TWI295326B - Carbon nanofiber and method for producing carbon nanofiber - Google Patents
Carbon nanofiber and method for producing carbon nanofiber Download PDFInfo
- Publication number
- TWI295326B TWI295326B TW091136984A TW91136984A TWI295326B TW I295326 B TWI295326 B TW I295326B TW 091136984 A TW091136984 A TW 091136984A TW 91136984 A TW91136984 A TW 91136984A TW I295326 B TWI295326 B TW I295326B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalyst
- group
- carbon fiber
- nano carbon
- nano
- Prior art date
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 93
- 238000004519 manufacturing process Methods 0.000 title claims description 65
- 239000002134 carbon nanofiber Substances 0.000 title claims description 9
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 175
- 239000003054 catalyst Substances 0.000 claims description 154
- 239000000463 material Substances 0.000 claims description 132
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 101
- 239000004917 carbon fiber Substances 0.000 claims description 101
- 239000000126 substance Substances 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 47
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 32
- 239000000758 substrate Substances 0.000 claims description 32
- 229910052799 carbon Inorganic materials 0.000 claims description 30
- 229910052742 iron Inorganic materials 0.000 claims description 29
- 229910052759 nickel Inorganic materials 0.000 claims description 29
- 239000010419 fine particle Substances 0.000 claims description 19
- 238000005229 chemical vapour deposition Methods 0.000 claims description 17
- 238000004050 hot filament vapor deposition Methods 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 17
- 229910052720 vanadium Inorganic materials 0.000 claims description 17
- 229910052804 chromium Inorganic materials 0.000 claims description 16
- 229910052758 niobium Inorganic materials 0.000 claims description 16
- 229910052715 tantalum Inorganic materials 0.000 claims description 16
- 229910052735 hafnium Inorganic materials 0.000 claims description 15
- 229910052748 manganese Inorganic materials 0.000 claims description 15
- 229910052750 molybdenum Inorganic materials 0.000 claims description 15
- 229910052718 tin Inorganic materials 0.000 claims description 14
- 229910052721 tungsten Inorganic materials 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 229910052719 titanium Inorganic materials 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 238000010586 diagram Methods 0.000 claims description 3
- 239000002072 nanorope Substances 0.000 claims description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 1
- 239000010949 copper Substances 0.000 description 65
- 239000007789 gas Substances 0.000 description 65
- 229910052802 copper Inorganic materials 0.000 description 41
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000002245 particle Substances 0.000 description 27
- 239000000835 fiber Substances 0.000 description 21
- 239000010410 layer Substances 0.000 description 19
- 239000000243 solution Substances 0.000 description 18
- 239000011859 microparticle Substances 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 229910052738 indium Inorganic materials 0.000 description 14
- 239000003575 carbonaceous material Substances 0.000 description 13
- 229910052725 zinc Inorganic materials 0.000 description 12
- 229910052787 antimony Inorganic materials 0.000 description 10
- 238000010790 dilution Methods 0.000 description 10
- 239000012895 dilution Substances 0.000 description 10
- 238000001878 scanning electron micrograph Methods 0.000 description 10
- 239000002356 single layer Substances 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 239000002121 nanofiber Substances 0.000 description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 229910052707 ruthenium Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- -1 0 H f Inorganic materials 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical compound C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical group [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 241000645849 Marseilleviridae Species 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Composite Materials (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Chemical Vapour Deposition (AREA)
- Inorganic Fibers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002001773A JP4404961B2 (ja) | 2002-01-08 | 2002-01-08 | カーボンナノ繊維の製造方法。 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200301785A TW200301785A (en) | 2003-07-16 |
| TWI295326B true TWI295326B (en) | 2008-04-01 |
Family
ID=27641821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW091136984A TWI295326B (en) | 2002-01-08 | 2002-12-23 | Carbon nanofiber and method for producing carbon nanofiber |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6986877B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP4404961B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100627949B1 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI295326B (cg-RX-API-DMAC7.html) |
Families Citing this family (114)
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| KR100478145B1 (ko) * | 2002-03-06 | 2005-03-22 | 재단법인 포항산업과학연구원 | 탄소나노섬유의 제조방법 |
| JP2003298338A (ja) * | 2002-04-02 | 2003-10-17 | Fuji Xerox Co Ltd | アンテナおよび通信装置 |
| JP4454353B2 (ja) | 2003-05-09 | 2010-04-21 | 昭和電工株式会社 | 直線性微細炭素繊維及びそれを用いた樹脂複合体 |
| JP4665113B2 (ja) * | 2003-06-18 | 2011-04-06 | 国立大学法人京都工芸繊維大学 | 微粒子製造方法および微粒子製造装置 |
| WO2005061382A1 (en) * | 2003-12-24 | 2005-07-07 | Nanometrix Inc. | Continuous production of carbon nanotubes |
| JP2005294109A (ja) * | 2004-04-01 | 2005-10-20 | Toyota Motor Corp | 燃料電池用基体及び燃料電池 |
| US20050233380A1 (en) * | 2004-04-19 | 2005-10-20 | Sdc Materials, Llc. | High throughput discovery of materials through vapor phase synthesis |
| CN1302986C (zh) * | 2004-05-10 | 2007-03-07 | 华东理工大学 | 一种制备碳纳米管的方法 |
| CN101018737A (zh) * | 2004-07-16 | 2007-08-15 | 独立行政法人科学技术振兴机构 | 催化剂粒径控制式碳纳米结构物的制造方法、制造装置以及碳纳米结构物 |
| JPWO2006033367A1 (ja) * | 2004-09-24 | 2008-05-15 | 独立行政法人科学技術振興機構 | カーボンナノ構造物の製造方法及び製造装置 |
| CN101076716B (zh) * | 2004-10-08 | 2011-04-13 | Sdc材料有限责任公司 | 采样和收集在气流中流动的粉末的装置和方法 |
| TWI465391B (zh) * | 2004-11-10 | 2014-12-21 | 尼康股份有限公司 | Carbon nanotube aggregate and manufacturing method thereof |
| DE102004054959A1 (de) * | 2004-11-13 | 2006-05-18 | Bayer Technology Services Gmbh | Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator |
| US7739285B2 (en) * | 2005-09-29 | 2010-06-15 | Sap Ag | Efficient handling of multipart queries against relational data |
| JP5131616B2 (ja) * | 2005-10-27 | 2013-01-30 | ニッタ株式会社 | カーボンファイバ製造用触媒担持基板およびカーボンファイバ製造用触媒担持基板の製造方法 |
| JP2007212006A (ja) * | 2006-02-07 | 2007-08-23 | Nissan Motor Co Ltd | 触媒燃焼器の燃焼状態検知装置 |
| JP5072244B2 (ja) * | 2006-03-20 | 2012-11-14 | 公立大学法人大阪府立大学 | カーボンナノコイル製造用触媒粒子およびその製造方法ならびにカーボンナノコイルの製造方法 |
| KR100773151B1 (ko) * | 2006-04-05 | 2007-11-02 | 금호전기주식회사 | 탄소나노계 물질을 이용한 전계방출램프용의 음극선제조방법 |
| JP5002187B2 (ja) * | 2006-05-12 | 2012-08-15 | 株式会社アルバック | カーボンナノコイルの成長方法 |
| WO2007148820A1 (ja) * | 2006-06-23 | 2007-12-27 | Sakai Ovex Co., Ltd. | 樹脂材料 |
| JP2008059841A (ja) * | 2006-08-30 | 2008-03-13 | Toyota Motor Corp | 燃料電池及び燃料電池の製造方法 |
