CA2063787A1 - Membrane semi-permeable pour flux eleve - Google Patents

Membrane semi-permeable pour flux eleve

Info

Publication number
CA2063787A1
CA2063787A1 CA2063787A CA2063787A CA2063787A1 CA 2063787 A1 CA2063787 A1 CA 2063787A1 CA 2063787 A CA2063787 A CA 2063787A CA 2063787 A CA2063787 A CA 2063787A CA 2063787 A1 CA2063787 A1 CA 2063787A1
Authority
CA
Canada
Prior art keywords
high flux
semipermeable membranes
reaction product
aqueous solution
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2063787A
Other languages
English (en)
Other versions
CA2063787C (fr
Inventor
Michael M. Chau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kovalus Separation Solutions LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2063787A1 publication Critical patent/CA2063787A1/fr
Application granted granted Critical
Publication of CA2063787C publication Critical patent/CA2063787C/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/125In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

On peut préparer des membranes semi-perméables à flux élevé comprenant un produit de réaction polymérisé se trouvant à l'intérieur et/ou sur un support poreux, par mise en contact du support poreux tel qu'une feuille de polysulfone avec une solution aqueuse d'une polyamine, ladite solution aqueuse contenant un solvant aprotique polaire ne réagissant pas avec les amines, et facultativement un accepteur d'acide. On sèche la surface du support revêtu, puis on la met en contact avec une solution organique d'un halogénure d'acide polycarboxylique pendant une période suffisante pour former un produit de réaction polymérisé dans et/ou sur la surface de la matière de support. On peut post-traiter le composite obtenu par lavage à l'aide d'un composé alcalin. On peut utiliser le composite de la membrane obtenue dans des procédés de séparation tels que la dessalinisation d'eau saumâtre ou d'eau de mer, ou l'adoucissement d'eau domestique dure.
CA002063787A 1989-08-30 1990-07-18 Membrane semi-permeable pour flux eleve Expired - Lifetime CA2063787C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US400,440 1989-08-30
US07/400,440 US4950404A (en) 1989-08-30 1989-08-30 High flux semipermeable membranes
PCT/US1990/004030 WO1991003311A1 (fr) 1989-08-30 1990-07-18 Membranes semi-permeables a flux eleve

Publications (2)

Publication Number Publication Date
CA2063787A1 true CA2063787A1 (fr) 1991-03-01
CA2063787C CA2063787C (fr) 2000-05-23

Family

ID=23583629

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002063787A Expired - Lifetime CA2063787C (fr) 1989-08-30 1990-07-18 Membrane semi-permeable pour flux eleve

Country Status (13)

