US20060134032A1 - Nail varnish composition comprising a sequenced polymer - Google Patents
Nail varnish composition comprising a sequenced polymer Download PDFInfo
- Publication number
- US20060134032A1 US20060134032A1 US10/528,699 US52869905A US2006134032A1 US 20060134032 A1 US20060134032 A1 US 20060134032A1 US 52869905 A US52869905 A US 52869905A US 2006134032 A1 US2006134032 A1 US 2006134032A1
- Authority
- US
- United States
- Prior art keywords
- equal
- composition according
- block
- monomers
- glass transition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 [7*]N([8*])C(=O)C(=C)C Chemical compound [7*]N([8*])C(=O)C(=C)C 0.000 description 5
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Definitions
- the present invention relates to a nail varnish free from nitrocellulose comprising a block polymer.
- the invention also relates to a makeup or care process for the nails. These compositions may be applied to human nails or to false nails.
- compositions to be applied to the nails usually comprise at least one film-forming polymer, optionally plasticizer, pigments, rheological agents and solvents.
- Nitrocellulose is a film-forming agent commonly used in solvent-based nail varnishes to obtain glossy compositions with good strength.
- Nitrocellulose is a polymer consisting of an assembly of partially nitrated anhydroglucose rings obtained by esterification of some of the free hydroxyl functions of a cellulose with nitric acid in the presence of sulfuric acid.
- nitrocellulose is still the main film-forming agent the most widely used in solvent-based nail varnishes in formulations with optimized gloss and strength.
- nitrocellulose Certain known formulations comprising nitrocellulose have the drawback of yellowing on the nail over time.
- manufacture of nitrocellulose, its transportation and its incorporation into formulations pose safety problems which are such that it is sought to replace it with other film-forming agents.
- Patent application US 2002/18759 describes an acrylic acid/butyl methacrylate copolymer as film-forming polymer for partially replacing nitrocellulose. Nail varnishes containing this polymer do not show sufficient strength and in particular sufficient gloss strength, and require the addition of plasticizers.
- the Applicant has discovered a novel route for formulating a nitrocellulose-free nail varnish that has good gloss and strength properties.
- This nail varnish also makes it possible to obtain plasticization of films without the need to add large amounts of external plasticizers, while at the same time maintaining a good level of hardness of the films and good impact strength and/or chip strength of the varnishes on the nail, and thus an improvement in the strength over time of the varnishes on the nail and/or in their wear resistance.
- One subject of the invention is, more specifically, a nail varnish composition
- a nail varnish composition comprising, in a cosmetically acceptable organic solvent, at least one linear ethylenic film-forming block polymer, the said composition being free of nitrocellulose, the block polymer being such that, when it is present in sufficient amount in the composition, the mean gloss at 20° of a deposit of the said composition, once spread onto a support, is greater than or equal to 50 out of 100.
- a subject of the invention is also a nail varnish composition
- a nail varnish composition comprising, in a cosmetically acceptable medium, at least one linear block ethylenic film-forming polymer as described below, the said composition being free of nitrocellulose.
- nitrocellulose means any nitrated cellulose derivative, in particular nitrocellulose.
- film-forming polymer means a polymer that is capable of forming, by itself or in the presence of an auxiliary film-forming agent, a continuous film that adheres to a support, and especially to keratin materials.
- nitrocellulose-free composition means a composition containing less than 5%, preferably less than 3%, preferably less than 2%, preferably less than 1%, preferably less than 0.5%, preferably less than 0.1% and preferably less than 0.05% of nitrocellulose.
- a subject of the invention is also a non-therapeutic cosmetic process for making up or caring for the nails, comprising the application to the nails of at least one coat of the nail varnish composition as defined above.
- a subject of the invention is also a nail varnish composition
- a nail varnish composition comprising at least one film-forming linear ethylenic block polymer, the said composition being free of nitrocellulose, to obtain a film, once spread onto a support, which has a gloss at 200 of greater than 50 out of 100, and which incidentally has good strength.
- gloss means the gloss as may be conventionally measured using a glossmeter by the following method.
- a coat of between 50 ⁇ m and 150 ⁇ m in thickness of the composition is spread using an automatic spreader onto a Leneta brand contrast card of reference Form 1A Penopac.
- the coat covers at least the white background of the card.
- the deposit is left to dry for 24 hours at a temperature of 30° C., and the gloss at 20° is then measured on the white background using a Byk Gardner brand glossmeter of reference microTri-Gloss.
- This measurement (between 0 and 100) is repeated at least three times, and the mean gloss is the mean of the at least three measurements taken.
- the mean gloss of the composition measured at 20° is advantageously greater than or equal to 50 out of 100, better still greater than or equal to 55, even better still greater than or equal to 60, even better still greater than or equal to 65, even better still greater than or equal to 70 or even better still greater than or equal to 75 out of 100, or even greater than or equal to 80 out of 100.
- the mean gloss of the composition, once spread onto a support, measured at 60° is greater than or equal to 50, better still greater than or equal to 60, better still greater than or equal to 65, better still greater than or equal to 70, better still greater than or equal to 75, better still greater than or equal to 80, better still greater than or equal to 85 or better still greater than or equal to 90 out of 100.
- the mean gloss at 60° is measured as follows.
- the gloss may be conventially measured using a glossmeter by the following method.
- a coat of between 50 ⁇ m and 150 ⁇ m in thickness of the composition is spread using an automatic spreader onto a Leneta brand contrast card of reference Form 1A Penopac.
- the coat covers at least the white background of the card.
- the deposit is left to dry for 24 hours at a temperature of 30° C., and the gloss at 60° is then measured on the white background using a Byk Gardner brand glossmeter of reference microTri-Gloss.
- This measurement (between 0 and 100) is repeated at least three times, and the mean gloss is the mean of the at least three measurements taken.
- the gloss of the composition measured at 20° is preferably greater than or equal to 60, preferably 65, 70 or 75 out of 100, and/or the gloss of the composition measured at 60° is preferably greater than or equal to 80, 85 or 90 out of 100.
- composition according to the present invention contains at least one block polymer.
- block polymer means a polymer comprising at least two different blocks and preferably at least three different blocks.
- the block polymer of the composition according to the invention is an ethylenic polymer.
- ethylenic polymer means a polymer obtained by polymerization of ethylenically unsaturated monomers.
- the block polymer of the composition according to the invention is a linear polymer.
- a polymer of non-linear structure is, for example, a polymer of branched, starburst or grafted structure, or the like.
- the block polymer of the composition according to the invention is a film-forming polymer.
- film-forming polymer means a polymer that is capable of forming, by itself or in the presence of an auxiliary film-forming agent, a continuous film that adheres to a support and especially to keratin materials.
- the block polymer of the composition according to the invention is a non-elastomeric polymer.
- non-elastomeric polymer means a polymer which, when subjected to a stress intended to stretch it (for example by 30% relative to its initial length), does not return to a length substantially identical to its initial length when the stress is removed.
- non-elastomeric polymer means a polymer with an instantaneous recovery R i ⁇ 50% and a delayed recovery R 2h ⁇ 70% after having undergone a 30% elongation.
- R i is ⁇ 30%
- R 2h is ⁇ 50%.
- non-elastomeric nature of the polymer is determined according to the following protocol:
- a polymer film is prepared by pouring a solution of the polymer into a Teflon-coated mould followed by drying for 7 days under ambient conditions regulated to 23 ⁇ 5° C. and 50 ⁇ 10% relative humidity.
- a film about 100 ⁇ m thick is thus obtained, from which are cut rectangular specimens (for example using a punch) 15 mm wide and 80 mm long.
- This sample is subjected to a tensile stress using a machine sold under the reference Zwick, under the same temperature and humidity conditions as for the drying operation.
- the specimens are drawn at a speed of 50 mm/minute and the distance between the jaws is 50 mm, which corresponds to the initial length (l 0 ) of the specimen.
- the instantaneous recovery R i is determined in the following manner:
- R i (( ⁇ max ⁇ i )/ ⁇ max ) ⁇ 100
- the residual elongation of the sample is measured as a percentage ( ⁇ 2h ), 2 hours after returning to zero stress.
- R 2h (( ⁇ max ⁇ 2h )/ ⁇ max ) ⁇ 100
- a polymer according to an embodiment of the invention has an instantaneous recovery R i of 10% and a delayed recovery R 2h of 30%.
- the block polymer of the composition according to the invention does not comprise any styrene units.
- polymer free of styrene units means a polymer comprising less than 10%, preferably less than 5%, preferentially less than 2% and more preferentially less than 1% by weight i) of styrene units of formula —CH(C 6 H 5 )—CH 2 — or ii) of substituted styrene units, for instance methylstyrene, chlorostyrene or chloromethylstyrene.
- the block polymer of the composition according to the invention is derived from aliphatic ethylenic monomers.
- aliphatic monomer means a monomer comprising no aromatic groups.
- the block polymer is an ethylenic polymer derived from aliphatic ethylenic monomers comprising a carbon-carbon double bond and at least one ester group —COO— or amide group —CON—.
- the ester group may be linked to one of the two unsaturated carbons via the carbon atom or the oxygen atom.
- the amide group may be linked to one of the two unsaturated carbons via the carbon atom or the nitrogen atom.
- the block polymer comprises at least one first block and at least one second block.
- At least one block means one or more blocks.
- the block polymer comprises at least one first block and at least one second block that have different glass transition temperatures (Tg).
- first and second blocks may be linked together via an intermediate segment with a glass transition temperature between the glass transition temperatures of the first and second blocks.
- the block polymer comprises at least one first block and at least one second block linked together via an intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block.
- the intermediate block is derived essentially from constituent monomers of the first block and of the second block.
- the term “essentially” means at least 85%, preferably at least 90%, better still 95% and even better still 100%.
- the intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block of the polymer is a random polymer.
- the block polymer comprises at least one first block and at least one second block that are incompatible in the organic liquid medium of the composition of the invention.
- mutant blocks means that the mixture formed from the polymer corresponding to the first block and from the polymer corresponding to the second block is not miscible in the organic liquid that is in major amount by weight contained in the organic liquid medium of the composition, at room temperature (25° C.) and atmospheric pressure (10 5 Pa), for a content of the polymer mixture of greater than or equal to 5% by weight, relative to the total weight of the mixture (polymers and major organic liquid), it being understood that:
- the said polymers are present in the mixture in a content such that the respective weight ratio ranges from 10/90 to 90/10, and
- each of the polymers corresponding to the first and second blocks has an average (weight-average or number-average) molecular mass equal to that of the block polymer ⁇ 15%.
- the organic liquid medium comprises a mixture of organic liquids, in the case of two or more liquids present in identical mass proportions, the said polymer mixture is immiscible in at least one of them.
- the organic liquid medium comprises only one organic liquid
- this liquid obviously constitutes the liquid that is in major amount by weight.
- organic liquid medium means a medium containing at least one organic liquid, i.e. at least one organic compound that is liquid at room temperature (25° C.) and atmospheric pressure (10 5 Pa)
- the major liquid of the organic liquid medium is a volatile or non-volatile oil (fatty substance).
- the organic liquid is cosmetically acceptable (acceptable tolerance, toxicology and feel).
- the organic liquid medium is cosmetically acceptable, in the sense that it is compatible with keratin materials, for instance the oils or organic solvents commonly used in cosmetic compositions.
- the major liquid of the organic liquid medium is the polymerization solvent or one of the polymerization solvents of the block polymer, as are described below.
- polymerization solvent means a solvent or a mixture of solvents.
- the polymerization solvent may be chosen especially from ethyl acetate, butyl acetate, alcohols such as isopropanol and ethanol, aliphatic alkanes such as isododecane, and mixtures thereof.
- the polymerization solvent is a mixture of butyl acetate and isopropanol, or isododecane.
- the block polymer may be incorporated into the composition to a high solids content, typically greater than 10%, greater than 20%, more preferably greater than 30% and more preferentially greater than 45% by weight relative to the total weight of the composition, while at the same time being easy to formulate.
- the block polymer comprises no silicon atoms in its skeleton.
- skeleton means the main chain of the polymer, as opposed to the pendent side chains.
- the polymer according to the invention is not water-soluble, i.e. the polymer is not soluble in water or in a mixture of water and linear or branched lower monoalcohols containing from 2 to 5 carbon atoms, for instance ethanol, isopropanol or n-propanol, without pH modification, at an active material content of at least 1% by weight, at room temperature (25° C.).
- the block polymer has a polydispersity index I of greater than 2.
- the block polymer used in the. compoisitions according to the invention has a polydispersity index greater than 2, for example ranging from 2 to 9, preferably greater than or equal to 2.5, for example ranging from 2.5 to 8 and better still greater than or equal to 2.8 and especially ranging from 2.8 to 6.
- the polydispersity index I of the polymer is equal to the ratio of the weight-average mass Mw to the number-average mass Mn.
- the weight-average molar mass (Mw) and number-average molar mass (Mn) are determined by gel permeation liquid chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector).
- the weight-average mass (Mw) of the block polymer is preferably less than or equal to 300 000; it ranges, for example, from 35 000 to 200 000 and better still from 45 000 to 150 000.
- the number-average mass (Mn) of the block polymer is preferably less than or equal to 70 000; it ranges, for example, from 10 000 to 60 000 and better still from 12 000 to 50 000.
- Each block of the block polymer is derived from one type of monomer or from several different types of monomer.
- each block may consist of a homopolymer or a copolymer; this copolymer constituting the block may in turn be random or alternating.
- Tg values indicated for the first and second blocks in the present patent application are theoretical Tg values.
- the difference between the glass transition temperatures of the first and second blocks is generally greater than 10° C., preferably greater than 20° C. and better still greater than 30° C.
- the block polymer comprises at least one first block and at least one second block such that the first block may be chosen from:
- a block with a Tg of between 20 and 40° C. and the second block may be chosen from a category a), b) or c) that is different from the first block.
- the expression: “between . . . and . . . ” is intended to denote a range of values for which the limits mentioned are excluded, and “from . . . to . . . ” and “ranging from . . . to . . . ” are intended to denote a range of values for which the limits are included.
- the block with a Tg of greater than or equal to 40° C. has, for example, a Tg ranging from 40 to 150° C., preferably greater than or equal to 50° C., for example ranging from 50° C. to 120° C. and better still greater than or equal to 60° C., for example ranging from 60° C. to 120° C.
- the block with a Tg of greater than or equal to 40° C. may be a homopolymer or a copolymer.
- the block with a Tg of greater than or equal to 40° C. may be totally or partially derived from one or more monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40° C.
- this block is a homopolymer, it is derived from monomers which are such that the homopolymers prepared from these monomers have glass transition temperatures of greater than or equal to 40° C.
- This first block may be a homopolymer consisting of only one type of monomer (for which the Tg of the corresponding homopolymer is greater than or equal to 40° C.).
- the first block is a copolymer
- it may be totally or partially derived from one or more monomers, the nature and concentration of which are chosen such that the Tg of the resulting copolymer is greater than or equal to 40° C.
