TWI606989B - 低ｃｔｅ之離子可交換玻璃組成物及包含其之玻璃物件 - Google Patents
低ｃｔｅ之離子可交換玻璃組成物及包含其之玻璃物件 Download PDFInfo
- Publication number
- TWI606989B TWI606989B TW102107040A TW102107040A TWI606989B TW I606989 B TWI606989 B TW I606989B TW 102107040 A TW102107040 A TW 102107040A TW 102107040 A TW102107040 A TW 102107040A TW I606989 B TWI606989 B TW I606989B
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- Taiwan
- Prior art keywords
- glass
- mole
- cover layer
- composition
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- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims description 481
- 239000000203 mixture Substances 0.000 title claims description 270
- 239000010410 layer Substances 0.000 claims description 113
- 238000005342 ion exchange Methods 0.000 claims description 48
- 239000012792 core layer Substances 0.000 claims description 38
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 33
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 32
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 30
- 229910052708 sodium Inorganic materials 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 19
- 229910052744 lithium Inorganic materials 0.000 claims description 18
- 229910052700 potassium Inorganic materials 0.000 claims description 18
- 229910052725 zinc Inorganic materials 0.000 claims description 18
- 229910052791 calcium Inorganic materials 0.000 claims description 17
- 229910052749 magnesium Inorganic materials 0.000 claims description 17
- 229910052788 barium Inorganic materials 0.000 claims description 16
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 11
- 238000009792 diffusion process Methods 0.000 claims description 11
- 239000006025 fining agent Substances 0.000 claims description 7
- 239000007791 liquid phase Substances 0.000 claims description 7
- 239000006059 cover glass Substances 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- 238000005253 cladding Methods 0.000 claims description 3
- 239000005328 architectural glass Substances 0.000 claims 2
- 230000005693 optoelectronics Effects 0.000 claims 2
- 239000008395 clarifying agent Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 description 27
- 239000005340 laminated glass Substances 0.000 description 25
- 150000002500 ions Chemical class 0.000 description 23
- 239000007788 liquid Substances 0.000 description 17
- 239000011701 zinc Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- 239000006060 molten glass Substances 0.000 description 14
- 230000008569 process Effects 0.000 description 14
- 239000003513 alkali Substances 0.000 description 13
- 239000000155 melt Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000005728 strengthening Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 238000003475 lamination Methods 0.000 description 6
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 238000005496 tempering Methods 0.000 description 5
- 229910001409 divalent cation oxide Inorganic materials 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229910018068 Li 2 O Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910001423 beryllium ion Inorganic materials 0.000 description 3
- 238000003280 down draw process Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052839 forsterite Inorganic materials 0.000 description 2
- 239000000156 glass melt Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 229910018071 Li 2 O 2 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910001408 cation oxide Inorganic materials 0.000 description 1
- 238000007495 chemical tempering process Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000006058 strengthened glass Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/308—Heat stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/02—Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261604833P | 2012-02-29 | 2012-02-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201341334A TW201341334A (zh) | 2013-10-16 |
| TWI606989B true TWI606989B (zh) | 2017-12-01 |
Family
ID=47844518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW102107040A TWI606989B (zh) | 2012-02-29 | 2013-02-27 | 低ｃｔｅ之離子可交換玻璃組成物及包含其之玻璃物件 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9868664B2 (enEXAMPLES) |
| EP (1) | EP2819965B1 (enEXAMPLES) |
| JP (1) | JP6214570B2 (enEXAMPLES) |
| KR (1) | KR102250735B1 (enEXAMPLES) |
| CN (1) | CN104379532B9 (enEXAMPLES) |
| IN (1) | IN2014DN07444A (enEXAMPLES) |
| TW (1) | TWI606989B (enEXAMPLES) |
| WO (1) | WO2013130665A2 (enEXAMPLES) |
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| US9346699B2 (en) | 2008-10-06 | 2016-05-24 | Corning Incorporated | Method of making a glass laminate having controlled strength |
| US9302937B2 (en) | 2010-05-14 | 2016-04-05 | Corning Incorporated | Damage-resistant glass articles and method |
| TWI572480B (zh) | 2011-07-25 | 2017-03-01 | 康寧公司 | 經層壓及離子交換之強化玻璃疊層 |
| IN2014DN07758A (enEXAMPLES) | 2012-02-29 | 2015-05-15 | Corning Inc | |
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| WO2013130665A2 (en) | 2012-02-29 | 2013-09-06 | Corning Incorporated | Low cte, ion-exchangeable glass compositions and glass articles comprising the same |
| US10202303B2 (en) | 2012-10-04 | 2019-02-12 | Corning Incorporated | Compressively stressed laminated glass article via photosensitive glass and method of making the article |
| US20150251949A1 (en) * | 2012-10-04 | 2015-09-10 | Corning Incorporated | Article with glass layer and glass-ceramic layer and method of making the article |
| US9434632B2 (en) * | 2013-02-26 | 2016-09-06 | Corning Incorporated | Glass forming apparatus and method |
| US11079309B2 (en) | 2013-07-26 | 2021-08-03 | Corning Incorporated | Strengthened glass articles having improved survivability |
| JP6976057B2 (ja) * | 2013-11-20 | 2021-12-01 | コーニング インコーポレイテッド | 耐スクラッチアルミノホウケイ酸ガラス |
| US9517968B2 (en) | 2014-02-24 | 2016-12-13 | Corning Incorporated | Strengthened glass with deep depth of compression |
| JP6542758B2 (ja) * | 2014-04-24 | 2019-07-10 | 日本板硝子株式会社 | ガラス組成物、化学強化用ガラス板、強化ガラス板およびディスプレイ用強化ガラス基板 |
| KR102433785B1 (ko) * | 2014-05-07 | 2022-08-18 | 코닝 인코포레이티드 | 적층 유리 제품 및 이의 형성방법 |
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| TWI705889B (zh) | 2014-06-19 | 2020-10-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| US11097974B2 (en) | 2014-07-31 | 2021-08-24 | Corning Incorporated | Thermally strengthened consumer electronic glass and related systems and methods |
| EP3183223A1 (en) * | 2014-08-21 | 2017-06-28 | Corning Incorporated | Methods for preventing blisters in laminated glass articles and laminated glass articles formed therefrom |
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| US10034801B2 (en) | 2014-10-03 | 2018-07-31 | The Procter & Gamble Company | Adult disposable absorbent articles and arrays comprising improved product lengths |
| US11123959B2 (en) | 2014-10-07 | 2021-09-21 | Corning Incorporated | Glass article with determined stress profile and method of producing the same |
| TWI699343B (zh) | 2014-10-08 | 2020-07-21 | 美商康寧公司 | 含有金屬氧化物濃度梯度之玻璃以及玻璃陶瓷 |
| US10864117B2 (en) | 2014-10-09 | 2020-12-15 | The Procter & Gamble Company | Length-to-waist and hip-to-side silhouettes of adult disposable absorbent articles and arrays |
| CN107108317B (zh) | 2014-10-30 | 2019-11-05 | 康宁股份有限公司 | 用于对玻璃制品的边缘进行密封的方法和设备 |
| US10195825B2 (en) | 2014-10-30 | 2019-02-05 | Corning Incorporated | Methods for strengthening the edge of laminated glass articles and laminated glass articles formed therefrom |
| KR102639258B1 (ko) * | 2014-10-30 | 2024-02-22 | 코닝 인코포레이티드 | 유리-세라믹 조성물 및 이를 혼입한 적층 유리 제품 |
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| WO2016196615A1 (en) * | 2015-06-02 | 2016-12-08 | Corning Incorporated | Laminated glass article with tinted layer |
| KR20180019127A (ko) * | 2015-06-02 | 2018-02-23 | 코닝 인코포레이티드 | 도광판들을 포함하는 적층 구조들 및 자동차 글레이징들 |
| JP6867946B2 (ja) | 2015-06-30 | 2021-05-12 | ＡｖａｎＳｔｒａｔｅ株式会社 | ディスプレイ用ガラス基板およびその製造方法 |
| KR102295451B1 (ko) | 2015-06-30 | 2021-08-27 | 아반스트레이트 가부시키가이샤 | 디스플레이용 유리 기판 및 그 제조 방법 |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
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| KR20220113539A (ko) | 2016-04-08 | 2022-08-12 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함하는 유리-계 제품 |
| US10271442B2 (en) | 2016-04-08 | 2019-04-23 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
| WO2017188126A1 (ja) | 2016-04-27 | 2017-11-02 | 旭硝子株式会社 | 無アルカリガラス |
| CN109071318B (zh) | 2016-05-04 | 2022-09-27 | 康宁股份有限公司 | 着色硅铝酸盐玻璃组合物及包含该玻璃组合物的玻璃制品 |
| TW201806884A (zh) | 2016-05-04 | 2018-03-01 | 康寧公司 | 玻璃積層系統與方法 |
| CN115028360B (zh) * | 2016-05-27 | 2025-05-27 | 康宁股份有限公司 | 耐破裂和耐划痕玻璃制品 |
| TWI763731B (zh) * | 2016-11-07 | 2022-05-11 | 美商康寧公司 | 低黏度玻璃及其製造方法與系統 |
| US10065880B2 (en) | 2016-11-07 | 2018-09-04 | Corning Incorporated | Lithium containing glasses |
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Also Published As
| Publication number | Publication date |
|---|---|
| US9868664B2 (en) | 2018-01-16 |
| EP2819965A2 (en) | 2015-01-07 |
| TW201341334A (zh) | 2013-10-16 |
| CN104379532B9 (zh) | 2021-08-24 |
| EP2819965B1 (en) | 2018-09-19 |
| IN2014DN07444A (enEXAMPLES) | 2015-04-24 |
| CN104379532A (zh) | 2015-02-25 |
| CN104379532B (zh) | 2021-07-30 |
| WO2013130665A2 (en) | 2013-09-06 |
| KR20140129345A (ko) | 2014-11-06 |
| JP6214570B2 (ja) | 2017-10-18 |
| KR102250735B1 (ko) | 2021-05-12 |
| US20150030827A1 (en) | 2015-01-29 |
| WO2013130665A3 (en) | 2014-01-16 |
| JP2015516930A (ja) | 2015-06-18 |
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