TWI291478B - Flame retardant compositions - Google Patents
Flame retardant compositions Download PDFInfo
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- TWI291478B TWI291478B TW092128535A TW92128535A TWI291478B TW I291478 B TWI291478 B TW I291478B TW 092128535 A TW092128535 A TW 092128535A TW 92128535 A TW92128535 A TW 92128535A TW I291478 B TWI291478 B TW I291478B
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- carbon atoms
- acid
- alkyl
- bis
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- 239000000203 mixture Substances 0.000 title claims abstract description 104
- 239000003063 flame retardant Substances 0.000 title claims abstract description 100
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 89
- -1 polypropylene Polymers 0.000 claims abstract description 205
- 239000002253 acid Substances 0.000 claims abstract description 63
- 150000001412 amines Chemical class 0.000 claims abstract description 62
- 239000003381 stabilizer Substances 0.000 claims abstract description 41
- 239000000945 filler Substances 0.000 claims abstract description 25
- 239000002516 radical scavenger Substances 0.000 claims abstract description 23
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 14
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 9
- 239000011574 phosphorus Substances 0.000 claims abstract description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001301 oxygen Substances 0.000 claims abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
- 230000002195 synergetic effect Effects 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 98
- 125000000217 alkyl group Chemical group 0.000 claims description 81
- 229920000642 polymer Polymers 0.000 claims description 80
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 64
- 239000001257 hydrogen Substances 0.000 claims description 57
- 229910052739 hydrogen Inorganic materials 0.000 claims description 57
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 56
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 46
- 125000003118 aryl group Chemical group 0.000 claims description 44
- 150000001875 compounds Chemical class 0.000 claims description 43
- 229920001577 copolymer Polymers 0.000 claims description 43
- 239000000654 additive Substances 0.000 claims description 31
- 125000002947 alkylene group Chemical group 0.000 claims description 31
- 239000005977 Ethylene Substances 0.000 claims description 30
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 28
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims description 26
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 22
- 239000011159 matrix material Substances 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 125000003545 alkoxy group Chemical group 0.000 claims description 18
- 150000002148 esters Chemical class 0.000 claims description 18
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 16
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000000052 vinegar Substances 0.000 claims description 13
- 235000021419 vinegar Nutrition 0.000 claims description 13
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 12
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 11
- 125000006309 butyl amino group Chemical group 0.000 claims description 11
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 11
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 11
- 239000000454 talc Substances 0.000 claims description 11
- 229910052623 talc Inorganic materials 0.000 claims description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 10
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 10
- 229940116351 sebacate Drugs 0.000 claims description 10
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 229920000620 organic polymer Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 6
- 229910052740 iodine Inorganic materials 0.000 claims description 6
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims description 6