- the copolymer may comprise, for example:
- the monomers whose homopolymers have a glass transition temperature of greater than or equal to 40° C. are chosen, for example, from the following monomers, also known as the main monomers:
- Main monomers that are particularly preferred are methyl methacrylate, isobutyl (meth)acrylate and isobornyl (meth)acrylate, and mixtures thereof.
- the block with a Tg of less than or equal to 20° C. has, for example, a Tg ranging from ⁇ 100 to 20° C., preferably less than or equal to 15° C., especially ranging from ⁇ 80° C. to 15° C. and better still less than or equal to 10° C., for example ranging from ⁇ 50° C. to 0° C.
- the block with a Tg of less than or equal to 20° C. may be a homopolymer or a copolymer.
- the block with a Tg of less than or equal to 20° C. may be totally or partially derived from one or more monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20° C.
- this block is a homopolymer, it is derived from monomers which are such that the homopolymers prepared from these monomers have glass transition temperatures of less than or equal to 20° C.
- This second block may be a homopolymer consisting of only one type of monomer (for which the Tg of the corresponding homopolymer is less than or equal to 20° C.).
- the block with a Tg of less than or equal to 20° C. is a copolymer, it may be totally or partially derived from one or more monomers, the nature and concentration of which are chosen such that the Tg of the resulting copolymer is less than or equal to 20° C.
- It may comprise, for example
- the block with a Tg of less than or equal to 20° C. is a homopolymer.
- the monomers whose homopolymer has a Tg of less than or equal to 20° C. are preferably chosen from the following monomers, or main monomer:
- the main monomers that are particularly preferred for the block with a Tg of less than or equal to 20° C. are alkyl acrylates whose alkyl chain contains from 1 to 10 carbon atoms, with the exception of the tert-butyl group, such as methyl acrylate, isobutyl acrylate and 2-ethylhexyl acrylate, and mixtures thereof.
- the block with a Tg of between 20 and 40° C. may be a homopolymer or a copolymer.
- the block with a Tg of between 20 and 40° C. may be totally or partially derived from one or more monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of between 20 and 40° C.
- the block with a Tg of between 20 and 40° C. may be totally or partially derived from monomers which are such that the corresponding homopolymer has a Tg of greater than or equal to 40° C., and from monomers which are such that the corresponding homopolymer has a Tg of less than or equal to 20° C.
- this block is a homopolymer, it is derived from monomers (or main monomer) which are such that the homopolymers prepared from these monomers have glass transition temperatures of between 20 and 40° C.
- This first block may be a homopolymer, consisting of only one type of monomer (for which the Tg of the corresponding homopolymer ranges from 20° C. to 40° C.).
- the monomers whose homopolymer has a glass transition temperature of between 20 and 40° C. are preferably chosen from n-butyl methacrylate, cyclodecyl acrylate, neopentyl acrylate and isodecylacrylamide, and mixtures thereof.
- the block with a Tg of between 20 and 40° C. is a copolymer, it is totally or partially derived from one or more monomers (or main monomer) whose nature and concentration are chosen such that the Tg of the resulting copolymer is between 20 and 40° C.
- the block with a Tg of between 20 and 40° C. is a copolymer totally or partially derived from:
- Such main monomers are chosen, for example, from methyl methacrylate, isobornyl acrylate and methacrylate, butyl acrylate and 2-ethylhexyl acrylate, and mixtures thereof.
- the proportion of the second block with a Tg of less than or equal to 20° C. ranges from 10% to 85% by weight, better still from 20% to 70% and even better still from 20% to 50% by weight of the polymer.
- each of the first and second blocks comprises at least one monomer chosen from acrylic acid, acrylic acid esters, (meth)acrylic acid and (meth)acrylic acid esters, and mixtures thereof.
- each of the first and second blocks is totally derived from at least one monomer chosen from acrylic acid, acrylic acid esters, (meth)acrylic acid and (meth)acrylic acid esters, and mixtures thereof.
- each of the blocks may contain in small proportion at least one constituent monomer of the other block.
- the first block may contain at least one constituent monomer of the second block, and vice versa.
- Each of the first and/or second blocks may comprise, in addition to the monomers indicated above, one or more other monomers known as additional monomers, which are different from the main monomers mentioned above.
- This additional monomer is chosen, for example, from:
- hydrophilic monomers such as:
- acrylic acid methacrylic acid, crotonic acid, maleic anhydride, itaconic acid, fumaric acid, maleic acid, acrylamidopropanesulphonic acid, vinylbenzoic acid, vinylphosphoric acid, and salts thereof,
- R 6 represents a linear or branched alkyl group containing from 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, the said alkyl group being substituted with one or more substituents chosen from hydroxyl groups (for instance 2-hydroxypropyl methacrylate and 2-hydroxyethyl methacrylate) and halogen atoms (Cl, Br, I or F), such as trifluoroethyl methacrylate,
- R 9 representing a linear or branched C 6 to C 12 alkyl group in which one or more hetero atoms chosen from O, N and S is (are) optionally intercalated, the said alkyl group being substituted with one or more substituents chosen from hydroxyl groups and halogen atoms (Cl, Br, I or F);
- R 10 representing a linear or branched C 1 to C 12 alkyl group substituted with one or more substituents chosen from hydroxyl and halogen atoms (Cl, Br, I or F), such as 2-hydroxypropyl acrylate and 2-hydroxyethyl acrylate, or R 10 represents a (C 1 -C 12 ) alkyl-O-POE (polyoxyethylene) with repetition of the oxyethylene unit 5 to 30 times, for example methoxy-POE, or R 10 represents a polyoxyethylenated group comprising from 5 to 30 ethylene oxide units
- ethylenically unsaturated monomers comprising one or more silicon atoms, such as methacryloxypropyltrimethoxysilane and methacryloxypropyltris(trimethylsiloxy)silane,
- Additional monomers that are particularly preferred are acrylic acid, methacrylic acid and trifluoroethyl methacrylate, and mixtures thereof.
- each of the first and second blocks of the block polymer comprises at least one monomer chosen from (meth)acrylic acid esters and optionally at least one additional monomer such as (meth)acrylic acid, and mixtures thereof.
- each of the first and second blocks of the block polymer is totally derived from at least one monomer chosen from (meth)acrylic acid esters and optionally from at least one additional monomer such as (meth)acrylic acid, and mixtures thereof.
- the block polymer is a non-silicone polymer, i.e. a polymer free of silicon atoms.
- This or these additional monomer(s) generally represent(s) an amount of less than or equal to 30% by weight, for example from 1% to 30% by weight, preferably from 5% to 20% by weight and more preferably from 7% to 15% by weight, relative to the total weight of the first and/or second blocks.
- the block polymer may be obtained by free-radical solution polymerization according to the following preparation process:
- the block polymer comprises a first block with a Tg of greater than or equal to 40° C., as described above in a) and a second block with a Tg of less than or equal to 20° C., as described above in b).
- the first block with a Tg of greater than or equal to 40° C. is a copolymer derived from monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40° C., such as the monomers described above.
- the second block with a Tg of less than or equal to 20° C. is a homopolymer derived from monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20° C., such as the monomers described above.
- the proportion of the block with a Tg of greater than or equal to 40° C. ranges from 20% to 90%, better still from 30% to 80% and even better still from 50% to 70% by weight of the polymer.
- the proportion of the block with a Tg of less than or equal to 20° C. ranges from 5% to 75%, preferably from 15% to 50% and better still from 25% to 45% by weight of the polymer.
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the polymer according to the invention may comprise:
- the amounts are expressed in grams.
- 100 g of butyl acetate are introduced into a 1 litre reactor and the temperature is then raised so as to pass from room temperature (25° C.) to 90° C. in 1 hour.
- 180 g of methyl methacrylate, 30 g of acrylic acid, 40 g of butyl acetate, 70 g of isopropanol and 1.8 g of 2,5-bis(2-ethylhexanoylperoxy)-2,5-dimethyl-hexane (Trigonox® 141 from Akzo Nobel) are then added, at 90° C. and over 1 hour.
- the mixture is maintained at 90° C. for 1 hour.
- the mixture is maintained at 90° C. for 3 hours and then diluted with 105 g of butyl acetate and 45 g of isopropanol, and the mixture is then cooled.
- This polymer has a weight-average mass of 52 000 and a number-average mass of 18 000, i.e. a polydispersity index I of 2.89.
- the block polymer comprises a first block having a glass transition temperature (Tg) of between 20 and 40° C., in accordance with the blocks described in c) and a second block having a glass transition temperature of less than or equal to 20° C., as described above in b) or a glass transition temperature of greater than or equal to 40° C., as described in a) above.
- Tg glass transition temperature
- the proportion of the first block with a Tg of between 20 and 40° C. ranges from 10% to 85% by weight of the polymer, better still from 30% to 80% and even better still from 50% to 70%.
- the second block is a block with a Tg of greater than or equal to 40° C., it is preferably present in a proportion ranging from 10% to 85% by weight, better still from 20% to 70% and even better still from 30% to 70% by weight of the polymer.
- the second block is a block with a Tg of less than or equal to 20° C., it is preferably present in a proportion ranging from 10% to 85% by weight, better still from 20% to 70% and even better still from 20% to 50% by weight of the polymer.
- the first block with a Tg of between 20 and 40° C. is a copolymer derived from monomers which are such that the corresponding homopolymer has a Tg of greater than or equal to 40° C., and from monomers which are such that the corresponding homopolymer has a Tg of less than or equal to 20° C.
- the second block with a Tg of less than or equal to 20° C. or with a Tg of greater than or equal to 40° C. is a homopolymer.
- the block polymer may comprise:
- the block polymer may comprise:
- the block polymer may comprise:
- the polymers corresponding to this second embodiment may be produced as follows.
- the mixture is maintained at 90° C. for 1 hour.
- the mixture is maintained at 90° C. for 3 hours and then diluted with 105 g of butyl acetate and 45 g of isopropanol, and the mixture is then cooled.
- the polymer obtained comprises a first poly(methyl acrylate/methyl methacrylate/acrylic acid) block with a Tg of 35° C., a second poly(methyl methacrylate) block with a Tg of 100° C. and an intermediate block that is a methyl methacrylate/acrylic acid/polymethyl acrylate random polymer.
- compositions of the invention contain from 0.1% to 60% by weight, preferably from 0.5% to 50% by weight and more preferably from 1% to 40% by weight of the block polymer according to the invention.
- the cosmetic composition may comprise an organic solvent medium or a mixture of organic solvents.
- the organic solvent may be chosen from:
- the organic solvent medium preferably has a polarity P ranging from 0.422 to 0.725.
- organic solvents with a polarity ranging from 0.422 to 0.725 mention may be made in particular of methyl acetate, isopropyl acetate, methoxypropyl acetate, butyl lactate, acetone, methyl ethyl ketone, diacetone alcohol, ⁇ -butyrolactone, tetrahydrofuran, propylene carbonate, ethyl 3-ethoxypropionate and dimethyl sulphoxide, and mixtures thereof.
- the organic solvent medium may represent from 10% to 95% by weight, preferably from 15% to 80% by weight and better still from 20% to 60% by weight, relative to the total weight of the composition.
- composition may comprise, besides the block polymer of the composition according to the invention, an additional polymer such as a film-forming polymer.
- film-forming polymers that may be used in the composition of the present invention, mention may be made of synthetic polymers, of free-radical type or of polycondensate type, and polymers of natural origin, and mixtures thereof.
- the film-forming polymer may be chosen in particular from cellulose-based polymers such as cellulose acetate, cellulose acetobutyrate, cellulose acetopropionate or ethylcellulose, or alternatively polyurethanes, acrylic polymers, vinyl polymers, polyvinylbutyrals, alkyd resins, resins derived from aldehyde condensation products such as arylsulphonamide-formaldehyde resins, for instance toluenesulphonamide-formaldehyde resin, and arylsulphonamide-epoxy resins.
- cellulose-based polymers such as cellulose acetate, cellulose acetobutyrate, cellulose acetopropionate or ethylcellulose
- polyurethanes acrylic polymers, vinyl polymers, polyvinylbutyrals, alkyd resins, resins derived from aldehyde condensation products such as arylsulphonamide-formaldehyde resins, for instance tol
- Film-forming polymers that may especially be used include the toluenesulphonamide-formaldehyde resins “Ketjentflex MS80” from the company Akzo or “Santolite MHP” or “Santolite MS 80” from the company Faconnier or “Resimpol 80” from the company Pan Americana, the alkyd resin “Beckosol ODE 230-70-E” from the company Dainippon, the acrylic resin “Acryloid B66” from the company Rohm & Haas, and the polyurethane resin “Trixene PR 4127” from the company Baxenden.
- toluenesulphonamide-formaldehyde resins “Ketjentflex MS80” from the company Akzo or “Santolite MHP” or “Santolite MS 80” from the company Faconnier or “Resimpol 80” from the company Pan Americana
- the alkyd resin “Beckosol ODE 230-70-E” from the
- the additional film-forming polymer may be present in the composition according to the invention in a content ranging from 0.1% to 60% by weight, preferably ranging from 2% to 40% by weight and better still from 5% to 25% by weight, relative to the total weight of the composition.
- the composition may also comprise at least one plasticizer.
- plasticizers such as:
- the amount of plasticizer may be chosen by a person skilled in the art on the basis of his general knowledge, so as to obtain a composition with cosmetically acceptable properties.
- the plasticizer is preferably present in an amount of less than 20%, preferably less than 15%, better still less than 10% and even better still less than 5% by weight, relative to the total weight of the composition.
- the composition according to the invention is preferably free of plasticizer.
- composition according to the invention may also comprise one or more dyestuffs chosen from water-soluble dyes and pulverulent dyestuffs, for instance pigments, nacres and flakes that are well known to those skilled in the art.
- the dyestuffs may be present in the composition in a content ranging from 0.01% to 50% by weight and preferably from 0.01% to 30% by weight, relative to the weight of the composition.
- pigments should be understood as meaning white or coloured, mineral or organic particles of any shape, which are insoluble in the physiological medium and which are intended to colour the composition.
- nacres should be understood as meaning iridescent particles of any shape, produced especially by certain molluscs in their shell, or alternatively synthesized.
- the pigments may be white or coloured, and mineral and/or organic.
- mineral pigments that may be mentioned are titanium dioxide, optionally surface-treated, zirconium oxide or cerium oxide, and also zinc oxide, iron oxide (black, yellow or red) or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, and metal powders, for instance aluminium powder or copper powder.
- organic pigments that may be mentioned are carbon black, pigments of D & C type, and lakes based on cochineal carmine or on barium, strontium, calcium or aluminium.
- the nacreous pigments may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, coloured nacreous pigments such as titanium mica coated with iron oxides, titanium mica coated especially with ferric blue or chromium oxide, titanium mica coated with an organic pigment of the abovementioned type and also nacreous pigments based on bismuth oxychloride.
- the water-soluble dyes are, for example, beetroot juice or methylene blue.
- the composition according to the invention may also comprise one or more fillers, especially in a content ranging from 0.01% to 50% by weight and preferably ranging from 0.01% to 30% by weight, relative to the total weight of the composition.
- fillers should be understood as meaning colourless or white, mineral or synthetic particles of any shape, which are insoluble in the medium of the composition, irrespective of the temperature at which the composition is manufactured. These fillers serve especially to modify the rheology or the texture of the composition.
