WO1991003311A1 - Membranes semi-permeables a flux eleve - Google Patents

Membranes semi-permeables a flux eleve Download PDF

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Publication number
WO1991003311A1
WO1991003311A1 PCT/US1990/004030 US9004030W WO9103311A1 WO 1991003311 A1 WO1991003311 A1 WO 1991003311A1 US 9004030 W US9004030 W US 9004030W WO 9103311 A1 WO9103311 A1 WO 9103311A1
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WO
WIPO (PCT)
Prior art keywords
membrane
high flux
aqueous solution
polyamine
solution
Prior art date
Application number
PCT/US1990/004030
Other languages
English (en)
Inventor
Michael M. Chau
Original Assignee
Allied-Signal Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allied-Signal Inc. filed Critical Allied-Signal Inc.
Priority to CA002063787A priority Critical patent/CA2063787C/fr
Priority to AT90911263T priority patent/ATE91242T1/de
Priority to KR1019920700429A priority patent/KR0143548B1/ko
Publication of WO1991003311A1 publication Critical patent/WO1991003311A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction

Definitions

  • This invention is generally concerned with the purification of liquids.
  • water which contains unacceptable amounts of dissolved salts, such as seawater, brackish water or hard water.
  • Such waters may be purified by forcing the water through a semipermeable reverse osmosis membrane, leaving behind the contaminants or salts which do not pass through the membrane.
  • This method may be used for softening of hard waters, but heretofore the pressures required to operate the separation process made use of reverse osmosis for such a purpose less attractive.
  • a reverse osmosis membrane must reject a high fraction of the dissolved salts.
  • the membrane generally must be tolerant to the chlorine. It is particularly important that such membranes pass a relatively large amount of water (i.e., have a high flux) through the membrane at relatively low pressures.
  • Reverse osmosis membranes have been made from a wide variety of known polymeric materials. While many of these polymeric materials can reject a large fraction of the salt, some cannot provide a sufficiently high flux of water.
  • the semipermeable membrane used in the desalination process ordinarily will be relatively thin in order to increase the flux.
  • the membrane often is formed on a porous support.
  • Scala et al. suggest reacting a broad group of amines or bisphenols with acyl halides or sulfonyl halides on a support material to form thin membranes. This provides strength to the composite.
  • the supports should possess pore sizes which are sufficiently large so that the water (permeate) can pass through the support without reducing the flux of the entire composite. Conversely, the pore size should not be so large that the thin semipermeable membrane will be unable to bridge the pores or will tend to fill up or penetrate too far into the pores.
  • Scala et al. suggest that above about 8 microns the rejection of impurities is reduced.
  • U.S. Patent 4,277,344 discloses a reverse osmosis membrane made in situ according to Scala et al., which has been prepared from a polyacyl halide and an arylene polyamine. According to the '344 patent, no advantage was found for surfactant and acid-accepting additives and it is preferred to carry out the interfacial polymerization without the presence of acid acceptors.
  • the '344 patent teaches that the membrane contains a plurality of sites having the formula:
  • the present invention provides still further improvement in the performance of supported membranes by using polar aprotic solvents which are capable of dissolving or plasticizing the support material.
  • the invention provides improved membranes which have a surprisingly improved flux and yet retain effective salt rejection and tolerance to chlorine and other oxidants.
  • the membrane will be formed by the reaction of polyacyl halides, polysulfonyl halides, or polyisocyanates, with polyamines or bisphenols.
  • the membranes preferably will comprise the reaction product resulting from the reaction of an aliphatic or aromatic polyamine with an aliphatic or aromatic polycarboxylic acid halide, the membrane being deposited within and/or on a porous support backing material.
  • Such membranes are prepared in the presence of a solvent capable of dissolving or plasticizing the porous support, which unexpectedly provides enhanced water flux through the membrane.
  • the polyamine preferably is an aromatic diamine and more preferably is at least one member of the group consisting of m- phenylenediamine, p_-phenylenediamine, o-phenylenediamine, 4- chlorophenylenediamine, and 5-chlorophenylenediamine.
  • the polycarboxylic acid halide preferably is an aromatic polycarboxylic halide and more preferably is a member of the group consisting of isophthaloyl chloride, tri esoyl chloride, tri ellitoyl chloride and terephthaloyl chloride.
  • the solvent capable of dissolving or plasticizing the support material preferably is a polar aprotic solvent which does not react with amines and more preferably is at least one member of the group consisting of N-methylpyrrolidone, 2-pyrrolidones, N,N-dimethylformamide, dioxane, pyridine, lutidines, picolines, tetrahydrofuran, sulfolane, sulfolene, hexamethyl phosphoramide, triethyl phosphite, N,N-dimethylacetamide, acetonitrile, and N,N- dimethylpropiona ide.
  • the solvent will be present in the aqueous polyamine solution in a concentration of 0.01 to 75% by weight, preferably 0.1 - 20%, most preferably 1-20%.
  • One embodiment of this invention is a high flux semipermeable membrane prepared by coating on a porous support backing material an aqueous solution of an aromatic polyamine which contains a polar aprotic solvent for the backing material, removing excess solution, drying the surface of the coated support, contacting the dried surface of the support material with an aromatic polycarboxylic acid halide in an organic solvent to form a reaction product within and/or on the surface of the porous support material, and curing the resultant composite to form the finished high flux semipermeable membrane.
  • a specific embodiment of this invention is a high flux semipermeable membrane prepared by casting an aqueous solution having a pH of about 8 to 14 containing about 0.1 to 20 wt. % of m-phenylenedi mine, said aqueous solution containing 1-20 weight % N-methylpyrrolidone and sodium carbonate (an acid acceptor) on a polysulfone backing material, removing excess solution, drying a surface of the coated support until it is dry to the touch, contacting the dried face of the support with a naphtha solution of about 0.01 % to 10 wt.
  • Optional finishing steps may include subjecting the composite to treatment with sodium carbonate at a temperature in the range of from about 20° to about 100°C at a pH in the range of from about 9 to about 11.
  • the membranes may be prepared by the method generally described by Scala et al.
  • An aqueous solution of a polyamine or a bisphenol, preferably a polyamine is coated on a porous support material and the excess removed by drawing, rolling, sponging, air knifing or other suitable techniques. Thereafter the surface of the coated support material is dried and then is contacted with an organic solution of a polyacyl halide, polysulfonyl halide or polyisocyanate, preferably a polyacyl halide. Since the porous support material surface is dry, the polymerized reaction product is formed within and/or on the porous support. The resulting composite is then cured to provide a semipermeable membrane which exhibits high water flux and good salt rejection as well as tolerance to chlorine.
  • the membrane formed by drying the surface of the coated support and then contacting the dry surface of the support with an organic solution of an polyacyl, polysulfonyl halide, or polyisocyanate exhibits a high water flux superior to the membranes made according to the teachings of prior art which did not utilize a solvent for the porous support.
  • the new membranes permit operation at much lower pressures while retaining an acceptable flux, which is particularly valuable for softening of domestic hard water.
  • the semipermeable membranes of the present invention may be prepared by coating a porous support material with an aqueous solution of an aromatic polyamine.
  • the porous support material comprises a polymeric material containing pores which are of sufficient size to permit the passage of permeate therethrough.
  • the pore size of the porous support material will range from about 1 to about 5,000 millimicrons.
  • Examples of porous support materials which may be used to prepare the desired membrane composite of the present invention may include such polymers as polysulfone, polycarbonate, icroporous polypropylene, the various polya ides, polyamines, polyphenylene ether, and various halogenated polymers such as polyvinylidine fluoride. As noted in U.S.
  • the porous support backing material may be coated with an aqueous solution of monomeric polyamines or, to render the resulting membrane more resistant to environmental attacks, of monomeric substituted polyamines.
  • monomeric polyamines may comprise cyclic polyamines such as piperazine; substituted cyclic polyamines such as methyl piperazine, dimethyl piperazine; aromatic polyamines such as m-phenylenediamine, o- phenylenediamine, ⁇ -phenylenediamine, biphenylene diamines; substituted aromatic polyamines such as chlorophenylenediamine, N,N'-dimethyl-l,3-phenylenediamine; multi-aromatic ring polyamines such as benzidine; substituted multi-aromatic ring polyamines such as 3,3'dimethylbenzidine, 3,3'dichlorobenzidine and dia inonaph- thalenes; or mixtures thereof, depending on the separation requirements as well as the environmental stability requirements of the resulting
  • aromatic diamines selected from the group consisting of m-phenylenediamine, o-phenylenediamine, p_-phenylenediamine, 4-chlorophenylenediamine, and 5-chlorophenylene diamine.
  • the solution which is utilized as the carrier for the polyamine will comprise water in which the polyamine will be present in the solution in an amount in the range of from about 0.1 to about 20% by weight.
  • the aqueous solution may also contain basic acid acceptors such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, and triethylamine.
  • the acid acceptor may be present in a relatively small amount ranging from about 5 to about 1000 parts per million.
  • the pH of the aqueous solution is maintained in the range of from about 8 to about 14. It has been found that if the solution includes a solvent for the porous support in amounts ranging from 0.01 to about 75% by weight, preferably 0.1 to 20%, most preferably 1-20%, that the rate of transfer of water through the membrane (i.e.
  • the concentration selected will depend on, among other things, the residence time of the support material in the polyamine solution. That is, a short residence time would permit a higher concentration of the polar aprotic solvent.
  • solvents will be polar aprotic solvents which do not react with amines and preferably will be at least one member of the group consisting of N-methyl pyrrolidone, 2-pyrrolidones, N,N- dimethylformamide, dioxane, pyridine, lutidines, picolines, tetrahydrofuran, sulfolane, sulfolene, hexamethylphosphora ide, triethylphosphite, N,N-dimethylacetamide, acetonitrile, and N,N- dimethylpropionamide.
  • the solvent e.g., N-methylpyrrolidone
  • aromatic polycarboxylic acid halides which may be employed will include di- or tricarboxylic acid halides such as trimesoyl chloride (1,3,5-benzene tricarboxylic acid chloride), trimellitoyl chloride (1,2,4-benzene tricarboxylic acid chloride), isophthaloyl chloride, terephthaloyl chloride, trimesoyl bromide (1,3,5-benzene tricarboxylic acid bromide), trimellitoyl bromide (1,2,4-benzene tricarboxylic acid bromide), isophthaloyl bromide, terephthaloyl bromide, trimesoyl iodide (1,3,5-benzene tricarboxylic acid iodide), trimellitoyl
  • the di- or tricarboxylic acid halides may be substituted to render them more resistant to further environmental attack.
  • aromatic acid halides selected from the group consisting of isophthaloyl chloride, trimesoyl chloride, trimellitoyl chloride, and terephthaloyl chloride.
  • the aromatic polycarboxylic acid halide is present in the organic solvent solution in a range of from about 0.01 to about 10% by weight of the solution.
  • the organic solvents which are employed in the process of this invention will comprise those which are immiscible with water and may comprise paraffins such as n-pentane, n-hexane, n-heptane, cyclopentane, cyclohexane, methylcyclopentane, naphtha, and the like, or halogenated hydrocarbons.
  • paraffins such as n-pentane, n-hexane, n-heptane, cyclopentane, cyclohexane, methylcyclopentane, naphtha, and the like, or halogenated hydrocarbons.
  • the support surface coated with the polyamine is dried before contact with the organic solution, the polymerization of the two components of the membrane will occur within and/or on the surface of the support.
  • the addition of a solvent for the backing material may affect the membrane forming reaction since such solvents will be generally somewhat miscible in the organic phase.
  • the contact time used for the formation of the thin film membrane will vary over a relatively wide range of from about 1 second to about 60 seconds, but the reaction is bel eved to occur in less than one second.
  • the resultant composite may be cured to remove any remaining solvent and reactants.
  • the time and temperature for the curing process will be interdependent, the primary criteria for the curing of the membrane being that the curing time and temperature are sufficient to provide the desired membrane, but not excessive. For example, too much heat or time may completely dry the membrane or affect the pore size of the backing material, thus decreasing the flux or rejection of the membrane. Accordingly, curing at ambient temperatures for a time less than is required to dry the membrane is preferred. More generally, the curing of the composite membrane may be effected over a temperature range ambient (20°- 25°C) up to about 150°C for a period of time ranging from about 1 second to about 2 hours or more in duration.
  • the composite high flux membrane may be subjected to one or more optional post treatments.
  • the membrane may be washed with an aqueous solution having a pH in the range of from about 9 to about 11.
  • the solution may include a basic compound such as sodium hydroxide, potassium hydroxide, lithium hydroxide, sodium carbonate, potassium carbonate, lithium carbonate, and the like.
  • the wash temperature may be in the range of from about 20° to about 100°C for a period of time in the range of from about 1 to about 15 minutes.
  • any unreacted aromatic polyamine which may still be present can be removed by leaching, although such a step is not generally necessary.
  • Leaching of the unreacted aromatic polyamine may be done by treating the membrane with a 0.01 to 5 wt. % solution of sodium bisulfite at a temperature in the range of from about 20° to about 100°C for a period of time in the range of from about 1 to about 60 minutes.
  • High flux semipermeable membranes may be prepared in a continuous manner.
  • a porous support backing material is continuously passed through a bath of an aqueous solution of the polyamine or bisphenol which contains a polar aprotic solvent according to the invention and optionally an acid acceptor. After passage through the bath, the backing material is continuously withdrawn and any excess solution is removed by suitable techniques familiar to those skilled in the art.
