TWI321143B - Flame retardant polymeric electrical parts - Google Patents

Description

1321143 Hydrocarbons, including specific NOR hindered amines, and halogen-containing and ball-containing flame retardants 〇

Advances in a Revolutionary Flame T?pf^rdant System fill__Polyolefins — R. Srinivasan, B. Rotzinger, Polyolefins 2000 > Int. Conf. Polyolefins 2000 > 57 1 — 58 1 > Revealing a Polycarbonate, including a Specific NOR Hindered amines, and desertified and phosphorus-containing flame retardants. N. Kaprinidis and R. King, in a post on Society 〇f

A summary of the Plastics Engineers website (posted on September, September) discusses the use of NOR hindered amines as flame retardants for polyolefins. This summary was sent to the Polymer Modifiers and Additives Division on paper and was published at the p〇iy〇iefins 2002 conference in Houston, Texas on February 24, 2002. This site is www.PMAD.rtrg. EP 079291 1 A2 discloses a polyolefin composition comprising an alkoxyamine functionalized hindered amine and a tris(trifunctionalized amyl) oleic acid vinegar flame retardant. WO 99/00450 'Application in co-application, us patent application 09/5 02, 239, application date November 3, 1999, and 09/714, 717, application 曰 November 16 '2000' reveals the use of specific The N-oxooxy hindered amine acts as a flame retardant. U.S. Patent No. 6,225,387 discloses organic halide flame retardant polymer compositions. SUMMARY OF THE INVENTION It has now been discovered that specific compositions of sterically hindered aerobic amine stabilizers and organic functional flame retardants are particularly useful for providing flame retardancy to plastic parts for lighting applications and for hard attacking the bond. The ring-shaped floor of a solid carbon atom, ? : 18 carbon atoms of wealth, a linear or branched chain containing 18 carbon atoms of the ring olefinic, one, or by - or two with 4 slave atoms Alkane, and which is substituted by a phenyl group; a phenyl group substituted with an alkyl group of 4 carbon atoms is "widely 1, 2 or 3, but the premise is that b cannot exceed the number of 1 in T, and bS 2戍* The slave in the same carbon atom. When each of the warp groups is linked to τ

An example is alkoxy, cycloalkoxy or aralkyloxymethoxy, propoxy, cyclohexyloxy or octyloxy. U. An example of the steric hindrance stabilizer of the component (1) of the present invention is a formula VIII.

RCH

E--N RCH

(A)

- 3 N - R

4 R

S

P 9 1321143

[|3]k

CO I

10 1321143

11 121321143

τ (Κ) Τ Ρ

Τ Τ τ

Ε. 13 (L) (Μ)

12 1321143

(P)

(Q)

(R) 13 1321143 wherein 疋i is an alkoxy group of 18 carbon atoms, 5 to 12 carbon precursors, an alkoxy group or an alkoxy group of 7 to 15 carbon atoms, or ε β τ —(〇H b) a linear or branched alkylene group containing from 18 carbon atoms to a naphthenic B5 -7 ^ ^ to 18 carbon atoms, 5 to 18 carbons straight: containing a bond Carbonogen TM and IS phenyl substitution ^Phenyl 6疋1' 2 or 3' substituted by one or a group of 1 to 4 carbon atoms, but the premise is that b cannot exceed the number of carbon atoms in τ When b or 2, 3, each hydroxyl group is bonded to the same carbon atom of τ; R is hydrogen or sulfhydryl, m is 1 to 4, when m is 1, I is 虱, h - Cu alkyl , or the alkyl group is selectively interrupted by one or more oxygen atoms, c2-Ci2 alkenyl, c "Ci. aryl, q - C1S aryl, epoxy propyl, aliphatic, ring a monovalent fluorenyl group of a monoester fluorenyl or amino citric acid of a fatty acid or an aromatic acid, such as a fatty carboxylic acid having 2 to 18 carbon atoms, a cycloaliphatic carboxylic acid having 5 1 12 carbon atoms or having 7 — a sulfhydryl group of an aromatic carboxylic acid of 15 carbon atoms, or 1321143

Where X is 0 or 1,

Wherein y is 2 - 4 ; when m is 2, 112 is a C, -C12 alkylene, C4 - C12 olefinic, diphenylene, a series, a cycloaliphatic or a divalent fluorenyl of an aromatic dicarboxylic acid or a diaminodecanoic acid fluorenyl group, for example, an aliphatic dicarboxylic acid having 2 to 18 carbon atoms, a sulfhydryl group of 8 to 14 carbon atoms or a aryl group of an aromatic dicarboxylic acid, or having 14 carbons Atomic fat, cycloaliphatic or aromatic diaminodecanoic acid; fat II has 8 醯15 1321143

or

HCICH ο: ο

ο: ο:

NH

NH wherein D and D 2 are unrelated, respectively, are hydrogen, an alkyl 'aryl or aralkyl group containing up to § carbon atoms, including 3,5-di-tert-butyl-4 benzophenone a group, d3 is hydrogen, or an alkyl or alkenyl group having up to 18 carbon atoms, and d is 〇-20; when m is 3' R2 is a fatty system, an unsaturated fat system, a cycloaliphatic system or an aromatic a trivalent fluorenyl group of a tricarboxylic acid; when m is 4, R2 is a saturated or unsaturated aliphatic or aromatic tetracarboxylic acid tetravalent fluorenyl group, including 1,2,3,4-butane tetracarboxylic acid Acid, 1, 2, 3, 4 - butyl-2 - enetetracarboxylic acid, and 1,2,3,5- and 1,2,4,5-pentanetetracarboxylic acid; P is 1, 2 or 3 , R3 is hydrogen, C, - C12 alkyl, c5-C7 cycloalkyl, C7-C9 aryl, 匚2-C1S decyl, C3 - c5 olefin or benzoquinone; when P is 1 , R 4 is hydrogen, c, —c 18 alkyl, c 5 —c 7 cycloalkyl, c 2 —c 8 alkenyl, which is unsubstituted or substituted by a cyano, carbonyl or carbon quinone diamine, 16 ^/1143 An aryl 'aralkyl group, or a glycidyl group of a formula of CH2~CH(OH)-2 or a formula of CO-Z or a CONH-Z group, wherein Z Hydrogen, Yue or phenyl; or a group of formulas ^ / 1143 or

R

When P is 1, 'Rs and Rule 4 together can be 4 to 6 carbon atoms in the alkane floor or 2~~ oxygen-poly pit floor' fat or aromatic 1,2 or 1,3-dicarboxylic acid醯 醯, when p is 2, I is a direct bond or C 〗 C12 alkylene, C6 - C12 aryl, dimethyl

Stupid, a CH2CH(OH)-CH2 group or a group of CH2—CH(OH)—CH2 ～Q — X — 〇—CH 2 — Cli(OH) — CH 2 —, where X 1321143 is C 2 — C ,. Alkyne, c6-c, 5 arylene or c6-c12 cycloalkane; or, if R3 is not alkane, olefin or phenylhydrazine, r4 can also be a fatty, cycloaliphatic or aromatic dicarboxylic acid a divalent fluorenyl group of an acid or diaminodecanoic acid, or a group of the formula C0-; or r4

Wherein T8 and T9 are not related to each other by hydrogen, an alkyl group of 1 to 18 carbon atoms, or an alkylene or 3-oxapentaylene group of 4 to 6 carbon atoms together with butyl 8 and oxime 9 together, for example, Τ8 Together with Τ9 is a 3-oxo quinone support; when ρ is 3,

R4 is 2,4,6-triazinyl, η is 1 or 2'. When η is 1, R5 and R'5 are each unrelated, respectively, C, -C, 2 alkyl, C2-C12 alkenyl, C7-C12 aralkyl, or R5 is also hydrogen, or R5 and R'5 are C2-C8 alkylene or hydroxyalkylene or C4-C22 nonoxyalkylene; when η is 2, R5 and R' 5 — is (—CH 2 ) 2 C (CH 2 — ) 2 ; r 6 is hydrogen, C, a c 12 alkyl, allyl, phenyl fluorenyl, epoxypropyl or C 2 -C 6 alkoxyalkyl; 18 1321143 When η is 1, R7 is hydrogen, C, -C, 2 alkyl, C3-C5 alkenyl, C7-C9 aralkyl, C5-C7 cycloalkyl, C2-C4 hydroxyalkyl, C2_C6 alkoxy Alkyl, C6-C10 aryl, epoxypropyl, mono-(CH2)t-COO-Q or a formula (CH2)t - 0-CO-Q group, wherein t is 1 or 2, and (^ Is C, -C4 alkyl or phenyl; or when η is 2, 117 is C2-C12 alkylene, c6-c12 aryl, mono-CH2CH(OH)-CH2-0-X-O-CH2-CH (OH)—CH 2 — group, wherein χ is C 2 —C 1 G alkylene, C 6 —C 15 argon or c 6 —C 2 cycloalkane, or a formula —CH 2 CH(OZ′)CH 2 —(0CH 2 -CH(0Z,)CH 2 ) 2-group, where ζ· is an atmosphere, C]-C18 alkyl-allyl, benzyl, c2-C12 alkane or benzoquinone; Q, is -N(R8)- or -ο-; e7 is Ci-c3 alkyl-support _ CH2- CH(R9)—0-group, wherein I is hydrogen, methyl or phenyl, a formula —(CH 2 ) 3 —NH—, or a direct bond; R 10 is nitrogen or C,—C18, r8 Is hydrogen, C〗-c] 8-alkyl, C5-c7 cycloalkyl-c7-cu aryl-cyanoethyl, C6-l aryl, formula -CH2-CH(R9)-0H-based m R9 As defined above; the following formula 1321143