- the fillers may be mineral or organic in any form, platelet-shaped, spherical or oblong, irrespective of the crystallographic form (for example leaflet, cubic, hexagonal, orthorhombic, etc.). Mention may be made of talc, mica, silica, kaolin, polyamide (Nylon®) powders (Orgasol® from Atochem), poly- ⁇ -alanine powder and polyethylene powder, powders of polytetrafluoroethylene polymers (Teflon®), lauroyllysine, starch, boron nitride, hollow polymer microspheres such as those of polyvinylidene chloride/acrylonitrile, for instance Exapancel® (Nobel Industrie) or acrylic acid copolymers (Polytrap® from the company Dow Corning) and silicone resin microbeads (for example Tospearls® from Toshiba), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, magnesium carbonate, magnesium hydrocarbonate
- composition may also comprise other ingredients commonly used in cosmetic compositions.
- ingredients may be chosen from spreading agents, wetting agents, dispersants, antifoams, preserving agents, UV-screening agents, active agents, surfactants, moisturizers, fragrances, neutralizers, stabilizers and antioxidants.
- a subject of the present invention is also a cosmetic assembly comprising:
- the container may be in any adequate form. It may especially be in the form of a bottle, a case or a tube.
- the closing member may be in the form of a removable stopper.
- the container is preferably equipped with an applicator to allow the application of the product to the nails.
- an applicator may be in the form of a fine brush consisting of at least one tuft of hairs.
- the tuft of hairs may be embedded at the end of a rod borne by the closing member.
- the hairs are preferably oriented along the axis of the rod.
- the hairs may be embedded by means of stapling, bonded, or obtained by moulding.
- the applicator is in the form of a tape made of porous material, especially of open-cell foam or of felt.
- the applicator may be in the form of a spatula, especially made of elastomeric material.
- the closing member may be coupled to the container by screwing.
- the coupling between the closing member and the container is done other than by screwing, especially via a bayonet mechanism or by click-fastening.
- click-fastening in particular means any system involving the crossing of a bead or cord of material by elastic deformation of a portion, especially of the closing member, followed by return to the elastically unconstrained position of the said portion after the crossing of the bead or cord.
- the container is preferably made of glass. However, materials other than glass may be used. Examples that will be mentioned include certain thermoplastic materials appropriately chosen so as to be compatible with the composition. Alternatively also, the container may be made of metal.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0211949 | 2002-09-26 | ||
FR0211949 | 2002-09-26 | ||
FR0216437 | 2002-12-20 | ||
FR0216437 | 2002-12-20 | ||
FR0306121 | 2003-05-21 | ||
FR0306121 | 2003-05-21 | ||
PCT/FR2003/002846 WO2004028494A2 (fr) | 2002-09-26 | 2003-09-26 | Composition de vernis à ongles comprenant un polymère séquencé |
Publications (1)
Publication Number | Publication Date |
---|---|
US20060134032A1 true US20060134032A1 (en) | 2006-06-22 |
Family
ID=32045662
Family Applications (10)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/528,698 Abandoned US20060127334A1 (en) | 2002-09-26 | 2003-09-26 | Lipstick comprising a sequenced polymer |
US10/529,265 Active 2029-03-28 US9017704B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising a block polymer and a film-forming agent |
US10/529,264 Abandoned US20060147403A1 (en) | 2002-09-26 | 2003-09-26 | Non-transfer cosmetic composition comprising a sequenced polymer |
US10/528,835 Active 2028-09-08 US8992903B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising at least one block polymer and at least one gelling agent |
US10/529,318 Expired - Fee Related US7875265B2 (en) | 2002-09-26 | 2003-09-26 | Cosmetic composition comprising a sequenced polymer and a plasticizer |
US10/528,699 Abandoned US20060134032A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a sequenced polymer |
US10/529,266 Abandoned US20060134051A1 (en) | 2002-09-26 | 2003-09-26 | Glossy non-transfer composition comprising a sequenced polymer |
US10/529,267 Abandoned US20060099164A1 (en) | 2002-09-26 | 2003-09-26 | Composition for coating keratin fibres, comprising a high dry extract that contains a sequenched polymer |
US10/670,388 Abandoned US20040120906A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a block polymer |
US10/529,218 Abandoned US20060115444A1 (en) | 2002-09-26 | 2003-09-26 | Glossy liquid composition comprising a sequenced polymer |
Family Applications Before (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/528,698 Abandoned US20060127334A1 (en) | 2002-09-26 | 2003-09-26 | Lipstick comprising a sequenced polymer |
US10/529,265 Active 2029-03-28 US9017704B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising a block polymer and a film-forming agent |
US10/529,264 Abandoned US20060147403A1 (en) | 2002-09-26 | 2003-09-26 | Non-transfer cosmetic composition comprising a sequenced polymer |
US10/528,835 Active 2028-09-08 US8992903B2 (en) | 2002-09-26 | 2003-09-26 | Composition comprising at least one block polymer and at least one gelling agent |
US10/529,318 Expired - Fee Related US7875265B2 (en) | 2002-09-26 | 2003-09-26 | Cosmetic composition comprising a sequenced polymer and a plasticizer |
Family Applications After (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/529,266 Abandoned US20060134051A1 (en) | 2002-09-26 | 2003-09-26 | Glossy non-transfer composition comprising a sequenced polymer |
US10/529,267 Abandoned US20060099164A1 (en) | 2002-09-26 | 2003-09-26 | Composition for coating keratin fibres, comprising a high dry extract that contains a sequenched polymer |
US10/670,388 Abandoned US20040120906A1 (en) | 2002-09-26 | 2003-09-26 | Nail varnish composition comprising a block polymer |
US10/529,218 Abandoned US20060115444A1 (en) | 2002-09-26 | 2003-09-26 | Glossy liquid composition comprising a sequenced polymer |
Country Status (8)
Country | Link |
---|---|
US (10) | US20060127334A1 (fr) |
EP (10) | EP1565148B1 (fr) |
JP (8) | JP3981130B2 (fr) |
AT (7) | ATE487468T1 (fr) |
AU (10) | AU2003288305A1 (fr) |
BR (2) | BR0314489A (fr) |
DE (7) | DE60335007D1 (fr) |
WO (10) | WO2004028490A2 (fr) |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040120906A1 (en) * | 2002-09-26 | 2004-06-24 | Beatrice Toumi | Nail varnish composition comprising a block polymer |
US20050220747A1 (en) * | 2004-03-25 | 2005-10-06 | Bertrand Lion | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
US20070196306A1 (en) * | 2005-07-22 | 2007-08-23 | Nathalie Jager Lezer | Process for coating eyelashes |
US20080014158A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US20080145325A1 (en) * | 2006-09-13 | 2008-06-19 | Lizabeth-Anne Coffey-Dawe | Nail varnish comprising at least one resin |
US20100215605A1 (en) * | 2008-11-24 | 2010-08-26 | L'oreal | Solid cosmetic composition for application to keratin fibres |
US20110020263A1 (en) * | 2009-06-01 | 2011-01-27 | L'oreal | Composition containing a block polymer and a nonvolatile ester oil |
US8119110B2 (en) | 2003-09-26 | 2012-02-21 | L'oreal S.A. | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
US20120118314A1 (en) * | 2009-07-21 | 2012-05-17 | Danny Lee Haile | Compositions for removable gel applications for nails and methods of their use |
US20130213426A1 (en) * | 2010-11-02 | 2013-08-22 | L'oreal | Two-step nail polish product |
US8710152B2 (en) | 2006-07-27 | 2014-04-29 | L'oreal | Block polymers and their process of preparation |
US9125468B2 (en) | 2010-03-29 | 2015-09-08 | L'oreal | Device for the application of fibers to human keratinous fibers |
US20170360683A1 (en) * | 2016-06-15 | 2017-12-21 | Mycone Dental Supply Co., Inc. | One Part Acrylic Nail Formulation |
US10532021B2 (en) | 2011-12-20 | 2020-01-14 | L'oreal | Composition comprising a specific acrylic polymer and a silicone copolymer, and method for treating keratin fibres using same |
US10744080B2 (en) | 2011-12-20 | 2020-08-18 | L'oreal | Method for the application of a pigment dyeing composition based on specific acrylic polymer and on silicone copolymer, and appropriate device |
US11376208B2 (en) | 2011-12-20 | 2022-07-05 | L'oreal | Pigment dyeing composition based on a particular acrylic polymer and silicone copolymer |
US11576852B2 (en) | 2012-06-29 | 2023-02-14 | L'oreal | Two coat process for dyeing keratin fibres |
US11771629B2 (en) | 2016-06-23 | 2023-10-03 | L'oreal | Process for the elongation and/or densification of fibers |
Families Citing this family (131)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0407375A (pt) | 2003-02-19 | 2006-02-07 | Rinat Neuroscience Corp | Métodos para tratar dor por meio da administração de um antagonista do fator de crescimento neural e u nsaid e composições contendo os mesmos |
FR2851468B1 (fr) * | 2003-02-25 | 2008-07-11 | Oreal | Composition cosmetique comprenant une dispersion de particules de polymere et un compose plastifiant le polymere |
FR2851467B1 (fr) * | 2003-02-25 | 2006-07-07 | Oreal | Composition cosmetique comprenant une dispersion de particules de polymere et un ester d'acide et de polyol |
WO2005030155A1 (fr) * | 2003-09-26 | 2005-04-07 | L'oréal | Composition de photoprotection a base de phase aqueuse continue contenant un polymere comportant au moins de blocs mutuellement incompatibles et ayant differentes temperatures de transition vitreuse |
FR2860156B1 (fr) * | 2003-09-26 | 2007-11-02 | Oreal | Composition cosmetique comprenant un agent tenseur et un polymere ethylenique sequence particulier |
FR2860142B1 (fr) * | 2003-09-26 | 2007-08-17 | Oreal | Produit cosmetique bicouche, ses utilisations et kit de maquillage contenant ce produit |
FR2860155A1 (fr) * | 2003-09-26 | 2005-04-01 | Oreal | Composition photoprotectrice a phase aqueuse continue contenant un polymere comprenant au moins deux sequences incompatibles l'une avec l'autre et ayant des temperatures de transition vitreuse differentes |
DE10358091A1 (de) * | 2003-12-10 | 2005-07-14 | Eckart Gmbh & Co. Kg | Kosmetische Zusammensetzung zur Erzeugung eines kosmetischen Überzugs mit einem metallisch und mehrfarbig schillernden Erscheinungsbild und künstlicher Fingernagel |
FR2864895A1 (fr) * | 2004-01-13 | 2005-07-15 | Oreal | Composition de revetement des fibres keratiniques comprenant un polymere sequence, un polymere cationique et un polymere anionique |
FR2871470B1 (fr) * | 2004-06-11 | 2007-01-12 | Oreal | Copolymere a gradient, composition et procede cosmetique de maquillage ou de soin |
US20050281769A1 (en) * | 2004-06-11 | 2005-12-22 | Toumi Beatrice | Cosmetic composition comprising a polymer |
FR2871372A1 (fr) * | 2004-06-11 | 2005-12-16 | Oreal | Composition cosmetique comprenant un polymere |
FR2874311B1 (fr) | 2004-08-20 | 2006-11-17 | Oreal | Kit de maquillage ou de soin des ongles |
US9649261B2 (en) | 2004-10-05 | 2017-05-16 | L'oreal | Method of applying makeup to a surface and a kit for implementing such a method |
FR2876011B1 (fr) * | 2004-10-05 | 2006-12-29 | Oreal | Procede de maquillage d'un support et kit pour la mise en oeuvre de ce procede |
FR2879442B1 (fr) | 2004-12-21 | 2007-07-20 | Oreal | Composition cosmetique pour le maquillage resistante a l'eau et facilement demaquillable |
FR2880268B1 (fr) * | 2005-01-05 | 2008-10-24 | Oreal | Composition brillante et non transfert comprenant deux polymeres sequences |
FR2881648B1 (fr) * | 2005-02-04 | 2008-12-05 | Oreal | Composition cosmetique comprenant une dispersion de particules de polymeres, dispersion de particules de polymeres et procede cosmetique l'utilisant |
US20060193803A1 (en) * | 2005-02-04 | 2006-08-31 | Celine Farcet | Polymer particle dispersions, cosmetic compositions comprising at least one polymer particle dispersion, and cosmetic process using same |
US20090053270A1 (en) * | 2005-03-18 | 2009-02-26 | Kao Corporation | Cosmetic for eyelashes |
FR2887770A1 (fr) * | 2005-07-04 | 2007-01-05 | Oreal | Produit de maquillage et/ou de soin "double-geste" |
FR2888115B1 (fr) * | 2005-07-08 | 2013-02-15 | Oreal | Fond de teint liquide, procede de maquillage et kit pour la mise en oeuvre d'un tel procede. |
FR2889921B1 (fr) | 2005-08-30 | 2007-12-28 | Oreal | Ensemble de conditionnement et d'application comportant un dispositif magnetique. |
US20070081954A1 (en) * | 2005-10-06 | 2007-04-12 | Nathalie Mougin | Dispersion of polymer particles, composition comprising it and cosmetic treatment method |
FR2892925B1 (fr) * | 2005-11-09 | 2007-12-14 | Oreal | Composition de revetement des cils sous forme de mousse |
US20070134181A1 (en) * | 2005-12-08 | 2007-06-14 | L'oreal | Cosmetic composition comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant |
ATE458328T1 (de) * | 2005-12-22 | 2010-03-15 | Axis Ab | Überwachungssystem und -verfahren zur verbindung eines überwachungsgeräts mit einem dienstserver |
JP2009522268A (ja) * | 2005-12-30 | 2009-06-11 | エイボン プロダクツ インコーポレーテッド | まつげをカールする方法 |
