WO2005006381A1 - プラズマディスプレイパネルの製造方法 - Google Patents
プラズマディスプレイパネルの製造方法 Download PDFInfo
- Publication number
- WO2005006381A1 WO2005006381A1 PCT/JP2004/010365 JP2004010365W WO2005006381A1 WO 2005006381 A1 WO2005006381 A1 WO 2005006381A1 JP 2004010365 W JP2004010365 W JP 2004010365W WO 2005006381 A1 WO2005006381 A1 WO 2005006381A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- film
- substrate
- chamber
- vacuum
- plasma display
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/10—AC-PDPs with at least one main electrode being out of contact with the plasma
- H01J11/12—AC-PDPs with at least one main electrode being out of contact with the plasma with main electrodes provided on both sides of the discharge space
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/34—Vessels, containers or parts thereof, e.g. substrates
- H01J11/40—Layers for protecting or enhancing the electron emission, e.g. MgO layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/50—Filling, e.g. selection of gas mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/02—Manufacture of electrodes or electrode systems
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
Definitions
- the present invention relates to a method for manufacturing a plasma display panel, which forms a film on a substrate for a plasma display panel (PDP), which is known as a thin, lightweight display device having a large screen.
- PDP plasma display panel
- ultraviolet light is generated by gas discharge, and the phosphor is excited by the ultraviolet light to emit light, thereby displaying an image.
- PDPs can be broadly classified into AC and DC drive systems. Discharge systems include surface discharge and opposing discharge types, and are manufactured in accordance with higher definition, larger screen, and simpler structure. For simplicity, AC-type and surface-discharge PDPs with a three-electrode structure are currently the mainstream.
- the PDP of the AC type surface discharge consists of a front plate and a back plate.
- the front plate has, on a substrate such as glass, a display electrode composed of a scanning electrode and a sustain electrode, a dielectric layer covering the display electrode, and a protective layer covering the display electrode.
- the back plate has a plurality of address electrodes, a dielectric layer covering the address electrodes, partitions on the dielectric layers, and phosphor layers provided on the dielectric layers and on the side surfaces of the partitions.
- the front plate and the rear plate are arranged to face each other so that the display electrode and the address electrode are orthogonal to each other, and a discharge cell is formed at the intersection of the display electrode and the address electrode.
- PDPs can display at higher speeds than liquid crystal panels, have a wide viewing angle, are easy to increase in size, and are self-luminous. Due to its high quality, it has recently attracted particular attention among flat panel displays, and has been used as a display device in places where many people gather and as a display device for enjoying large-screen images at home. It is used for applications.
- electrodes are formed on the glass substrate of the front plate on the image display surface side, a dielectric layer covering the electrodes is formed, and a metal oxide film as a protective layer covering the dielectric layers is formed. It forms a magnesium oxide (MgO) film.
- MgO magnesium oxide
- an electron beam evaporation method that can form a relatively high-quality MgO film with a high deposition rate is widely used. For example, this is disclosed in, for example, 2000 FPD Technology Ichizen (Electronic Journal, Inc., October 25, 2000, p598-P600). ⁇
- gas is introduced into the deposition site during deposition to control the atmosphere in the deposition site and stabilize film properties. Therefore, it is necessary to appropriately control the gas introduction state in order to stabilize the film properties.
- the present invention has been made in view of such problems, and has as its object to form a high-quality metal oxide film such as a MgO film on a PDP substrate. Disclosure of the invention
- the method for producing a PDP of the present invention comprises: And have your method of manufacturing a PDP comprising a step of forming a metal oxide film to the substrate DP, upon deposition of the metal oxide film, the degree of vacuum in the film deposition chamber 1 X 1 0- a ⁇ l X 1 0- 2 It is characterized by being in the range of Pa.
- FIG. 1 is a sectional perspective view showing a schematic structure of a plasma display panel according to one embodiment of the present invention.
- FIG. 2 is a sectional view showing a schematic configuration of a film forming apparatus according to one embodiment of the present invention.
- FIG. 1 is a cross-sectional perspective view showing an example of a schematic configuration of a PDP manufactured by a method of manufacturing a PDP according to an embodiment of the present invention.
- the front panel 2 of the PDP 1 has a display electrode 6 including a scan electrode 4 and a sustain electrode 5 formed on one main surface of a transparent and insulating substrate 3 such as glass, and a dielectric covering the display electrode 6.
- the structure has a body layer 7 and a protective layer 8 made of, for example, MgO, which further covers the dielectric layer 7.