Or a group of the formula G-N-E-CO-N-C —OR2 HX R CH 3

Wherein 〇4 is a C2-C6 alkylene or a C6-C12 aryl group; or R8 is a group of the formula -e7-co-nh-ch2-or10; Formula F represents a repeating structural unit of the polymer, wherein T3 is ethylene or [, 2 - Propylene, is a repeating structural unit derived from an olefin copolymer and a monoalkyl acrylate or a methacrylate; a final polymer such as ethylene and ethyl acetate, wherein k is from 2 to 100; When p is 1 or 2, T4 has the same definition as 114, Τ5 is methyl, Τ6 is fluorenyl or ethyl, or butyl 5 and butyl 6 are tetra- or quinone, such as Τ 5 and Τ 6 is methyl, Μ and Υ are not related to each other, respectively, 曱 or carbonyl, and Τ 4 is ethylene 20 1321143, where η is 2; Τ7 is the same as R7, and Τ7 is for example octagonal, where η Is 2, T1Q and Τ, mutually unrelated are alkylenes of 2 to 12 carbon atoms, respectively, or Tn is

Τ12 is piperazinyl, -NRn-(CH2)d-NR] or -NR(CH2)-N(CH2)-N[(CH2)-N] η a b c f where Rn is the same as R3 or

a, b and c are not related to each other by 2 or 3, and f is 0 or 1, for example, a and c are 3, b is 2 and f is 1; and e is 2, 3 or 4, for example 4; 21 gas Τη is the same as R2, but the premise is that when 11 is 1, T13 cannot be: and Ε2 is different '_c〇- or Ν(6)_, respectively, where Ρθ hydrogen C〗Cl2 alkyl or (: 22 alkoxycarbonylalkyl, for example 1 疋-C0- and e2 are an n(e5)-, I 疋 hydrogen ' 1 i 3G carbon atom of a burnt group, phenyl, naphthyl, the benzene: or the naphthalene The group is substituted by a gas or an alkyl group of from i to 4 carbon atoms, or a phenylalkyl group of 12 carbon atoms, or the phenylalkyl group is substituted with an alkyl group of from i to 4 carbon atoms, I Anthracene hydrogen, an alkyl group of 1 to 30 carbon atoms, a stylyl group, a decyl group or a phenylalkyl group of 7 to 12 carbon atoms, or A and E4 together with a polymethylene group of 4 to 17 carbon atoms. Or the polybenzazole is substituted with up to 4 alkyl groups having 1 to 4 carbon atoms, such as methyl, which is a fatty or aromatic tetravalent group, and R 2 of the formula (Ν) is as described above. The claw is the definition of 1 hour; it is a direct bond, C12 alkylene, phenylene or - nh-g, - NH 'where 〇' is C , -C12 alkylene; or wherein the hindered amine compound is a compound of formula I, II, III, IV, V, VI, VII, VIII, IX, X or XI, 22 1321143

23 1321143

24 1321143

25

丄"+J

In addition, E2, E3 and A are not related to each other, respectively, from 1 to 4, and the red and four unrelated atoms are 1 and 4 carbon atoms. Together with E4 is Wujialou, or E2; and £: another] is a five-pronged support, 4 knife R is an alkyl group of 1 to 18 carbon atoms, and a ring of 5 to 12 carbon atoms is '7 to a bicyclic or tricyclic hydrocarbon group of 12 carbon atoms, a phenylalkyl group of 15 carbon atoms, an aryl group of 6 to 10 carbon atoms or the aromatic group is - to three alkane having 1 to 8 carbon atoms Substituted, R2 is nitrogen or a bond or a bond containing a bond. The alkyl group R_3 to 12 carbon atoms is a burn of 1 to 8 carbon atoms, or r3 is ~

-CO-Rr, a CONR: or a CO-NR2-R wide, R_4 is a calcination of 1 to 8 carbon atoms, and R5 is a hydrogen--linear or branched alkane having 12 to 12 carbon atoms Base or 26 1321143

Or when r4 is ethylene, the two r5 methyl substituents can be bonded by a direct bond, such that the triazine bridge group -N(R5) - R4 - N(R5)- is a piperazine-1,4 —Diyl' R6 is an alkylene of 2 to 8 carbon atoms, or R6 is

The premise is that when R6 is the above structure, Y is not a 0H, A is a 0- or a NR7-, wherein R7 is hydrogen, a straight chain or a branched alkyl group of 1 to 12 carbon atoms, or R7 Yes

27 1321143 i an alkyl alkoxy group of 4 carbon atoms or —N(R 2 ) 2 , wherein τ is a phenoxy group, and one or two substituted phenoxy groups are not hydrogen among 1 to 8 carbon atoms Or maybe

-NCO, an oh-〇-epoxypropyl group, or an X is -nh2 nhnh2, and Υ is -OH, -NH2, - NHR2, wherein & is not hydrogen; or γ is an NCO '-COOH, epoxy The combination of ethane group, monomethyloxypropyl group, or —Si(〇R2)3; or R3—is a ch2ch(oh)r2, wherein r2 is a leuco group, or the alkyl group is one to four oxygen Interrupted by the atom, or r3 —

Γ- is -CH2OR2; or wherein the hindered amine compound is a N, Ν' 'N"--three {2,4-bis[(1 - alkoxy-2,2,6,6-tetradecyl) Acridine-4-yl)alkylamino]-s-triazine-6-yl}-3,3,monoethylenediimine dipropylamine; Ν,Ν, ,Ν'·-三{2 , 4 pairs of [(1-hydrocarbyloxy-2,2,6,6-tetramethyl-spin-4-yl)alkylamino]-s-triazine-6-yl}-3,3' a mixture of an ethylene diimine dipropylamine and a derivative of the formula I, 11 'I Α and a truss bridge, 28 1321143 R丨NH-CH2CH2CH2NR2CH2CH2NR3CH2CH2CH2NHR4(I) T~ Ei- T, (II) T~ E , (IIA) G—Ei— Gr E丨—G2 (III) wherein among the tetraamines of formula I,

Ri and Rz are s-triazine groups E; and one of r3 and r4 is s-triazine group E, the other of ruler 3 or 114 is hydrogen, and E is €1

OR OR R is a fluorenyl 'propyl' 5 hexyl or octyl group such as cyclohexyl

a radical of R 5 疋1 to 1 2 carbon atoms wherein an octyl group in the compound of the formula 11 or IIA, such as 11 - butyl, when R is a propyl group, a cyclohexyl group or a tetraamine substituted by an R 4 group is a group Ε, T and 乃 are each as defined in the above formula (1) in each of the tetraamine s-triazine groups E, forming a bridging group between two tetraamines τ and I, 29 1321143 E ,Yes

乂N everyone is too An^C

II II

OR 〇-L-0 OR or (2) As in Formula IIA, the group E can have two terminal groups in the same tetraamine T, wherein the E group of the two tetraamines is one E, group substitution, or (3) three s-triazine substituents in all tetraamines T can be E, such that in tetraamine T, one E 丨 is linked to T and T 丨, and the second E The hydrazine has two terminal groups, and L is a propylenediyl group, a cyclohexanediyl group or a octyldiyl group; wherein in the compound of the formula III, G, G, and G2 are respectively substituted by R, —R4 as defined in the formula I. a tetraamine, but G and G2 each have an alternative s-tri-D-methyl group E, and G, having two triazine groups E substituted by E, such that there is a bridging group between G and G, And a second bridging group between G, and G2; the mixture is composed of two to four equivalents of 2,4-bis[(1 - alkoxy- 2,2,6,6-tetradecyl) bite 4 -butyl)butylamino]-6-gas-s-30 1321143 triazine and one equivalent of hydrazine, Ν'-bis(3-aminopropyl)ethylenediamine; or the hindered amine is a Illb compound,

A

(Illb) wherein the index η ranges from 1 to 15; R12 is C2-C12 alkylene, C4-C12 olefinic, C5-C7 cycloalkane, C5-C7 cycloalkylene-di(C, -C4 alkylene) , C, — C4 alkylene di(C5—C7 cycloalkane), phenylene di(Crh alkylene) or C4- interrupted by 1,4-piperazinyl, 〇-4>N — X a C12 alkylene group, wherein hydrazine is (: 12 fluorenyl or (h - Cu alkoxy) carbonyl, or has one of the definitions as defined in R14 below, but does not include hydrogen; or R12 is a formula ( Lb1) or (Ic1) compound; 31 1321143 CH. (lb1)

(IC)

Wherein X is c, -c alkyl group 'C5-C12 ring-based group' which is unsubstituted or substituted by 1, 2 or 3 (^-(: 4 alkyl; phenyl, which is unsubstituted Or a C7-c9 phenyl group substituted by i ' 2 or 3 C, — C 4 alkyl or alkoxy, which is unsubstituted or 1 ' 2 or 3 c on the phenyl group — C4 alkyl substituted; and the groups & unrelated are c2_C12 alkylene; R13 ' R14 and R15, (same or different) are hydrogen, C丨-cls alkyl, c5 - Cl2 cycloalkyl 'It is unsubstituted or substituted by 1,2 or 3 C,-C:4 alkyl; C:3 - CIS alkenyl, phenyl, which is unsubstituted, or 1' 2 or 3 C, — C 4 alkyl or Cl — C 4 alkoxy substituted; c 7 — C 9 phenylalkyl, which is unsubstituted or substituted on the phenyl by i, 2 or 3 C 丨 C 4 alkyl a tetrahydrofuranyl group or a C2-C4 alkyl group which is substituted at the 2nd, 3rd or 4th position by a mono-H-substituted 'C丨-C8 alkoxy'-(C丨-c4 alkyl)amine group or a formula ( Ie,) group base;

(Ie')

