WO2003040201A1 - Isotactic propylene copolymers, their preparation and use - Google Patents

Isotactic propylene copolymers, their preparation and use Download PDF

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Publication number
WO2003040201A1
WO2003040201A1 PCT/US2002/014158 US0214158W WO03040201A1 WO 2003040201 A1 WO2003040201 A1 WO 2003040201A1 US 0214158 W US0214158 W US 0214158W WO 03040201 A1 WO03040201 A1 WO 03040201A1
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WIPO (PCT)
Prior art keywords
copolymer
ethylene
propylene
reactor
weight percent
Prior art date
Application number
PCT/US2002/014158
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English (en)
French (fr)
Inventor
James C. Stevens
Daniel D. Vanderlende
Original Assignee
Dow Global Technologies Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Dow Global Technologies Inc. filed Critical Dow Global Technologies Inc.
Priority to JP2003542246A priority Critical patent/JP2005508415A/ja
Priority to EP02725927A priority patent/EP1444276A1/en
Publication of WO2003040201A1 publication Critical patent/WO2003040201A1/en

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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
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    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
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    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
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    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
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    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
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    • D01F6/28Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/30Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising olefins as the major constituent
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    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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PCT/US2002/014158 2001-11-06 2002-05-06 Isotactic propylene copolymers, their preparation and use WO2003040201A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2003542246A JP2005508415A (ja) 2001-11-06 2002-05-06 アイソタクチックプロピレンコポリマー類、その製法および用途
EP02725927A EP1444276A1 (en) 2001-11-06 2002-05-06 Isotactic propylene copolymers, their preparation and use

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US33888101P 2001-11-06 2001-11-06
US60/338,881 2001-11-06

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WO2003040201A1 true WO2003040201A1 (en) 2003-05-15

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EP (1) EP1444276A1 (US20030194575A1-20031016-C00022.png)
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CN (2) CN101319050A (US20030194575A1-20031016-C00022.png)
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Cited By (191)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004014998A2 (en) 2002-08-12 2004-02-19 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
WO2004026925A1 (en) * 2002-09-17 2004-04-01 Dow Global Technologies Inc. Improved process for manufacture of polymers
WO2004041928A1 (en) * 2002-11-05 2004-05-21 Dow Global Technologies Inc. Thermoplastic elastomer compositions
WO2004099309A1 (en) * 2003-05-05 2004-11-18 Dow Global Technologies Inc. Filled thermoplastic olefin composition
WO2005080495A1 (en) 2004-02-12 2005-09-01 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
JP2005263771A (ja) * 2004-02-18 2005-09-29 Shinko Kagaku Kogyo Kk 高純度テトラキス(ジアルキルアミノ)ハフニウムの製造法
JP2005298467A (ja) * 2004-04-12 2005-10-27 Kojundo Chem Lab Co Ltd 高純度テトラキスジメチルアミノハフニウムとその製造方法およびそれを用いたゲート絶縁膜の製造方法。
WO2005103123A1 (en) * 2004-04-19 2005-11-03 Dow Golbal Technologies Inc. Composition suitable for single-sided, low-noise, stretch cling film and films made therefrom
WO2006009976A1 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Polymerization process
US6994763B2 (en) 2002-10-24 2006-02-07 Advanced Design Concept Gmbh Elastomeric multicomponent fibers, nonwoven webs and nonwoven fabrics
EP1655341A1 (en) 2004-11-05 2006-05-10 Advanced Elastomer Systems, L.P. Transparent polyolefin compositions
WO2006057369A1 (ja) 2004-11-26 2006-06-01 Mitsui Chemicals, Inc. ポリプロピレンの不織布およびその用途
WO2006065649A1 (en) 2004-12-17 2006-06-22 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blends and molded articles therefrom
US7087690B2 (en) 2000-11-07 2006-08-08 Symyx Technologies, Inc. Substituted pyridyl amine catalysts and processes for polymerizing crystalline polymers
WO2007001694A1 (en) 2005-06-24 2007-01-04 Exxonmobil Chemical Patents Inc. Functionalized propylene copolymer adheside composition
WO2007044544A2 (en) 2005-10-07 2007-04-19 Dow Global Technologies Inc. Multilayer elastic film structures
WO2006101926A3 (en) * 2005-03-17 2007-07-19 Dow Global Technologies Inc Interpolymers of ethylene/alpha-olefins blends and profiles and gaskets made therefrom
US7256296B2 (en) 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
JP2007525323A (ja) * 2004-02-27 2007-09-06 ダウ グローバル テクノロジーズ インコーポレイティド 水性ポリマー分散物およびそれらの分散物による製品
US7309522B2 (en) 2003-07-09 2007-12-18 Advanced Design Concepts Gmbh Fibers made from block copolymer
WO2008002841A2 (en) 2006-06-29 2008-01-03 Dow Global Technologies, Inc. Thermoplastic articles and processes for making the same using an improved masterbatch
US7319077B2 (en) 2004-12-17 2008-01-15 Exxonmobil Chemical Patents Inc. Polymer blends and nonwoven articles therefrom
JP2008511742A (ja) * 2004-08-31 2008-04-17 ダウ グローバル テクノロジーズ インコーポレイティド 熱成形性シートに好適な組成物および熱成形性シートから製造される物品
US7387980B2 (en) 2004-09-22 2008-06-17 Symyx Technologies, Inc. Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts
WO2008076589A1 (en) 2006-12-20 2008-06-26 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
DE112005000058T5 (de) 2004-04-15 2008-07-03 Exxon Mobil Chemical Patents Inc., Baytown Polyolefinklebstoffzusammensetzung und daraus hergestellte Gegenstände
WO2008109212A1 (en) * 2007-03-06 2008-09-12 Exxonmobil Chemical Patents Inc. Polymer production under supersolution conditions
WO2009035580A1 (en) 2007-09-13 2009-03-19 Exxonmobil Research And Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
US7514517B2 (en) 2004-03-17 2009-04-07 Dow Global Technologies Inc. Anti-blocking compositions comprising interpolymers of ethylene/α-olefins
US7585917B2 (en) 2005-06-13 2009-09-08 Exxonmobil Chemical Patents Inc. Thermoplastic blend compositions
WO2009126277A2 (en) 2008-04-10 2009-10-15 Exxonmobil Research And Engineering Company Monomer/solvent separation and recycle process for propylene containing polymers
US7619038B2 (en) 2004-12-17 2009-11-17 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and articles therefrom
US7622529B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
WO2009142730A1 (en) 2008-05-22 2009-11-26 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US7645829B2 (en) 2004-04-15 2010-01-12 Exxonmobil Chemical Patents Inc. Plasticized functionalized propylene copolymer adhesive composition
US7671106B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Cap liners, closures and gaskets from multi-block polymers
US7671131B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom
US7671148B2 (en) 2004-04-26 2010-03-02 Basell Polyolefine Gmbh Catalyst system for olefin polymerization, its production and use
WO2010027491A1 (en) 2008-09-05 2010-03-11 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
US7683129B2 (en) 2004-12-17 2010-03-23 Exxonmobil Chemical Patents Inc. Films from polymer blends
US7705157B2 (en) 2004-12-16 2010-04-27 Symyx Solutions, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US7714071B2 (en) 2004-03-17 2010-05-11 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
WO2010088488A1 (en) 2009-01-30 2010-08-05 Dow Global Technologies Inc. Polymeric compositions and filled tpo articles having improved aesthetics
US20100227986A1 (en) * 2008-11-17 2010-09-09 Fina Technology, Inc Methods of Catalyst Activation
WO2010117612A2 (en) 2009-03-31 2010-10-14 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US7829623B2 (en) 2004-11-05 2010-11-09 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates having improved fabricability
US7858817B2 (en) 2008-03-10 2010-12-28 Exxonmobil Chemical Patents Inc. Metallocene-substituted pyridyl amines, their metal complexes, and processes for production and use thereof
US7863364B2 (en) 2006-01-17 2011-01-04 Exxonmobil Chemical Patents Inc. Process for making dynamically-loaded articles comprising propylene-based elastomers, composition for use in such processes, and article made using such processes
US7867433B2 (en) 2008-05-30 2011-01-11 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
WO2011011124A1 (en) 2009-07-23 2011-01-27 Exxonmobil Chemical Patents Inc. Polypropylene-based elastomer coating compositions
EP2281859A1 (en) * 2004-12-21 2011-02-09 Dow Global Technologies Inc. Polypropylene-based adhesive compounds
WO2011019474A2 (en) 2009-08-14 2011-02-17 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US7893161B2 (en) 2005-10-31 2011-02-22 Dow Global Technologies Inc. Propylene-based elastomeric composition
US7897093B2 (en) 2006-04-19 2011-03-01 Dow Global Technologies Inc. Thermoplastic articles and improved processes for making the same
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US7910637B2 (en) 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
WO2011053406A1 (en) 2009-10-29 2011-05-05 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
US7947786B2 (en) 2004-10-13 2011-05-24 Exxonmobil Chemical Patents Inc. Elastomeric reactor blend compositions
US7951732B2 (en) 2007-01-26 2011-05-31 Exxonmobil Chemical Patents Inc. Elastomeric laminates for consumer products
WO2011068728A1 (en) 2009-12-03 2011-06-09 Exxonmobil Oil Corporation Multi-layer opaque films, articles including such films, and uses thereof
WO2011087693A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.1. Elastic fiber containing an anti-tack additive
WO2011087695A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.L. Polyolefin elastic fiber
WO2011087692A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.L. Stretch articles including polyolefin elastic fiber
WO2011090859A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
US7994237B2 (en) 2007-12-20 2011-08-09 Exxonmobil Research And Engineering Company In-line process to produce pellet-stable polyolefins
US8003740B2 (en) 2005-07-26 2011-08-23 Basell Polyolefine Gmbh Method of controlling the relative activity of the different active centers of hybrid catalysts
EP2363445A1 (en) 2006-06-15 2011-09-07 Dow Global Technologies LLC Functionalized propylene interpolymers, compositions and articles prepared therefrom, and methods for making the same
WO2011112308A1 (en) 2010-03-12 2011-09-15 Exxonmobil Chemical Patents Inc. Composite materials comprising propylene-based polymer blend coatings
WO2011112309A1 (en) 2010-03-12 2011-09-15 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
US8093335B2 (en) 2008-12-15 2012-01-10 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin in-reactor blends and molded articles therefrom
EP2407495A1 (en) 2005-07-11 2012-01-18 Dow Global Technologies LLC (formerly Known As Dow Global Technologies Inc.) Silane-Grafted Olefin Polymers, Compositions and Articles Prepared Therefrom, and Methods For Making The same
US8101685B2 (en) 2008-12-15 2012-01-24 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom
US8106127B2 (en) 2008-12-15 2012-01-31 Exxonmobil Chemical Patents Inc. Heterogeneous in-reactor polymer blends
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
WO2012051239A1 (en) 2010-10-15 2012-04-19 Exxonmobil Chemical Patents Inc. Polypropylene-based adhesive compositions
WO2012051479A1 (en) 2010-10-14 2012-04-19 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs, and methods of making and using the same
WO2012074599A1 (en) 2010-12-03 2012-06-07 Exxonmobil Oil Corporation Antistatic films and methods to manufacture the same
US8202467B2 (en) 2006-08-02 2012-06-19 Exxonmobil Chemical Patents Inc. Propylene-based polymer article
US8202941B2 (en) 2008-06-27 2012-06-19 Exxonmobil Chemical Patents Inc. High shrinkage propylene-based films
US8227547B2 (en) 2008-12-15 2012-07-24 Exxonmobil Chemical Patents Inc. Foamable thermoplastic reactor blends and foam article therefrom
US8236878B2 (en) 2007-09-07 2012-08-07 Exxonmobil Chemical Patents Inc. Composition and manufacture thereof
WO2012106025A1 (en) 2011-01-31 2012-08-09 Exxonmobil Chemical Patents Inc. Coextruded films and processes for making such films
US8241753B2 (en) 2007-06-04 2012-08-14 Exxonmobil Chemical Patents Inc. Composite thermoplastic elastomer structures with high adhesion performance and uses for the same
WO2012112259A2 (en) 2011-02-15 2012-08-23 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
WO2012118546A1 (en) 2011-03-03 2012-09-07 Exxonmobil Chemical Patents Inc. Ethylene-vinyl alcohol based thermoplastic elastomers and vulcanizates
US8338540B2 (en) 2007-10-22 2012-12-25 Dow Global Technologies Llc Polymeric compositions and processes for molding articles
WO2013013116A1 (en) 2011-07-20 2013-01-24 The Procter & Gamble Company Polymer composition
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US8410217B2 (en) 2008-12-15 2013-04-02 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
WO2013055496A1 (en) 2011-10-14 2013-04-18 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
US8445620B2 (en) 2011-08-04 2013-05-21 Exxonmobil Research And Engineering Company Elastic propylene-alpha-olefin copolymer compositions and processes to produce them
WO2013096532A1 (en) 2011-12-22 2013-06-27 Exxonmobil Research And Engineering Company Method for improving engine fuel efficiency
US8497325B2 (en) 2008-12-15 2013-07-30 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends and films therefrom
US8530581B2 (en) 2011-12-12 2013-09-10 Exxonmobil Chemical Patents Inc. Powder, compositions thereof, processes for making the same, and articles made therefrom
US8609772B2 (en) 2007-10-23 2013-12-17 Exxonmobil Chemical Patents Inc. Elastic films having improved mechanical and elastic properties and methods for making the same
US8709316B2 (en) 2008-03-14 2014-04-29 Dow Global Technologies Llc Process for shaping polymeric articles
WO2014088827A1 (en) 2012-12-05 2014-06-12 Exxonmobil Chemical Patents Inc. Hdpe modified polyethylene blown film compositions having excellent bubble stability
WO2014099356A2 (en) 2012-12-18 2014-06-26 Exxonmobil Chemical Patents Inc. Polyethylene films and method of making same
US8858986B2 (en) 2008-06-12 2014-10-14 3M Innovative Properties Company Biocompatible hydrophilic compositions
WO2014185996A1 (en) 2013-05-14 2014-11-20 Exxonmobil Chemical Patents Inc. Ethylene-based polymers and articles made therefrom
US8932704B2 (en) 2010-02-23 2015-01-13 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US8975334B2 (en) 2009-07-23 2015-03-10 Exxonmobil Chemical Patents Inc. Crosslinkable propylene-based copolymers, methods for preparing the same, and articles made therefrom
EP2853549A2 (en) 2008-08-01 2015-04-01 ExxonMobil Chemical Patents Inc. Process for olefin polymerization
WO2015047988A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Compositions, wipes, and methods
WO2015047806A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Fibers, wipes, and methods
WO2015047890A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Fibers and wipes with epoxidized fatty ester disposed thereon, and methods
US8999907B2 (en) 2009-04-28 2015-04-07 Exxonmobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
US9005739B2 (en) 2009-07-23 2015-04-14 Exxonmobil Chemical Patents Inc. Laminated articles and their production
US9012578B2 (en) 2012-04-19 2015-04-21 Exxonmobil Chemical Patents Inc. Blocky ethylene propylene copolymers and methods for making them
US9168720B2 (en) 2009-02-27 2015-10-27 Exxonmobil Chemical Patents Inc. Biaxially elastic nonwoven laminates having inelastic zones
US9168718B2 (en) 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
WO2015169831A1 (en) 2014-05-06 2015-11-12 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers and process for their preparation
US9194065B2 (en) 2009-12-17 2015-11-24 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US9227346B2 (en) 2004-10-22 2016-01-05 Dow Global Technologies Llc Plastic composite articles and methods of making same
US9296182B2 (en) 2006-06-09 2016-03-29 Exxonmobil Chemical Patents Inc. Coextrusion processes for making multilayer films and films made thereby
WO2016053483A1 (en) 2014-10-03 2016-04-07 Exxonmobil Chemical Patents Inc. Polyethylene polymers, films made therefrom, and methods of making the same
WO2016069089A1 (en) 2014-10-29 2016-05-06 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions for elastic applications
WO2016076969A1 (en) 2014-11-12 2016-05-19 Exxonmobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
US9416485B2 (en) 2009-12-17 2016-08-16 3M Innovative Properties Company Process of making dimensionally stable nonwoven fibrous webs
US9422444B2 (en) 2012-12-28 2016-08-23 Dow Global Technologies Llc Coating compositions
WO2016172099A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Polyethylene composition
US9487653B2 (en) 2015-12-08 2016-11-08 Exxonmobil Chemical Patents Inc. Process of making crosslinked polyolefin polymer blends and compositions prepared thereof
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
WO2017105614A1 (en) 2015-12-16 2017-06-22 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions
US9708488B2 (en) 2013-11-22 2017-07-18 Trinseo Europe Gmbh Polycarbonate containing compositions
EP3214158A1 (en) 2008-08-08 2017-09-06 ExxonMobil Chemical Patents Inc. Improved olefinic copolymer compositions for viscosity modification of motor oil
WO2017155609A1 (en) 2016-03-11 2017-09-14 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2017172102A1 (en) 2016-03-31 2017-10-05 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
WO2017184234A1 (en) 2016-04-22 2017-10-26 Exxonmobil Chemical Patents Inc. Polyethylene sheets
WO2018013284A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013283A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013285A1 (en) 2016-07-14 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene-catalyzed bimodal copolymer compositions
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
US9938413B2 (en) 2012-12-28 2018-04-10 Dow Global Technologies Llc Coating composition and articles made therefrom
WO2018102091A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patents Inc. Polyethylene films
WO2018106480A1 (en) 2016-12-06 2018-06-14 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
EP3336113A1 (en) 2016-12-13 2018-06-20 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and c3-c10 alpha-olefins
US10041190B2 (en) 2009-12-23 2018-08-07 Invista North America S.A.R.L. Fabric including polyolefin elastic fiber
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US10066102B2 (en) 2013-11-22 2018-09-04 Trinseo Europe Gmbh Polycarbonate containing compositions
WO2018187047A1 (en) 2017-04-06 2018-10-11 Exxonmobil Chemical Patents Inc. Cast films and processes for making the same
WO2018194740A1 (en) 2017-04-19 2018-10-25 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2018226311A1 (en) 2017-06-08 2018-12-13 Exxonmobil Chemical Patents Inc. Polyethylene blends and extrudates and methods of making the same
WO2018231224A1 (en) 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US10174442B2 (en) 2012-12-03 2019-01-08 Exxonmobil Chemical Patents Inc. Polypropylene fibers and fabrics
WO2019027605A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. FILMS MANUFACTURED FROM POLYETHYLENE COMPOSITIONS AND METHODS OF MAKING THE SAME
WO2019027587A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. POLYETHYLENE COMPOSITIONS AND FILMS PREPARED THEREFROM
WO2019027585A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING UNDRAWNED HAFNOCENES WITH -CH2-SIME3 FRACTIONS
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
WO2019027586A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING 2,6-BIS (IMINO) PYRIDYL-IRON COMPLEXES AND BRONZED HAFNOCENES
WO2019108326A1 (en) 2017-11-28 2019-06-06 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2019108977A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
WO2019156802A1 (en) 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Metallocene catalyst feed system for solution polymerization process
WO2019162760A1 (en) 2018-02-05 2019-08-29 Exxonmobil Chemical Patents Inc. A Corporation Of State Of Delaware Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
WO2019240899A1 (en) 2018-06-13 2019-12-19 Exxonmobil Chemical Patents Inc. Polyolefin blend compositions
WO2019246069A1 (en) 2018-06-19 2019-12-26 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
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WO2020046597A1 (en) 2018-08-29 2020-03-05 Exxonmobil Chemical Patents Inc. Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
US10584297B2 (en) 2016-12-13 2020-03-10 Afton Chemical Corporation Polyolefin-derived dispersants
WO2020068497A1 (en) 2018-09-25 2020-04-02 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2020092587A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio by trim and olefin polymerization with the same
WO2020092599A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. Slurry trim catalyst feeder modifications
WO2020092597A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of catalysts by trim and olefin polymerization
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WO2020092584A2 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. In-line trimming of dry catalyst feed
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WO2020167441A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Oriented multilayer polyethylene films and laminates thereof
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WO2020190507A1 (en) 2019-03-19 2020-09-24 Exxonmobil Chemical Patents Inc. Multilayer oriented films
WO2020205311A1 (en) 2019-04-05 2020-10-08 Exxonmobil Chemical Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
WO2020205337A1 (en) 2019-04-05 2020-10-08 Exxonmobil Chemical Patents Inc. Controlling molecular weight distribution and chemical composition distribution of a polyolefin product
WO2020219378A1 (en) 2019-04-24 2020-10-29 Dow Global Technologies Llc Multi-layer stretch hood film with enhanced tear strength
WO2020218874A1 (ko) * 2019-04-26 2020-10-29 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
US10850484B2 (en) 2015-03-17 2020-12-01 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2021011638A1 (en) * 2019-07-18 2021-01-21 Exxonmobil Chemical Patents Inc. Silyl-bridged pyridylamide catalysts and methods thereof
WO2021034400A1 (en) 2019-08-20 2021-02-25 Exxonmobil Chemical Patents Inc. Films and methods of making the same
WO2021034471A1 (en) 2019-08-16 2021-02-25 Exxonmobil Chemical Patents Inc. Producing blocks of block copolymer in a separator downstream of a reactor
WO2021080813A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions and processes for the production thereof
WO2021080803A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Impact copolymer compositions
WO2021086552A1 (en) 2019-10-29 2021-05-06 Exxonmobil Chemical Patents Inc. Production of gradient copolymers using monomer and comonomer concentration gradients in a loop reactor
WO2021167739A1 (en) 2020-02-18 2021-08-26 Exxonmobil Chemical Patents Inc. High tenacity handwrap stretch film for improved pallet stability
WO2021195070A1 (en) 2020-03-26 2021-09-30 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polypropylene and semi-amorphous polymers
WO2022187814A2 (en) 2021-03-05 2022-09-09 Exxonmobil Chemical Patents Inc. Processes for making and using slurry catalyst mixtures
US11530279B2 (en) 2019-04-05 2022-12-20 Exxonmobil Chemicals Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
EP4050013A4 (en) * 2020-04-16 2023-01-11 LG Chem, Ltd. LIGAND COMPOUND, TRANSITION METAL COMPOUND AND CATALYST COMPOSITION COMPRISING THEM

Families Citing this family (159)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4962399A (en) 1998-07-01 2000-01-24 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US7217463B2 (en) 2002-06-26 2007-05-15 Avery Dennison Corporation Machine direction oriented polymeric films and methods of making the same
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
WO2005010896A1 (en) * 2003-07-24 2005-02-03 Union Carbide Chemicals & Plastic Technology Corporation Cable insulation system with flexibility, high temperature deformation resistance, and reduced degree of stickiness
ES2330946T3 (es) * 2004-01-06 2009-12-17 Dow Global Technologies Inc. Hojas polimericas de varias capas.
US7666918B2 (en) * 2004-03-17 2010-02-23 Dow Global Technologies, Inc. Foams made from interpolymers of ethylene/α-olefins
US7622179B2 (en) * 2004-03-17 2009-11-24 Dow Global Technologies Inc. Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof
US7803728B2 (en) * 2004-03-17 2010-09-28 Dow Global Technologies Inc. Fibers made from copolymers of ethylene/α-olefins
US7863379B2 (en) * 2004-03-17 2011-01-04 Dow Global Technologies Inc. Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers
US7579408B2 (en) * 2004-03-17 2009-08-25 Dow Global Technologies Inc. Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins
US7662881B2 (en) * 2004-03-17 2010-02-16 Dow Global Technologies Inc. Viscosity index improver for lubricant compositions
US7897689B2 (en) * 2004-03-17 2011-03-01 Dow Global Technologies Inc. Functionalized ethylene/α-olefin interpolymer compositions
US8273838B2 (en) * 2004-03-17 2012-09-25 Dow Global Technologies Llc Propylene/α-olefins block interpolymers
US7795321B2 (en) * 2004-03-17 2010-09-14 Dow Global Technologies Inc. Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom
US7687442B2 (en) * 2004-03-17 2010-03-30 Dow Global Technologies Inc. Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils
CN1976965B (zh) * 2004-03-17 2012-10-10 陶氏环球技术有限责任公司 用于形成乙烯多嵌段共聚物的包含梭移剂的催化剂组合物
NZ549262A (en) * 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7608668B2 (en) * 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
TW200536870A (en) * 2004-03-17 2005-11-16 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7741397B2 (en) * 2004-03-17 2010-06-22 Dow Global Technologies, Inc. Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof
US7582716B2 (en) * 2004-03-17 2009-09-01 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack
AR053693A1 (es) 2004-03-17 2007-05-16 Dow Global Technologies Inc Composiciones de interpolimero de etileno/alfa-olefina multibloque adecuado para peliculas
US7355089B2 (en) * 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
ITMI20040866A1 (it) * 2004-04-30 2004-07-30 Colines Srl Procedimento ed apparto per la realizzazione di una lastra a bolle d'aria
GB2423994B (en) * 2005-03-04 2008-07-30 Bespak Plc Seal for a dispensing apparatus
AR056640A1 (es) * 2005-03-17 2007-10-17 Dow Global Technologies Inc Composiciones de interpolimeros de multiples bloques de etileno/(alpha)-olefina para peliculas sopladas con elevada pegajosidad en caliente
AR055879A1 (es) * 2005-03-17 2007-09-12 Dow Global Technologies Inc Fibras realizadas de copolimeros de etileno/(alpha)-olefinas
US7786216B2 (en) * 2005-03-17 2010-08-31 Dow Global Technologies Inc. Oil based blends of interpolymers of ethylene/α-olefins
TWI375683B (en) * 2005-03-17 2012-11-01 Dow Global Technologies Llc Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
US7737215B2 (en) * 2005-03-17 2010-06-15 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US8084537B2 (en) * 2005-03-17 2011-12-27 Dow Global Technologies Llc Polymer blends from interpolymers of ethylene/α-olefin with improved compatibility
KR20070117675A (ko) * 2005-03-17 2007-12-12 다우 글로벌 테크놀로지스 인크. 택틱/아택틱 멀티-블록 공중합체의 형성을 위한 이동제를포함하는 촉매 조성물
US7910658B2 (en) * 2005-03-17 2011-03-22 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
EP1858962B1 (en) * 2005-03-17 2018-11-14 Dow Global Technologies LLC Filled polymer compositions made from interpolymers of ethylene/(a) -olefins and uses thereof
JP5231987B2 (ja) * 2005-03-17 2013-07-10 ダウ グローバル テクノロジーズ エルエルシー エチレン/α−オレフィン共重合体から製造される接着剤およびマーキング用組成物
MY142099A (en) * 2005-03-17 2010-09-15 Dow Global Technologies Inc Cap liners, closures and gaskets from multi-block polymers
CN103172961B (zh) * 2005-03-17 2016-08-17 陶氏环球技术有限责任公司 利用乙烯/α-烯烃共聚体对热塑性塑料的抗冲改性
JP5221334B2 (ja) * 2005-03-17 2013-06-26 ダウ グローバル テクノロジーズ エルエルシー フィルムに適するエチレン/α−オレフィンマルチブロック共重合体の組成物
TWI374151B (en) * 2005-03-17 2012-10-11 Dow Global Technologies Llc Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates
JP5231985B2 (ja) * 2005-03-17 2013-07-10 ダウ グローバル テクノロジーズ エルエルシー エチレン/α−オレフィンの共重合体およびそれらから製造される製品のレオロジー改良
WO2006134046A1 (en) * 2005-06-13 2006-12-21 Basell Polyolefine Gmbh Process for the copolymerization of propylene
JP2009504933A (ja) * 2005-08-19 2009-02-05 ダウ グローバル テクノロジーズ インコーポレイティド プロピレンをベースとしたメルトブローン不織層および複合構造
SG156614A1 (en) 2005-09-15 2009-11-26 Dow Global Technologies Inc Catalytic olefin block copolymers via polymerizable shuttling agent
KR20080055838A (ko) * 2005-09-15 2008-06-19 다우 글로벌 테크놀로지스 인크. 다중심 셔틀링제를 통한 중합체 구성 및 분자량 분포의제어
ES2391196T3 (es) * 2005-09-28 2012-11-22 Dow Global Technologies Llc Procedimiento de polimerización de olefinas de bajo peso molecular de alta actividad
CN101341021B (zh) * 2005-10-26 2012-07-25 陶氏环球技术有限责任公司 多层、弹性制品
RU2426650C2 (ru) * 2005-10-26 2011-08-20 Дау Глобал Текнолоджиз Инк. Многослойные предварительно вытянутые эластичные изделия
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
BRPI0620567B1 (pt) * 2005-12-09 2018-05-29 Dow Global Technologies Inc. Processo para produzir uma composição de interpolímero de etileno/(alfa)-olefina
EP1979409A1 (en) * 2006-01-10 2008-10-15 ExxonMobil Chemical Patents Inc. Films incorporating polymeric material combinations, articles made therefrom, and methods of making such films and articles
US20090306318A1 (en) * 2006-05-05 2009-12-10 Boone Harold W Ortho-metallated hafnium complexes of imidazole ligands
US8617717B2 (en) * 2006-06-09 2013-12-31 Exxonmobil Chemical Patents Inc. Heat sealable films from propylene and α-olefin units
CN101466543B (zh) 2006-06-14 2014-03-19 艾利丹尼森公司 可顺应和可冲切的轴向定向的标签原料和标签及制备方法
AU2007261011B2 (en) 2006-06-20 2012-04-05 Avery Dennison Corporation Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof
RU2446180C2 (ru) 2006-06-27 2012-03-27 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Полимеры, изготовленные с металлоценовыми катализаторами, для применения в изделиях, изготовленных центробежным и инъекционным формованием
AU2007265645B2 (en) 2006-06-27 2012-06-21 Univation Technologies, Llc Improved polymerization processes using metallocene catalysts, their polymer products and end uses
DE602007013041D1 (de) * 2006-06-27 2011-04-21 Univation Tech Llc Ethylen-alpha-olefin-copolymere und polymerisierungsverfahren für deren herstellung
US7632907B2 (en) * 2006-06-28 2009-12-15 Chevron Phillips Chemical Company Lp Polyethylene film having improved mechanical and barrier properties and method of making same
GB2441329B (en) * 2006-09-04 2011-06-29 Bespak Plc Seal for a dispensing apparatus
BRPI0714747A2 (pt) * 2006-09-06 2013-05-14 Dow Global Technologies Inc pano entrelaÇado , roupa , fibra apropriada para artigos tÊxteis , artigo entrelaÇado empenado e artigo entrelaÇado circular
US7847099B2 (en) 2006-09-21 2010-12-07 California Institute Of Technology Non-metallocene organometallic complexes and related methods and systems
JP5061842B2 (ja) * 2006-11-01 2012-10-31 王子製紙株式会社 二軸延伸ポリプロピレンフィルム
EP2078055B1 (en) * 2006-11-01 2017-11-22 Dow Global Technologies LLC Blends and aqueous dispersions comprising nonpolar polyolefin and polyurethane
BRPI0717715A2 (pt) * 2006-11-30 2013-10-22 Dow Global Technologies Inc Tecido e peça de vestuário
AU2007325009A1 (en) * 2006-11-30 2008-06-05 Dow Global Technologies Inc. Olefin block compositions for heavy weight stretch fabrics
BRPI0717718A2 (pt) 2006-11-30 2013-10-22 Dow Global Technologies Inc "tecido estirável capaz de ser submetido a um tratamento antienrugamento e peça de vestuario"
US8075830B2 (en) * 2006-12-15 2011-12-13 Fina Technology, Inc. Polypropylene blown film
US7713636B2 (en) * 2006-12-15 2010-05-11 Exxonmobil Chemical Patents Inc. Multi-layer films comprising propylene-based polymers
WO2008079784A2 (en) * 2006-12-21 2008-07-03 Dow Global Technologies Inc. Functionalized olefin polymers, compositions and articles prepared therefrom, and methods for making the same
TWI438238B (zh) * 2006-12-21 2014-05-21 Dow Global Technologies Llc 聚烯烴組成物與由其製備之物件,以及其之製造方法
JP5007116B2 (ja) * 2006-12-27 2012-08-22 日本ポリプロ株式会社 オレフィン共重合体の製造方法
US20100075079A1 (en) * 2006-12-29 2010-03-25 Dow Global Technologies Inc. Ozone resistant compositions and articles
CN101595253A (zh) * 2007-01-16 2009-12-02 陶氏环球技术公司 烯烃嵌段组合物的不褪色织物和衣物
CA2674991A1 (en) * 2007-01-16 2008-07-24 Dow Global Technologies Inc. Cone dyed yarns of olefin block compositions
AU2008206334A1 (en) * 2007-01-16 2008-07-24 Dow Global Technologies Inc. Stretch fabrics and garments of olefin block polymers
KR20100015391A (ko) * 2007-03-07 2010-02-12 다우 글로벌 테크놀로지스 인크. 테더링된 담지 전이 금속 착체
US20090068436A1 (en) * 2007-07-09 2009-03-12 Dow Global Technologies Inc. Olefin block interpolymer composition suitable for fibers
US9000099B2 (en) 2007-07-16 2015-04-07 Dow Global Technologies Llc Functionalized polymers, articles prepared therefrom, and methods for making the same
WO2009029487A1 (en) 2007-08-24 2009-03-05 Dow Global Technologies, Inc. Self-limiting catalyst system with controlled aluminum rto sca ratio and method
EP2042552A1 (en) * 2007-09-27 2009-04-01 Borealis Technology Oy Polyolefin compositions having improved optical and mechanical properties
WO2009042602A1 (en) * 2007-09-28 2009-04-02 Dow Global Technologies Inc Thermoplastic olefin composition with improved heat distortion temperature
DE102007048090A1 (de) * 2007-10-05 2009-04-09 Wipak Walothen Gmbh Kuvertfenster
EP2052857A1 (en) 2007-10-22 2009-04-29 Dow Global Technologies Inc. Multilayer films
EP2214903A1 (en) * 2007-11-27 2010-08-11 Dow Global Technologies Inc. A multilayer structure for the manufacture of packaging and packaging thereof
EP2080615A1 (en) * 2008-01-18 2009-07-22 Dow Global Technologies Inc. Coated substrates and packages prepared therefrom
US8088163B1 (en) 2008-02-06 2012-01-03 Kleiner Jeffrey B Tools and methods for spinal fusion
US8398833B2 (en) * 2008-04-21 2013-03-19 Honeywell International Inc. Use of DC magnetron sputtering systems
US20090269566A1 (en) * 2008-04-23 2009-10-29 Berry Plastics Corporation Pre-stretched multi-layer stretch film
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
US8283428B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymacromonomer and process for production thereof
US8796383B2 (en) * 2008-06-30 2014-08-05 Fina Technology, Inc. Polypropylene and polylactic acid formulations for heat seal applications
EP2294102B1 (en) * 2008-06-30 2013-08-21 Dow Global Technologies LLC Polyolefin compositions and articles prepared therefrom and methods of making the same
US8710163B2 (en) 2008-07-25 2014-04-29 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US8674040B2 (en) * 2008-07-25 2014-03-18 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US7973116B2 (en) * 2008-07-25 2011-07-05 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US8394902B2 (en) 2008-07-25 2013-03-12 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
EP2315789B1 (en) * 2008-08-21 2015-09-02 W.R. Grace & CO. - CONN. Catalyst composition with mixed selectivity control agent and polymerisation method using it
BRPI0913756A2 (pt) * 2008-09-23 2015-10-20 Dow Global Technologies Llc composição, polímero a base de olefina funcionalizado, e processo para produzir um polímero a base de olefina funcionalizado
RU2011116768A (ru) * 2008-10-03 2013-03-20 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Композиции для износостойких пен и способы для их производства
USD853560S1 (en) 2008-10-09 2019-07-09 Nuvasive, Inc. Spinal implant insertion device
US20100119855A1 (en) * 2008-11-10 2010-05-13 Trazollah Ouhadi Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction
EP2346936A1 (en) * 2008-11-12 2011-07-27 Dow Global Technologies LLC Highly filled, propylene-ethylene copolymer compositions
US8366748B2 (en) * 2008-12-05 2013-02-05 Kleiner Jeffrey Apparatus and method of spinal implant and fusion
US9717403B2 (en) 2008-12-05 2017-08-01 Jeffrey B. Kleiner Method and apparatus for performing retro peritoneal dissection
USD656610S1 (en) 2009-02-06 2012-03-27 Kleiner Jeffrey B Spinal distraction instrument
CN102421807B (zh) * 2009-03-06 2015-03-18 陶氏环球技术有限责任公司 催化剂、制备催化剂的方法、制备聚烯烃组合物的方法和聚烯烃组合物
CN105500870A (zh) * 2009-04-15 2016-04-20 金达胶片美国有限责任公司 薄膜组合物和制造该薄膜组合物的方法
DE202009018172U1 (de) * 2009-04-22 2011-04-07 Hottinger Baldwin Messtechnik Gmbh Optische Dehnungsmessvorrichtung
BRPI1007705A2 (pt) * 2009-05-08 2019-09-24 Dow Global Technologies Llc película retrátil orientada em multicamada e envoltório retrátil
EP2275254A1 (en) 2009-07-17 2011-01-19 Dow Global Technologies Inc. Coated substrates and packages prepared therefrom
US8394892B2 (en) * 2009-09-14 2013-03-12 Sumitomo Chemical Company, Ltd. High performance thermoplastic elastomer composition
US9173694B2 (en) 2009-09-18 2015-11-03 Spinal Surgical Strategies, Llc Fusion cage with combined biological delivery system
US9629729B2 (en) 2009-09-18 2017-04-25 Spinal Surgical Strategies, Llc Biological delivery system with adaptable fusion cage interface
US8685031B2 (en) 2009-09-18 2014-04-01 Spinal Surgical Strategies, Llc Bone graft delivery system
USD723682S1 (en) 2013-05-03 2015-03-03 Spinal Surgical Strategies, Llc Bone graft delivery tool
US9186193B2 (en) 2009-09-18 2015-11-17 Spinal Surgical Strategies, Llc Fusion cage with combined biological delivery system
JP5748952B2 (ja) * 2009-11-27 2015-07-15 日東電工株式会社 塗膜保護シート
JP5606725B2 (ja) * 2009-11-27 2014-10-15 日東電工株式会社 塗膜保護シート
ES2665762T3 (es) 2009-12-18 2018-04-27 Dow Global Technologies Llc Películas y artículos preparados a partir de las mismas
US20110218283A1 (en) * 2010-03-02 2011-09-08 Nadeem Akhtar Bokhari Reactor thermoplastic polyolefin elastomer composition
US8278403B2 (en) * 2010-07-08 2012-10-02 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers
BRPI1107080A2 (pt) 2010-12-30 2013-04-24 Braskem Sa artigo formando por sopro e compressço
US8785562B2 (en) 2011-03-25 2014-07-22 Exxonmobil Chemical Patents Inc. Amphiphilic block polymers prepared by alkene metathesis
US8669330B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Olefin triblock polymers via ring-opening metathesis polymerization
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
US8669326B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Amine functionalized polyolefin and methods for preparation thereof
US8426659B2 (en) 2011-03-25 2013-04-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8455597B2 (en) 2011-03-25 2013-06-04 Exxonmobil Chemical Patents Inc. Catalysts and methods of use thereof to produce vinyl terminated polymers
US8501894B2 (en) 2011-03-25 2013-08-06 Exxonmobil Chemical Patents Inc. Hydrosilyation of vinyl macromers with metallocenes
US8809461B2 (en) * 2011-04-28 2014-08-19 Braskem America, Inc. Multimodal heterophasic copolymer and thermoformed articles from same
US9296836B2 (en) 2011-05-12 2016-03-29 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
ES2667692T3 (es) * 2011-06-30 2018-05-14 Dow Global Technologies Llc Películas basadas en poliolefina multicapeadas que tienen una capa que comprende un material compuesto de copolímero en bloque cristalino o una resina de material compuesto de copolímero en bloque
EP2739679B1 (en) 2011-08-04 2017-05-03 Prysmian S.p.A. Energy cable having a thermoplastic electrically insulating layer
CA2844851A1 (en) * 2011-08-15 2013-02-21 Calgary Scientific Inc. Method for flow control and for reliable communication in a collaborative environment
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
US9315526B2 (en) 2014-03-03 2016-04-19 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
BR112016028445B1 (pt) 2014-06-02 2022-05-31 Avery Dennison Corporation Filme orientado com resistência à abrasão, clareza e conformabilidade, conjunto de rótulo compreendendo o filme e método para produzir um artigo rotulado
US10557005B2 (en) 2014-06-23 2020-02-11 Dow Global Technologies Llc Painted polyolefin articles
MX2017002193A (es) 2014-08-21 2017-05-03 Dow Global Technologies Llc Contenedor flexible y proceso para elaborar un contenedor flexible.
KR102223974B1 (ko) * 2016-12-29 2021-03-09 보레알리스 아게 폴리프로필렌 조성물의 제조 방법
EP3606986A4 (en) 2017-04-04 2021-01-20 Braskem America, Inc. HIGH ETHYLENE RANDOM COPOLYMER CONTAINING NON-MIGRANT OLIGOMERS
US11244815B2 (en) 2017-04-20 2022-02-08 Honeywell International Inc. Profiled sputtering target and method of making the same
WO2019009950A1 (en) 2017-07-06 2019-01-10 Exxonmobil Chemical Patents Inc. POLYETHYLENE COMPOSITIONS COMPRISING CYCLIC OLEFIN COPOLYMERS
WO2019094667A1 (en) * 2017-11-10 2019-05-16 Polyone Corporation Polyolefin elastomer blends for elastomeric films
JP7021915B2 (ja) * 2017-11-17 2022-02-17 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒の製造方法およびオレフィン類重合体の製造方法
JP7118623B2 (ja) 2017-11-17 2022-08-16 花王株式会社 不織布の製造方法
US11241868B2 (en) * 2018-02-27 2022-02-08 Inteplast Group Corporation Clear film for tapes and labels
CA3116210A1 (en) * 2018-10-12 2020-04-16 Berry Global, Inc. Machine direction-oriented polymeric film, and method of making the machine direction-oriented polymeric film
CN113993977A (zh) 2019-05-24 2022-01-28 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
JP2021059387A (ja) * 2019-10-09 2021-04-15 昭和電工パッケージング株式会社 油脂含有食品収容用の成形容器及び包装体
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
KR20220093368A (ko) 2019-11-07 2022-07-05 이스트만 케미칼 컴파니 재활용물 알파 올레핀 및 지방 알코올
JP7075921B2 (ja) * 2019-12-27 2022-05-26 株式会社アシックス 緩衝体及び靴
WO2022075350A1 (ja) * 2020-10-06 2022-04-14 三井化学株式会社 樹脂組成物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000059961A1 (en) * 1999-04-01 2000-10-12 Symyx Technologies, Inc. Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and methods of making same
WO2001074910A2 (en) * 2000-04-04 2001-10-11 Symyx Technologies, Inc. Ether-amine based polymerization catalysts, compositions and processes using same
WO2002038628A2 (en) * 2000-11-07 2002-05-16 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith

Family Cites Families (134)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US748846A (en) * 1904-01-05 Robert r
US515203A (en) * 1894-02-20 Support for spinning-spindles
US593083A (en) * 1897-11-02 Thomas m
US628343A (en) * 1899-02-27 1899-07-04 Werner Menzel Fixing of insulators for carrying electric-line wires.
US663422A (en) * 1900-08-11 1900-12-11 Steel Cable Engineering Company Hopper-delivery mechanism.
US676421A (en) * 1900-09-27 1901-06-18 David P Clark Locomotive toy.
US683176A (en) * 1900-10-16 1901-09-24 Frank Marshall Ho-Glen Binder.
US728772A (en) * 1901-01-03 1903-05-19 Leopoldo Sconfietti Moistening, cooling, or heating the air in factories, workrooms, or the like.
US692500A (en) * 1901-01-15 1902-02-04 George W Barnett Display-rack.
US699213A (en) * 1901-10-03 1902-05-06 James Mossman Combined wire stretcher, cutter, splicer, and staple-puller.
US697420A (en) * 1901-10-19 1902-04-08 Kempshall Mfg Co Golf-ball.
US728150A (en) * 1901-12-07 1903-05-12 William R Wolf Sectional bookcase.
US721798A (en) * 1901-12-31 1903-03-03 Fredrick Hagen Snapping-rolls for corn-husking machines.
US716121A (en) * 1902-01-02 1902-12-16 Charles William Sievert Oil-burner.
US735058A (en) * 1902-05-19 1903-08-04 Thaddeus M Boggs Brick-machine.
US728771A (en) * 1902-08-20 1903-05-19 James B Schuman Grain-elevator.
US728151A (en) * 1903-02-12 1903-05-12 Carl Baeker Time-fuse for artillery projectiles.
US780404A (en) * 1903-09-22 1905-01-17 Basf Ag Process of oxidizing methyl groups in aromatic hydrocarbons.
US2051634A (en) * 1931-10-22 1936-08-18 Johns Manville Pipe wrapping machine
US2051928A (en) * 1934-11-30 1936-08-25 Anaconda Copper Mining Co Electrodeposition
USB632416I5 (US20030194575A1-20031016-C00022.png) 1956-03-01 1976-03-09
US3520861A (en) 1968-12-26 1970-07-21 Dow Chemical Co Copolymers of ethylene
US4237190A (en) * 1977-09-26 1980-12-02 American Can Company Propylene/polystyrene composition and substrates coated with such compositions
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
DE3240383A1 (de) 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4599392A (en) 1983-06-13 1986-07-08 The Dow Chemical Company Interpolymers of ethylene and unsaturated carboxylic acids
AU602873B2 (en) * 1985-11-29 1990-11-01 American National Can Company Films using blends of polypropylene and polyisobutylene
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
US4988781A (en) 1989-02-27 1991-01-29 The Dow Chemical Company Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters
US5093415A (en) 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
US5015749A (en) 1987-08-31 1991-05-14 The Dow Chemical Company Preparation of polyhydrocarbyl-aluminoxanes
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US4960878A (en) 1988-12-02 1990-10-02 Texas Alkyls, Inc. Synthesis of methylaluminoxanes
US5041584A (en) 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
EP0521876B1 (en) 1989-02-27 2000-08-16 The Dow Chemical Company Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5044438A (en) 1990-03-16 1991-09-03 Young Joe A Wellhead bowl protector and retrieving tool
US5200131A (en) * 1990-04-09 1993-04-06 Mitsui Toatsu Chemicals, Inc. Method for molding syndiotactic polypropylene
US5041585A (en) 1990-06-08 1991-08-20 Texas Alkyls, Inc. Preparation of aluminoxanes
US5041583A (en) 1990-06-28 1991-08-20 Ethyl Corporation Preparation of aluminoxanes
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5134209A (en) * 1990-12-26 1992-07-28 Shell Oil Company Process of producing ethylene-propylene rubbery copolymer
DE69223823T2 (de) * 1991-02-15 1998-05-20 Mitsui Toatsu Chemicals Durchsichtige schlagzähe Formkörper
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
CA2067451A1 (en) 1991-05-24 1993-10-29 Gregory B. Kharas Polylactide blends
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5710224A (en) 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5525695A (en) 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
EP0614468B1 (en) 1991-11-25 1997-09-17 Exxon Chemical Patents Inc. Polyonic transition metal catalyst composition
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
ES2137266T3 (es) 1992-07-01 1999-12-16 Exxon Chemical Patents Inc Catalizadores de polimerizacion de olefinas a base de metales de transicion.
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5608019A (en) 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
AU682821B2 (en) 1993-04-26 1997-10-23 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5883188A (en) 1993-04-28 1999-03-16 The Dow Chemical Company Paintable olefinic interpolymer compositions
FR2705252B1 (fr) 1993-05-19 1995-07-21 Bp Chemicals Snc Procédé d'introduction d'un solide dans un réacteur et appareillage.
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
CA2125246C (en) * 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
ES2096475T3 (es) * 1993-06-24 1997-03-01 Dow Chemical Co Complejos de titanio (ii) o circonio (ii) y catalizadores de polimerizacion por adicion obtenidos a partir de los mismos.
US5504223A (en) 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides
DE4416876A1 (de) 1994-05-13 1995-11-16 Basf Ag Verfahren zur Herstellung von verbrückten Halbsandwichkomplexen
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5972822A (en) * 1994-08-02 1999-10-26 The Dow Chemical Company Biscyclopentadienyldiene complex containing addition polymerization catalysts
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
CA2164461C (en) 1994-12-06 2000-08-08 Tatsuya Tanizaki Polypropylene composition and uses thereof
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US5637660A (en) 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
US5731253A (en) 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
US5962714A (en) 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US5728855A (en) 1995-10-19 1998-03-17 Akzo Nobel Nv Modified polyalkylaluminoxane composition formed using reagent containing carbon-oxygen double bond
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
AU1685597A (en) 1996-01-26 1997-08-20 Dow Chemical Company, The Improved olefin addition polymerization catalyst composition
BR9708335A (pt) 1996-03-27 1999-08-03 Dow Chemical Co Processo de polimerização em solução para polimerizar olefinas
WO1997035893A1 (en) 1996-03-27 1997-10-02 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
EP0927187B1 (en) 1996-07-22 2002-12-04 Dow Global Technologies Inc. Metal complexes containing bridged, non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom
ATE276263T1 (de) 1996-08-08 2004-10-15 Dow Global Technologies Inc Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren
US6015868A (en) 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
TW442528B (en) 1996-12-02 2001-06-23 Chisso Corp Polypropylene composition
US6245856B1 (en) 1996-12-17 2001-06-12 Exxon Chemical Patents, Inc. Thermoplastic olefin compositions
CN1244208A (zh) 1996-12-17 2000-02-09 埃克森化学专利公司 热塑性烯烃组合物
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
CA2210131C (en) 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6525157B2 (en) 1997-08-12 2003-02-25 Exxonmobile Chemical Patents Inc. Propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6150297A (en) 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
US6197910B1 (en) * 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
WO1999045062A1 (en) 1998-03-04 1999-09-10 Exxon Chemical Patents Inc. Product and method for making polyolefin polymer dispersions
US6034240A (en) 1998-03-09 2000-03-07 Symyx Technologies, Inc. Substituted aminomethylphosphines, coordination complexes of aminomethylphosphines and their synthesis
DE19812229A1 (de) * 1998-03-20 1999-09-23 Basf Ag Polymere des Propens
AU4962399A (en) * 1998-07-01 2000-01-24 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US6288171B2 (en) 1998-07-01 2001-09-11 Advanced Elastomer Systems, L.P. Modification of thermoplastic vulcanizates using random propylene copolymers
EP1091984A1 (en) * 1998-07-02 2001-04-18 Exxon Chemical Patents Inc. Propylene olefin copolymers
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
ATE412793T1 (de) 1999-05-13 2008-11-15 Exxonmobil Chem Patents Inc Elastische fasern und daraus hergestellte artikel,die kristalline und kristallisierbare propylenpolymere enthalten
US6750284B1 (en) 1999-05-13 2004-06-15 Exxonmobil Chemical Patents Inc. Thermoplastic filled membranes of propylene copolymers
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
HU223380B1 (hu) 1999-05-19 2004-06-28 Exxon Chemical Patents Inc. Javított szilárdságú, rugalmasságú és csökkentett permeabilitású izobutilénalapú elasztomer blendek, eljárás előállításukra, és alkalmazásuk
CN1209404C (zh) 1999-09-01 2005-07-06 埃克森化学专利公司 透气膜及其制备方法
US20020165329A1 (en) 1999-12-10 2002-11-07 Jerzy Klosin Alkylphenyl-substituted group 4 metal complexes, catalysts and olefin polymerization process
WO2001042315A1 (en) 1999-12-10 2001-06-14 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
AU780051B2 (en) 1999-12-21 2005-02-24 Exxonmobil Chemical Patents Inc Adhesive alpha-olefin inter-polymers
JP4964389B2 (ja) 2000-06-30 2012-06-27 ダウ グローバル テクノロジーズ エルエルシー 多環式、縮合環化合物、金属錯体及び重合方法
KR20030064415A (ko) 2000-12-22 2003-07-31 엑손모빌 케미칼 패턴츠 인코포레이티드 다성분계 고분자 구조체
AU2002239587A1 (en) 2000-12-22 2002-07-08 Exxonmobil Chemical Patents Inc. Composites comprising semicrystalline random ethylene / propylenecopolymers
EP1554344B1 (en) 2002-10-17 2014-03-19 ExxonMobil Chemical Patents Inc. Hetero phase polymer compositions
AU2003297134A1 (en) 2002-12-17 2004-07-29 Exxonmobil Chemical Patents Inc. Elastic blends comprising elastic crystalline polymer and crystallizable polymers for ethylene
ATE506930T1 (de) 2003-01-08 2011-05-15 Exxonmobil Chem Patents Inc Elastische artikel und herstellungsverfahren dafür

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000059961A1 (en) * 1999-04-01 2000-10-12 Symyx Technologies, Inc. Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and methods of making same
WO2001074910A2 (en) * 2000-04-04 2001-10-11 Symyx Technologies, Inc. Ether-amine based polymerization catalysts, compositions and processes using same
WO2002038628A2 (en) * 2000-11-07 2002-05-16 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith

Cited By (250)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087690B2 (en) 2000-11-07 2006-08-08 Symyx Technologies, Inc. Substituted pyridyl amine catalysts and processes for polymerizing crystalline polymers
WO2004014998A2 (en) 2002-08-12 2004-02-19 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
WO2004026925A1 (en) * 2002-09-17 2004-04-01 Dow Global Technologies Inc. Improved process for manufacture of polymers
US6994763B2 (en) 2002-10-24 2006-02-07 Advanced Design Concept Gmbh Elastomeric multicomponent fibers, nonwoven webs and nonwoven fabrics
EP1772487A1 (en) * 2002-11-05 2007-04-11 Dow Gloval Technologies Inc. Thermoplastic elastomer compositions
WO2004041928A1 (en) * 2002-11-05 2004-05-21 Dow Global Technologies Inc. Thermoplastic elastomer compositions
WO2004099309A1 (en) * 2003-05-05 2004-11-18 Dow Global Technologies Inc. Filled thermoplastic olefin composition
US7309522B2 (en) 2003-07-09 2007-12-18 Advanced Design Concepts Gmbh Fibers made from block copolymer
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US9416291B2 (en) 2003-08-25 2016-08-16 Dow Global Technologies Llc Coating compositions
WO2005080495A1 (en) 2004-02-12 2005-09-01 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
JP4567387B2 (ja) * 2004-02-18 2010-10-20 新興化学工業株式会社 高純度テトラキス(ジアルキルアミノ)ハフニウムの製造法
JP2005263771A (ja) * 2004-02-18 2005-09-29 Shinko Kagaku Kogyo Kk 高純度テトラキス(ジアルキルアミノ)ハフニウムの製造法
JP4809324B2 (ja) * 2004-02-27 2011-11-09 ダウ グローバル テクノロジーズ エルエルシー 水性ポリマー分散物およびそれらの分散物による製品
JP2007525323A (ja) * 2004-02-27 2007-09-06 ダウ グローバル テクノロジーズ インコーポレイティド 水性ポリマー分散物およびそれらの分散物による製品
US7671106B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Cap liners, closures and gaskets from multi-block polymers
US7671131B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom
US7622529B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
US7514517B2 (en) 2004-03-17 2009-04-07 Dow Global Technologies Inc. Anti-blocking compositions comprising interpolymers of ethylene/α-olefins
US7714071B2 (en) 2004-03-17 2010-05-11 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
JP2005298467A (ja) * 2004-04-12 2005-10-27 Kojundo Chem Lab Co Ltd 高純度テトラキスジメチルアミノハフニウムとその製造方法およびそれを用いたゲート絶縁膜の製造方法。
JP4562169B2 (ja) * 2004-04-12 2010-10-13 株式会社高純度化学研究所 Hf系酸化物ゲート絶縁膜のプリカーサーの精製方法
DE112005000058T5 (de) 2004-04-15 2008-07-03 Exxon Mobil Chemical Patents Inc., Baytown Polyolefinklebstoffzusammensetzung und daraus hergestellte Gegenstände
US7645829B2 (en) 2004-04-15 2010-01-12 Exxonmobil Chemical Patents Inc. Plasticized functionalized propylene copolymer adhesive composition
WO2005103123A1 (en) * 2004-04-19 2005-11-03 Dow Golbal Technologies Inc. Composition suitable for single-sided, low-noise, stretch cling film and films made therefrom
AU2005236061B2 (en) * 2004-04-19 2010-04-08 Dow Global Technologies Inc. Composition suitable for single-sided, low-noise, stretch cling film and films made therefrom
US7740950B2 (en) 2004-04-19 2010-06-22 Dow Global Technologies Inc. Composition suitable for single-sided, low-noise, stretch cling film and films made therefrom
JP2007533833A (ja) * 2004-04-19 2007-11-22 ダウ グローバル テクノロジーズ インコーポレイティド 片面、低騒音の延伸密着フィルムに好適な組成物およびこれから製造されるフィルム
US8147978B2 (en) 2004-04-19 2012-04-03 Dow Global Technologies Llc Composition suitable for single-sided, low-noise, stretch cling film and films made therefrom
US7671148B2 (en) 2004-04-26 2010-03-02 Basell Polyolefine Gmbh Catalyst system for olefin polymerization, its production and use
WO2006009976A1 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Polymerization process
JP2008511742A (ja) * 2004-08-31 2008-04-17 ダウ グローバル テクノロジーズ インコーポレイティド 熱成形性シートに好適な組成物および熱成形性シートから製造される物品
US7387980B2 (en) 2004-09-22 2008-06-17 Symyx Technologies, Inc. Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts
US7642324B2 (en) 2004-09-22 2010-01-05 Symyx Solutions, Inc. Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts
US7642216B2 (en) 2004-09-22 2010-01-05 Symyx Solutions, Inc. Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts
US7256296B2 (en) 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
US7947786B2 (en) 2004-10-13 2011-05-24 Exxonmobil Chemical Patents Inc. Elastomeric reactor blend compositions
US9227346B2 (en) 2004-10-22 2016-01-05 Dow Global Technologies Llc Plastic composite articles and methods of making same
EP1655341A1 (en) 2004-11-05 2006-05-10 Advanced Elastomer Systems, L.P. Transparent polyolefin compositions
US7829623B2 (en) 2004-11-05 2010-11-09 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates having improved fabricability
US7585796B2 (en) 2004-11-26 2009-09-08 Mitsui Chemicals, Inc. Polypropylene nonwoven fabric and use thereof
EP2518194A1 (en) 2004-11-26 2012-10-31 Mitsui Chemicals, Inc. Mixed fibre nonwoven fabric and use thereof
US7674734B2 (en) 2004-11-26 2010-03-09 Mitsui Chemicals, Inc. Polypropylene nonwoven fabric and use thereof
WO2006057369A1 (ja) 2004-11-26 2006-06-01 Mitsui Chemicals, Inc. ポリプロピレンの不織布およびその用途
US7705157B2 (en) 2004-12-16 2010-04-27 Symyx Solutions, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US7476710B2 (en) 2004-12-17 2009-01-13 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blends and molded articles therefrom
US7319077B2 (en) 2004-12-17 2008-01-15 Exxonmobil Chemical Patents Inc. Polymer blends and nonwoven articles therefrom
US7683129B2 (en) 2004-12-17 2010-03-23 Exxonmobil Chemical Patents Inc. Films from polymer blends
US7619038B2 (en) 2004-12-17 2009-11-17 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and articles therefrom
WO2006065649A1 (en) 2004-12-17 2006-06-22 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blends and molded articles therefrom
EP2281859A1 (en) * 2004-12-21 2011-02-09 Dow Global Technologies Inc. Polypropylene-based adhesive compounds
KR101315567B1 (ko) 2005-03-17 2013-10-08 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/알파-올레핀 혼성중합체 블렌드 및 이로부터 제조된프로파일 및 개스킷
WO2006101926A3 (en) * 2005-03-17 2007-07-19 Dow Global Technologies Inc Interpolymers of ethylene/alpha-olefins blends and profiles and gaskets made therefrom
US7585917B2 (en) 2005-06-13 2009-09-08 Exxonmobil Chemical Patents Inc. Thermoplastic blend compositions
WO2007001694A1 (en) 2005-06-24 2007-01-04 Exxonmobil Chemical Patents Inc. Functionalized propylene copolymer adheside composition
US7812085B2 (en) 2005-06-24 2010-10-12 Exxonmobil Chemical Patents Inc. Functionalized propylene copolymer adhesive composition
EP2407496A1 (en) 2005-07-11 2012-01-18 Dow Global Technologies LLC (formerly Known As Dow Global Technologies Inc.) Silane-grafted olefin polymers, compositions and articles prepared therefrom, and methods for making the same
EP2407495A1 (en) 2005-07-11 2012-01-18 Dow Global Technologies LLC (formerly Known As Dow Global Technologies Inc.) Silane-Grafted Olefin Polymers, Compositions and Articles Prepared Therefrom, and Methods For Making The same
US9012563B2 (en) 2005-07-11 2015-04-21 Dow Global Technologies Llc Silane-grafted olefin polymers, compositions and articles prepared therefrom, and methods for making the same
US8003740B2 (en) 2005-07-26 2011-08-23 Basell Polyolefine Gmbh Method of controlling the relative activity of the different active centers of hybrid catalysts
WO2007044544A2 (en) 2005-10-07 2007-04-19 Dow Global Technologies Inc. Multilayer elastic film structures
US8022144B2 (en) 2005-10-31 2011-09-20 Dow Global Technologies Llc Propylene-based elastomeric composition
US7893161B2 (en) 2005-10-31 2011-02-22 Dow Global Technologies Inc. Propylene-based elastomeric composition
US7863364B2 (en) 2006-01-17 2011-01-04 Exxonmobil Chemical Patents Inc. Process for making dynamically-loaded articles comprising propylene-based elastomers, composition for use in such processes, and article made using such processes
US7897093B2 (en) 2006-04-19 2011-03-01 Dow Global Technologies Inc. Thermoplastic articles and improved processes for making the same
US9296182B2 (en) 2006-06-09 2016-03-29 Exxonmobil Chemical Patents Inc. Coextrusion processes for making multilayer films and films made thereby
EP2363420A1 (en) 2006-06-15 2011-09-07 Dow Global Technologies LLC Functionalized olefin interpolymers, compositions and articles prepared therefrom, and methods for making the same
EP2363445A1 (en) 2006-06-15 2011-09-07 Dow Global Technologies LLC Functionalized propylene interpolymers, compositions and articles prepared therefrom, and methods for making the same
US9120888B2 (en) 2006-06-15 2015-09-01 Dow Global Technologies Llc Functionalized olefin interpolymers, compositions and articles prepared therefrom and methods for making the same
EP2363444A1 (en) 2006-06-15 2011-09-07 Dow Global Technologies LLC Functionalized olefin interpolymers, compositions and articles prepared therefrom, and methods for making the same
EP3205698A1 (en) 2006-06-15 2017-08-16 Dow Global Technologies LLC Functionalized olefin interpolymers, compositions and articles prepared therefrom, and methods for making the same
US7732521B2 (en) 2006-06-29 2010-06-08 Dow Global Technologies Inc. Thermoplastic articles and processes for making the same using an improved masterbatch
US7858688B2 (en) 2006-06-29 2010-12-28 Dow Global Technologies Inc. Thermoplastic articles and processes for making the same using an improved masterbatch
WO2008002841A2 (en) 2006-06-29 2008-01-03 Dow Global Technologies, Inc. Thermoplastic articles and processes for making the same using an improved masterbatch
US8202467B2 (en) 2006-08-02 2012-06-19 Exxonmobil Chemical Patents Inc. Propylene-based polymer article
WO2008076589A1 (en) 2006-12-20 2008-06-26 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
EP2535360A1 (en) 2006-12-20 2012-12-19 ExxonMobil Research and Engineering Company Process for fluid phase in-line blending of polymers
US7951732B2 (en) 2007-01-26 2011-05-31 Exxonmobil Chemical Patents Inc. Elastomeric laminates for consumer products
CN101600742B (zh) * 2007-03-06 2014-07-09 埃克森美孚化学专利公司 在超溶液条件下的聚合物制备
WO2008109212A1 (en) * 2007-03-06 2008-09-12 Exxonmobil Chemical Patents Inc. Polymer production under supersolution conditions
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
US8241753B2 (en) 2007-06-04 2012-08-14 Exxonmobil Chemical Patents Inc. Composite thermoplastic elastomer structures with high adhesion performance and uses for the same
US8236878B2 (en) 2007-09-07 2012-08-07 Exxonmobil Chemical Patents Inc. Composition and manufacture thereof
WO2009035580A1 (en) 2007-09-13 2009-03-19 Exxonmobil Research And Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
US7910637B2 (en) 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
US8338540B2 (en) 2007-10-22 2012-12-25 Dow Global Technologies Llc Polymeric compositions and processes for molding articles
US9187631B2 (en) 2007-10-22 2015-11-17 Trinseo Europe Gmbh Polymeric compositions and processes for molding articles
US8674028B2 (en) 2007-10-22 2014-03-18 Dow Global Technologies Llc Polymeric compositions and processes for molding articles
US9657166B2 (en) 2007-10-22 2017-05-23 Trinseo Europe Gmbh Polymeric compositions and processes for molding articles
US8609772B2 (en) 2007-10-23 2013-12-17 Exxonmobil Chemical Patents Inc. Elastic films having improved mechanical and elastic properties and methods for making the same
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US7994237B2 (en) 2007-12-20 2011-08-09 Exxonmobil Research And Engineering Company In-line process to produce pellet-stable polyolefins
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US8614277B2 (en) 2007-12-20 2013-12-24 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US7858817B2 (en) 2008-03-10 2010-12-28 Exxonmobil Chemical Patents Inc. Metallocene-substituted pyridyl amines, their metal complexes, and processes for production and use thereof
US8163853B2 (en) 2008-03-10 2012-04-24 Exxonmobil Chemical Patents Inc. Metallocene-substituted pyridyl amines, their metal complexes, and processes for production and use thereof
US8709316B2 (en) 2008-03-14 2014-04-29 Dow Global Technologies Llc Process for shaping polymeric articles
WO2009126277A2 (en) 2008-04-10 2009-10-15 Exxonmobil Research And Engineering Company Monomer/solvent separation and recycle process for propylene containing polymers
WO2009142730A1 (en) 2008-05-22 2009-11-26 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US7867433B2 (en) 2008-05-30 2011-01-11 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
US8178031B2 (en) 2008-05-30 2012-05-15 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
US8431065B2 (en) 2008-05-30 2013-04-30 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
US10138576B2 (en) 2008-06-12 2018-11-27 3M Innovative Properties Company Biocompatible hydrophilic compositions
US8858986B2 (en) 2008-06-12 2014-10-14 3M Innovative Properties Company Biocompatible hydrophilic compositions
US8202941B2 (en) 2008-06-27 2012-06-19 Exxonmobil Chemical Patents Inc. High shrinkage propylene-based films
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
EP2853549A2 (en) 2008-08-01 2015-04-01 ExxonMobil Chemical Patents Inc. Process for olefin polymerization
EP3214158A1 (en) 2008-08-08 2017-09-06 ExxonMobil Chemical Patents Inc. Improved olefinic copolymer compositions for viscosity modification of motor oil
WO2010027491A1 (en) 2008-09-05 2010-03-11 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
US9260541B2 (en) * 2008-11-17 2016-02-16 Fina Technology, Inc. Methods of catalyst activation
US20100227986A1 (en) * 2008-11-17 2010-09-09 Fina Technology, Inc Methods of Catalyst Activation
US8093335B2 (en) 2008-12-15 2012-01-10 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin in-reactor blends and molded articles therefrom
US8106127B2 (en) 2008-12-15 2012-01-31 Exxonmobil Chemical Patents Inc. Heterogeneous in-reactor polymer blends
US8410217B2 (en) 2008-12-15 2013-04-02 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
US8227547B2 (en) 2008-12-15 2012-07-24 Exxonmobil Chemical Patents Inc. Foamable thermoplastic reactor blends and foam article therefrom
US8101685B2 (en) 2008-12-15 2012-01-24 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom
US8481647B2 (en) 2008-12-15 2013-07-09 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom
US8497325B2 (en) 2008-12-15 2013-07-30 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends and films therefrom
WO2010088488A1 (en) 2009-01-30 2010-08-05 Dow Global Technologies Inc. Polymeric compositions and filled tpo articles having improved aesthetics
US9168720B2 (en) 2009-02-27 2015-10-27 Exxonmobil Chemical Patents Inc. Biaxially elastic nonwoven laminates having inelastic zones
WO2010117612A2 (en) 2009-03-31 2010-10-14 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US9487893B2 (en) 2009-03-31 2016-11-08 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US9168718B2 (en) 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US9175240B2 (en) 2009-04-28 2015-11-03 Exxonmobil Chemical Patents Inc. Ethylene-based copolymers, lubricating oil compositions containing the same, and methods for making them
US9006161B2 (en) 2009-04-28 2015-04-14 Exxonmobil Chemical Patents Inc. Polymeric compositions useful as rheology modifiers and methods for making such compositions
US8999907B2 (en) 2009-04-28 2015-04-07 Exxonmobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
US9441060B2 (en) 2009-04-28 2016-09-13 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
US8975334B2 (en) 2009-07-23 2015-03-10 Exxonmobil Chemical Patents Inc. Crosslinkable propylene-based copolymers, methods for preparing the same, and articles made therefrom
US9005739B2 (en) 2009-07-23 2015-04-14 Exxonmobil Chemical Patents Inc. Laminated articles and their production
WO2011011124A1 (en) 2009-07-23 2011-01-27 Exxonmobil Chemical Patents Inc. Polypropylene-based elastomer coating compositions
US8835587B2 (en) 2009-08-14 2014-09-16 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
WO2011019474A2 (en) 2009-08-14 2011-02-17 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
WO2011053406A1 (en) 2009-10-29 2011-05-05 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
WO2011068728A1 (en) 2009-12-03 2011-06-09 Exxonmobil Oil Corporation Multi-layer opaque films, articles including such films, and uses thereof
US9194065B2 (en) 2009-12-17 2015-11-24 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US9416485B2 (en) 2009-12-17 2016-08-16 3M Innovative Properties Company Process of making dimensionally stable nonwoven fibrous webs
WO2011087695A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.L. Polyolefin elastic fiber
US10041190B2 (en) 2009-12-23 2018-08-07 Invista North America S.A.R.L. Fabric including polyolefin elastic fiber
US10039855B2 (en) 2009-12-23 2018-08-07 Invista North America S.A.R.L. Elastic fiber containing an anti-tack additive
WO2011087693A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.1. Elastic fiber containing an anti-tack additive
WO2011087692A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.L. Stretch articles including polyolefin elastic fiber
US9416206B2 (en) 2010-01-22 2016-08-16 Exxonmobil Chemical Patents Inc. Lubricating oil compositions and method for making them
US9815926B2 (en) 2010-01-22 2017-11-14 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
WO2011090859A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
WO2011090861A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Lubricating oil compositions and method for making them
US8932704B2 (en) 2010-02-23 2015-01-13 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
WO2011112309A1 (en) 2010-03-12 2011-09-15 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
WO2011112308A1 (en) 2010-03-12 2011-09-15 Exxonmobil Chemical Patents Inc. Composite materials comprising propylene-based polymer blend coatings
US9611572B2 (en) 2010-10-14 2017-04-04 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs, and methods of making and using the same
WO2012051479A1 (en) 2010-10-14 2012-04-19 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs, and methods of making and using the same
WO2012051239A1 (en) 2010-10-15 2012-04-19 Exxonmobil Chemical Patents Inc. Polypropylene-based adhesive compositions
WO2012074599A1 (en) 2010-12-03 2012-06-07 Exxonmobil Oil Corporation Antistatic films and methods to manufacture the same
WO2012106025A1 (en) 2011-01-31 2012-08-09 Exxonmobil Chemical Patents Inc. Coextruded films and processes for making such films
WO2012112259A2 (en) 2011-02-15 2012-08-23 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
WO2012118546A1 (en) 2011-03-03 2012-09-07 Exxonmobil Chemical Patents Inc. Ethylene-vinyl alcohol based thermoplastic elastomers and vulcanizates
WO2013013116A1 (en) 2011-07-20 2013-01-24 The Procter & Gamble Company Polymer composition
US8445620B2 (en) 2011-08-04 2013-05-21 Exxonmobil Research And Engineering Company Elastic propylene-alpha-olefin copolymer compositions and processes to produce them
US8765832B2 (en) 2011-10-14 2014-07-01 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
WO2013055496A1 (en) 2011-10-14 2013-04-18 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
US8530581B2 (en) 2011-12-12 2013-09-10 Exxonmobil Chemical Patents Inc. Powder, compositions thereof, processes for making the same, and articles made therefrom
WO2013096532A1 (en) 2011-12-22 2013-06-27 Exxonmobil Research And Engineering Company Method for improving engine fuel efficiency
US9012578B2 (en) 2012-04-19 2015-04-21 Exxonmobil Chemical Patents Inc. Blocky ethylene propylene copolymers and methods for making them
US10174442B2 (en) 2012-12-03 2019-01-08 Exxonmobil Chemical Patents Inc. Polypropylene fibers and fabrics
WO2014088827A1 (en) 2012-12-05 2014-06-12 Exxonmobil Chemical Patents Inc. Hdpe modified polyethylene blown film compositions having excellent bubble stability
WO2014099356A2 (en) 2012-12-18 2014-06-26 Exxonmobil Chemical Patents Inc. Polyethylene films and method of making same
US10308776B2 (en) 2012-12-18 2019-06-04 Exxonmobil Chemical Patents Inc. Polyethylene films and method of making same
US9422444B2 (en) 2012-12-28 2016-08-23 Dow Global Technologies Llc Coating compositions
US9938413B2 (en) 2012-12-28 2018-04-10 Dow Global Technologies Llc Coating composition and articles made therefrom
WO2014185996A1 (en) 2013-05-14 2014-11-20 Exxonmobil Chemical Patents Inc. Ethylene-based polymers and articles made therefrom
WO2015047890A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Fibers and wipes with epoxidized fatty ester disposed thereon, and methods
WO2015047988A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Compositions, wipes, and methods
WO2015047806A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Fibers, wipes, and methods
US10006165B2 (en) 2013-09-30 2018-06-26 3M Innovative Properties Company Fibers and wipes with epoxidized fatty ester disposed thereon, and methods
US9982128B2 (en) 2013-09-30 2018-05-29 3M Innovative Properties Company Fibers, wipes, and methods
US9708488B2 (en) 2013-11-22 2017-07-18 Trinseo Europe Gmbh Polycarbonate containing compositions
US10066102B2 (en) 2013-11-22 2018-09-04 Trinseo Europe Gmbh Polycarbonate containing compositions
US10550265B2 (en) 2013-11-22 2020-02-04 Trinseo Europe Gmbh Polycarbonate containing compositions
US10549515B2 (en) 2013-12-10 2020-02-04 Exxonmobil Chemical Patents Inc. Methods for making multilayer films and films made thereby
WO2015169831A1 (en) 2014-05-06 2015-11-12 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers and process for their preparation
WO2016053483A1 (en) 2014-10-03 2016-04-07 Exxonmobil Chemical Patents Inc. Polyethylene polymers, films made therefrom, and methods of making the same
WO2016069089A1 (en) 2014-10-29 2016-05-06 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions for elastic applications
WO2016076969A1 (en) 2014-11-12 2016-05-19 Exxonmobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
US10850484B2 (en) 2015-03-17 2020-12-01 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2016172099A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Polyethylene composition
US9487653B2 (en) 2015-12-08 2016-11-08 Exxonmobil Chemical Patents Inc. Process of making crosslinked polyolefin polymer blends and compositions prepared thereof
WO2017105614A1 (en) 2015-12-16 2017-06-22 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions
WO2017155609A1 (en) 2016-03-11 2017-09-14 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2017172102A1 (en) 2016-03-31 2017-10-05 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
WO2017184234A1 (en) 2016-04-22 2017-10-26 Exxonmobil Chemical Patents Inc. Polyethylene sheets
WO2018013283A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013284A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013285A1 (en) 2016-07-14 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene-catalyzed bimodal copolymer compositions
WO2018013286A1 (en) 2016-07-14 2018-01-18 Exxonmobil Chemical Patents Inc. Lubricating oil compositions comprising dual metallocene-catalyzed bimodal copolymer compositions useful as viscosity modifiers
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018102091A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patents Inc. Polyethylene films
WO2018106480A1 (en) 2016-12-06 2018-06-14 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2018111849A1 (en) 2016-12-13 2018-06-21 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and c3-c10 alpha-olefins
US10584297B2 (en) 2016-12-13 2020-03-10 Afton Chemical Corporation Polyolefin-derived dispersants
WO2019117993A1 (en) 2016-12-13 2019-06-20 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and c3-c10 alpha-olefins
US10221267B2 (en) 2016-12-13 2019-03-05 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and C3-C10 alpha-olefins
EP3336113A1 (en) 2016-12-13 2018-06-20 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and c3-c10 alpha-olefins
US11091613B2 (en) 2016-12-13 2021-08-17 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and C3-C10 alpha-olefins
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
WO2018187047A1 (en) 2017-04-06 2018-10-11 Exxonmobil Chemical Patents Inc. Cast films and processes for making the same
WO2018194740A1 (en) 2017-04-19 2018-10-25 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2018226311A1 (en) 2017-06-08 2018-12-13 Exxonmobil Chemical Patents Inc. Polyethylene blends and extrudates and methods of making the same
WO2018231224A1 (en) 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
WO2019027585A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING UNDRAWNED HAFNOCENES WITH -CH2-SIME3 FRACTIONS
WO2019027586A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. MIXED CATALYSTS COMPRISING 2,6-BIS (IMINO) PYRIDYL-IRON COMPLEXES AND BRONZED HAFNOCENES
WO2019027587A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. POLYETHYLENE COMPOSITIONS AND FILMS PREPARED THEREFROM
WO2019027605A1 (en) 2017-08-04 2019-02-07 Exxonmobil Chemical Patents Inc. FILMS MANUFACTURED FROM POLYETHYLENE COMPOSITIONS AND METHODS OF MAKING THE SAME
WO2019108326A1 (en) 2017-11-28 2019-06-06 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
WO2019108977A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
WO2019162760A1 (en) 2018-02-05 2019-08-29 Exxonmobil Chemical Patents Inc. A Corporation Of State Of Delaware Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
WO2019156802A1 (en) 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Metallocene catalyst feed system for solution polymerization process
WO2019240899A1 (en) 2018-06-13 2019-12-19 Exxonmobil Chemical Patents Inc. Polyolefin blend compositions
WO2019246069A1 (en) 2018-06-19 2019-12-26 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
WO2020046597A1 (en) 2018-08-29 2020-03-05 Exxonmobil Chemical Patents Inc. Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
WO2020068497A1 (en) 2018-09-25 2020-04-02 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2020092587A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio by trim and olefin polymerization with the same
WO2020092599A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. Slurry trim catalyst feeder modifications
WO2020092597A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of catalysts by trim and olefin polymerization
WO2020092606A1 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. On-line adjustment of mixed catalyst ratio and olefin polymerization
WO2020092584A2 (en) 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. In-line trimming of dry catalyst feed
WO2020139499A1 (en) 2018-12-26 2020-07-02 Exxonmobil Chemical Patents Inc. Multilayer metallized cast polypropylene films doped with hydrocarbon resin
WO2020167929A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Methods for making films and films made thereby
WO2020167441A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Oriented multilayer polyethylene films and laminates thereof
WO2020190507A1 (en) 2019-03-19 2020-09-24 Exxonmobil Chemical Patents Inc. Multilayer oriented films
WO2020205311A1 (en) 2019-04-05 2020-10-08 Exxonmobil Chemical Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
WO2020205337A1 (en) 2019-04-05 2020-10-08 Exxonmobil Chemical Patents Inc. Controlling molecular weight distribution and chemical composition distribution of a polyolefin product
US11530279B2 (en) 2019-04-05 2022-12-20 Exxonmobil Chemicals Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
WO2020219378A1 (en) 2019-04-24 2020-10-29 Dow Global Technologies Llc Multi-layer stretch hood film with enhanced tear strength
WO2020218874A1 (ko) * 2019-04-26 2020-10-29 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
WO2021011638A1 (en) * 2019-07-18 2021-01-21 Exxonmobil Chemical Patents Inc. Silyl-bridged pyridylamide catalysts and methods thereof
WO2021034471A1 (en) 2019-08-16 2021-02-25 Exxonmobil Chemical Patents Inc. Producing blocks of block copolymer in a separator downstream of a reactor
WO2021034400A1 (en) 2019-08-20 2021-02-25 Exxonmobil Chemical Patents Inc. Films and methods of making the same
WO2021080813A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate compositions and processes for the production thereof
WO2021080803A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Impact copolymer compositions
WO2021086552A1 (en) 2019-10-29 2021-05-06 Exxonmobil Chemical Patents Inc. Production of gradient copolymers using monomer and comonomer concentration gradients in a loop reactor
WO2021167739A1 (en) 2020-02-18 2021-08-26 Exxonmobil Chemical Patents Inc. High tenacity handwrap stretch film for improved pallet stability
WO2021195070A1 (en) 2020-03-26 2021-09-30 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polypropylene and semi-amorphous polymers
EP4050013A4 (en) * 2020-04-16 2023-01-11 LG Chem, Ltd. LIGAND COMPOUND, TRANSITION METAL COMPOUND AND CATALYST COMPOSITION COMPRISING THEM
WO2022187814A2 (en) 2021-03-05 2022-09-09 Exxonmobil Chemical Patents Inc. Processes for making and using slurry catalyst mixtures

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