US20070207096A1 (en) * | 2006-02-13 | 2007-09-06 | Virginie Puisset | Nail varnish having a gelled texture |
DE102006012354A1 (de) * | 2006-03-17 | 2007-09-20 | Bayer Materialscience Ag | Wässrige Dispersionen auf Basis von Nitrocellulose-Polyurethan-Teilchen |
JP2007308544A (ja) * | 2006-05-17 | 2007-11-29 | Hitachi Ltd | 低誘電率低屈折率ナノコンポジット材料 |
FR2902006B1 (fr) * | 2006-06-13 | 2009-06-05 | Oreal | Composition cosmetique pour les levres associant un tensioactif phosphate et un polymere silicone |
FR2905068B1 (fr) * | 2006-08-25 | 2008-10-31 | Oreal | Procede de maquillage des cils et ensemble de conditionnement. |
DE202007018702U1 (de) * | 2006-10-20 | 2009-02-19 | Faber-Castell Ag | Kosmetische Zubereitung zum Färben der Augenlider und der Augenbrauen |
FR2908773B1 (fr) * | 2006-11-16 | 2008-12-19 | Oreal | Nouveaux polymeres sequences, compositions les comprenant et procede de traitement. |
GB0624729D0 (en) * | 2006-12-12 | 2007-01-17 | Univ Leeds | Reversible micelles and applications for their use |
FR2910280B1 (fr) | 2006-12-22 | 2009-01-23 | Oreal | Vernis a ongles comprenant un polycondensat et un copolymere polyoxyalkylene |
FR2911065B1 (fr) | 2007-01-04 | 2009-03-20 | Oreal | Kit de maquillage des fibres keratiniques. |
US20080260665A1 (en) * | 2007-01-08 | 2008-10-23 | Laurence Guerchet | Nail varnish comprising at least one polycondensate and at least one polyoxyalkylene copolymer |
FR2915892B1 (fr) | 2007-05-10 | 2009-07-03 | Oreal | Composition sous forme de mousse comprenant un structurant polymerique |
FR2915893B1 (fr) | 2007-05-10 | 2012-05-11 | Oreal | Composition cosmetique sous forme de mousse sans cire |
US20090035335A1 (en) * | 2007-07-30 | 2009-02-05 | Marotta Paul H | Cosmetic Composition Containing a Polymer Blend |
US8562960B2 (en) | 2007-07-30 | 2013-10-22 | Elc Management, Llc | Cosmetic composition containing a polymer blend |
EP2025320A1 (fr) | 2007-08-10 | 2009-02-18 | L'Oréal | Ensemble de conditionnement et d'application d'un vernis à ongles de viscosité élevée |
US20090136439A1 (en) * | 2007-11-27 | 2009-05-28 | L'oreal | Cosmetic composition capable of imparting exceptional curl-retention properties |
CN101980694A (zh) * | 2007-12-05 | 2011-02-23 | 莱雅公司 | 使用硅氧烷树脂和极性蜡的美容性化妆和/或护理方法 |
WO2009076070A2 (fr) * | 2007-12-05 | 2009-06-18 | 3M Innovative Properties Company | Ensemble lié à un adhésif structural et procédé et applicateur pour le fabriquer |
FR2924939B1 (fr) | 2007-12-13 | 2010-02-26 | Oreal | Procede de coloration des cheveux a partir d'une composition comprenant un polymere filmogene hydrophobe, un pigment et un solvant volatil |
FR2925849B1 (fr) * | 2007-12-27 | 2010-06-04 | Oreal | Procede cosmetique procurant un effet allongeant des cils et kit correspondant a base d'un polymere filmogene |
US9925396B2 (en) | 2008-01-30 | 2018-03-27 | L'oreal | Adhesive article containing colorant and/or active agent |
FR2931670B1 (fr) | 2008-06-02 | 2015-05-22 | Oreal | Compositions a base de polyester dans une phase grasse et leurs utilisations. |
FR2936419B1 (fr) | 2008-09-30 | 2010-10-01 | Oreal | Composition de maquillage des cils et ensemble de conditionnement. |
FR2936420A1 (fr) | 2008-09-30 | 2010-04-02 | Oreal | Composition et procede de maquillage des cils comprenant l'application de 2 compositions. |
FR2937645B1 (fr) * | 2008-10-24 | 2010-12-17 | Oreal | Dispersion de particules souples de polymere, compostion cosmetique la comprenant et procede de traitement cosmetique |
FR2938764B1 (fr) | 2008-11-24 | 2012-06-08 | Oreal | Composition cosmetique solide pour application sur les fibres keratiniques |
FR2939033B1 (fr) | 2008-12-02 | 2012-08-31 | Oreal | Composition cosmetique de maquillage et/ou de soin des matieres keratiniques, et procede de maquillage |
EP2355785A4 (fr) | 2008-12-09 | 2014-08-13 | Oréal Sa L | Émulsion résistant au transfert contenant un tensioactif |
FR2939657B1 (fr) | 2008-12-15 | 2011-02-11 | Oreal | Composition cosmetique comprenant une polyamine portant des groupes diazirines et utilisation pour le photo-greffage d'un polymere non saccharidique different des polymeres polyamines |
WO2010077887A2 (fr) | 2008-12-16 | 2010-07-08 | L'oreal S.A | Fond de teint résistant au transfert et de longue tenue sous forme d'émulsion contenant des poudres absorbant l'huile |
WO2010077940A2 (fr) | 2008-12-16 | 2010-07-08 | Hy Si Bui | Produit de réaction insoluble dans l'eau d'une polyamine et d'un polymère modifié de façon polaire et soluble dans l'huile, qui présente une teneur élevée en carbone |
FR2940111B1 (fr) | 2008-12-19 | 2012-06-01 | Oreal | Kit de revetement des matieres keratiniques comprenant un polysaccharide et un agent de complexation ionique ou dative |
FR2940115B1 (fr) | 2008-12-19 | 2012-06-15 | Oreal | Kit de revetement des matieres keratiniques comprenant un polysaccharide et un agent de reticulation chimique |
FR2943225B1 (fr) | 2009-03-17 | 2011-06-03 | Oreal | Dispositif de conditionnement et d'application d'au moins une composition cosmetique solide |
FR2943253B1 (fr) | 2009-03-20 | 2011-04-22 | Oreal | Composition contenant l'association de madecassoside, d'une arginine et de polysorbate |
FR2944958B1 (fr) | 2009-04-30 | 2011-07-08 | Oreal | Emulsion cire-dans-eau comprenant l'association d'un derive d'acide glutamique et d'un alkylpolyglycoside |
FR2945942B1 (fr) * | 2009-06-01 | 2012-12-28 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile ester non volatile |
FR2945941B1 (fr) * | 2009-06-02 | 2011-06-24 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile ester non volatile |
WO2010146147A2 (fr) | 2009-06-18 | 2010-12-23 | L'oreal | Composition pour traiter des fibres de kératine comprenant un copolymère à blocs, résine siloxane et solvant volatile associés |
EP2448554A4 (fr) | 2009-06-29 | 2014-03-12 | Oreal | Fond de teint crème rafraîchissant sous forme de gel |
BRPI1003178A2 (pt) | 2009-06-29 | 2012-03-20 | L'oreal S.A. | composição |
US8663609B2 (en) * | 2009-06-29 | 2014-03-04 | L'oreal | Composition comprising a polyol, a sugar silicone surfactant and a oil-soluble polar modified polymer |
EP2305210A3 (fr) * | 2009-06-29 | 2011-04-13 | L'oreal S.A. | Composition comprenant un agent tensioactif de silicone et sucre et un polymère modifié polaire soluble dans l'huile |
US8597626B2 (en) * | 2009-06-29 | 2013-12-03 | L'oreal | Long wear, waterproof mascara composition with water washability |
BRPI1003794A2 (pt) | 2009-06-29 | 2012-03-20 | L'oreal S.A. | composição e produto de reação |
BRPI1002588A2 (pt) * | 2009-06-29 | 2012-03-13 | L'oreal S.A. | Composição e método de maquilagem de um substrato queratínico |
FR2949675B1 (fr) * | 2009-09-08 | 2011-10-21 | Oreal | Composition cosmetique comprenant un polymere filmogene acide et une charge minerale basique |
FR2949958B1 (fr) | 2009-09-11 | 2012-10-05 | Oreal | Ensemble cosmetique de maquillage et/ou de soin des matieres keratiniques |
CN105708729A (zh) | 2009-10-12 | 2016-06-29 | 欧莱雅 | 用光子颗粒抗太阳uv辐射的光照保护材料方法及组合物 |
WO2011045746A2 (fr) | 2009-10-12 | 2011-04-21 | L ' Oreal | Composition comprenant une dispersion de particules photoniques et procédés de traitement de divers matériaux |
WO2011045741A2 (fr) | 2009-10-12 | 2011-04-21 | L'oreal | Particules photoniques; compositions les contenant; procédés de photoprotection de divers matériaux |
JP2013508351A (ja) | 2009-10-22 | 2013-03-07 | ロレアル | 光防御組成物およびフィルム、ならびに製造方法 |
US20110146702A1 (en) | 2009-12-17 | 2011-06-23 | L'oreal | Extending cosmetic composition comprising behenyl alcohol as thickener |
US9072686B2 (en) * | 2009-12-18 | 2015-07-07 | L'oreal | Mascara containing aqueous dispersion of polyurethane and a hard wax |
EP2353582A1 (fr) | 2009-12-18 | 2011-08-10 | L'Oréal | Composition de maquillage des cils et des sourcils |
KR20130103619A (ko) | 2010-03-29 | 2013-09-23 | 로레알 | 속눈썹 또는 눈썹의 메이크업용 조성물, 조합 및 방법 |
US9192561B2 (en) | 2010-05-14 | 2015-11-24 | L'oreal | Compositions containing hyperbranched polyol and acrylic film former |
FR2959932A1 (fr) | 2010-05-17 | 2011-11-18 | Oreal | Composition de maquillage et/ou de soin des fibres keratiniques presentant des proprietes de tenue ameliorees |
FR2961396B1 (fr) | 2010-06-16 | 2013-03-15 | Oreal | Procede de maquillage ou de soin des fibres keratiniques mettant en oeuvre des fibres retractables et utilisation |
FR2967058B1 (fr) | 2010-11-05 | 2013-10-04 | Oreal | Composition cosmetique et procede de recourbement des fibres keratiniques |
FR2967059B1 (fr) | 2010-11-05 | 2015-07-17 | Oreal | Composition cosmetique et procede de recourbement des fibres keratiniques |
FR2967057B1 (fr) | 2010-11-05 | 2013-08-02 | Oreal | Composition cosmetique et procede de recourbement des fibres keratiniques |
FR2967912B1 (fr) | 2010-11-26 | 2013-05-10 | Oreal | Composition de maquillage des fibres keratiniques |
FR2968520B1 (fr) | 2010-12-14 | 2013-08-30 | Oreal | Element pour l'application de fibres sur des fibres keratiniques humaines |
US8747868B2 (en) | 2010-12-30 | 2014-06-10 | L'oreal | Reaction product of a polar modified polymer and an alkoxysilane and a composition containing the reaction product |
CN102199261B (zh) * | 2011-04-13 | 2012-09-19 | 山东交通学院 | 聚乙二醇-b-聚苯乙烯-b-聚全氟己基乙基丙烯酸酯及其制备方法 |
FR2982771B1 (fr) * | 2011-11-23 | 2013-12-20 | Oreal | Composition comprenant un copolymere bloc polysiloxane/polyuree, un copolymere ethylenique sequence et un solvant volatil |
FR2983718B1 (fr) * | 2011-12-12 | 2016-09-30 | Oreal | Emulsion huile-dans-eau solaire comprenant un polymere ethylenique lipophile, un copolymere d'olefine, un melange de tensio-actifs non-ioniques |
FR2984089B1 (fr) | 2011-12-20 | 2014-01-10 | Oreal | Dispositif d'application comprenant une composition a base de polymere filmogene hydrophobe et un solvant volatil, procede de traitement des fibres keratiniques le mettant en oeuvre |
WO2013102060A1 (fr) | 2011-12-30 | 2013-07-04 | L'oreal | Compositions contenant une résine de silicium et un agent donnant du collant |
WO2013101171A1 (fr) | 2011-12-30 | 2013-07-04 | L'oreal | Compositions contenant un agent filmogène acrylique, un agent poisseux et un ester |
JP6038952B2 (ja) | 2011-12-30 | 2016-12-07 | ロレアル | ケイ素樹脂、油及びゲル化剤を含有する組成物 |
FR2985422B1 (fr) | 2012-01-10 | 2014-08-08 | Oreal | Composition cosmetique solide a effets magnetiques |
FR2992558B1 (fr) | 2012-06-29 | 2014-06-20 | Oreal | Procede pour former un motif colore sur les fibres keratiniques avec une composition comprenant un polymere filmogene hydrophobe, au moins un solvant volatil et au moins un pigment. |
FR3015260B1 (fr) * | 2013-12-19 | 2018-08-31 | L'oreal | Composition anhydre anti-transpirante sous forme d'aerosol comprenant un actif anti-transpirant et un polymere ethylenique filmogene non hydrosoluble et sequence |
FR3025099B1 (fr) * | 2014-08-28 | 2016-12-16 | Oreal | Composition cosmetique de type gel a tenue amelioree et non collante |
FR3025098B1 (fr) * | 2014-08-28 | 2018-03-09 | Oreal | Composition cosmetique de type gel facilement demaquillable |
FR3027796B1 (fr) * | 2014-10-31 | 2016-11-25 | Oreal | Procede cosmetique pour attenuer les rides |
KR101773680B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773684B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773681B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773682B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773683B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
KR101773679B1 (ko) * | 2014-12-15 | 2017-08-31 | 주식회사 엘지생활건강 | 피부 외용제 조성물 |
FR3030257B1 (fr) * | 2014-12-18 | 2016-12-23 | Oreal | Composition comprenant des particules de polymere et un epaississant mineral, procede la mettant en oeuvre |
ES2838755T3 (es) * | 2014-12-18 | 2021-07-02 | Oreal | Composiciones y métodos para mejorar el aspecto de la piel |
EP3218435B1 (fr) * | 2014-12-18 | 2019-05-15 | L'oreal | Composition comprenant des particules polymères, huile et copolymère séquencé à base d'hydrocarbures, et procédé l'utilisant |
FR3030260B1 (fr) * | 2014-12-18 | 2017-01-13 | Oreal | Composition comprenant des particules de polymere stabilise et un tensioactif non ionique |
FR3030261B1 (fr) * | 2014-12-18 | 2017-01-13 | Oreal | Composition comprenant des particules de polymere stabilise et un polymere filmogene hydrophobe |
FR3045378B1 (fr) * | 2015-12-22 | 2018-01-12 | L'oreal | Polymere sequence a groupements alcoxysilane et son utilisation en cosmetique |
US11708470B2 (en) | 2016-12-21 | 2023-07-25 | Ppg Industries Ohio, Inc. | Plastic substrate adhesion promoter with random copolymer |
WO2018119038A1 (fr) * | 2016-12-21 | 2018-06-28 | Ppg Industries Ohio, Inc. | Promoteur d'adhérence |
WO2018156927A1 (fr) | 2017-02-27 | 2018-08-30 | Burgess Tamara L | Composition de traitement des ongles à base d'eau |
US11890262B2 (en) | 2017-07-10 | 2024-02-06 | Wella Operations Us, Llc | Nail hardening composition and method of use |
FR3075627B1 (fr) * | 2017-12-22 | 2021-11-05 | Oreal | Procede de traitement des cheveux mettant en oeuvre une dispersion de particules de polymere stabilisees dans un milieu non aqueux et un polymere filmogene hydrophobe |
