TW201035207A - Method of modifying gloss with melamine derivatives and related products and uses - Google Patents

Abstract

The present invention relates to methods of modulating the gloss of plastics materials and products made from them, such as articles in the automotive industry e.g. for the interior of automobiles, as well as the use of certain additives for that purpose and related invention embodiments. The modulating comprises adding a melamine derivative, especially a melamine phosphate or a melamine cyanurate, or mixtures thereof, to a polymer composition used as polymer substrate for the articles.

Description

201035207 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to the use of a melamine derivative as a gloss modifier in a polymer product, a corresponding method and process, and an available product. . [Prior Art] In short, the present invention also provides a method of adjusting (especially reducing the gloss of a polymeric composition) which comprises adding a melamine derivative to a polymeric composition; a method of producing the same, and a corresponding polymerization combination And products produced from such polymer compositions. The low gloss polymeric composition formed in accordance with the present invention is suitable for use in the polymerization having a matte surface treatment. The system is advantageous for applications such as certain automotive (internal) applications. It has long been considered that polymers (especially ρρ (poly(propylene)) and τρ〇 (thermoplastic = (lean)) have technical and % advantages in the automotive market for objects such as automotive interior parts. Most of the shortcomings of commercial τρο materials used for this application are: painting or coatings or other coatings to provide adequate resistance to the final part and to maintain a uniform (low) gloss. Balances such as low degree, convenient processing performance and good cost/performance == advantages are based on the desire of advanced materials for automotive interiors and exteriors. End customers (especially car buyers) are high in quality. Manufacturers (especially car manufacturers) are trying to borrow again. Surface properties, such as scratch resistance, expensive appearance, and good safety properties (such as 2; adjustment, color and new requirements, etc., (1, such as avoiding light reflection annoyance) and meet 143814.doc 201035207 internal application most affected y,, * + + y „ ^ is found in the instrument panel structure, console, Α; inside: decorative parts, the dashboard itself and the surface of the door panel, and also the seat group "handle, cargo lining, engine room components Or other fields of analogy, etc., such as for casings, appliances, consumer or outdoor vehicles and devices or any other optical condition requiring good mechanical strength HZ (such as low cut) Parts or (for example, fibers or thin substrates (low gloss and improved scratch resistance are still unrealized, such as illusion, talc-filled ruthenium copolymer or based on rushing (surface layer) The substrate of these materials. Since the composition of these materials can vary widely, it is clear that low gloss and scratch resistance depend on the type and content of the resin, elastomer and talc used, stabilizer, and co-additives and pigments. And other fillings In addition, the processing conditions and surface texture (texture) also play an important role. These novel materials are intended to be used without any coating, and the right (formed during the surface layer manufacturing) and the negative mold (in the mold) Both forming processes can be used. In order to achieve low gloss, the material has been filled with materials. However, in many applications, these types of fillers are likely to damage the mechanical properties of the resulting article, and at the same time, it is not always possible to provide a uniform surface treatment. Low gloss can also be achieved by using a suitable surface texture on the injection molding tool. However, maintaining a relatively low gloss during manufacturing requires frequent cleaning/reprocessing, which can be expensive and requires a large amount of labor. Surface 'but in principle hope that the subsequent scratches are not necessarily external, although the coating has been used to adjust the corresponding body material itself to be exposed to the surface, due to the wear of the table (the same material is still on the surface), and after More V steps can be used in manufacturing (eg, without the addition of a film, it may additionally require a Or other layers (such as adhesives or the like, extensive drying steps (for example for coating), etc.). 'Thus, it is necessary to find further polymer compositions that allow for the manufacture of ... without the need for additional coating Or surface treatment, especially in the important properties of the temple, such as scratch resistance and mechanical properties (such as tensile modulus I split tensile stress 'break tensile strain and financial impact) while having low gloss properties Compositions 8. The need for improved resistance to sputum (especially TPO) with low gloss for use in/flying applications is well known. It is found in the structure of the instrument panel, the console, other interior decorative parts, the silver plate itself and the surface of the door panel. The reason why IJ needs the internal gloss surface of the car for two major reasons. a) Safety 'for example, from the dashboard to the wind Lower reflection on the glass. b) Ten and beautiful windings. Low-gloss surfaces are considered as parts with higher quality and higher value. The main polymer substrate (meaning the substrate of the object) (its low gloss and improved-resistance is still unfulfilled) is such as talc-filled pp copolymer or PP-based TPE The substrate of the (surface layer). Since the composition of these materials can vary widely, it is clear that low gloss and scratch resistance depend on the type and amount of resin, elastomer and talc used, stabilizers, co-additives and pigments, and other fillers. . In addition, processing conditions and surface texture (texture) also play an important role. 143814.doc 201035207 These novel materials are intended for (at the very least, preferably) without the use of any coatings, and can be used for male molds (texturing during surface manufacturing) and negative molds (texturing in molds) Molding process. It has now surprisingly been found that the addition of melamine derivatives, in particular melamine phosphate and/or melamine cyanurate, to these polymer composition cards can substantially maintain or even improve other important properties (eg just mentioned) At the same time, the desired gloss properties are achieved. SUMMARY OF THE INVENTION Thus, in the first aspect, the present invention provides a method of adjusting, in particular, reducing the gloss of a polymeric composition. The low gloss polymeric composition formed in accordance with the present invention is suitable for applications in which the use of a matte surface treatment is advantageous, such as certain automotive (internal) applications. The polymeric compositions formed in accordance with the present invention exhibit improved low gloss characteristics and good or even improved physical properties. In general, a low gloss composition is formed by melt mixing a polypropylene composition with the inventive melamine additive. = Materials such as talc and rock stone and other processing additives may also be included in the composition of::: month. In the field of polymers, other additives may also be present. Poly-eight objects The invention includes, inter alia, a method for adjusting, in particular, reducing (lowering: the gloss of the article (the term article includes a planar product such as a thin gland product) and/or for producing a low gloss polymer' The melamine derivative is refined by melt mixing) to adjust the overall starting polymer mixture, in particular 143814.doc 201035207 to reduce (reduce) the gloss (compared to the same mixture except for the addition of the melamine derivative) and then form The use of an article, or a melamine derivative, as an additive to reduce the gloss of a polymeric article by adding it to a mixture used to form the polymeric article. Preferably, the modified polymer is effective in reducing the amount of gloss in comparison with the lack of the modified polymer (but otherwise identical).

It is also preferred to select the manufacturing conditions for the production of the polymeric article such that the addition of the melamine derivative, especially the amount and the second type of the melamine derivative: in combination with the selected process conditions results in a gloss compared to the absence of the melamine derivative. Items other than the same composition are reduced. The term "adjusting" gloss as used in the specification of the present invention also means that the gloss can be adjusted to a desired value, in other words, the gloss can be increased in principle. In one embodiment of all of the inventive embodiments described herein: the term is specifically used to "reduce" (reduce) gloss. The thermoplastic resin composition according to the present invention can be formed by a known method such as hot press forming, extrusion, treatment of a fibrous substrate, sheet formation, or especially, such as extrusion molding, hollow molding, profile molding, foaming. Molding: injection molding, blow molding, compression molding, rotational molding, and the like to form different articles. The present invention also relates to the use of a melamine derivative as a gloss-attenuating agent for the purpose of periodic application, and thus the addition of the melamine derivative to a mixture for forming a polymer article. In general, each of the embodiments of the invention 1, 2 or more to all of the more general forms within the scope of the invention may be replaced by the above-identified and more detailed I438i4.doc 201035207, to obtain the invention. A more advantageous embodiment. Where the indefinite article "a" is used, it is meant to include "at least one", such as "one or more", and the meaning of "the" is used for a feature that has an indefinite article. . The resulting polymeric composition consistent with the present invention exhibits improved low gloss properties and improved physical properties. In general, a low gloss composition is suitably formed by melt mixing the polymeric substrate (e.g., a polypropylene composition) with an additive included in the present invention. In particular, the invention relates to commercially available flame retardant products melamine cyanurate (MELAPUR MC) and melamine polyphosphate (MELApuR 2®). Such products are useful as described herein and as surface modifiers, particularly as a low gloss additive in PP/TPO polymer compositions and in automotive applications. The 1,3,5-triazine compound melamine can be described in chemical terms as 2,4,6-triamine-1,3,5-triazine. There are many derivatives known, such as melam, melem, diammonium cyanamide, diammonium cyanamide, cyanuric acid, guanamine, 2-ureido melamine, acetamidine. Amine, benzoguanamine, diamine phenyl triazine, and the like. In the most useful melamine derivative of the present invention, melamine cyanurate is preferred, which is generally described as, for example, summarized in the following formula: 143814.doc 201035207 ?rNr° 'N "N 丫NH Ο should Noting that at least 71 of the trimeric face composition of the melamine derivative composition is, for example, at least 1% by weight, at least 20% of the amine, at least 30% by weight, at least 40% by weight, at least 40% by weight, at least 50% by weight, at least 6% by weight, at most 5% by weight, at least 90% by weight, respectively, may have the above-mentioned general formula. To the point of participation in the atom, its simple system. The structure, for example, the melamine derivative of the present invention preferably comprises a simplified form characterized by the following formula:

This formula is only used to illustrate structural features that may be included in the composition without providing a defined structure for the entire composition, particularly to illustrate how the molecules involved may be in a small portion of the invention. Vinegar 143814.doc 201035207 Interaction in the composition. Corresponding compositions are preferably known from CAS Nr: 37640-57-6, in particular by the trade name Ciba MELAPUE® MC (Ciba, Basel, Switzerland). These melamine cyanurates are according to the art (for example Manufactured by known methods, which are described in WO 3/035736 or in particular US Pat. No. 5,2,2,438, each of which is incorporated herein by reference in its entirety in its entirety herein in For the products described therein. Alternatively or additionally, in the most effective melamine derivative of the present invention, a melamine acetonate is mentioned. These can be described briefly as follows:

It includes melamine monophosphate (n = 1), melamine pyrophosphate (η 2) and dimeric decyl phthalic acid vinegar (n = 3 or more). Such compositions are also commonly referred to as melamine polyphosphates. In terms of the elements that function, the typical simple system (c3H6N6).(HP〇3)m, where π and m are independent numbers, especially the integers p, 2, 3, ..). Preferred as melamine (poly) phosphate is known as CAS Nr: 218768-84·4, in particular under the trade name Ciba MELAPUR® 200 (Ciba, 143814.doc 201035207

Basel, Switzerland) indicates the corresponding composition.