Where Y is a 〇-, a CH

-CH2CH2 - or > N - CH or -N(R14)(Ri5) is additionally a group of formula (Ie,); 32 1321143 Group A is not related to each other by one-N (Rl4) (Ri5) or 〆 Group of formula (Illd);

X is a 0—or 〉N— Ri6; (Illd) R16 is nitrogen, C! a C18 yard, C3–Ci8, C5 — C12 ί 炫*, which is unsubstituted or consists of 1 , 2 or 3 C1-C4 alkyl substituted; c7-c9 phenylalkyl, which is unsubstituted or substituted with 1,2 or 3C丨-C4 alkyl on the phenyl; tetrahydrofuranyl' (inf) group, H3^CH3 - 0-CHj-CH; -CH3 (inf) H3c ch5 or c2 - c4 alkyl, which is replaced by -oh at the 2, 3 or 4 position - Ci-C8 An alkoxy group, a (C^-C4 Hyun) group or an Ie1 group;

Ri] has one of the definitions as defined by R16; and group B is unrelated to one of the definitions as defined in A. The alkyl group is linear or branched and is, for example, methyl, ethyl, η-propyl 'n-butyl' second-butyl, tert-butyl&, η-hexyl, η-xin Base, 2-ethyl [yl, η-fluorenyl, η-fluorenyl, η-undecylalkyl, η-dodecyl, η-tridecyl, η-tetradecyl Dihexadecanyl or η-octadecyl. The cycloalkyl group includes a cyclopentyl group and a cyclohexyl group; a typical ring-dense group includes a cyclohexane 33 1321143 alkenyl group; however, a typical aralkyl group includes a phenyl fluorenyl group, a methyl-phenylmethyl group, and an α-α-dimethylbenzene. Methyl or phenethyl. Alkoxy and cycloalkoxy groups include relatively equivalent alkyl and cycloalkyl groups. Let h be a monovalent thiol group of a monocarboxylic acid, such as acetic acid, stearic acid, salicylic acid, benzoic acid or 10,000-(3,5-di-n-tert-butyl-4-hydroxyphenyl)propionic acid醯基. Φ is a divalent sulfhydryl group of a dicarboxylic acid, which is, for example, oxalic acid, adipic acid, succinic acid, suberic acid, azelaic acid, dibutylmalonic acid, diphenylmethyl propyl a diacid or butyl-(3,5-di-tri-t-butyl-4-hydroxybenzoinyl)-malonic acid, or a fluorenyl group of a bicycloheptene dicarboxylic acid, wherein the succinate Acid esters and isophthalates are special examples. Suppose I is a divalent fluorenyl group of dicarbamic acid, which is, for example, a fluorenyl group of hexamethyldicarbamic acid or 2'4-nonyldiaminodecanoic acid. The sterically hindered alkoxyamine stabilizers of component (i) are well known in the art 'also known as N-oxo-hindered amines and] Sf 0 R hindered amines or NOR hindered amines. Agent or NOR HALS. It is disclosed, for example, in US Patent Nos. 5,004,770, 5,204,473, 5,096,950, 5,300,544, 5,112,890, 5,124, 378, 5, 145, 893, 5, 216, 156, 5, 844, 026, 6, 117, 995, 6 ' 271, 377, and U_S. Patent Application Serial No. 09/505, 529, application 曰, February 17 曰, 2000, 09/794 , 710, application 曰 'February 27 曰, 2001, 09/714, 717, application 曰, November 16 '2000, 09/502, 239, application date November 3, 1999 and 60 /312,517, filing date, August 15th, 2001. The related disclosures of these patents are incorporated herein by reference. The above-mentioned US Patent No. 6,271,377, and uS Patent Application No. 09/505,529, Shen surname n, - 日丄上上明曰, January 17曰, 2〇〇〇, and 09/794,710 , application 曰, 一曰一|January 17th, 2001, revealing sterically hindered serotonylamine stabilized U b. For the purpose of the present invention (d), this hindered base alkoxyamine stabilizer is considered to be A subclass of sterically hindered alkoxyamine stabilizers and is a part of component (1) of the invention. The hindered methoxy-amine stabilizers are also conventional hydrazine-hydroxyalkoxy hindered amines, or NOR alcohols HALS. A hindered amine suitable for the component (1) includes, for example: '6-tetramethyl- 4----- NOR1 1 - cyclohexyloxy-2,2, octadecylaminopiperidine; NOR2 double (1 Octyloxy-2,2,6,6-tetramethylidenyl-4-yl)sebacate; NOR3 2 '4-bis[(1 -cyclohexyloxy-2,2,6,6_) Tetramethyl acridine-4-yl)butylamino]-6-(2-hydroxyethylamino-s-triazine; NOR4 2' 4-double [(1-cyclohexyloxy-2,2) ,6,6-tetradecylidene-4-yl)butylamino]chloro-s-triazine; NOR5 1 - (2-hydroxy-2-methylpropoxy)_4_hydroxy-2, 2 , 6' 6 - tetramethyl-bite; N0R6 1-(2-hydroxy-2-mercaptopropoxy)_4-oxo-2,2,6,6-tetradecyl bite; NOR 7 1 — ( 2—经基~2—I, I, Shan, h, z-methylpropoxy), 4,18-carbonoxy, 2,2,6,6-tetradecyl Bite; 35 1321143 N0R8 bis (1 -(2-hydroxy-methylpropoxy)_2,2,6,6-tetramethyl-pyrene-one 4-yl) 癸-acid cool'; N0R9 double (1_( 2-hydroxy-2-methylpropoxy 2,2,6 6 —Tetramethyl?. A 4-amino) adipic acid; NOR10 2,4 A pair of {N — Π — (2-hydroxy-2-methylpropoxy)-2, 2, 6,6 -tetramethylimidin-4-yl]-N-butylamino ιό-(2-hydroxyethylamino)-s-triazine; N0R11 2,4-double [(1-cyclohexyloxy- 2 , 2' 6' 6 - Tetramethylpyridinyl-4 Methyl)butylamino]-6-chloro-s-triazine and hydrazine, Ν'-bis(3-aminopropyl)ethylenediamine) Reaction product [CAS Reg. No. 191680 - 81-6]; and N0R12 compound of the formula

Wherein η is from 1 to 15; the compound NOR12 is disclosed in Example 2 of U.S. Patent No. 6,117,995. N0R13 is a bis(1-cyclohexyloxy-2,2' 6,6-tetramethylton0-tetramethyl) adipate. 36 a substance (such as a thickener) and a mixture of polyalkylene and starch. The homopolymers and copolymers of the above 1) to 4) may have any stereostructure including syndiotactic stereoisomerism, semi-isotactic or atactic, wherein the atactic polymer It is better. Also included are stereoblock polymers. . Polystyrene, poly(p-methylstyrene), poly(α-mercaptostyrene). Earth 6 · Aromatic homopolymers and copolymers, derived from ethylene-based aromatic monomers 'including styrene, α-methylstyrene, all isomers of vinyl benzene, especially fluorene-vinyl Toluene, ethyl styrene, propyl styrene, vinyl bisphenyl, vinyl naphthalene, and all isomers of vinyl fluorene' and mixtures thereof. The homopolymers and copolymers may comprise any stereostructure, including syndiotactic, isotactic, semi-isotactic or atactic; wherein atactic polymers are preferred. Also included are stereoblock polymers. 6a. comprising the aforementioned vinyl aromatic monomer and a copolymer selected from the group consisting of ethylene, propylene 'diene, nitriles, acids, maleic anhydride, maleic acid imide 'vinyl Acetate and vinyl vapor or acrylic acid derivatives and mixtures thereof 'eg styrene/butadiene, styrene/acrylonitrile' styrene/ethylene (interpolymer), styrene/alkyl hydrazine acrylate, benzene Ethylene/butadiene/alkyl acrylate, styrene/butadiene/alkyl methacrylate, styrene/maleic anhydride, styrene/acrylonitrile/mercapto acrylic acid; high impact strength styrene copolymer Mixture with other polymers, such as polyacrylates, diene polymers or ethylene/propylene/diene terpolymers; and block copolymers of styrene, like styrene/butadiene/styrene, styrene 43 1321143 Alkene/isoprene/styrene, stupid ethylene/ethylene/butylene/styrene or stupid ethylene/ethylene/propylene/styrene. 6b. Hydrogenated aromatic polymers derived from the aforementioned 6) hydrogenation of polymers', especially including polycyclohexylethylene (PCHE), hydrogenation from atactic polystyrene, commonly referred to as polyvinyl rings Hexane (pvcH). 6c. A hydrogenated aromatic polymer derived from the hydrogenation of the aforementioned 6&) polymer. The homopolymers and copolymers may comprise any stereostructure, including syndiotactic, isotactic, semi-isotactic, or atactic; wherein atactic polymers are preferred, Includes stereoblock polymers. 7. A graft copolymer of a vinyl aromatic monomer, such as a graft copolymer of styrene or α-mercaptostyrene, such as styrene attached to polybutadiene, stupid ethylene to polybutadiene-benzene Ethylene or polybutadiene-acrylonitrile copolymer; styrene and acrylonitrile (or methacrylonitrile) attached to polybutadiene; stupid ethylene, propionitrile and mercapto methacrylate attached to polybutadiene ; styrene and maleic anhydride attached to polybutadiene; # ethylene, acrylonitrile and maleic anhydride or maleimide attached to polybutadiene; styrene and maleimide Attached to polybutadiene; styrene and alkyl acrylate or methacrylic acid s are attached to polybutadiene; styrene and acrylonitrile are attached to ethylene/propylene/diene dimer; styrene and propylene Nitrile is attached to the polyalkyl acrylate or polyalkylene methane oxime on the styrene and acrylonitrile to the acrylate/butadiene copolymer, and the copolymer of the above 6th) Mixtures such as the conventional copolymers ABS, MBS, ASA or AES polymers. 8 · Chlorinated and brominated copolymers (halogenated butyl rubber) containing nitrite polymers, such as polychloroprene, chlorinated rubber, iso 1321143 butene isoprene, chlorinated or sulfur gasification Ethylene, ethylene and gasified ethylene copolymers, surface gas alcohol homopolymers and copolymers 'especially polymers containing halogenated vinyl compounds, for example, polyethylene vapors, polyvinylidene vapors, polyvinyl fluorides, polyvinylidene Fluoride 'and its copolymers' like ethylene gasification / acetylene gasification, ethylene chloride / ethylene acetate or acetylene gas / ethylene acetate copolymer 0 9 · by a ' yS - unsaturated acid The polymers prepared by the preparation thereof, such as polyacrylate and polymethacrylate; polymethyl methacrylate, polyacrylamide and polyacrylonitrile, are modified by butyl acrylate. 10. The copolymer formed between the monomers of the above 9) and other unsaturated monomers, such as acrylonitrile/butadiene copolymer, acrylonitrile/alkyl acrylate copolymer, acrylonitrile/alkoxyalkylacrylic acid Copolymer or copolymer of acrylonitrile/ethylene iodide or acrylonitrile/alkylmethacrylate/butadiene terpolymer. a polymer derived from an unsaturated alcohol and an amine or a halogenated derivative thereof or an acetal thereof, for example, polyvinyl alcohol, polyvinyl acetate, polyethylene stearate, polyvinyl benzoate , polyethylene maleate, polyethyl acetal, polyallyl phthalate or polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1 above. 1 2 . Homopolymers and copolymers of cyclic ethers, such as polyolefin diols, polyethylene oxides, polypropylene oxides or copolymers thereof with dioxypropylcycloether. 1 3. Polyacetal, like polyoxymethane and those polyoxymethylene supports, which contain ethylene oxide as a co-monolithic 'polyurethane, acrylic acid or 45 1321143 MBS modified poly Acetal" 1 4. Polyphenylene oxides and sulfides, and polyphenylene oxides and stupid polymers or polyamines. 1 5 · Shouting by hydroxyl terminal, polyester or polybutadiene on one side, and on the other side, and its precursor. 1 6 · Polyamine and copolymer 6 derived from diamine and equivalent indoleamine, polyamin 6/6,6/1〇6,12/12, polyamine 11 stupid diamine and hexamethylene An acid-derived aromatic citric acid or/and a cation derived from a diacid is used as a modifier, for example, a pair of decylamine or poly-indoline olefin, an olefin copolymer, an ion a compound, or a polystyrene, such as a block copolymer with polyethylene glycol; and an E PDM polyamine; and in the preparation process (RI guanamine. 17. 7. Polyurea, poly-imine saliva. 1 8. A polyester derived from a dicarboxylic acid and a diol and an ester, for example, a polylactic acid or a polyurethane aliphatic or aromatic polycondensation derived from a poly(1,4,2-methanol ring). Acid dicarboxylic acid and/or from amino carboxylic acid or, for example, polyamidamine 4, polyamidamine, 6/9, 6/12, 4/' poly urethane 1 2, made from m-dimethyl glycerol An amine; a hexamethylene diamine and a heteropolyamide having or without 2'4,4-trimethylhexamethyleneamine; and the above polyamine and a polyolefin or a chemically bonded or grafted elastomer; Polypropylene glycol or polytetramethylene glycol Concentrated poly(polyamine) and polybenzazole in AB S modified polyamine or conjugated polyamine system, or from hydroxycarboxylic acid or equivalent internal ethylene terephthalate, Butylene to hexane hexane phthalate, polyalkylene phthalic acid 46 1321143 11% to about 20%, from about 14% to about 20% or from about 17% to about 20% by weight (based on ingredient (a) Weight calculation). For the polypropylene-based resin of the present invention, the concentration of the component (b) additive composition is preferably from about 10% to about 2% by weight based on the weight of the component (a). For example, the ingredient It is present in an amount from about 12% to about 18% or from about 14% to about 16% by weight (based on the weight of ingredient (3)), for example, ingredient (b) is present in an amount from about 12% to about 2〇% 'from about 14% to about 20%, from about 16% to about 2% or from about 18% to about 20% by weight (based on the weight of ingredient (a), for example, the presence of ingredient (b) The amount is from about 10% to about 18%, from about 1% to about 16%, from about 10% to about 14% or from about 1% to about 12% by weight of the component (a). For the polyethylene-based resin of the present invention, the concentration of the component (b) additive composition is preferably from about 5% to about 15% by weight (based on the weight of the component (a)), for example, about From 7% to about 13% or from about to 11% by weight (based on the weight of ingredient (a)). For example, ingredient (8) is present in an amount from about 5% to about 12%, from about 5% to about 9%. Or from about 5% to 8% by weight (based on the weight of ingredient (a)). For example, ingredient (b) is present in an amount from about 8% to about 15%, from about 11% to about 15% or from about 13% to about 15 % by weight (calculated according to the weight of the component (a), the ratio (parts by weight) of the wound (1) to the component (ii) is, for example, from about i to about 1:200', for example, about i: 15 to about i: 1 〇 〇, for example, from about! to about 1:70, or about 30:30 to about 丨:5〇. For example, ingredients (1) Shou 48 1321143 ingredients (1) and ingredients (ii) 1: 25 to about 1: 40 to about 1:200 The ratio of part (ii) is about 1:4 〇 by weight. For example, the ratio is from about 1:15 to about 1:200, from about 200 'from about 1 ··30 to about 1:200 or from about i : the ratio is from about 1:5 to about 1: from about 1:5 to about 1:50, or from, for example, the weight of the ingredient (1) and the component (ii), from about 1:5 to about 1: 7〇, about 1:5 to about 1:40. The composition of the present invention conforms to the flame retardant specification, and contains no or only a small amount of an antimony compound, such as Sb2〇3, such as less than about 1%, such as less than About 0.1% by weight (calculated based on the weight of the component (4)); for example, the composition of the present invention There is no bismuth on the shell. However, in certain formulations, bismuth compounds are advantageous for compliance with flame retardant specifications. To improve flame retardant properties and achieve higher ratings, such as UL 1694, UL 94 and NFPA 701 tests A flame retardant filler is not necessary. Therefore, the composition of the present invention may contain only a small amount of a flame retardant filler, such as less than about 3%, such as less than 1%, such as less than about 〇丨% by weight (based on The weight of the component (a) is calculated, for example, the composition of the invention is in principle free of flame retardant fillers. Flame retardant fillers are well known in the art and are selected from the group consisting of magnesium hydroxide, alumina trihydrate and zinc borate. The flame retardant filler is an inorganic compound having flame retardancy and its concentration is high enough, so it is called a "filler". In case conventional fillers such as talc, calcium carbonate and the like are generally used, for example, for flow properties to reduce the diffusion of combustion droplets (non-flame retardant itself), then this conventional filler may also be used due to the use of the composition of the present invention. For example, the composition of the present invention may contain only a small amount of a conventional filler, for example, 49 1321143 to about 3%, such as less than 1%, such as less than about 8% by weight (depending on the polymer component a The weight calculation); for example, the composition of the present invention is substantially free of conventional fillers. Furthermore, the present invention allows conventional fillers to replace the more expensive flame retardant fillers. As a result of the present invention, the stabilized compositions may optionally contain various conventional additives, for example, from about 1 to about 1 Torr. %, for example from about 0.025 to about 4%, for example from about 〇 to about 2% by weight & (based on the weight of ingredient (a)), such as those listed below, or mixtures thereof. 1. Anti-deuteration agent 曱 ring 壬 L ·!. alkylation, such as 2, 6 - 2, 3 - butyl - 4 - nonyl phenol, 2 - butyl - 4, 6 - dimethyl phenol , 2, 61-2—"Third-butyl-tetraethyl phenol, 2,6-di-tertiary-butyl-4-n-butyl, 2, 6-three-third Base_4_isobutyl, 2,6-dicyclopentyl-4-methylphenol, 2_(α-methylcyclohexyl)-4,6-ylphenol, 2,6-octadecyl- 4-methylphenol, 2,4,6-chain nonylphenol or nonylphenol (which is branched on the side), such as 2,6-amino-4-methylphenol, 2,4-dimethyl 6_(1,-methylundecyl-^-yl)-phenol '2,4-dimethyl-methylheptadeca- 1 ,1-yl]--' 2' 4-trimethyl-6- (1'-methyltridecyl-, a base) and a mixture thereof. 1.2. dadyl sulfur, for example 2,4-dioctylthiomethyl-6-tert-butylphenol '2,4-dioctylthiomethyl-6-methylphenol, hexylphenol, 2 , 6-di-tertiary-tert-butyl 4-methoxymethylphenol 50 1321143 2, 4-dioctylthiomethyl-6-ethylphenol, 2,6-docosylalkylsulfide On behalf of the base of a 4 - 壬 纷. 11 m ^ ^ /, ./.& ns . ..