- the scanning electrode 4 and the sustaining electrode 5 have a structure in which bus electrodes 4b and 5b made of a metal material, for example, Ag are laminated on the transparent electrodes 4a and 5a for the purpose of reducing electric resistance.
- the back plate 9 includes an address electrode 11 formed on one main surface of an insulating substrate 10 such as glass, a dielectric layer 12 covering the address electrode 11, and a dielectric layer 12.
- This structure has a partition wall 13 located at a position corresponding to an upper adjacent electrode electrode 11 and phosphor layers 14 R, 14 G, and 14 B between the partition walls 13.
- the front plate 2 and the rear plate 9 are arranged so that the display electrode 6 and the address electrode 11 are opposed to each other with the partition wall 13 therebetween, and the periphery outside the image display area is sealed with a sealing member. Have been.
- a Ne-Xe 5% discharge gas is supplied at a pressure of 66.5 kPa (500 Torr). Enclosed.
- the intersection of the display electrode 6 and the address electrode 11 in the discharge space 15 operates as a discharge cell 16 (unit light emitting area).
- the front plate 2 first forms the scan electrodes 4 and the sustain electrodes 5 on the substrate 3. Specifically, a film of, for example, ITO is formed on the substrate 3 by a film forming process such as vapor deposition or sputtering, and thereafter, the transparent electrodes 4a and 5a are formed by patterning by a photolithography method or the like. Further, a film of, for example, Ag is formed thereon by a film forming process such as vapor deposition or sputtering, and thereafter, patterning is performed by a photolithography method or the like, thereby forming bus electrodes 4b and 5b. Thus, the display electrode 6 including the scanning electrode 4 and the sustain electrode 5 can be obtained.
- a film of, for example, ITO is formed on the substrate 3 by a film forming process such as vapor deposition or sputtering, and thereafter, the transparent electrodes 4a and 5a are formed by patterning by a photolithography method or the like.
- a film of, for example, Ag is formed there
- the dielectric layer 7 is formed by applying a paste containing a lead-based glass material by screen printing, for example, and then firing the paste.
- the above lead-based glass materials The pastes containing additives include, for example, PbO (70 wt%), B 2 ⁇ 3 (15 wt%) Si 0 2 (10 wt%), and Al 2 ⁇ 3 (5 wt% ) And an organic binder (for example, ⁇ -Euichi pineole with 10% ethyl cellulose dissolved).
- a protective layer 8 made of a metal oxide film, for example, MgO.
- the back plate 9 forms the address electrode 11 on the substrate 10.
- a film made of, for example, an Ag material is formed on the substrate 10 by a film forming process such as vapor deposition and sputtering, and then the address electrodes 11 are patterned by a photolithography method or the like. Form. Further, the address electrode 11 is covered with a dielectric layer 12 to form a partition 13.
- phosphor layers 14 R, 14 G, and 14 B composed of red (R), green (G), and blue (B) phosphor particles are formed in the grooves between the partition walls 13.
- a paste-like phosphor ink composed of phosphor particles of each color and an organic binder is applied, and the paste is burned to burn off the organic vanida, thereby forming a phosphor layer 14 R formed by binding the phosphor particles. , 14G and 14B.
- the front plate 2 and the rear plate 9 manufactured as described above are overlapped so that the display electrode 6 of the front plate 2 and the address electrode 11 of the rear plate 9 are orthogonal to each other, and the periphery is sealed with sealing glass. This is baked to form an airtight seal layer (not shown) through a bonding member, thereby sealing. Then, once the discharge space 15 is evacuated to a high vacuum, a discharge gas (for example, He-Xe-based or Ne-Xe-based inert gas) is filled at a predetermined pressure.
- a discharge gas for example, He-Xe-based or Ne-Xe-based inert gas
- FIG. 2 is a cross-sectional view illustrating an example of a schematic configuration of a film forming apparatus 20 for forming the protective layer 8.
- the film forming apparatus 20 includes a vapor deposition chamber 21 that is a film forming chamber for depositing MgO on a PDP substrate 3 to form a protective layer 8 that is a Mg thin film, and a substrate Substrate 3 is pre-heated before charging 3, substrate input chamber 22 for pre-evacuation, and substrate removal for cooling substrate 3 taken out after evaporation in evaporation chamber 21 Room 23 is provided.
- Each of the above-mentioned substrate loading chamber 22, vapor deposition chamber 21, and substrate unloading chamber 23 has a hermetically sealed structure so that the inside can be evacuated, and each chamber has an independent vacuum evacuation system 24. a, 24b, 24c are provided respectively.
- a transport means 25 such as a transport roller, a wire, and a chain is provided through the substrate input chamber 22, the vapor deposition chamber 21, and the substrate unloading chamber 23. Also, between the outside air and the substrate input chamber 22, between the substrate input chamber 22 and the evaporation chamber 21, between the evaporation chamber 21 and the substrate extraction chamber 23, and between the substrate extraction chamber 23 and the outside air.
- the walls are separated by partition walls 26a, 26b, 26c and 26d which can be opened and closed. The interlocking of the drive of the transfer means 25 and the opening and closing of the partition walls 26a, 26b, 26c, 26d allows the substrate loading chamber 22, vapor deposition chamber 21 and substrate unloading chamber 23 Variations in vacuum are minimized.
- the substrate 3 is sequentially passed from outside the film forming apparatus through the substrate loading chamber 22, the vapor deposition chamber 21, and the substrate unloading chamber 23, performing predetermined processing in each chamber, and then out of the film forming apparatus 20. It is possible to carry it out, and it is possible to continuously form a film of Mg on a plurality of substrates 3.
- Heating lamps 27a and 27b for heating the substrate 3 are installed in each of the substrate loading chamber 22 and the vapor deposition chamber 21. Note that substrate 3 Is usually carried out while being held by the substrate holder 30.
- the vapor deposition chamber 21 which is a film formation chamber will be described.
- the vapor deposition chamber 21 is provided with a hearth 28 b containing M g ⁇ particles serving as a vapor deposition source 28 a, an electron gun 28 c, and a deflection magnet (not shown) for applying a magnetic field.
- the electron beam 28 d emitted from the electron gun 28 c is deflected by the magnetic field generated by the deflection magnet and irradiates the evaporation source 28 a, and the vapor flow of the evaporation source 28 a, M g O 28 e Generate.
- the generated vapor flow 28 e is deposited on the surface of the substrate 3 held by the substrate holder 30 to form the MgO protective layer 8.
- the present inventors have confirmed by examination that the physical properties of the MgO film serving as the protective layer 8 change due to oxygen deficiency or impurity contamination during the film formation process. This is because, for example, if oxygen is deficient or impurities such as C and H are mixed in the MgO, the bond between the Mg atom and the ⁇ atom in the MgO film is disturbed, and this is caused by This is probably because the state of secondary electron emission changes due to the presence of dangling pounds that are not involved in the bonding.
- various gases are deposited during the film formation in order to control the amount of dangling bonds in the MgO film.
- the atmosphere is controlled by being introduced into a film formation chamber.
- oxygen gas can be used for the purpose of preventing oxygen deficiency and suppressing the amount of dangling bonds.
- At least one gas selected from water, hydrogen, carbon monoxide, and carbon dioxide can be used for the purpose of increasing the amount of dangling bonds by being incorporated into the water.
- gas is introduced to control the atmosphere in evaporation chamber 21
- the present inventors have studied and confirmed that if the degree of vacuum in the film formation field changes when film formation is to be performed, the film formation rate and film quality will be adversely affected.
- the present inventors have study results, as an index of the degree of vacuum in Japanese to the deposition field by vapor deposition chamber 2 1 a deposition chamber, 1 X 1 0 1 P a to; the LX 1 0 _2P a It has been confirmed that it is important to form a film while maintaining it within a certain range in order to form a high quality metal oxide film.
- the film formation field refers to a space between the hearth 28 b and the substrate 3 in the vapor deposition chamber 21, and the degree of vacuum in the following description refers to the degree of vacuum. It refers to the degree of vacuum in the membrane field.
- the method for manufacturing a plasma display panel of this embodiment Contact information, a step of forming a metal oxide film such as MgO, the degree of vacuum Narumakujo is 1 ⁇ 0- i P a ⁇ l X 1 0 It is characterized in that it is performed while controlling to be in the range of 2Pa.
- the film formation rate and film quality are improved, and thus, a high-quality MgO film can be formed.
- various gases for controlling the atmosphere of the vapor deposition chamber 21 can be introduced into the vapor deposition chamber 21 which is a film forming chamber.
- At least one gas introducing means 29a is installed.
- an inert gas such as argon, nitrogen, and helium can be introduced alone or in combination.
- control means for controlling the gas introduction amount from the gas introduction means 29a and the exhaust amount by the vacuum exhaust system 24b so that the degree of vacuum in the chamber 21 is within a certain range. have.
- 1 X 1 0 one 1 P a ⁇ lxi 0- 2 can be a state of being controlled in the range of P a, in this state, it is possible to perform the deposition of a e.g. Mg O a metal oxide film Become.
- the degree of vacuum in the film formation site may be controlled within a certain range by introducing a gas containing oxygen or oxygen into the film formation site, adjusting the amount of gas introduced therein, and equilibrating with the exhaust gas.
- oxygen or a gas containing oxygen is introduced in a fixed amount, and at least one gas selected from water, hydrogen, carbon monoxide, and carbon dioxide is also introduced in a fixed amount to obtain a predetermined physical property of Mg.
- the degree of vacuum at the film formation site is controlled by introducing an inert gas such as Ar, nitrogen, or helium into the film formation site, adjusting the amount of introduction, and equilibrating with the exhaust gas. In this way, control can be performed within a certain range.
- the inert gas does not have a chemical effect on the MgO film, so it only affects the degree of vacuum without affecting the physical properties of the Mg ⁇ film. Can be made.
- At least one of an inert gas and carbon dioxide and an oxygen gas are introduced into the film formation site, and the amount of the introduced gas is adjusted and equilibrated with the exhaust gas to control the degree of vacuum within a certain range. Is also good.
- the substrate 3 is heated by the heating lamp 27b and kept at a constant temperature. This temperature is set at about 100 ° C. (: up to about 400 ° C.) so that the display electrodes 6 and the dielectric layer 7 already formed on the substrate 3 are not thermally degraded. Then, with the shirt 28 f closed, the electron beam 28 d is irradiated from the electron gun 28 c onto the evaporation source 28 a to preheat, thereby removing the impure gas.
- the gas is introduced from the gas introducing means 29a, such as oxygen gas, at least one gas selected from water, hydrogen, carbon monoxide, and carbon dioxide, for example.
- An inert gas such as argon can be used.
- the introduction amount of the gas to the introduction by balancing the exhaust volume by vacuum exhaust system 2 4 b, 1 X 1 0- ⁇ a vacuum; LX 1 0 - controls to one holding the 2 P a .
- the vapor stream 28 e of MgO is jetted toward the substrate 3.
- a protective layer 8 of a MgO film is formed on the substrate 3 by the vaporized material flying on the substrate 3.
- the film thickness of the protective layer 8, which is a deposited film of the MgO film formed on the substrate 3 reaches a predetermined value (for example, about 0.5 mm), close the shirt 28 mm,
- the substrate 3 is transferred to the substrate unloading chamber 23 through the partition wall 26c.
- the film formation site in the above description refers to the space between the housing 28 b and the substrate 3 in the evaporation chamber 21.
- the degree of vacuum at the deposition site indicates the degree of vacuum in the space.
- the introduction of the predetermined gas for maintaining the quality of the MgO film at a predetermined level and the introduction of the gas for controlling the degree of vacuum of the film deposition site at that time are performed by the gas introduction means 29a as described above. It is.
- the substrate 3 is heated between the substrate loading chamber 22 and the vapor deposition chamber 21 according to the setting condition of the temperature profile of the substrate 3.
- one or more substrate cooling chambers between the evaporation chamber 21 and the substrate extraction chamber 23 may be used.
- the deposition of MgO on the substrate 3 in the vapor deposition chamber 21 may be performed while the substrate 3 is stopped and stopped, or may be performed while the substrate 3 is being transferred.
- the structure of the film forming apparatus 20 is not limited to the above-described one, and a structure in which a buffer is provided between each chamber for tact adjustment and a chamber for heating and cooling are provided.
- the effects of the present invention can be obtained even for a structure, a structure in which a film is formed by a batch method, and the like.
- the protective layer 8 was formed by vapor deposition with MgO.
- the present invention is not limited to MgO or vapor deposition, and a metal oxide film is formed. A similar effect can be obtained for the case.
- a method of manufacturing a PDP capable of forming a metal oxide film having good film physical properties can be realized, and excellent display performance can be achieved.
- Plasma display device and the like can be realized.
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- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Gas-Filled Discharge Tubes (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/532,672 US20060003086A1 (en) | 2003-07-15 | 2004-07-14 | Method for manufacturing plasma display panel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003197158 | 2003-07-15 | ||
JP2003-197158 | 2003-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005006381A1 true WO2005006381A1 (ja) | 2005-01-20 |
Family
ID=34055844
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/010365 WO2005006381A1 (ja) | 2003-07-15 | 2004-07-14 | プラズマディスプレイパネルの製造方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060003086A1 (ja) |
JP (1) | JP5152249B2 (ja) |
KR (2) | KR20070070261A (ja) |
CN (1) | CN1717765A (ja) |
WO (1) | WO2005006381A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015159309A1 (en) | 2014-04-18 | 2015-10-22 | Cadila Healthcare Limited | Novel purification process of gonadotropin |
DE102014215387A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
DE102014215380A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5040217B2 (ja) * | 2005-09-13 | 2012-10-03 | パナソニック株式会社 | 保護膜形成方法および保護膜形成装置 |
US11735643B2 (en) * | 2019-10-28 | 2023-08-22 | Ramot At Tel-Aviv University Ltd. | Heterogeneous structures comprising III-V semiconductors and metal oxide dielectrics, and a method of fabrication thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000129428A (ja) * | 1998-10-23 | 2000-05-09 | Anelva Corp | 酸化マグネシウム膜の作製方法 |
WO2001059173A1 (en) * | 2000-02-09 | 2001-08-16 | Fujikura Ltd. | METHOD FOR FABRICATING MgO POLYCRYSTALLINE THIN FILM |
JP2001243886A (ja) * | 2000-03-01 | 2001-09-07 | Toray Ind Inc | プラズマディスプレイ用部材およびプラズマディスプレイならびにその製造方法 |
JP2002056773A (ja) * | 2000-08-08 | 2002-02-22 | Matsushita Electric Ind Co Ltd | プラズマディスプレイパネル用膜形成方法及びプラズマディスプレイパネル用膜形成装置 |
JP2003031136A (ja) * | 2001-07-18 | 2003-01-31 | Nec Corp | プラズマディスプレイパネルおよびその製造方法 |
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JP3836184B2 (ja) * | 1996-05-01 | 2006-10-18 | 中外炉工業株式会社 | 酸化マグネシウム膜の製造方法 |
JPH10204625A (ja) * | 1997-01-14 | 1998-08-04 | Sumitomo Heavy Ind Ltd | MgO膜成膜方法及び成膜装置 |
KR100798986B1 (ko) * | 2000-03-31 | 2008-01-28 | 마츠시타 덴끼 산교 가부시키가이샤 | 플라즈마 디스플레이 패널의 제조방법 |
JP4153983B2 (ja) * | 2000-07-17 | 2008-09-24 | パイオニア株式会社 | 保護膜、その成膜方法、プラズマディスプレイパネル及びその製造方法 |
US7037156B2 (en) * | 2001-12-25 | 2006-05-02 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a plasma display panel with adsorbing an impurity gas |
JP2005050804A (ja) * | 2003-07-15 | 2005-02-24 | Matsushita Electric Ind Co Ltd | プラズマディスプレイパネルの製造方法およびその製造装置 |
-
2004
- 2004-07-14 KR KR1020077013482A patent/KR20070070261A/ko not_active Application Discontinuation
- 2004-07-14 WO PCT/JP2004/010365 patent/WO2005006381A1/ja active Application Filing
- 2004-07-14 CN CNA2004800014668A patent/CN1717765A/zh active Pending
- 2004-07-14 KR KR1020057008408A patent/KR20050071683A/ko not_active IP Right Cessation
- 2004-07-14 US US10/532,672 patent/US20060003086A1/en not_active Abandoned
-
2010
- 2010-04-28 JP JP2010103404A patent/JP5152249B2/ja not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000129428A (ja) * | 1998-10-23 | 2000-05-09 | Anelva Corp | 酸化マグネシウム膜の作製方法 |
WO2001059173A1 (en) * | 2000-02-09 | 2001-08-16 | Fujikura Ltd. | METHOD FOR FABRICATING MgO POLYCRYSTALLINE THIN FILM |
JP2001243886A (ja) * | 2000-03-01 | 2001-09-07 | Toray Ind Inc | プラズマディスプレイ用部材およびプラズマディスプレイならびにその製造方法 |
JP2002056773A (ja) * | 2000-08-08 | 2002-02-22 | Matsushita Electric Ind Co Ltd | プラズマディスプレイパネル用膜形成方法及びプラズマディスプレイパネル用膜形成装置 |
JP2003031136A (ja) * | 2001-07-18 | 2003-01-31 | Nec Corp | プラズマディスプレイパネルおよびその製造方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015159309A1 (en) | 2014-04-18 | 2015-10-22 | Cadila Healthcare Limited | Novel purification process of gonadotropin |
DE102014215387A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
DE102014215380A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
Also Published As
Publication number | Publication date |
---|---|
KR20050071683A (ko) | 2005-07-07 |
JP5152249B2 (ja) | 2013-02-27 |
KR20070070261A (ko) | 2007-07-03 |
CN1717765A (zh) | 2006-01-04 |
JP2010192461A (ja) | 2010-09-02 |
US20060003086A1 (en) | 2006-01-05 |
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