TW200413457A - Flame retardant polymeric electrical parts - Google Patents

Abstract

Disclosed is a flame retardant lighting assembly comprising thermoplastic insulation, plugs and sockets. The thermoplastic resin is for example polypropylene homopolymer and comprises a synergistic combination of an N-alkoxyoxy hindered amine and a conventional organohalogen flame retardant. The addition of low levels of acid scavengers such as hydrotalcites is advantageous.

Description

200413457 发明 Description of the invention: [Technical field to which the invention belongs] The present invention relates to a flame-retardant polymer motor / electronics unit, especially the flame-resistant polyolefin-based, wire insulation for lighting applications. Table connection seat. [Prior Art] Background U.S. Patent No. 5,096,950 discloses the common use of a specific NOR (N-alkoxy) hindered amine and a monobromide-containing 203-flame flame retardant in polypropylene. U.S. Patent No. 5,3 9 3,8 12 discloses a polysmoke composition which is made by combining a halogenated hydrocarbyl phosphate or phosphate flame retardant and a monoalkoxyamine functionalized hindered amine. Flame retardant. U.S. Patent No. 5,844,026 discloses a polysmoky composition comprising a specific NOR hindered amine and a specific conventional flame retardant. U.S. Patent No. 6,117,995 discloses that specific N-alkoxy hindered amines are useful as flame retardants for organic polymers. U.S. Patent No. 6,271,377 discloses a polyolefin composition including an N-hydroxyalkoxy hindered amine and one! | Chemical flame retardant. U.S. Patent No. 6,309,987, and relative WO 99/54530, disclose a polyolefin non-woven flame retardant fabric comprising N-alkoxyamines. A Revo1i} tionary UV Stable Flpim ^ Retardant System for Polyolefins — R. Srinivasan, A. Gupta and D. Horsey, Int. Conf. Addit. Polyolefins 1998, 69 — S3, reveals a hawk poly poet 200413457 hydrocarbons, including specific nor Hindered amines, and traditional flame retardants containing I and phosphorus

Advances in a Revolutionary Flame Retardant Sygb for Polyolefins — R. Srinivasan, B. Rotzinger, Polyolefins 2000 f Int. Conf. Polyolefins 2000 j 57 1 — 58 1, revealing a polyolefin, including specific NOR hindered amines, and Brominated and phosphorus-containing flame retardants. N. Kaprinidis and R. King, in a summary posted on the Society of Plastics Engineers website (posted September 2001), discuss the use of NOR hindered amines as flame retardants for polyolefins. This abstract was sent to the Polymer Modifiers and Additives Division in paper form and was published at the p〇iy〇iefins 2002 conference in Houston, Texas on February 24, 2002. This website is www.PMAD.org 〇EP 079291 1 A2 A polyhydrocarbon composition comprising a hindered amine functionalized with a oxyamine and a tris (tri-pentyl) phosphate flame retardant. WO 99/00450, Applications in Common Applications, uS · Patent Application 09 / 502,239, Application Date November 3, 1999, and 09 / 714,717, Application Date 1 January 16, 2000, Revealing Use Specific n-alkyloxy hindered amines are used as flame retardants. U.S. Patent No. 6,225,387 discloses organic flame retardant polymer compositions. [Summary of the Invention] It has been found that a specific composition of a sterically hindered alkoxyamine stabilizer and an organic halogen flame retardant is effective for providing flame retardance of plastic parts for lighting applications. The detailed description is particularly specific. The present invention relates to a flame-retardant polymer motor component composition including (a)-a thermoplastic resin, and (b)-an effective flame-retardant amount of a synergistic mixture containing the following composition (i) at least steric hindrance Alkoxyamine stabilizers, and (ii) at least one conventional organic halide flame retardant. Stereo hindered alkoxyamine stabilizer of component VII. Examples of hindered amines of the present invention are monomeric compounds or oligomeric or polymeric compounds. The steric hindrance stabilizer of ingredient VII of the present invention is well known in the art and is, for example, a compound of the following formula

among them

G1 and G2 are unrelated to each other alkyl groups of 1 to 8 carbon atoms, or fluorene together is Wujialou, z] and 4 are methyl groups, respectively, or B and Z2 together form a linking group 'and it may be In addition, it is substituted by an ester, ether, ammonium, amine, carboxyl, or ethyl carbamic acid, and E alkoxy, cycloalkoxy, aralkoxy, aryloxy, or 0-T- (OH) b, 200413457 Yes—Straight or branched chain containing 1 to 18 carbon atoms, f to 18 carbon atoms, cycloalkane '5 to 18 carbon atoms, thin chain, straight chain Or a branched chain containing 4 carbon atoms of ii, and it is substituted by phenyl 'or by-or: a U group having 1 to 4 carbon atoms; b is B 2 or 3, but The premise is that b cannot exceed the number of carbon atoms in d 'and that when b is 2 or 3, each aryl group is connected to a different carbon atom of τ. E is, for example, alkoxy, cycloalkoxy or aralkoxy. For example, ε is methoxy, propoxy, cyclohexyloxy or octyloxy. An example of a steric hindrance stabilizer of component VII of the present invention is the formula A- r RCH Ε-Ν RCH,

(Α)

200413457

[T3] k i CO I

10 200413457

(G)

11 200413457

e τ p

12 200413457

(P)

HX CH2R E——NX: h3c ch2r

(Q)

⑻ 13 200413457 where jg] alkoxy to 18 carbon atoms, 5 to cycloalkoxy or 7 to 1 Wm

Aralkyloxy with 5 fluorene atoms, or 10-T-(OH) b, 疋 U to chain or branched alkylene group with 1 to 18 carbon atoms, 5 to 18; ε Antiatomic elysene, cycloalkene of 5 to 18 carbon atoms, straight chain or § branched bond ^ to 4 carbon atoms, and it is your

, Or substituted by one or-octadecane, ..., benzene I; ... 3 to 4 carbon atoms substituted with phenyl group: 1 '2 or 3, but the premise is that b can not exceed in T The number of carbons, and when the counties in B County are 2 or 3%, each hydroxyl group is bonded to the same carbon atom; R, H, and T to T are not hydrogen or amidino, and m is 1 to 4 When m is 1, or more: oxygen is a monovalent fluorenyl group of the original chloro group I2 dilute A- ^ aryl group, or it is now "Yueyueyue" or Fangxiangyue quaternary acid t Monovalent fluorenyl groups, for example, cycloaliphatic carboxylic acids having 2 to 18 stone anaerobic fatty acids, and $ n / to 12 stone antiatoms

Or have 7 to 15 carbon eyebrows; 々 # 去 / 夂 I ′, Zi Zhi Fang Yue is a sour base, or 14 200413457

Where χ is 0 or 1,

Where y is 2-4; when m is 2, R2 is (^ -C12 alkylene, C4-C12 olefin, xylene, a divalent fluorenyl group of a fatty, cycloaliphatic or aromatic dicarboxylic acid or , A divalent fluorenyl group of diaminophosphonic acid, for example, a fatty dicarboxylic acid having 2 to 18 carbon atoms, a fluorenyl group having a cycloaliphatic or aromatic dicarboxylic acid having 8 to 14 carbon atoms, or having 8 A fluorenyl group of an aliphatic, cycloaliphatic or aromatic diaminophosphonic acid of 14 carbon atoms; 15 200413457

〇 g — (CH2) d- where D1 and D2 are independent of each other, hydrogen, alkyl, aryl or aralkyl containing up to 8 carbon atoms, including 3,5-di-tert-butyl- Hydroxybenzyl, D3 is hydrogen, or an alkyl or dilute group containing up to 18 carbon atoms, and d is 0-20; when m is 3, R2 is a fatty, unsaturated fatty, cycloaliphatic Trivalent fluorenyl group of aromatic or tricarboxylic acid; when π is 4, 'R2 is a saturated or unsaturated fatty or aromatic tetravalent fluorenyl group including 1,2' 3,4-monobutyl Burnt tetracarboxylic acid, 1,2,3,4-butane-2-tetracarboxylic acid, and 1,2,3,5- and 1,2,4,5 pentanetetracarboxylic acid; p is 1, 2 or 3, R3 is hydrogen, Cl—CI2 alkyl, C5—C7 cycloalkyl, c7—c9 aralkyl, C2—C] 8 acid group 'C3-C5 alkenyl or benzamidine; when P When it is 1, R4 is hydrogen, Cl-Cis alkyl, C5-c7 cycloalkyl, c2-c8 alkenyl, which is unsubstituted or substituted by monocyano, carbonyl or carbodiamine, 16 200413457 Aryl, aralkyl, so that it is glycidyl, ch2 ~ ch (oh) — Z or formula — Z〇 Ring 〆C〇NH z - Z-yl group, wherein Z is hydrogen, Yue group or stupid group; or a group of formulas

Where h is 0 or 1 '. When P is 1, R3 and R4 together can be alkylene or 2-oxo-polyalkylene of 4 to 6 carbon atoms, fatty or aromatic 1, 2, 1 or 1, 3 —Cyclofluorenyl group of dicarboxylic acid, when P is 2, R4 is a direct bond or Ci—C12—C6—C] 2 aromatic standard, difluorene phenylene, a CH2CH (OH) —CH2 group Or a formula of CH2 ~ (^ (OH) — CH2 ~ 〇 × —〇—CH2 — CH (〇H) —CH2 — where χ 17 200413457 is C2 — c1G alkylene, C6 — c15 arylene or c6 —Ci2 cycloalkylene; or, if R3 is not alkane, alkene, or benzamidine, r4 can also be a divalent fluorenyl group of a fatty, mounting or aromatic dicarboxylic acid or diaminophosphonic acid, Or can be a group of formula CO—; or r4 is

Among them, Ts and D9 are independently related to hydrogen, and alkyl groups of 8 to 8 carbon atoms, or alkylenes or 3-oxapentafluorene of 4 to 6 carbon atoms from D8 and T9- For example, T8 and T9 are starting from 3-oxapentaethylene; when P is 3, R4 疋 2'4'6-trisyl, η is 1 or 2, and when η is 1, R5 and R, 5 Irrelevant are Ci—C] 2 alkyl, c2—Ci2 alkenyl, C7—C12 aralkyl, or Rs is also hydrogen, or & together with I—cs or hydroxyalkylene or I— c22 alkoxyalkylene; when η is 2, and R, 5 are (monoCH2) 2C (CH2—) 2; R6 hydrogen, alkyl, allyl, phenylfluorenyl, epoxypropyl Or C2—C6 alkoxyalkyl; 18 200413457 when η is 1, R7 is hydrogen, c! —C12 alkyl, C3-C5 diaryl 'C7 ~ c9 aromatic alkyl, c5-〇7 cycloalkyl, c2—c4 via alkyl group, c2—c6 alkyl group, C6—C10 aryl group, epoxypropyl group, (CH2) t—C00 ~ Q or (CH2) t — 0 — CO— Q group base 'where t is 1 or 2' and q is ^ a C4 radical or phenyl; or when η is 2, R? Is C2-C12 burned, C6-C12 arylene, a formula CH2CH (0H) a CH2-ο—X— 0 — CH2 — CH (OH) — CH2 — group, where χ is a c2—c1 () group, a c6—c15 arylene group or a c6—c12 ring group, or -CH2CH (OZ ') CH2 — (OCH2 — CH (OZ') CH2) 2- group, where Z ′ is hydrogen, c] —C18 alkyl, allyl, benzyl, C2 ~ C12 alkyl Or phenylhydrazone;

Qi is an N (R8) —or —0—; £ 7 is a (^ —103 alkylene, formula — CH2 — CH (R9) — 0 — group, where r9 is hydrogen, fluorenyl or phenyl, formula — (CH2) 3 — NH— group, or a direct bond; R10 is hydrogen or C] -C18 alkyl, r8 is hydrogen, Ci-Ci8 alkyl, c5-c7 cycloalkyl, c7-ci2 aralkyl , Cyanoethyl, c6-aryl, formula —CH2 — CH (R9) — 0H group, where h has the definition above; group 19 200413457

Or the following formula G.-N-E, —CO-N-C- OR.

ΗΧ

Wherein 0 is C2-C6 alkylene or C6-C12 arylene; or R8 is a group of the formula —E7—CO—NH — CH2—OR]; Formula F represents the repeating structural unit of the polymer, where T3 is ethyl Propylene or 1,2-propane # is a repeating structural unit derived from an α-dilute hydrocarbon copolymer and a monoalkyl acrylate or methacrylate; for example, a copolymer of ethylene and ethyl acetate, in which k is 2 to 100; when p is 1 or 2, T4 has the same definition as R4, T5 is fluorenyl, T6 is fluorenyl or ethyl, or T5 and butyl 6 together are tetra- or penta-supported For example, T5 and T6 are fluorenyl groups, M and Υ are unrelated to methylene or carbonyl, respectively, and T4 is ethylene 20 200413457, where η is 2; T7 is the same as R7, and T7 is, for example, octadecyl Where η is 2, and T1 () and Tη are independent of each other and are alkylenes of 2 to 12 carbon atoms, or Tη is

Τ12 is erazinyl, NRn- (CH2) d-NRn—or -NR (CH2) -N (CH2) -N [(CH2) * N] η a b c f where Rn is the same as R3 or

a, b and c are independent of 2 or 3, and f is 0 or 1, for example a and c are 3, b is 2 and f is 1; and e is 2, 3 or 4, such as 4; 21 200413457

Tl3 疋 is the same as R2, but the premise is that when η is 1, T13 cannot be · hydrogen;, ,, Ε! And Ε2 are different, respectively, a c0- or -ν (Ε5)-, where h is Lice, c ^ —c ^ 2 alkyl or c22 alkoxycarbonylalkyl, for example E! Is a CO—and e2 * —N (E5) ~,

Is hydrogen, an alkyl'phenyl group of 1 to 30 carbon atoms, a naphthyl group, the naphthyl group, or the naphthyl group is substituted by chlorine or an alkyl group of i to 4 carbon atoms, or 7 to 12 carbon atoms Anatomic phenylcarbyl, or the phenylcarbyl is substituted with an alkyl group of 1 to * carbon atoms, hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl or 12-carbon phenylalkyl, or polymethylene with I and E4 from 4 to 17 carbon atoms, or the polyfluorene is substituted by 4 i-alkyl groups with i to 4 carbon atoms Is a fatty or aromatic tetravalent group, and the formula (N) is as defined above when m is 1.