Agglomerates, for example as described in WO 03/03 14 17 , ^3,5-triazine building blocks and ammonium structures, which are generally readily available and (especially in the case of compounds of the formula and their manufacture) The manner of reference is incorporated. The composition for forming the article of the present invention preferably comprises from about 2 to about 30% or preferably, for example from about 5 to about 15 and from about 0.2 to 40% by weight of the melamine derivative, to about 25, as described herein. % is better, about 2 to about 18% or even better, and the amount is %. The melamine derivative may have a particle size ranging from about 0.1 to about 100 ^1 〇1.

The average particle size (e.g., by electron microscopy) - the particle size distribution is preferably greater than 50, and more than 75 wt% of the particles are preferably in the range of 50 〇 / 〇 of the average soil). The best number mentioned above refers to the d50 particle size obtained according to or similar to is〇. When "about" is used, it means that the predetermined value after "about" may be slightly changed (often inevitable in technical practice), for example, within ±1〇%, for example, ± 3% of the predetermined value. The reference to "the amount of melamine derivative added to effectively reduce the gloss", especially when compared with a composition which is not added to the melamine derivative and which is otherwise identical except for 143814.doc 201035207, includes one The amount of reduction in the gloss of the resulting article, such as (by the established method in the examples) reduced gloss or more, such as a reduction of 5% or more, such as a reduction of from 1% to 99%. Moreover, the process conditions in the method or use according to the present invention can be modified to reduce the gloss as compared to conditions where the possible gloss loss is reduced. In the parameters, the temperature that can be adjusted, such as the temperature of the transfer, the speed at which the material is moved into the device forming the desired product (for example, the mold used for molding, the extruder, the nozzle, etc.), the temperature of the mold for filling molding (especially in the temperature of the mold which is processed into a solid product), and the temperature at which the temperature of the device is formed. Those skilled in the art can also conveniently design appropriate process conditions based on the evidence of the case towel, by means of tests or a very limited number of tests. For example, in the case of forming an article by molding, the temperature of the mold may be selected from the range of about 20 to about 6 (the range of TC, for example, in the range of (9) to the scratch, and the injection temperature may preferably be selected from 20 〇. The range of (:, for example, in the range of 2 〇〇 to 230 t, and the ejection speed under the equipment conditions given in the examples may preferably be selected from the range of 5 _ / sec to 12 〇 mm / sec. For example, to about 100 mm/sec, at least as a starting point if further testing is required. The base material (polymaterial substrate) of the composition of the low gloss product which can be used in the present invention may be selected from those suitable for melt mixing. Any type of polymerization: mixture of substances. Among the possible polymers, the following examples may be mentioned: polymers containing styrene, such as ABS (acrylic acid dilute-benzene), SBS (stupid ethylene) _ butyl: styrene styrene trisole copolymer), s (styrene-acrylonitrile copolymer), ASA (acrylonitrile acrylate elastomer - stupid ethylene copolymer) is also acrylonitrile styrene. Propionate vinegar), poly _ (eg Yan 143814.doc •12· 201035207 Born in dicarboxylic acid and diol and/or derived Hydroxycarboxylic acid or corresponding lactone such as PBT (poly(butylene terephthalate)), PET (poly(ethylene terephthalate)), poly-1,4-dimethylolcyclohexane Terephthalate, polyhydroxybenzoate, copolyetherester or UPES (unsaturated polyester)), PA (polyamine, such as bamboo derived from monoamine and - tartrate and / or derived from amine rebellion A polyamine of an acid or a corresponding internal brewing amine, such as polyamine 4, polyamine 6, polyamine 6/6, 6/10, 6/9, 6/12, 4/6, 66/6 , 6/66, polyamidamine 11, polyamine 12, partially aromatic (co)polyamine (for example, polyamines based on aromatic diamines and adipic acid), Ο self-extension alkyl diamines and Polyamines prepared from isophthalic acid and/or terephthalic acid and their copolymerized decylamines, copolyether amines, copolyester decylamines, etc.), TPU (amino phthalate-based thermoplastic elastomers) , pS (poly(styrene), HIPS (high impact poly(styrene)), PC (polycarbonate), such as poly (aromatic pyroate) or poly (aliphatic carbonate), for example based on Double-awaiting A and "carbonated" units or other doubles as comonomers And/or dicarbonate units, PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene blend), 〇ABS/PBT (acrylonitrile-butadiene-styrene/poly(terephthalic acid) Butadiene) admixture), PVC (poly(vinyl chloride)); PVC/ABS (poly(ethylene)/acrylonitrile_butadiene_styrene polymer), PVC/ASA (poly(ethylene)) /acrylonitrile-styrene-acrylate), PVC/acrylate (acrylate modified vc) and ionic polymer (ionized (at least partially) and copolymerized product of electrically neutral monomer). In a preferred embodiment, the polymeric substrate is a polyolefin (e.g., high crystalline PP) PC/AB S, ABS, polyamine, such as PA-6 or polystyrene rubber TPE, or, for example, a polymerization as mentioned in detail in one example. Things. -η· 143814.doc 201035207 Examples of polyene smokes: polymers of monoolefins and diolefins (for example, polypropylene, such as high crystalline polypropylene, poly-1-ene, poly-4-mercapto-1- Alkene, polyisoprene or polybutadiene) and cyclic olefins (such as polymers of cyclopentene or norbornene, polyethylene (optionally crosslinked) (eg high density polyethylene (HDPE), high density) And high molecular weight polyethylene (HDPE-HMW), high density and ultra high molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), VLDPE and ULDPE)), or a mixture of two or more of the above polymers (for example, a mixture of polypropylene and polyisobutylene, a mixture with polyethylene (for example, PP/HDPE or PP/LDPE)) or a mixture of different types of polyethylene (eg LDPE/HDPE), copolymers of monoolefins and diolefins with each other or with other vinyl monomers (eg ethylene/propylene copolymers, linear low density polyethylene (LLDPE) and their association with low density polyethylene (LDPE) Mixture, propylene/but-1-ene copolymer, propylene/isobutylene copolymer, ethylene /but-1-ene copolymer, ethylene/hexane copolymer, ethylene/decylpentene copolymer, ethylene/heptene copolymer, ethylene/octene copolymer, propylene/butadiene copolymer, isobutylene/ Isoprene copolymer, ethylene/alkyl acrylate copolymer, ethylene/alkyl methacrylate copolymer, ethylene/vinyl acetate copolymer and copolymers thereof with carbon monoxide, and polymerization of ethylene with propylene and diene , such as hexadiene, dicyclopentadiene or ethylene-formylene; and copolymers of such copolymers with each other or with other polymers mentioned above, such as poly(propylene/ethylene-propylene) , LDPE/ethylene-vinyl acetate copolymer (EVA), LLDPE/EVA, and the like. For example, suitable polyolefins are as described in WO 2006/003127 (Ciba) 143814.doc -14·201035207. Thermoplastic elastomers (TPE) include, for example, rubber modified polyolefins, which are also known as thermoplastic polyolefins (TPO). These are mainly mentioned above as polymers as blends of polyolefins and impact modifiers, such as ethylene-propylene-diene monomer copolymers (EPDM), copolymers of ethylene and higher carbon olefins ( For example, ethylene-octene copolymer), polybutadiene, polyisoprene, styrene-butene-ene copolymer, hydrogenated styrene-butadiene copolymer, styrene-different

