WO2003027348A2 - Selbstreinigende keramische schichten für backöfen und verfahren zur herstellung selbstreinigender keramischer schichten - Google Patents

Selbstreinigende keramische schichten für backöfen und verfahren zur herstellung selbstreinigender keramischer schichten Download PDF

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Publication number
WO2003027348A2
WO2003027348A2 PCT/DE2002/002773 DE0202773W WO03027348A2 WO 2003027348 A2 WO2003027348 A2 WO 2003027348A2 DE 0202773 W DE0202773 W DE 0202773W WO 03027348 A2 WO03027348 A2 WO 03027348A2
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Prior art keywords
ceramic
porous
layer
powder
oxide
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PCT/DE2002/002773
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German (de)
English (en)
French (fr)
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WO2003027348A3 (de
Inventor
Ralph Nonninger
Olaf Binkle
Stefan Faber
Martin Jost
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Itn Nanovation AG
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Itn Nanovation AG
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7698007&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2003027348(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to EP02799383A priority Critical patent/EP1427870B2/de
Priority to JP2003530908A priority patent/JP2005519829A/ja
Priority to ES02799383T priority patent/ES2303869T5/es
Priority to DE50212297T priority patent/DE50212297D1/de
Priority to KR10-2004-7003285A priority patent/KR20040041602A/ko
Application filed by Itn Nanovation AG filed Critical Itn Nanovation AG
Priority to BR0212371-1A priority patent/BR0212371A/pt
Priority to AU2002333160A priority patent/AU2002333160A1/en
Priority to US10/488,809 priority patent/US7303784B2/en
Publication of WO2003027348A2 publication Critical patent/WO2003027348A2/de
Publication of WO2003027348A3 publication Critical patent/WO2003027348A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62625—Wet mixtures
    • C04B35/6264—Mixing media, e.g. organic solvents
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    • B82—NANOTECHNOLOGY
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
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    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
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    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
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    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5409—Particle size related information expressed by specific surface values
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5454—Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]

Definitions

  • the invention relates to a method for producing a highly porous, ceramic layer which can be applied to metallic, ceramic, enameled and / or glass substrates using porous, ceramic particles, preferably aluminum oxide, titanium oxide and zirconium oxide, and an inorganic binder system.
  • the inorganic binder system contains at least one ceramic nanoparticle with a particle size below 100 nm, preferably below 50 nm and particularly preferably below 25 nm, and water is used as the solvent.
  • Layers produced in this way are suitable as self-cleaning, catalytically active layers, e.g. in ovens, in internal combustion engines etc. or in general for coating substrates in order to drastically increase their specific surface, e.g. for catalytic applications.
  • Ovens contain a cooking space that can be closed by a door and limited by an oven muffle.
  • the side walls of the cooking space are soiled, for example, by fat splashes or roast juices or the like. Since these contaminants are unavoidable when baking and roasting, there are several options from the manufacturers, the walls, the ceiling and the floor, so to clean the inside of 'cooking space.
  • a general distinction is made between catalytic and pyrolytic cleaning.
  • the cooking space contains so-called grill bars, which can be controlled and heated using a separate, electronically controlled program and are preferably attached to the ceiling of the cooking space.
  • the pyrolysis systems are preferable to the catalytic systems, since a catalytic combustion of contaminants takes place at lower temperatures, i.e. below 500 ° C.
  • a catalytic combustion of contaminants takes place at lower temperatures, i.e. below 500 ° C.
  • Matsushita Elec. Ind. Co. Ltd. [JP 03056144] the interior of the furnace with a catalytically active coating consisting of a binder system and a catalytically active powder.
  • Metal oxides are used as the catalyst, preferably manganese dioxide, and silicone resins as the binder.
  • the mixing of a catalyst with a binder system or a layer matrix for coating the inner surface of an oven can also be found at other oven manufacturers.
  • Toshiba uses manganese oxide or ferrite as a catalyst and water glass as the binding phase.
  • Sharp KK uses quartz sand or water glass as the binding phase and iron oxide or copper oxide as the catalyst. No information on the efficiency of these two catalytic coatings can be found in the respective property rights.
  • the onset temperature of the coating that is the temperature at which the layer begins to work, is said to have been reduced to 270 ° C to 300 ° C at Toshiba and even to 250 ° C at Sharp KK.
  • the pyrolytic cleaning works very effectively above 500 ° C, but is costly due to procedural conditions. These systems are currently only used in high-price segment stoves (maximum 10% of all stoves). The cost reduction favored the development of catalytic cleaning.
  • the inner walls of the cooking space are lined with a layer that always contains a catalyst. Manganese oxide, iron oxide and copper oxide are suitable as catalysts, and temperature-resistant polymers, water glass, quartz sand and enamel are used as the binder phase of the catalyst and as the layer component.
  • the catalytic converters work above 380 ° C, which in turn causes safety precautions and thus additional costs.
  • the invention is based on the object of developing an oven interior coating which independently removes the dirt accumulating during roasting and baking, that is to say by applying a temperature significantly below 320 ° C., the working temperature of the layer preferably being 250 ° C.
  • a ceramic mixture a mixture of a porous ceramic powder and an inorganic binder system, comprising at least one porous ceramic powder with a primary particle size between 1 nm and 500 ⁇ m, preferably between 50 ⁇ m and 150 ⁇ m and an inorganic binder system, that contains at least one nanoscale particle.
  • porous ceramic layers that are stable to high temperatures and very resistant to abrasion. These layers contain both large pores / pore volumes that are accessible for organic contaminants (eg greases) and small pores via the porous ceramic particles that are not accessible for organic contaminants.
  • the porous ceramic layers have a very high absorbency and first transport the organic impurities (eg fat and meat juices) into the interior of the layer according to the invention. The contaminants are spread there, ie distributed over a very large surface. At a temperature of 250 ° C all impurities become almost complete decomposes and this without the layer containing a catalyst.
  • a very high inner surface preferably greater than 20 m 2 / g, particularly preferably greater than 70 m 2 / g and particularly preferably greater than 120 nfYg, generated, which is loaded with organic contaminants.
  • the reaction partner oxygen required for combustion is already stored in the porous, ceramic particles, similar to a reservoir, and is immediately available, so that the oxidative combustion of the contaminants is initiated early and almost quantitatively is carried out at 250 ° C.
  • a self-cleaning layer for ovens can be produced that removes organic impurities almost quantitatively at temperatures well below 380 ° C, preferably well below 320 ° C.
  • the self-cleaning layer according to the invention is furthermore distinguished by a significantly higher efficiency, at lower temperatures, preferably between 280 ° C. and 250 ° C., and early varnishing of the coating is avoided.
  • the ceramic layer according to the invention is characterized by the presence of numerous pores of different sizes and a high internal pore volume.
  • the batch according to the invention preferably contains two different ceramic powder particles and particularly preferably three different ceramic powder particles.
  • the ceramic particles used are, in particular, chalcogenide, carbide or nitride powders, at least one of these powders being nanoscale.
  • the chalcogenide powders can be an oxide, sulfide, selenide or telluride powder, with oxide powders being preferred. All powders that are usually used for powder sintering can be used.
  • examples are (optionally hydrated) oxides such as ZnO, Ce0 2 , Sn0 2 , Al 2 0 3 , Si0 2 , Ti0 2 , ln 2 0 3 , Zr0 2 , yttrium stabilized ZrO 2 , Fe 2 0 3 , Fe 3 0 4l Cu 2 0 , or W0 3 , but also phosphates, silicates, zirconates, aluminates and stannates, carbides such as WC, CdC 2 or SiC, nitrides such as BN, AIN, Si 3 N 4 and Ti 3 N, corresponding mixed oxides such as metal-tin oxides, eg indium tin oxide (ITO). Mixtures of the specified powder particles can also be used.
  • ITO indium tin oxide
  • the batch according to the invention contains a ceramic powder which is characterized by a high specific, largely internal surface area, greater than 50 m 2 / g, preferably greater than 100 m 2 / g and particularly preferably greater than 150 m 2 / g.
  • This porous, ceramic powder has an average particle size distribution greater than 500 nm, preferably greater than 1 ⁇ m and particularly preferably greater than 30 ⁇ m.
  • This ceramic powder is an oxide, hydrated oxide, chalcogenide, nitride or carbide of Si, Al, B, Zn, Zr, Cd, Ti, Ce, Sn, In, La, Fe, Cu, Ta, Nb, V , Mo or W, particularly preferably of Si, Zr, Al, Fe, and Ti.
  • Oxides are particularly preferably used.
  • Preferred inorganic solid particles are aluminum oxide, boehmite, zirconium oxide, iron oxide, silicon dioxide, titanium dioxide, silicates, stone powder, perlite and zeolites or mixtures of these inorganic solid particles.
  • the batch according to the invention further contains an inorganic binder system consisting of a solvent and at least one nanoscale powder.
  • the primary particles of the nanoscale powder can be in agglomerated form, preferably they are not agglomerated or essentially not agglomerated. All known alcohols, preferably 2-butoxyethanol, ethanol, 1-propanol, 2-propanol, but particularly preferably water, can be used for the solvent.
  • the ceramic powder is an oxide, hydrated oxide, chalcogenide, nitride or carbide of Si, Al, B, Zn, Zr, Cd, Ti, Ce, Sn, In, La, Fe, Cu, Ta, Nb, V , Mo or W, particularly preferably of Si, Zr, Al, Fe, and Ti.
  • Oxides are particularly preferably used.
  • Preferred inorganic, nanoscale solid particles are aluminum oxide, boehmite, zirconium oxide, iron oxide, silicon dioxide, titanium dioxide and godite or mixtures of these inorganic, nanoscale solid particles.
  • All known inorganic and organic acids and bases can be selected to adjust the viscosity of the inorganic binder system, preferably hydrochloric acid, Phosphoric acid, sulfuric acid and nitric acid.
  • a third ceramic powder can be added to the batch according to the invention, in order to adjust the porosity in a targeted manner. This powder is ceramic particles with an average particle size distribution between 10 nm and 1 ⁇ m, preferably between 150 nm and 600 nm.
  • the third ceramic powder is an oxide, hydrated oxide, chalcogenide, nitride or carbide of Si , AI, B, Zn, Zr, Cd, Ti, Ce, Sn, In, La, Fe, Cu, Ta, Nb, V, Mo or W, particularly preferably of Si, Zr, AI, Fe, and Ti.
  • oxides are preferably used.
  • Preferred inorganic solid particles are aluminum oxide, boehmite, zirconium oxide, iron oxide, silicon dioxide, titanium dioxide, silicates and stone powder.
  • the offset according to the invention can also optionally be expanded by adding one or more coloring inorganic components. All known inorganic dyes, preferably spies, can be used as the coloring component. The combination of several coloring components allows you to set color effects (patterns and speckles) as well as pure colors.
  • the third, optionally used ceramic powder is mixed with the optionally used coloring powders and slurried with the solvent.
  • the porous, ceramic powder and the inorganic binder system are added to this slurry.
  • a ceramic suspension is formed which can be applied to a desired substrate by spin coating, dip coating, dipping, flooding or, preferably, spraying, dried and then compacted to form a porous, ceramic layer.
  • Temperatures of up to 1200 ° C. can be used for compression, but preferably between 400 ° C. and 1000 ° C. and particularly preferably between 700 ° C. and 850 ° C.
  • porous ceramic layers can be applied to metal, glass, enamel or ceramic surfaces, with layer thicknesses between 20 ⁇ m and 1 mm, preferably between 70 ⁇ m and 600 ⁇ m.
  • these porous, ceramic layers can be coated with catalysts, so that the layers can be used for catalytic reactions, for example in the chemical industry.
  • the invention relates to a method for producing a highly porous, ceramic layer and for applying this layer to metallic, ceramic, enameled and / or glass substrates using porous, ceramic particles, preferably aluminum oxide, titanium oxide and zirconium oxide and an inorganic binder system.
  • the inorganic binder system contains at least one ceramic nanoparticle with a particle size below 100 nm, preferably below 50 nm and particularly preferably below 25 nm. Water serves as the solvent.
  • Layers produced in this way are suitable as self-cleaning, active layers, e.g. in ovens, in internal combustion engines etc. or in general for coating substrates in order to drastically increase their specific surface, e.g. for catalyst substrates.

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  • General Chemical & Material Sciences (AREA)
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  • Application Of Or Painting With Fluid Materials (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
PCT/DE2002/002773 2001-09-06 2002-07-29 Selbstreinigende keramische schichten für backöfen und verfahren zur herstellung selbstreinigender keramischer schichten Ceased WO2003027348A2 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
US10/488,809 US7303784B2 (en) 2001-09-06 2002-07-29 Method for producing self-cleaning ceramic layers and a composition therefore
JP2003530908A JP2005519829A (ja) 2001-09-06 2002-07-29 オーブン用の自己クリーニングセラミック層及び自己クリーニングセラミック層を製造する方法
ES02799383T ES2303869T5 (es) 2001-09-06 2002-07-29 Capas cerámicas autolimpiantes para hornos de cochura y procedimiento de fabricación de capas cerámicas autolimpiantes
DE50212297T DE50212297D1 (de) 2001-09-06 2002-07-29 Selbstreinigende keramische schichten für backöfen und verfahren zur herstellung selbstreinigender keramischer schichten.
KR10-2004-7003285A KR20040041602A (ko) 2001-09-06 2002-07-29 오븐용 자정식 세라믹층 및 자정식 세라믹층의 제조방법
EP02799383A EP1427870B2 (de) 2001-09-06 2002-07-29 Selbstreinigende keramische schichten für backöfen und verfahren zur herstellung selbstreinigender keramischer schichten.
BR0212371-1A BR0212371A (pt) 2001-09-06 2002-07-29 Camadas cerâmicas autolimpantes para fornos e processo para produção de camadas cerâmicas autolimpantes
AU2002333160A AU2002333160A1 (en) 2001-09-06 2002-07-29 Self-cleaning ceramic layers for baking ovens and method for production of self-cleaning ceramic layers

Applications Claiming Priority (2)

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DE10143837.0 2001-09-06
DE10143837A DE10143837A1 (de) 2001-09-06 2001-09-06 Selbstreinigende keramische Schichten für Backöfen und Verfahren zur Herstellung selbstreinigender keramischer Schichten

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WO2003027348A3 WO2003027348A3 (de) 2003-10-02

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EP (1) EP1427870B2 (enExample)
JP (1) JP2005519829A (enExample)
KR (1) KR20040041602A (enExample)
CN (1) CN1276126C (enExample)
AT (1) ATE396289T1 (enExample)
AU (1) AU2002333160A1 (enExample)
BR (1) BR0212371A (enExample)
DE (2) DE10143837A1 (enExample)
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EP1448721B1 (de) * 2001-10-15 2016-04-13 BSH Hausgeräte GmbH Katalytische beschichtung für die selbstreinigung von öfen und herden
AU2004205146B2 (en) * 2003-08-19 2006-09-28 Garth Australia Pty Ltd Self Cleaning Barbecue Roasting Hood
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US8709616B2 (en) 2007-01-30 2014-04-29 Sumitomo Osaka Cement, Co., Ltd. Cooking device and method of manufacture of the same
DE102007016946A1 (de) 2007-04-05 2008-10-09 Nano-X Gmbh Beschichtungsmaterial mit einer katalytischen Aktivität und Verwendung des Beschichtungsmaterials
DE102007034633A1 (de) 2007-04-05 2009-01-29 Nano-X Gmbh Beschichtungsmaterial mit einer katalytischen Aktivität und Verwendung des Beschichtungsmaterials
EP2011901B1 (de) * 2007-06-28 2017-10-18 Siemens Aktiengesellschaft Bauteil mit einer keramischen Schicht, in die Partikel eingelagert sind, und Verfahren zu dessen Herstellung
EP2025649B1 (de) * 2007-07-25 2020-10-14 BSH Hausgeräte GmbH Backofen
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WO2010097300A1 (de) * 2009-02-26 2010-09-02 Basf Se Schutzbeschichtung für metallische oberflächen und ihre herstellung
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EP2620525A1 (de) * 2012-01-24 2013-07-31 Linde Aktiengesellschaft Verfahren zum Kaltgasspritzen
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CN102776470A (zh) * 2012-07-09 2012-11-14 陈曦 用于机械零件的表面化学热处理的方法及其所用设备
DE102017200565A1 (de) 2017-01-16 2018-07-19 BSH Hausgeräte GmbH Beschichtungsmaterial für selbstreinigende Beschichtung und Verfahren zur Herstellung
WO2018130534A1 (de) 2017-01-16 2018-07-19 BSH Hausgeräte GmbH Beschichtungsmaterial für selbstreinigende beschichtung und verfahren zur herstellung

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DE10143837A1 (de) 2003-03-27
BR0212371A (pt) 2004-12-14
CN1558963A (zh) 2004-12-29
ES2303869T5 (es) 2012-11-15
US20040253432A1 (en) 2004-12-16
EP1427870B2 (de) 2012-08-29
DE50212297D1 (de) 2008-07-03
AU2002333160A1 (en) 2003-04-07
WO2003027348A3 (de) 2003-10-02
JP2005519829A (ja) 2005-07-07
ATE396289T1 (de) 2008-06-15
EP1427870A2 (de) 2004-06-16
CN1276126C (zh) 2006-09-20
EP1427870B1 (de) 2008-05-21

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