Laboratory Co., Ltd. that had been crushed to 10 m or less. Except that the oxidized silicon particles were used in place of SiO as the active material, the same operation as in Example 27 was performed to prepare composite particles containing silicon and carbon nanofibers. The obtained composite particles can be used, for example, as a negative electrode material for a nonaqueous electrolyte secondary battery.
- a composite particle containing tin and carbon nanofibers was prepared in the same manner as in Example 27 except that the oxidized tin particles were used instead of SiO as the active material.
- the obtained composite particles can be used, for example, as a negative electrode material for a nonaqueous electrolyte secondary battery.
- Example 27 The same procedure as in Example 27 was performed, except that SnO manufactured by Kojundo Chemical Laboratory Co., Ltd., pulverized to 10 ⁇ m or less, was used as the active material instead of SiO.
- Composite particles containing tin and carbon nanofibers were prepared. The obtained composite particles can be used, for example, as a negative electrode material for a non-aqueous electrolyte secondary battery.
- Example 27 The same operation as in Example 27 was performed, except that SnO manufactured by Kojundo Chemical Laboratory Co., Ltd. ground to 10 ⁇ m or less was used as the active material instead of SiO. Carbon
- Composite particles containing nanofibers were prepared.
- the obtained composite particles can be used, for example, as a negative electrode material for a non-aqueous electrolyte secondary battery.
- Composite particles were prepared containing The obtained composite particles can be used, for example, as a negative electrode material for a non-aqueous electrolyte secondary battery.
- Example 27 The same procedure as in Example 27 was performed, except that GeO manufactured by Kojundo Chemical Laboratory Co., Ltd., pulverized to 10 ⁇ m or less, was used as the active material instead of SiO. ⁇ Composite particles containing germanium and carbon nanofibers were prepared. The obtained composite particles can be used, for example, as a negative electrode material for a nonaqueous electrolyte secondary battery.
- Example 27 The same procedure as in Example 27 was performed, except that GeO manufactured by Kojundo Chemical Laboratory Co., Ltd., pulverized to 10 ⁇ m or less, was used as the active material instead of SiO. ⁇ Germanium and
- a composite active material containing carbon nanofibers was prepared.
- the obtained composite particles can be used, for example, as a negative electrode material for a nonaqueous electrolyte secondary battery.
- the active material instead of SiO, LiCoO ground to 10 ⁇ m or less was used.
- Example 27 the same operation as in Example 27 was performed to prepare composite particles containing lithium conoleate and carbon nanofibers.
- the obtained composite particles can be used, for example, as a positive electrode material for a nonaqueous electrolyte secondary battery.
- composite particles containing lithium nickelate and carbon nanofibers were prepared.
- the obtained composite particles can be used, for example, as a positive electrode material for a non-aqueous electrolyte secondary battery.
- LiMn O pulverized to 10 ⁇ m or less was used as the active material.
- Example 61 the same operation as in Example 27 was performed to prepare composite particles containing lithium manganate and carbon nanofibers.
- the obtained composite particles can be used, for example, as a positive electrode material for a nonaqueous electrolyte secondary battery.
- Example 61
- LiFePO ground to 10 ⁇ m or less was used as the active material.
- Example 27 In addition, the same operation as in Example 27 was performed, and a composite containing LiFePO and carbon nanofibers was obtained.
- the obtained composite particles can be used, for example, as a positive electrode material of a nonaqueous electrolyte secondary battery.
- Composite particles containing Bonn nanofibers were prepared.
- the obtained composite particles can be used, for example, as an electrode material for an electrochemical capacitor.
- Example 27 The same procedure as in Example 27 was performed, except that MnO manufactured by Kojundo Chemical Laboratory Co., Ltd. pulverized to 10 ⁇ m or less was used as the active material instead of SiO. ⁇ Manganese and power
- Composite particles containing one-bonn nanofibers were prepared.
- the obtained composite particles can be used, for example, as an electrode material for an electrochemical capacitor.
- Example 27 The same procedure as in Example 27 was performed, except that Si, manufactured by Kojundo Chemical Laboratory Co., Ltd., pulverized to 10 ⁇ m or less, was used as the active material instead of SiO. And composite particles containing carbon nanofibers were prepared. The obtained composite particles can be used, for example, as a negative electrode material for a non-aqueous electrolyte secondary battery.
- Table 9 shows the production rate of carbon nanofibers and the presence or absence of structural changes in the active material.
- the production rate of carbon nanofibers is calculated using the above formula ( Obtained from 1).
- the active material before and after the growth of the carbon nanofibers was measured by powder X-ray diffraction to investigate the thermal history and whether there was a change in the crystal structure due to hydrogen gas reduction.
- an electrode plate for a non-aqueous electrolyte secondary battery was produced. That is, 10 parts by weight of a binder composed of vinylidene fluoride resin and 100 parts by weight of composite particles are mixed with an appropriate amount of N-methyl-2-pyrrolidone (NMP) to prepare a mixture slurry. Made. The slurry was cast on both sides of a 10 m thick Cu foil, and after drying, the mixture was rolled to obtain an electrode plate. The mixture density of the obtained electrode plate was 1.2 g / cm 3 .
- NMP N-methyl-2-pyrrolidone
- This electrode plate was sufficiently dried in an oven at 80 ° C to obtain a working electrode.