A pentene copolymer, a hydrogenated styrene-isoprene copolymer, and the like. These blends are generally referred to as bismuth (thermoplastic polyolefin). For example, suitable hydrazines have from about 10 to about 90% by weight of propylene homopolymer, copolymer or terpolymer ' and from about 90 to about 1% by weight of ethylene sulphur copolymer. body. The cows are stunned and the appropriate tethers are revealed in us 6 〇 48 942 (M〇ntell). The binene and the rubber-modified polyolefin may not be used alone as the agglomerate substrate of the composition of the present invention. However, the copolymer of polyolefin and other polymers or the blend of a polyolefin and other polymers mentioned above is not excluded as a polymer substrate. For the purposes of the present invention, the agent 0 may be added to the polymer composition t, and the polymer composition (polymer substrate) of the present invention may be added thereto, thereby optionally encapsulating to 5% by weight. From about 0.025 to about 2% by weight, and particularly preferably from about (U to about!% by weight of additional different additives (such as the compounds listed below), and optionally adding up to 40%, for example, to 35, 1 to a nucleating agent or filler (such as talc), or a mixture thereof, etc.: 143814.doc 201035207 1 · Antioxidant 1·1. Alkylation of monophenols, such as 2,6-di-t-butyl-4-methyl Phenol, 2-tert-butyl-4,6-di-methylphenol, 2,6-di-t-butyl-4-ethylphenol), 2.6-mono-second butyl-4-n-butyl Benzophenone, 2,6-di-tert-butyl-4-isobutylphenylhydrazine, 2,6-dicyclopentyl-4-4-nonylphenol, 2_(〇c_methylcyclohexyl)_4.6 - dimethyl phenol, 2,6-dioctadecyl-4-nonyl phenol, 2,4,6-tricyclohexyl phenol, 2,6-di-t-butyl-4- methoxy fluorene a phenol, a straight chain or a thiol benzene in the side chain (eg 2,6-di-mercapto-4-mercaptobenzene), 2,4- Methyl-6-(1-methylundecyl)phenol, 2,4-dimethyl "-(b-methylheptadecan-1-yl)phenol, 2,4-dimethyl-6-(1) -Methyltridecane-1-yl) a mixture of two or more of them. 1.2. Alkylthiononylphenols such as 2,4_dioctylthio, yl- 6• Tributylphenol, 2,4-dioctylthioindolyl-6-methylphenol, 2,4-dioctylthiononyl-6-ethylphenol, 2,6-di-dodecanesulfide Methyl 4- 4 -mercaptophenol. 1.3. Hydroquinone and alkylated hydroquinone, such as 2,6-di-t-butyl-4-yloxyphenol, 2,5-di- Tertiary butyl hydroquinone, 2,5-di-third pentyl p-benzoate, 2,6-diphenyl-4-octadecyloxyoxybenzene, 2,6-di- Tributyl hydroquinone, 2,5-di-t-butyl 4-hydroxyphenyl ether, 3,5-di-tert-butyl-4-hydroxyanisole, stearic acid 3,5 -Di-tert-butyl-4-hydroxyphenyl ester, bis-(3,5-di-t-butyl-4-hydroxyphenyl) adipate 1.4. Tocopherol 1.5. Hydroxylated thio-di Phenyl ether 1.6. Alkylene bisphenol, such as 2,2,-fluorenylene bis(6-t-butyl-4-nonylphenol), 2,2'-methylene double (6- Butyl-4-ethylphenol), 2,2,-Aarene 143814.doc -16- 201035207 bis[4-methyl-6-(α-methylcyclohexyl)-phenol], 2,2' -methylenebis(4-methyl-6-cyclohexylphenol), 2,2'-methylenebis(6-fluorenyl-4-methylphenol), 2,2.-methylenebis ( 4,6-di-t-butylphenol), 2,2'-ethylenebis(4,6-di-t-butylphenol), 2,2'-ethylenebis(6-di- Third butyl-4-isobutylphenol), 2,2'-methylenebis[6-fluorenylmethylbenzyl)-4-nonylphenol], 2,2, methylenebis ([ 6-(α,α-dimethylbenzyl)-4-nonylphenol], 4,4·-methylenebis(2,6-di-t-butylphenol), 4,4·- Yttrium bis(6-tert-butyl-2-methylphenol), 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)azetane, 2,6 - bis(3-tert-butyl-5-methyl-2-hydroxyphenylindenyl)-4-methylphenol, 1,1,3-anthracene (5-tert-butyl-4-hydroxy-2- Methylphenyl)butane, anthracene, bis (5-fluorenated dibutyl-4-yl-pyridyl-2-methyl-phenyl)-3-n-dodecyl-propyl butane, ethylene glycol double [3] , 3-bis(3-t-butyl-4-hydroxyphenyl)butyrate], double (3-di-di-butyl-4-transyl-5-methyl-phenyl)dicyclopentadiene, bis[2_(3'-tert-butyl-2-hydroxy-5-methylbenzamide -6-tert-butyl-4-methylphenyl]terephthalate, fluorene-bis-(3,5-didecyl-2-hydroxyphenyl)butane, 2,2- Bis-(3,5-di-t-butyl-4-phenylphenyl)propane, 2,2-bis-(5-t-butyl-4-yl-2-methylphenyl) -4-正十二烧基基基丁院, 1,1,5,5-tetra-(5-t-butyl-4-hydroxy-2-methylphenyl)pentane. The I.7. benzoinyl compound, for example, 3,5,3',5,_tetra-tert-butyl-4,4,-di-base is called a sulfhydryl group. 1. 8. Hydroxybenzylated malonate 1.10· Other triazine compounds, such as 2,4-bis(octylfluorenyl)-6-(3,5-di-t-butyl-4-hydroxyanilino) H5-triazine, 2-octylsulfonyl-4,6-bis(3,5-mono-secondbutylhydroxyanilino)_i,3,5-triazine, 2 octyldecyl·143814.doc 17 201035207 4,6-bis(3,5-di-t-butyl-4-hydroxyphenoxy)-1,3,5-triazine, 2,4,6_ 叁 (3,5-di-third Butyl-4-hydroxyphenoxy)-1,2,3-triazine, (3,5-di-t-butyl-4-yl-based methyl)isocyanate, 1,3,5 _Volume (4_Terbutyl-3-hydroxy-2,6-dimethylbenzyl)isocyanate, 2,4,6-volume (3,5-di-tert-butyl-4-perylene) Ethylethyl)-1,3,5-trimethyl, i,3,5-|(35-di-t-butyl-4-hydroxyphenylpropanyl)-hexahydro-l,3,5-tri Pyrazine, 135_ 叁 (3,5-dicyclohexyl-4-hydroxybenzyl)isocyanate. 1.11. Phenylmethylphosphonate such as dimercapto-2,5-di-t-butyl-4-yl-benzoic methylphosphonate, diethyl-3,5-di-t-butyl 4-Hydroxybenzylphosphonate, dioctadecyl-3,5-di-t-butyl-4-hydroxybenzylphosphonate, dioctadecyl-δ-t-butyl a salt of -to-hydroxymethyl alumhylphosphonate, 3,5 bis-t-butyl-4-transpyridylphosphonic acid monoethyl ester. 1.12. Amidinophenol 1.13. The purpose of β-(3,5-di-t-butyl-4-perphenyl)propionic acid with a monohydric or polyhydric alcohol. 1.14. Esters of β-(5-t-butyl-4-hydroxy-3-indolyl)propionic acid with monohydric or polyhydric alcohols. 1·15· β-(3,5-Dicyclohexyl-4-mercaptophenyl)propionic acid and a monohydric or polyhydric alcohol. 1.16. An ester of 3,5-di-t-butyl-4-hydroxyphenylacetic acid with a monohydric or polyhydric alcohol. 1·17_β-(3,5-Di-t-butyl-4-hydroxyphenyl)propanoic acid decylamine. 1.1 8 · Ascorbic acid (vitamin c). 1.19. Amine Antioxidant, 143814.doc •18· 201035207 2. UV absorber and light stabilizer. 2.1· 2-(2-Hydroxyphenyl)-2H-benzotriazole, for example, commercially known transphenyl-2-H-benzotriazole and disclosed in U.S. Patents 3,004,896, 3,055,896, 3,072,585, 3,074,910, 3,189,615 , 3,218,332, 3,230,194, 4,127,586 >. 4,226,763, 4,275,004, 4,278,589, 4,315,848, 4,347,180, 4,3 83,863, 4,675,352, 4,681,905, 4,853,471, »5,268,450, 5,278,314, 5,280,124, 5,319,091, 〇5,410,071 '5,436,349' 5,516,914 > 5,554,760 5,563,242, Benzotriazoles in 5,574,166, 5,607,987, 5,977,219 and 6,166,218, such as 2-(2-hydroxy-5-methylphenyl)_2H benzotriazole, 2-(3,5-di-t-butyl _2_light phenyl)_2H_benzotriene. Sit, 2_(2_ per group-5-t-butylphenyl)_2H-benzotriene. Sodium, 2-(2-p-phenylphenyl-5-second octylphenyl)-2H-benzotriazole, 5-chloro-2-(3,5-di-t-butyl-2-hydroxybenzene Base-2H-stuppyrazole, 5_gas_2_(3_t-butyl-2-hydroxyl_5_indolyl q-phenyl)-2H_benzotriazole, 2-(3-second Butyl-5-tert-butyl-2-hydroxyl-)-2H-benzodiazole, 2-(2-hydroxy-4-inocyloxyphenyl)_2h_benzotriazole, 2-(3,5 -di-p-pentyl-2-hydroxyphenyl)_2H_benzotriazole, (3,5-bis-α-propylphenyl-2-hydroxyphenyl)-2H-benzotriazole, 2_( 3_Tert-butyl-2-yl-5-(2-(ω-hydroxy-octyl)-(ethoxy)carbonyl-ethyl)-phenyl)-2-pyrene-iso-triazole, 2-( 3-dodecyl-2_hydroxy-5-nonylphenyl)_211_benzotriazole, 2-(3-t-butyl-2-hydroxyl-5_(2-octyloxy)_ Ethyl phenyl benzobisazole, dodecyl esterified 2-(2-hydroxy-5-mercaptophenyl) 2 fluorene-benzotrizane, 2♦ tert-butyl-2 _ base _5_(2 _ octyloxyethyl)benzene 143814.doc 201035207 base)_5-chloro-2H_benzotriazole, 2_(3_t-butyl_5_(2_(2-ethylhexyloxy)-carbonyl) Ethyl)-2-hydroxyphenyl)_5_gas_211_benzotriazole, 2_(3_third 2-hydroxy-5-(2-methoxycarbonylethyl)phenyl)-5-chloro-2H-benzotriazole, 2-(3-secondbutyl-2-hydroxy_5_(2_ Methoxycarbonylethyl)phenyl_2H_benzotrienyl, 2-(3-t-butyl-5-(2.(2-ethylhexyl)methyl)ethyl 2-hydroxyphenyl -2Η-benzotriazole, 2_(3_t-butyl-2-hydroxyl_5_(2-isooctyloxycarbonylethyl)phenyl-2-indole-benzotriazole, 2 2,_Methylene Bis (4_second octyl-(6-2Η-benzotriazol-2-yl)phenol), 2_(2hydroxy_3_〇c_propylphenyl-5-second octylphenyl) -2H-benzotriazole, 2·(2_hydroxy_3_t-octyl-5-α-propylphenylphenyl)-2Η-benzotriazole, 5_fluoro_2_(2_hydroxy_ 3,5_二_^propylphenylphenyl)-2Ηbenzotriazole, 5_gas_2_(2_hydroxy_3,5_:_α_propylphenyl)-2Η-benzotriazole, 5-Chloro-2_(2_hydroxy_3_α_propylphenyl_5_t-octylphenyl)-2Η-benzotriazole, 2_(3_t-butyl-2-hydroxy_5_(2) Octyl-oxycarbonylethyl)phenyl)-5-chloro-2-indole-benzotriazole, 5-trifluoromethyl-2-(2-hydroxy-3-α-propylphenyl-5-th-octyl Phenyl) 2Η_benzotriazole, 5-trifluoromethyl-2_(2-hydroxy-5-trisin Phenyl)_2Η_benzotriazole, 5-trifluoromethyl-2-(2-hydroxy-3,5-di-th-octylphenyl)_211_benzotriazole, fluorenyl 3-(5 -difluoromethyl-2Η-benzotriazole_2_yl)_5_t-butyl-4-hydroperhydride, 5-butylsulfonyl-2-(2_hydroxy-3) Phenyl_5_t-octyl-phenyl)-2Η-stuppyrazole, 5-trifluoromethyl 2 (2-hydroxy-3α-propylphenyl-5-secondoctyl-phenyl) _2Η-benzotriazole, 5-trifluoromethyl_2_(2_hydroxy-3,5-mono-secondbutylphenyl)_2仏benzotriazole, 5-trifluoroindolyl_2_(2_ Hydroxy-3,5-di-α-propylphenyl phenyl 2 Η-benzotriazole, 5-butylsulfonyl-2-(2-hydroxy-3,5-di-t-butylphenyl) _2Η_Benzotriazole and 5-phenylsulfonate 143814.doc -20- 201035207 Mercapto-2-(2-hydroxy-3,5-di-t-butylphenyl)-2-indole-benzotriazole. 2.2. 2-Hydroxybenzophenone, for example 4-hydroxy, 4-decyloxy, 4-octyl, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2 , 4-triionyl and 2-hydroxy-4,4'-dimethoxy derivative. ❹ 〇2·3. Substituted or unsubstituted benzoic acid, such as 4-tert-butyl phenyl salicylic acid sulphate, succinic salicylic acid S, octyl phenyl salicylic acid vinegar, diphenyl Mercaptan resorcinol, bis(4-tert-butylphenylhydrazolyl) resorcinol, phenylindole-based, 2,4-di-t-butylphenyl, 3, 5-di-t-butyl _4_ via basic 曱醢S曰, hexadecane-SS-di-second butyl _4_p-benzophenone octadecyl-3,5-di -T-butyl-4-hydroxybenzoate, 2_fluorenyl-4,6-mono-butylidene-3-3,5-di-t-butyl-3-ylbenzoic acid ester. 2.4. Acrylates and malonic esters such as α-cyano-ρ, ρ-di-p-propyl acrylate or isooctyl ester, α-methoxycarbonyl-cinnamic acid decyl ester, α-cyano-β _ 曱 _ 对 p-methoxy cinnamate decyl or butyl ester, α_曱 oxycarbonyl _ p-methoxy cinnamic acid decyl ester, Ν-(β-曱 oxycarbonyl _β cyanovinyl)_2 曱Benzyl porphyrin, Sanduvor® PR25, dimercapto-p-methoxyphenylidene malonate (CAS# 7443-25-6), and Sanduvor® PR31, methylpiperidine _4_ Benzimidinomalonate (C AS# 147783-69-5). 