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 125000001624 naphthyl group Chemical group 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 235000021317 phosphate Nutrition 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical group C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000002102 aryl alkyloxo group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 125000000000 cycloalkoxy group Chemical group 0.000 claims description 4
- 235000019197 fats Nutrition 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 4
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 3
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- 125000003282 alkyl amino group Chemical group 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- PXXJHWLDUBFPOL-UHFFFAOYSA-N benzamidine Chemical compound NC(=N)C1=CC=CC=C1 PXXJHWLDUBFPOL-UHFFFAOYSA-N 0.000 claims description 3
- IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000004914 cyclooctane Substances 0.000 claims description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 3
- 238000002309 gasification Methods 0.000 claims description 3
- 150000002430 hydrocarbons Chemical group 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 150000002923 oximes Chemical class 0.000 claims description 3
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 3
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- NZUPFZNVGSWLQC-UHFFFAOYSA-N 1,3,5-tris(2,3-dibromopropyl)-1,3,5-triazinane-2,4,6-trione Chemical compound BrCC(Br)CN1C(=O)N(CC(Br)CBr)C(=O)N(CC(Br)CBr)C1=O NZUPFZNVGSWLQC-UHFFFAOYSA-N 0.000 claims description 2
- SCSMZMBYJMIJTK-UHFFFAOYSA-N 2,4,9,10,11-pentaoxa-5,8-diaza-1lambda5,3lambda5-diphosphatricyclo[6.1.1.13,5]undecane 1,3-dioxide Chemical compound O1P(=O)(O2)ON2CCN2OP1(=O)O2 SCSMZMBYJMIJTK-UHFFFAOYSA-N 0.000 claims description 2
- GVLRGMSHUKNBDP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-ylamino)ethanol Chemical compound OCCNC1=NC=NC=N1 GVLRGMSHUKNBDP-UHFFFAOYSA-N 0.000 claims description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 2
- UWDMKTDPDJCJOP-UHFFFAOYSA-N 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-ium-4-carboxylate Chemical compound CC1(C)CC(O)(C(O)=O)CC(C)(C)N1 UWDMKTDPDJCJOP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- UJOHNXQDVUADCG-UHFFFAOYSA-L aluminum;magnesium;carbonate Chemical compound [Mg+2].[Al+3].[O-]C([O-])=O UJOHNXQDVUADCG-UHFFFAOYSA-L 0.000 claims description 2
- 230000008901 benefit Effects 0.000 claims description 2
- 125000002619 bicyclic group Chemical group 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 210000000078 claw Anatomy 0.000 claims description 2
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 2
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 claims description 2
- 125000005647 linker group Chemical group 0.000 claims description 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
- 229920000582 polyisocyanurate Polymers 0.000 claims description 2
- 239000000779 smoke Substances 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- JZZBTMVTLBHJHL-UHFFFAOYSA-N tris(2,3-dichloropropyl) phosphate Chemical compound ClCC(Cl)COP(=O)(OCC(Cl)CCl)OCC(Cl)CCl JZZBTMVTLBHJHL-UHFFFAOYSA-N 0.000 claims description 2
- 235000021081 unsaturated fats Nutrition 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- 150000002431 hydrogen Chemical group 0.000 claims 15
- 239000004593 Epoxy Substances 0.000 claims 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims 2
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 claims 2
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 claims 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims 1
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims 1
- RPUFWOAXMFQSDJ-UHFFFAOYSA-N 1,1,2,3,3,4-hexachlorocyclopentane Chemical compound ClC1CC(Cl)(Cl)C(Cl)C1(Cl)Cl RPUFWOAXMFQSDJ-UHFFFAOYSA-N 0.000 claims 1
- BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 claims 1
- QMHVPCORYVUUBD-UHFFFAOYSA-N 2,2,3,3-tetrachlorodecanoic acid Chemical compound CCCCCCCC(Cl)(Cl)C(Cl)(Cl)C(O)=O QMHVPCORYVUUBD-UHFFFAOYSA-N 0.000 claims 1
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims 1
- SKWTVENEYZYQLV-UHFFFAOYSA-N 3,4-diaminophthalic acid Chemical compound NC1=CC=C(C(O)=O)C(C(O)=O)=C1N SKWTVENEYZYQLV-UHFFFAOYSA-N 0.000 claims 1