- a coin-type lithium ion battery whose capacity was regulated by the working electrode was fabricated.
- a non-aqueous electrolyte a solution in which LiPF was dissolved at a concentration of 1. OmolZL in a 1: 1 mixed solvent of ethylene carbonate and jetinole carbonate was used.
- a coin-type lithium ion battery was produced in the same manner as in Example 64 except that the composite particles produced in Example 51 were used instead of the composite particles produced in Example 27.
- a coin-type lithium ion battery was produced in the same manner as in Example 64 except that the composite particles produced in Reference Example 6 were used instead of the composite active material produced in Example 27. .
- the cycle efficiency is the ratio of the discharge capacity when 100 cycles of charge / discharge are repeated at the same charge / discharge rate to the initial discharge capacity obtained at the charge / discharge rate of 1C.
- Example 65 and Comparative Example 11 From the results of Example 65 and Comparative Example 11, it can be seen that excellent battery characteristics can be obtained by using an active material containing an oxide in the surface layer portion. In this regard, it is considered that the presence of oxide in the surface layer is caused by the catalyst element being firmly supported on the surface of the active material and the carbon nanofibers growing more uniformly.
- an electrode plate for a non-aqueous electrolyte secondary battery was produced. That is, a mixture slurry was prepared by mixing 10 parts by weight of a binder composed of vinylidene fluoride resin and an appropriate amount of NMP with respect to 100 parts by weight of the composite particles. Thickness the slurry 1 Casting was performed on both surfaces of 0 m Al foil, and after drying, the mixture was rolled to obtain an electrode plate. The mixture density of the obtained electrode plate was 2.8 g / cm 3 .
- This electrode plate was sufficiently dried in an oven at 80 ° C to obtain a working electrode.
- a coin-type lithium ion battery whose capacity was regulated by the working electrode was fabricated.
- a non-aqueous electrolyte a solution in which LiPF was dissolved at a concentration of 1. OmolZL in a 1: 1 mixed solvent of ethylene carbonate and jetinole carbonate was used.
- the conductive material is acetylene rubber.
- a coin-type lithium ion battery was produced in the same manner as in Example 66 except that the obtained mixture was used in place of the composite particles produced in Example 58.
- Table 11 shows the initial discharge efficiency and cycle efficiency of the batteries obtained in Example 66 and Comparative Example 12.
- the initial discharge efficiency is the ratio of the 2C discharge capacity to the 1C discharge capacity when the battery is charged at a rate of 0.2C and discharged at each speed of 1C or 2C.
- Discharge efficiency (%) (2C discharge capacity ⁇ 1C discharge capacity) X 100 "
- the cycle efficiency is the ratio of the discharge capacity when 500 cycles of charge / discharge are repeated at the same charge / discharge rate to the initial discharge capacity obtained at the charge / discharge rate of 1C.
- Example 67 As shown in Table 11, the initial discharge efficiency and the cycle efficiency obtained in Example 66 were superior to those in Comparative Example 12. Carbon nanofiber electrochemically accumulates electric capacity By growing on the surface of possible materials, it was possible to form a strong conductive network, which led to improvements in initial discharge characteristics and cycle efficiency.
- Example 67
- An electrode plate for an electric double layer capacitor was produced using the composite particles produced in Example 62. That is, a mixture slurry was prepared by mixing 7 parts by weight of a binder composed of polytetrafluoroethylene (PTFE) with 100 parts by weight of composite particles and an appropriate amount of water. The slurry was cast on both surfaces of a SUS foil having a thickness of 10 m, and after drying, the mixture was rolled to obtain an electrode plate.
- PTFE polytetrafluoroethylene
- This electrode plate was sufficiently dried in an oven at 150 ° C. A pair of electrode plates was produced, and a cellulosic separator was sandwiched between them to produce a coin-type electric double layer capacitor.
- the electrolyte used was ethylmethylimidazolium tetrafluoroborate dissolved in sulfolane at a concentration of 1.5 molZL.
- a coin-type electric double layer capacitor was produced in the same manner as in Example 67 except that the obtained mixture was used in place of the composite particles produced in Example 62.
- Example 67 As shown in Table 12, the impedance of ⁇ obtained in Example 67 was lower than that in Comparative Example 13. Carbon nanofibers can be stored electrochemically in electrical capacity The growth on the surface of the material enables the formation of a strong conductive network, which is thought to have led to a reduction in the interfacial resistance component.
- the present invention is applicable to all active material particles used for electrodes of electrochemical devices.
- the present invention provides composite particles (electrode material) that provide a nonaqueous electrolyte secondary battery or capacitor having excellent initial charge / discharge characteristics or cycle characteristics.
- the present invention is effective in improving both the positive electrode active material and the negative electrode active material of a non-aqueous electrolyte secondary battery, and further the active material (dielectric material) of a capacitor.
- active material dielectric material
- carbon nanofibers can be efficiently grown on the surface of an active material. Therefore, it is useful as a method for producing an active material used for electrodes of electrochemical elements such as batteries and electrochemical capacitors.
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Also Published As
Publication number | Publication date |
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KR100816604B1 (ko) | 2008-03-24 |
CN100553016C (zh) | 2009-10-21 |
CN1965428A (zh) | 2007-05-16 |
KR20070026699A (ko) | 2007-03-08 |
US20080160409A1 (en) | 2008-07-03 |
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