| DE102006047691A1 (de) * | 2006-10-09 | 2008-04-17 | Siemens Audiologische Technik Gmbh | Absorption elektromagnetischer Strahlungen in Hörvorrichtungen |
| US20100247419A1 (en) * | 2006-11-01 | 2010-09-30 | Nguyen Khe C | Solid phase synthesized carbon nano fiber and tube |
| JP4197729B2 (ja) * | 2006-12-21 | 2008-12-17 | 昭和電工株式会社 | 炭素繊維および炭素繊維製造用触媒 |
| CN100439242C (zh) * | 2006-12-26 | 2008-12-03 | 华东理工大学 | 制备螺旋纳米碳纤维的方法 |
| US8158217B2 (en) | 2007-01-03 | 2012-04-17 | Applied Nanostructured Solutions, Llc | CNT-infused fiber and method therefor |
| US20120189846A1 (en) * | 2007-01-03 | 2012-07-26 | Lockheed Martin Corporation | Cnt-infused ceramic fiber materials and process therefor |
| US9005755B2 (en) | 2007-01-03 | 2015-04-14 | Applied Nanostructured Solutions, Llc | CNS-infused carbon nanomaterials and process therefor |
| US8951631B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused metal fiber materials and process therefor |
| US8951632B2 (en) * | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused carbon fiber materials and process therefor |
| US20100279569A1 (en) * | 2007-01-03 | 2010-11-04 | Lockheed Martin Corporation | Cnt-infused glass fiber materials and process therefor |
| US9173967B1 (en) * | 2007-05-11 | 2015-11-03 | SDCmaterials, Inc. | System for and method of processing soft tissue and skin with fluids using temperature and pressure changes |
| JP4963679B2 (ja) * | 2007-05-29 | 2012-06-27 | キヤノン株式会社 | 液体吐出ヘッド用基体及びその製造方法、並びに該基体を用いる液体吐出ヘッド |
| US20090081383A1 (en) * | 2007-09-20 | 2009-03-26 | Lockheed Martin Corporation | Carbon Nanotube Infused Composites via Plasma Processing |
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| US8466044B2 (en) * | 2008-08-07 | 2013-06-18 | Sandisk 3D Llc | Memory cell that includes a carbon-based memory element and methods forming the same |
| US8835892B2 (en) * | 2008-10-30 | 2014-09-16 | Sandisk 3D Llc | Electronic devices including carbon nano-tube films having boron nitride-based liners, and methods of forming the same |
| US20100108976A1 (en) * | 2008-10-30 | 2010-05-06 | Sandisk 3D Llc | Electronic devices including carbon-based films, and methods of forming such devices |
| US8421050B2 (en) * | 2008-10-30 | 2013-04-16 | Sandisk 3D Llc | Electronic devices including carbon nano-tube films having carbon-based liners, and methods of forming the same |
| CN102292853B (zh) * | 2009-02-04 | 2014-05-14 | 独立行政法人产业技术综合研究所 | 锂二次电池用纤维电极及其制造方法以及具备纤维电极的锂二次电池 |
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| JP2944246B2 (ja) * | 1990-09-29 | 1999-08-30 | セントラル硝子株式会社 | コイル状炭素繊維の製造方法 |
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| JP3491747B2 (ja) * | 1999-12-31 | 2004-01-26 | 喜萬 中山 | カーボンナノコイルの製造方法及び触媒 |
| JP3595233B2 (ja) * | 2000-02-16 | 2004-12-02 | 株式会社ノリタケカンパニーリミテド | 電子放出源及びその製造方法 |
| JP3734400B2 (ja) * | 2000-02-25 | 2006-01-11 | 双葉電子工業株式会社 | 電子放出素子 |
| JP3585033B2 (ja) * | 2000-04-29 | 2004-11-04 | 喜萬 中山 | カーボンナノコイル生成用のインジウム・スズ・鉄系触媒の製造方法 |
| ATE546412T1 (de) * | 2000-06-16 | 2012-03-15 | Penn State Res Found | Verfahren zur herstellung von kohlenstofffasern |
| US6849245B2 (en) * | 2001-12-11 | 2005-02-01 | Catalytic Materials Llc | Catalysts for producing narrow carbon nanostructures |
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| US20030148097A1 (en) | 2003-08-07 |
| JP2003213530A (ja) | 2003-07-30 |
| KR20030060801A (ko) | 2003-07-16 |
| TW200301785A (en) | 2003-07-16 |
| KR100627949B1 (ko) | 2006-09-22 |
| JP4404961B2 (ja) | 2010-01-27 |
| US6986877B2 (en) | 2006-01-17 |
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