- XYUINKARGUCCQJ-UHFFFAOYSA-N 3-imino-n-propylpropan-1-amine Chemical compound CCCNCCC=N XYUINKARGUCCQJ-UHFFFAOYSA-N 0.000 claims 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- YYYJTBWRNLEYHZ-UHFFFAOYSA-N CC(C(C(C1(Cl)Cl)(Cl)Cl)(C(O)=O)Cl)(C=C1Cl)C(O)=O Chemical compound CC(C(C(C1(Cl)Cl)(Cl)Cl)(C(O)=O)Cl)(C=C1Cl)C(O)=O YYYJTBWRNLEYHZ-UHFFFAOYSA-N 0.000 claims 1
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Classifications
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
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| MY139230A (en) * | 2002-10-17 | 2009-08-28 | Ciba Holding Inc | Flame retardant polymeric electrical parts |
| US7138448B2 (en) * | 2002-11-04 | 2006-11-21 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| FR2881141B1 (fr) * | 2005-01-24 | 2007-02-23 | Rhodia Chimie Sa | Composition ignifugeante |
| JP4937610B2 (ja) * | 2005-04-12 | 2012-05-23 | 第一工業製薬株式会社 | 難燃性発泡ポリスチレン系樹脂およびその成形体 |
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| RU2407551C1 (ru) * | 2006-10-25 | 2010-12-27 | Дау Глобал Текнолоджиз Инк. | Полиолефиновые дисперсии, пены и пеноматериалы |
| US20080303006A1 (en) * | 2007-06-08 | 2008-12-11 | Frank Huijs | Flame retardant thermoplastic resinous compostion |
| US20110046250A1 (en) * | 2007-07-06 | 2011-02-24 | Stowell Jeffrey K | Flame retardant composition and flexible polyurethane foam prepared therewith |
| US20100048780A1 (en) * | 2008-08-22 | 2010-02-25 | Polymer Products Company, Inc. | Prevention of color formation in polyolefins |
| US7714611B1 (en) * | 2008-12-03 | 2010-05-11 | Advantage Logic, Inc. | Permutable switching network with enhanced multicasting signals routing for interconnection fabric |
| US20100152352A1 (en) * | 2008-12-10 | 2010-06-17 | Polymer Products Company, Inc. | Substrates coated with flame retardant compositions based on organic polymers and zeolites |
| WO2010108076A2 (en) * | 2009-03-19 | 2010-09-23 | Jeffrey Jacob Cernohous | Biobased polymer compositions |
| US9915069B1 (en) | 2009-12-31 | 2018-03-13 | Firestone Building Products Co., LLC | Non-black EPDM roof membranes with improved weathering |
| US9051478B2 (en) * | 2010-07-22 | 2015-06-09 | Basf Se | Additive combination for sealants applications |
| US8604105B2 (en) | 2010-09-03 | 2013-12-10 | Eastman Chemical Company | Flame retardant copolyester compositions |
| CN102477208B (zh) * | 2010-11-30 | 2014-06-25 | 深圳市亚塑科技有限公司 | 耐蓄电池溶液腐蚀的阻燃abs复合材料及其制备方法 |
| CN102382401B (zh) * | 2011-10-25 | 2013-01-23 | 宁波一舟塑胶有限公司 | 一种cmr级高阻燃聚氯乙烯线缆护套料及其制备方法 |
| PL2825589T3 (pl) * | 2012-03-16 | 2020-11-02 | Basf Se | Związki nor-hals jako środki zmniejszające palność |
| CN102828397B (zh) * | 2012-08-31 | 2014-10-22 | 江苏高博智融科技有限公司 | 一种用于棉纺织产品阻燃处理的阻燃剂 |
| CN103122101B (zh) * | 2013-01-24 | 2015-04-29 | 广东聚石化学股份有限公司 | 一种高灼热丝不起燃聚丙烯复合材料及其生产方法 |
| US9518176B2 (en) * | 2013-06-05 | 2016-12-13 | Gse Environmental, Llc | High temperature geomembrane liners and master batch compositions |
| MX2016007457A (es) * | 2013-12-10 | 2016-10-03 | General Cable Tech Corp | Composiciones termoconductoras y sus cables. |
| CN105778264B (zh) * | 2014-08-11 | 2020-06-02 | 江苏理工学院 | 无卤阻燃poe材料的制备方法 |
| EP3002311A1 (en) * | 2014-10-03 | 2016-04-06 | Kaneka Belgium N.V. | Flame retardant pre-expanded polymer material, in-mold or extruded foamed article and process for producing the material |
| JP6630674B2 (ja) | 2014-10-03 | 2020-01-15 | カネカ ベルギー ナムローゼ フェンノートシャップKaneka Belgium N.V. | ポリオレフィン系樹脂予備発泡粒子および型内発泡成形体、並びにそれらの製造方法 |
| EP3325547B1 (en) * | 2015-07-20 | 2019-07-10 | Basf Se | Flame retardant polyolefin articles |
| RU2739354C1 (ru) * | 2017-05-22 | 2020-12-23 | Эксонмобил Кемикэл Пейтентс Инк. | Галогенированные эластомеры, обладающие стабильной вязкостью по муни, и способ их получения |
| US10889704B2 (en) | 2017-05-22 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with Mooney viscosity stability and method for preparing same |
| WO2018217294A1 (en) * | 2017-05-22 | 2018-11-29 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with mooney viscosity stability and method for preparing same |
| BR112020000138A2 (pt) | 2017-07-06 | 2020-07-07 | Basf Se | composição, artigo moldado, métodos para preparar o artigo moldado e para estabilizar uma poliolefina contra os efeitos prejudiciais do calor, luz e oxigênio, e, composição aditiva. |
| WO2019007935A1 (en) | 2017-07-06 | 2019-01-10 | Basf Se | POLYETHYLENE PIPE |
| JP2020526607A (ja) | 2017-07-06 | 2020-08-31 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ベンゾフラノンおよびヒンダードアミン光安定剤を含む安定化ポリオレフィン組成物 |
| WO2019077529A2 (en) | 2017-10-17 | 2019-04-25 | Celanese Sales Germany Gmbh | FLAME RETARDANT POLYAMIDE COMPOSITION |
| US10696819B2 (en) | 2017-10-19 | 2020-06-30 | International Business Machines Corporation | Ultraviolet light stabilizing polymeric filler materials |
| KR102848554B1 (ko) | 2019-03-08 | 2025-08-22 | 바스프 에스이 | 입체 장애 아민 안정화제 혼합물 |
| KR20200116385A (ko) | 2019-04-01 | 2020-10-12 | 주식회사 가이아 | 판스프링용 높이조절 샤클 |
| JP2023524284A (ja) * | 2020-05-07 | 2023-06-09 | ソルベイ スペシャルティ ポリマーズ ユーエスエー, エルエルシー | ポリアミド組成物を含む電気及び電子物品 |
| CN113801320B (zh) * | 2020-06-01 | 2023-11-07 | 中国石油化工股份有限公司 | 生物基嵌段聚合物及其制备方法和应用以及阻燃复合物及其制备方法 |
| EP4208324A4 (en) * | 2020-09-03 | 2024-09-25 | W. R. Grace & Co.-Conn | POLYMER COMPOSITION WITH RESISTANCE TO OXIDATIVE DEGRADATION AND ARTICLES MANUFACTURED THEREFROM |
| CA3204117A1 (en) * | 2021-01-05 | 2022-07-14 | Basf Se | Stabilizing a shaped polymer article against degradation induced by artificial uv-c light |
| EP4474417A1 (en) * | 2023-06-09 | 2024-12-11 | Borealis AG | Polypropylene composition having intumescent flame retardant and improved uv stabilization |
| EP4474416A1 (en) * | 2023-06-09 | 2024-12-11 | Borealis AG | Polypropylene composition having intumescent flame retardant and improved uv stabilization |
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| ES2318059T3 (es) * | 2001-12-10 | 2009-05-01 | Ciba Holding Inc. | Composiciones ignifugantes. |
| EP1483323A1 (en) * | 2002-03-01 | 2004-12-08 | Dow Global Technologies Inc. | Dimensionally-stable propylene polymer foam with improved thermal aging |
| CA2498975A1 (en) | 2002-10-03 | 2004-04-15 | Ciba Specialty Chemicals Holding Inc. | Flame retardant compositions |
-
2003
- 2003-09-30 US US10/675,157 patent/US7109260B2/en not_active Expired - Fee Related
- 2003-10-09 CA CA2501384A patent/CA2501384C/en not_active Expired - Lifetime
- 2003-10-09 KR KR1020057006359A patent/KR101010588B1/ko not_active Expired - Fee Related
- 2003-10-09 JP JP2004544120A patent/JP4490276B2/ja not_active Expired - Fee Related
- 2003-10-09 ES ES03773639T patent/ES2342054T3/es not_active Expired - Lifetime
- 2003-10-09 WO PCT/EP2003/011185 patent/WO2004035671A1/en not_active Ceased
- 2003-10-09 EP EP03773639A patent/EP1554336B1/en not_active Expired - Lifetime
- 2003-10-09 AT AT03773639T patent/ATE462749T1/de not_active IP Right Cessation
- 2003-10-09 AU AU2003282026A patent/AU2003282026A1/en not_active Abandoned
- 2003-10-09 DE DE60331938T patent/DE60331938D1/de not_active Expired - Lifetime
- 2003-10-09 CN CNB2003801014336A patent/CN100439434C/zh not_active Expired - Fee Related
- 2003-10-10 MY MYPI20033870A patent/MY136645A/en unknown
- 2003-10-15 TW TW092128535A patent/TWI291478B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006503138A (ja) | 2006-01-26 |
| MY136645A (en) | 2008-11-28 |
| ES2342054T3 (es) | 2010-07-01 |
| CA2501384A1 (en) | 2004-04-29 |
| ATE462749T1 (de) | 2010-04-15 |
| DE60331938D1 (de) | 2010-05-12 |
| AU2003282026A1 (en) | 2004-05-04 |
| US7109260B2 (en) | 2006-09-19 |
| JP4490276B2 (ja) | 2010-06-23 |
| WO2004035671A1 (en) | 2004-04-29 |
| EP1554336B1 (en) | 2010-03-31 |
| US20040097620A1 (en) | 2004-05-20 |
| KR101010588B1 (ko) | 2011-01-24 |
| EP1554336A1 (en) | 2005-07-20 |
| CN100439434C (zh) | 2008-12-03 |
| KR20050083756A (ko) | 2005-08-26 |
| TW200512279A (en) | 2005-04-01 |
| CN1705705A (zh) | 2005-12-07 |
| CA2501384C (en) | 2011-08-09 |
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Legal Events
| Date | Code | Title | Description |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |