WO2005087829A1 - ポリウレタン系重合性組成物およびそれからなる光学用樹脂の製造方法 - Google Patents
ポリウレタン系重合性組成物およびそれからなる光学用樹脂の製造方法 Download PDFInfo
- Publication number
- WO2005087829A1 WO2005087829A1 PCT/JP2005/002762 JP2005002762W WO2005087829A1 WO 2005087829 A1 WO2005087829 A1 WO 2005087829A1 JP 2005002762 W JP2005002762 W JP 2005002762W WO 2005087829 A1 WO2005087829 A1 WO 2005087829A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- compound
- poly
- molecule
- hydroxy
- bis
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/757—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the cycloaliphatic ring by means of an aliphatic group
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
Definitions
- a polythiourethane resin having a high refractive index has been developed by increasing the thiol content of thiol used for polythiourethane (see Patent Document 12).
- polyurethane resins using the alicyclic isocyanate compounds represented by the formulas (1) and (2) (described later) provide a plastic lens having a very high balance of high Abbe number and high heat resistance. (See Patent Document 3).
- n represents an integer from 0 to 3.
- the polythiolic compound having two or more thiol groups in one molecule according to the present invention and / or one or more (in addition to two or more thiol groups and one or more thiol groups in one molecule) includes: Methanedithiol, 1,2-ethanedithiol, 1,1 propanedithiol, 1,2-propanedithiol, 1,3-propanedithiol, 2,2-propanedithiol, 1,6-hexandithiol, 1,, 2,3 propanetrithiol / re, 1,1-cyclohexanedithiol, 1,2-cyclohexanedithiol, 2,2-dimethylpropane-1,3-dithiol, 3,4-dimethoxybutane1-1, 2-dithiol, 2-methylcyclohexane-1,2,3-dithiol, ter, 2,3-dimercap
- the ratio of the number of moles of the hydroxy group was 25.2% with respect to the sum of the number of moles of the hydroxy group and the thiol group.
- G a polyhydroxy compound having two or more hydroxy groups in one molecule and / or a (poly) hydroxy (poly) mercapto compound having at least one hydroxy group and at least one thiol group. Numerical values indicate the number of moles of the thiol group, and 0 indicates the number of moles of the hydroxy group.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05710493A EP1746118B1 (en) | 2004-03-12 | 2005-02-22 | Polyurethane polymerizable composition and method for producing optical resin composed of same |
US10/592,375 US8772441B2 (en) | 2004-03-12 | 2005-02-22 | Polyurethanes polymerizable composition and method for producing optical resin of the same |
JP2006510900A JP4473267B2 (ja) | 2004-03-12 | 2005-02-22 | ポリウレタン系重合性組成物およびそれからなる光学用樹脂の製造方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004070948 | 2004-03-12 | ||
JP2004-070948 | 2004-03-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005087829A1 true WO2005087829A1 (ja) | 2005-09-22 |
Family
ID=34975538
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/002762 WO2005087829A1 (ja) | 2004-03-12 | 2005-02-22 | ポリウレタン系重合性組成物およびそれからなる光学用樹脂の製造方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8772441B2 (ja) |
EP (1) | EP1746118B1 (ja) |
JP (1) | JP4473267B2 (ja) |
KR (1) | KR100769373B1 (ja) |
CN (1) | CN100516107C (ja) |
WO (1) | WO2005087829A1 (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007191598A (ja) * | 2006-01-20 | 2007-08-02 | Mitsui Chemicals Inc | ポリチオウレタン系重合性組成物およびそれらからなる光学用樹脂、およびその製造方法。 |
US8304506B2 (en) * | 2005-08-18 | 2012-11-06 | Mitsui Chemicals, Inc. | Polythiourethane-based polymerizable composition and optical resin obtained from the same |
CN101228203B (zh) * | 2005-08-18 | 2012-11-28 | 三井化学株式会社 | 聚氨酯·硫氨酯类光学用树脂及其制备方法 |
WO2012176439A1 (ja) | 2011-06-23 | 2012-12-27 | 三井化学株式会社 | 重合性組成物 |
WO2015060259A1 (ja) * | 2013-10-21 | 2015-04-30 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
WO2015060260A1 (ja) * | 2013-10-21 | 2015-04-30 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
WO2015115648A1 (ja) | 2014-02-03 | 2015-08-06 | 三井化学株式会社 | 光学材料用重合性組成物、当該組成物から得られる光学材料およびプラスチックレンズ |
KR20180041180A (ko) | 2015-09-16 | 2018-04-23 | 미쯔이가가꾸가부시끼가이샤 | 광학 재료용 중합성 조성물, 해당 조성물로부터 얻어지는 광학 재료 및 플라스틱 렌즈 |
KR20180041710A (ko) | 2015-09-16 | 2018-04-24 | 미쯔이가가꾸가부시끼가이샤 | 성형체 및 광학 재료용 중합성 조성물 |
Families Citing this family (6)
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CN102918073B (zh) * | 2010-03-31 | 2014-12-10 | 陶氏环球技术有限责任公司 | 具有改善抗冲击性和光学性质的聚氨酯组合物 |
ITMI20112102A1 (it) * | 2011-11-18 | 2013-05-19 | Acomon Ag | Composizione polimerizzabile, articolo ottico ottenuto dalla stessa e metodo per la produzione di detto articolo ottico |
FR3005054B1 (fr) * | 2013-04-26 | 2016-07-01 | Michelin & Cie | Polymere utilisable notamment comme primaire d'adhesion pour le collage de metal a du caoutchouc |
WO2017099715A1 (en) * | 2015-12-07 | 2017-06-15 | Bemis Company, Inc. | Diisocyanate-scavenging packaging laminates |
TWI656112B (zh) * | 2016-03-24 | 2019-04-11 | 日商三菱瓦斯化學股份有限公司 | 含有硫醇化合物之新穎光學材料用組成物 |
KR20210121873A (ko) * | 2020-03-31 | 2021-10-08 | 주식회사 엠엘텍 | 티오우레탄계 광학재료용 수지 조성물과 티오우레탄계 광학재료용 수지의 제조방법 |
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JPH0616657A (ja) * | 1992-03-24 | 1994-01-25 | Daiso Co Ltd | 環状スルフィド化合物、それを用いて得られる光学用樹脂及び光学製品 |
JPH07252207A (ja) * | 1994-01-26 | 1995-10-03 | Mitsui Toatsu Chem Inc | 新規なポリチオール及びそれを用いた含硫ウレタン系プラスチックレンズ |
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2005
- 2005-02-22 JP JP2006510900A patent/JP4473267B2/ja active Active
- 2005-02-22 US US10/592,375 patent/US8772441B2/en active Active
- 2005-02-22 CN CNB2005800078147A patent/CN100516107C/zh active Active
- 2005-02-22 EP EP05710493A patent/EP1746118B1/en active Active
- 2005-02-22 WO PCT/JP2005/002762 patent/WO2005087829A1/ja active Application Filing
- 2005-02-22 KR KR1020067019240A patent/KR100769373B1/ko active IP Right Grant
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Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8304506B2 (en) * | 2005-08-18 | 2012-11-06 | Mitsui Chemicals, Inc. | Polythiourethane-based polymerizable composition and optical resin obtained from the same |
CN101228203B (zh) * | 2005-08-18 | 2012-11-28 | 三井化学株式会社 | 聚氨酯·硫氨酯类光学用树脂及其制备方法 |
JP2007191598A (ja) * | 2006-01-20 | 2007-08-02 | Mitsui Chemicals Inc | ポリチオウレタン系重合性組成物およびそれらからなる光学用樹脂、およびその製造方法。 |
JP4621146B2 (ja) * | 2006-01-20 | 2011-01-26 | 三井化学株式会社 | ポリチオウレタン系重合性組成物およびそれらからなる光学用樹脂、およびその製造方法。 |
WO2012176439A1 (ja) | 2011-06-23 | 2012-12-27 | 三井化学株式会社 | 重合性組成物 |
US9482787B2 (en) | 2011-06-23 | 2016-11-01 | Mitsui Chemicals, Inc. | Polymerizable composition |
JP5830629B2 (ja) * | 2013-10-21 | 2015-12-09 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
WO2015060260A1 (ja) * | 2013-10-21 | 2015-04-30 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
JP5872736B2 (ja) * | 2013-10-21 | 2016-03-01 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
JP2016047911A (ja) * | 2013-10-21 | 2016-04-07 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
JP2016047910A (ja) * | 2013-10-21 | 2016-04-07 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
WO2015060259A1 (ja) * | 2013-10-21 | 2015-04-30 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
JPWO2015060260A1 (ja) * | 2013-10-21 | 2017-03-09 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
JPWO2015060259A1 (ja) * | 2013-10-21 | 2017-03-09 | 三井化学株式会社 | 光学材料用重合性組成物および光学材料 |
KR101814305B1 (ko) | 2013-10-21 | 2018-01-02 | 미쯔이가가꾸가부시끼가이샤 | 광학 재료용 중합성 조성물 및 광학 재료 |
WO2015115648A1 (ja) | 2014-02-03 | 2015-08-06 | 三井化学株式会社 | 光学材料用重合性組成物、当該組成物から得られる光学材料およびプラスチックレンズ |
KR20160106122A (ko) | 2014-02-03 | 2016-09-09 | 미쯔이가가꾸가부시끼가이샤 | 광학 재료용 중합성 조성물, 당해 조성물로부터 얻어지는 광학 재료 및 플라스틱 렌즈 |
KR20180041180A (ko) | 2015-09-16 | 2018-04-23 | 미쯔이가가꾸가부시끼가이샤 | 광학 재료용 중합성 조성물, 해당 조성물로부터 얻어지는 광학 재료 및 플라스틱 렌즈 |
KR20180041710A (ko) | 2015-09-16 | 2018-04-24 | 미쯔이가가꾸가부시끼가이샤 | 성형체 및 광학 재료용 중합성 조성물 |
Also Published As
Publication number | Publication date |
---|---|
CN1930203A (zh) | 2007-03-14 |
US20070203318A1 (en) | 2007-08-30 |
EP1746118B1 (en) | 2012-09-26 |
KR100769373B1 (ko) | 2007-10-22 |
JP4473267B2 (ja) | 2010-06-02 |
EP1746118A1 (en) | 2007-01-24 |
CN100516107C (zh) | 2009-07-22 |
JPWO2005087829A1 (ja) | 2008-01-24 |
US8772441B2 (en) | 2014-07-08 |
EP1746118A4 (en) | 2010-08-18 |
KR20060117370A (ko) | 2006-11-16 |
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