2-Di-tert-butyl- 4-hydroxy-hydroxy stearate, bis(3,5-di-di-tert-butyl-4-hydroxyphenyl) adipate. There are many births, such as alpha-tocopherol, one tocopherol, gamma-producing, 5-tocopherol and a mixture thereof (vitamin). ~ cold-based sulphuric sulphur phenols, such as 2,2·-thiobis(6-second-butyl-4-methylphenol), 2,2,monothiobis (4-xin) 4,4 thiobis(6-t-monobutyl-3-methyl-), 4,4'-thiobis(6-second-butyl- 2~~methylphenol), 4,4,monothiobis(3,deca-di-second-pentylphenol), 4,4, a double (2,0-dimethyl-4-hydroxyl) disulfide. I·-6. Alkylidene double I, such as 2,2'-methylene bis (6-t-monobutyl-4-methylphenol), 2, 2'~methyl bis (6 - third butyl) 4--4-ethylphenol), 2,2, monomethyl bis[4~~methyl-6-(α-methylcyclohexyl)phenol],

2'-B-double (6-Third-B-B double (4, ό12-Ter 1 butyl phenol), 2, T-butyl- 4-isobutyl phenol), 2, 2 , a methyl group 51 1321143 bis [6-monomethylbenzyl)- 4-nonyl phenol], 2, 2, a bismuth [6 (α, α-dimethyl benzyl) - 4 - Nonylphenol], 4 4 , _ methylene bis ( 2, 6 - 2 - 3 - butyl phenol), 4, 4, monomethyl bis (6 - tert-butyl meth phenol), i - bis(5_third-butyl-4-hydroxy-2-methylphenyl)butane '2' 6-bis(3-tert-butyl-5-fluorenyl-2-hydroxybenzyl) 4- 4-methylphenol, 1,1,3-tris(5-tri-tert-butyl-4-yl-2-methylphenyl)butane, 1,i-double (5-third-but —4~ 经基基 2- mercaptophenyl)_3_n — dodecyl cetylbutane, ethylene glycol bis[3,3 —bis(3′—third-butyl-4, monohydroxy Phenyl)butyrate], bis(3-tert-butyl-4-hydroxy-5-methylphenyl)dicyclopentadiene, bis[2-(3, a third butyl- 2 , a hydroxy group - 5 ι - decyl benzyl group) a 6 - third one Base _4_methylphenyl]p- phthalate, bis-(3,5-dimercapto-2-hydroxyphenyl)butane, 2,2-bis (3,5-2nd second) Butyl-4-pyridylphenyl)propane, 2,2-bis(5-t-butyl-butyl-4-hydroxy-2-methylphenyl)-4-n-dodecylalkyl Butane, 1,1,5,5—41 (5-t-monobutyl-4-hydroxy-2-methylphenyl)pentane. U · 0 — 'On [- and s - stupid methyl compounds, such as 3,5,3', 5, 141, butyl, 4,4,-dihydroxydiphenyl decyl ether, 18 Carboalkyl 4-hydroxy-3,5-dimethylbenzyl decyl acetate, tridecyl-4-tetrahydroxy-3, 5-di-tert-butylbenzyl fluorenyl Acetate, bis(3,5-di-di-t-butyl-4-cyclohydroxyindolyl)amine, bis(4-second-butyl-3-hydroxy- 2,6-dimethylbenzyl Dithiobenzoic acid S曰, bis(3,5-di-tertiary-tert-butyl__4-hydroxyphenylhydrazine) 52 1321143 sulfide, isooctyl- 3,5-di-third Butyl_4 monobenzylidene thioglycolate. 1.8-hydroxybenzylated propylene di-branched cat, such as di-octadecyl 2,2-bis(3,5-di-di-tert-butyl-2-hydroxybenzyl)malonic acid Ester, octadecyanoalkyl 2-(3-t-butyl- 4-hydroxy-5-methylbenzyl)malonate, di-dodecyldecylethyl 2, 2 a pair of (3,5-di-tert-t-butyl-4-hydroxybenzyl)malonate, di-[4-(1,1,3,3-tetradecylbutyl)benzene Base] 2, 2-double (3,5-di-tert-tert-butyl-4-hydroxyphenylindenyl)malonate. 1^·. an aromatic compound such as 1,3,5-tris(3,5-one-second-butyl-4-hydroxybenzoinyl)_2,4,0-trimethylbenzene, 1, 4-bis(3,5-di-tertiary-butyl-4-hydroxybenzyl) 3,5'-6-tetradecylbenzene, 2, 4, 6-three (3, 5-2-1) Tri-butyl- 4-hydroxy-hydroxymethyl)phenol. U 〇. Diazine varnish complex 'for example 2,4 a double octyl fluorenyl group 6 - (3, 5 - a third monobutyl 4-hydroxyanilino, 3, 5 - triazine, 2: Octyl thiol-4,6-double (3,5-di-tert-tert-butyl-4-hydroxylamino)-1,3,5-triazine, 2-octyldecyl- 4, 6 _ double (3,5-tris-butyl-1,4-hydroxyphenoxy, 3,5-triazine, 2,4,6-three (3,5-two-third, one-butyl- 4-) Hydroxyphenoxy)_1 2,3-triazine, 1,3,5-tris(3,5-di-t-buty-4-hydroxymethyl)isocyanurate, 1,3,5 - three (4 - 13 - butyl - 3 - hydroxy - 2,6 - dimethylphenyl fluorenyl) isocyanurate, 2, 4, 6 - (3' 5 - di - 3 - butyl 4- 4-hydroxyphenylethyl)-1,3,5 53-azine, 1,3,5-tris(3,5-di-tert-tert-butyl-4-hydroxyphenylpropyl)hexahydrogen -1,3,5-triazine, 1,3,5-tris(3,5-dicyclohexyl-4-hydroxybenzyl)isocyanurate. For example, dimethyl 2,5-two Third butyl ~ 4 - via benzyl phosphate, diethyl 3, 5 - a tert-butyl 4-yl-p-methyl phosphate, octadecyl 3,5-di-di-butyl- 4-hydroxybenzyl phosphate, dioctadecane Base 5 - a soil - a second - butyl - 4 - hydroxy - 3 - methyl benzyl phosphate, 3 - a second monobutyl - 4-hydroxybenzyl monophosphonic acid monoethyl ester Calcium salt. Baseline stearamine, N_(3,5-diylamine^, for example, 4-hydroxylaurate decyl anilide, 4 tri-butyl- 4-phenylphenyl) carbamic acid octyl Vinegar _X_基一四-hydroxy 莫)) Bingham mouth signed one point - kind of Yongtai exhibition) and one or more -hydro alcohol esters, such as methanol, ethanol, η-octyl isooctyl alcohol , octadecyl alcohol, i, 6-hexane diol, eb 9 - smoldering di-alcohol two-burning diol, neopentyl glycol, thiodiethylene glycol. 14. β -(5- ^ three Diol 'pentaerythritol' tris(transethylethyl) isoflurane 曰N,N,-bis(hydroxyethyl) oxalate diamine, 3-_undec carbon g, 3~瞳pentadecyl alcohol 'Trimethyl hexane diol, trimethyl propylene hydride, 4 _ mei methyl ke _2, 6, 7 - trioxabicyclo[2 .2.2] Xinxeng butyl- 4~hydroxy-3-methyl 1 1 > 1 〇/iT ^ and a single singularity of ft a, A 级 頬 頬 ester, for example with methanol, ethanol, η alcohol, Octanol, octadecyl alcohol, 1,6-hexadiol, 1,9~壬54 1321143 Fermentation 'ethylene glycol, hydrazine, 2-propane diol, neopentyl glycol, thiodiethylene Alcohol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate 'N,N, bis(hydroxyethyl) oxalate diamine, 3__11 carbon yeast ' 3 — _ pentadecyl alcohol 'trimethyl hexane diol, trimethyl methacrylate, 4 - hydroxymethyl - 1 - phosphorus - 2,6,7 - trioxabicyclo[2.2.2] octane; 3 , 9 a pair of [2-{3 - (3 - tert-butyl -4-hydroxyl-5-methylphenyl) propenoxy}- 1,1 - dimethylethyl]- 2, 4,8,1〇-tetra-oxazepine [5.5] undecane. 5. Point one (3,5 - diconazole) 4 _ _ _ phenyl) propionic acid and esters of mono- or polyhydric alcohols 'for example and methanol, ethanol, octanol, stearyl alcohol, 1 ,6-hexanediol, 1,9-nonanediol, ethylene glycol, 2,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol 'Pentaerythritol' tris(transethylethyl)isocyanuric acid g, hydrazine, ν'-bis(transethylethyl)-ethylic acid-branched amine '3 - fluorenyl undecyl alcohol' 3 - fluorenylpentadecanol Trimethyl hexane diol, trimethyl methoxide, 4-hydroxymethyl ketone, ruthenium, 6,7-trioxabicyclo[2.2.2] octane. LJ6_ 3,5 - two = _ third monobutyl ~ 4 - hydrazine acetic acid and mono- or polyhydric alcohol vinegar 'for example with methanol, ethanol, octanol, octadecyl alcohol, 1' 6 - hexane diol ' 1,9 - hydrazine diol, ethylene glycol, 1,2-propanol diol 'neopentyl glycol' thiodiethylene glycol, diethylene glycol, triethylene glycol, Pentaerythritol 'tris(hydroxyethyl)isocyanurate, hydrazine, hydrazine, mono-(hydroxyethyl) oxalate diamine, 3-thidecitol, 3-thipentadecanol, dimethyl A hexane diol, a trimethyl ketone, a 4-methyl group, a ketone, a 2,6' 7-trioxabicyclo[2.2.2] octane. 55 1321143 iAL·^2 (3, 5 - 2 1st, 1st, 1st, 4th, 4th, 1st, 1st, 1st, 1st, 1st, 1st, 1st, 1st, 3rd, 3rd, 3rd, 3rd Butyl-4 hydroxyphenylpropanyl)hexamethylenediamine, hydrazine, hydrazine, a double (3,5-di-tert-butyl-butyl- 4-hydroxyphenylpropanyl) triterpenoid Indoleamine, hydrazine, hydrazine, bis (3,5-di-tri-tert-butyl-4-hydroxyphenylpropanyl) hydrazine, hydrazine, hydrazine, a pair [2 - (3 [3, 5 2-Di-tert-butyl- 4-hydroxyphenyl]-propenyloxy)ethyl]ethylenediaminediamine (Naugard® XL-1, available from Uniroyal). 1 · 18 · Ascorbic acid (vitamin c) » - 19, - saddle anti-gasification agent 'such as N, N'-di-isopropyl _p_phenylene diamine, N, N, one two one second one Benzyl-P-phenylenediamine, N,N,-bis(1 '4-dimethylamyl)_p_phenidene diamine, hydrazine, hydrazine - bis(mono)ethylidene-3-ylpentylpentyl) a p-benzene standard diamine, N, Ν'-bis(1-methylheptyl)-indole-phenylenediamine, hydrazine, hydrazine--dicyclohexyl _p_phenylenediamine, hydrazine, hydrazine -diphenyl-ρ-phenylenediamine, ν' Ν, bis(2-naphthyl)_ρ-phenylenediamine, hydrazine-isopropyl- ν'-phenyl-p-phenylene diamine, N_(l,3-dimethylbutyl)-anthracene, monophenyl-ρ-stupylenediamine, anthracene-(1-methylheptyl)-anthracene-phenyl-p-phenylenediamine, Ν_cyclohexyl-N,-phenyl-p-phenylenediamine, 4-(p-toluenesulfonyl)-diphenylamine, hydrazine, hydrazine, -dimercapto-purine, Ν·-di- Di-butyl-ρ-phenylenediamine, diphenylamine, decylallyldiphenylamine, 4-isopropoxydiphenylamine, ν_styl-1-naphthylamine, hydrazine- (4-Third-octylbenzene Keb-chatylamine, fluorenyl-phenyl-2-naphthylamine, octylated diphenylamine, such as ρ, 〆1-2 di-octyldiphenylamine, 4_η-butylamino Phenol, 4-buter 56 1321143 fluorenylamine group, 4 - bromoamino group, 4--f~ di-carbon Si-amino group, '4-18 carbonase-based amine test' (1 - 4曱oxybenyl)amine ' 2 ' 6 —— —t-butyl-1,4-dimethylaminomethylphenol, 2,4′-diaminodiphenyl decane, 4,4·—two Aminodiphenylmethane' Ν, Ν' N·, N·-tetramethyl- 4, 4-diaminodiphenylmethane, 1,2_bis[(2-methylphenyl)amine Ethyl, 1,2-bis(phenylamino)propane, (〇-曱phenyl)-biguanide, bis[4-(indolyl)-(3-dimethylbutyl)phenyl]amine, Tri-octylated quinone-phenyl-l-nylamine 'single and di-alkylated tri-butyl-/tri-octyl-diphenylamine mixture, single and two-one a mixture of thiolated diphenylamines, a mixture of mono- and di-alkylated twely-carbon diphenylamines - single and a mixture of di-alkylated isopropyl/isohexyldiphenylamine, a mixture of mono- and di-alkylated tert-butyldiphenylamine, 2,3-dihydro-3,3 - dimethyl-4-indolyl-1,4-benzothiazide, a mixture of phenanthrene-mono- and di-alkylated third-butyl-/second-octyl-indenyl, single- And a mixture of a di-alkylated octyl phenyl phenyl azine, fluorenyl-allyl phenothiazine or hydrazine, hydrazine, hydrazine ''' 一 四 四 phenyl 1,4-1,4-diamino butyl butyl _2-ene, ^[,1^~~ bis(2,2,6,6-tetradecyl cyclidine-4-yl-hexamethylenediamine, bis(2' 2,6 ' 6-tetra Kepidin-4-yl) sebacate, 2,2,6 '6-tetradecyl-biting ~4__ 2' 2' 6' 6-tetramethyl-biting a 4-alcohol. k UV only powder and Duo Zhiding - - 笨 笨 笨 一 一 一 一 一 一 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫 岫No. 3, 〇04,896; 3,055 ' 896 ; 3 ' 072 , 585 57 1321143 ; 3 , 074 , 910 ; 3 , 189 , 615 ; 3 , 218 , 332 ; 3 , 230 , 194 ; 4, 127 , 586 ; 4,226,763 ; 4,275,004 ; 4 , 278 , 589 ; 4 , 315 , 848 ; 4 , 347 , 180 ; 4 , 383 , 863 ; 4 , 675 , 352 ; 4 , 681 , 905 , 4 , 853 , 471 ; 5 , 268 , 450 ; 5 , 278 , 314 ; 5 , 280 , 124 ; 5 , 319 , 091 ; 5 , 410 , 071 ; 5 , 436 , 349 ; 5 , 516 , 914 -5 , 554, 760; 5, 563, 242; 5, 574, 166; 5, 607 '987, 5,977,219 and 6,166,218 compounds, like 2-(2-hydroxy-5-methylphenyl) a 2H-benzotriazole, 2 - (3,5-butyl-2-iso-phenyl)- 2H-benzotrisamine, 2 _ (2 - thiol 5-t-butylbenzene Base) a 2H - benzotrim, 2 - (2 - thiol-5-t-octylphenyl)- 2 hydrazine-benzotriazole, 5-gas- 2 - (3,5-di-t-t-butyl-2-hydroxyphenyl)-2H- Benzotriazole, 5-gas-2 - (3-t-butyl-2-hydroxy-5-methylphenyl)- 2H-benzotriazole, 2 - (3 a second butyl-5 —t — Butyl-2-hydroxyphenyl)-2H-benzotrisene, 2-(2-hydroxy-4-isooctyloxyphenyl)-2H-benzotriazole, 2 — (3,5 — Di-t-pentyl 2-hydroxyphenyl)-2H-benzotriazole, 2 —(3,5~bis-α-cumyl-2-hydroxyphenyl)-2H_benzotriazole, 2 —(3-t-butyl-2-hydroxy-5-(2 - (ω-hydroxy-octyl-(ethyleneoxy)carbonyl-ethyl)-, phenyl)-2Η-benzotriazole, 2 —(3 —dodecyl-2-hydroxy-5-methylphenyl)_2Η-benzotriazole, 2 —(3-t-butyl-2-hydroxy-5-(2-octyloxy) Carbonyl)ethylphenyl)-2Η-benzotriazine, dodecaminized 2-(2-hydroxy-5-methylphenyl)_2Η~benzotriazole, 2 — (3 t — butyl 2-hydroxy-5 — (2-octyl 58 1321143 oxycarbonylethyl)phenyl)-5-gas_2H-benzotriazole, 2 — (3_second-butyl-5 —(2-(2-ethylhexyloxy)-carbonylethyl)-2-hydroxyphenyl)-5-chloro-2H-benzotriazole, 2(3_t_butyl-2-hydroxy-5- (2-methoxycarbonylethyl)phenyl)-5-gas_2H_benzotriazole 2 (3 4 butyl-2-hydroxy-5-(2-methoxycarbonylethyl)phenyl) 2H-benzotriazole, 2 - (3-t-butyl-5-(2-(2-ethylhexyloxy)carbonylethyl)-2-hydroxyphenyl)_2H-benzotriazole, 2_(3 —t-butyl-2-hydroxy-5—(2-isooctyloxycarbonylethyl)phenyl-2H-benzotriazole, 2, 2'-f-supported double (4-t-octyl) (6:_2H-benzotriazol-2-yl)phenol), 2-(2-hydroxy-3-α-cumyl-5-(-octylphenyl)-2Η-benzotriazole, 2_( 2_hydroxy-3-t-octyl_5-α-cumylphenyl)-2H_benzotriazole,5-fluoro-2-(2-hydroxy- 3'----^-cumylphenyl )—2H—benzotriazole, 5 - gas - 2 - (2-hydroxy_3,5-di-α-cumylphenyl)_2H_benzotriazole, 5-gas- 2-(2-hydroxy-3-α-cumyl_5-t - octylphenyl) - 2h - benzotriazole, 2-(3-t-butyl-2-hydroxyl_5-(2-isooctyloxycarbonylethyl)phenyl)-5-chloro-2H -benzotriazole, 5-trifluoromethyl-2 - (2-hydroxy-3 - fluorene: - cumyl-5-t-octylphenyl) - 2H monobenzodiazole, 5-trifluoromethyl 2-(2-hydroxy-5-t-octylphenyl)_2H-benzotriazole, 5-trifluoromethyl-2-(2-hydroxy-3,5-di_t_

3~(5_Trifluoromethyl 2H octylphenyl)-2H-benzotriazine, methyl-benzotriazole-2-yl)-5-t-butyl-4-hydroxyhydrocinna Acid ester, 5-butylsulfonyl-2-(2-hydroxy-3-(α-cumyl)-5-t-octylphenyl)-2H-benzotriazole, 5-trifluoromethyl-2(2) _hydroxy-3_^ 59 1321143 — cumyl-5-t-butylphenyl)_2H~benzotriazole, trifluoromethyl-2(2-hydroxy-3-3,5-di-t-butylbenzene Base)_2H_benzotriazole, 5-trifluoromethyl-2(2-hydroxy-3,5-di-α-cumylphenyl)-2Η-benzotriazole, 5-butylsulfonate —2 — (2-hydroxy-3,5-di-t-butylphenyl)-2Η-benzotriazole and 5-phenylsulfonyl- 2—(2 — carpet base 3,5 — one-one t — butylphenyl)~~2U —benzotriene. —i——by benzofuranone, for example, 4-carbyl, 4-methoxy, 4-octyloxy, 4-methoxycarbonyl, 4-dodecyloxy, 4-phenyloxy, 4,2,4·-trihydroxy and 2'-hydroxy- 4,4,1-dimethoxy derivative 2,3. Substituted and unsubstituted molybdenum, such as 4 - third Base-stupyl salicylate phenyl salicylate, octylphenyl salicylate, a benzoyl-based resorcinol, bis(4-mono-butylbenzylidene) 4,21,3,1-butylphenyl stilbene phenolphthalein resorcinol, 2 second monobutyl-4-hydroxybenzoate, hexadecyl tertiary butyl group 4-hydroxybenzoate, octadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, 2-mercapto- 4,6-one-second-butylbenzene Base 3,5-di-tertiary tert-butyl- 4-hydroxy hydroxyformate. 'eg α-cyano-indenyl, /3-diphenylpropionic acid ethyl ester or α-cyano-stone, no-diphenyl diphenyl acrylate, α-methoxycarbonyl cinnamic acid fluorenyl Ester, cyano-indenyl _ Ρ - methoxy cinnamic acid methyl ester or α - cyano - point monomethyl _ methoxy cinnamate butyl ester, α - methoxycarbonyl ρ - A氧基 氧基 曱 曱 曱 114 114 114 114 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱96/28431 and U.S. Patent Nos. 3,843,371; 4,619,956; 4, 740, 542; 5, 096, 489; 5, 106, 891; 5, 298, 067; 5, 300, 414; , 354 , 794 , 5 , 461 , 151 , 5 , 476 , 937 , 5 , 489 , 503 , 5 , 543 , 518 , 5 , 556 , 973 , 5 , 597 , 854 , 5 , 681 , 955 , 5 , 726 309 ; 5 , 736 , 597 ; 5 , 942 , 626 ; 5 , 959 , 008 ; 5 , 998 , 116 ; 6»013 >704; 6 , 060 , 543 ; 6 , 187 , 919 ; 6 , 242 , 598 And 6,255,483 Triazines such as 4,6-bis-(2,4-indanyl)-(2-di-amino-octyloxyphenyl)-s-triazine, Cyasorb® 1164, Cytec Corp, 4,6-bis-(2,4-dimethylphenyl)-2-(2,4-dihydroxyphenyl)-s-triazine, 2,4-bis(2,4-dihydroxyphenyl) a 6-(4-chlorophenyl)_s_triazine, 2,4-bis[2-hydroxy-4-(2-hydroxyethoxy)phenyl]-6(4-chlorophenyl)- S_triazine, 2, 4-bis[2-hydroxy-4-yl-(2-hydroxyl-4-(2-hydroxyethoxy)phenyl]-6-(2,4-diphenyl)- s —triazine, 2,4 a pair of [2-hydroxy-4-(2-hydroxyethoxy)phenyl]- 6-(4-bromophenyl)-s-triazine, 2,4-double [2 —hydroxy 4-(2-oxoethoxyethoxy)phenyl]-6-(4-chlorophenyl)-s-triazine, 2, 4_bis(2,4-dihydroxyphenyl) a 6-(2,4-dimethylphenyl)-3-triazine, 2,4-bis(4-diphenyl)- 0-(2-hydroxy-4-isooctyloxycarbonylethylideneoxy Phenyl) - s - di D Qin, 2 - phenyl - 4 - [2 - hydroxy - 4 - (3 —二—Butoxy 2-(transpropionyloxy)phenyl]-6 — [2 — via the group -4-(3—second-64 pentyloxy- 2-hydroxypropoxy)phenyl ]_s__triazine, 2,4-bis(2,4-methylphenyl)-anthracene-[2-hydroxy-4-yl-(3-phenyloxy-2-hydroxypropyloxy)phenyl]- s —triazine, 2, 4 —bis(2-hydroxy-4-yl-butoxyphenyl)di-6-(2,4-di-n-butoxyphenyl)-s-triazine, 2,4 A pair of (2,4-dimethylphenyl)-6-[2__hydroxy-4_(3-indolyloxy]-2-hydroxypropyloxy)-cumylphenyl]_s-triazine (* represents a mixture of octyloxy, decyloxy and decyloxy groups), methyl bis-{2, 4-bis(2,4-dimethylphenyl)-6-[2------- Butoxy 2-hydroxypropyloxy)phenyl]-s_triazine}, a dimeric mixture of a bridge bridging 'bridge position at 3 H 5, and 3: 3, position, ratio 5: 4 : 1,2, 4, 6 -tris(2-hydroxy-4-4-isooctyloxycarbonylisopropylisooxyphenyl)-s-triazine, 2,4-bis(2,4-dimethylbenzene Base)—6—(2—经基一4- Hexyloxy_5 - ο:-cumylphenyl)-s-triazine, 2_(2,4,6-dimethylphenyl)_4,6-double [2-hydroxyl_4_(3-butoxy) 2 propyloxy)phenyl]-s-triterpene, 2,4,6-tris[2--trans-yl-4-(3-bis-butoxy-2-hydroxypropyloxy)phenyl ]_s_triazine, 4,6-bis-(2,4-dimercaptophenyl)_2-(2-hydroxy-4-yl-(3-undecanoyloxy-2-hydroxypropyloxy)-benzene Base)—3_三_ and 4,6 again (2,4 —monomethylphenyl)_2—(2—transformed by a 4-(3 f" 'three-cracked oxy- 2 - propyloxy a mixture of phenyl)-s-triazine,

Tinuvin® 400 'Ciba Specialty Chemicals corp., 4,6-bis-(2,4-didecylphenyl)_2-(2-hydroxy-4-yl-(3-(2-ethylhexyloxy)-2) Hydroxypropoxy)-phenyl)_s_triazine and 4,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)_s-triazine. 65 1321143 h-^ is deactivated and deactivated, such as ν, ν·-diphenyl oxalate diamine, hydrazine - salicylaldehyde, hydrazine, hydrazine, ν, Ν, _ bis (水扬醯)肼, Ν , Ν '~ bis (3, 5 - 2, 3 - butyl - 4 - hydroxyphenyl propyl fluorenyl) hydrazine, 3 - salicylamine 1,2,4 - triazole, double ( Benzene fork) oxalic acid two brewing wins 'grass aniline, isophthalic acid diterpenoids, azelaic acid bis-phenyl hydrazine 一 — ethoxylated hexanoic acid, ν, Ν' ·—Double one (shuiyang brewing) Ethylene sorghum, Ν, Ν 'one double one (shuiyang 醯) thiopropionate diterpenoid. k bismuth citrate and phosphonic acid vinegar _, such as triphenyl phosphite, diphenyl ketone squamous acid vinegar, the base of the first base of the sub-acid acid, the tris(nonylphenyl) phthalic acid Vinegar 'trilauryl eutectic acid vinegar, tri-octadecyl alkyl phosphite, distearyl pentaerythritol di arsenate, tris(2,4-di-tert-butylphenyl) Phosphate ester, diisodecyl pentaerythritol diphosphite, bis(2,4-di-tert-butyl-butyl)pentaerythritol diphosphite, bis(2,*-di-di-cumylphenyl)-pentaerythritol Diphosphite, bis(2,6-di- 2nd-butyl-4-methylphenyl)pentaerythritol diphosphite, bis-isodecyloxy-pentaerythritol diphosphite, double (2, 4_ _二—third _ butyl-6-methylphenyl) pentaerythritol diphosphite, bis(2, 4, 6_tri-_first butyl phenyl) pentaerythritol diphosphite, tristea sorbitol Sugar alcohol phosphite tetrad (2,4-di- 3rd-butylphenyl)- 4,4,phenylene diphosphonate, 6-isooctyloxy-2, 4, 8, 10-four a butyl- 12H-two stupid [d, g]- Phosphonine, bis(2,4-methylphosphite, bis(2,4-di-di-tert-butyl-6-methylphenyl)-di-tert-butyl- 6 Monomethylphenyl)ethyl phosphite, 6-fluoro-2, 4, 10 - tetra-tert-butyl-66 1321143 12-fluorenyl-dibenzo[d,g]-1,3,2 - Dioxo-filled, 2,2' ' 2"-Nitrogen [Triethyl-tris(3' 3',5' 5|_tetra-tert-butyl- 1,1'-diphenyl _2, 2'-diyl) monophosphite], 2-ethylhexyl-(3' 3'' 5,5'-tetrazol-tert-butyl- 1 '1'-diphenyl- 2 , 2'-'diyl) sub-salt' 5 - butyl _ 5-ethyl 2-(2,4,6-tri-t-butylphenoxy)_1,3,2 - two Oxygen scales. Specific examples are the following phosphites: tris(2,4-di-tert-tert-butylphenyl) linalic acid S (Irgafos® 168, Ciba-Geigy), tris(nonylphenyl) subscale Sour vinegar,

(CH3)3c

c(ch3)3

c(ch3)3 67 1321143

(CH3)3C

Today '00-. Credit (4) C(CH3)3 (CH3)3C (D)

<x

CH, (E)

Alkylamines such as N,N-diphenylmethylhydroxylamine, N,N_: ethylhydroxylamine, N,N-dioctylhydroxylamine, N,N-dilaurylhydroxylamine 'N,N-II~ Tetradecylhydroxylamine, n,N-dihexadecylhydroxylamine' N,N-dioctadecylamylhydroxylamine, N-hexadecylalkyl-N-octadecane Hydroxylamine, N-heptadecaalkyl-N-octadecenylhydroxylamine, N,N-dialkylhydroxylamine prepared by hydrogenating a fatty amine. 6. A nitrone, such as N-benzyl-α-phenyl nitrone, N-ethyl-α-mercaptonitrone, ν-octyl-α-heptyl nitrone, Ν-lauryl-68 α ~undecylalkyl nitrone, N-tetradecylalkyl-α-tridecyl nitroxanthene, hydrazine-hexadecylalkyl~a-pentadecylalkyl nitrone, Ν_18 carbon Alkyl α-heptadecyl nitrone, Ν-hexadecyl-α-heptadecacarbyl _, Ν—ten human Weiji-α-pentadecene (tetra) egg, Ν — heptadecane Base-α-heptadecylalkyl nitrone, Ν-octadecyl _ "- hexadecylalkyl nitrone, derived from hydrogenated animal fatty amine, derived from a hydroxylamine a nitrone. For example, dilauryl thiodipropionate or distearyl thiodipropionate. For example, vinegar of thio-dipropionic acid such as lauryl 'stearyl' four carbon Zinc or tridecyl burned vinegar 'nonylbenzimidazole' 2-zincimidazole zinc salt, dibutyldithiocarbamate zinc, di-octadecyl disulfide, pentaerythritol four cold one a dodecyl mercapto) propionate, such as a copper salt and a composition of an iodide and/or a phosphorus compound, and a divalent salt. A total of one agent, such as melamine, polyvinylpyrrolidone, monocyanoamide, triallyl cyanuric acid Esters, urea derivatives, anthracene derivatives 'amine' polyamines 'polyaminodecanoate ethyl esters' alkali metal and alkaline earth metal salts of higher carbon number fatty acids, such as calcium stearate, zinc stearate, hydrazine Magnesium diphosphate, magnesium stearate, sodium ricinate, potassium palmitate, catechin or pyrocatechin Μ, such as inorganic substances such as talc, metal oxides, like titanium dioxide or magnesium oxide, phosphoric acid Salt, carbonate' or preferably alkaline earth 69

丄i1·!· J metal sulfate; organic compound also - leap year - or polycarboxylic acid and its salts, such as 4 - second monobutyl benzoic acid, hydrazine I, dipyridyl acetic acid, butyl Sodium or sodium benzoate; polymeric compound ^ such as ionic copolymer ("ionic (1〇n〇merS) ·). Particularly good is & 1 j · 2 , 4-double (3丨, 4, monomethyl

Basic nails) sorbose. Alcohol, 1,3 · 9 A j. 2, bis (p- fluorenyl benzophenone) sorbitol and 1,3: 2,4 - (I Tian 1, one (this A) sorbitol. 1 _Filling agent tonic, you 灰 ash acid #5, oxalate, glass fiber, glass beads, talc, kaolin, Φ, farmer's barium sulfate, metal oxides and Hydroxide, carbon black, graphite, hibiscus and other natural products of powders and fibers, synthetic fibers. - Its $^JL' such as plasticizers, lubricants, emulsifiers, pigments, 'rheological additives' catalysts, Flow improver, "study brightener, fire retardant, antistatic agent, bl〇wing agents. ϋ. Feng and taste dinanone and fluorenone, as described in us 4325863; US4338244; US 5175312, US 5216052; US 5252643, DE-A-431661 1; DE-A-4316622; DE-A-4316876; EP-A-0589839 or EP-A-0591 102 compounds ' or 3 - [4 - (2 —ethoxyethoxyethoxy)phenyl]-5,7-di-t-butyl-benzofuran-2-one, 5,7-di-tert-butyl_3_[4-—( 2 - Stearyloxyethoxy)phenyl]benzofuran-2-one, 3,3,-bis[5,7-di-p-tert-butyl-3-(4-[2-hydroxyethoxy] Phenyl]phenyl)-benzofuran-2-branched]],5,7-di-tert-t-butyl-3-(4-ethoxyethyl)benzobenzoin-2-one, 3- ( 4-ethyloxy-3,5-dimethylphenyl)-5,7-di-tert-monobutyl-benzofuran-2-70 1321143 ketone, 3-(3,5-didecyl) 4- 4-trimethylethoxymethyl-phenyl)-5,7-di-second-butyl-benzofuran~~2-ketone, 3-(3,4-dimethylphenyl) 5, 7_Di-tert-butyl-benzofuran-2-one, 3-(2'3-dimethylphenyl)-5,7-2,2-di-tertyl-tert-butyl Monobenzofuran 15. amine green. 'For example, amine oxide derivatives' are disclosed in U.S. Patent Nos. 5,844,029 and 5,880,191, Dimercaptomethylamine oxide, dodecane Alkylamine oxides, tri-dodecylalkylamine oxides and trihexadecylalkylamine oxides. U.S. Patent Nos. 5,844, 〇29 and 5,880,191 disclose the use of The saturated hydrocarbyl amine oxide stabilizes the thermoplastic resin, wherein the thermoplastic composition further comprises a second selected from the group consisting of a phenol antioxidant, a hindered amine light stabilizer, an ultraviolet absorber, an organophosphorus compound, an alkali metal salt of a fatty acid, and a sulfur synergistic agent. a stabilizer or a mixture of stabilizers. The use of a stable polyolefin in combination with an amine oxide and other stabilizers is not illustrated. Examples of specific additives are phenolic antioxidants (Section VIII above), other sterically hindered amines (Section 2.6 above), benzotriazoles and/or quinone-hydroxyphenyl fluorene-based light stabilizers (the above Items 2.1 and 2.8), bismuth citrate and phosphonic acid S (class 4 above) and peroxide-destroying compound (item 5 above). Other special additives (stabilizers) are benzofuran-2-ones, as described, for example, in US-A-4, 325,863, US-A-4,338, 244 or US-A-5,175. Substance in 312" The composition of the present invention can additionally include other flame retardants selected from the group consisting of s-triazine, oxalic anilide, hydroxybenzophenone, benzoate-α-cyanoacrylate 71 1321143 It is also advantageous, for example, that the melamine-based flame retardant is present in an amount of from about 5% to about 15% by weight, based on the weight of the thermoplastic resin, for example about 6%, 7%, 8%, 9%. Or 10% by weight. This formula passes UL 1 694. 78

Claims (1)

1321143 • ·Λ, ί t, _ please patent Male 曰 丨 · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · 5% to 20% by weight (based on the weight of component (a)) a synergistic mixture containing the following composition: (Ο at least one sterically hindered alkoxyamine stabilizer selected from the group consisting of: 1 - cyclohexyloxy-2, 2, 6, 0-tetradecyl- 4-octadecylalkylaminobutyryl; bis(1-octyloxy-2,2, fluorene, 0-tetramethyl Pyridyl 4-yl) sebacate; 2 4 bis[(1 - hexyloxy- 2 '2' 6,6-tetramethyl butyl 4-yl) butylamino]_6 — (2 - hydroxyethylamino-s-triazine; bis(1-cyclohexyl-~2,2,6,6-tetramethyl-n--4-yl) adipate; 6 —Tetramethyldenine bite; 1 (2-hydroxy-2-pyridylpropoxy)-4 Oxo-2,2,6, 2,2,6,6-tetradecyl bite; , 2,6,6—tetradecyl group determination; 79 1321143 bis(1_(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylton °1 Adipic acid S; bis (1 - (2-hydroxy-2-methylpropoxy)- 2,2,6,6-tetramethyl-n-diphenyl) adipate; , 4 — double {N—[1 —(2—hydroxy-2-indolylpropoxy)_2,2,6′ 6-tetramethylhistidine-4-yl]-N —butylamino}— 6 —(2 —transethylethylamino)-s-triazine; 2,4-bis[(1—cyclohexyloxy-2,2,6,6-tetramethylthene-4-yl) Reaction product of butylamino]-6-chloro-s-triazine and N,N1-bis(3-aminopropyl)ethylenediamine; 2'4-bis[(1-cyclohexyloxy-2) , 2' 6,6 - tetramethyl?. -4 -yl)butylamino]-6-(2-hydroxyethylamino-s-triazine; 4,4'-hexa-# double (Amino-2,2' 6,6-tetradecyl) and 2,4-dichloro- 6-[(1 -cyclohexyloxy-2,2,6,6~4) a 4-alkyl)butylamino]-s-three a polymerized compound of a condensation reaction product of a 2-chloro-5,6-bis(dibutylamino)-s-triazine terminal cap; and a compound of the formula 1321143 NIOI Wherein η is from 1 to 15; and (ii) at least one organohalogen flame retardant, gasification burnt base acid, tris(2-chloroethyl) phosphate, polybrominated diphenyl ether, decabromo Diphenyl ether, tris[3 _ _ _ 2,2 — bis (indiyl) propyl]phosphoric acid S, tris(2,3-dibromopropyl) phosphate tris(2,3-di-propyl propyl Phosphate ester, chlorendic acid, tetra-glycolic acid, tetrabromo acid, bis(indole, Ν'-hydroxyethyl) tetra-phenylphenylamine, poly---ethyl triphosphonate Mixture, bis(2,3-dibromopropyl ether) of tetrabromobisphenol A, brominated epoxy resin, ethylene mono-(tetrabromoimide), 81 1321143 bis (six gas% • pentyl sulphide) ring octane, chlorinated paraffin, eight desert two base shouting > hexachlorocyclopentadiene derivative, 1 ' 2 - bis (tribromophenoxy) Ethylene, tetrabromo-bisphenol A, ethylene bis(dibromo-norbornane dicarboxy quinone imine) 'bis-(hexachlorocyclopenta)cyclooctane, PTFE, Trinium 2, 3 -dibromopropyl)-isocyanurate, and a double-tetra-bromopeptide quinone imine, and the weight ratio of the component (1) to the component (ii) ranges from 1:5 to 1: 200. 2. The composition of claim 1, further comprising (c) an acid scavenger selected from the group consisting of natural or synthetic hydrotalcite and amorphous basic aluminum magnesium carbonate. 3. The composition of claim 2, wherein the acid scavenger is present in an amount from 0.1% to K0% by weight (based on the weight of the component (a)). Pick up, round: (none) 82