2.5. Nickel compound 'for example, nickel complex of 2,2,- thio-bis-[4_(1,133-tetramethylbutyl)phenol], nickel dibutyldithiocarbamate, a nickel salt of a monoalkyl ester, a nickel complex of ketone oxime, or a nickel complex of phenyl 4-decadecyl fluorenyl-5-hydroxypyrazole, with or without additional ligands ^ " _ pyridine 2.6 _ steric hindered amine stabilizer, such as 4 _ _ base 2, 2, 6, tetramethyl. Bottom 1 allyl-4-light-based 2,2,6,6-tetramethylanthine, pu-methyl methyl 143814.doc -21 · 201035207 yl-2,2,6,6-tetramethyl Bottom bite, double (2,2,6,6-tetradecyl-4-η|π-decyl) sebacic acid S曰, bis(2,2,6,6-tetradecyl-4-βchen bite Alkyl vinegar, bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, dioctyloxy _ 2.2.6.6-tetramethyl _4_per pipe Pyridyl) sebacate, bis(1,2,2,6,6-pentainyl-4-pyredyl) n-butyl-3,5-di-tert-butyl-4-yl a condensate of methylmalonic acid vinegar, 1-(2-hydroxyethyl)_2,2,6,6-tetramethyl-4-hydroxypiperidine with a succinic acid, 1^,]^,-double ( 2,2,6,6-Tetramethyl-4-piperidinyl) hexamethylene amide - 4- and 3-octylamino 2,6-diox-indole, 3,5-triazine Straight chain or human & clothing-like sigma, bismuth (2,2,6,6-tetramethyl-4-β bottom bite) nitrogen-based triacetin (2,2,6,6- Tetramethyl _4_11 bottom bite) -1,2,3,4-ding Hyun>-four-sauer acid dragon, ~ 1,1 ' ~ (1,2-ethylenediyl)_double (3,3, 5,5_tetramethylpiperazine _ ), 4_ τ τ 职 - 2.2.6.6- tetradecyl 0 bottom bite, 4-stearyl oxy-2,2,6,6-tetradecyl 0 Bottom beer Bis(1,2,2,6,6-pentamethylπ.decyl)-2-n-butyl- 2- (2-carbyl_3 $ _ 5 "" '-1 Benzomethyl)malonic acid 6-, 3-n-octyl-7,7,9,9-tetradecyl) 1,3,8, triazaspiro[4.5]decane-2,4-di Ketone, bis(1-octyloxy-2,2,6,6-tetradecyl) D-didecyl, bis(1-octyloxy-2,2,6,6-tetradecyl) _ „ 定 定 ) ^ ^ ^ ^ 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Linear or cyclic condensate of phenyl 2,6-dichloro-1,3,5-triazine, 2-chloro-4,6-bis(4-n-butylamino-2,2,6 ,6-tetramethylpiperidinyl)_13 5 5 3 condensate of di-n-methyl and 1,2-bis(3-aminopropylamino)ethene, 2_chloro-4,6-n-butyl Condensate of amino-1,2,2,6,6-pentamethylpiperidinyl)_1,3,5-triazine with 1,2, toluene~(3-aminopropylamino)ethene , 8_乙醯-7'7'9'9-tetraf-yl-1'3'8-triazaspiro[4,5]癸2,4_2,12-alkyl-1-( 2,2,6,6-tetramethyl_4_piperidinyl).Byrrolidine_2,5_二纲~ 143814.doc -22- 201035207 Burnt soil (,2,2,6,6-five Methyl _4 -α bottom bite) n 卩 卩 , , _2 _2 , , , _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 _2 Mixture, N,N-bis(2,2,6,6-tetramethyl-4(piperidinyl)hexamethylenediamine and 4-dehexylamino 2,6·monochloro-1,3,5 a condensation product of triazine, 1,2-bis(3-amine-propylpropylamino)ethane and 2,4,6-trichloro-U3,5-triazine and 4-butylamino group. The condensation product of 2,2,6,6-tetramethylpiperidine (CAS Reg N〇[1365〇4 96_ 6]); N-2,2,6,6-tetramethyl-endridinyl)-positive Dodecyl succinimide, N-(l,2,2,6,6-pentamethyl_4_piperidinyl)-n-dodecyl sulphate, hydrazine, 2_11 Base-7,7,9,9-tetramethylacetooxa-3,8-diaza- 4_sideoxy-spiro[4,5] brothel, 7,7,9,9-tetraquinone The reaction product of the base 2·cycloundecyl-1-oxa-3,8-aza-aza-oxyxime, 5]decane with epichlorohydrin, ^^ double (1, 2, 2,6,6-pentamethyl_4-piperidinyloxycarbonylmethoxyphenyl)ethene, N,N'-bis-methylindenyl-N,N,_bis (2,2,6,6 _tetramethyl-4(piperidinyl)hexadecyldiamine, 4-methoxyl-indenyl-malonic acid and pentadecyl-4-hydroxypiperidine Ester, poly[mercaptopropyl_3_oxy_4_(2 2,6,6-tetradecyl_q 4_piperidinyl)]decane, maleic anhydride-α-hydrocarbon copolymer The reaction product of 2,2,6,6-tetramethyl-4-aminopiperidine or iota, 2,2,6,6-pentamethyl-4-aminopiperidine. The steric hindrance amine may also be one of the compounds described in U.S. Patent No. 5,980,783, the entire disclosure of which is hereby incorporated by reference inso a compound of Ie), if), Ig), i_h), ι_0, Ij), Ik) or 1-1), especially a light stabilizer i_a_i, i, which is listed in columns 64 to 72 of U.S. Patent No. 5,980,783. -a_2, 1-b_ 1 , l_c_2, 1-dl, ld-2, ld-3, 1-el, 1-fl, ι_ t43R14.doc -23 - 201035207 g-1, 1 -g-2 or 1 - K-1. The steric hindrance amine may also be described as one of the compounds of U.S. Patent Nos. 6,046, 3, 4 and 6,297, 299, the disclosures of which are incorporated herein by reference, for example, as in the claim 1 or 38 or the examples 1 to 12 or D a compound as described in -1 to D-5. 2.7. A sterically hindered amine substituted with a hydroxy-substituted alkoxy group at the N-atom such as 1-(2-yl-2-methylpropoxy)-4-octadecyloxy _ 2,2 6,6-tetramethylpiperidine, 1-(2-hydroxy-2-mercaptopropoxy)_4_hexadecyloxy-2,2,6,6-tetramethylpiperidine, 1- Reaction product of oxy-4-hydroxy-2,2,6,6-tetramethylpyridinium with a carbon group derived from a third pentanol, 1-(2-hydroxy-2-methylpropoxy)-4- The base-2, 2, 6, 6-four-base brigade. 1,1-(2-Phenyl-2-mercaptopropenyl)-4-yloxy-2,2,6,6-tetradecylpyridine, bis(ι_(2_经基基_2) _Mercaptopropoxy)-2,2,6,6-tetramethylpiperidin-4-yl) sebacate, bis(ι_(2_-yl-2-ylindolyloxy)-2 , 2,6,6 -tetradecyl brigade 4-yl) adipate, biguanide · (2-hydroxy-2-mercaptopropoxy)-2,2,6,6-tetradecyl Piperidine-4-yl) succinate, bis(1-(2-yl-2-methylpropoxy)-2,2,6,6-tetramethylpyr. Acid esters and 2,4-bis{N-[ 1-(2-hydroxy-2-methylpropoxy)_2,2,6,6-tetradecylpiperidin-4-yl]-indole-butyl Amino}-6-(2-hydroxyethylamino)-S-trisin. 2.8. Grassy amine. 2.9. Indole-aryl-hydrazine-hydroxyphenyl-s-triazines, such as the commercially known indole-aryl-hydrazino-p-phenyl-s-triazine, and are described in U.S. Patent Nos. 3,843,371, 4,619,956, 4,740,542. 5,096,489,5,106,891, 5,298,067,5,300,414,5,354,794,5,461,151, 143814.doc -24-201035207 5,476,937, 5,489,503, 5,543,518, 5,556,973, 5,597,854, 5,681,955, 5,726,309, 5,736,597, 5,942,626, 5,959,008, 5,998,116, 6,013,704, 6,060,5 43 , 6,242,598 and 6,25 5,483 triazines, such as 4,6-bis-(2,4-dimethylphenyl)-2-(2-hydroxy-4-octyloxyphenyl)-s- Triazine, Cyasorb® 1164, Cytec Corp, 4,6-bis-(2,4-dimethylphenyl)-2-(2,4-dihydroxyphenyl)-s-triazine, 2,4- Bis(2,4-dihydroxyphenyl)-6-(4-chlorophenyl)-s-triazine, 2,4-bis[2-hydroxy-4-(2-hydroxyethoxy)phenyl] -6-(4-chlorophenyl)-s-triazine, 2,4-bis[2-hydroxy-4-(2-hydroxy-4-(2-hydroxyethoxy)phenyl]-6-( 2,4-Dimethylphenyl)-s-triazine, 2,4-bis[2-hydroxy-4-(2-hydroxyethoxy)phenyl]-6-(4-bromophenyl)- S-triazine, 2,4-double [2-hydroxy-4-(2-ethylantoxyethoxy)phenyl]_6-(4-phenylphenyl)_s_trisole, 2,4-bis(2,4-monophenylene) -6-(2,4-dimethylphenyl)_s_triazine, 2,4-bis(4-biphenyl)-6-(2-hydroxy-4-octyloxycarbonylethyleneoxybenzene Base)_s_triazine, 2_phenyl-4-[2-hydroxy-4-(3-secondbutoxy-2-hydroxypropyloxy)phenyl]_6_ [2-hydroxy-4-(3- Second pentyloxy-2-hydroxypropoxy)phenyl]_s_triazine, 2,4-bis(2,4-dimethylphenyl)-6-[2-hydroxy-4-(3- Phenoxy-2-hydroxypropoxy)phenyl]-s-triazine, 2,4-bis(2-hydroxy-4-n-butoxyphenyl)_6_(2,4-di-n-butoxy Phenyl)-s-triazine, 2,4-bis(2,4-dimethylphenyl)-6-[2-hydroxy-4-(3-decyloxy*-2-hydroxypropoxy) )_5_α_propylphenylphenyl]_s_triazine (* octyloxy, a mixture of decyloxy and decyloxy), fluorenylene bis-{2,4_ bis (2,4-dimercaptobenzene) -6-[2-hydroxy-4-(3-butoxy-2-hydroxypropyloxy)phenyl]-s-triazine}, at 3:5, 5:5, and 3:3 , a position in a ratio of 5:4:1 via a fluorenylene bridged polymer mixture, 2,4,6-volume (2-carbyl-4-isooctyloxy 143814.doc -25-201 035207 Carbonylisopropoxyphenyl)-s-tripa, 2,4-bis(2,4-dimethylphenyl)_6_ (2-hydroxy~4-hexyloxy-5-α-propylbenzene Phenyl)-s-triazine, 2-(2,4,6-trimethylphenyl)-4,6-bis[2-hydroxy-4(3-butoxy-2-hydroxypropoxy) Phenyl]_s_monomethyl, 2,4,6-volume [2-trans- 4-(3-butoxybutylideneoxy)phenyl]-s-triazine, 4 ,6-bis-(2,4-dimercaptophenyl)-2-(2-hydroxy-4-iso-3-hydroxypropoxy)phenyl)s-triazine 4,6_bis-(2,4-dimethylphenyl)-2-(2-propionyl-4-(3-volume-tridecyloxy-2-propyloxy)-phenyl a mixture of -s-diazine, Tinuvin® 400 (Ciba Specialty Chemicals Co., Ltd.), 4,6-bis-(2,4-dimethylphenyl)-2-(2-hydroxy-4-(3) -(2-ethylhexyloxy)_2_ mercaptopropoxy)-phenyl)-s-triazine and 4,6-diphenyl-2-(4-hexyloxy_2_ via basic group)- S - one - beta Qin. 3 · Metal deactivator. 4. Asian acid esters and phosphonates, such as triphenyl phosphite, diphenylalkyl phosphite, phenyl dialkyl phosphite, decyl (decylphenyl) phosphorous acid S 曰, 叁- dodecyl phosphite, decane-octadecyl phosphite, di-stearyl decyl pentaerythritol diphosphite, hydrazine (2,4-di-tert-butylphenyl) sulphite Vinegar, diisodecyl pentaerythritol diphosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite 'bis(2,6-di-t-butyl-4-methyl) Phenyl)-pentaerythritol diphosphite, diisodecyloxy pentaerythritol diphosphite, bis(2,4-di-t-butyl-6-nonylphenyl) pentaerythritol diphosphorus is is, double (2,4,6-volume (second butylphenyl) pentaerythritol diphosphite vinegar, volume hard ruthenium sorbitol di squaric acid g, four (2, bis-tert-butylphenyl) 4,4'-diphenylene diphosphonate, 6-isooctyloxy-2,4,81〇_tetra-t-butyl-dibenzo-[4,3,2] Ethylene cycloheptane, 6_fluoro-2,4,8,1〇_tetra_ 143814.doc 26 - 201035207 tert-butyl-12-mercaptodibenzo[d,g][ 1,3,2 ] Oxyphosphorus, bis(2,4-di-t-butyl-6-nonylphenyl)phosphonium phosphite, bis(2,4-di-t-butyl-6-nonylbenzene) Ethyl phosphite, 2, 2,, 2μ-nitro [triethyl hydrazine (3,3,5,5,-tetra-t-butyl-1,1|, _biphenyl, _2 , 2,_diyl)phosphite], 2-ethylhexyl (3,3,5,5-tetra-t-butyl-i5l,_biphenyl-2,2,-diyl) Phosphate. 5. By amine 6. Nitron. 〇 7. Oxidizing amine 8 · Benzo ketone and 丨β 琳 酿 酿 。 。 。 。 。 。 。 。 。 peroxide emulsifier 11 · Polystyrene stabilizer. 12. Alkaline co-stabilizers, such as melamine, polyvinylpyrrolidone, dicyandiamide, diallyl cyanurate, urea derivatives, hydrazine derivatives, Q 16 And (iv) amines, polyamine phthalic acid S, metal salts and alkaline earth metal salts of higher carbon fatty acids, such as calcium stearate, zinc stearate, magnesium citrate, magnesium stearate, ricinoleic acid Sodium and potassium palmitate 'catechol quinone or catechol zinc. 13. Nucleating agents' such as inorganic substances such as talc, metal oxides (such as magnesium dioxide), Preferred as a phosphonate, carbonate or sulfur salt of an organic earth, an organic compound such as a monohydric or polybasic acid and a salt thereof, such as 4_ butyl benzoic acid 'adipic acid, diphenylacetic acid, horn Sodium or sodium benzoate compound such as ionic copolymer, polymer). Authentic and reinforcing agents, such as carbonic acid dance, oxalate, glass fiber, broken 143814.doc -27- 201035207 glass, asbestos, talc, kaolin, and hydroquinone, black smoke, graphite, or fiber, synthetic fiber . Mica, barium sulfate, metal oxide wood powder and other natural product powders 15. Dispersants, such as polyoxyethylene wax or mineral oil. 16. Other additives such as plasticizers, lubricants, emulsifiers, pigments, dyes, optical brighteners, rheological additives, catalysts, fluid control agents, slip agents, crosslinkers, crosslinking aids, Halogen scavengers, smoke inhibitors, : fire extinguishing agents, antistatic agents, clarifying agents (such as substituted or unsubstituted dimethylene methylene chopped), benzo-oxazinone UV absorbers (such as (3,1 stupid and oxazinone)), Cyasorb® 3638 (CAS # 18600-59-4), and/or a blowing agent. Preferably, the further additive is selected from one or more of the following groups: a hindered amine light (especially, UV) stabilizer, hindered benzene, phosphite sorbate, benzophenone _ stabilizer and Phenyl phenyl benzo K, phenyl phenyl I triazine or diphenyl fluorene ultraviolet absorber, filler or nucleating agent (such as talc and black smoke), and alkaline co-stabilizer (such as stearic acid) Calcium and also (with strong gloss and lower effect) melamine or trimeric urethane, or a mixture of two or more thereof. Of course 'except for the melamine derivative according to the invention In addition, it is also possible to add a non-lighting agent (such as talc), a fluorine containing a polymer, a polymer containing - or a plurality of epoxide groups, a talc, or especially a graft polymer, a deuterated polymer. This is always included in the examples of the invention. Another embodiment of the invention uses one or more of the melamines as defined herein as a scratch-resistant I438I4.doc in the polymer composition product as described herein. -28- 201035207 Improver. In addition to (although better) car In addition to applications, such as panel construction, control 2, other interior trim components 'dashboard itself and door panel surface, and seat: /, handle bedding lining bow chamber assembly or the like, the composition according to the invention is also Used in other potential markets, such as casings, appliances, consumer or electronic devices, outdoor vehicles and devices, or any other component that requires good mechanical strength and favorable optical conditions, such as low gloss, or for belts and Packaging market. 'Electric

[Embodiment] The following examples illustrate the invention without departing from the scope of the invention. In this case, the percentage is defined (%), which means that if it is not clearly expressed in another way, it is expressed by weight % (based on the total polymer composition). The following methods and techniques are used to test and characterize the application properties of the test samples produced. The Zehntner ZGM 1120 匕1〇88 gloss meter (Swiss, Sissach, Zehntner GmbH test instrument) was used to measure the gloss at 6 根据 according to ISO 2813. Or 85. . Scratch resistance was evaluated using a spectrophotometer Spectraflash Sf 6 〇〇 plus (Data C〇l〇r AG, DietHk〇n, Switzerland) by measuring the chromaticity difference). This measurement corresponds to the difference in brightness of the unscratched polymer surface by scratching. These scratches were made using a scratch hardness tester 43 〇p (Germany, Hemer'Erichsen GmbH & Co. KG), which is similar to a 1 mm diameter metal tip (a cylindrical hard metal pen with a spherical end) and Load 10 GME 6〇28〇 at room temperature (according to General M〇t〇rs I438J4.doc -29 - 201035207

Europe Engineering Standard GME 60280 ' No. 2 'Scratch Test, July 2004). Tensile properties were measured according to ISO 527 using a Zwick Z010 universal testing machine (Germany, Ulm, Zwick GmbH & Co. KG) at a punch speed of 100 mm/min. Test at least 5 samples for each calculation formula and average. The tensile modulus [MPa], the tensile stress at break [MPa], and the tensile strain at break [%] were recorded. The flexural properties were measured again according to ISO 178 using a Zwick Z010 universal testing machine. Test at least 5 samples for each calculation formula and average. The flexural modulus [MPa] and the flexural strength [MPa] are reported. Charpy impact energy was measured according to ISO l79/leA using a Zwick S113 rocking impact tester (Zwick GmbH & Co. KG' Ulm, Germany). The skill of the clock is 4 J. The sample was notched with a radius of 〇·25 mm before the impact test. Example 1: Treatment of injection molded plaques using TPO (Borealis Daplen ED 012AE) containing melamine cyanurate (MELAPUR MC) or melamine polywall ester (MELAPUR 200) to estimate their surface properties and mechanical properties, MELAPUR MC Or MELAPUR 200 is incorporated into the TPO injection molding plaque according to the following procedure: Daplen ED012AE (Borealis AG, Vienna, Austria) in powder form with 20% talc (Luzenac A-20; Rio Tinto, Luzenac Europe, Toulouse) , France), 2.5% black smoke masterbatch, 0. 05% calcium stearate, 0.05% IRGANOX B215 (phosphite (叁(2,4-di-(th))butyl-phenyl) Phosphate ester and hindered phenol (tetrakis(methylene-(3,5-di-(th))butyl-4-deuterated cinnamate)) oxane) synergistic antioxidant 143814.doc -30- 201035207 Mixture, Ciba, Basel, Switzerland), 0.2% TINUVIN 791 FB (UV stabilizer blended for high strength and low molecular weight HALS in thickness, Ciba, Basel, Switzerland) and added as shown in Table 1. Mix 5 or 10% melamine cyanurate or melamine polyphosphate. Formulations in a high speed mixer Mixaco Lab CM 12 (Mixaco,