FR3075628B1 (fr) * | 2017-12-22 | 2021-11-05 | Oreal | Composition aqueuse comprenant une dispersion de particules de polymere stabilisees dans un milieu non aqueux et un polymere filmogene hydrophobe |
US10543161B1 (en) * | 2018-08-24 | 2020-01-28 | L'oreal | Methods for protecting and improving the appearance of skin |
JP7179326B2 (ja) * | 2018-11-19 | 2022-11-29 | 株式会社サクラクレパス | 水性美爪料組成物 |
EP3886996A1 (fr) * | 2018-11-26 | 2021-10-06 | DSM IP Assets B.V. | Composition cosmétique comprenant des copolymères hyperramifiés spécifiques et des dispersions liquides d'un polymère acrylique |
FR3123805A1 (fr) * | 2021-06-11 | 2022-12-16 | Laboratoires De Biologie Vegetale Yves Rocher | Association de matieres premieres et composition cosmetique comprenant ladite association |
FR3130132B1 (fr) * | 2021-12-09 | 2023-11-17 | Oreal | Dispersion comprenant une particule polymerique, un agent stabilisant a groupe cycloalkyle, une huile, et de l’eau, procede de traitement des matieres keratiniques mettant en œuvre la dispersion |
WO2024049867A1 (fr) | 2022-08-31 | 2024-03-07 | L'oreal | Compositions cosmétiques présentant une résistance améliorée à l'abrasion et au transfert |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4425326A (en) * | 1980-04-01 | 1984-01-10 | Societe Anonyme Dite : L'oreal | Anhydrous nail varnishes |
US6410005B1 (en) * | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
US20030059392A1 (en) * | 2001-07-18 | 2003-03-27 | L'oreal | Composition for topical use containing a diblock polymer |
US20040009136A1 (en) * | 2002-05-31 | 2004-01-15 | L'oreal | Aqueous hair treatment compositions, thickened with an amphiphilic linear block copolymer |
US6692733B1 (en) * | 1999-04-06 | 2004-02-17 | L'oreal | Composition comprising polymers having a star structure, the polymers, and their use |
US20040039101A1 (en) * | 2002-05-31 | 2004-02-26 | Claude Dubief | Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer |
US20040077788A1 (en) * | 2002-07-19 | 2004-04-22 | Cid Centro De Investigacion Y Desarrollo Tecnologico, S.A. De. C.V. | Block copolymers containing functional groups |
US20040120920A1 (en) * | 2002-09-26 | 2004-06-24 | Bertrand Lion | Novel block polymers and cosmetic compositions and processes comprising them |
US20040120906A1 (en) * | 2002-09-26 | 2004-06-24 | Beatrice Toumi | Nail varnish composition comprising a block polymer |
US20050106197A1 (en) * | 2003-09-26 | 2005-05-19 | Xavier Blin | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
Family Cites Families (274)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US811910A (en) * | 1903-03-12 | 1906-02-06 | Albert H Emery | Cartridge. |
USRE23514E (en) | 1930-06-26 | 1952-06-24 | Artificial resins and process of | |
US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
US2723248A (en) | 1954-10-01 | 1955-11-08 | Gen Aniline & Film Corp | Film-forming compositions |
US2781354A (en) * | 1956-03-26 | 1957-02-12 | John J Mccabe Jr | Imidazoline derivatives and process |
FR1222944A (fr) | 1958-04-15 | 1960-06-14 | Hoechst Ag | Polymères greffés et leur procédé de préparation |
FR1400366A (fr) | 1963-05-15 | 1965-05-28 | Oreal | Nouveaux composés pouvant être utilisés en particulier pour le traitement des cheveux |
FR1517743A (fr) | 1966-08-03 | 1968-03-22 | Oreal | Nouveaux copolymères et compositions cosmétiques contenant ces copolymères |
LU54202A1 (fr) | 1967-07-28 | 1969-03-24 | Oreal | Procédé de préparation de nouveaux copolymères et compositions cosmétiques contenant ces copolymères |
US3925542A (en) | 1965-03-03 | 1975-12-09 | Oreal | Hair lacquer and wave setting compositions containing vinyl acetate-crotonic acid-containing polymers |
US4129711A (en) | 1965-03-03 | 1978-12-12 | L'oreal | Polymers comprising vinyl esters-crotonic acid |
NL136457C (fr) | 1967-03-23 | |||
SE375780B (fr) | 1970-01-30 | 1975-04-28 | Gaf Corp | |
US3910862A (en) | 1970-01-30 | 1975-10-07 | Gaf Corp | Copolymers of vinyl pyrrolidone containing quarternary ammonium groups |
FI55686C (fi) | 1970-02-12 | 1979-09-10 | Rhodiaceta | Foerfarande foer framstaellning av blanka vaermebestaendiga polyamidimidfibrer |
FR2079785A5 (en) | 1970-02-12 | 1971-11-12 | Rhodiaceta | Lustrous polyamide-imide based fibres by new process |
US4032628A (en) | 1970-04-07 | 1977-06-28 | Societe Anonyme Dite: L'oreal | Cosmetic emulsion compositions including black polymer emulsifiers |
LU60676A1 (fr) * | 1970-04-07 | 1972-02-10 | ||
US3836537A (en) | 1970-10-07 | 1974-09-17 | Minnesota Mining & Mfg | Zwitterionic polymer hairsetting compositions and method of using same |
FR2141556B1 (fr) * | 1971-06-14 | 1974-03-22 | Rhone Poulenc Textile | |
FR2140977A5 (en) | 1971-10-26 | 1973-01-19 | Oreal | Sequenced polymers - from lipophilic and hydrophilic monomers for cosmetic use |
CA981183A (en) | 1972-04-14 | 1976-01-06 | Albert L. Micchelli | Hair fixing compositions |
LU65552A1 (fr) * | 1972-06-20 | 1973-12-27 | ||
LU67772A1 (fr) | 1973-06-08 | 1975-03-06 | ||
USRE29871E (en) | 1973-06-08 | 1978-12-26 | L'oreal | Fatty compositions for use in cosmetic makeup compositions and said cosmetic makeup compositions |
LU69759A1 (fr) | 1974-04-01 | 1976-03-17 | ||
LU69760A1 (fr) | 1974-04-01 | 1976-03-17 | ||
US4076912A (en) | 1974-04-01 | 1978-02-28 | L'oreal | Tetrapolymers comprising (a) unsaturated acids (b) vinyl esters (c) branched allyl or methallyl esters and (d) vinyl ether or vinyl fatty ester or linear allyl or methallyl esters |
US4070533A (en) * | 1974-04-01 | 1978-01-24 | L'oreal | Terpolymer of (a) crotonic acid (b) vinyl acetate and (c) allyl or methallyl esters |
CH606154A5 (fr) | 1974-07-02 | 1978-11-15 | Goodrich Co B F | |
LU71577A1 (fr) * | 1974-12-30 | 1976-11-11 | ||
LU75371A1 (fr) | 1976-07-12 | 1978-02-08 | ||
JPS52123482A (en) | 1976-04-06 | 1977-10-17 | Oreal | Novel copolymers and process for producing same and cosmetic composition containing thereof |
AT364707B (de) | 1976-04-06 | 1981-11-10 | Oreeal L | Kosmetisches mittel zur behandlung der haare oder der naegel |
LU75370A1 (fr) | 1976-07-12 | 1978-02-08 | ||
US4031307A (en) * | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
GB1572837A (en) * | 1976-05-06 | 1980-08-06 | Berger Jenson & Nicholson Ltd | Coating composition |
FR2357241A2 (fr) | 1976-07-08 | 1978-02-03 | Oreal | Nouvelle composition cosmetique a base de copolymeres anhydrides mono-esterifies ou mono-amidifies, copolymeres nouveaux et leur procede de preparation |
US4152416A (en) * | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
US4128631A (en) | 1977-02-16 | 1978-12-05 | General Mills Chemicals, Inc. | Method of imparting lubricity to keratinous substrates and mucous membranes |
US4223009A (en) | 1977-06-10 | 1980-09-16 | Gaf Corporation | Hair preparation containing vinyl pyrrolidone copolymer |
US4165367A (en) | 1977-06-10 | 1979-08-21 | Gaf Corporation | Hair preparations containing vinyl pyrrolidone copolymer |
CA1091160A (fr) | 1977-06-10 | 1980-12-09 | Paritosh M. Chakrabarti | Produit pour traitement capillaire contenant un copolymere de pyrrolidone de vinyle |
US4131576A (en) | 1977-12-15 | 1978-12-26 | National Starch And Chemical Corporation | Process for the preparation of graft copolymers of a water soluble monomer and polysaccharide employing a two-phase reaction system |
FR2439798A1 (fr) | 1978-10-27 | 1980-05-23 | Oreal | Nouveaux copolymeres utilisables en cosmetique, notamment dans des laques et lotions de mises en plis |
US4296053A (en) * | 1979-05-24 | 1981-10-20 | Brown Group, Inc. | Method of making foamed plastisol insoles for shoes |
DE3271521D1 (en) * | 1981-03-25 | 1986-07-10 | Ciba Geigy Ag | Composition for fixing the hair, its preparation and its use in aerosol sprays |
DE3273489D1 (en) | 1981-11-30 | 1986-10-30 | Ciba Geigy Ag | Mixtures of quaternary polymeric acrylic ammonium salts, quaternary mono- or oligomeric ammonium salts and surfactants, their preparation and their use in cosmetic compositions |
US4459249A (en) * | 1982-01-22 | 1984-07-10 | Inoue Mtp Kabushiki Kaisha | Method of manufacturing a foamed protective and decorative molding for an automobile |
US4524037A (en) * | 1982-08-16 | 1985-06-18 | Michel Marc | Method and apparatus for forming a flexible thermoplastic resin foam article using an RF field |
US4525231A (en) * | 1983-06-08 | 1985-06-25 | Voplex Corporation | Method of making cushioned automotive strap handle |
US4509949A (en) * | 1983-06-13 | 1985-04-09 | The B. F. Goodrich Company | Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters |
US4514552A (en) | 1984-08-23 | 1985-04-30 | Desoto, Inc. | Alkali soluble latex thickeners |
US4592426A (en) * | 1984-12-10 | 1986-06-03 | Hughes Tool Company | Upper termination with sliding sleeve seals |
US4728571A (en) * | 1985-07-19 | 1988-03-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer release coating sheets and adhesive tapes |
AU612965B2 (en) | 1985-08-12 | 1991-07-25 | Ciba Specialty Chemicals Water Treatments Limited | Polymeric thickeners and their production |
US4693935A (en) | 1986-05-19 | 1987-09-15 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer pressure sensitive adhesive composition and sheet materials coated therewith |
JPH078505B2 (ja) * | 1986-07-30 | 1995-02-01 | 株式会社イノアックコ−ポレ−ション | プラスチツク発泡体の製造方法 |
FR2607373B1 (fr) | 1986-11-28 | 1989-02-24 | Oreal | Brosse pour l'application de mascara sur les cils |
JPS63313710A (ja) | 1987-06-16 | 1988-12-21 | Toray Silicone Co Ltd | 洗顔化粧料 |
LU87030A1 (fr) | 1987-10-28 | 1989-05-08 | Oreal | Utilisation en cosmetique de nouvelles substances a titre de reflecteurs du rayonnement infrarouge,compositions cosmetiques les contenant et leur utilisation pour la protection de l'epiderme humain contre le rayonnement infrarouge |
EP0320218A3 (fr) | 1987-12-11 | 1990-04-25 | The Procter & Gamble Company | Copolymères adhésifs à température de transition vitreuse basse pour utilisation dans des produits de traitement de cheveux |
US5266321A (en) | 1988-03-31 | 1993-11-30 | Kobayashi Kose Co., Ltd. | Oily make-up cosmetic comprising oil base and silicone gel composition |
US5061481A (en) | 1989-03-20 | 1991-10-29 | Kobayashi Kose Co., Ltd. | Cosmetic composition having acryl-silicone graft copolymer |
US5219560A (en) | 1989-03-20 | 1993-06-15 | Kobayashi Kose Co., Ltd. | Cosmetic composition |
US5156911A (en) | 1989-05-11 | 1992-10-20 | Landec Labs Inc. | Skin-activated temperature-sensitive adhesive assemblies |
DE69006556T2 (de) | 1989-08-07 | 1994-06-09 | Procter & Gamble | Haarkonditionierungs- und Haarformmittel. |
EP0412704B1 (fr) | 1989-08-07 | 1999-04-28 | THE PROCTER & GAMBLE COMPANY | Compositions pour traiter et fixer la chevelure |
US4972037A (en) | 1989-08-07 | 1990-11-20 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer topical binder composition with novel fluorochemical comonomer and method of coating therewith |
US4981903A (en) | 1989-08-07 | 1991-01-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafter copolymer topical binder composition with novel hydrophilic monomers and method of coating therewith |
US4981902A (en) * | 1989-08-07 | 1991-01-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer non-pressure sensitive topical binder composition and method of coating therewith |
US5209924A (en) * | 1989-08-07 | 1993-05-11 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer topical binder composition with novel fluorochemical comonomer and method of coating therewith |
FR2679444B1 (fr) * | 1991-07-25 | 1995-04-07 | Oreal | Utilisation comme agents epaississants des huiles, dans une composition cosmetique huileuse, d'une association de deux copolymeres. |
US6258916B1 (en) | 1991-12-24 | 2001-07-10 | Rhone-Poulenc Fibres | Process for spinning from solution of polyamide-imides (PAI) based on tolylene or meta-phenylene diisocyanates and fibers thus obtained |
US5756635A (en) | 1991-12-24 | 1998-05-26 | Rhone-Poulenc Fibres | Process for spinning from solution of polyamide-imides (PAI) based on tolylene or met-phenylene diisocyanates and fibres thus obtained |
FR2685354B1 (fr) | 1991-12-24 | 1996-03-29 | Rhone Poulenc Fibres | Procede de filage de solutions de polyamides-imides (pai) a base de toluylene ou de metaphenylene diisocyanates et fibres ainsi obtenues. |
JP3098604B2 (ja) | 1992-02-13 | 2000-10-16 | 株式会社コーセー | 口紅オーバーコート |
US5468477A (en) | 1992-05-12 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Vinyl-silicone polymers in cosmetics and personal care products |
WO1993023009A1 (fr) | 1992-05-12 | 1993-11-25 | Minnesota Mining And Manufacturing Company | Polymeres utilises dans des compositions cosmetiques et des produits de soins |
WO1993023446A2 (fr) | 1992-05-15 | 1993-11-25 | The Procter & Gamble Company | Agents adhesifs contenant un polymere a greffe polysiloxane et leur compositions cosmetiques |
DE4220807A1 (de) * | 1992-06-25 | 1994-01-05 | Basf Ag | In Zweistufenfahrweise hergestellte Vinylpolymerisate und ihre Verwendung als Lackbindemittel |
EP0582152B1 (fr) * | 1992-07-28 | 2003-04-16 | Mitsubishi Chemical Corporation | Composition cosmétique pour les cheveux |
