US20080258356A1 - Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, and preform for making it - Google Patents
Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, and preform for making it Download PDFInfo
- Publication number
- US20080258356A1 US20080258356A1 US11/785,749 US78574907A US2008258356A1 US 20080258356 A1 US20080258356 A1 US 20080258356A1 US 78574907 A US78574907 A US 78574907A US 2008258356 A1 US2008258356 A1 US 2008258356A1
- Authority
- US
- United States
- Prior art keywords
- preform
- blow
- moulding
- layer
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000654 additive Substances 0.000 title claims abstract description 30
- 238000000071 blow moulding Methods 0.000 claims abstract description 47
- 230000000996 additive effect Effects 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 15
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 6
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 5
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- -1 PGAc Substances 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229910003460 diamond Inorganic materials 0.000 claims description 3
- 239000010432 diamond Substances 0.000 claims description 3
- 239000012954 diazonium Substances 0.000 claims description 3
- 150000001989 diazonium salts Chemical class 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 125000005537 sulfoxonium group Chemical group 0.000 claims description 3
- 229920001903 high density polyethylene Polymers 0.000 claims 2
- 239000004700 high-density polyethylene Substances 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 239000010410 layer Substances 0.000 description 113
- 238000004519 manufacturing process Methods 0.000 description 16
- 230000032798 delamination Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920006020 amorphous polyamide Polymers 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- VMJFYMAHEGJHFH-UHFFFAOYSA-M triphenylsulfanium;bromide Chemical compound [Br-].C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 VMJFYMAHEGJHFH-UHFFFAOYSA-M 0.000 description 1
Images
Classifications
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- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/22—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
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- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
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- B29C49/06—Injection blow-moulding
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- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
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- B65D23/02—Linings or internal coatings
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- B65D83/00—Containers or packages with special means for dispensing contents
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- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B29C2035/0822—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using IR radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/04—Polyesters derived from hydroxycarboxylic acids
- B29K2067/046—PLA, i.e. polylactic acid or polylactide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0032—Pigments, colouring agents or opacifiyng agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0047—Agents changing thermal characteristics
- B29K2105/005—Heat sensitisers or absorbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/258—Tubular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Definitions
- the present invention relates in general to new developments in dispensing bag-in-containers and, in particular, to integrally blow-moulded bag-in-containers made of different materials. It also relates to a method for producing the bag-in-containers and, in particular, to preforms used for their production, as well as a method for producing said preform.
- Bag-in-containers also referred to as bag-in-bottles or bag-in-boxes depending on the geometry of the outer vessel, all terms considered herein as being comprised within the meaning of the term bag-in-container, are a family of liquid dispensing packaging consisting of an outer container comprising an opening to the atmosphere—the mouth—and which contains a collapsible inner bag joined to said container and opening to the atmosphere at the region of said mouth.
- the system must comprise at least one vent fluidly connecting the atmosphere to the region between the inner bag and the outer container in order to control the pressure in said region to squeeze the inner bag and thus dispense the liquid contained therein.
- bag-in-containers were—and still are—produced by independently producing an inner bag provided with a specific neck closure assembly and a structural container (usually in the form of a bottle). The bag is inserted into the fully formed bottle opening and fixed thereto by means of the neck closure assembly, which comprises one opening to the interior of the bag and vents fluidly connecting the space between bag and bottle to the atmosphere. Examples of such constructions can be found inter alia in U.S. Pat. No. 3,484,011, U.S. Pat. No. 3,450,254, U.S. Pat. No. 4,330,066, and U.S. Pat. No. 4,892,230. These types of bag-in-containers have the advantage of being reusable, but they are very expensive and labour-intensive to produce.
- the multilayer preform may be extruded or injection moulded (cf. U.S. Pat. No. 6,238,201, JPA-10128833, JPA11010719, JPA9208688, U.S. Pat. No. 6,649,121.
- the former method is advantageous in terms of productivity, the latter is preferable when wall thickness accuracy is required, typically in containers for dispensing beverage.
- 6,238,201 a method is described including co-extruding a two layer parison followed by blow-moulding said parison into a bag-in-container wherein the outer layer preferably comprises an olefin and the inner layer an amorphous polyamide.
- the heating rate of the two layers can be substantially different due to the wide difference in thicknesses between the inner and outer layers.
- the inner layer is sheltered by the thick, outer layer from the IR-radiation of the IR-oven usually used to bring the preform to blow-moulding temperature. It follows that even for materials having little or no difference in blow-moulding temperature, there can be a problem to heat up simultaneously both layers to their process temperatures.
- the different preform components may be heated separately in different ovens to heat them at their respective blow-moulding temperature (cf. e.g., JPA57174221).
- This solution is expensive in terms of equipment and space and does not apply to integral preforms, which inner and outer layers cannot be separated.
- blow-moulded co-layer containers i.e., not meant to delaminate
- energy absorbing additives has also been proposed in the inner layer of blow-moulded co-layer containers (i.e., not meant to delaminate) to compensate for the greater strain undergone by the inner layer compared with the outer layer during blow-moulding operation.
- co-layer containers it is very important that the inner layer is allowed to stretch sufficiently to contact and adhere to the outer layer over substantially the whole of their interface.
- the inner layer containing the energy absorbing additives is thus heated to a higher temperature than the outer layer and can be stretched further to adhere to the outer layer.
- a bag-in-container is comprised of an outer structural envelope containing a flexible, collapsible bag. It follows that the outer layer of the container is substantially thicker than the inner bag. This same relationship can of course be found in the preforms as well, which are characterized by an outer layer being substantially thicker than the inner layer. This has a detrimental effect on the heating efficacy of IR-lamps on heating the inner layer, since the latter is separated from the IR-lamps by the thick wall of the outer layer.
- the present invention relates to a preform for blow-moulding a bag-in-container.
- An inner layer and an outer layer are used, wherein said preform forms a two layer container upon blow-moulding, and wherein the obtained inner layer of the container releases from the thus obtained outer layer upon introduction of a gas at a point of interface between said two layers.
- At least one of the inner and outer layers includes at least one additive allowing both inner and outer layers to reach their respective blow-moulding temperatures substantially simultaneously when heated together in a single oven.
- the present invention relates to the use of energy absorbing additives for the substantially simultaneous heating to the respective blow-moulding temperatures of the inner and outer layers of a preform for blow-moulding a bag-in-container.
- FIG. 1A is a schematic cross-sectional representation of a first embodiment of a preform according to the present invention and the bag-in-container obtained after blow-moulding thereof.
- FIG. 1B is a schematic cross-sectional representation of a second embodiment of a preform according to the present invention and the bag-in-container obtained after blow-moulding thereof.
- FIGS. 1A and 1B there is illustrated an integrally blow-moulded bag-in-container ( 2 ) and a preform ( 1 )&( 1 ′) for its manufacturing.
- the preform ( 1 ) comprises an inner layer ( 11 ) and an outer layer ( 12 ) joined at least at the level of the neck region ( 6 ) by an interface (shown on the right hand side).
- the region between inner and outer layers ( 11 ) and ( 12 ) may either consist of an interface ( 14 ) wherein the two layers are substantially contacting each other, or comprise a gap ( 14 ′) in fluid communication with at least one vent ( 3 ) opening to the atmosphere in ( 4 ).
- vent geometries have been disclosed, and it is not critical which geometry is selected. It is preferred, however, that the vent be located adjacent to, and oriented coaxially with said preform's mouth ( 5 ) as illustrated in FIG. 1 . More preferably, the vents have the shape of a wedge with the broad side at the level of the opening ( 4 ) thereof and getting thinner as it penetrates deeper into the vessel, until the two layers meet to form an interface ( 14 ) at least at the level of the neck region.
- This geometry allows for a more efficient and reproducible delamination of the inner bag upon use of the bag-in-container.
- the container may comprise one or several vents evenly distributed around the lip of the bag-in-container's mouth.
- vents are advantageous as they permit the interface of the inner and outer layers ( 21 ) and ( 22 ) of the bag-in-container ( 2 ) to release more evenly upon blowing pressurized gas through said vents.
- the preform comprises two vents opening at the vessel's mouth lip at diametrically opposed positions. More preferably, three, and most preferably, at least four vents open at regular intervals of the mouth lip.
- the preform may consists of an assembly of two separate preforms ( 11 ) and ( 12 ) produced independently from one another and thereafter assembled such that the inner preform ( 11 ) fits into the outer preform ( 12 ).
- This solution allows for greater freedom in the design of the neck and vents.
- it can be an integral preform obtained by injection moulding one layer on top of the other.
- the latter embodiment is advantageous over the assembled preform in that it comprises no assembly step and one production station only is required for the preform fabrication.
- the design of the vents in particular is restricted by this process.
- a preform for the production of a typical 8 liter bag-in-container for dispensing beer has an outer layer ( 12 ) about 210 mm thick, preferably 36 mm, most preferably 45 mm thick, whilst the inner layer generally is about 0.33 mm thick, preferably 0.31.5 mm, most preferably 0.51 mm thick
- Preferred materials for the inner and outer layers of the preform and bag-in-container of the present invention are pairs of different materials selected from the group of polyesters like PET, PEN, PTT, PTN; polyamides like PA6, PA66, PA11, PA12; polyolefins like PE, PP; EVOH; biodegradable polymers like polyglycol acetate (PGAc), polylactic acid (PLA); and copolymers and blends thereof.
- Materials like PET or PEN should optimally be heated before blow-moulding, whilst polyolefins and polyamides should be heated.
- energy absorbing additives are added to the resin having highest process temperature. It is, however, also possible that both layers comprise energy absorbing additives of different nature and/or in different amounts, as long as the time required to arrive at the respective process temperatures of the materials of the inner and outer layers is substantially the same.
- the additives useful in the present invention may be any compound that selectively absorbs radiation in the wavelength region of 500 to 2000 nm and which is preferably sufficiently fine not to be visible to the eye. They comprise energy absorbing additives and colorants. Examples of energy absorbing additives include but are not limited to carbon black, graphite, diamond dust, diazonium salts, sulphonium salts (e.g., triphenylsulphonium bromide), sulfoxonium salts, odonium salts, etc.
- the amount of additive present in a layer depends on the additive itself and on the resins used for the inner and outer layers. A larger amount may impair stretchability of the layers.
- the two layers ( 11 ) and ( 12 ) of the preform may be connected by an interface ( 14 ) throughout substantially the whole inner surface of the outer layer. Inversely, they may be separated over a substantial area of the preform's body by a gap ( 14 ) containing air and which is in fluid communication with at least one interface vent ( 3 ).
- the latter embodiment is easier to realize when using a preform assembly designed such that the inner preform is firmly fixed to the outer preform at the neck region ( 6 ) and a substantial gap ( 14 ) may thus be formed between inner and outer layers ( 11 ) and ( 12 ).
- the bag-in-container ( 2 ) of the present invention can be obtained by providing a preform as described above, at least one layer of which comprising energy absorbing additives; bringing each layer of said preform to their respective blow-moulding temperatures; fixing the thus heated preform at the level of the neck region with fixing means in the blow-moulding tool; and blow-moulding the thus heated preform to form a bag-in-container, wherein, the type and amount of energy absorbing additives comprised in at least one of the inner and outer layers of said preform are such that said two layers reach their respective blow-moulding temperatures substantially simultaneously.
- the inner and outer layers ( 21 ) and ( 22 ) of the thus obtained bag-in-container are connected to one another by an interface ( 24 ) over substantially the whole of the inner surface of the outer layer.
- Said interface ( 24 ) is in fluid communication with the atmosphere through the vents ( 3 ), which maintained their original geometry through the blow-moulding process since the neck region of the preform where the vents are located is held firm by the fixing means and is not stretched during blowing.
- the interface ( 24 ) between inner and outer layers ( 21 ) and ( 22 ) releases upon blowing pressurized gas through the vents in a consistent and reproducible manner.
- the success of said operation depends on a number of parameters, in particular, on the interfacial adhesive strength, the number, geometry, and distribution of the vents, and on the pressure of the gas injected.