Dr. Herfeld GmbH & Co. KG Maschinenfabrik, Neuenrade, Germany) mixed and placed in a twin screw extruder at 220 ° C for remixing into pellets, for example Berstorff ZE 25x33D 〇 (KraussMaffei Berstorff GmbH, Hannover ,Germany). These pellets were further injection molded into a plaque having a thickness of 2 mm using a standard injection molding machine (e.g., Engel HL60 (Engel Austria GmbH, Schwertberg, Austria)). The treatment temperature is around 240 °C. The resulting surface and mechanical properties are summarized in Table 1. Table 1: Gloss 60. Scratch resistance AL (1〇n) Tensile modulus breaking Tensile stress Tensile strain Charpy impact (MPa) (MPa) (%) (kJ/m2) Blank 14.8 4.0 1017 13.4 17.9 51.9 5% Melapur MC 15 11.1 ______3-7 1040 13.1 14.9 46.3 10% Melapur MC 15 9.7 1072 11.7 9.9 39.6 5% Melapur MC 25 11.6 3.7 1017 ~~ΪΪ9~~ 7.2 44.0 10% Melapur MC 25 10.0 _____4.2 1022 12.3 17.9 33.3 5% Melapur MC 50 11.1 _3.9 970 13.2 13.2 33.0 10% Melapur MC 50 10.0 4.2 1037 11.8 13.0 24.8 5% Melapur 200/70 9,9 _4.4 1046 13.0 33.6 30.4 10% Melapur 200/70 8.5 5-3 1118 13.7 21.1 19.2 5 % Melapur 200 9.8 3.9 981 12.7 26.4 35.2 10% Melapur 200 8.8 5-0 1055 13.0 19.9 22.4 5% Melapur 200 FINE 10.0 4.8 1104 13.3 36.9 45.1 10% Melapur 200 FINE 7.8 4.9 848 ~1Ϊ2~~ 25.0 34.0 5% Melapur 200 FF 11.5 4.8 967 13.8 10.6 22.6 10% Melapur 200 FF 10.1 __4.9 1198 14.0 13.2 12.1 I43814.doc -31 - 201035207 In the case of Melapur 200 FINE, the average particle size is 2_5 μηι. Gloss is reduced by the addition of additives, and the scratch resistance and mechanical properties are consistent. Example 2: Treatment of injection molding plaques with TPO (Borealis Daplen ED 012 AE) containing melamine cyanurate (MELAPUR MC) or melamine polyphosphate (MELAPUR 200) A process condition change as in Example 1. It was prepared as described, but its process conditions during injection molding were changed. The injection temperature, injection speed and mold temperature are different, as follows: Change low standard 13⁄4 Mold temperature 25〇C 40°C 60°C Injection temperature 210°C 240〇C 270〇C Injection speed 10 mm/s 24 mm/s 100 Mm/s Table 2 shows the results when the gloss is 60°: Table 2: Gloss 60. Gloss 6015 Mold temperature Injection temperature Injection rate Standard conditions Low rij South low Low Low Low Low 13⁄4 Low blank 13 30 50 11 24 59 5% Melapur 200 70 15 25 32 9 23 56 10% Melapur 200 70 19 22 53 9 22 57 5% Melapur 200 FINE 14 26 46 10 23 56 10% Melapur 200 FINE 12 23 49 9 21 58 5% Melapur MC 15 15 22 45 10 25 60 10% Melapur MC 15 22 23 47 10 22 54 Table 3 shows Gloss at 85°. 143814.doc -32- 201035207 Table 3: Glossiness 85° Mold temperature Injection temperature Injection rate Standard conditions Low and low two South and South Low Low Low Low South South South South Low South Blank 80 97 98 72 92 98 5% Melapur 200 70 82 94 94 62 93 101 10%Melapur200 70 77 89 91 52 89 100 5% Melapur 200 FINE 72 92 98 64 91 98 10% Melapur 200 FINE 65 87 94 56 87 96 5% Melapur MC 15 81 93 101 66 95 101 10% Melapur MC 15 84 92 98 62 92 97 This shows that suitable conditions for the reduction of gloss of products using melamine derivatives can be found in comparison with the blank group without melamine derivatives. This also shows that it is advantageous to use high quality melamine derivatives. Table 4 shows the case of scratch resistance AL at 10 N: Table 4: Scratch resistance mold temperature △ L (10 N) Injection temperature injection speed Standard conditions Low low Low Low Low Low Low 2.9 4.1 3.2 4.1 4.5 2.8 5 % Melapur 200 70 2.6 4.1 3.0 4.2 4.2 3.1 10% Melapur 200 70 4.6 4.4 3.0 4.5 4.5 2.9 5% Melapur 200 FINE 4.0 3.9 3.3 4.3 4.4 3.7 10% Melapur 200 FINE 4.4 4.4 3.0 4.7 4.7 3.2 5% Melapur MC 15 3.2 3.3 3.0 3.4 3.6 2.6 10% Melapur MC 15 3.2 3.2 3.0 3.7 3.7 2.7 This shows that after the addition of the melamine derivative, at least equivalent and in some cases even superior scratch resistance can be found. Example 3: Treatment of injection molded plaques with TPO (Borea丨is Daplen ED 012 AE) containing melamine polyphosphate (MELAPUR 2〇0) 143oj4.doc 33- 201035207 These formulations were prepared as described in Example 1, However, it incorporates a higher concentration of MELAPUR 200. These results are shown in Table 5: Table 5: Gloss 60° Scratch Resistance AL (10N) Tensile Modulus (MPa) Tensile Tensile Strain (MPa) Flexural Modulus (MPa) Flexural Strength (MPa) Charpy impact (kJ/m2) blank, 20% talc 21 4.7 1798.5 13.2 1648.5 28.9 51·7 2% MELAPUR 200 FINE 18 5.2 1725.6 14.0 1597.0 28.7 47.6 5% MELAPUR 200 FINE 16 5.5 1755.3 13.8 1616.3 28.7 40.3 10% MELAPUR 200 FINE 14 5.5 1812.4 13.1 1732.7 29.0 27.9 15% MELAPUR 200 FINE 20 6.1 1869.2 12.9 1754.2 29.0 14.8 20% MELAPUR 200 FINE 23 6.5 1980.6 12.7 1874.5 29.3 10.0 25% MELAPUR 200 FINE 26 6.6 2073.0 13.2 1965.3 29.4 7·8 30% MELAPUR 200 FINE 25 6.4 2190.3 14.0 2141.5 29.0 6.4 The minimum of 10% of the melamine derivative can be achieved at 60° gloss. Gloss can be increased again by adding a higher concentration of melamine derivative. The total amount of talc and melamine derivatives is preferably in the range of 30%. Example 4: Treatment of injection molded plaques with TPO (Borealis Daplen ED 012 AE) containing melamine polyphosphate (MELAPUR 200) without the addition of talc. These formulations were prepared as described in Example 3, but were formulated therein. No talc is used in the material. Table 6 shows the experimental results: -34- 143814.doc 201035207 Table 6: Gloss 60° Resistance ΔL (10N) Tensile modulus (MPa) Tensile strain at break (MPa) Flexural modulus (MPa) Scratch Flexural strength (MPa) Charpy impact (kJ/m2) Blank, no talc 30 0.5 593.6 12.8 691.8 22.4 56.3 2% MELAPUR 200 FINE 28 1.1 804.9 12.4 741.8 22.8 58.1 5% MELAPUR 200 FINE 26 2.1 875.3 12.0 785.8 23.4 59.5 10% MELAPUR 200 FINE 20 3.1 940.9 11.6 865.4 24.3 60.9 15% MELAPUR 200 FINE 19 3.7 1012.6 11.3 890.8 23.8 55.7 20% MELAPUR 200 FINE 16 4.2 1090.1 11:1 962.0 24.6 46.0 25% MELAPUR 200 FINE 14 4.6 1176.2 10.6 1051.8 25.2 33.7 30% MELAPUR 200 FINE 23 5.9 1278.3 10.0 1147.0 25.8 16.0

This is shown in the absence of talc and can be significantly extinct by the addition of melamine derivatives. The minimum of the 25% range of melamine derivatives can be achieved in 60° gloss. The gloss is increased again by adding a higher concentration of the melamine derivative. These results correspond adequately to the results in Table 5, with the minimum being preferably in the range of 30% (the total amount of talc and melamine derivatives). Example 5: Containing melamine polyphosphate (MELAPUR 200) and scratch resistance

SPO Additives IRGOSURF SR 100 TPO (Borealis Daplen ED 012AE) Treatment of Injection Molding Plasters These formulations were prepared as described in Example 1. In addition, 2.5% of the scratch-resistant additive IRGASURF SR 100 (Switzerland, Basel, Ciba) was added to these formulations. The experimental results are shown in Table 7. -35 - 201035207 Table 7: 60. Glossiness Scratch Resistance △L(10N) Tensile Modulus (MPa) Tensile Tensile Strain (MPa) Flexural Modulus (MPa) Flexural Strength (MPa) Charpy Impact (kJ/m2) Blank, 20% Talc 21 4.7 1798.5 13.2 1648.5 28.9 51.7 5% MELAPUR 200 FINE 2.5% IRGASURF SR 100 19 0.5 1664.1 11.8 1452.4 26.9 43.4 10% MELAPUR 200 FINE 2.5% IRGASURF SR 100 15 1.4 1685.4 12.0 1471.8 26.7 35.1 15% MELAPUR 200 FINE 2.5% IRGASURF SR 100 21 2.2 1746.4 12.2 1500.5 26.8 24.8 This display provides additional improvement in scratch resistance by the addition of scratch-resistant additives. Example 6: Treatment of injection molded plaques with HCPP (Sabic PP CX02-81) The formulations were prepared as described in Example 4, but using high crystalline PP, Sabic PP CX02-81 (polypropylene copolymer plastic, SABIC Deutschland GmbH & Co. KG, Dtisseldorf, Germany) replaces Borealis Daplen ED 012AE. The results are shown in Table 8. Table 8: 60° gloss 85° gloss scratch resistance AL (10N) blank, no talc 57 100 0.6 5% Melapur MC 15 52 99 0.7 10% Melapur MC 15 44 94 0.7 5% Melapur MC 25 52 97 0.3 10 % Melapur MC 25 42 92 0.8 5% Melapur MC 50 54 94 0.5 10% Melapur MC 50 42 92 0.6 5% Melapur 200 70 49 95 0.8 10% Melapur 200 70 40 89 0.9 5% Melapur 200 43 91 0.9 10% Melapur 200 38 90 0.9 5% MELAPUR 200 FINE 49 94 0.7 10% MELAPUR 200 FINE 37 93 1.0 5% Melapur 200 FF 49 93 0.6 10% Melapur 200 FF 41 89 0.9 143814.doc -36- 201035207 Example 7: Using PC/ABS ( Dow Pulse A35-105) Treatment of Injection Molding Plasters These formulations were prepared as described in Example 4, but using Bobalis instead of PC/ABS, Dow Pulse A35-105 (Dow Automotive, Auburn Hills, Michigan, USA) Daplen ED 012 AE. The test results are shown in Table 9. Table 9: 60. Glossiness 85° Gloss resistance ΔL (10N) Flexural modulus (MPa) Flexural strength (MPa) Charpy impact (kJ/m2) Tensile modulus (MPa) Tensile tensile stress (MPa) Blank 51 90 0.3 2206 71.7 38 2258 44 5% Melapur MC 15 26 54 0.0 2361 72.7 11.6 2398 41 10%Melapur MC15 18 38 0.1 2592 72.6 5.9 2547 41 5% Melapur MC 25 25 51 0.0 2727 72.6 10.3 2396 41 10% Melapur MC 25 18 36 0.1 2892 72.7 5.9 2561 41 5% Melapur MC 50 23 51 0.1 2399 72.6 10.3 2398 41 10% Melapur MC 50 18 38 0.1 2565 72.6 5.6 2533 41 5% Melapur 200 70 14 39 -0.2 2512 0 2.5 2363 43 10 % Melapur 200 70 11 31 •0.2 2519 0 1.3 2520 29 5% Melapur 200 12 36 -0.1 2384 0 1.5 2430 39 10% Melapur 200 10 27 -0.0 2547 0 0 2513 22 5% Melapur 200 FINE 14 3S -0.7 2326 0 1.4 2392 40 10% Melapur 200 FINE 10 28 0.3 2503 0 0 2528 28 5% Melapur 200 FF 13 36 -0.6 2330 0 1.7 2365 39 10% Melapur 200 FF 11 29 •0.2 2537 0 0.7 2416 30

Example 8: Treatment of injection molded plaques with ABS (Dow Magnum 35 〇 4) The formulations were prepared as described in Example 4, but using ABS, Dow Magnum 3504 (Dow Automotive, Auburn Hi 11s, Michigan, USA) ) Replaces Borealis Daplen ED 012AE. The results are shown in Table 10. -37 - 143814.doc 201035207 Table ίο : 60° Gloss 85° Gloss Scratch Resistance AL ( ION ) Blank 17 85 0.1 5% MelapurMC 15 16 63 -0.4 10% Melapur MC 15 14 51 -0.1 5% Melapur MC 25 16 62 -0.4 10% Melapur MC 25 14 59 0.1 5% Melapur MC 50 17 72 0.1 10% Melapur MC 50 15 63 0.3 5% Melapur 200 70 15 72 0.6 10% Melapur 200 70 15 63 0.2 5% Melapur 200 16 73 0.4 10% Melapur 200 13 65 0.8 5% Melapur 200 FINE 14 73 0.8 10% Melapur 200 FINE 13 68 0.8 5% Melapur 200 FF 16 72 0.7 10% Melapur 200 FF 13 63 0.9 Example 9: Using TPE (Kraiburg STP 9363 /33 B102 Treatment of Injection Molding Plasters These formulations were prepared as described in Example 4, but using TPE, Kraiburg STP 9363/33 B 102 (Waldkraiburg, Germany,

Kraiburg TPE GmbH & Co. KG) replaces Borealis Daplen ED 012AE (a thermoplastic elastomer). The results are shown in Table 11. Table 11: 20° gloss 60° gloss scratch resistance AL (ION) blank 48 78 -0.7 5% MELAPUR 200 FINE 22 57 -0.4 10% MELAPUR 200 FINE 16 49 -0.3 143814.doc •38- 201035207 Example 10 : Treatment of fibers with PA-6 (Ultramid BS 700) Formulation of Polyamido-6 (Ultramid BS 700 from BASF SE, Ludwigshafen, Germany) in a high speed mixer Mixaco Lab CM 12 (Mixaco, Dr. Herfeld GmbH & Co. KG Maschinenfabrik, Neuenrade, Germany) mixed and placed in a twin screw extruder (Haake-Poly-Lab extruder from Thermo Fisher Scientific inc., KaHsruhe, Germany) at a temperature of 240 °C . The strip of polymer is then granulated. The obtained pellets were dried overnight in a vacuum dry box at a temperature of 80 °C. The pellets were then processed via a fiber extruder Spinboy II (Deerlijk, Belgium, Busschaert Engineering) to know Denier 10.0 fibers. The gloss values of the fibers are then determined by winding the fibers around the mirror. The results are shown in Table 12. Table 12: 20° gloss 60. Gloss blank 12 50 — ______ 12% MELAPUR MC 15 1 9 _______ 20%MELAPURMC 15 0 6 12% MELAPUR MC 5 1 8 ---- 20% MELAPUR MC 5 1 7__ — In summary, melamine derivatives can be derived from the examples An effective alternative to the system to reduce many different types of polymers and in different forms such as fibers, articles of a certain thickness, and the like. 141814 doc -39-

Claims (1)

201035207 · VII. Scope of application: The gloss of the whole polymer object and / or the method or process for manufacturing a low-light material object, including the melamine derivative starting polymer to reduce (10) degrees Then, a / dimethyl melamine derivative is formed in the melt mixing. The method is added as in the method of claim 1. 3. A method according to claim 1 or 2, wherein a mixture of melamine cyanurate derivatives according to any one of claims 1 to 3. G 'where the adjustment means lowering the gloss. The method of the present invention, wherein the melamine derivative, the dimeric decyl urate or the melamine is ❹, as in the case of any of the first eve of the term 1 to 4, the β y term, wherein § melamine derivative The system is present in an amount of from 2 to 4% by weight of the total polymer mixture. 6. The method of any one of claims 1 to 5 wherein the polymer substrate of the polymer mixture is selected from the group consisting of styrene-containing polymers, polyesters, polyamines, amine-based Thioester-based thermoplastic elastomer, poly(styrene), high impact poly(styrene), polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, acrylonitrile- Butadiene-styrene/poly(butylene terephthalate) blend, poly(vinyl chloride), poly(ethylene ethylene V acrylonitrile-butadiene styrene polymer, poly(vinyl chloride)/ Acrylonitrile-stupid ethylene-acrylic acid ester, acrylate-modified poly(vinyl chloride)' ionic polymer, polyolefin and polyolefin rubber or TPE, or one of these polymers or more The method of claim 6, wherein the polymer substrate is selected from the group consisting of the following composition I43814.doc 201035207: acryl guess-butadiene-styrene polymer, styrene_ding Styrene triblock copolymer, styrene-acrylonitrile copolymer, acryl guess acrylate elastomer-styrene copolymer, (butylene terephthalate), poly(ethylene terephthalate), poly-1,4-dihydroxydecyl cyclohexane terephthalate, polyhydroxybenzoate, copolymerization Ether ester, polyamidamine 4, polyamidamine 6, polyamido 6/6, polyamido 6/1 0, polyamine 6/9, polyamine 6/12, polyamine 4/6, poly Indole 66/6, polyamine 6/66, polyamine 11, polyamide 12, polyamine based on aromatic diamine and adipic acid, self-extended diamine and isophthalic acid and/or Or polydecylamine prepared by p-benzoic acid and its copolymerized decylamine, copolyether decylamine, copolyester decylamine, urethane-based thermoplastic elastomer, poly(styrene), high impact resistance (stupid ethylene), polycarbonate, polycarbonate/acrylonitrile butadiene-styrene blend based on bisphenol A and "carbonated" units or other bisphenol and/or dicarbonate units as comonomers, Acrylonitrile-butadiene-styrene/poly(butylene terephthalate) blend, poly(ethylene); poly(ethylene)/acrylonitrile-butadiene-styrene polymer, poly (gas ethylene) / acrylonitrile _ styrene acrylic acid 6 An acid ester-modified PVC and an ionic polymer, or a mixture of two or more of the polymer substrates. The method of claim 6, wherein the polymer substrate is a polyolefin, PC/ ABS, ABS, polyamide (such as pA_6), or polyolefin rubber or TPE. 9. The method of claim 8, wherein the polyolefin monoolefin and the polymer of the diene (for example, polypropylene, such as high Crystalline polypropylene, poly-butene-ene, poly-1,4-indolyl-1-ene, polyisoprene or polybutadiene), cyclic olefin 143814.doc 201035207 (eg cyclopentene or raw borneol thin) Polymer, cross-linked poly &, (i) ★ 冋 male polyethylene, high density and high molecular weight polyethylene, high male and ultra high molecular weight polyethylene, medium density polyethylene, low density polyethylene Linear low-density polyethylene, VLDPE and ULDPE), or a mixture of the above two or more polymers (for example, a mixture of polypropylene and polyisobutylene, with polyethylene or a different type of polyethylene), monoolefin , work and monoolefin phase 1 or with other vinyl monomers #polymer (such as ethylene / 'h line Low-density polyethylene ruthenium and its ruthenium mixture with low-density polyethylene, propylene/butadiene copolymer, propylene/isobutylene copolymer, ethylene/butadiene-dilute copolymer, ethylene/hexane copolymer, ethylene/methyl Ethylene co-hydrate, ethylene/heptene copolymer, ethylene/octene copolymer, propylene/butadiene', 1 isobutylene/isoprene copolymer, ethylene/acrylic acid vinegar copolymer, ethylene/ Alkyl methacrylate copolymer, ethylene/acetic acid, ethylene oxime copolymer and copolymers thereof with carbon monoxide, and ethylene with propylene and diene (such as hexadiene, dicyclopentadiene or ethylene-origin a copolymer of borneol); and mixtures of such copolymers with each other or with other polymers mentioned above. The method of claim 8, wherein the thermoplastic elastomer comprises a rubber-modified polyolefin which is substantially the blend of the polymer as a polyolefin and the impact modifier as mentioned in claim 9 And materials, such as ethylene-propylene-diene monomer copolymer, copolymer of ethylene and higher carbon olefin, polybutylene, polyisoprene, styrene-butadiene copolymer, hydrogenated benzene Ethylene-butadiene copolymer, styrene-isoprene copolymer, hydrogenated styrene-isoprene copolymer, TPO preferably has from about 1 Torr to about 90% by weight of U3814doc 201035207 propylene homopolymer, A copolymer or terpolymer, and from about 9 angstroms to about 1% by weight of an elastomeric copolymer of ethylene and a C3 to Cs-a-olefin. The method of any one of claims 1 to 10, wherein one or more other additives are additionally added to the polymer composition, the additives being selected from the group consisting of antioxidants, uv absorbers, light Stabilizer, metal deactivator, phosphate ester, phosphonate, hydroxylamine, nitrone, amine oxide, benzofuranone, porphyrinone, thiosynergizer, peroxide scavenger, polyamine stabilizer , Detective co-ampere (four), nucleating agent, dispersing agent, plasticizing agent (7) agent, emulsifier, pigment, dye, optical brightener, rheological additive, catalyst, flow control, slip agent, delivery A combination of a crosslinking agent, a crosslinking agent, an A-acid scavenger, a smoke suppressant, a fire retardant, an antistatic agent, a clarifying agent, and a foaming agent, wherein the total amount of the additive other than the nucleating agent in the composition is all The polymer composition may be from about 5% to about 5% by weight and the amount of nucleating agent may be up to 4% by weight. 12. The method of any one of claims 1 to 12, wherein the process conditions of the production and the amount and/or type of the melamine derivative are selected to combine to result in the same or other melamine derivative as the other components. The object's object has a reduced gloss compared to the object. 13. The method of claim 12, wherein the process conditions include: melting temperature, moving the material into a device for forming and removing the object, and filling is used for the mold. The mold of the plastic, the field, the fruit, the temperature of the forming device and the temperature of the solid product. 143814.doc 201035207 The substance is added to the toluene for forming the polymer such as the object, and it is preferably used in any one of the two items 1 to 3, -, and preferably added and lacking The poly-amino street bio-combination composition can effectively reduce the amount of gloss of the melamine street organism 'or use a melamine derivative as a gloss reducing agent' thereby adding the melamine derivative to form a polymerization Object: in a mixture. 15· — by object such as the request item. The polymer produced by the method of any one of 13 1M5MA rW ▲ *-β V 丨· V· 201035207 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If the case has a chemical formula' Please reveal the chemical formula that best shows the characteristics of the invention: (none) 143814.doc