Gi is a direct bond, Ci-C12 alkylene NH, where 0 ' is Cl-C12 alkylene; or benzyl or one NH ~ G,-

Where the hindered amine compound is a compound of formula VII, VIII, IX, X or XI

II ^ III IV, V, vi, 22 200413457

23 200413457

200413457

25

(XI) Al-based radicals El or t: 3 Γ Mutual: related ones are 1 to 4 carbon ... groups, ~ -2: related ones are ... carbon atoms are burned 4 pentamethylene, formula · < Do not use pentamethyl, ^ 1 2, and Ε3 and Ε4 points R] 疋 1 to 18 carbon flakes + and ^ ^ alkyl group, 5 to 12 carbons; ^ ss alkyl group, 7 to 12 Carbon atom cone ^% of anaerobic atoms Mosquito Am ring tobacco base, 7 to 15 carbons, phenyl radicals, 6 to] 〇 细 χ 山 店 1 # The main square of 10 slave atoms or The aryl group is substituted with one to two alkyl groups containing 1 to 8 carbon atoms, I is hydrogen or-straight or branched alkyl group containing 1 to 12 carbon atoms) R3 is 1 to 8 carbons Atomic alkylene, or r3 is _co-, a CC-R4-, -CONR, or a co-NR2-R4-, I is an alkylene of 1 to 8 carbon atoms, r5 is hydrogen,- Straight or branched alkyl groups of i to 12 carbon atoms, or 26 200413457

Or when r4 is ethylene, the two r5 fluorenyl substituents can be connected by a direct bond, so the triazine bridging group -N (R5)-R4-N (R5)-is a mouthful D Q-1, 4-diyl 'R6 is an alkylene of 2 to 8 carbon atoms, or R6 is

R

The premise is that when R6 is the aforementioned structure, then Y is not an OH, and A is a 10—or an NR7—wherein R7 is a straight bond or a branched alkyl group containing 1 to 12 carbon atoms, or R7 is

27 200413457 1 An alkylalkoxy group of 4 carbon atoms or an N (R2) 2, where τ is a phenoxy group, and after one or two substituted phenoxy groups, R2 is not 1 to 8 carbon atoms. Hydrogen, or Τ is

〇 ~ oxypropyl 'or -X is -NH2, -NC0, -OH nhnh2, and Y is -1, -NH2, -NHR2, where r2 is not hydrogen; or γ is -NCO, -COOH, ethylene oxide Group, —0-epoxypropyl group, or —Si (0R2) 3; or the combination of R3—Y—is a ch2ch (oh) r2, where r2 is an alkyl group, or the alkyl group is one to four oxygen atoms The interrupted, or r3 — Y— is a ch2or2; or wherein the sterically hindered amine compound is an N, N ,, N ,,, one {2,4 one bis [(1—hydrocarbyloxy-2, 2 , 6, 6-tetramethylmethylpyridine-4-yl) alkylamino] -s-triazine-6-yl} -3,3'-ethylenediimine dipropylamine; n, N, , N '' one three {2,4 one bis [(1 one alkoxy group 2,2,6,6 —tetramethyl group ° fixed one 4 —yl) alkylamino] one s — three one 6-yl} -3,3'-ethylenediimide dipropylamine, and a mixture of bridged derivatives of formula I, Π, ΠΑ and III, 28 200413457 R ^ H- CH2CH2CH2NR2CH2CH2NR3CH2CH2CH2NHR4 (I) τ Ε 「Τι (II) TE! (IIA) G— E "G" E "G2 (III) where in the tetraamine of formula I,

R] and R2 are s-triazine group E; and one of R3 and R4 is s-triazine group E, the other of R3 or R4 is nitrogen, and E is

N N R5, N, N

OR OR R is fluorenyl, propyl, cyclohexyl or octyl, such as cyclohexyl, and R 5 is an alkyl group of 1 to 12 carbon atoms, such as η-butyl, where in compounds of formula II or IIIA, when R When it is propyl, cyclohexyl or octyl, T and L are respectively I-R4 substituted tetraamines as defined in formula I above, where (1) is in each tetraamine One is replaced by the group Eι to form a bridging group between two tetraamines T and T, 29 200413457 E] is

乂 N 太 人 太 II II OR 〇-L-〇 OR

Or (2) As in formula IIA, the group E can have two terminal groups in the same tetraamine T, where the E group in the two tetraamines is replaced by an Ei group, or ( 3) The three s-triazine substituents in all tetraamines T can be Ei, so in tetraamine T, one E! Is linked to T and T1, and the second has two terminal groups, and L is propanediyl , Cyclohexanediyl or octyldiyl; wherein in the compound of formula III, G, G] and G2 are tetraamines substituted by R, —R4 as defined in formula I, but G and G2 each have an E by E ! Replaced s-triamyl group E, and G] have two triazine groups E replaced by I, so there is a bridge group between G and G], and a second bridge group between Gi and G2; The mixture is composed of two to four equivalents of 2,4-bis [(1-hydrocarbyloxy-2,2,6,6-tetramethylsulfanyl-1, 4-yl) butylamino] -6-gas. s — 30 200413457 prepared from triazine and one equivalent of N, N′-bis (3-aminopropyl) ethylenediamine; or the hindered amine is a compound of formula Illb,

(Illb) where the index n ranges from 1 to 15; R12 is C2-C12 alkylene, C4-C12 alkylene, C5-C7 cycloalkylene, C5-C7 cycloalkylene-di (q-C4 alkylene), C〗 One C4 alkylene di (C5 — C7 cycloalkylene), phenylene di (C wide C4 alkylene) or C4 interrupted by 1,4 monotonazine diyl, one O — or> N — X! — C] 2 alkylene, where X! Is C! — C12 fluorenyl or (C “C12 alkoxy) carbonyl, or one of the definitions described below for R14, but excluding hydrogen; or R12 is of the formula ( lb ') or (Ic') compounds; 31 200413457

CH2 ~ CH

Wherein X is 0-0: 18 alkyl, C5-C12 cycloalkyl, which is unsubstituted 'or substituted with 1, 2 or 3 Ci-C4 alkyl; phenyl, which is unsubstituted , Or substituted by 1,2 or 3 Ci-C4 alkyl or Ci-C4 alkoxy, C7-c9 phenylalkyl, which is unsubstituted, or substituted by 1,2 or alkyl on phenyl Substituted; and groups X3 which are unrelated to each other are C2-C12 alkylene; R13, R14 and R15, (same or different) are hydrogen, Ci-c " alkyl 'C5-C12%: alkyl group' which Is unsubstituted, or substituted with ι, 2 or 3 C-C4 alkyl, C3-C] 8 alkenyl, phenyl, which is unsubstituted, or by 1, 2 or 3 C] -C4 Alkyl or Ci-alkyloxy substituted; & -C9 phenylalkyl, which is unsubstituted or substituted on the phenyl with i, 2 or 3 C] -C4 alkyl; tetrahydrofuranyl Or C2-C4 alkyl, which is in the 2nd, G alkoxy 'di (ci ~ C4

The 2, 3 or 4 position is a C4 alkyl) amino group substituted by -OH or a group of formula (Ie,); (Ie,)

Where Y is a 〇—, ~ cH or a N (R) 4) (R ”) and the group base of formula…,); 32 200413457

OR 13 -n (r) 4) (r15) or groups A which are not related to each other are group groups of formula (Illd);

(Hid) X is 10- or> N-R16; R16 is hydrogen, q-Cu alkyl group, which is unsubstituted, or i; C7-C: 9phenylalkyl group, which is unsubstituted C3 ~ c18 alkenyl substituted with or 3 C] -C4 alkyl, c5-c12 cycloalkane '2 or 3 c, -C4 alkyl substituted, or 1,2 on phenyl

Tetrahydrofuranyl, a group of formula (Illf),

(Illf) or C2-C4 alkyl, which is substituted by -〇11 at the 2, 3, or 4 position, c, -c8 alkoxy, bis (Ci-q alkyl) amino, or a formula (). Group base

R " has one of the definitions as described in R] 6; and groups B are independent of each other and have one of the definitions as described in a. Carbonyl is linear or branched and is, for example, methyl, ethyl, η-diyl, η-butyl, second-butyl, third-butyl, η-hexyl, octyl, 2-ethylhexyl, η-nonyl, η-decyl, η-undecyl, η-dodecyl, η-tridecyl, η-tetradecyl, ten Six-carbon alkyl or n-octadecyl. Cycloalkyl includes cyclopentyl and cyclohexyl; typical cycloalkenyl includes hexyl 33 200413457 methylmonophenylalkenyl; however, typical aralkyl includes benzyl, α 'α, α -difluorenyl Benzyl or stupid ethyl. Alkoxy and cycloalkoxy include equivalent alkyl and cycloalkyl. If I is a monovalent fluorenyl group of a carboxylic acid, it is, for example, acetic acid, stearic acid'salicylic acid, phenylarsinic acid, or fluorenylbutyl at / 3- (3,5-di-l-diphenylphenyl) propionic acid. Assuming that I is a divalent fluorenyl group of a dicarboxylic acid, it is, for example, oxalic acid, adipic acid, succinic acid, suberic acid, sebacic acid, dibutylmalonate, diphenyl Fluorenylmalonate or butylmono (3,5,1,2-tri-butyl-4-hydroxyphenylfluorenyl) monomalonate, or fluorenyl group of dicycloheptene dicarboxylic acid, of which succinate , Sebacate, phthalate and isophthalate are special examples. Assume that the divalent fluorenyl group of R2 fluorenylamino acid is, for example, the fluorenyl group of hexafluorenyldiaminofluoric acid or 2,4-phenylenediaminophosphonic acid. The sterically hindered alkoxyamine stabilizer of component ⑴ is well known in this technical field, and is also a conventional N-alkoxy hindered amine and no HR hindered amine or NOR hindered amine light stabilizer or NOR. HALS. It is disclosed, for example, in US Pat. Nos. 5,004,770, 5,204, 473, 5,096,950, 5,300,544, 5,112,890, 5, 124'378'5, 145, 893 5, 5, 216, 156, 5, 844, 026, 6 '117' 995 '6, 271, 377, and US patent application serial number 09/505, 529, application date, February 17th, 2000, 09 / 794,710, application date, February 27, 2001, 09 / 714,717, application date, November 16, 2000, 09/502, 239, application date November 3, 1999 and 60 / 312,517, application date, August 15, 2001. The disclosures of these patents 34 200413457 and patent applications are incorporated herein by reference. The above-mentioned US Patent Nos. 6,271,377, and Us · Patent Application Serial No. 09 / 505,529, filing date, February 17, 2000, and 09 / 794,710, filing date, February 20 On the 7th, 2001 showed a sterically hindered mesitylamine elixir. For the purpose of the present invention, this hindered mesityloxyamine stabilizer is considered to be a subclass of this hindered alkoxyamine stabilizer and is a part of ingredient VII of the invention. Hindered hydroxyalkoxyamine stabilizers are also known N-hydroxyalkoxy hindered amines, or no alcohol hals. Sterically hindered amines suitable for the component fluorene include, for example: NOR1 1-cyclohexyloxy ~ 2,2,6,6-tetramethyl-1,18-octadecylalkylaminopyridine; NOR2bisG-octyloxy-1 2,2,6,6-tetramethylpyridin-4-yl) sebacate; NOR3 2 '4-bis [(1-cyclohexyloxy-2,2,6,6-tetramethyl? Pyridinyl-4-yl) butylamino] -6- (2-hydroxyethylamino-s-triazine; NOR4 2,4-bis [[1-cyclohexyloxy-2, 2, 6, 6, 6 Tetramethylmethylfluorenyl-4-yl) butylamino] -chloro-s_trifluorene; NOR5 1 — (2-hydroxy-2-2-fluorenylpropoxy) -4-hydroxy-2,2,6 ， 6—tetramethyltonine bite; NOR6 1- (2-hydroxy-2—methylpropoxy) —4—oxy-2,2,6,6—tetramethylton. Fixed; NOR7 1- (2 -gyl-2-ψpropylpropoxy) -4,18-carbofluorenyloxy-2,2,6,6-tetramethylpiperidine; 35 200413457 NOR8 bis-0- (2-hydroxyl-2-methyl) Propylpropoxy) —2, 2, 6, 6′-tetramethylpyridyl, π- (4-yl) sebacate; NOR9 bis (1- (2-hydroxy-2—methylpropoxy) -2 , 2,6,6—Tetramethylmeridine A 4-adenyl) adipate; NOR10 2 '4 a bis {N— [1— (2-amyl-2-methylpropoxy) -2,2,6,6—tetramethylpyridine One 4-one group] ~ n-butylamino group 6- (2-alkylethylamino group) -s-triamidine; NOR11 2, 4-bis [[1-cyclohexyloxy-2, 2, 6 , 6-tetramethylne- 4-methyl) butylamino]-6-chloro-s-triamidine and N, N, bis (3-aminopropyl) ethylenediamine) reaction product [ CAS Reg. No. 191680 -81- 6]; and NOR12 compounds of formula

Where n is from 1 to 15; compound NOR12 is disclosed in U.S. Patent No. 6,117,995, Example 2.