Country Link
US (1) US4950404A (fr)
EP (1) EP0489746B1 (fr)
JP (1) JP2947291B2 (fr)
KR (1) KR0143548B1 (fr)
CN (1) CN1028609C (fr)
AT (1) ATE91242T1 (fr)
AU (1) AU631912B2 (fr)
CA (1) CA2063787C (fr)
DE (1) DE69002165T2 (fr)
DK (1) DK0489746T3 (fr)
ES (1) ES2043384T3 (fr)
NZ (1) NZ234346A (fr)
WO (1) WO1991003311A1 (fr)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK0503596T3 (da) * 1991-03-12 1996-07-29 Toray Industries Fremgangsmåde til fremstilling af en semipermeabel kompositmembran
US5234598A (en) * 1992-05-13 1993-08-10 Allied-Signal Inc. Thin-film composite membrane
US5368889A (en) * 1993-04-16 1994-11-29 The Dow Chemical Company Method of making thin film composite membranes
JP3006976B2 (ja) * 1993-06-24 2000-02-07 日東電工株式会社 高透過性複合逆浸透膜の製造方法
EP0636403A3 (fr) * 1993-07-28 1996-03-27 Toyo Boseki Membrane d'hémodialyse en acétate de cellulose.
US5693227A (en) * 1994-11-17 1997-12-02 Ionics, Incorporated Catalyst mediated method of interfacial polymerization on a microporous support, and polymers, fibers, films and membranes made by such method
JP3489922B2 (ja) * 1994-12-22 2004-01-26 日東電工株式会社 高透過性複合逆浸透膜の製造方法
US5614099A (en) * 1994-12-22 1997-03-25 Nitto Denko Corporation Highly permeable composite reverse osmosis membrane, method of producing the same, and method of using the same
US5989426A (en) * 1995-07-05 1999-11-23 Nitto Denko Corp. Osmosis membrane
US6171497B1 (en) 1996-01-24 2001-01-09 Nitto Denko Corporation Highly permeable composite reverse osmosis membrane
JP3681214B2 (ja) * 1996-03-21 2005-08-10 日東電工株式会社 高透過性複合逆浸透膜
AU5694496A (en) * 1996-05-09 1997-12-05 Proyectos, Acondicionamiento Y Servicios Del Agua S.A. Interfacially synthetized reverse osmosis membranes based on 4-chloro-1,3-diaminobenzen, and production process
US5776324A (en) * 1996-05-17 1998-07-07 Encelle, Inc. Electrochemical biosensors
FR2761617A1 (fr) * 1997-04-04 1998-10-09 Fluid Sys Corp Membranes de separation selective
KR100506537B1 (ko) * 1997-08-28 2005-11-08 주식회사 새 한 가교 폴리아미드계 역삼투 분리막의 제조방법
US6015495A (en) * 1998-02-18 2000-01-18 Saehan Industries Incorporation Composite polyamide reverse osmosis membrane and method of producing the same
JP3985387B2 (ja) * 1998-04-27 2007-10-03 東レ株式会社 複合半透膜の製造方法
US6063278A (en) * 1998-04-28 2000-05-16 Saehan Industries Inc. Composite polyamide reverse osmosis membrane and method of producing the same
US6162358A (en) * 1998-06-05 2000-12-19 Nl Chemicals Technologies, Inc. High flux reverse osmosis membrane
US6368507B1 (en) * 1998-10-14 2002-04-09 Saekan Industries Incorporation Composite polyamide reverse osmosis membrane and method of producing the same
KR100477587B1 (ko) * 1998-11-09 2005-07-18 주식회사 새 한 폴리아미드계 복합소재 분리막 제조방법
KR20000051527A (ko) * 1999-01-22 2000-08-16 한형수 고유량 반투과 역삼투막의 제조방법
KR20000051528A (ko) * 1999-01-22 2000-08-16 한형수 고유량 역삼투 복합막의 제조방법
US6245234B1 (en) * 1999-06-03 2001-06-12 Saehan Industries Incorporation Composite polyamide reverse osmosis membrane and method of producing the same
KR100506538B1 (ko) * 1999-08-17 2005-08-05 주식회사 새 한 폴리아마이드 역삼투 복합막 및 이의 제조방법
US6337018B1 (en) 2000-04-17 2002-01-08 The Dow Chemical Company Composite membrane and method for making the same
US6783711B2 (en) * 2000-05-23 2004-08-31 Ge Osmonics, Inc. Process for preparing a sulfonamide polymer matrix
JP4705746B2 (ja) * 2000-05-23 2011-06-22 ジーイー・オズモニクス・インコーポレイテッド ナノ濾過のための酸安定性膜
MXPA02011570A (es) * 2000-05-23 2004-09-09 Osmonics Inc Polimeros de sulfonamida modificados.
US6837996B2 (en) * 2000-05-23 2005-01-04 Ge Osmonics, Inc. Polysulfonamide matrices
JP4656503B2 (ja) * 2004-10-01 2011-03-23 日東電工株式会社 複合半透膜及びその製造方法
JP4656502B2 (ja) 2004-10-01 2011-03-23 日東電工株式会社 複合半透膜及びその製造方法
JP2006102594A (ja) * 2004-10-01 2006-04-20 Nitto Denko Corp 複合半透膜の製造方法
JP4656511B2 (ja) * 2004-10-04 2011-03-23 日東電工株式会社 複合逆浸透膜の製造方法