  • a surface of the coated support is dried to the touch and then continuously passed through the organic solvent solution of the polyacyl halide, polysulfonyl halide, or polyisocyanate. Formation of the membrane on only the dry face of the support is preferred and thus only one surface will be contacted with the organic solution.
  • the polymerization reaction will occur while the organic solution is in contact with the amine coating, following which the composite comprising the polymerized reaction product in the form of a thin film semipermeable membrane within and/or on the surface of the porous support backing material will be cured, for example, by passage through a chamber which is maintained at the desired curing temperature, the passage through said chamber being at a predetermined rate so as to avoid any possible damage to the composite membrane. Curing at ambient temperature is preferred since the membrane should not be completely dried. Complete drying may lead to an irreversible loss of performance. Thereafter, the optional finishing steps may be carried out and the finished membrane is subsequently recovered.
  • the resultant high flux semipermeable membrane may then be employed for the separation process desired such as the desalination of seawater or brackish water, other treatments of water such as softening of hard water, boiler water treatment, concentration of whey or fruit juices, and the like.
  • the membranes which are in the form of flat sheets are particularly applicable for use in modules either in single sheet or multiple sheet units whereby the sheet or sheets are wound in a spiral type configuration.
  • a high flux membrane was formed by polymerization on a 0.076 mm thick porous polysulfone film backed with polyester fabric.
  • the film was brought into contact first with an aqueous solution of m- phenylenedi mine and N-methylpyrrolidone (NMP) and then with naphtha solution of trimesoyl chloride (TMC) .
  • NMP N-methylpyrrolidone
  • TMC trimesoyl chloride
  • the film was in contact with the amine solution for 10.5 seconds at room temperature, after which it was wiped free of excess solution on the fabric side but blown dry to the touch on the film side by two air knives.
  • the film side was then contacted for 6.5 seconds with the naphtha solution of the acyl halide.
  • the film was then dried for about 3 minutes at room temperature and then rinsed, although the rinsing procedures are not considered essential.
  • Two rinse baths were used, the first operated at room temperature and contained an aqueous solution of 170 wt. ppm Na 2 C0 3 and 53 wt. ppm NaHS0 3 , the second was held at 40°C and contained 100 wt. ppm NaHS0 3 .
  • the film was allowed to dry at room temperature for about 14 minutes in a chamber at which time it was considered finished and ready for use.
  • a high flux membrane was prepared by the method just described using an aqueous solution containing 3 wt. % m- phenylenediamine, 3.0 wt. % NMP and 100 wt. ppm of sodium carbonate and a naphtha solution containing 0.1 wt. % TMC.
  • the finished film was tested by placing samples in a stainless steel flat cell and passing a synthetic brackish water feed containing 2 gm/liter of sodium chloride across the surface of a 25 x 76 mm membrane at a feed rate of 4.27 liters/minute.
  • EXAMPLE II (Comparative) A membrane was prepared and tested and described as above except that no NMP was added to the aqueous amine solution. The results are included in the table below.
  • EXAMPLE III High flux membranes according to the invention were prepared as described above using (A) 1 wt. %, (B) 2 wt. %, and (C) 20 wt. % NMP instead of the 3 wt. % NMP of Example I. Test results of these membranes are shown in the table below.
  • EXAMPLE IV A high flux membrane according to the invention was prepared as described above except that 5 wt. % dimethylformamide (DMF) was substituted for NMP as the protic polar solvent. The test results of this membrane are shown in the table below.
  • DMF dimethylformamide
  • N-methylpyrrolidone up to 3% provides membranes with about 40% increase in flux while retaining good salt rejection (see Examples I-III), further increase in NMP will provide increased flux but at the expense of some loss of salt rejection.
  • Dimethyl formamide also provides an increased flux and good salt rejection.
  • EG ethylene glycol
  • a thin film reverse osmosis membrane 1s prepared by polymerization as described in Example 1 using an aqueous solution of 3 wt. % p_-phenylened1amine plus 20 wt. % 2-pyrrolidone and 0.01 wt. % Na 2 C0 3 and followed by a solution of 0.2 wt. % isophthaloyl chloride in naphtha.
  • the membrane 1s tested according to Example I and the flux and salt rejection are determined.
  • EXAMPLE VII Another thin film reverse osmosis membrane is prepared as in Example I using an aqueous solution of 3 wt. % o- phenylenedlamine plus 10 wt. % N,N-d1methylformamide and 0.01 wt. % Na 2 C0 3 and followed by a solution of 0.2 wt. % terephthaloyl chloride in naphtha.
  • a reverse osmosis membrane is prepared using an aqueous solution of 3 wt. % 4-chlorophe ⁇ ylenediamine plus
  • a reverse osmosis membrane is prepared using an aqueous solution of 3 wt. % 5-chlorophenylenedi mine plus