N0R13 is a bis (1-cyclohexyloxy-2,2,6,6-tetramethylpyridyl-a-4-yl) adipate. 36 200413457 For example, the hindered alkoxyamine of the present invention is a hindered cyclohexyloxyamine. This N-cyclohexyloxy hindered amine is, for example, a composition selected from: (a) a mixture of compounds of formulas I, II, IIA and III, wherein R is cyclohexyl; & (b) 1-cyclohexyloxy A-2,2,6,6-tetramethyl-1,4-octadecylalkylaminopyridine; (c) 2'4-bis [(1-cyclohexyloxy-2'2,6, 6-tetramethyl mouthpiece-4 -yl) butylamino]-6-(2-hydroxyethylamino-s-triamidine; (d) bis (1-cyclohexyloxy-2, 2 , 6,6-tetramethylbutane_4 monoyl) adipate; (e) 4 '4-hexamethylenebis (amino-2,2,6,6-tetramethylpyridinium) and 2 ， 4-chloro-1-6-[(1 hexamethyloxy-2,2,6,6-tetramethylpyridine-4-yl) butylamino] -s-triazine, 2- An oligomeric compound prepared by the condensation reaction of chlorine 4,6-bis (dibutylamino) -s-triazine terminal capping; and (f) 2,4-bis [(1-cyclohexyloxy-2, 2,6,6-tetramethylpyridine-4-yl) butylamino] -6-gas-s-triazine. Examples of organic halogen flame retardants: Organic halogen flame retardants: alkylphosphonium chloride Acid esters (ANTIBLAZE® AB — 100, Albright &Wilson; FYROL® FR-2, Akzo Nobel), tris (2-chloroethyl) phosphonic acid, quaternary poly-desertification diphenyl oxide (DE-60F, Great Lakes Corp.) 37 200413457 Decabromodiphenyl oxide (DBDPO; SAYTEX⑧102E), tris [3-bromo-1,2,2-bis (bromomethyl) propyl] phosphate (PB 370®, FMC Corp .), Tris (2,3-dibromopropyl) phosphate Tris (2,3-dichloropropyl) phosphate, Hexachloro-pinenyl-tetrahydrophthalic acid, Tetrachloro acid , Tetrabromoacid, Bis (N, N'-hydroxyethyl) tetrachlorophenylene diamine, Poly-Chloroethyl triphosphonate mixture Tetrabromobisphenol A Bis (2,3-Dibromo Propyl) ether (PEE68), Brominated epoxy resin, Ethylene-bis (tetrabromopeptideimide) (SAYTEX® BT — 93), Bis (hexachlorocyclopentadiene) cyclooctane (DECLORANE PLUS® ), Gasified alkane, octabromodiphenyl ether, hexachlorocyclopentane dilute derivative, 1,2-bis (tribromophenoxy) ethane (FF680), tetrabromo-bisphenol A (SAYTEX ® RB100), ethylene double one (two Bromo-orb-norbornene dicarboximide) (SAYTEX® BN —451), bis- (hexachlorocyclopentadiene) cyclooctane,

PTFE Trinyl (2,3-dibromopropyl) -isocyanurate, and 38 200413457 ethylene ~ bis ~ tetrabromophthalimide. For example, 'the traditional flame retardant is an organic bromine flame retardant' is preferably selected from the group consisting of polybromide dibenzyl oxide, ten, odorized diphenyl oxide, tri [3 monobromo ~ 2,2-bis (bromofluorenyl) propyl] phosphate, bis (2,3-dibromopropyl) phosphate tetrabromofluoric acid, tetra > bis (2,3-dibromo) of bisphenol A Propyl ester), brominated epoxy resin, ethylene bis (tetrabromophthalimide), octabromodiphenyl ether, 1 '2 ~ bis (tri ,; phenoxy) ethane, tetra & gt Stinky one-two-year-old A, ethylene bis-one (dibromo-orthobornane dicarboximide),

Trinyl (2, 3-dibromopropyl) -isocyanurate, and ethylene-bis-tetrabromofluorenimide. Also preferred compositions are base phosphates or phosphonates, such as tripropyl] phosphate (PB 370 ,.) The dentified flame retardant compounds used in the present invention, like halogenated benzene, bisbenzene, and their oxides The aromatic carboxylic acid or its multi-organic cycloaliphatic or polycycloaliphatic dentition is a brominated hydrocarbon [3-bromo-2,2-bis (bromofluorenyl) agent, which is optional. From organic aromatic systems, chemical compounds or esters, bisphenols, diphenylhydrin I anhydrides, donkey amines or donkey imines, compounds; and organic fatty compounds, chemical compounds 39 200413457, like compounds Alkanes, oligomeric polymers or polymers, alkyl phosphates or alkyl isocyanurates. These ingredients are well known in the art, such as with reference to US Patent No. 4,579,906 (as described in Section 3) , Lines 30 — 41) '5' 393 '812, see also Plastics Additives

Handbook, Ed. By Η · Zweifd, 5th Ed ·, Hanser Publ.,

Miinich 2001 ’pp. 681 — 698 〇 Thermoplastic resins The thermoplastic resins of component (a) are various types of polymers, including polyolefins, polystyrene, and PVC. For example, the thermoplastic resin may be selected from the group consisting of polyolefins, thermoplastic olefins, styrene polymers and copolymers, ABS and polymers containing heteroatoms, double bonds or aromatic rings. Specific specific examples are components (a) of polypropylene, polyethylene, thermoplastic olefin (Tp0), ABS or polystyrene. For example, the thermoplastic resin is selected from polyolefins, thermoplastic olefins, styrene polymers and copolymers. , And ABS.

另一 Another specific example of the present invention is one in which the thermoplastic resin is selected from the group consisting of polypropylene and ethylene 'thermoplastic olefin (Tpo), ABS, and polystyrene. For example, the thermoplastic resin is polypropylene, polyethylene, or a thermoplastic olefin (0). The organic polymer that is used to damage (a) is, for example, a thermoplastic polymer, such as a dilute hydrocarbon such as polyethylene, or a copolymer thereof. This thermolong polymer = as listed, the thermoplastic resin of component (a) is a polymer of early olefins and diolefins, for example, polypropylene butene, polybutylene-1, polyisobutylene, polybutylene-1 Limonene, 3 40 200413457 Diene or polybutadiene, and polymers of cyclic olefins, 彳 7 columns such as ring six, knee, norbornene, polyethylene (which can be selected, or the original ice release crosslinked , Such as high-density polyethylene (HDPE), high-density and paleo) 'dilute (HDPE-HMW), high-density and ultra-high molecular denier W polyethylen' Α 乙 埽 (ΗΓ) Ρρ

A UHMW), medium density polyethylene (MDPE), ^ E low density polyethylene Γ L D P E), linear low density polyethylene (l τ η ^ K L L ^ P E), r VLDPE) and (ULDPE). As mentioned in the previous paragraph, polypropylene can be prepared from different polyolefins, that is, polymers of monoolefins, such as monoolefin polymers, preferably polyethylene, and methods, especially the following method : A) Polymerization of free-form reactive groups (usually under high pressure and high temperature) b) Catalyst polymerization using a catalyst, which can be used for more than one type of IVb, Vb, Vib or Vl on the periodic table Metals of group jj. These metals usually have one or more types, typically oxides, halides, alcohol esters, esters, ethers, amines, alkylates, alkenyls and / or aryls, which may be 7Γ— Or (7—covalent. These metal complexes can be free or immobilized on a substrate, typically in activated magnesium chloride, titanium (III) chloride, aluminum or silicon oxide. These catalysts are soluble or insoluble In the polymer boundary, and these catalysts can be used in the polymerization reaction themselves or can use activators, typically metal alkylates, metal hydrides, metal alkyl halides, metal alkyl oxides or metals Alkyloxane, the gold It is an element of group Ia, Ia, and / or II of the periodic table. The activator can be further modified with esters, ethers, amines or silane ethers. These catalyst systems are commonly called Phillips, standard Oil 41 200413457

Indiana, Ziegler (-Natta), TNZ (DuPont), metallocene or single-sided catalyst (SSC). 2. Mixtures of polymers & in 1), for example, polypropylene and polyisobutylene, polypropylene and polyethylene (for example, PP / HDPE, PP / LDPPE), and different types of polyethylene mixtures ( (Eg LDPE / HDPE). 3. Copolymers of monoolefins and diolefins with each other, or copolymers with other ethylene monomers, such as ethylene / propylene copolymers, linear low-density polyethylene (LLD PE) and mixtures thereof and low-strength polyethylene (Ethyl d Ρ Ε), propylene / butane-1-ene copolymer, propylene / isobutylene copolymer, ethylene / butane-1 monoene copolymer, ethylene / hexene copolymer, ethylene / methylpentene copolymer Fine / heptane copolymer, ethylene / octane copolymer, propylene / butadiene copolymer, isobutylene / isoprene copolymer, ethylene / alkyl acrylate copolymer, and its formation with carbon monoxide Copolymers or ethylene / acrylic acid copolymers, and their blues (ionized compounds), and terpolymers of acetylene, propylene, and diene, like hexadiene, dicyclopentadiene, or ethylene diene Ene-orbornene; and mixtures of the copolymers and the above-mentioned polymers), such as polypropylene, ethylene, propylene copolymers, LDPe / ethylene-ethylene acetate copolymer (eva), ld PE / Ethylene-acrylic acid copolymer (EAA), LLDPE / E VA, LLDPE / EAA and have a staggered Scattered polyalkoxylated a support structure of carbon monoxide copolymer, and a mixture of other polymers, such as polyethylene amine stuffed. 4 · Hydrocarbon resins (such as Cs-C9) include their hydrogenated compounds 42 200413457 shellfish (thickener) and a mixture of paraffin and starch. The above 1) _ / 1 \) homopolymers and copolymers may have a fluorene structure, including the stereostructure of syndiotactic succinyl, and the stereotactic structure of semi-isotactic or semi-isotactic Random objects. '', ', And fluorene polymers are preferred. It also includes stereoblock polymerization (? -Styrene, poly (P-fluorenylstyrene), ethylene).

Homopolymers and copolymers of monomethyl aromatics, derived precursors 'include styrene' α-methylstyrene, isomers of ethyl ethyl toluene, especially P-vinyl toluene, ethyl All the isomers of acetophenone, propylbenzyl'vinylbisphenyl, vinylnaphthalene, and ethyleneg, and mixtures thereof. Homopolymers and copolymers can include any three-dimensional structure, including syndiotactic 'isotactic' semi-isotactic or atactic; their atactic polymers are preferred. Stereotactic polymers are also included.

6a. A copolymer comprising the aforementioned vinyl aromatic monomer and a co-monomer selected from the group consisting of ethylene, propylene, diene, nitriles, acids, maleic acid, maleic acid, Vinyl acetate and vinyl vapors or acrylic acid derivatives and mixtures thereof, such as styrene / butadiene, styrene / acrylonitrile, styrene / ethylene (interpolymer), styrene / alkylmethacrylate , Styrene / butadiene / fired acrylate, styrene / butadiene / fired methacrylate, styrene / maleic anhydride, styrene / acrylonitrile / methacrylic acid; high impact strength Mixtures of styrene copolymers and other polymers, such as polyacrylates, diene polymers or ethylene / propylene / diene terpolymers; and block copolymers of styrene, like styrene / butadiene / styrene Dilute, Styrene 43 200413457 Ethylene / Isopropyl Diene / Smallene / Ethylene / Ethylene Ethylene / Ethylene, Butene, Styrene or Styrene / Ethylene / propylene / styrene. Chemical :: A diaromatic polymer, derived from the aforementioned 6 ·) polymer, hydrogen phenylethyl 2 polycyclohexylethylbenzene (PCHE), obtained from atactic polyunsaturated / chemical, usually called polyethylene Base ring has been dazzled (PVCH). 6C · Hydrogenated aromatic polymer Hydrogenation reaction. "Polymeric, homopolymers and copolymers can include any stereostructure, including syndiotactic or isotactic +-isotactic, or atactic polymers are preferred and also include stereoblock polymerization Graft copolymers of —7 G alkenyl aromatic monomers, such as styrene or —I-based acetophenone, such as styrene to polybutadiene: ethylene to polybutadiene Diene-styrene or polybutadiene-acrylonitrile co-styrene and acrylonitrile (or methacrylonitrile) are connected to the polybutadiene; the ethylene, propylene, and methyl methacrylate ^ T-based methyl Acrylate to polybutadiene; styrene and maleic acid to polybutadiene; styrene, acrylonitrile, and maleic acid or maleimide to polybutylene Diluted; styrene and maleimide connected to polybutadiene; styrene and burned acrylic or methyl acrylate connected to polybutadiene; styrene and acrylic Dilute nitrile is connected to acetamidine / acrylic / dilute dimer; styrene is suspected to be acetonitrile and polyalkyl acrylate or polyalkyl methacrylic acid To Acrylic acid / butadiene copolymers, and mixtures thereof with the copolymers of item 6), such as the conventional copolymers ABS, MBS, dove or aes polymers. 8 3 prime polymers' like poly Chloroprene, chlorinated rubber, iso200413457 butadiene, isobutylene, a thin gasification and desertification copolymer (_butylated rubber) 'gasified or thiochlorinated polyethylene, ethylene and gasified ethylene copolymer, Epichlorohydrin homopolymers and copolymers, especially polymers containing halide acetofluorene compounds, such as polyvinyl chloride, polyethylene gaseous, polyethylene fluoride, polyethylene fluoride, and copolymers thereof , Such as ethylene gaseous / ethylene diene chloride, ethylene chloride / ethylene acetate or ethylene diene gaseous / ethylene acetate copolymer. 9 · from α '/ 5-unsaturated acid and its derivatives The obtained polymers, such as polyacrylate and polyfluorene acrylate; polyfluorenyl methacrylate, polypropylene amine and polyacrylonitrile, were modified by butyl acrylate. 1 0 · 9) Copolymers formed by occasional and other unsaturated monomers, such as acrylonitrile / butadiene copolymers Polymer, acrylonitrile / alkyl acrylic copolymer, acrylonitrile / alkoxyalkyl acrylate or acrylonitrile / ethylene halide copolymer or acrylonitrile / alkyl methacrylate / butadiene terpolymer copolymer 1 1 · Polymers derived from unsaturated alcohols and amines or their halogenated derivatives or their acetals', for example, polyvinyl alcohol, polyvinyl acetate, polyethylene stearate, polyvinyl benzoic acid Esters, polyethylene maleate, polybutyric acid 'polyfluorenyl caprate or polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1) above. 1 2 · Homopolymers and copolymers of ring scales, such as polyolefin diols, polyethylene oxides, polypropylene oxides, or copolymers of them with dioxypropylene ethers. 1 3 · I fine finish, like polyoxygen Methylene and those polyoxyfluorenes, which contain ethylene oxide as a comonomer, are modified with thermoplastic polyurethane, acrylate, or 45 200413457 M BS. 1 4 · Polyphenylene oxides and sulfides, and mixtures of polystyrene oxides and styrene polymers or polyamides. 15 · Polyurethane derived from hydroxyl terminated polyether, polyester or polybutadiene on one side, and aliphatic or aromatic polyisocyanate on the other side, and its precursors. 16 · Polyamines and copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent lactams, for example, polyamine 4, polyamine 6, polyamine 6/6, 6/10, 6/9, 6/12, 4/6 '12/12, Polyamine 11, Polyamine 12, Aromatic starting from m-dimethylbenzylamine and adipic acid Polyamines; Polyamines derived from hexamethylene diamine and isolies or / and parabens, with or without elastomers used as modifiers, for example, poly-2,4,4- Trimethylhexamethylene p-amine or poly-m-phenylene isoamidine; and the above-mentioned polyamine and polyolefin, olefin copolymer, ionized compound, or chemically bonded or grafted elastomer; or and polyether , Such as block copolymers with polyethylene glycol, polypropylene glycol or polytetramethylene glycol; and polyamines or copolyamides modified with E PDM or AB S; and during the preparation process (R 丨M polyamine system). 1 7 · Polyurea, Polyimide, Polyamidide-Polyimide and Polybenzimidyl sigma 〇18 · Derived from dibasic acid and glycol and / or from hydroxycarboxylic acid or equivalent lactone Polyacetic acid, for example, polyethylene terephthalate, polybutylene parapeptide, poly 1,4-dimethanol cyclohexane terephthalate, polyalkylene cylic acid 46 200413457 ester (PAN) and poly Hydroxybenzoates, and block copolyetheresters derived from hydroxyl-terminated polyethers; and polyesters modified with polycarbonate or BS modified. 19 · Polycarbonate and polyester carbonate. 2 0 · Polyketone. 2 1 · Polyboron, polyether mill and polyetherketone. 2 2 · Blends (polymer blends) of the above polymers, such as PP / EPDM, polyamide " EPDM or ABS, PVC / EVA, PVC / ABS, PVC / MBS, PC / ABS, PBTP / ABS, PC / ASA, PC / PBT, PVC / CPE, PVC / acrylic resin, POM / thermoplastic PUR, PC / thermoplastic PUR, POM / acrylate, POM / MBS, PPO / HIPS, PPO / PA 6.6 and copolymer, PA / HDPE, PA / PP, PA / PPO, PBT / PC / ABS or PBT / PET / PC. The thermoplastic resin of the component (a) is, for example, a polypropylene homopolymer. In particular, it is a resin mainly composed of a polypropylene homopolymer, a wire insulator, a plug, and a socket. The term "plug" here means that the plug forms a part of a plastic container. An example of a plastic motor part of the present invention is a festive decoration lamp. The composition ingredient (b) of the present invention is added at a concentration of about 5% to about 20% Percent by weight (calculated based on the weight of ingredient (a)) For example, component (b) is present in an amount of about 8% to about 17%, or about 11% to about 14% by weight (calculated based on the weight of component (a) ), For example, 'ingredient (b) is present in an amount of about 5% to about 17%, from about 5% to about 14%, from about 5% to about 11%, or from about 5% to about 8% by weight (based on (By weight of ingredient (a)). For example, ingredient (b) is present in an amount of from about 8% to about 20%, from about 47 200413457 to 11% to about 20%, from about 14% to about 20% or from about 17% to about 20% by weight (based on the weight of component (a)). For the polypropylene-based resin of the present invention, the concentration of the component additive composition is preferably about 10% to about 20% Percent by weight (calculated based on the weight of ingredient (a)), for example, ingredient (b) is present in an amount from about 2% to about 18% or from about 14% to about 16% Amount percentage (calculated based on the weight of the & ingredient), for example, ingredient (} 5) is present from about 12% to about 20%, from about 14% to about 20%, from about 16% to about 2 0% or from about 18% to about 20% by weight (calculated based on the weight of component (a). For example, componentized) is present in an amount from about 10% to about 18%, from about 10% to about 16 %, From about 10% to about 14% or from about 10% to about 12% (based on the weight of component (a)) 0 For the polyethylene-based resin of the present invention, component (b) additive composition The concentration is preferably about 5% to about 15% by weight (based on the weight of ingredient (a)), for example, about 7% to about 13% or about to about 11% by weight (based on ingredient (a) Calculated by weight). For example, the amount of ingredient ⑻ is from about 5% to about 12%, from about 5% to about 9% or from: 5% to about 8% by weight (based on the weight of component (a) ). For example, the amount of component (b) is from about 8% to about 15%, from about 1% to about η%, or from about 13% to about 15% by weight (based on the weight of component (a) 〇) to about 1: 200 'for example丨: 15 to about 丨: 100, such as from about 1:70, or about 1:30 to about 1:50. For example, the ingredient (i 48 200413457 is about 1:40 by weight. For example, ingredient ⑴ And ingredients ⑼ 001: 15 1: 20 ° M ^^ 1: 25 1: 'you about 1:30 to about 1: 200 or from about 1:40 to about 1: 200. 〇, ingredients ⑴ and ingredients (Ii) The weight ratio is from 100, from about 1: 5 to about H, and from about 1.5 to -5 about -5 to about 1:40. ^ 1. 5 to about or from a composition of the present invention meets the flame retardant specifications, while not containing or containing only a small amount =: dagger compound 'like Sb203, such as less than about ι%, such as less About eccentricity (calculated based on the weight of ingredient ⑷); for example, the composition of the present invention is not widely recorded. However, in certain formulations, rhenium compounds are advantageous for meeting flame retardant specifications. In order to improve the flame retardant properties and obtain higher evaluation, such as according to Shen UL 94 * NFPA 701 test, flame retardant filler is not necessary. Therefore, 'the composition of the present invention may contain only a small amount of flame retardant filler, such as less than about 3%, such as less than 1%, such as less than about 0.01% by weight based on the weight of ingredient ⑷), for example, The composition of the invention is in principle free of flame retardant fillers. Flame retardant fillers are well known in the art and are selected from the group consisting of magnesium oxychloride, oxide trihydrate, and acid. Flame retardant fillers are called "fillers" because they use inorganic compounds with flame retardancy and their concentration is high enough. If traditional fillers like talc, calcium carbonate and the like are generally used for 'e.g. flow properties' to reduce the diffusion of burning droplets (non flame retardants themselves), then this traditional filler can also be used for the composition of the present invention For example, the composition of the present invention may contain only a small amount of conventional fillers, such as 49 200413457 less 3 / 〇, such as less than 1%, such as less than about 0.00% by weight: ... by weight); for example, the present invention = the suspension is free of conventional fillers. Furthermore, the present invention allows traditional fillers to replace the more expensive flame retardant fillers. As a result of the present invention, the stabilized composition can optionally contain various traditional additives, such as adding from about 0.001 to about 1 〇%, such as from about = 025 to about 4%, such as from about 0.001 to about 2% by weight (based on the weight 1 of the statistic (a)), like the substances listed below, or mixtures thereof. • L-antioxidation, such as 2,6-di-tri-butyl-4 methyl pentane '2--butyl-4,6-dimethylphenol, 2,6 to di-tri-butyl -4-monoethylphenol, 2, 6-di-tertiary-butyl_4_η_τ-based phenol, 2, 6-di-tertiary-butyl-4-isobutylphenol, 2, 6_dicyclopentyl 4-methylol, 2- (α_methylcyclohexyl) _4, 6-dimethylamino 2 6 octadecyl-4 4-methylphenol, 2,4,6-tricyclohexylphenol , 2,6-di-tertiary-butyl-4-methoxymethylphenol, straight-bonded nonyl age or nonylphenol (which has branches on the side), such as 2, 6-dinonyl 4methyl fen '2' 4-dimethyl-1 6- (1'-methyl undecyl-1, 1-yl) -phenol, 2, 4 ~ difluorenyl- 1 (1, 1-methyl 10) Seven-carbon-one, one-base) age, 2,4-one-amidyl- 6- (1'-methyltridecyl-one 1'-one) -pan and its mixture. U · —Sweet-based stone melons substituted with a certain secret, such as 2 ′ 4 —-one octylthiomethyl-1 to third-butyl octylthiomethyl-6-methylpan 50 200413457 2,6 ~ Twenty-two carbane 2,4-dioctylthiomethyl-6-ethylphenolylthiomethyl-4 nonanyl g. ~ And burn a certain hydrogen, for example, 2, a 4-methoxy group, 2, 5 one two one three two three third-buty "quinone, 2, 5- two di-tripentyl Hydroquinone, 2,6-dihydrazine / benzyl ~ 4 ~ octadecyl alkoxyphenol, 2, 6-di-third-butylhydroquinone, 2, 5-dione-three- Butyl_4-hydroxyanisole, 3,5-di-tertiary-butyl_4-hydroxy fungi, 3,5-tris-butyl-4-hydroxyphenyl stearate, bis (3 Butyl-1, 4-phenylyl) adipate, 5-bis-1, ϋΑ, such as α ~ tocopherol, succinate-tocopherol, r-tocopherol, (5-tocopherol and its mixture (vitamin ...) L5 Alkyl phenols, such as 2,2'-thiobis (6-tri-butyl-4-methylphenol), 2, 2, monothiobis (4-octylphenol), 4, 4 ' —Thiobis (6-third-butyl-3-methylphenol), 4, 4, monothiobis (6-third-butyl ~ 2 ~ methylphenol), 4, 4, monosulfide Substituted bis (3, 6-di-di-pentylphenol), 4,4, bis (2, ό-difluorenyl 4-hydroxyphenyl) disulfide. L6 .- ^, for example 2,2,1-methylenebis (6-third-butyl-4-methylphenol), 2, 2, ~ methylenebis (6-third-butyl-4-ethylphenol), 2, 2'monofluorenebis [4 ~ fluorenyl-6- (α-methylcyclohexyl) phenol], 2,2'monomethylbis (4 ~ fluorenyl-cyclohexylphenol), 2,2,1 Bis (bis (6-nonyl-4-methylphenol), 2, 2, monostilb (bis, 4, 6-bis-tris-butylphenol), 2, 2'-ethyl and bis (4, 6 One hundred two one three butyl phenol), 2, 2 'one ethylidene bis (6 to third-butyl_4 one isobutyl phenol), 2, 2, one methylidene 51 200413457 bis [6 — ( α-methylbenzyl) _4_nonylphenol], 2,2, monomethylenebis [6 (Q ^ monomethylbenzyl) -1, 4-nonylphenol], 4,4 'monomethylenebis (2,6-di-tris-butylphenol), 4,4, 1-bis (6-tris-butyl-2-fluorenylphenol), 丨, 丨 -bis (5-tris-1 Butyl-4_hydroxy_2 monomethylphenyl) butane, 2,6-bis (3-third-butyl-5-methyl_2-hydroxybenzyl) -4 monofluorenylphenol, 1,1,3-tris (5-third-butyl-4-1 -2-methylphenyl) butane, 丨, 丨 -bis (5-_third-butyl-4_hydroxy-2-fluorenylphenyl) -3_η_dodecyl mercaptobutane, Ethylene glycol bis [3,3-bis (3,3-tertiary-butyl-4, _hydroxyphenyl) butyrate], bis (3-tertiary-butyl_4_hydroxy-5 monomethyl) Phenyl) dicyclopentadiene, bis [2- (3'-third-butyl-2, -hydroxy_5, monomethylbenzyl) -6-third-butyl-4 methyl Phenyl] terephthalate, i-bis (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis (3,5-di-tertiary-butyl-4) Hydroxyphenyl) propane, 2, 2-bis (5-third-butyl-4-hydroxy-2-2-fluorenylphenyl) 4-n-dodecyl mercaptobutane, 1, 1, 5 ,, 5-tetra- (5-tertiary-butyl-4_hydroxy-2-methylphenyl) pentanyl. U · θ— 'N-diphenylmethyl compound fluorene, for example 3,5 5' —tetrakis-tri-butyl-4,4, -dihydroxydiphenylmethyl ether 5 3, octacarbyl-4 G-methyl-benzyl-wetyl-acetic acid g, butyl-benzyl-wetyl-carbyl-b-yl-4,4-methyl- 3,5-di-di-d-yl-4-hydroxybenzyl) amine, '6 —Dimethyl benzyl) dithio-butyl-4 4-hydroxybenzyl) acetate, tris (3,5 to di-third-butylbis (4-tri-butyl-3-hydroxy) One or two generations of peptidic acid esters, bis (3,5-dione third 52 200413457 sulfide 'isooctyl-3'5-di-third-butyl-4-hydroxybenzylidene acetic acid vinegar. Lithium diacids of i 二 b, such as di- ^ octadecane 2 bis (3,5-di-tri-butyl-2-hydroxybenzyl) malonate, di-18 Carboalkyl 2- (3-tertiary-butyl_4_hydroxy-5a-methylbenzyl) malonate, di-dodecylalkenylweiylethyl 2 _____ (3, $ one one third — Butyl-1,4-hydroxybenzyl) malonate, [4-1 (1'1,3,3-tetra-methylbutyl) phenyl] 2,2 Bis (3,5-mono-second-butyl-4-hydroxybenzyl) malonate. For example 1,3,5_tri (3, -di-third-butyl-4-hydroxybenzyl) Radicals) 2,4,6-trimethyltoluene 1 4 bis (3, 5 one two one three one butyl one 4-hydroxybenzyl) = 2'3,5,6 ~ tetra-methylbenzene , 2,4,6-tris (3,5_di_tertiary-butyl-4-hydroxybenzyl) phenol. For example, 2,4-bisoctylmercapto-6_ (3,5 ~ —di-section Tris-butyl-4-hydroxyaniline) -1,3,5-triazine, 2 'octylmercapto ~ 4,6 —bis (3,5 --_ 筮 --r «. 1 2nd — Butyl-4-hydroxy, 4,6-tris (3'2,3-triazine-feminyl) -ι, 3,5-triazine, 2-octylmercapto_4,6-bisG, 5- One second one butyl one 4-hydroxy styryloxy) one 1,3,5 ~ triamidine, two five one two one third ~ butyl one 4-hydroxy styryl oxy) one 1,3,5 — three (3,5 — one one Chu one v) — younger two ~ butyl one four one succinyl methyl) isocyanurate, 1, three, five two (4 one dai -3 ~ ,, one 14 Second-butyl (3,5-third-butyl-4-hydroxyphenylethyl ～〗, 3 ～ Hydroxy-2, 6-dimethylbenzyl) isocyanurate, 2, 4, 6 53 200413457 — dinoise, P j, 5—tri (3, 5—2—third —Butyl-1, 4-hydroxyphenylpropionyl) hexahydro-1,3,5-triazine, i, 3,5-tris (3,5—dicyclohexyl—4—hydroxybenzyl) isocyanate Uric acid ester.