DE4225045A1 (de) | 1992-07-29 | 1994-02-03 | Basf Ag | Verwendung von wasserlöslichen oder in Wasser dispergierbaren Polyurethanen als Hilfsmittel in kosmetischen und pharmazeutischen Zubereitungen und Polyurethane, die Polymilchsäurepolyole einpolymerisiert enthalten |
JP3393903B2 (ja) | 1992-11-30 | 2003-04-07 | 株式会社資生堂 | メーキャップ化粧料 |
FR2701818B1 (fr) * | 1993-02-22 | 1995-06-16 | Oreal | Applicateur. |
US6663885B1 (en) | 1993-03-15 | 2003-12-16 | A. Natterman & Cie Gmbh | Aqueous liposome system and a method for the preparation of such a liposome system |
JP3214674B2 (ja) | 1993-03-26 | 2001-10-02 | 出光興産株式会社 | 新規スチリル化合物,その製造法およびそれからなる有機エレクトロルミネッセンス素子 |
JPH06279232A (ja) * | 1993-03-30 | 1994-10-04 | Nisshin Chem Ind Co Ltd | アイメークアップ化粧料 |
DE69401230T3 (de) | 1993-04-06 | 2006-02-16 | National Starch And Chemical Investment Holding Corp., Wilmington | Verwendung von Polyurethanen, die funktionelle Carboxylatogruppe enthalt, zur Haarfestigung |
US5374388A (en) * | 1993-04-22 | 1994-12-20 | Lockheed Corporation | Method of forming contoured repair patches |
US5476901A (en) | 1993-06-24 | 1995-12-19 | The Procter & Gamble Company | Siloxane modified polyolefin copolymers |
US5472798A (en) | 1993-07-16 | 1995-12-05 | Nissan Motor Co., Ltd. | Coloring structure having reflecting and interfering functions |
FR2708615B1 (fr) | 1993-08-04 | 1995-09-15 | Oreal | Nouveaux polyester-polyuréthannes, leur procédé de préparation, pseudo-latex réalisés à partir desdits polyester-polyuréthannes et leur utilisation dans des compositions cosmétiques. |
US6106813A (en) | 1993-08-04 | 2000-08-22 | L'oreal | Polyester polyurethanes, process for preparing them, produced from the said polyester polyurethanes and their use in cosmetic compositions |
SG52692A1 (en) | 1993-08-23 | 1998-09-28 | Procter & Gamble | Silicone grafted thermoplastic elastomeric copolymers and hair and skin care compositions containing the same |
FR2710552B1 (fr) | 1993-09-30 | 1995-12-22 | Lvmh Rech | Utilisation de copolymères-blocs acryliques comme agents mouillants et/ou dispersants des particules solides et dispersions en résultant. |
FR2710646B1 (fr) * | 1993-10-01 | 1995-12-22 | Lvmh Rech | Microdispersions stables et microgels à base de polymères acryliques, leur procédé d'obtention et compositions, notamment cosmétiques, les contenant. |
FR2711059B1 (fr) | 1993-10-15 | 1996-02-02 | Oreal | Composition cosmétique sous forme de vernis à ongles aqueux, coloré ou incolore, contenant en tant que substance filmogène des particules de polyester-polyuréthanne anionique à l'état dispersé. |
JP3338057B2 (ja) * | 1993-10-18 | 2002-10-28 | ザ、プロクター、エンド、ギャンブル、カンパニー | 非発汗性口紅 |
JP3410189B2 (ja) | 1993-12-28 | 2003-05-26 | 株式会社コーセー | アイメークアップ化粧料 |
FR2715063B1 (fr) | 1994-01-17 | 1996-03-22 | Oreal | Composition cosmétique pour le maquillage sous forme d'un mascara contenant au moins une cire et un pseudo-latex de dérivés de la cellulose. |
FR2715306B1 (fr) | 1994-01-25 | 1996-03-15 | Oreal | Composition cosmétique ou dermopharmaceutique sous forme de pâte souple et procédé de préparation de ladite composition. |
US6160054A (en) | 1995-05-08 | 2000-12-12 | Fmc Corporation | Hetero-telechelic polymers and processes for making same |
JPH07309721A (ja) | 1994-05-17 | 1995-11-28 | Kao Corp | 2液型水系美爪料 |
JP3166482B2 (ja) | 1994-06-07 | 2001-05-14 | 日産自動車株式会社 | 反射干渉作用を有する発色構造体 |
FR2722380A1 (fr) | 1994-07-12 | 1996-01-19 | Oreal | Applicateur pour l'application d'un produit cosmetique liquide et ensemble de maquillage muni d'un tel applicateur |
FR2724843A1 (fr) | 1994-09-28 | 1996-03-29 | Lvmh Rech | Vernis a ongles contenant des microgels |
JPH08119836A (ja) | 1994-10-21 | 1996-05-14 | Nippon Oil & Fats Co Ltd | ネイル化粧用組成物 |
FR2727609B1 (fr) | 1994-12-06 | 1997-01-10 | Oreal | Ensemble de distribution pour l'application d'un produit de consistance liquide a pateuse |
FR2727608B1 (fr) | 1994-12-06 | 1997-01-10 | Oreal | Distributeur pour un produit de consistance liquide a pateuse |
DE69533055T2 (de) | 1994-12-06 | 2005-05-12 | L'oreal | Spender für ein flüssiges oder pastöses Produkt mit einem Auftragsteil |
US5686067A (en) | 1995-01-05 | 1997-11-11 | Isp Investments Inc. | Low voc hair spray compositions |
FR2733683B1 (fr) | 1995-05-05 | 1997-06-06 | Oreal | Composition de vernis a ongles comprenant un polyester reticule |
US5747017A (en) | 1995-05-15 | 1998-05-05 | Lip-Ink International | Lip cosmetic |
ATE187190T1 (de) | 1995-06-15 | 1999-12-15 | Raychem Ltd | Gele hergestellt aus triblockkopolymeren |
US5969068A (en) | 1995-06-19 | 1999-10-19 | The Lubrizol Corporation | Dispersant-viscosity improvers for lubricating oil compositions |
CA2225996A1 (fr) | 1995-06-26 | 1997-01-16 | Revlon Consumer Products Corporation | Composition cosmetique brillante presentant une resistance amelioree au transfert |
FR2736057B1 (fr) | 1995-06-27 | 1997-08-01 | Oreal | Polycondensats sequences polyurethanes et/ou polyurees a greffons silicones, compositions cosmetiques les contenant et utilisations |
TW413692B (en) | 1995-06-30 | 2000-12-01 | Chiba Seifun Kk | Novel silicone derivatives, their production and use |
US6071503A (en) | 1995-11-07 | 2000-06-06 | The Procter & Gamble Company | Transfer resistant cosmetic compositions |
ATE249197T1 (de) | 1995-11-07 | 2003-09-15 | Procter & Gamble | Übertragungsbeständige kosmetische zusammensetzungen |
US5690918A (en) | 1995-12-19 | 1997-11-25 | Maybelline, Inc. | Solvent-based non-drying lipstick |
FR2743297B1 (fr) | 1996-01-05 | 1998-03-13 | Oreal | Composition cosmetiques a base de polycondensats ionisables multisequences polysiloxane/polyurethane et/ou polyuree en solution et utilisation |
FR2745174B1 (fr) | 1996-02-22 | 1998-04-30 | Oreal | Composition cosmetique de fixation et de brillance |
JP3605938B2 (ja) | 1996-03-29 | 2004-12-22 | 株式会社コーセー | 睫用化粧料 |
US6228967B1 (en) * | 1996-05-22 | 2001-05-08 | Mona Industries, Inc. | Organosilicone having a carboxyl functional group thereon |
US5849318A (en) | 1996-06-26 | 1998-12-15 | Kao Corporation | Oil-based solid cosmetic composition |
DE19638795A1 (de) * | 1996-09-20 | 1998-03-26 | Basf Ag | Wäßrige oder wäßrig/alkoholische haarkosmetische Formulierung |
US5783657A (en) | 1996-10-18 | 1998-07-21 | Union Camp Corporation | Ester-terminated polyamides of polymerized fatty acids useful in formulating transparent gels in low polarity liquids |
JP3814032B2 (ja) * | 1996-11-01 | 2006-08-23 | 本田技研工業株式会社 | 成形品 |
FR2756176B1 (fr) | 1996-11-26 | 1998-12-18 | Oreal | Composition cosmetique comprenant un compose fluore et presentant un confort ameliore |
CA2220033A1 (fr) | 1996-11-26 | 1998-05-26 | L'oreal | Composition topique sans transfert comprenant un compose fluore ou silicone et presentant un confort ameliore, son utilisation |
FR2758083B1 (fr) | 1997-01-03 | 1999-02-05 | Oreal | Composition cosmetique et/ou dermatologique contenant une dispersion d'un systeme polymerique et utilisation de ce systeme comme tenseur |
US5736125A (en) | 1997-01-10 | 1998-04-07 | National Starch And Chemical Investment Holding Corporation | Compositions containing copolymers as a thickening agent |
EP0909157A1 (fr) * | 1997-01-20 | 1999-04-21 | L'oreal | Composition cosmetique comprenant comme agent de revetement des fibres keratiniques un melange filmogene constitue de particules de polymere filmifiables et de particules non-filmifiables |
US6140431A (en) | 1997-02-27 | 2000-10-31 | Rohm And Haas Company | Process for preparing continuously variable-composition copolymers |
US6433068B1 (en) | 1997-03-07 | 2002-08-13 | David S. Morrison | Hydrocarbon gels as suspending and dispersing agents and products |
AU6548798A (en) * | 1997-03-26 | 1998-10-20 | Avon Products Inc. | Wear resistant cosmetics |
US6267951B1 (en) | 1997-03-26 | 2001-07-31 | Avon Products, Inc. | Cosmetic composition for the nails and hair |
US6303105B1 (en) | 1997-03-26 | 2001-10-16 | Avon Products, Inc. | Cosmetic composition for imparting wear resistance and shine |
US5879670A (en) | 1997-03-31 | 1999-03-09 | Calgon Corporation | Ampholyte polymers for use in personal care products |
FR2761959B1 (fr) * | 1997-04-15 | 1999-05-21 | Oreal | Ensemble de conditionnement et d'application d'un produit fluide |
US6165457A (en) | 1997-05-12 | 2000-12-26 | The Procter & Gamble Company | Personal care compositions containing toughened grafted polymers |
JPH11124312A (ja) | 1997-10-20 | 1999-05-11 | Shiseido Co Ltd | パック化粧料及びその処理方法 |
EP0918069B1 (fr) | 1997-05-30 | 2008-04-09 | Shiseido Company Limited | Compositions contenant un copolymere aux groupes silyles reactifs et methodes de leur emploi |
US6153206A (en) * | 1997-08-27 | 2000-11-28 | Revlon Consumer Products Corporation | Cosmetic compositions |
JPH11100307A (ja) | 1997-09-29 | 1999-04-13 | Kao Corp | 被膜形成剤及び化粧料 |
FR2774587B1 (fr) | 1998-02-09 | 2000-03-10 | Oreal | Utilisation d'une microdispersion de cire dans une composition cosmetique ou dermatologique |
FR2774588B1 (fr) * | 1998-02-11 | 2000-05-05 | Oreal | Composition cosmetique ou dermatologique contenant au moins une proteine de soie d'arachnides naturelle, recombinante ou un analogue |
FR2775566B1 (fr) | 1998-03-03 | 2000-05-12 | Oreal | Cupule porte raisin et ensemble de conditionnement pour un produit de maquillage la comportant |
FR2775593B1 (fr) * | 1998-03-09 | 2002-06-14 | Oreal | Composition filmogene comprenant un polyurethane en dispersion aqueuse et un agent plastifiant |
FR2776509B1 (fr) | 1998-03-31 | 2001-08-10 | Oreal | Composition topique contenant un ester d'acide ou d'alcool gras ramifie en c24 a c28 |
DE69910880T2 (de) | 1998-04-21 | 2004-07-15 | L'oreal | Ein Olefincopolymer mit kontrolierter Kristallisation enthaltende Zusammensetzung zur topischen Anwendung |
US6225390B1 (en) * | 1998-05-08 | 2001-05-01 | Shell Oil Company | Oil gel formulations containing polystyrene-polydimethylsiloxane or polyethylene-polydimethylsiloxane block copolymers dissolved in siloxane monomers |
CA2276568C (fr) * | 1998-07-03 | 2007-01-02 | Kuraray Co., Ltd. | Copolymere sequence et composition polymerique comprenant celui-ci |
FR2782003B1 (fr) * | 1998-08-10 | 2000-10-13 | Oreal | Composition de maquillage ou de soin sans transfert a base d'isoparaffines et de cires synthetiques fonctionnalisees |
US6068421A (en) | 1998-08-25 | 2000-05-30 | Rexam Cosmetic Packaging, Inc. | Protective shell for a cosmetic container |
WO2000026285A1 (fr) | 1998-10-29 | 2000-05-11 | Penreco | Compositions de gel |
US6881776B2 (en) * | 1998-10-29 | 2005-04-19 | Penreco | Gel compositions |
AU1316199A (en) * | 1998-11-12 | 2000-06-05 | Procter & Gamble Company, The | Cosmetic compositions |
US6268466B1 (en) * | 1999-01-04 | 2001-07-31 | Arizona Chemical Company | Tertiary amide terminated polyamides and uses thereof |
DE19903391A1 (de) | 1999-01-29 | 2000-08-03 | Bayer Ag | Wäßriges Überzugsmittel, Verfahren zu seiner Herstellung und seine Verwendung |
US6423306B2 (en) * | 1999-02-26 | 2002-07-23 | L'oreal Sa | Cosmetic compositions containing di-block, tri-block, multi-block and radial block copolymers |
FR2791042B1 (fr) | 1999-03-16 | 2001-05-04 | Oreal | Ensemble articule monopiece |
EP1169364B1 (fr) | 1999-03-18 | 2009-07-29 | California Institute Of Technology | Nouveaux copolymeres a trois sequences et a deux sequences aba, et procedes de preparation correspondant |
FR2791987A1 (fr) * | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
FR2792190B1 (fr) | 1999-04-16 | 2001-09-28 | Sophim | Procede de fabrication d'un emollient non gras a base de cires-esters |
FR2792618B1 (fr) | 1999-04-23 | 2001-06-08 | Oreal | Dispositif de conditionnement et d'application d'un produit ayant un organe d'essorage comprenant une fente |
US6197883B1 (en) | 1999-06-03 | 2001-03-06 | Ppg Industries Ohio, Inc. | Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization |
US6254878B1 (en) | 1999-07-01 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Nail polish compositions containing acrylic polymers |
FR2795957B1 (fr) * | 1999-07-08 | 2001-09-28 | Oreal | Composition de maquillage comprenant des fibres |
JP2003520063A (ja) | 1999-07-09 | 2003-07-02 | ブルジヨワ | 局所組成物の適用用物品及びその製造方法 |
FR2796272B1 (fr) | 1999-07-15 | 2003-09-19 | Oreal | Composition sans cire structuree sous forme rigide par un polymere |
MXPA01002934A (es) | 1999-07-21 | 2002-04-08 | Oreal | Dispositivo para la aplicacion de un producto sobre las fibras queratinicas. |
FR2796529B1 (fr) | 1999-07-21 | 2001-09-21 | Oreal | Dispositif de conditionnement et d'application d'un produit sur les cils ou les sourcils |
FR2796528B1 (fr) | 1999-07-21 | 2001-09-21 | Oreal | Dispositif de conditionnement et d'application d'un produit sur les cils ou les sourcils |
DE19939326A1 (de) | 1999-08-19 | 2001-02-22 | Basf Ag | Wässrige kosmetische Zusammensetzung |
US6174968B1 (en) | 1999-08-24 | 2001-01-16 | Shell Oil Company | Oil gel formulations containing polysiloxane block copolymers dissolved in hydrogenated silicone oils |
FR2798061A1 (fr) | 1999-09-07 | 2001-03-09 | Oreal | Composition cosmetique comprenant des dispersions de particules de polymeres dans une phase grasse liquide |
US7101928B1 (en) | 1999-09-17 | 2006-09-05 | Landec Corporation | Polymeric thickeners for oil-containing compositions |
US6124490A (en) | 1999-10-26 | 2000-09-26 | Mona Industries, Inc. | Zwitterionic siloxane polymers and ionically cross-linked polymers formed therefrom |
US6309629B1 (en) | 1999-12-14 | 2001-10-30 | Avon Products, Inc. | Wear resistant cosmetic compositions |
EP1112735A1 (fr) * | 1999-12-20 | 2001-07-04 | Avon Products, Inc. | Composition cosmétique appliquée sur les cils |
FR2803743B1 (fr) * | 2000-01-14 | 2005-04-15 | Atofina | Compositions cosmetiques contenant des dispersions aqueuses de polymeres, filmogenes en l'absence de solvant organique |
FR2806273B1 (fr) * | 2000-03-16 | 2002-10-04 | Oreal | Dispositif de conditionnement et d'application d'un produit cosmetique ou de soin |
US20020018759A1 (en) | 2000-05-04 | 2002-02-14 | Pagano Frank Charles | Nail enamel compositions, related methods, and a two component kit for painting the nails |
DE10022247A1 (de) | 2000-05-08 | 2001-11-15 | Basf Ag | Polyurethan und dessen Verwendung zur Modifizierung rheologischer Eigenschaften |
FR2809306B1 (fr) | 2000-05-23 | 2004-02-06 | Oreal | Utilisation en cosmetique de copolymeres ethyleniques sequences a caractere elastique et compositions les contenant |
JP4768103B2 (ja) * | 2000-06-06 | 2011-09-07 | 日東電工株式会社 | 粘着剤組成物とその粘着シ―ト類およびこれらの製造方法 |
FR2810237B1 (fr) | 2000-06-15 | 2002-07-26 | Oreal | Composition cosmetique filmogene |
US6423304B1 (en) | 2000-06-15 | 2002-07-23 | Cognis Corporation | Dimerized fatty acid based polyamides useful for clear candle and gel applications |
DE10029697A1 (de) * | 2000-06-16 | 2001-12-20 | Basf Ag | Feststoffhaltige Bindemittelzusammensetzung mit radikalisch polymerisierten Blockcopolymeren |
FR2811546B1 (fr) | 2000-07-13 | 2003-09-26 | Oreal | Kit et procede de maquillage longue tenue |
FR2811885B1 (fr) * | 2000-07-18 | 2003-06-06 | Oreal | Composition cosmetique contenant un copolymere sequence constitue de sequences a indices de refraction differents |
FR2811993B1 (fr) | 2000-07-21 | 2006-08-04 | Oreal | Nouveaux polymeres associatifs cationiques et leur utilisation comme epaississants |
FR2814365B1 (fr) * | 2000-09-28 | 2002-12-27 | Oreal | Composition cosmetique comprenant au moins une phase grasse liquide structuree par des polyurethanes et/ou polyurees |
US6518364B2 (en) * | 2000-09-28 | 2003-02-11 | Symyx Technologies, Inc. | Emulsion living-type free radical polymerization, methods and products of same |
FR2814673B1 (fr) * | 2000-09-29 | 2003-04-11 | Oreal | Composition cosmetique filmogene |
WO2002028358A1 (fr) * | 2000-10-03 | 2002-04-11 | Unilever Plc | Compositions de soins cosmetiques et personnels |
US20020076390A1 (en) | 2000-10-25 | 2002-06-20 | 3M Innovative Properties Company | Acrylic-based copolymer compositions for cosmetic and personal care |
BR0114845A (pt) | 2000-10-25 | 2003-10-07 | 3M Innovative Properties Co | Composição na forma de uma emulsão ou dispersão aquosa |
FR2815847B1 (fr) | 2000-10-27 | 2002-12-13 | Oreal | Composition cosmetique comprenant des fibres et une cire |
FR2816503B1 (fr) | 2000-11-10 | 2003-03-28 | Oreal | Composition cosmetique structuree par un polymere a cristaux liquides thermotrope |
DE10059828A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Kammförmige Copolymere auf Basis von Acryloyldimethyltaurinsäure |
DE10059822A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Saure kosmetische, pharmazeutische und dermatologische Mittel |
DE10059832A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Gepfropfte Copolymere auf Basis von Acryloyldimethyltaurinsäure |
DE10059821A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Tensidfreie kosmetische, dermatologische und pharmazeutische Mittel |
DE10059829A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Gepfropfte Kammpolymere auf Basis von Acryloyldimethyltaurinsäure |
DE10059825A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Verwendung von kammförmigen Copolymeren auf Basis von Acryloyldimethyltaurinsäure in kosmetischen, pharmazeutischen und dermatologischen Mitteln |
DE10059826A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Kosmetische, pharmazeutische und dermatologische Mittel |
DE10059831A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Siliziummodifizierte Kammpolymere auf Basis von Acryloyldimethyltaurinsäure |
JP2002327102A (ja) | 2000-12-01 | 2002-11-15 | Clariant Gmbh | アクリロイルジメチルタウリン酸をベースとするコポリマーおよび相乗作用添加物を含有する組成物 |
DE10059833A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Fluormodifizierte Kammpolymere auf Basis von Acryloyldimethylaurinsäure |
DE10059830A1 (de) | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Kationisch modifizierte Kammpolymere auf Basis von Acryloyldimethyltaurinsäure |
DE10059824A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Elektrolythaltige kosmetische, pharmazeutische und dermatologische Mittel |
DE10059823A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Deodorantien und Antiperspirantien |
DE10059819A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Tensidhaltige kosmetische, dermatologische und pharmazeutische Mittel |
DE10059827A1 (de) | 2000-12-01 | 2002-06-20 | Clariant Gmbh | Kosmetische und dermatologische Haarbehandlungsmittel |
DE10059818A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Dekorative kosmetische und dermatologische Mittel |
JP2002201244A (ja) | 2000-12-28 | 2002-07-19 | Nippon Shokubai Co Ltd | アクリル系ブロック共重合体、制振材用組成物及びアクリル系ブロック共重合体の製造方法 |
US20020159960A1 (en) | 2001-02-27 | 2002-10-31 | Scancarella Neil D. | Method for improving the properties of transfer resistant lip compositions and related compositions and articles |
FR2822698B1 (fr) | 2001-04-03 | 2006-04-21 | Oreal | Nouvelle composition tinctoriale pour la teinture des fibres keratiniques comprenant un colorant monoazoique dicationique |
US20030039621A1 (en) * | 2001-04-10 | 2003-02-27 | L'oreal | Two-coat make-up product, its use and a kit containing the make-up product |
FR2823101B1 (fr) | 2001-04-10 | 2004-02-06 | Oreal | Produit de maquillage bi-couche, ses utilisations et kit de maquillage contenant ce produit |
FR2823103B1 (fr) | 2001-04-10 | 2003-05-23 | Oreal | Produit de maquillage bicouche contenant un pigment goniochromatique et un pigment monocolore et kit de maquillage contenant ce produit |
FR2824267B1 (fr) | 2001-05-04 | 2008-06-27 | Oreal | Composition cosmetique filmogene |
JP4666442B2 (ja) | 2001-07-27 | 2011-04-06 | 株式会社吉野工業所 | 衝撃吸収容器 |
US20030024074A1 (en) * | 2001-08-01 | 2003-02-06 | Hartman Paul H. | Biconcave connector for tubular assemblies and tool handles |
WO2003018423A1 (fr) | 2001-08-21 | 2003-03-06 | L'oréal Usa, Inc. | Articulation virtuelle |
JP2003286142A (ja) | 2002-03-29 | 2003-10-07 | Mitsubishi Chemicals Corp | 毛髪化粧料用重合体組成物およびそれを用いた毛髪化粧料 |
JP4039829B2 (ja) * | 2001-09-13 | 2008-01-30 | 三菱化学株式会社 | 化粧料用樹脂組成物およびそれを用いた化粧料 |
WO2003024414A1 (fr) * | 2001-09-13 | 2003-03-27 | Mitsubishi Chemical Corporation | Compositions de resine pour cosmetiques et cosmetiques |
FR2831430B1 (fr) | 2001-10-26 | 2004-02-06 | Oreal | Composition cosmetique et/ou de soin contenant un polyester-siloxane filmogene, non reticule |
FR2832719B1 (fr) * | 2001-11-29 | 2004-02-13 | Oreal | Copolymeres ethyleniques sequences adhesifs, compositions cosmetiques les contenant, et utilisation de ces copolymeres en cosmetique |
FR2832720B1 (fr) * | 2001-11-29 | 2004-02-13 | Oreal | Copolymeres ethyleniques sequences, compositions cosmetiques les contenant, et utilisation de ces copolymeres en cosmetique |
WO2003046032A2 (fr) | 2001-11-29 | 2003-06-05 | L'oreal | Copolymeres ethyleniques sequences adhesifs, compositions cosmetiques les contenant, et utilisation de ces copolymeres en cosmetique |
FR2834458A1 (fr) | 2002-01-08 | 2003-07-11 | Oreal | Composition cosmetique filmogene, en particulier de vernis a ongles |
US20030185774A1 (en) | 2002-04-02 | 2003-10-02 | Dobbs Suzanne Winegar | Cosmetic coating composition comprising carboxyalkyl cellulose ester |
FR2840205B1 (fr) | 2002-05-31 | 2005-08-05 | Oreal | Shampooings contenant au moins un copolymere sequence amphiphile et au moins un polymere cationique ou amphotere |
FR2840206B1 (fr) | 2002-05-31 | 2005-08-05 | Oreal | Shampooing contenant au moins une silicone et au moins un copolymere lineaire sequence amphiphile, anionique ou non- ionique |
FR2840209B1 (fr) | 2002-05-31 | 2005-09-16 | Oreal | Composition capillaire aqueuse, epaissie par un copolymere lineaire sequence amphiphile |
US7176170B2 (en) * | 2002-05-31 | 2007-02-13 | L'oreal | Shampoo comprising at least one silicone and at least one anionic or nonionic, amphiphilic linear block copolymer |
FR2842417B1 (fr) | 2002-07-19 | 2005-01-21 | Oreal | Composition cosmetique |
US7008629B2 (en) | 2002-07-22 | 2006-03-07 | L'ORéAL S.A. | Compositions comprising at least one heteropolymer and fibers, and methods of using the same |
US7923002B2 (en) | 2002-09-06 | 2011-04-12 | L'oreal S.A. | Composition for coating keratin fibres comprising a tacky wax |
ATE328643T1 (de) | 2002-09-06 | 2006-06-15 | Oreal | Kosmetische zusammensetzung die ein klebriges wachs enthält |
US20060099231A1 (en) | 2002-09-06 | 2006-05-11 | De La Poterie Valerie | Make-up composition for keratin fibres such as eyelashes |
US20060134038A1 (en) | 2002-09-06 | 2006-06-22 | De La Poterie Valerie | Make-up composition for keratin fibres such as eyelashes |
GB2392910A (en) | 2002-09-10 | 2004-03-17 | Bayer Ag | 2-Oxopyrimidine derivatives and their use as human leukocyte elastase inhibitors |
PL375647A1 (en) | 2002-09-10 | 2005-12-12 | Bayer Healthcare Ag | Pyrimidinone derivatives as therapeutic agents against acute and chronic inflammatory, ischaemic and remodelling processes |
FR2844709A1 (fr) | 2002-09-20 | 2004-03-26 | Oreal | Composition cosmetique comprenant des fibres rigides et une cire |
US20060128578A9 (en) | 2002-09-20 | 2006-06-15 | Nathalie Jager Lezer | Cosmetic composition comprising rigid fibres and at least one compound chosen from film-forming polymers and waxes |
US6905696B2 (en) | 2003-01-06 | 2005-06-14 | Color Access, Inc. | Alignment of enhancers in cosmetic compositions |
FR2860142B1 (fr) | 2003-09-26 | 2007-08-17 | Oreal | Produit cosmetique bicouche, ses utilisations et kit de maquillage contenant ce produit |
FR2860156B1 (fr) | 2003-09-26 | 2007-11-02 | Oreal | Composition cosmetique comprenant un agent tenseur et un polymere ethylenique sequence particulier |
FR2864894A1 (fr) * | 2004-01-13 | 2005-07-15 | Oreal | Composition de revetement des fibres keratiniques ayant un extrait sec eleve comprenant un polymere sequence et des fibres |
FR2864896B1 (fr) | 2004-01-13 | 2006-03-31 | Oreal | Composition de revetement des fibres keratiniques comprenant un polymere sequence et un polymere semi-cristallin |
US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
DE102004014806B4 (de) * | 2004-03-24 | 2006-09-14 | Daimlerchrysler Ag | Rapid-Technologie-Bauteil |
US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
FR2871057B1 (fr) | 2004-06-08 | 2006-07-28 | Oreal | Composition cosmetique contenant un ester et un agent filmogene |
US20050287103A1 (en) | 2004-06-08 | 2005-12-29 | Vanina Filippi | Cosmetic composition comprising at least one ester and at least one film-forming polymer |
FR2876011B1 (fr) | 2004-10-05 | 2006-12-29 | Oreal | Procede de maquillage d'un support et kit pour la mise en oeuvre de ce procede |
JP2006151867A (ja) | 2004-11-29 | 2006-06-15 | Rohto Pharmaceut Co Ltd | 固形リップグロス |
FR2880268B1 (fr) | 2005-01-05 | 2008-10-24 | Oreal | Composition brillante et non transfert comprenant deux polymeres sequences |
US20070134181A1 (en) | 2005-12-08 | 2007-06-14 | L'oreal | Cosmetic composition comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant |
FR2904320B1 (fr) * | 2006-07-27 | 2008-09-05 | Oreal | Polymeres sequences, et leur procede de preparation |
FR2904218B1 (fr) * | 2006-07-27 | 2012-10-05 | Oreal | Composition cosmetique associant un copolymere, une huile non volatile et une huile brillante. |
CN101980694A (zh) | 2007-12-05 | 2011-02-23 | 莱雅公司 | 使用硅氧烷树脂和极性蜡的美容性化妆和/或护理方法 |
ES2645387T3 (es) | 2009-06-01 | 2017-12-05 | L'oréal | Composición cosmética que comprende un polímero secuenciado y un aceite éster no volátil |
GB0922457D0 (en) | 2009-12-23 | 2010-02-03 | Parry Mark | GPS enabled software that appraises surfing performance on a mobile device |
US9192561B2 (en) | 2010-05-14 | 2015-11-24 | L'oreal | Compositions containing hyperbranched polyol and acrylic film former |
US8586013B2 (en) | 2010-12-30 | 2013-11-19 | L'oreal | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions having a non-tacky feel |
US10076487B2 (en) | 2010-12-30 | 2018-09-18 | L'oreal | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions |
-
2003
- 2003-09-26 WO PCT/FR2003/002844 patent/WO2004028490A2/fr not_active Application Discontinuation
- 2003-09-26 JP JP2005501932A patent/JP3981130B2/ja not_active Expired - Fee Related
- 2003-09-26 DE DE60335007T patent/DE60335007D1/de not_active Expired - Lifetime
- 2003-09-26 WO PCT/FR2003/002849 patent/WO2004028487A2/fr active Application Filing
- 2003-09-26 BR BR0314489A patent/BR0314489A/pt not_active IP Right Cessation
- 2003-09-26 AU AU2003288305A patent/AU2003288305A1/en not_active Abandoned
- 2003-09-26 US US10/528,698 patent/US20060127334A1/en not_active Abandoned
- 2003-09-26 AT AT03798231T patent/ATE487468T1/de not_active IP Right Cessation
- 2003-09-26 AU AU2003285389A patent/AU2003285389A1/en not_active Abandoned
- 2003-09-26 DE DE60335996T patent/DE60335996D1/de not_active Expired - Lifetime
- 2003-09-26 AU AU2003299071A patent/AU2003299071A1/en not_active Abandoned
- 2003-09-26 WO PCT/FR2003/002840 patent/WO2004028492A2/fr not_active Application Discontinuation
- 2003-09-26 JP JP2005501935A patent/JP3981132B2/ja not_active Expired - Lifetime
- 2003-09-26 AT AT03798229T patent/ATE497756T1/de not_active IP Right Cessation
- 2003-09-26 AU AU2003283478A patent/AU2003283478A1/en not_active Abandoned
- 2003-09-26 DE DE60335009T patent/DE60335009D1/de not_active Expired - Lifetime
- 2003-09-26 EP EP20030798228 patent/EP1565148B1/fr not_active Expired - Lifetime
- 2003-09-26 DE DE60336577T patent/DE60336577D1/de not_active Expired - Lifetime
- 2003-09-26 DE DE60335008T patent/DE60335008D1/de not_active Expired - Lifetime
- 2003-09-26 US US10/529,265 patent/US9017704B2/en active Active
- 2003-09-26 US US10/529,264 patent/US20060147403A1/en not_active Abandoned
- 2003-09-26 AT AT03798230T patent/ATE488221T1/de not_active IP Right Cessation
- 2003-09-26 BR BR0303890A patent/BR0303890A/pt not_active IP Right Cessation
- 2003-09-26 JP JP2005501930A patent/JP3981129B2/ja not_active Expired - Fee Related
- 2003-09-26 AU AU2003299069A patent/AU2003299069A1/en not_active Abandoned
- 2003-09-26 EP EP20030798229 patent/EP1545441B1/fr not_active Expired - Lifetime
- 2003-09-26 AU AU2003290143A patent/AU2003290143A1/en not_active Abandoned
- 2003-09-26 US US10/528,835 patent/US8992903B2/en active Active
- 2003-09-26 JP JP2005501934A patent/JP3981131B2/ja not_active Expired - Fee Related
- 2003-09-26 AT AT03782505T patent/ATE488276T1/de not_active IP Right Cessation
- 2003-09-26 JP JP2003336450A patent/JP2004269497A/ja active Pending
- 2003-09-26 DE DE60334709T patent/DE60334709D1/de not_active Expired - Lifetime
- 2003-09-26 DE DE60334921T patent/DE60334921D1/de not_active Expired - Lifetime
- 2003-09-26 US US10/529,318 patent/US7875265B2/en not_active Expired - Fee Related
- 2003-09-26 US US10/528,699 patent/US20060134032A1/en not_active Abandoned
- 2003-09-26 WO PCT/FR2003/002846 patent/WO2004028494A2/fr not_active Application Discontinuation
- 2003-09-26 JP JP2005501928A patent/JP3984268B2/ja not_active Expired - Fee Related
- 2003-09-26 EP EP20030782505 patent/EP1545440B1/fr not_active Expired - Lifetime
- 2003-09-26 AT AT03798228T patent/ATE503457T1/de not_active IP Right Cessation
- 2003-09-26 WO PCT/FR2003/002847 patent/WO2004028485A2/fr active Application Filing
- 2003-09-26 JP JP2005501929A patent/JP3981128B2/ja not_active Expired - Fee Related
- 2003-09-26 AT AT03780204T patent/ATE485809T1/de not_active IP Right Cessation
- 2003-09-26 AT AT03776945T patent/ATE488222T1/de not_active IP Right Cessation
- 2003-09-26 EP EP20030776945 patent/EP1545438B1/fr not_active Expired - Lifetime
- 2003-09-26 AU AU2003283477A patent/AU2003283477A1/en not_active Abandoned
- 2003-09-26 US US10/529,266 patent/US20060134051A1/en not_active Abandoned
- 2003-09-26 EP EP20030798230 patent/EP1545436B1/fr not_active Expired - Lifetime
- 2003-09-26 US US10/529,267 patent/US20060099164A1/en not_active Abandoned
- 2003-09-26 EP EP03775450A patent/EP1545450A2/fr not_active Withdrawn
- 2003-09-26 WO PCT/FR2003/002841 patent/WO2004028493A2/fr active Application Filing
- 2003-09-26 AU AU2003299072A patent/AU2003299072A1/en not_active Abandoned
- 2003-09-26 WO PCT/FR2003/002848 patent/WO2004028486A2/fr active Application Filing
- 2003-09-26 EP EP20030292383 patent/EP1421928A3/fr not_active Ceased
- 2003-09-26 EP EP20030780204 patent/EP1545439B1/fr not_active Expired - Lifetime
- 2003-09-26 WO PCT/FR2003/002842 patent/WO2004028488A2/fr active Application Filing
- 2003-09-26 AU AU2003286204A patent/AU2003286204A1/en not_active Abandoned
- 2003-09-26 WO PCT/FR2003/002845 patent/WO2004028491A2/fr active Application Filing
- 2003-09-26 JP JP2005501936A patent/JP3981133B2/ja not_active Expired - Lifetime
- 2003-09-26 US US10/670,388 patent/US20040120906A1/en not_active Abandoned
- 2003-09-26 EP EP03778378A patent/EP1545443A2/fr not_active Withdrawn
- 2003-09-26 WO PCT/FR2003/002843 patent/WO2004028489A2/fr active Application Filing
- 2003-09-26 EP EP20030798231 patent/EP1545442B1/fr not_active Expired - Lifetime
- 2003-09-26 AU AU2003299070A patent/AU2003299070A1/en not_active Abandoned
- 2003-09-26 US US10/529,218 patent/US20060115444A1/en not_active Abandoned
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4425326A (en) * | 1980-04-01 | 1984-01-10 | Societe Anonyme Dite : L'oreal | Anhydrous nail varnishes |
US6692733B1 (en) * | 1999-04-06 | 2004-02-17 | L'oreal | Composition comprising polymers having a star structure, the polymers, and their use |
US6410005B1 (en) * | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
US20030059392A1 (en) * | 2001-07-18 | 2003-03-27 | L'oreal | Composition for topical use containing a diblock polymer |
US20040009136A1 (en) * | 2002-05-31 | 2004-01-15 | L'oreal | Aqueous hair treatment compositions, thickened with an amphiphilic linear block copolymer |
US20040039101A1 (en) * | 2002-05-31 | 2004-02-26 | Claude Dubief | Washing compositions comprising at least one amphiphilic block copolymer and at least one cationic or amphoteric polymer |
US20040077788A1 (en) * | 2002-07-19 | 2004-04-22 | Cid Centro De Investigacion Y Desarrollo Tecnologico, S.A. De. C.V. | Block copolymers containing functional groups |
US20040120920A1 (en) * | 2002-09-26 | 2004-06-24 | Bertrand Lion | Novel block polymers and cosmetic compositions and processes comprising them |
US20040120906A1 (en) * | 2002-09-26 | 2004-06-24 | Beatrice Toumi | Nail varnish composition comprising a block polymer |
US20060093568A1 (en) * | 2002-09-26 | 2006-05-04 | Xavier Blin | Composition comprising a block polymer and a film-forming agent |
US20060127334A1 (en) * | 2002-09-26 | 2006-06-15 | Veronique Ferrari | Lipstick comprising a sequenced polymer |
US20060134051A1 (en) * | 2002-09-26 | 2006-06-22 | Xavier Blin | Glossy non-transfer composition comprising a sequenced polymer |
US20060147402A1 (en) * | 2002-09-26 | 2006-07-06 | Xavier Blin | Composition comprising a sequenced polymer and a gelling agent |
US20050106197A1 (en) * | 2003-09-26 | 2005-05-19 | Xavier Blin | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
Cited By (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7875265B2 (en) * | 2002-09-26 | 2011-01-25 | L'oreal | Cosmetic composition comprising a sequenced polymer and a plasticizer |
US20080014158A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US8992903B2 (en) | 2002-09-26 | 2015-03-31 | L'oreal | Composition comprising at least one block polymer and at least one gelling agent |
US7915347B2 (en) | 2002-09-26 | 2011-03-29 | L'oreal S.A. | Block polymers and cosmetic compositions and processes comprising them |
US9017704B2 (en) | 2002-09-26 | 2015-04-28 | L'oreal | Composition comprising a block polymer and a film-forming agent |
US20080014234A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US20080014235A1 (en) * | 2002-09-26 | 2008-01-17 | L'oreal | Novel Block Polymers and Cosmetic Compositions and Processes Comprising Them |
US20040120906A1 (en) * | 2002-09-26 | 2004-06-24 | Beatrice Toumi | Nail varnish composition comprising a block polymer |
US7932324B2 (en) | 2002-09-26 | 2011-04-26 | L'oreal | Block polymers and cosmetic compositions and processes comprising them |
US7803877B2 (en) | 2002-09-26 | 2010-09-28 | L'oreal S.A. | Block polymers and cosmetic compositions and processes comprising them |
US8119110B2 (en) | 2003-09-26 | 2012-02-21 | L'oreal S.A. | Cosmetic composition comprising a block polymer and a non-volatile silicone oil |
US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
US20050220747A1 (en) * | 2004-03-25 | 2005-10-06 | Bertrand Lion | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US8728451B2 (en) * | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US20070196306A1 (en) * | 2005-07-22 | 2007-08-23 | Nathalie Jager Lezer | Process for coating eyelashes |
US8460645B2 (en) | 2005-07-22 | 2013-06-11 | L'oreal S.A. | Process for coating eyelashes |
US8710152B2 (en) | 2006-07-27 | 2014-04-29 | L'oreal | Block polymers and their process of preparation |
US20080145325A1 (en) * | 2006-09-13 | 2008-06-19 | Lizabeth-Anne Coffey-Dawe | Nail varnish comprising at least one resin |
US20100215605A1 (en) * | 2008-11-24 | 2010-08-26 | L'oreal | Solid cosmetic composition for application to keratin fibres |
US9895561B2 (en) | 2009-06-01 | 2018-02-20 | L'oreal | Composition containing a block polymer and a nonvolatile ester oil |
US20110020263A1 (en) * | 2009-06-01 | 2011-01-27 | L'oreal | Composition containing a block polymer and a nonvolatile ester oil |
US20120199151A1 (en) * | 2009-07-21 | 2012-08-09 | Danny Lee Haile | Compositions for removable gel applications for nails and methods of their use |
US9023326B2 (en) * | 2009-07-21 | 2015-05-05 | Nail Alliance Llc | Compositions for removable gel applications for nails and methods of their use |
US9526686B2 (en) | 2009-07-21 | 2016-12-27 | Nail Alliance, Llc | Compositions for removable gel applications for nails and methods of their use |
US20120118314A1 (en) * | 2009-07-21 | 2012-05-17 | Danny Lee Haile | Compositions for removable gel applications for nails and methods of their use |
US9125468B2 (en) | 2010-03-29 | 2015-09-08 | L'oreal | Device for the application of fibers to human keratinous fibers |
US20130213426A1 (en) * | 2010-11-02 | 2013-08-22 | L'oreal | Two-step nail polish product |
US10532021B2 (en) | 2011-12-20 | 2020-01-14 | L'oreal | Composition comprising a specific acrylic polymer and a silicone copolymer, and method for treating keratin fibres using same |
US10744080B2 (en) | 2011-12-20 | 2020-08-18 | L'oreal | Method for the application of a pigment dyeing composition based on specific acrylic polymer and on silicone copolymer, and appropriate device |
US11376208B2 (en) | 2011-12-20 | 2022-07-05 | L'oreal | Pigment dyeing composition based on a particular acrylic polymer and silicone copolymer |
US11576852B2 (en) | 2012-06-29 | 2023-02-14 | L'oreal | Two coat process for dyeing keratin fibres |
US20170360683A1 (en) * | 2016-06-15 | 2017-12-21 | Mycone Dental Supply Co., Inc. | One Part Acrylic Nail Formulation |
US11771629B2 (en) | 2016-06-23 | 2023-10-03 | L'oreal | Process for the elongation and/or densification of fibers |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20060134032A1 (en) | Nail varnish composition comprising a sequenced polymer | |
US7915347B2 (en) | Block polymers and cosmetic compositions and processes comprising them | |
US8710152B2 (en) | Block polymers and their process of preparation | |
US7423104B2 (en) | Hyperbranched copolymer comprising monomers of choice, a composition, and a cosmetic method | |
US8119110B2 (en) | Cosmetic composition comprising a block polymer and a non-volatile silicone oil | |
US7906126B2 (en) | Adhesive block ethylenic copolymers, cosmetic compositions containing them and cosmetic use of these copolymers | |
US8852564B2 (en) | Cosmetic composition combining a copolymer, a non-volatile oil and a glossy oil | |
US10745582B2 (en) | Dispersion of soft polymer particles, cosmetic composition comprising it and cosmetic treatment method | |
US20050220731A1 (en) | Nail varnish composition comprising at least one polymer and at least one plasticizer | |
US20060127339A1 (en) | Two-coat makeup product with improved staying power, uses thereof and makeup kit comprising this product | |
US20100178257A1 (en) | Block polymer, cosmetic composition comprising it and cosmetic treatment process | |
US20080175804A1 (en) | Novel block polymers, compositions comprising them, and treatment methods | |
ES2363604T3 (es) | Composición de esmalte de uñas que contiene un polímero secuenciado y un agente plastificante. | |
US20060008431A1 (en) | Copolymer functionalized with an iodine atom, compositions comprising the copolymer and treatment processes | |
US20080181859A1 (en) | Novel block (Co)polymers, compositions containing them, method of treatment and method of preparation | |
ES2353495T3 (es) | Polímeros secuenciados y composiciones cosméticas que contienen tales polímeros. | |
US20100021408A1 (en) | Block polymer, cosmetic composition comprising it and cosmetic treatment process | |
US20050244364A1 (en) | Novel polymers, compositions comprising them, processes therefor, and use thereof | |
US20050288410A1 (en) | Copolymer functionalized with an iodine atom, composition comprising it and treatment process | |
US20050220732A1 (en) | Novel polymers, compositions comprising them, processes therefor and use thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: L'OREAL S.A., FRANCE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ILEKTI, PHILIPPE;LION, BERTRAND;REEL/FRAME:017592/0435;SIGNING DATES FROM 20050415 TO 20050421 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |