WO2004097469A1 - コレステリック液晶フィルム、その製造方法および円偏光反射フィルム、ニ波長域反射型反射フィルム - Google Patents
コレステリック液晶フィルム、その製造方法および円偏光反射フィルム、ニ波長域反射型反射フィルム Download PDFInfo
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- WO2004097469A1 WO2004097469A1 PCT/JP2004/005360 JP2004005360W WO2004097469A1 WO 2004097469 A1 WO2004097469 A1 WO 2004097469A1 JP 2004005360 W JP2004005360 W JP 2004005360W WO 2004097469 A1 WO2004097469 A1 WO 2004097469A1
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3016—Polarising elements involving passive liquid crystal elements
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
- G02F1/133533—Colour selective polarisers
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
- G02F1/133543—Cholesteric polarisers
Definitions
- Cholesteric liquid crystal film method for producing the same, circularly polarized light reflective film, dual wavelength reflective film
- the present invention relates to a cholesteric liquid crystal film and a method for producing the same.
- INDUSTRIAL APPLICABILITY The cholesteric liquid crystal film of the present invention has at least two independent selective reflection wavelength bands and is useful as a circularly polarized light reflector (a circularly polarized light reflective polarizer).
- the reflection plate can be used as a reflection film, which is formed by stacking the reflection plates and specifically reflecting two specific wavelength regions. For example, two specific wavelength regions are
- these are useful as visual protection films. They are suitably used for eyeglasses such as sunglasses, safety glasses for laser work, vehicle window glass for automobiles, and residential window glass. Further, when two specific wavelength regions exist in the visible light wavelength region, they are suitably used as a complementary color filter or the like of a liquid crystal display device.
- a cholesteric liquid crystal having a function of separating circularly polarized light has a selective reflection characteristic that reflects only the circularly polarized light whose wavelength is the spiral pitch of the liquid crystal because the direction of rotation of the liquid crystal helix coincides with the direction of circular polarization. is there.
- This selective reflection characteristic only specific circularly polarized light of natural light in a certain wavelength band is transmitted and separated, and the remaining is reflected and reused, so that a highly efficient circularly polarized light reflective film can be manufactured. .
- the circularly polarized light reflective film can also obtain a function as a reflective film by laminating two types of cholesteric spirals having substantially the same selective reflection wavelength band and opposite rotation directions.
- the same reflection film can also be obtained by laminating two types of cholesteric spirals having substantially the same selective reflection wavelength band and the same cholesteric helix rotation direction with two plates interposed therebetween. .
- the selective reflection characteristics of cholesteric liquid crystals are limited to only a specific wavelength band, and it has been difficult to perform power analysis over the entire visible light range.
- the selective reflection wavelength range width ⁇ ⁇ of the cholesteric liquid crystal is
- ne Refractive index of cholesteric liquid crystal molecules to extraordinary light
- the selective reflection wavelength region width ⁇ ⁇ is widened, but ne- ⁇ is usually 0.3 or less. If this value is increased, other functions (alignment characteristics, liquid crystal temperature, etc.) of the liquid crystal become insufficient, and practical use was difficult. Therefore, in practice, the selective reflection wavelength region width ⁇ ⁇ was at most 150 nm at most. Most of the cholesteric liquid crystals that can be practically used are only about 30 to 100 nm.
- the selective reflection center wavelength ⁇ is
- the pitch is constant, it depends on the average refractive index of the liquid crystal molecules and the pitch length. Therefore, in order to freely control the reflection / transmission characteristics for different arbitrary reflection wavelength bands, a plurality of cholesteric liquid crystal layers having different selective reflection center wavelengths are laminated.
- a protective eyeglass filter that selectively reflects ultraviolet and infrared wavelengths is required.
- at least another set of identical films is required for a cholesteric liquid crystal film to function as a reflective film. Therefore, in order to obtain the above-mentioned safety glasses filter, the number of laminated cholesteric liquid crystal layers must be at least four, and when two plates are interposed, at least five layers are required.
- two or more types of cholesteric liquid crystal layers can be coated by two methods. Only a method of laminating the above cholesteric liquid crystal layers or a method of mixing two or more types of pulverized liquid crystal thin films to form a film containing a mixture is known. In other words, the conventional method requires at least two cholesteric liquid crystal layer deposition steps. ⁇
- the same optical material (polarized reflection film) as the cholesteric liquid crystal layer is used.
- an interference filter obtained by depositing an inorganic material is known.
- the interference filter is manufactured by the vacuum evaporation method, so that the cost of the manufacturing apparatus is high, and the number of laminations is more than ten to twenty or more, so high cost cannot be avoided.
- stretched products of resin layer thin film laminates with different refractive indices such as 3M DBEF, ESR, and GBO multilayer films, are known. A stretching step was required. Disclosure of the invention
- An object of the present invention is to provide a cholesteric liquid crystal film which is easily obtained and has at least two independent selective reflection wavelength bands, and a method for producing the same.
- the present invention provides a circularly polarized light reflective plate using the cholesteric liquid crystal film, a reflective film using the circularly polarized light reflective film, and various kinds of films using the reflective film. It is intended to provide an optical article.
- the present inventors have made intensive studies to solve the above problems, and as a result, have found that the following objects can be achieved by the following cholesteric liquid crystal film and a method for producing the same, and have completed the present invention. That is, the present invention is as follows.
- a cholesteric liquid crystal film obtained by applying a liquid crystal mixture containing a polymerizable mesogen compound (A) and a polymerizable chiral agent (B) to an alignment substrate, and irradiating with ultraviolet light.
- Cholesteric LCD film consists of one layer
- a cholesteric liquid crystal film having at least two independent selective reflection wavelength bands having at least two independent selective reflection wavelength bands.
- a two-wavelength-range-compatible reflective film obtained by laminating a ⁇ 2 plate between two circularly polarized light-reflective films described in the above item 8.
- a reflection film compatible with a two-wavelength region, wherein the reflection wavelength bands substantially match and the cholesteric twist direction is the same.
- the cholesteric liquid crystal film of the present invention is a single-layer film, and has at least two independent selective reflection wavelength bands.
- the independent selective reflection wavelength band is appropriately selected depending on the purpose of use.
- the independent selective reflection wavelength bandwidth is preferably about 20 to 200 nm.
- the selective reflection wavelength bandwidth is measured by the method described in the embodiment.
- Such a cholesteric liquid crystal film is prepared, for example, by applying a liquid crystal mixture containing a polymerizable mesogen compound (A) and a polymerizable chiral agent (B) to an alignment substrate, and preventing polymerization on the alignment substrate side under oxygen-induced polymerization inhibition. It can be obtained by irradiating ultraviolet light from above. Therefore, a cholesteric liquid crystal film having any two or more selective reflection wavelength bands can be obtained at a low cost by reducing the number of layers and the number of steps as compared with the conventional method. .
- the method for producing a cholesteric liquid crystal film of the present invention includes the polymerization of a cholesteric liquid crystal exposed surface due to oxygen inhibition and a non-exposed surface with a base material as described in Japanese Patent Application No. 2001-339396. This is based on the speed difference. In other words, when the exposure direction is set from the substrate surface side, the difference in polymerization rate is remarkably enlarged, and the composition ratio of the cholesteric liquid crystal mixture is changed so as to change in the thickness direction, whereby the cholesteric liquid crystal is formed. This is a further development of the technique of forming the difference in pitch length between the cholesteric liquid crystal exposed surface and the substrate surface side.
- cholesteric liquid crystal materials having different reaction rates are used, and these are heated under the polymerization conditions for the purpose of broadening the band described in Japanese Patent Application No. 2001-3396932.
- the pitch length of the cholesteric liquid crystal layer can be separated into at least two discontinuous portions farthest apart from each other due to the difference in mass transfer speed of the liquid crystal material.
- the basic principle is that the selective reflection wavelength band of the cholesteric liquid crystal obtained by the initial polymerization exists at a value determined by the liquid crystal composition before polymerization, while the liquid crystal composition is obtained by polymerization and heating. Is promoted, and independent selective reflection wavelength bands are generated in different wavelength bands.
- cholesteric liquid crystal material a mixture of a polymerizable mesogen compound (A) and a polymerizable helical agent (B) is used.
- the reactivity ⁇ reaction rate is such that the polymerizable mesogen compound (A) ⁇ the polymerizable chiral agent (B)
- the polymerization starts at the selective reflection wavelength determined by the initial mixing ratio by the initiation of polymerization.
- the consumption rate of the polymerizable chiral agent (B) is high, the polymerizable mesogen compound (A) is left with the progress of polymerization, and the monomer ratio in the remaining composition changes from the initial ratio.
- the monomer transfer rate can be controlled to control the mixing ratio of the polymerizable mesogen compound (A): polymerizable chiral agent (B) at the latter stage of the polymerization. .
- the polymerizable chiral agent (B) was mostly consumed, that is, the polymerizable mesogen compound (A) was completed in a rich situation, so the latter was cured in the latter half of the polymerization.
- This layer can form a selective reflection wavelength band that is largely shifted on the long wavelength side where the twist is weak.
- the liquid crystal mixture containing the polymerizable mesogen compound (A) and the polymerizable chiral agent (B) is formed by one-layer coating and by one irradiation of ultraviolet light. Regions having different pitches can be formed in the thickness direction of the formed cholesteric liquid crystal layer, and a cholesteric liquid crystal film having two or more selective reflection wavelength bands can be obtained.
- the ambient temperature in the ultraviolet irradiation is increased to achieve the same effect as described above by one-layer coating.
- a cholesteric liquid crystal film having more than one kind of selective reflection wavelength band can be obtained. In this case, it is possible to raise the environmental temperature in the ultraviolet irradiation and to control the ultraviolet illuminance.
- the reaction rate By using various relationships, it is also possible to control the film structure formed by reversing the above, the interval between the selective reflection wavelength bands, and the magnitude of the peak of the selective reflection center wavelength.
- FIG. 1 shows the reflection spectrum of the cholesteric liquid crystal film obtained in Example 1.
- FIG. 2 shows the reflection spectrum of the cholesteric liquid crystal film obtained in Example 2.
- the broadband cholesteric liquid crystal film of the present invention is obtained by ultraviolet polymerization of a liquid crystal mixture containing a polymerizable mesogen compound (A) and a polymerizable chiral agent (B). It is preferable that the polymerizable mesogen compound (A) and the polymerizable chiral agent (B) have different reaction rates. For example, when the number of polymerizable functional groups is large, the reaction rate increases.
- the polymerizable mesogen compound (A) a compound having at least one polymerizable functional group and having a mesogen group composed of a cyclic unit or the like is preferably used.
- the polymerizable functional group include an acryloyl group, a methacryloyl group, an epoxy group, and a vinyl ether group. Of these, an acryloyl group and a methacryloyl group are preferable. Also, by using a compound having two or more polymerizable functional groups, a crosslinked structure can be introduced to improve durability.
- Examples of the cyclic unit to be a mesogen group include biphenyl-based, phenylbenzoate-based, phenylcyclohexane-based, azoxybenzene-based, azomethine-based, azobenzene-based, and phenylpyrimido. Gins, diphenylacetylenes, diphenylbenzoates, bicyclohexanes, cyclohexylbenzenes, terphenyls and the like can be mentioned.
- the terminal of these cyclic units may have a substituent such as a cyano group, an alkyl group, an alkoxy group, and a halogen group.
- the mesogen group may be bonded via a spacer that imparts flexibility.
- the spacer section include a polymethyl chain and a polyoxymethylene chain.
- the number of repeating structural units that form the spacer portion is appropriately determined by the chemical structure of the mesogen portion, but the number of repeating units in the polymethylene chain is 0 to 20, preferably 2 to 12, and
- the repeating unit of the xymethylene chain is from 0 to: 10, preferably:! ⁇ 3.
- the polymerizable mesogen compound (A) having one polymerizable functional group is, for example, represented by the following general formula (1):
- n represents an integer of 1 to 5).
- polymerizable mesogen compound (A) having one polymerizable functional group examples include, for example, compounds represented by the following polymerizable mesogen compounds (1) to (4). .
- the polymerizable chiral agent (B) for example, one having at least one polymerizable functional group and having an optically active group is preferably used.
- the polymerizable functional group is the same as described above.
- the polymerizable mesogen compound (A) has one polymerizable functional group
- the polymerizable chiral agent (B) is preferably a compound having two or more polymerizable functional groups.
- polymerizable chiral agent (B) having two or more polymerizable functional groups for example, the following general formula (2):
- R 2 and R 3 each represent a hydrogen atom or a methyl group
- R 4 and R 5 each represent an optionally substituted alkylene group having 1 to 12 carbon atoms
- 1 and m are each independently And an integer of 1 to 3).
- Examples of the polymerizable chiral agent (B) having two or more polymerizable functional groups include LC756 made by BASF.
- the compounding amount of the polymerizable chiral agent (B) is the same as that of the polymerizable mesogen compound (A).
- the amount is preferably about 1 to 20 parts by weight, more preferably 3 to 7 parts by weight, based on the total of 100 parts by weight of the sex chiral agent (B).
- the helical torsional force (HTP) is controlled by the ratio of the polymerizable mesogen compound (A) and the polymerizable chiral agent (B). By setting the ratio within the above range, the reflection spectrum of the obtained cholesteric liquid crystal film can select a reflection band even in a long wavelength region.
- the liquid crystal mixture usually contains a photopolymerization initiator (C).
- a photopolymerization initiator C
- Various photopolymerization initiators (C) can be used without particular limitation.
- Lucylene TPO (Lucirin TPO) manufactured by BASF is preferably used.
- the compounding amount of the photopolymerization initiator is preferably about 0.01 to 10 parts by weight based on 100 parts by weight of the total of the polymerizable mesogen compound (A) and the polymerizable chiral agent (B). 0.5-5 parts by weight is more preferred. Under an air atmosphere, the required amount of the photopolymerization initiator tends to be large. However, if irgacure 369 irgacure 907 is used, the desired purpose can be achieved with an addition amount of about 3 to 5 parts by weight.
- An additive such as a surfactant may be used in the liquid crystal mixture in order to smooth a coated surface.
- the addition amount of the surfactant and the like can be set according to the coating characteristics of the liquid crystal mixture.
- the amount is about 0.1 part by weight or less based on 100 parts by weight of the total of the polymerizable mesogen compound (A) and the polymerizable chiral agent (B). More preferably, the amount is about 0.01 to 0.1 part by weight.
- Fluorad71 manufactured by 3M, Zony1Fsn, manufactured by Dupnt, BYK3661, manufactured by BigChem Japan, etc. are suitably used.
- These additives can be appropriately selected in consideration of the type of liquid crystal mixture, mixing characteristics, and the like.
- the mixture may be mixed with an ultraviolet absorber to increase the difference in ultraviolet exposure intensity in the thickness direction.
- an ultraviolet absorber to increase the difference in ultraviolet exposure intensity in the thickness direction.
- a similar effect can be obtained by using a photopolymerization initiator having a large molar extinction coefficient.
- the mixture can be used as a solution.
- Solvents used for preparing the solution are usually chloroform, dichloromethane, dichloromethane, tetrachlorethane, trichloroethylene, tetrachloroethylene, and chloroethylene.
- Halogenated hydrocarbons such as mouth benzene, phenols such as phenol and parachlorophenol, aromatic hydrocarbons such as benzene, toluene, xylene, methoxybenzene, 1,2-dimethoxybenzene, and others , Acetone, methylethyl ketone, ethyl acetate, tert-butyl alcohol, glycerin, ethylene glycol, triethylene glycol cone, ethylene glycol Norlev, 2—pyrrolidone, N— Chill-2—pyrrolidone, pyridine, triethylamine, tetrahydrofuran, dimethylformamide, dimethylacetamide, dimethylsulfoxide, acetonitrile, ptyronitrile, carbon disulfide, cyclopentano And cyclohexanone can be used.
- the solvent to be used is not particularly limited, but methylethyl ketone, cyclohexanone, cyclopentanonone and the like are preferable.
- the concentration of the solution cannot be said unconditionally because it depends on the solubility of the thermotropic liquid crystalline compound and the final thickness of the target cholesteric liquid crystal film, but it is usually about 3 to 50% by weight. Is preferred.
- the production of the broadband cholesteric liquid crystal film of the present invention includes a step of applying the liquid crystal mixture to an alignment substrate, and a step of irradiating the liquid crystal mixture with ultraviolet rays and polymerizing and curing.
- the alignment base material As the alignment base material, a conventionally known one can be used.
- a polymer with a photocrosslinking group such as a rubbing film, obliquely deposited film, or cinnamate diazobenzene formed by forming a thin film made of polyimide or polybutyl alcohol on a substrate and rubbing it with rayon cloth or the like
- a light directing film or a stretched film obtained by irradiating a polyimide with polarized ultraviolet light is used.
- it can be oriented by magnetic field, electric field orientation, and shear stress operation.
- the type of the base material is not particularly limited, but a material having a high transmittance is desirable in view of the method of irradiating irradiation light (ultraviolet rays) from the base material side.
- the substrate is more than 200 n It is required that the transmittance be 10% or more, more preferably 20% or more, in the ultraviolet region of 300 nm or more and 400 nm or less.
- the plastic film has a transmittance of 10% or more to ultraviolet light having a wavelength of 365 nm, more preferably 20% or more.
- the transmittance is a value measured by a U-410 Spectrophotometer manufactured by HI TAC HI.
- a plastic film, glass, or quartz sheet can be used as a substrate.
- the plastic film include polyethylene terephthalate, polyethylene naphthalate (PEN), polyvinyl alcohol (PVA), polycarbonate (PC), triacetyl cellulose (TAC),
- PEN polyethylene naphthalate
- PVA polyvinyl alcohol
- PC polycarbonate
- TAC triacetyl cellulose
- PET polyimide
- polyacrylate polycarbonate
- polysulfone polyethersulfone
- Examples include Mellinex (PET) manufactured by ICI.Corp, Lumira (PET) manufactured by Toray, Diamond Foil (PET) manufactured by Mitsubishi Chemical Polyester, and Mylar (PET) manufactured by Teijin Dubon.
- the substrate may be used while being bonded to the cholesteric liquid crystal layer or may be peeled off.
- a material whose retardation value is sufficiently small for practical use for example, Fujifilm's Triacetyl Cell p-film (T-TAC, TD_TAC, UZ-TAC), JSR's AR TON, Nippon Zeon's Zonex Zeonaire Film, unstretched PC It is preferable to use a film or the like.
- the side chain is substituted and / or unsubstituted.
- the resin composition include a thermoplastic resin having a mid group and (B) a thermoplastic resin having a substituted or unsubstituted phenyl and a ditril group in a side chain.
- a film of a resin composition containing an alternating copolymer composed of isoptylene and N-methylmaleimide and an acrylonitrile-styrene copolymer is exemplified.
- a film made of a mixed extruded product of a resin composition or the like can be used.
- the base material When the base material is used while being bonded, it is desirable that the base material does not decompose, deteriorate or yellow even when irradiated with ultraviolet rays.
- light stabilizers etc. Achieve the intended purpose rather than doing it.
- Tinuvin 120 and 144, manufactured by Chipa Specialty Chemicals, etc. are preferably used.
- the wavelength of the exposure light By increasing the wavelength of the exposure light to a wavelength of 300 nm or less, coloring, deterioration, and yellowing can be reduced.
- the coating thickness of the liquid crystal mixture (the coating thickness after drying the solvent in the case of a solution) is preferably about 2 to 20 m. If the coating thickness is less than 1 m, the reflection bandwidth can be secured, but the degree of polarization itself tends to decrease, which is not preferable.
- the coating thickness is preferably 2 ⁇ m or more, and more preferably 3 Xm or more. On the other hand, when the coating thickness is more than 20 m, no remarkable improvement is observed in both the reflection bandwidth and the degree of polarization, and the cost is simply increased, which is not preferable.
- the coating thickness is more preferably 15 ⁇ or less, and more preferably the following.
- the coating thickness of the liquid crystal mixture is from 2 to: L O / im, preferably from 3 to 7 / ⁇ , when importance is attached to the chromaticity that enhances the entire visible light range.
- the infrared reflective film is to have selective reflection characteristics outside the visible light range, it should be 1 ⁇ or more in order to obtain sufficient reflection characteristics up to the long wavelength end of the infrared region where the reflection characteristics are required. Thickness is also used. This is because the selective reflection of the cholesteric liquid crystal has a proportional relationship between the selective reflection wavelength and the helical pitch interval as can be seen from the above equation, and the pitch length needs to be longer as the wavelength becomes longer. To obtain a sufficient reflectance for selective reflection, a thickness of several pitches is required.
- the mixed solution for example, a roll coating method, a gravure coating method, a spin coating method, a bar coating method, or the like can be adopted.
- the solvent is removed, and a liquid crystal layer is formed on the substrate.
- the conditions for removing the solvent are not particularly limited, and it is sufficient that the solvent can be substantially removed, and the liquid crystal layer does not flow or drop.
- the solvent is removed by drying at room temperature, drying in a drying oven, or heating on a hot plate.
- the liquid crystal layer formed on the alignment base material is heated to a temperature equal to or higher than the isotropic transition temperature to be in a liquid crystal state to be cholesterically aligned, and then gradually cooled to maintain a uniform alignment state.
- the liquid crystal mixture is aligned so that the cholesteric spiral axis is perpendicular to the alignment substrate surface.
- heat treatment is performed so that the liquid crystal layer has a liquid crystal temperature range.
- the heat treatment can be performed by the same method as the above-described drying method.
- the heat treatment temperature varies depending on the type of the liquid crystal material and the alignment base material, and cannot be unconditionally determined.
- the heat treatment temperature is usually in the range of 60 to 300 ° C, preferably 70 to 200 ° C.
- the heat treatment time varies depending on the heat treatment temperature and the type of liquid crystal material or alignment base material used, but cannot be unconditionally determined, but is usually in the range of 10 seconds to 2 hours, preferably in the range of 20 seconds to 30 minutes. Selected.
- ultraviolet irradiation is performed from the alignment base material side to polymerize and cure the liquid crystal mixture.
- the ultraviolet irradiation is performed in a state where the liquid crystal mixture is in contact with a gas containing oxygen.
- UV irradiation is performed from the alignment substrate side to actively utilize the inhibition of polymerization by oxygen. That is, the polymerization starts from the side of the oriented base material, and the polymerization proceeds with a delay on the side of oxygen.
- a change in the cholesteric pitch of the cholesteric liquid crystal layer can be formed from the difference in polymerization rate in the thickness direction due to inhibition of oxygen polymerization.
- oxygen that acts as a radical trap when performing ultraviolet irradiation is naturally diffused from the coating film surface side, and the oxygen concentration difference in the thickness direction from the surface to which oxygen is supplied to the alignment substrate side. It is formed.
- the polymerization rate a rate difference is formed in accordance with the concentration of oxygen, which is a polymerization inhibitor, and the cholesteric pitch length changes in the thickness direction.
- the ultraviolet irradiation conditions are not particularly limited, but by combining the ultraviolet irradiation conditions and the heating conditions and controlling them, an independent selective reflection wavelength band can be formed, or the center wavelength of the selective reflection wavelength band can be adjusted. You can change the distance.
- the environmental temperature in UV irradiation can be increased to increase the mass transfer rate.
- the irradiation temperature should be 20 ° C or more. It is preferably about 30 to 150 ° C.
- the ultraviolet irradiation intensity, 2 0 ⁇ 2 0 0 mWZ cm 2 or so, is Raniwa 3 0 ⁇ : 1 5 0 m is preferably WZ cm 2.
- the ultraviolet irradiation time is about 20 to 120 seconds, preferably 25 to 60 seconds.
- the UV irradiation intensity is lower than 20 mWZ cm 2 , polymerization will not be performed to the extent that a monomer distribution is formed in the thickness direction, so that at least two independent selective reflection wavelength bands will not be obtained.
- the polymerization reaction rate is higher than the diffusion rate, so that at least two independent selective reflection wavelength bands are not obtained.
- the irradiation temperature can be adjusted so that the latter stage is higher than the former stage.
- the irradiation temperature in the former stage is preferably about 20 to 100 ° C., and more preferably 30 to 50 ° C.
- the ultraviolet irradiation intensity is preferably about 10 to 200 mW / cm 2 , and more preferably 20 to 150 mWZ cm 2 .
- the ultraviolet irradiation time is about 0.2 to 7 seconds, and preferably 0.3 to 5 seconds.
- the UV irradiation intensity is lower than 10 mWZ cm 2 , polymerization is not performed to the extent that a monomer distribution is formed in the thickness direction, so that at least two independent selective reflection wavelength bands are not obtained.
- the polymerization reaction rate becomes higher than the diffusion rate, so that at least two independent selective reflection wavelength bands are not obtained.
- the heat treatment is performed at about 70 to 100 ° C.
- the heating time is preferably about 2 seconds or more, and more preferably 10 seconds or more. Usually, 2 to: about 20 seconds.
- the irradiation temperature in the latter stage is preferably about 60 to 140 ° C, more preferably 80 to 120 ° C.
- the temperature difference between the former stage and the latter stage is preferably at least 10 ° C within the above range, and more preferably at least 20 ° C.
- the ultraviolet irradiation intensity is preferably about 1 to 20 mW / cm 2 .
- the ultraviolet irradiation time is about 10 to 120 seconds, and preferably 10 to 60 seconds. If the UV irradiation intensity is lower than 1 mW / .c in 2 , polymerization will not take place so that a monomer distribution is formed in the thickness direction. Does not fall into two selective reflection wavelength bands. In addition, even when the UV irradiation intensity is higher than 20 mWZ cm 2 , the polymerization reaction rate becomes higher than the diffusion rate, so that at least two independent selective reflection wavelength bands are not obtained.
- the exposure environment in the ultraviolet irradiation is performed in a state where the liquid crystal mixture applied to the alignment substrate is in contact with a gas containing oxygen.
- the gas containing oxygen contains 0.5% or more of oxygen.
- Such an environment may be any as long as oxygen polymerization inhibition can be utilized, and can be performed under a general atmospheric atmosphere.
- the oxygen concentration may be increased or decreased in consideration of the wavelength width for controlling the pitch in the thickness direction and the speed required for polymerization.
- the polymerization may be completed by irradiating strong ultraviolet rays.
- Such UV irradiation is preferably performed in the absence of oxygen.
- curing is performed without deteriorating the cholesteric reflection band.
- the ultraviolet irradiation may be performed from either the alignment substrate side or the applied liquid crystal mixture side.
- the absence of oxygen can be, for example, an inert gas atmosphere.
- the inert gas is not particularly limited as long as it does not affect the ultraviolet polymerization of the liquid crystal mixture.
- examples of such an inert gas include nitrogen, argon, helium, neon, xenon, and krypton. Of these, nitrogen is the most versatile and preferred. Further, by bonding a transparent base material to the cholesteric liquid crystal layer, it is possible to eliminate the presence of oxygen.
- the ultraviolet irradiation condition is not particularly limited as long as the liquid crystal mixture is cured. Usually, it is preferable to irradiate at an irradiation intensity of about 40 to 300 mW / cm 2 for about 1 to 60 seconds.
- the irradiation temperature is about 20 to 100 ° C.
- the cholesteric liquid crystal film thus obtained may be used without being separated from the substrate, or may be used after being separated from the substrate.
- the cholesteric liquid crystal film of the present invention has at least two arbitrarily selected independent selective reflection wavelength bands, and in each selective reflection wavelength band, a circularly polarized light reflection band is provided. It has a transmission function.
- the cholesteric liquid crystal film of the present invention is used as a circularly polarized light reflection film.
- a circularly polarized light reflective film As a circularly polarized light reflective film, two layers with selective reflection wavelength bands that are almost the same and cholesteric twist directions are opposite are laminated to two arbitrarily selected selective reflection wavelength band wavelengths. Only those that function as a reflective film are obtained. In addition, when two layers of circularly polarized light reflective films having substantially the same selective reflection wavelength band and the same cholesteric twist direction are laminated, two circularly polarized light reflective films may be disposed between the circularly polarized light reflective films. A similar reflective film can be obtained by laminating the plates in between.
- the 1/2 plate is stretched, but not particularly limited, by stretching such as polypropylene, polyethylene terephthalate, polystyrene, polysulfone, polybutyl alcohol, polymethyl methacrylate, and the like.
- a general-purpose transparent resin film that generates a phase difference or a norbornene-based resin film such as ARTON film manufactured by JSR is preferably used.
- a second plate obtained by fixing a ⁇ / 2 layer obtained by aligning a liquid crystal other than the expression of a retardation by stretching a resin may be used.
- the fact that the front phase difference is 1/2 means that light having a wavelength of 550 nm is preferably within a range of L ⁇ 2 ⁇ 40 nm, and more preferably ⁇ 15 nm.
- the thickness of the ⁇ / 2 plate can be significantly reduced.
- the thickness of the phase difference plate can be significantly reduced.
- a retardation plate produced by stretching has a thickness of several tens of meters
- a retardation plate formed by liquid crystal alignment has a thickness of several / im.
- the thickness of the two-wavelength plate is preferably 0.5 to 20 ⁇ , and particularly preferably:! To 10.
- the ⁇ / 2 plate works well only for a specific wavelength with a single layer made of a single material, but may degrade as a ⁇ / 2 plate for other wavelengths due to wavelength dispersion characteristics. . Therefore, if two or more different retardation plates are laminated with the axis angle and phase difference defined, a broadband ⁇ / that functions as practically acceptable in both two selective reflection wavelength bands It can be used as two plates.
- each retardation plate may be the same material, or may be a combination of those made of different materials obtained by the same method as the above-described ⁇ 2 plate.
- Such a broadband ⁇ / 2 plate is particularly effective when the distance between the center wavelengths of two selective reflection wavelength bands is large, for example, when the selective reflection wavelength bands are in the ultraviolet wavelength region and the infrared wavelength region.
- a cholesteric liquid crystal film (circularly polarized light reflective film) in which the selective reflection center wavelengths of the independent selective reflection wavelength bands exist in the ultraviolet light wavelength region and the infrared light wavelength region, respectively, are applied to the reflection film.
- the reflection film can be used as a visual protection plate bonded to a transparent support substrate.
- the transparent support substrate the substrate used in producing the cholesteric liquid crystal film can be used as it is, or can be obtained by separately bonding the same substrate.
- Damage to the eyeball due to ultraviolet light includes damage to the cornea (snow grain), clouding of the lens body (cataract), and retinal damage (photoretinopathy). These are not the damages due to the heat of light but the damages due to the photochemical reaction, and the degree of damage differs depending on the wavelength range of the irradiated light and the irradiation time. It is known that in the case of irradiation in the short wavelength side of the visible region from blue to purple, there is an additivity of the exposure amount to time at an irradiation amount of several hundredths to tenths of a thousandths of the thermal damage threshold. . G. ibbonsand R. G. Alien: Invest O phthalmol.
- the visual protection film and the visual protection plate can be applied to various visual translucent members.
- an optical filter for safety glasses it can be applied to eyeglasses such as sunglasses and safety glasses for laser work. It is also used for vehicle window glass of automobiles, housing window glass, etc. It is preferably used.
- the reflection spectrum of the cholesteric liquid crystal film was measured with a spectrophotometer (Otsuka Electronics Co., Ltd., Instant Multisystem MC PD 2000), and the selective reflection wavelength bandwidth was half of the maximum reflectance.
- the wavelength band has a reflectance.
- the selective reflection center wavelength is the value at the center of the selective reflection wavelength band.
- a spectrophotometer U410 manufactured by Hitachi, Ltd. was used for measuring the spectral characteristics of transmission and reflection.
- the front phase difference is defined as X axis, the direction perpendicular to the X axis is the Y axis, the film thickness direction is the Z axis, and the refractive index in each axis direction is n X,
- the refractive indices nx, ny and nz at 550 nm are the values measured by an automatic birefringence measurement device (Oji Scientific Instruments Co., Ltd., automatic birefringence meter KOBRA 21 ADH). From the thickness d (nm) of the retardation layer, the front retardation: (nX—ny) Xd and the retardation in the thickness direction: (nx—nz) Xd were calculated. The phase difference measured when tilted can be measured by the automatic birefringence measuring device.
- UV exposure machine used was UV C32 1 AM 1 manufactured by Shio Denki.
- Example 1 The UV exposure machine used was UV C32 1 AM 1 manufactured by Shio Denki.
- Photopolymerizable mesogen compound (1) (polymerizable nematic liquid crystal monomer) 94.9 Parts, polymerizable chiral agent (LC756 manufactured by BASF) 5.1 parts by weight of a solvent (cyclopentanone) dissolved in a solution, and the solid content is added to a photopolymerization initiator (Chipa Specialty Chemicals Co., Ltd.). Was prepared by adding 0.5% by weight of Irgacure 907).
- the coating solution is applied on a stretched polyethylene terephthalate film (oriented substrate) using a wire par so that the thickness after drying is 5 ⁇ , and the solvent is dried at 100 for 2 minutes.
- LC756 polymerizable chiral agent
- the obtained film was irradiated with ultraviolet rays at 50 mW / cm 2 for 30 seconds in an air atmosphere at 85 ° C. from the alignment substrate side.
- a cholesteric liquid crystal film having selective reflection central wavelengths of 370 nm and 800 nm was obtained.
- ultraviolet irradiation was performed at 80 mW / cm 2 for 30 seconds from the alignment substrate side to complete the polymerization.
- the selective reflection center wavelength did not change by this ultraviolet irradiation.
- Figure 1 shows the reflection spectrum of the obtained cholesteric liquid crystal film.
- the alignment substrate was peeled off to obtain a two-wavelength reflection type reflective film.
- the reflective film had two selective reflection wavelength bands having a selective reflection central wavelength of 370 nm ⁇ bandwidth of 75 nm and a selective reflection central wavelength of 85 O nm * bandwidth of 170 nm.
- a photopolymerizable mesogen compound (1) 94.9 parts by weight of a photopolymerizable mesogen compound (1), 5.1 parts by weight of a polymerizable chiral agent (LC756, manufactured by BASF) and a solution of a solvent (cyclopentanone) dissolved in a solution containing the solid content
- a coating solution solid content: 30% by weight
- a photopolymerization initiator IRGACURE 907, manufactured by Chipa Specialty Chemicals.
- the coating liquid is applied on a stretched polyethylene terephthalate film (alignment base) using a wire par so that the thickness after drying is 5 ⁇ m, and the solvent is applied at 100 ° C. for 2 minutes. Let dry.
- the obtained film was irradiated with a first ultraviolet ray at 10 mWZ cm 2 for 1 second in an air atmosphere at 40 ° C. from the alignment substrate side. Then, at 90 ° C for 1 minute without UV irradiation For a while. Next, second ultraviolet irradiation was performed at 90 ° C. in an air atmosphere at 5 mW / cm 60 seconds from the alignment substrate side. As a result, a cholesteric liquid crystal film having selective reflection center wavelengths at 370 nm and 800 nm was obtained. Then, under a nitrogen atmosphere, ultraviolet irradiation was performed at 80 mW / cm 2 for 30 seconds from the alignment substrate side to complete the polymerization. In addition, the selective reflection center wavelength did not change by this ultraviolet irradiation.
- Figure 2 shows the reflection spectrum of the obtained cholesteric liquid crystal film.
- the liquid crystal surface of the cholesteric liquid crystal film obtained above was bonded, and then the alignment substrate was peeled off to obtain a two-wavelength reflection film.
- the reflective film had two selective reflection wavelength bands having a central wavelength of selective reflection of 405 nm and a bandwidth of 75 nm and a central wavelength of selective reflection of 880 nm and a bandwidth of 150 nm.
- a photopolymerizable mesogen compound (1) 96.5 parts by weight of a photopolymerizable mesogen compound (1), 3.5 parts by weight of a polymerizable chiral agent (LC756, manufactured by BASF) and 3.5 parts by weight of a solvent (cyclopentanone) are selectively reflected.
- a photopolymerization initiator Irgacure 907, manufactured by Ciba Specialty Chemicals Co., Ltd.
- the two types of coating liquids are separately applied to a stretched polyethylene terephthalate film (oriented substrate) using a wire bar so as to have a thickness of 3 m after drying, and the solvent is added to a solvent of 10%. It was dried at 0 ° C for 2 minutes.
- the obtained film was irradiated with ultraviolet rays at 47.5 mWZ cm 2 for 10 seconds in an air atmosphere at 40 ° C. from the cholesteric liquid crystal side.
- a cholesteric liquid crystal film with a selective reflection center wavelength of 370 nm (A) and a cholesteric liquid crystal film (B) having a selective reflection center wavelength of 80 nm were obtained.
- ultraviolet irradiation was performed from the cholesteric liquid crystal side with SO mWZ cm 2 for 30 seconds to complete the polymerization. The center wavelength of selective reflection was not changed by this ultraviolet irradiation.
- the cholesteric liquid crystal film (A) and the cholesteric liquid crystal film (B) are transferred and laminated with a translucent adhesive (Special Color Materials Co., Ltd., Ad 249, 5 m thick).
- a translucent adhesive Special Color Materials Co., Ltd., Ad 249, 5 m thick.
- a broadband circularly polarized reflective polarizer was obtained.
- the resulting reflective polarizers had selective reflection center wavelengths at 370 and 800 nm.
- Example 2 This was laminated on both sides of the same retardation plate as in Example 1 to obtain a two-wavelength reflection film.
- the thickness of the obtained reflective film was the same as that of Example 1, but the number of laminations was doubled, the productivity was poor, and the yield was reduced due to foreign matters.
- the cholesteric liquid crystal film of the present invention is useful as a circularly polarized light reflecting plate (a circularly polarized light reflecting polarizer) and has two specific wavelength regions.
- a circularly polarized light reflecting plate a circularly polarized light reflecting polarizer
- two specific wavelength regions exist in the ultraviolet wavelength region and the infrared wavelength region, respectively, it is useful as a visual protective film. They are preferably used for eyeglasses such as sunglasses, safety glasses for laser work, vehicle window glass for automobiles, and residential window glass. Further, when two specific wavelength regions exist in the visible light wavelength region, they are suitably used as a color-capturing color filter of a liquid crystal display device.
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- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polarising Elements (AREA)
- Optical Filters (AREA)
- Liquid Crystal (AREA)
- Eyeglasses (AREA)
Abstract
Description
Claims
Priority Applications (1)
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US10/555,377 US20060209238A1 (en) | 2003-05-02 | 2004-04-15 | Cholesteric liquid crystalline film, method for production thereof and circularly polarized light reflecting film, two wavelength region reflection type reflecting film |
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JP2003126998A JP4233379B2 (ja) | 2003-05-02 | 2003-05-02 | コレステリック液晶フィルム、その製造方法および円偏光反射フィルム、二波長域反射型反射フィルム |
JP2003-126998 | 2003-05-02 |
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US (1) | US20060209238A1 (ja) |
JP (1) | JP4233379B2 (ja) |
WO (1) | WO2004097469A1 (ja) |
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JP5493629B2 (ja) * | 2008-11-07 | 2014-05-14 | Jnc株式会社 | 重合性液晶組成物 |
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US20120219707A1 (en) * | 2009-12-24 | 2012-08-30 | Nitto Denko Corporation | Process for production of broad-band cholesteric liquid crystal film |
JP2012063528A (ja) * | 2010-09-15 | 2012-03-29 | Fujitsu Ltd | 反射型カラー表示素子およびカラー表示装置 |
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WO2014181846A1 (ja) * | 2013-05-10 | 2014-11-13 | 国立大学法人東京工業大学 | 広帯域コレステリック液晶フィルム、広帯域コレステリック液晶フィルムの製造方法、液晶組成物 |
US9500882B2 (en) | 2013-09-17 | 2016-11-22 | Johnson & Johnson Vision Care, Inc. | Variable optic ophthalmic device including shaped liquid crystal elements with nano-scaled droplets of liquid crystal |
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US9541772B2 (en) | 2013-09-17 | 2017-01-10 | Johnson & Johnson Vision Care, Inc. | Methods and apparatus for ophthalmic devices including cycloidally oriented liquid crystal layers |
US9592116B2 (en) | 2013-09-17 | 2017-03-14 | Johnson & Johnson Vision Care, Inc. | Methods and apparatus for ophthalmic devices including cycloidally oriented liquid crystal layers |
US9880398B2 (en) | 2013-09-17 | 2018-01-30 | Johnson & Johnson Vision Care, Inc. | Method and apparatus for ophthalmic devices including gradient-indexed and shaped liquid crystal layers |
JP6238128B2 (ja) * | 2013-12-12 | 2017-11-29 | 国立大学法人東京工業大学 | 二帯域コレステリック液晶フィルム及びその製造方法 |
JP2015197604A (ja) * | 2014-04-01 | 2015-11-09 | Jx日鉱日石エネルギー株式会社 | 光学フィルムの製造方法 |
CN104297836B (zh) * | 2014-10-17 | 2016-05-11 | 京东方科技集团股份有限公司 | 一种液晶薄膜的制备方法及所制得的液晶薄膜、圆偏振片 |
JP6938384B2 (ja) * | 2015-11-19 | 2021-09-22 | 日本化薬株式会社 | アイウェア用光学フィルム、並びにこれを有するアイウェア用機能性フィルム、アイウェア用光学積層体およびアイウェア |
JP7113961B2 (ja) * | 2019-03-28 | 2022-08-05 | 富士フイルム株式会社 | コレステリック液晶膜の製造方法 |
JP7265621B2 (ja) * | 2019-05-10 | 2023-04-26 | 富士フイルム株式会社 | センサー |
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US20060209238A1 (en) | 2006-09-21 |
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