Lii · Signature methyl ester network_, such as dimethyl 2,5-di-tri-butyl-4-triphenylbenzyl phosphate, diethyl 5-di-tri-butyl-4-hydroxy Benzyl phosphate, di-octadecyl 3, 5 one-two-third tri-butyl ~ 4 mono-hydroxy benzyl phosphate, di-octadecyl 5--3 tert-butyl ~ 4 Monohydroxy_3_fluorenylphenylfluorenyl phosphate, 3,5 ~ bis-tris-butyl-4-mercaptophenylfluorenyl-phosphonic acid monoethyl ester calcium salt.

Uj · fluorenylamino ^, such as 4-hydroxylauryl sulfanilide, 4 monostearyl sulfanilide, N- (3,5-di-third-butyl-4-hydroxyphenyl) amino fluorene Octyl g | 1-13. Esters of β- (3,5-—tri-butyl-4-hydroxybenzyl) propionic acid and single or multiple monohydric alcohols, such as with methanol, ethanol, η-octanol, isooctyl Alcohol, stearyl alcohol, 丨, 6-hexanediol, 丨, 9-nonanediol 'ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, Diethylene glycol 'triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N bis (· ethylethyl) dioxamine dioxamine, 3-thiaundecanol, 3- Thiapentyl alcohol, trimethylhexanediol, trimethylolpropane, 4-monohydroxymethyl-1-conyl-2, 6, 7-trioxabicyclo [2 · 2 · 2] octane. Butyl-4, a certain 3-methylbenzyl) propyl group, and esters of single or multiple monohydric alcohols, such as formazan, ethanol, n-octanol 'isooctanol, octadecyl alcohol, 1,6-hexanediol, 1,9-nonanedi 54 200413457 alcohol, ethylene glycol, 1,1 ^ ~ propylene glycol 'new' '^ hand' thio ^ a glycol 5 2 Glycol 5 2 7 1-Dihexyl glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N, ~ hetero ^ bis (sorylethyl) diamidamide, 3 — Hitachi Undecyl Carbohydrate 3 Hitomi Pentadecanol, Trimethyl Hexane Glycol, Tri Methanol Propane, 4_Phenylmethyl 1 —Dish ~ 2, 6, 7, Trioxabicyclo [2 · 2 · 2] octane; 3, bis [2 ~ (3 ~ third-butyl-1, 4-hydroxy-1; 5-methylphenyl) propanyloxy 丨 -1 ,! f b dimethylethyl] -2,4,8,10-tetraoxaoxa [5.5] undecundamidine. ^ Dicyclohexyl-1, 4-hydroxybenzyl) propionic acid and mono- or more-known-a "-esters of alcohols such as methanol, ethanol, octanol, stearyl alcohol, 1, 6 ^ Hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, hetero # — & 4-pentyl alcohol, thiodiethylene glycol, diethylene glycol, triethylene glycol Ethylene glycol, quaternary ethyl) ethyl methyl hexatetrazolium 'tris (hydroxyethyl) isocyanurate, N, N, bis (hydroxyethyl, τ __ — > amidine, 3-thia Undecyl alcohol, 3-pentadecyl alcohol, triol 'dimethanol propane, 4-methyl via propyl-1, hexacyclobicyclo [2.2.2] octane. Acetic acid and Mono 5 M6. Esters of alcohols or poly-hydroalcohols, such as with methanol, ethanol, octanol, octadecane, "Hexanediol, ^ 9-nonanediol, ethylene di-2-one, Guangxin Pentylene glycol, thiodiethylene glycol, diethylene glycol, trihexylpentaerythritol, tris (hydroxyethyl) isocyanurate, N, N, bis (tert-ethyl) dioxalamide , 3_thia-1 ¥ 苴. Sergeol, 3-thiopentadecanol, hexanediol, Methanol propane, 4-6 oxabicyclo [2.2.2] octane hydroxymethyl-1 1 Lin-1 2 55 200413457 I ΛΊ. Β — (3,5 —Butyl-4 4-hydroxypropionic acid butyl-4— Hydroxylamines, such as N, N1-etc. nc ^, 5-di-tertiary phenylpropionyl) hexamethylene diamidoamine, N, N, bis (3, 5 one two one three one Butyl-1, 4-Aminophenylpropionyl) trimethylenediamine, N, N, —bis (3,5 — 1 —2 —butyl — 4 ~ hydroxyphenylpropanyl) hydrazine) , N, N, —Bis [2— (3 — [3 '5 —Two first pot Λ ^ ^ butyl di 4-butyl hydroxyphenyl] 1 propionyloxy) ethyl] ethylenedifluorene Diamine (Naugard @ XL_i, from