CA2600481A1 (fr) * 2005-03-09 2006-09-21 The Regents Of The University Of California Membranes nanocomposites et procedes de fabrication et d'utilisation associes
KR100680109B1 (ko) * 2005-07-27 2007-02-07 웅진코웨이주식회사 폴리아미드 역삼투 복합막 및 그 제조방법
US7909179B2 (en) * 2005-08-16 2011-03-22 Ge Osmonics, Inc. Modified polyamide matrices and methods for their preparation
US7575687B2 (en) 2005-08-16 2009-08-18 Ge Osmonics, Inc. Membranes and methods useful for caustic applications
US7537697B2 (en) * 2006-02-01 2009-05-26 Woongjin Chemical Co., Ltd. Selective membrane having a high fouling resistance
US7913857B2 (en) * 2006-02-01 2011-03-29 Woongjin Chemical Co., Ltd. Selective membrane having a high fouling resistance
US20070227966A1 (en) 2006-03-31 2007-10-04 Koo Ja-Young Composite polyamide reverse osmosis membrane showing high boron rejection and method of producing the same
US20070251883A1 (en) * 2006-04-28 2007-11-01 Niu Q Jason Reverse Osmosis Membrane with Branched Poly(Alkylene Oxide) Modified Antifouling Surface
KR101360751B1 (ko) 2006-05-12 2014-02-07 다우 글로벌 테크놀로지스 엘엘씨 개질된 막
KR100905901B1 (ko) * 2006-09-07 2009-07-02 웅진코웨이주식회사 폴리아미드 역삼투 복합막 활성층 형성용 아민 수용액,이를 이용한 폴리아미드 역삼투 복합막, 및 이의 제조방법
JP4936438B2 (ja) * 2006-10-10 2012-05-23 日東電工株式会社 乾燥複合半透膜の製造方法
JP2008093544A (ja) * 2006-10-10 2008-04-24 Nitto Denko Corp 複合半透膜及びその製造方法
EP2117688B1 (fr) 2007-02-05 2011-07-13 Dow Global Technologies LLC Membrane en polyamide modifié
JP2008246419A (ja) * 2007-03-30 2008-10-16 Nitto Denko Corp 複合半透膜の製造方法
US7806275B2 (en) * 2007-05-09 2010-10-05 The United States Of America As Represented By The Secretary Of The Interior, The Bureau Of Reclamation Chlorine resistant polyamides and membranes made from the same
US20090107922A1 (en) * 2007-10-26 2009-04-30 General Electric Company Membrane, water treatment system, and associated method
US8177978B2 (en) 2008-04-15 2012-05-15 Nanoh20, Inc. Reverse osmosis membranes
KR20100003799A (ko) 2008-07-02 2010-01-12 웅진케미칼 주식회사 높은 안티파울링성을 가지는 선택적 분리막 및 그의제조방법
US8961790B2 (en) 2008-10-17 2015-02-24 General Electric Company Separator assembly
US8968566B2 (en) * 2008-10-17 2015-03-03 General Electric Company Separator assembly
US20100096308A1 (en) * 2008-10-17 2010-04-22 General Electric Company Separator assembly
US20100096319A1 (en) * 2008-10-17 2010-04-22 General Electric Company Separator assembly
US8021550B2 (en) * 2008-10-17 2011-09-20 General Electric Company Central core element for a separator assembly
US8580341B2 (en) * 2009-05-22 2013-11-12 General Electric Company Method of making composite membrane
ES2715823T3 (es) 2009-06-29 2019-06-06 Nanoh2O Inc Membranas TFC para RO híbridas mejoradas con aditivos nitrogenados
US20110049055A1 (en) * 2009-08-31 2011-03-03 General Electric Company Reverse osmosis composite membranes for boron removal
PL2510026T3 (pl) * 2009-12-11 2014-07-31 Basf Se Ulepszone porowate materiały na bazie amin aromatycznych
CN101897995B (zh) * 2010-07-09 2012-12-19 深圳市北科生物科技有限公司 一种可植入的披膜三维载体及其制备方法
GB201012083D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Thin film composite membranes for separation
AU2011326483B2 (en) 2010-11-10 2017-02-23 Nanoh2O, Inc. Improved hybrid TFC RO membranes with non-metallic additives
CN103328081B (zh) 2011-01-24 2015-08-19 陶氏环球技术有限责任公司 复合聚酰胺膜
US8820540B2 (en) 2011-01-28 2014-09-02 Woongjin Chemical Co., Ltd. Method for preparing a filtration membrane and filtration membrane prepared by said method
JP5110227B2 (ja) * 2011-01-31 2012-12-26 東レ株式会社 水処理用分離膜およびその製造方法
KR101240956B1 (ko) 2011-02-18 2013-03-11 웅진케미칼 주식회사 내오염성능이 우수한 역삼투 복합막 및 그의 제조방법
CN103764264B (zh) 2011-08-31 2016-11-16 陶氏环球技术有限责任公司 源自包含胺反应性官能团和含磷官能团的单体的复合聚酰胺膜
WO2013048764A1 (fr) 2011-09-29 2013-04-04 Dow Global Technologies Llc Procédé pour préparer un composé halogénure d'acyle monohydrolysé de haute pureté
