CN102828397B - 一种用于棉纺织产品阻燃处理的阻燃剂 - Google Patents
一种用于棉纺织产品阻燃处理的阻燃剂 Download PDFInfo
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 46
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 17
- 239000004753 textile Substances 0.000 title claims abstract description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 8
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 8
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
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- 229930188012 Bromoether Natural products 0.000 claims description 9
- HJCMMOODWZOXML-UHFFFAOYSA-N bromo hypobromite Chemical compound BrOBr HJCMMOODWZOXML-UHFFFAOYSA-N 0.000 claims description 9
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 6
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 claims description 3
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- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000004114 Ammonium polyphosphate Substances 0.000 abstract 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 abstract 1
- 229920001276 ammonium polyphosphate Polymers 0.000 abstract 1
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- 229920003023 plastic Polymers 0.000 description 3
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- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
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- 125000000524 functional group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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Abstract
本发明公开了一种用于棉纺织产品阻燃处理的阻燃剂，包括有以下组分：双氰胺、八溴醚、聚磷酸铵、十溴二苯醚和磷系阻燃物；各组分按照重量份计分别为双氰胺14-16份，八溴醚3-10份，聚磷酸铵25-35份，十溴二苯醚15-20份，磷系阻燃物40-50份，水1000-1500份。本发明的有益效果为：本发明提供的一种用于棉纺织产品阻燃处理的阻燃剂，制备工艺简单，只需混合即可使用，效果是以往阻燃剂的2-3倍，并且低毒害，市场前景良好。
Description
技术领域
本发明涉及一种用于棉纺织产品阻燃处理的阻燃剂。
背景技术
阻燃剂，又称难燃剂，耐火剂或防火剂：是一种赋予易燃聚合物难燃性的功能性助剂；依应用方式分为添加型阻燃剂和反应型阻燃剂。根据组成，添加型阻燃剂主要包括无机阻燃剂、卤系阻燃剂（有机氯化物和有机溴化物）、磷系阻燃剂（赤磷、磷酸酯及卤代磷酸酯等）和氮系阻燃剂等。反应型阻燃剂多为含反应性官能团的有机卤和有机磷的单体。此外，具有抑烟作用的钼化合物、锡化合物和铁化合物等亦属阻燃剂的范畴。主要适用于有阻燃需求的塑料，延迟或防止塑料尤其是高分子类塑料的燃烧。使其点燃时间增长，点燃自熄，难以点燃。
棉纺织行业中，经常会用的阻燃剂，以保证生产过程中的安全问题，但以往的阻燃剂，阻燃效果不佳，毒害作用较强。
发明内容
本发明的目的就是针对上述现有技术中的缺陷，提供了一种低毒无害，阻燃效果优异的用于棉纺织产品阻燃处理的阻燃剂。
为了实现上述目的，本发明提供的技术方案为：一种用于棉纺织产品阻燃处理的阻燃剂，包括有以下组分：双氰胺、八溴醚、聚磷酸铵、十溴二苯醚和磷系阻燃物；各组分按照重量份计分别为双氰胺14-16份，八溴醚3-10份，聚磷酸铵25-35份，十溴二苯醚15-20份，磷系阻燃物40-50份，水1000-1500份。
进一步的，上述的一种用于棉纺织产品阻燃处理的阻燃剂，各组分按照重量份计可优选为双氰胺15份，八溴醚7份，聚磷酸铵30份，十溴二苯醚18份，磷系阻燃物45份，水1200份。
进一步的，上述的一种用于棉纺织产品阻燃处理的阻燃剂，所述磷系阻燃剂为红磷、磷酸胺或磷酸三甲苯酯。
本发明的有益效果为：
本发明提供的一种用于棉纺织产品阻燃处理的阻燃剂，制备工艺简单，只需混合即可使用，效果是以往阻燃剂的2-3倍，并且低毒害，市场前景良好。
具体实施方式
实施例1：
一种用于棉纺织产品阻燃处理的阻燃剂，是将以下组分混合得到的，双氰胺14kg，八溴醚3 kg，聚磷酸铵25 kg，十溴二苯醚15 kg，红磷40 kg，水1000kg。
实施例2：
一种用于棉纺织产品阻燃处理的阻燃剂，是将以下组分混合得到的，双氰胺16kg，八溴醚10 kg，聚磷酸铵35 kg，十溴二苯醚20kg，磷酸胺50 kg，水1500 kg。
实施例3：
一种用于棉纺织产品阻燃处理的阻燃剂，是将以下组分混合得到的，双氰胺15kg，八溴醚7kg，聚磷酸铵30kg，十溴二苯醚18kg，磷酸三甲苯酯45kg，水1200kg。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (3)
1.一种用于棉纺织产品阻燃处理的阻燃剂，其特征在于，包括有以下组分：双氰胺、八溴醚、聚磷酸铵、十溴二苯醚和磷系阻燃物；各组分按照重量份计分别为双氰胺14-16份，八溴醚3-10份，聚磷酸铵25-35份，十溴二苯醚15-20份，磷系阻燃物40-50份，水1000-1500份。
2.根据权利要求1所述的一种用于棉纺织产品阻燃处理的阻燃剂，其特征在于，各组分按照重量份计分别为双氰胺15份，八溴醚7份，聚磷酸铵30份，十溴二苯醚18份，磷系阻燃物45份，水1200份。
3.根据权利要求1或2所述的一种用于棉纺织产品阻燃处理的阻燃剂，其特征在于，所述磷系阻燃剂为红磷、磷酸胺或磷酸三甲苯酯。
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| CN102828397B true CN102828397B (zh) | 2014-10-22 |
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| CN103046332A (zh) * | 2012-12-28 | 2013-04-17 | 苏州市华智顾纺织有限公司 | 一种阻燃棉织物的制造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040097620A1 (en) * | 2002-10-17 | 2004-05-20 | Nikolas Kaprinidis | Flame retardant compositions |
| EP1486606A1 (en) * | 2002-02-05 | 2004-12-15 | YKK Corporation | Flame-retardant molded article and fabric product |
| CN1693577A (zh) * | 2005-05-09 | 2005-11-09 | 烟台万华超纤股份有限公司 | 一种阻燃性聚氨酯合成革及其制备方法 |
| CN101456962A (zh) * | 2008-12-29 | 2009-06-17 | 黄华昌 | 一种高含量红磷阻燃母料 |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1486606A1 (en) * | 2002-02-05 | 2004-12-15 | YKK Corporation | Flame-retardant molded article and fabric product |
| US20040097620A1 (en) * | 2002-10-17 | 2004-05-20 | Nikolas Kaprinidis | Flame retardant compositions |
| CN1693577A (zh) * | 2005-05-09 | 2005-11-09 | 烟台万华超纤股份有限公司 | 一种阻燃性聚氨酯合成革及其制备方法 |
| CN101456962A (zh) * | 2008-12-29 | 2009-06-17 | 黄华昌 | 一种高含量红磷阻燃母料 |
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