Uniroyal) 〇1.18 · Anti-blood pressure (vitamin c) 〇For example, N, N, -di-isopropyl-p-phenylene-amine N'N---the second ~ butyl-p-phenylenediamine, N, N, -bis (1,4-dimethylpentyl) _p monophenylene diamine, N, n, -bis-ethyl 3 methylpentyl) -P-benzyl diamine, n, N , A bis (1-methylheptyl) -P-phenylenediamine, N, N, a dicyclohexyl-p-phenylenediamine, Ν, Ν'-diphenyl_p_phenylenediamine , N, N, —di (2-naphthyl p p-phenylenediamine, N-isopropyl-N, —benzyl-P-phenylenediamine, N- (l, 3—monomethylbutane Group) -N'-phenyl-phenylene diamine, n-g-methylheptyl) -N'-phenyl-p-phenylene diamine, N-cyclohexyl-n, -phenyl-p —Phenylenediamine '4- (p-Phenylenesulfonylamino) -diphenylamine, N, N, Dimethylamino-N, N, 1,2nd ~ butyl-p-phenylenediamine , Diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1-nylylamine, N- (4-third-octylphenyl )One! —Naphthylamine 'N —phenyl — 2 —desynylamine, octylated diphenylamine, such as p, p,' monodioctyl monobenzylamine '4 — η monobutylamino 4, 4-butane 56 200413457 fluorenylamino group, 4-nononylamino group, 4--h dicarbonamino group, 4-18 carbonamino group phenol, di (4-fluorenyl group) Phenyl) amine, 2,6-di-tris-butyl-4-dimethylaminomethylpan, 2,4'-diaminodiphenylsulfonium, 4, W-diamino Diphenyl methane, N, N, N *, N, tetrakismethyl-4, V-diaminodiphenylphosphonium, 1,2-di [(2-methylphenyl) amino ] Ethyl '1' 2-bis (phenylamino) propane, (0 mono-phenyl) monobiguanidine, di [4- mono (Γ, 3'-dimethylbutyl) phenyl] amine, section Tri-octyl N-phenyl-1naphthylamine, mono- and di-alkylated tertiary-butyl mono / tri-octyl-diphenylamine mixtures, mono- and diphenyl Mixtures of nonyldiphenylamines, mono- and dione alkylated dodecyldiphenylamines, mono- and dione A mixture of acylated isopropyl mono / isohexyl ^ -benzylamine 'a mixture of early one and two one alkylated tertiary butyl diphenylamines, 2,3-dihydro-1,3,3 —Dimethyl—4H —1,4 —benzothiazine, phenothiazine, single and di-alkylated tertiary-butyl mono / tertiary octyl-phenothiazine mixture, single With di-alkylated tertiary octylphenothiazine, N-allylphenothiazine or n, N, N ', N'-tetraphenylphenyl-1,4-diaminobutane — 2-ene, N, N — bis (2,2,6,6-tetramethylpyridine-4-ylhexahexamethylene diamine, bis (2,2,6,6-tetramethylpiperidine -4-1-base) sebacate, 2, 2, 6, 6-tetramethyl-tetramethyl-one 4-ketone, 2, 2, 6, 6, 6-tetramethylpyridine- 4-alcohol. 2 · UV absorption Agents and photostabilizers 2 · 1 · _ 2 — (2-hydroxyphenyl 2Η — jazotriazole, such as the conventionally known basic radicals — 2Η — benzotrisigma and benzotrisigma, as described In U.S. Patent Nos. 3,004,896; 3,055,896; 3,072,585 57 200413457; 3,074,910; 3, 189, 615; 3, 218, 332; 3, 230, 194; 4,127,586; 4,226,763; 4,275,004; 4,278,589; 4,315,848; 4,347, 180; 4, 383, 863; 4, 675, 352; 4, 681, 905, 4, 853, 471; 5, 268, 450; 5, 278, 314; 5, 280, 124; 5, 319, 091; 5, 410, 071; 5, 436, 349; 5, 516, 914; 5, 554, 760; 5, 563, 242; 5, 574, 166; 5, 607, 987, 5, 977, 219, and 6, 166,218 compounds like 2- (2-hydroxy-5methylphenyl)-2H-benzotriazole, 2- (3,5-di-t-butyl-2-hydroxyphenyl)- 2ίί—benzotriazole, 2- (2-hydroxy-butylphenyl)-2Η-benzotriazole, 2- (2-hydroxy ~ 5 — t-octylbenzyl) —2Η-benzotriazine Azole, 5-chloro-2- (3, 5-di-t-butyl- 2-phenylphenyl)-2H-benzotrifluorene, 5-qi- 2-(3-t-butyl- 2 ~ hydroxy -5-Phenylphenyl) -2H-benzotriazole, 2- (3-Second-Butyl-5-t-Butyl-2 2-hydroxy Group) -2H-benzotriazole '2 ~ (2-hydroxy-4 4-octyloxyphenyl)-2H-benzotriazole, 2-(3,5 ~ di ~ 〖monopentyl-2-hydroxyl Phenyl) -2H-benzotriazole, 2_ (3, 5 ~ bis-α-cumyl-2-hydroxyphenyl) -2H_benzotriazole, 2- (3-t-butyl-2-1 Hydroxy_5- (2- (ω_hydroxy-octyl (ethyleneoxy) carbonyl-ethyl)-, phenyl)-2Η-benzotriazole, 2- (3-dodecylalkyl-2 ~ Hydroxy-5-pyridylphenyl) _2Η-benzotriazole, 2- (3-t-butyl ~ 2-hydroxy-5 (2-octyloxycarbonyl) ethylphenyl) _2Η —benzo Triazole, dodecane alkylated 2-one (2-hydroxy-5 5-fluorenylphenyl) —2 pyrene-benzotriazole, 2- (3-t-butyl-1 2-hydroxy-1 5-1 (2-1 Oct 58 200413457 Oxyweiylethyl) phenyl) -5'-gas-2H-benzotrioxa '2- (3-third-butyl-5'-(2- (2-ethylhexyloxy) -weiylethyl Yl)-2-phenylphenyl)-5-chloro-2H-benzotriazole, 2-(3-t-butyl-2-hydroxy-5-(2-methoxycarbonyl) (Ethyl) phenyl)-5 -gas -2H -benzotriazole, 2- (3- t -butyl- 2 -transyl- 5-(2-methoxyepiethyl) phenyl)- 2H —benzotriazole, 2 — (3-t-butyl-5 — (2 — (2-ethylhexyloxy) carbonylethyl) — 2-hydroxyphenyl) — 2H —benzotriazole, 2— (3-t-butyl-1, 2-Ethyl-5, (2-isooctyloxyethyl) phenyl, 2H-benzotrisigma, 2,2 ', 1A, 1double (4- t —octyl-1 (6 — 2 pyrene —benzotrimethylene — 2 radical), 2 — (2 —transyl — 3 — α —cumyl — 5 —t-octylphenyl) 2H —benzene Benzotriazole, 2- (2-hydroxy-1, 3-t-octyl-5-α-cumylphenyl)-2H-benzotriazole, 5-fluoro-2-(2-hydroxy-3'5 — Di-CK-cumylphenyl)-2H-benzotrifluorene, 5-gas-1 2- (2-hydroxy-3,5-di-α-cumylphenyl)-2fluorene-benzotriazole, 5 — chloro-2 — (2 —hydroxy — 3 — α —cumyl — 5 — t —octylphenyl) — 2Η — benzotriazole, 2 — (3 — t —butyl — 2 —Hydroxy-5— (2-Isooctyloxyethyl) phenyl) —5-Gas—2H—benzotrisigma, 5-trifluoromethyl—2— (2—Hydroxy-3—α —Cumyl-5—t—octylphenyl) —2Η—Benzotrione ′ 5 —trifluoromethyl—2— (2-Cyclo-5—t—octylphenyl) —2H—benzo Three σ sitting '5 _ three said methyl one 2-(2-methy 3' 5-two one t octylphenyl)-2H-benzotriazole, methyl 3-(5-trifluoromethyl A 2H —benzotrisigma 2 —yl) — 5 —t — butyl — 4 after hydrazine hydrochloride, 5 — butylsulfonium — 2 — (2 —hydroxy — 3 — α —cumen A 5-t-octylphenyl) -2H-benzotriazole, 5-trifluoromethyl-2— (2-hydroxy-3—α 59 200413457-cumyl-5—t-butylphenyl Bu 2H—benzotriwa, 5-trifluoromethyl-2- (21yl-3,5-di-butylbutylphenyl) -neo-benzotrifluorene '5-trifluoromethyl-2_ (2-1 Hydroxy_3,5-di-"-cumylphenyl"-2'-benzotriazole, 5'-butylsulfonyl-2-(2-hydroxy-3, ^ -di-t-butylphenyl) 2H- benzotriazole and 5-phenyl sulfonylurea -2_ (2 - hydroxy-3,5-di-t- butylphenyl a) -2H_ benzotriazole. Hydroxybenzobenzofluorene, such as 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4'2, '4, -trisyl and 2,4-tris-4,4 | -dimethoxy derivatives are substituted and unbenzyl, such as 4-tert-butyl-phenyl water Salicylic acid esters, phenyl salicylic acid esters, octylphenylsalicylic acid esters, 'dibenzofluorenyl resorcinol', bis (4-tertiary-butylbenzylhydrazine), resorcinol 'I Formamyl isophthalene, 2, 4 -—]-tertiary-butylphenyl 3,5-—one-second-butyl 4-hydroxybenzoate, hexadecyl 3,5— One one second-butyl-4-hydroxybenzoate, octadecyl 3 hydroxybenzoate, 2-methyl-4, -di-third-butyl-1 4-mercapto, 5 —Di-tris-butyl-4 6-Di-tris-butylphenyl 3, benzoate. ια ·. Acrylic acid vinegars, such as ~ cyano-stone, stone-ethyl diphenyl acrylate or α-cyano one-dot-point diphenyl isooctyl acrylate, methoxycarbonyl cinnamon Acid methyl ester, α-cyano-fluorene-methyl-P-methoxycinnamate methyl ester or 0 ~ cyano-lu-methyl_ρ-methoxycinnamate butyl ester, 0: _ Methoxycarbonyl—ρ-methoxycinnamic acid fluorene 60 200413457 Since N (stone-methoxycarbonyl-1 /?-Cyanovinyl)-2 methyl one mouthful. Nickel compound ^, such as 2,2 'monothio-bis [4 — (1,1,3,3-tetra-methylbutyl) phenol] nickel complex, like 丨: 丨 or 丨: 2 complex , Far-selective with other ligands, such as n-butylamine, triethanolamine or ammonium monoethanolamine, monobutyl monothiocarbamate, 4-mercapto ~ 3, 5-bione Third-nickel salt of butylbenzylphosphonic acid monoalkyl, like methyl or ethyl nickel salt, nickel complex of ketooxime, like 2-hydroxy-4 methylphenyl undecyl Nickel complex of alkyl ketone tire, nickel complex of 1-phenyl-4, lauryl, 5-hydroxypyrazole, optionally with other ligands. U · Other steric hindrances, such as bis (2,2,6,6 ~ tetramethyl-4 monomorphinyl) sebacate, bis (2,2,6,6—tetramethyl-4— Succinate) succinate, bis (1,2,2,6,6-pentafluorenyl-4-succinium) sebacate 'bis (1 octyloxy-2,2,6, 6-tetrafluorenyl-4, 4-pyridyl) sebacate, bis (1,2,2,6,6-pentamethyl-1,4-benzyl) η-butyl-1,3,5-dione Tris-butyl-4-hydroxybenzyl malonate, bismuth '1 — (2-Ethylethyl) -2,2,6,6-tetramethyl-1, 4-Ethylmethylpyridine and succinic acid Condensation products, N, N, a bis (2,2,6,6-tetramethyl-4- 4-pyridinyl) hexamethylene diamine and 4 a third-octylamino-2,6-dichloro One 1,3,5-triamidine linear or cyclic condensation product, tris 2,2,6,6-tetramethyl-4-n-pyridinyl) azatriacetate, tetra (2,2,6 , 6—Tetrafluorenyl—4—eridinyl) —1,2,3,4-butane—tetracarboxylic acid ester, i, 1 ′ — (1,2-ethylenediyl) —bis (3, 3 , 5, 5-tetramethylpiperazinone), 61 200413457 4-Benzamidine-2,2,6,6-tetramethylmethylpyridine, 4-stearylmethyloxy-2,2,6,6-tetramethylpiperidine, bis (1,2, 2,6,6 -pentamethylpyridinyl)-2-η-butyl-2-(2-hydroxy-3,5-bis-tert-butylbenzyl) malonate '3 — π-octyl-7,7,9,9-tetrafluorenyl-1,3,8 —tri-D-acyl [4.5] decyl-2,4-dione, bis (1-octyloxy-2,2 , 6,6-tetramethyltonidinyl) sebacate, bis (1-octyloxy-2,2,6,6-tetramethylpiperidinyl) succinate, ν, N, one Straight chain of bis (2,2,6,6-tetramethyl-4-pyridinyl) hexamethylenediamine and 4-morpholine-2,6-dichloro-1,3,5-triazine or Cyclic condensation products, 2-gas-4,6-bis (4-η-butylamino-2,2,6, ό-tetramethylpyridinyl) -1,3,5-triazine and 1,2 —Condensation product of bis (3-aminopropylamino) ethane, 2-gas-4,6-di ((4-η-butylamino) -1,2,2,6,6-pentamethyl Pyridinyl) -1,3,5-triazine and 1,2 Condensation product of bis (3-aminopropylamino) ethane, 8-ethylfluorenyl- 3—h dicarbon alkyl-7, 7, 9, 9-tetramethyl-1, 3, 8 —Triacyl [4.5] decane-2,4-dione, 3-dodecyl-1— (2,2,0, ό—tetramethyl-1—4-pentidyl) pyrrolidine-1 2,5 —dione, 3 —dodecyl — 1 — (1,2,2,6,6 —pentamethyl — 4 —tonidyl) pyrrolidine — 2,5 —dione, 4 — A mixture of hexadecyloxy and 4-stearyloxyoxy-2,2,6,6-tetramethylisocyanate, N, N 'bis (2,2,6,6-tetramethyl Condensation products of a radical 4—orophyl 17-base) hexamethylenediamine and 4-cyclohexylamino—2,6-digas-1,3,5-triazine, 1,2-bis (3-aminopropyl Aminoamino) ethane and 2,4,6-trisgas-1,3,5-triamidine and 4-butylamino-2,2'6,6-tetramethylmeridine (CAS Reg. No. [136504 — 62 200413457 96 6]) 'n — (2' 2 '6, 6 -tetrafluorenyl-4 -piperidinyl) -n-dodecyl butanediamine, N _〇, 2, 2, 6, 6-pentamethyl-4 monofluorenyl) nh dicarbonyl succinimide, 2——h —carbon radical 7 ′ 7 ′ 9, 9-tetramethyl—buoxa — 3, 8_ diacid-4 monooxy-spiro [4: 5] decyl, 7, 7, 9 '9 ~ tetramethyl-2-cyclodeca-chanyl-oxan ~ 3,8—-η Λλ ^ Acryl-12-oxospiro [2,3] decane and chlorohydrin reaction house, 1,1 ~ 雔. ^ ^ ^, 2 '2' 6 '6-pentamethyl-4- 4-methylpyridyloxycarbonyl soil 2 ~ (4-methoxybenzyl) ethene, N, N, -bis-methyl brewer_n , N, — (2,2 f \ '' 6 ~ tetrafluorenyl-4-eridinyl) hexamethylenediamine, 4-methoxy-methylenemalonic acid and 1,2,2,6,6 —The diester of pentamethyl-4-methylpiperidine, poly [fluorenylpropyl-3—oxy-4- (2,2,6,6 tetramethyl-4—piridinyl)] siloxane , Maleic anhydride mono-α-olefins and 2 '2' 6,6-tetramethyl-1 4-aminopyridine or i, 2,6,6-pentamethyl-4 monoaminopyridine reaction product. 63 1 Ethylenediamine, such as 4,4'-dioctyloxypyridoxine 2 amine, 2, 2'_diethoxyoxaloxantil, 2, 2, 1-dioctyloxy-5, 3 One one one second-butyl oxafenacetin, 2, 2, 12-12 alkoxy ~ 5 '5' one two-third butyl oxafenthidine, 2-ethoxyl 2, 1-Ethylpyridamine, N, N, 1-bis (3-dimethylaminopropyl) ethylenediamine, 2-ethoxy-tertiary-butyl-2, 2-ethyl Acetochlor and its mixture with 2-ethoxy-2, -ethyl-5,4, 1,2-tri-butyl oxapyrazine, and 0- and P-methyloxyaniline A mixture of substituted linacetanilide, and a mixture of 0- and p-ethoxy-di-substituted linacetanilide. 200413457 2.8. Triarylaryl-O-Hydroxy-S-Triazine, such as the conventional commercial triaryl-O-Hydroxyphenyl-S-Triazine and disclosed in WO 96/28431 and US Patent No. 3,843,371; 4,619,956; 4,740,542; 5,096,489; 5,106,891; 5,298,067; 5,300,414; 5,354,794; 5 5,461,151; 5,476,937; 5,489,503; 5,543,518; 5,556,973; 5,597,854; 5,681,955; 5,726,309; 5,736 5,597; 5,942,626; 5,959,008; 5,998,116; 6,013,704; 6,060,543; 6,187,919; 6,242,5 98, and 6,255, 483 triazine, such as 4,6-bis (2'4-dimethylphenyl) -2- (2-Cyclo-4-octyloxyphenyl) -s-tri-n-qin, Cyasorb (R) 1164, Cytec Corp, 4,6-bis- (2,4-difluorenylphenyl) -2- (2,4-diacrylphenyl) -s-tri-D-Qin, 2,4-bis (2 '4 —Dimethyphenyl) — 6 — (4-chlorophenyl) — s —trifluorene, 2, 4 — bis [2 —hydroxyl 4 — (2 — Hydroxyethoxy) phenyl] -6- (4-monophenyl) —s-tri-n-qin, 2,4-bis [2-hydroxy-4— (2-hydroxy-4— (2-hydroxyethoxy ) Phenyl] -6- (2,4-difluorenylbenzyl) _s-triazine, 2,4-bis [2-hydroxy-4 (2-hydroxyethoxy) phenyl] -6- ( 4 monobromophenyl) -s-triazine, 2, 4-bis [2-hydroxy-4- (2-ethoxymethylethoxy) phenyl] -6- (4-chlorophenyl) -s —Triazine, 2,4 —bis (2,4-dimethyphenyl) — 6 — (2, 4-dimethylphenyl) —s —triazine, 2, 4—bis (4—bisbenzene Group)-6-(2-hydroxy-4 4-octyloxycarbonyl ethylideneoxyphenyl) -s -dihydrazone, 2-phenyl-4-[2-hydroxy-4-(3-second monobutyl Oxy-2—redylpropoxy) phenyl] —6— [2 —Cyclo-4— (3—2—64 200413457 —oxyl 2—Cyclopropyloxy) phenyl] —s —Triazine, 2,4 —bis (2,4 monomethylphenyl) —6— [2—Cyclo-4— (3-Benzyloxy-2—Cyclopropyloxy) phenyl] — s —Three B Qin, 2, 4 —Bis (2-Cyclo-4—η—butoxyphenyl) —6— (2,4-dione—n—butoxyphenyl) —s—triazine, 2 4 to bis (2,4— Dimethylphenyl) -6- [2-Hydroxy-4- (3-nonyloxy-hydroxypropoxy) -5-α-cumylphenyl] -s_triazine represents octyloxy, nonyloxy A mixture of aryl and decoxy), methylidene {2,4 bis (2,4 dioxenylphenyl) -6— [2—Cyclo-4— (3—butoxy-2) Propylpropoxy) phenyl] -s-triazine}, a dimer mixture of methylated bridges' bridging positions are at 3: 5, 5: 5, and 3: 3, and the ratio is 5: 4: 1,2,4,6-tris (2 monohydroxy-4 monoisooctyloxycarbonyl isopropylideneoxyphenyl) s-triazine, 2,4 bis (2,4 dimethylphenyl) ) — — (2-hydroxy-4 —hexyloxy-5 — α —cumylphenyl) — s —triazine, 2,1,4,6 —trimethylphenyl) —4,6—bis [2 Monohydroxy-4_ (3_butoxy-2-Mylpropoxy) phenyl] -s-triamidine, 2,4,6-tris [2-meryl-4-1 (3-second-butoxy Keiichi 2-hydroxypropoxy) phenyl] -8-triazine, 4,6-bis- (2,4-dimethylphenyl) -2 — (2-hydroxy-4 4- (3-dodecane) Oxy- 2-hydroxypropoxy) -phenyl) -s_triazine and 4, 6-bis- (2,4-diamidinophenyl)-2- (2-hydroxy-4-(3- A mixture of thirteen stone and sulphuroxy-2-propanyloxy) -phenyl) -s-trioxine,

Tinuvin® 400, Ciba Specialty Chemicals Corp., 4,6-bis (2,4-dimethylphenyl) -2— (2—Cyclo-4— (3— (2-ethylhexyloxy)) -2-hydroxypropoxy) -phenyl) -s-triazine and 4,6-diphenyl-2- (4-hexyloxy-2-ylphenyl) -s-triamidine. 65 200413457

Go to .it 'I agent, such as N, N, ~ diphenylglyoxamide N — salicylaldehyde — N' salicylhydrazine, N, N, bis (salicyl salamander), N N ′ _Bis (3, 5-bis-tris-butyl__4_hydroxyphenylpropanyl) hydrazine, 3-salicylamido-1,2,4-triazole, bis (benzyl) ethyl Diacid hydrazide diacid, cirrhotic filament, iso-dihydrazine, * diacid bis-phenyl biscuits, Ν, Ν '~ diethylhydrazine adipate dihydrazide, Ν, ν, -bis- (Hydrazine) Ethylhydrazine dihydrazine, N, N'-bis- (Hydrazine) dihydrazine thiopropionate. Acetic acid complexes such as triphenyl phosphite, diphenyl alkyl phosphite, phenyl dialkyl phosphite, tri (nonylphenyl) phosphite, trilauryl phosphite , Tris-octadecyl phosphite, distearyl monopentaerythritol diphosphite, tris (2, 4-bis-third-butylphenyl) phosphite, diisodecyl pentaerythritol diphosphite Phosphate, bis, 4-11-2 -butylphenyl) pentaerythritol diphosphite, bis (2, 4-cumylphenyl) pentaerythritol diphosphite, bis (2, 6-12) 1-Third-butyl-4 monomethylphenyl) pentaerythritol diphosphite, bis-isodecyloxy-quaternary tetraol-diphosphite g, bis (2,4 ~ di-traditional --- shown Di-butyl-6-methylphenyl) pentaerythritol diphosphite, bis (2,4,6-bis-, distearyl sorbfurol monobutylphenyl) ~ 4,4, tertiary butyl Phenyl) pentaerythritol diphosphite, triphosphinate, tetrakis (2,4 one, two, one, three-diphenylene diphosphonate, isooctyloxy 2, 4, 8, 10, 1 ^ Four-first Fluorenylbenzyl) 6-methylbenzyl) butyl ^ tris-butyl-12H-dibenzo [d, g]-〗, 3,2-dioxaphosphine (phosphocine), bis (2, 4-di-tri-butyl-6-third methyl phosphite, bis (2, 4-di-tri-butyl ethyl phosphinate, 6-fluoro-2, 4, 8, 10—Fat 66 200413457 Butan—dibenzo [d, g] —1,3, 2-dioxaphosene, 2, 2, 2 Nitrogen [triethyl-tri (3, 3f, 5, 5 , One four one three one butyl — 1, ′ ′-bisphenyl one 2, 2, one diyl) monophosphite], ethylhexyl — (3, 3 ', 5, 5' one four one Tert-butyl-ii, -bisphenyl-2,2-diyl) phosphite, 5-butyl-5-ethyl-2- (2,4, ό one-three-third-butylbenzene (Oxy) ~ 1,3,2-dioxaphosphane. Specific examples are the following phosphites: Tris (2,4,1,2-tri-butylphenyl) phosphite (Irgafos @ 168, Ciba — Geigy), tris (nonylphenyl) phosphite

(ch3) 3c

c (ch3):

c (ch3): 67 200413457

5. Triphenylamine ". For example n, n-diphenylmethylhydroxylamine, N, N-di-ethylhydroxylamine, N, dioctylhydroxylamine, N, N-dilaurylhydroxylamine, N, N-214 carbon alkyl amines, N, N- hexadecyl alkyl hydroxyamine, N, N- 218 carbon alkyl hydroxyamine, N- hexadecyl alkyl N -Octadecyl hydroxyamine, N-heptadecyl-N-octadecyl hydroxyamine, N, N-dioxanyl amine prepared from hydrogenated fatty amines. 6. Stone ketones, such as N-benzyl-α-phenylnitrone'N-ethyl-α-fluorenylnitrone, N-octyl-α-heptylnitrone, N-lauryl-68 200413457 α-]-Carbon alkyl nitrone, ν—tetradecyl alkyl—α—tridecyl alkyl nitrone, N—h six carbon alkyl—a—h five carbon alkyl nitrone , N-octadecyl-α-h seven-carbon alkyl nitrone, N-h six-carbon alkyl-α-heptadecenyl nitrone, N-h eight-carbon alkyl-a-h Five-Carbon Base Nitrones, N 17-Carbon Alkyl-α-17-Carbon Nitrate, ν-octadecyl Al-Carbon N-One Ketone, Derived from Hydrogenated Animal Fatty Amines Nitrogenone derived from N, N-dialkylhydroxylamine. 2 Dithio synergists such as dilauryl thiodipropionate or distearyl thiodipropionate. Peroxide breaking compounds, such as esters of thio-dipropionic acid, such as lauryl, stearyl, tetradecyl or tridecyl alkyl, fluorenyl benzimidazole, 2-mercaptobenzene Zinc salt of imidazole, ethyl zinc dibutyl dithiocarbamate, 218 carbon alkyl disulfide, pentaerythritol tetra- (β ~ dicarbon sulfhydryl) propionate g, amine stable, such as steel salt And iodide and / or phosphorus compounds, and divalent ammonium salts. For example, melamine, polyvinyl pyrrolizidine'monocyanodifluoride, tri-dipropyl cyanurate, raw material derivatives, hydrazine derivatives: methamine, polyamine 'polyethyl formate, higher Carbon number fatty acid genus and earth metal salts' such as stearate, zinc stearate, stilbene, magnesium stearate, sodium ricinole, zinc catechin. "Palm ... a pyrocatechuic acid or pyrolizer, such as inorganic substances like titanium dioxide or magnesium oxide, phosphates such as talc 'carbonates,' metal oxides, or preferably alkaline earths 69 200413457 metal sulfates; organic Compounds, such as early mono- or poly-carboxylic acids and their salts, such as 4-tert-butyl benzoic acid, hexamethylene di-Piao ''s, a monoacetic acid, sodium succinate or sodium benzoate; polyhumanization Eighty y a ^ σ mouthpieces, such as ionic copolymers ("ionic bodies (icmomers)"). Special days], soil 疋 1,3: 2,4 a double (3,4,1 two Methylphenylhydrazone) Sorbitol 5. Sorbitol and 3: 2,4 3 · 2,4-bis (p-methyldiphenylidene) mountain (benzyl) sorbitol 1 filled stimulus such as calcium carbonate , Silicates, glass fibers, glass beads, moonstone, Nanling clay, mica, sulfate lock, metal oxide and lice emulsion 'carbon black' stone !, wood powder, and other natural product powders and fibers , Synthetic fibers. MT additives, such as plasticizers, lubricants, emulsifiers, pigments, rheological additives, catalysts, flow modification Agents, fluorene brighteners, fire retardants, antistatic agents, and foaming agents. —'- benzopyrene Youli |?. Indole __, as described in US 4325863; US 4338244; US 5 1753 12 ^ US 5216052; US 5252643; DE-A- 431661 1; DE-A- 4316622; DE-A -43 16876; EP— A— 0589839 or EP—A — 0591 102 compounds, or 3 — [4 Mono (2-ethoxyethoxy) phenyl] -5,7-di-third-butyl-benzofuran-2-one, 5,7-di-tri-butyl-3 — [4 — (2-Stearylethoxyethoxy) phenyl] benzofuran-2-one, 3,3, bis [5,7 —di-tri-butyl-3 — (4 — [2-Hydroxyethoxy] phenyl) monobenzofuran-2-one], 5,7-di-tri-butyl-3-3- (4-diethyl-lactyl radical) Benzofuran-2 — 顚 1 '3 — (4-ethylethyloxy-3,5-difluorenylphenyl) -5 ′ 7-di-tri-butyl-benzofuran—2—70 200413457 ketone, 3— (3, 5 -difluorenyl-4 -trimethylethoxy-phenyl) _5, 7 -di-tertiary-butyl- Benzofuran 2-ketone, 3- (3,4-dimethylphenyl) -5, 7-di-tri-butyl-benzofuran_2-one, 3- (2,3-dimethyl Phenyl) -5,7 ~ di-tertiary-butyl-benzofuran-2-pyridine with 0 $ amine oxides, for example, amine oxide derivatives, as disclosed in US Patent No. 5'844'029 And 5 '880,191, didecylmethylamine oxide, tridecylalkylamine oxide, tris-dodecylamineamine oxide and tris-hexadecylalkylamine oxide. U.S. Patent Nos. 5,844,029 and 5,880,191 disclose the use of saturated hydrocarbon amine oxide-stabilized thermoplastic resins. The disclosed thermoplastic compositions may further include a member selected from the group consisting of phenol antioxidants, hindered amine light stabilizers, and ultraviolet absorbers. , Organic phosphorus compounds, stabilizers or mixtures of stabilizers of alkali metal salts of fatty acids and thiosynergists. The use of amine oxides and stabilizing tinctures for stabilizing polyhydrocarbons is not exemplified. Examples of specific additives are phenol antioxidants (item 丄 above), steric position _ U. item 2.6)) benzotriwa and / or o-triphenylphenyl tri-type light stabilizers ( Item 2. " mentioned above, item 2.8), linoleic acid and 脎 驮 S (see item 4 above) and peroxide-destroying compounds (item 5 above). Other special additives (stabilizers) are benzofuran-2 monoketones, as described in, for example, US-A-4,325,863, us_A-4,338,244 or US-A-5,175, Substance in 312.

The composition of the present invention can further include other UV-i-receiving agents selected from the group consisting of aniline, hydroxybenzophenone, benzoates, and α-s-triazine, oxalocyanoacrylate 71 200413457. In particular, the composition of the present invention may further comprise an effective stable amount of at least one other 2-hydroxyphenyl-2H-benzotriazole; other triaryl-s-triazine; or a hindered amine or a mixture thereof . For example, the other ingredients are selected from the group consisting of pigments, dyes, tinctures, antioxidants, thixotropic agents: leveling aids, alkaline co-stabilizers, other light stabilizers, I absorbers and / or sterically hindered amines, metal passivation Agents, metal oxides, organic fillers, amines and mixtures thereof, especially pigments, antioxidants, calcium stearate, zinc stearate, 2- (2, _hydroxyphenyl) benzotriazole and 2 ~ (2-Ethylphenyl) ~ Stereo hindered amine. , 5-triazine UV absorbers, and can be added separately to the polymer, this separate component such as dry mixing or in the additives and other optional ingredients of the present invention, or mixed with other and then added. If it can be mixed with another substance before being added to the polymer, the molten state will be densified. Advantageously, the composition of the invention may include an acid scavenger. Therefore, the other subject matter of the present invention relates to a flame retardant & composite electrical component composition, including (a)-thermoplastic resin, (b)-effective flame retardant amount of a synergistic mixture containing the following composition (i) at least A sterically hindered alkoxyamine stabilizer, and (ii) at least one conventional organic halogen flame retardant, and (c) an acid scavenger. Acid scavengers are, for example, materials such as hydrogenated talc and amorphous basic magnesium aluminum carbonate, such as those disclosed in US Patent Nos. 4,427,816, 5,106,898, and 5 72 200413457,234,98 1 and their related The disclosure is incorporated herein by reference. Hydrogen talc is also known as hycite or DHT4A. Hydrogenated talc is natural or synthetic. The structure of natural hydrogenated talc is Mg6Al2 (0H) 16C03 · 4 H2O. The basic experimental formula for synthetic talc is ALMgusOH " 36C03 (1 67) · x h2O. Examples of synthetic products include: MgQ.7AlQ.3 (〇HMc: () 3 :) () 15 0.54 H20, Mg4.5Al2 (〇H) 13C03 · 3.5 H20 and

Mg4 2Al (OH) i2 4C03 〇, the acid scavenger is present in the polymer composition in an amount of from about 0.1% to about 1.0% by weight (calculated based on the weight of component (a)). For example, the present invention The acid scavenger is present in an amount from about 0.2% to about 0.8%, or from about 0.4% to about 0.6% by weight (based on the weight of the ingredients). For example, the acid scavengers of the present invention are present from about 0.1% to about 0.8%, from about 0.01% to about 0.6%, from about 0.1% to about 0.4%, or from about 0.1% to About 0.2% by weight (calculated based on the weight of component (a)). For example, the acid scavenger of the present invention is present in an amount from about 0.2% to about 1.0%, from about 0.4% to about ι · 0 / 〇, from about 0.6% to about 1.0%, or from about 0.8% Up to about 10% by weight (calculated based on the weight of ingredient (a)). Acid scavengers can improve the color, odor, and stability of the composition of the present invention. The composition of the present invention may include nano-grade fillers. Nano-sized fillers are also referred to as "nanite," and are disclosed in, for example, US Patent Nos. 5,853,886 and 6,002,419, the relevant disclosures of which are incorporated herein by the present invention as a tea test 73 200413457 Examples of nano-sized fillers of the present invention are phyllosilicates or smectite clays, such as organophilic phyllosilicates, naturally occurring phyllosilicates, synthetic phyllosilicates Acid salt or salt / salt complex of these leaf fragments. Nanometer fillers of the present invention are, for example, montmorillonite, bentonite, beidellites, hectorites, soapstone or stevenstone (Stevensites). For example, nanometer montmorillonite has a "flat plate," or a small plate-like structure. Small plate-like structures generally have a thickness of less than about 2 nm. Small plate-like structures or granular structures usually have an average diameter of about 20 and about 30,000 nm, and a length-to-width ratio between about 30'000: 1 and 20 ·· i. Commercially available nanostructured montmorillonite of this structure is Nanomer® I.42E, available from Nanocor, and Cloisite® 30B 'from Southern Clay. Nano-sized fillers have a very large surface with high surface energy. Therefore, in order to avoid coagulation and allow this nano-sized filler to disperse well in the polymer, the surface energy of this nano-sized filler is inactivated, and it and the polymer Compatibility is more important than general millimeter fillers. Like phyllosilicates, this nano-scale filler is made into an organophilic substance by an ion exchange method, such as reacting with an ammonium salt. This nano-grade organophyllosilicate is easier to swell and is easier to disperse in the polymer matrix. Treated nano-level fillers are also called "treated layered clay material" or "organoclay." The presence of this nano-level filler in the composition of the present invention The concentration is about 0.1% to about 10% by weight (calculated based on the weight of ingredient (a)), such as about 1% to about 9% by weight, such as about 3% to about 7% by weight, 200413457 such as about 5% by weight Percentage (based on the weight of component (a) ... The composition of the present invention may include a melamine-based flame retardant. Examples of this melamine-based flame retardant are: melamine cyanurate, honey Amine borate, amine linoleate g purpose, melamine polyscale acid ester, amine amine pyroscale acid purpose, melamine ammonium polyphosphate, and melamine ammonium pyrophosphate. It is present in an amount from about 0.5% to about 15% by weight, from about 1% to about 15%, from about 3% to about 15% or from about 5% to about 15% by weight (based on ingredient (a) By weight), for example, the amount of melamine-based flame retardant used is from about 0 to 5% to about 12%, from about 0.5% to about 10% 'from about 0.5% to about 8%, or from about 0.5% to about 6% by weight (based on the weight of component (a)). [Embodiment] · The following examples are not intended to be any The method limits the scope of the present invention. The effective flame retardant component (B) refers to the amount required to show effective flame retardance as measured by one of the standard methods for evaluating flame retardance. These include UL 1 694, UL94 and NFPA 701, UL 1694 Test for Flammability of

Small Polymeric Component Materials, 2002; NFPA 701 Standard Methods of Fire Tests for Flame-Resistant Textiles and Films, 1989 and 1996 hdr 1999 editions. UL 94 Test 75 200413457 for Flammability of Plastic Materials for Parts in Devices and Appliances, 5th edition, October 29, 199th. The evaluation is based on the UL 94 V test. The results are shown in the following table: The time after the fire was evaluated and the droplets were burned to condense. V-0 < 10 seconds without V-1 < 30 seconds_ without V-2 < Is there a defect in 30 seconds < Has a defect in 30 seconds > 30 seconds without Example 1: A polypropylene homopolymer sample made of a polypropylene motor insulator comprising 5% by weight of N-cyclohexyloxy hindered amine ( a) — a combination of one of (f) and tris [3-monobromo-2,2-bis (bromomethyl) propyl] linate, each of which is N_cyclohexyloxy hindered amine to traditional The weight ratio of the organic brominated flame retardant is 1:14. The weight percentage is calculated based on the weight of the polymer. Each formulation meets (passes) the tests described in UL 1694, Tests f0r Flammability of Small Polymer Component Materials. f—Example 2: Polyethylene motor parts made of polyethylene motor parts, HDPE and LDPE, including 8% by weight of each of N-cyclohexyloxy hindered amines (a) — (f) and three [3 A composition of monobromo-2,2-bis (bromomethyl) propyl] phosphate, wherein the weight ratio of each N-cyclohexyloxy hindered amine relative to the traditional organic brominated flame retardant is 76 200413457. 1: 14. Each formulation meets (passes) the NFPA 701 test. Example 3: Polystyrene motor parts Repeat Example 2 but the motor parts are polystyrene. Each formulation is tested to UL 94 and UL 1694. Example 4: Acid scavenger Repeated from Examples 1 to 3, but with the addition of about 0.01% to about the acid scavenger of the present invention, an excellent flame retardant effect can be obtained. This additional 0.6% by weight (calculated based on the weight of the polymer) of the acid scavenger of the present invention improves the color, odor, and stability of the flame retardant polymer. Example 5: Repeat the previous example, but replace the tri [3 _ Mo_ 2, 2 bis (bromomethyl) propyl] filler with the following: bis (2, 3-bis $ C) Ether). The bis (2,3-dibromopropyl ether) concentration of the tetrabromobisphenol A is from about 9% to about 15% by weight (calculated based on the amount of the thermoplastic resin). For example, about 10%, 12 % Or 14% by weight. In the present invention, the weight of the sterically hindered alkoxyamine to the traditional organic brominated flame retardant is, for example, from about 丨: 25 to about 丨: 70, from about 丨:% to about ^ = , Such as about 1:40 or 1:50. Trioxide is present in an amount of about 2%; weight percent (based on the weight of the thermoplastic resin). For example, ^, ⑴ @ 3%, 4% ’5% or 6% by weight. Flame retardants based on melamine 4 77 200413457 are also advantageous, for example the presence of melamine-based flame retardants is from about 5% to about 15% by weight (based on the weight of the thermoplastic resin), such as About 6%, 7%, 8%, 9% or 10% by weight. This formulation passed XJL 1694.

78

Claims (1)

200413457 Scope of patent application: 1. A flame-retardant polymer motor component composition, including (a)-thermoplastic resin, and (b)-effective flame-retardant amount of a synergistic mixture containing the following composition (I) at least three-dimensional Alkoxyamine stabilizers, and (II) at least one conventional organic anthracin flame retardant. 2. The composition according to item 1 of the scope of patent application, wherein the alkoxyamine stabilizer of the component (1) is a compound of the following formula E — »-N, wherein G1 and unrelated ones are 1 to 8 respectively. The alkyl groups of two carbon atoms are either pentamethyl, and Z and Z2 are methyl groups, respectively, or & and Z2 together form a linking group, which can be composed of an ester, ether, amidine, and amine. Aryl, carboxyl or ethyl carbamate substituted, and ^ 1 to 18 carbon atoms alkoxy, 5 to 12 carbon atoms% lactyl or 7 to 15 carbon atoms aryl alkoxy , Or e is 〇 ~ τ-(〇H) b, T 疋 is straight chain or branched chain containing alkylene with 18 to 18 carbon atoms, ring to carbon with 18 to 18 carbon atoms, 5 to 18 Diluted ring of carbon atom, straight chain or branched chain alkylene with 4 to 4 carbon atoms, and it is substituted by benzene 79 200413457 group or by one or two alkyl groups of 4 to 4 carbon atoms Substituted by phenyl; b is 1, 2, or 3, but only if b cannot exceed the number of carbon atoms in τ and § 6 疋 2 or 3, each hydroxyl group is bonded to a different carbon atom of τ . 3. The composition according to item 2 of the scope of the patent application, in which alkoxy, cyclohexyloxy, or 10-T- (〇H) b of 18 to 18 carbon atoms, wherein b 疋 1 and T are C2 — Cs alkylene or cyclohexylene. 4. The composition according to item 2 of the scope of patent application, wherein the component alkoxyamine is selected from the group consisting of the following compounds: i —cyclohexyloxy-2,2,6,6 —tetramethyla 4--octadecylalkylaminopyridine; bis-U-octyloxy-2,2,6,6-tetramethyl-n-fluorenyl-4-yl) decanoic acid; 2 '4-bis [ (1-cyclohexyloxy-2,2,6,6-tetramethylpyridinyl-butyl) butylamino] -6- (2-hydroxyethylamino-s-triazine; bis (1- Cyclohexyloxy-2,2,6,6-tetramethylpyridine- 4-yl) adipate; 2 '4-bis [(1-cyclohexyloxy_2,2,6,6— Tetramethylpyridine-4-yl) butylamino] -6-chloro-s_triazine; 1- (2-hydroxy-2-methylpropoxy) -4-hydroxy_2, 2, 6 , 6-tetramethylmorphine; 1- (2-hydroxy-2-fluorenylpropoxy) _4_oxy_2,2,6,6 ~ tetramethylmorphine; 200413457 1- (2-meridyl -2-methylpropoxy) -4- ^ octadecanoyloxy-2,2,6,6-tetramethylpyridine; bis (1- (2-hydroxy- 2-methylpropoxy) Base) _2,2,6, 6-tetramethylpiperidine- 4-yl) sebacate; bis (1- (2-meryl-2-pyridylpropoxy) -2, 2, 6, 6-tetramethylpyridine-1 4-mono) adipate; 2,4-bis [N— [1 -— (2-hydroxy-2—methylpropoxy) —2, 2, 6, 6—tetramethylimidine—4— [] -Butylamino} -6- (2-hydroxyethylamino) -s-tristilbene; 2 '4-bis [(1-¾hexyloxy-2, 2, 6, 6, 6-tetrafluorene) The reaction product is a reaction product of 4-methyl-butylamino] -6-gas-S-triazine and n, N, bis (3-aminopropyl) ethylenediamine); and 2,4 A bis [(1-cyclohexyloxy_2,2,6,6-tetramethylsulfanyl 4- 4-yl) butylamino] -6- (2-hydroxyethylamino-8-triazine ; 4, 4'-hexamethylenebis (amino-2, 2, 6, 6-tetramethylpiperidine) and 2,4-dichloro-6-[(1-cyclohexyloxy-2, 2 , 6,6-Tetramethylpiperidine-4-yl) butylamino] -s-triazine condenses with 2-gas-4,6-bis (dibutylamino) -s-triazine terminal cap An oligomeric compound obtained by the reaction, and a compound of the formula 81 200413457 —I In where n is from 1 to 15. 5. The composition according to item 1 of the application, wherein the organic halogen flame retardant (ii) is selected from the group consisting of chlorinated alkyl phosphates, tris (2-chloroethyl) phosphates, and polybrominated diphenyls. Oxide, decabromodiphenyl oxide, tris [3-mo-2,2-bis (momethyl) propyl] phosphonic acid, tris (2,3-dibromopropyl) phosphate tris (2,3-dichloropropyl) carboxylic acid, hexachloroendo-enyl-tetrahydrobenzenedicarboxylic acid, tetrachloro acid, tetrabromoacid, bis (N, N'-hydroxyl Ethyl) tetrakisphenylenediamine, poly (monochloroethyltriphosphonic acid) S mixture, tetrabromobisphenol A bis (2,3-dibromopropyl ether), brominated epoxy resin, 82 200413457 ethylene bis (tetrabromofluorenimide), bis (hexachlorocyclopentadiene) cyclooctane, chlorinated paraffin, octadiphenyl ether, hexagas cyclopentadiene derivative, 1 , 2 ~ bis (tribromophenoxy) ethane, tetrabromomonobisphenol A, ethylene bis- (dibromo-orbornene dicarboximide), bis ~ (hexagas cyclopentadiene) ring Octane, PTFE, Trinity (2,3-dibromo Yl) - isocyanurate, and one pair of ethylene - tetrabromo peptide (PEI). 6. The composition according to item 1 of the scope of patent application, wherein the organic dentition resistance; (11) the KF machine '4 flame retardant' is preferably a desertified hydrocarbyl acid vinegar or phosphonate. 7. The composition as claimed in claim 1, wherein the thermoplastic resin (a) is polypropylene, polyethylene, propylene / ethylene copolymer or polystyrene. 8. The composition according to item 1 of the patent application range, wherein the weight ratio of the component (i) and the component (ii) is from i: 5 to i: 200. 9. The composition according to item 1 of the patent application range, wherein the component (b) is a synergistic mixture and the present amount is from 5% to 20% by weight (based on the weight of the component (a)). 10. The composition according to item 1 of the patent application scope further includes a melamine-based flame retardant. 83 200413457 The composition of item 1 of Shen Qing's patent scope does not contain fillers, or the content of fillers is less than 3% by weight (based on the weight of component (a)). 12 · The composition of claim 1 which further includes (c) an acid scavenger. 13. A composition as claimed in claim 12 wherein the acid scavenger is free of natural or synthetic hydrogenated talc and amorphous magnesium aluminum carbonate. 14. If the composition of the scope of patent application No. 12 wherein the acid scavenging is present from 0.1% to weight percent (depending on the weight of the component 5 1 5) Such as the scope of the patent application No. 1 plug, socket or socket Wire insulator @ < Motor component composition, which is a pick-up, diagram ... (none) 84 200413457 柒, designated representative picture · β (a) The designated representative picture in this case is: (none) picture. (Two) ) A brief description of the component representative symbols of this representative diagram: (none) 捌 If there is a chemical formula in this case, please disclose the chemical formula that can best show the characteristics of the invention