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

On peut préparer des membranes semi-perméables à flux élevé comprenant un produit de réaction polymérisé se trouvant à l'intérieur et/ou sur un support poreux, par mise en contact du support poreux tel qu'une feuille de polysulfone avec une solution aqueuse d'une polyamine, ladite solution aqueuse contenant un solvant aprotique polaire ne réagissant pas avec les amines, et facultativement un accepteur d'acide. On sèche la surface du support revêtu, puis on la met en contact avec une solution organique d'un halogénure d'acide polycarboxylique pendant une période suffisante pour former un produit de réaction polymérisé dans et/ou sur la surface de la matière de support. On peut post-traiter le composite obtenu par lavage à l'aide d'un composé alcalin. On peut utiliser le composite de la membrane obtenue dans des procédés de séparation tels que la dessalinisation d'eau saumâtre ou d'eau de mer, ou l'adoucissement d'eau domestique dure.
PCT/US1990/004030 1989-08-30 1990-07-18 Membranes semi-permeables a flux eleve WO1991003311A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA002063787A CA2063787C (fr) 1989-08-30 1990-07-18 Membrane semi-permeable pour flux eleve
AT90911263T ATE91242T1 (de) 1989-08-30 1990-07-18 Semipermeable membranen mit hohem fluss.
KR1019920700429A KR0143548B1 (ko) 1989-08-30 1990-07-18 고플럭스 반투막

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US400,440 1989-08-30
US07/400,440 US4950404A (en) 1989-08-30 1989-08-30 High flux semipermeable membranes

Publications (1)

Publication Number Publication Date
WO1991003311A1 true WO1991003311A1 (fr) 1991-03-21

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US (1) US4950404A (fr)
EP (1) EP0489746B1 (fr)
JP (1) JP2947291B2 (fr)
KR (1) KR0143548B1 (fr)
CN (1) CN1028609C (fr)
AT (1) ATE91242T1 (fr)
AU (1) AU631912B2 (fr)
CA (1) CA2063787C (fr)
DE (1) DE69002165T2 (fr)
DK (1) DK0489746T3 (fr)
ES (1) ES2043384T3 (fr)
NZ (1) NZ234346A (fr)
WO (1) WO1991003311A1 (fr)

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US8851297B2 (en) 2006-10-10 2014-10-07 Nitto Denko Corporation Composite semipermeable membrane and process for producing the same

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NZ234346A (en) 1992-01-29
AU6078990A (en) 1991-04-08
DK0489746T3 (da) 1993-08-30
JPH04507216A (ja) 1992-12-17
CA2063787C (fr) 2000-05-23
ATE91242T1 (de) 1993-07-15
KR0143548B1 (ko) 1998-07-15
CN1049799A (zh) 1991-03-13
DE69002165T2 (de) 1993-10-14
EP0489746A1 (fr) 1992-06-17
JP2947291B2 (ja) 1999-09-13
CN1028609C (zh) 1995-05-31
US4950404A (en) 1990-08-21
ES2043384T3 (es) 1993-12-16
US4950404B1 (fr) 1991-10-01
DE69002165D1 (de) 1993-08-12
KR920703190A (ko) 1992-12-17
CA2063787A1 (fr) 1991-03-01
AU631912B2 (en) 1992-12-10
EP0489746B1 (fr) 1993-07-07

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