GB201117950D0 (en) 2011-10-18 2011-11-30 Imp Innovations Ltd Membranes for separation
WO2013103666A1 (fr) 2012-01-06 2013-07-11 Dow Global Technologies Llc Membrane polyamide composite
US9610542B2 (en) 2012-07-19 2017-04-04 Dow Global Technologies Llc Composite polyamide membrane with increased carboxylic acid functionality
US9056284B2 (en) 2012-08-10 2015-06-16 The United States Of America, As Represented By The Secretary Of The Interior Chlorine resistant amides, polyamides, and membranes made from the same
CN104918687A (zh) 2013-01-14 2015-09-16 陶氏环球技术有限责任公司 使用非极性溶剂的掺合物经由界面聚合制造复合聚酰胺膜
US9895666B2 (en) 2013-01-14 2018-02-20 Dow Global Technologies Llc Composite polyamide membrane made using substituted benzamide monomer
US9051227B2 (en) 2013-03-16 2015-06-09 Dow Global Technologies Llc In-situ method for preparing hydrolyzed acyl halide compound
US9289729B2 (en) 2013-03-16 2016-03-22 Dow Global Technologies Llc Composite polyamide membrane derived from carboxylic acid containing acyl halide monomer
US9051417B2 (en) 2013-03-16 2015-06-09 Dow Global Technologies Llc Method for solubilizing carboxylic acid-containing compound in hydrocarbon solvent
CN105163837B (zh) 2013-05-03 2017-05-10 陶氏环球技术有限责任公司 衍生自脂肪族非环状叔胺化合物的复合聚酰胺膜
EP3077089B1 (fr) 2013-12-02 2018-02-28 Dow Global Technologies LLC Procede de fabrication d'une membrane polyamide composite traitée au moyen de composés de dihydroxyaryle et d'acide nitreux
EP3077088B1 (fr) 2013-12-02 2017-12-27 Dow Global Technologies LLC Methode de fabrication d'une membrane de polyamide composite post-traitée avec de l'acide nitreux
KR102289354B1 (ko) 2014-01-09 2021-08-12 다우 글로벌 테크놀로지스 엘엘씨 높은 산 함량 및 낮은 아조 함량을 갖는 복합 폴리아미드 막
CN105899283A (zh) 2014-01-09 2016-08-24 陶氏环球技术有限责任公司 具有偶氮含量和高酸含量的复合聚酰胺膜
CN105848765B (zh) 2014-01-09 2020-02-14 陶氏环球技术有限责任公司 具有优选偶氮含量的复合聚酰胺膜
CN103846014B (zh) * 2014-01-24 2016-02-17 北京碧水源膜科技有限公司 一种低压高通量反渗透膜的制备方法
GB201403432D0 (en) 2014-02-27 2014-04-16 Univ Leuven Kath Improved method for synthesis of composite membranes
JP2017513703A (ja) 2014-04-28 2017-06-01 ダウ グローバル テクノロジーズ エルエルシー 亜硝酸で後処理される複合ポリアミド膜
US9943810B2 (en) 2014-05-14 2018-04-17 Dow Global Technologies Llc Composite polyamide membrane post-treated with nitrous acid
CN104128102B (zh) * 2014-08-04 2016-03-09 郑州大学 一种环糊精改性复合有机溶剂纳滤膜及其制备方法
GB201509794D0 (en) 2015-06-05 2015-07-22 Univ Leuven Kath Method for preparing an assymetric membrane
US9861940B2 (en) 2015-08-31 2018-01-09 Lg Baboh2O, Inc. Additives for salt rejection enhancement of a membrane
CN106621829A (zh) * 2015-10-28 2017-05-10 中国石油化工股份有限公司 一种制备复合反渗透膜的方法及复合反渗透膜
CN105396471A (zh) * 2015-12-19 2016-03-16 杭州水处理技术研究开发中心有限公司 一种高水通量反渗透膜的制备方法
US9737859B2 (en) 2016-01-11 2017-08-22 Lg Nanoh2O, Inc. Process for improved water flux through a TFC membrane
US10155203B2 (en) 2016-03-03 2018-12-18 Lg Nanoh2O, Inc. Methods of enhancing water flux of a TFC membrane using oxidizing and reducing agents
US11148102B2 (en) * 2017-04-19 2021-10-19 The University Of Hong Kong Thin film composite membrane with nano-sized bubbles having enhanced membrane permeability, preparation methods and uses thereof
GB202005106D0 (en) 2020-04-07 2020-05-20 Imperial College Innovations Ltd Novel membranes and preparations thereof
EP4142921A1 (fr) 2020-04-28 2023-03-08 Katholieke Universiteit Leuven, KU Leuven R&D Membranes composites à couche mince, synthétisées par des procédés de revêtement en plusieurs étapes
CN112892233B (zh) * 2021-02-04 2022-03-18 浙江美易膜科技有限公司 耐氧化聚酯复合膜及其制备方法
CN114100381B (zh) * 2021-12-17 2024-07-12 启成(江苏)净化科技有限公司 一种高通量反渗透膜的制备方法
WO2024105106A1 (fr) 2022-11-15 2024-05-23 Katholieke Universiteit Leuven Membranes composites à film mince de polyamine aliphatique fabriquées par polymérisation interfaciale

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5443882A (en) * 1977-09-14 1979-04-06 Nippon Zeon Co Ltd Preparation of semipermeable membrane
US4277344A (en) * 1979-02-22 1981-07-07 Filmtec Corporation Interfacially synthesized reverse osmosis membrane
US4520044A (en) * 1984-07-30 1985-05-28 E. I. Du Pont De Nemours And Company Production of composite membranes
US4772394A (en) * 1984-12-26 1988-09-20 Uop Inc. Chlorine-resistant semipermeable membranes
US4661254A (en) * 1985-05-23 1987-04-28 Uop Inc. Chlorine-resistant semipermeable membranes
US4792404A (en) * 1988-03-28 1988-12-20 Allied-Signal Inc. Desalination of saline water
US4802984A (en) * 1988-05-04 1989-02-07 Ionics, Incorporated Composite semipermeable membrane

Also Published As

Publication number Publication date
NZ234346A (en) 1992-01-29
CA2063787C (fr) 2000-05-23
EP0489746B1 (fr) 1993-07-07
ES2043384T3 (es) 1993-12-16
ATE91242T1 (de) 1993-07-15
AU631912B2 (en) 1992-12-10
CN1028609C (zh) 1995-05-31
KR920703190A (ko) 1992-12-17
EP0489746A1 (fr) 1992-06-17
JPH04507216A (ja) 1992-12-17
JP2947291B2 (ja) 1999-09-13
DK0489746T3 (da) 1993-08-30
US4950404B1 (fr) 1991-10-01
AU6078990A (en) 1991-04-08
US4950404A (en) 1990-08-21
WO1991003311A1 (fr) 1991-03-21
KR0143548B1 (ko) 1998-07-15
DE69002165D1 (de) 1993-08-12
DE69002165T2 (de) 1993-10-14
CN1049799A (zh) 1991-03-13

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