- the interfacial strength is of course a key issue and can be modulated by the choice of the material for the inner and outer layers, and by the process parameters during blow-moulding.
- the pressure-time-temperature window used is of course of prime importance and greatly depends on the materials selected for the inner and outer layers.
- the inner layer is prevented from entering into contact with the outer layer by the air cushion enclosed within the gap separating the two layers when their respective temperatures are the highest.
- the gap becomes thinner and air pressure within the gap increases.
- the valve closing the vent opening releases, the air is ejected, and the inner layer is permitted to contact the outer layer and form an interface therewith at a stage where their respective temperatures have dropped to a level where adhesion between the layers cannot build up to any substantial level.
- Preforms comprising an inner and outer layers made of different materials were heated in an oven comprising six IR lamps. The heating conditions were maintained constant for all the tests. The temperatures, T inner and T outer , of the inner and outer layers were measured after residence in the oven and the preforms were then blow-moulded with a blow pressure of 10 bar in a mould set a temperature of 83° C. Table 1 below lists the measured temperatures of the inner and outer layers, comments on blow-mouldability, and indicates the values of the delamination pressure.
- the delamination pressure was determined as follows. The interface vents of an empty bag-in-container obtained as described above are connected to a source of pressurized air. Air is injected through the vents at a constant pressure and the interface between inner and outer layers is observed; the pressure is increased until delamination pressure is reached. Delamination pressure is defined as the pressure at which the inner bag separates from the outer layer over the whole of their interface and collapses. The surfaces of the thus separated layers are examined for traces of bonding. Preferred results are a low delamination pressure, of the order of above 0.3 to 0.9 bar overpressure, with no traces of bonding.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Electromagnetism (AREA)
- Toxicology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Geometry (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Priority Applications (23)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/785,749 US20080258356A1 (en) | 2007-04-19 | 2007-04-19 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, and preform for making it |
BRPI0810420-4A BRPI0810420B1 (pt) | 2007-04-19 | 2008-04-18 | Pré-forma para moldar por sopro um saco dentro de recipiente, processo por produzir um saco dentro de recipiente, saco em recipiente feito pelo processo e uso de aditivos ou colorantes absorventes de energia |
US12/450,893 US9555572B2 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energyabsorbing additives, preform for making it and process for producing it |
ES08736402T ES2371224T3 (es) | 2007-04-19 | 2008-04-18 | Bolsa en caja íntegramente moldeada a soplo que comprende una capa interior y una capa exterior que comprenden aditivos absorbentes de energía, preforma para su fabricación, procedimiento para su producción y uso de la misma. |
UAA200910386A UA95670C2 (ru) | 2007-04-19 | 2008-04-18 | Сформированный раздувом как единое целое "баллон в контейнере", включающий внутренний и внешний слои, который содержит поглощающие энергию добавки, преформа для его изготовления и процесс его изготовления и процесс его изготовления |
RU2009142610/05A RU2463159C2 (ru) | 2007-04-19 | 2008-04-18 | Составная упаковка "bag-in-container", изготовленная способом выдувного формования, состоящая из внутреннего слоя и слоя, содержащего энергопоглощающие присадки; преформа для ее изготовления и способ для ее производства |
DK08736402.2T DK2152486T3 (da) | 2007-04-19 | 2008-04-18 | Blæsestøbt pose-i-beholder i ét stykke, der omfatter et indvendigt lag og et udvendigt lag, der indeholder energiabsorberende tilsætningsstoffer, forform til fremstilling af denne og anvendelse |
KR1020097022327A KR101538323B1 (ko) | 2007-04-19 | 2008-04-18 | 에너지 흡수 첨가제를 함유하는 내층과 외층을 포함하는 일체형으로 블로우 성형된 백-인-컨테이너, 이를 생산하기 위한 프리폼 및 이의 생산방법 |
MEP-2009-312A ME00943B (me) | 2007-04-19 | 2008-04-18 | Integralni duvanjem oblikovan kontejner sa vrećicom koji obuhvata jedan unutrašnji sloj i jedan spoljni sloj koji sadrži aditive koji apsorbuju energiju, predforma za njegovu izradu i postupak za njegovu proizvodnju |
RS20110430A RS52122B (en) | 2007-04-19 | 2008-04-18 | PACKAGING WITH AN INTERIOR BAG INTEGRALLY DESIGNED TOBACCO, CONTAINING AN INTERIOR AND EXTERIOR, INCLUDING ADDITIONAL PARTS FOR THE ABSORPTION OF THE ENERGY |
AU2008240746A AU2008240746B2 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag- in- container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
AT08736402T ATE523307T1 (de) | 2007-04-19 | 2008-04-18 | Integral blasgeformter bag-in-container mit einer innenschicht und einer aussenschicht mit energieabsorbierenden additiven, vorformling zu dessen herstellung, herstellungsverfahren dafür sowie verwendung |
EP08736402A EP2152486B1 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag- in- container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it, process for producing it and use |
NZ580023A NZ580023A (en) | 2007-04-19 | 2008-04-18 | Preform for bag in container with additive in one of inner or outer layers to enable layers to reach blow moulding temperatures simultaneously |
CA2681834A CA2681834C (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag-in-container comprising an inner layer and an layer comprising energy absorbing additives, preform for making it and process for producing it |
PCT/EP2008/054766 WO2008129013A1 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag- in- container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
CN200880012731.0A CN101663144B (zh) | 2007-04-19 | 2008-04-18 | 包括含能量吸收添加剂的内层和外层的一体吹塑内装袋容器、用于制造该内装袋容器的预制坯、以及用于生产出该内装袋容器的方法 |
ARP080101650A AR062904A1 (es) | 2007-04-19 | 2008-04-21 | Contenedor con bolsa interior moldeado integralmente por soplado , que tiene una capa interior y una capa exterior que contienen aditivos absorbentes de energia y preforma para su fabricacion |
HR20110772T HRP20110772T1 (hr) | 2007-04-19 | 2011-10-24 | Posuda s vrećicom unutar nje sa unutarnjim slojem i vanjskim slojem koji sadrže aditive koji upijaju energiju, predsklop za njenu izradu, postupak njene izrade i korištenja |
US15/419,098 US10668659B2 (en) | 2007-04-19 | 2017-01-30 | Integrally blow-moulded bag-in-container comprising an inner layer ad an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US16/889,566 US20210114280A1 (en) | 2007-04-19 | 2020-06-01 | Integrally Blow-Moulded Bag-in-Container Comprising an Inner Layer and an Outer Layer Comprising Energy Absorbing Additives, Preform for Making It and Process for Producing it |
US17/735,051 US11752683B2 (en) | 2007-04-19 | 2022-05-02 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US18/353,014 US20230364848A1 (en) | 2007-04-19 | 2023-07-14 | Integrally blow-moulded bag-in-container comprising an inner layer and an layer comprising energy absorbing additives, preform for making it and process for producing it |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/785,749 US20080258356A1 (en) | 2007-04-19 | 2007-04-19 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, and preform for making it |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2008/054766 Continuation-In-Part WO2008129013A1 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag- in- container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US12/450,893 Continuation-In-Part US9555572B2 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energyabsorbing additives, preform for making it and process for producing it |
Publications (1)
Publication Number | Publication Date |
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US20080258356A1 true US20080258356A1 (en) | 2008-10-23 |
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US11/785,749 Abandoned US20080258356A1 (en) | 2007-04-19 | 2007-04-19 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, and preform for making it |
US12/450,893 Active 2031-02-07 US9555572B2 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energyabsorbing additives, preform for making it and process for producing it |
US15/419,098 Active 2028-06-28 US10668659B2 (en) | 2007-04-19 | 2017-01-30 | Integrally blow-moulded bag-in-container comprising an inner layer ad an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US16/889,566 Abandoned US20210114280A1 (en) | 2007-04-19 | 2020-06-01 | Integrally Blow-Moulded Bag-in-Container Comprising an Inner Layer and an Outer Layer Comprising Energy Absorbing Additives, Preform for Making It and Process for Producing it |
US17/735,051 Active US11752683B2 (en) | 2007-04-19 | 2022-05-02 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US18/353,014 Pending US20230364848A1 (en) | 2007-04-19 | 2023-07-14 | Integrally blow-moulded bag-in-container comprising an inner layer and an layer comprising energy absorbing additives, preform for making it and process for producing it |
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Application Number | Title | Priority Date | Filing Date |
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US12/450,893 Active 2031-02-07 US9555572B2 (en) | 2007-04-19 | 2008-04-18 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energyabsorbing additives, preform for making it and process for producing it |
US15/419,098 Active 2028-06-28 US10668659B2 (en) | 2007-04-19 | 2017-01-30 | Integrally blow-moulded bag-in-container comprising an inner layer ad an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US16/889,566 Abandoned US20210114280A1 (en) | 2007-04-19 | 2020-06-01 | Integrally Blow-Moulded Bag-in-Container Comprising an Inner Layer and an Outer Layer Comprising Energy Absorbing Additives, Preform for Making It and Process for Producing it |
US17/735,051 Active US11752683B2 (en) | 2007-04-19 | 2022-05-02 | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, preform for making it and process for producing it |
US18/353,014 Pending US20230364848A1 (en) | 2007-04-19 | 2023-07-14 | Integrally blow-moulded bag-in-container comprising an inner layer and an layer comprising energy absorbing additives, preform for making it and process for producing it |
Country Status (18)
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US (6) | US20080258356A1 (es) |
EP (1) | EP2152486B1 (es) |
KR (1) | KR101538323B1 (es) |
CN (1) | CN101663144B (es) |
AR (1) | AR062904A1 (es) |
AT (1) | ATE523307T1 (es) |
AU (1) | AU2008240746B2 (es) |
BR (1) | BRPI0810420B1 (es) |
CA (1) | CA2681834C (es) |
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- 2008-04-18 KR KR1020097022327A patent/KR101538323B1/ko active IP Right Grant
- 2008-04-18 ME MEP-2009-312A patent/ME00943B/me unknown
- 2008-04-18 RU RU2009142610/05A patent/RU2463159C2/ru active
- 2008-04-18 US US12/450,893 patent/US9555572B2/en active Active
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Also Published As
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US20210114280A1 (en) | 2021-04-22 |
WO2008129013A1 (en) | 2008-10-30 |
CA2681834C (en) | 2016-05-24 |
US20100227089A1 (en) | 2010-09-09 |
AU2008240746B2 (en) | 2013-07-25 |
BRPI0810420B1 (pt) | 2018-03-27 |
US20230364848A1 (en) | 2023-11-16 |
ME00943B (me) | 2012-06-20 |
RU2009142610A (ru) | 2011-05-27 |
DK2152486T3 (da) | 2011-12-05 |
US11752683B2 (en) | 2023-09-12 |
RS52122B (en) | 2012-08-31 |
CA2681834A1 (en) | 2008-10-30 |
ES2371224T3 (es) | 2011-12-28 |
US20220266498A1 (en) | 2022-08-25 |
AR062904A1 (es) | 2008-12-17 |
US20170136679A1 (en) | 2017-05-18 |
EP2152486B1 (en) | 2011-09-07 |
KR20100015905A (ko) | 2010-02-12 |
EP2152486A1 (en) | 2010-02-17 |
KR101538323B1 (ko) | 2015-07-22 |
CN101663144A (zh) | 2010-03-03 |
RU2463159C2 (ru) | 2012-10-10 |
US10668659B2 (en) | 2020-06-02 |
HRP20110772T1 (hr) | 2011-12-31 |
UA95670C2 (ru) | 2011-08-25 |
US9555572B2 (en) | 2017-01-31 |
NZ580023A (en) | 2012-06-29 |
BRPI0810420A2 (pt) | 2014-10-14 |
AU2008240746A1 (en) | 2008-10-30 |
CN101663144B (zh) | 2014-11-19 |
ATE523307T1 (de) | 2011-09-15 |
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