TW579381B - Thermoplastic elastomer, hot-melt composition, process for preparing a thermoplastic vulcanizate and composite articles thereof - Google Patents
Thermoplastic elastomer, hot-melt composition, process for preparing a thermoplastic vulcanizate and composite articles thereof Download PDFInfo
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- TW579381B TW579381B TW088118575A TW88118575A TW579381B TW 579381 B TW579381 B TW 579381B TW 088118575 A TW088118575 A TW 088118575A TW 88118575 A TW88118575 A TW 88118575A TW 579381 B TW579381 B TW 579381B
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- parts
- functionalized
- polyolefin
- rubber
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- 229920006342 thermoplastic vulcanizate Polymers 0.000 title claims abstract description 59
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims description 24
- 239000012943 hotmelt Substances 0.000 title claims description 4
- 239000002131 composite material Substances 0.000 title claims 11
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 claims abstract description 81
- 239000000835 fiber Substances 0.000 claims abstract description 55
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 229920006112 polar polymer Polymers 0.000 claims abstract description 17
- 229920000728 polyester Polymers 0.000 claims abstract description 8
- 239000004952 Polyamide Substances 0.000 claims abstract 4
- 229920002647 polyamide Polymers 0.000 claims abstract 4
- 229920001971 elastomer Polymers 0.000 claims description 71
- 239000005060 rubber Substances 0.000 claims description 71
- 229920000642 polymer Polymers 0.000 claims description 35
- 239000004743 Polypropylene Substances 0.000 claims description 32
- 229920001155 polypropylene Polymers 0.000 claims description 32
- 229920002098 polyfluorene Polymers 0.000 claims description 29
- 229930195733 hydrocarbon Natural products 0.000 claims description 27
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 125000000524 functional group Chemical group 0.000 claims description 23
- -1 Butylene dianhydride Chemical compound 0.000 claims description 21
- 239000004215 Carbon black (E152) Substances 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 19
- 229920001281 polyalkylene Polymers 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 18
- 229920002943 EPDM rubber Polymers 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 229920001169 thermoplastic Polymers 0.000 claims description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims description 12
- 150000001993 dienes Chemical class 0.000 claims description 11
- 150000005673 monoalkenes Chemical class 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 229920001400 block copolymer Polymers 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 8
- 229920006126 semicrystalline polymer Polymers 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 239000000779 smoke Substances 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 239000004745 nonwoven fabric Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 239000002759 woven fabric Substances 0.000 claims description 2
- 240000008866 Ziziphus nummularia Species 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 150000002220 fluorenes Chemical class 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 abstract description 7
- 150000002739 metals Chemical class 0.000 abstract description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 7
- 239000003054 catalyst Substances 0.000 description 25
- 238000004132 cross linking Methods 0.000 description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 17
- 229920003317 Fusabond® Polymers 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 239000004753 textile Substances 0.000 description 14
- 238000006459 hydrosilylation reaction Methods 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 238000001723 curing Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229920005549 butyl rubber Polymers 0.000 description 9
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 9
- 229920002292 Nylon 6 Polymers 0.000 description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 230000003993 interaction Effects 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 235000019260 propionic acid Nutrition 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920003313 Bynel® Polymers 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical class [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 229910052990 silicon hydride Inorganic materials 0.000 description 3
- HLWRUJAIJJEZDL-UHFFFAOYSA-M sodium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O HLWRUJAIJJEZDL-UHFFFAOYSA-M 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
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- 238000007306 functionalization reaction Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 238000010128 melt processing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
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- 239000002994 raw material Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
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- 239000003381 stabilizer Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 239000004636 vulcanized rubber Substances 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 description 1
- JBAUPCNQUQGXJT-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene;2-methylprop-1-ene Chemical compound CC(C)=C.CC1=CC=C(C=C)C=C1 JBAUPCNQUQGXJT-UHFFFAOYSA-N 0.000 description 1
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- CBNJXLNJDLIQTD-UHFFFAOYSA-N C(C)C=1C(=C(C=CC1)C1=CC=CC=2C3=CC=CC=C3CC12)CC Chemical compound C(C)C=1C(=C(C=CC1)C1=CC=CC=2C3=CC=CC=C3CC12)CC CBNJXLNJDLIQTD-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
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- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
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- 241000208125 Nicotiana Species 0.000 description 1
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- 239000005864 Sulphur Substances 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
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- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
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- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
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- 125000004122 cyclic group Chemical group 0.000 description 1
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- CIISBNCSMVCNIP-UHFFFAOYSA-N cyclopentane-1,2-dione Chemical compound O=C1CCCC1=O CIISBNCSMVCNIP-UHFFFAOYSA-N 0.000 description 1
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- 239000012188 paraffin wax Substances 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
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- 239000000049 pigment Substances 0.000 description 1
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- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
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- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
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- 239000001294 propane Substances 0.000 description 1
- ZDWVWKDAWBGPDN-UHFFFAOYSA-O propidium Chemical compound C12=CC(N)=CC=C2C2=CC=C(N)C=C2[N+](CCC[N+](C)(CC)CC)=C1C1=CC=CC=C1 ZDWVWKDAWBGPDN-UHFFFAOYSA-O 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
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- FBEIPJNQGITEBL-UHFFFAOYSA-J tetrachloroplatinum Chemical compound Cl[Pt](Cl)(Cl)Cl FBEIPJNQGITEBL-UHFFFAOYSA-J 0.000 description 1
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Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C08L23/10—Homopolymers or copolymers of propene
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- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
- Y10T428/31587—Hydrocarbon polymer [polyethylene, polybutadiene, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
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Landscapes
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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| US09/218,002 US6503984B2 (en) | 1998-12-22 | 1998-12-22 | TPE composition that exhibits excellent adhesion to textile fibers |
Publications (1)
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| TW579381B true TW579381B (en) | 2004-03-11 |
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| TW088118575A TW579381B (en) | 1998-12-22 | 1999-10-27 | Thermoplastic elastomer, hot-melt composition, process for preparing a thermoplastic vulcanizate and composite articles thereof |
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| AU2002217934A1 (en) * | 2000-11-30 | 2002-06-11 | Polymer Group, Inc. | High temperature polyester film extrusion |
| US6872784B2 (en) | 2000-12-29 | 2005-03-29 | Kimberly-Clark Worldwide, Inc. | Modified rubber-based adhesives |
| US6657009B2 (en) * | 2000-12-29 | 2003-12-02 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive having improved bonding strength |
| US20020123538A1 (en) * | 2000-12-29 | 2002-09-05 | Peiguang Zhou | Hot-melt adhesive based on blend of amorphous and crystalline polymers for multilayer bonding |
| US6774069B2 (en) * | 2000-12-29 | 2004-08-10 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive for non-woven elastic composite bonding |
| ATE423806T1 (de) | 2001-06-08 | 2009-03-15 | Exxonmobil Chem Patents Inc | Nanoverbundwerkstoffe mit geringer permeabilität |
| WO2002100936A1 (en) | 2001-06-13 | 2002-12-19 | Exxonmobil Chemical Patents Inc. | Low permeability nanocomposites |
| FR2829141B1 (fr) * | 2001-09-03 | 2006-12-15 | Nexans | Procede de fabrication d'un corps cylindrique et cable comportant un corps obtenu par ce procede |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| JP2005535748A (ja) | 2002-08-12 | 2005-11-24 | エクソンモービル・ケミカル・パテンツ・インク | 可塑性ポリオレフィン組成物 |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US20040137191A1 (en) * | 2003-01-15 | 2004-07-15 | Beren James R. | Recyclable extrusion-coated carpet having improved fiber lock |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| JP4726788B2 (ja) * | 2003-08-29 | 2011-07-20 | アドバンスド エラストマー システムズ，エル．ピー． | 成形冷却液ホースの製造方法 |
| US7955710B2 (en) | 2003-12-22 | 2011-06-07 | Kimberly-Clark Worldwide, Inc. | Ultrasonic bonding of dissimilar materials |
| US20050133145A1 (en) * | 2003-12-22 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Laminated absorbent product with ultrasonic bond |
| US20050136224A1 (en) * | 2003-12-22 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Ultrasonic bonding and embossing of an absorbent product |
| US7557162B2 (en) * | 2004-01-08 | 2009-07-07 | Teknor Apex Company | Toughened polymer compositions |
| US7041741B2 (en) * | 2004-01-08 | 2006-05-09 | Teknor Apex Company | Toughened polymer compositions |
| US7645829B2 (en) | 2004-04-15 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
| US7365131B2 (en) * | 2004-04-28 | 2008-04-29 | The Goodyear Tire & Rubber Company | Thermoplastic vulcanizate composition |
| US7671130B2 (en) * | 2004-12-16 | 2010-03-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomers having improved adhesive properties |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| WO2006102106A1 (en) * | 2005-03-17 | 2006-09-28 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
| US7445846B2 (en) * | 2005-04-01 | 2008-11-04 | Advanced Elastomer Systems, L.P. | Thermoplastic vulcanizates and laminates made therewith |
| JP4991710B2 (ja) * | 2005-06-24 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | 可塑化した官能性プロピレンコポリマー接着組成物 |
| US7909194B2 (en) * | 2005-07-01 | 2011-03-22 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and sealing devices made therewith |
| US8513347B2 (en) | 2005-07-15 | 2013-08-20 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| JP5468258B2 (ja) * | 2005-08-17 | 2014-04-09 | ボスティック・インコーポレーテッド | ホットメルトシーラントおよび発泡体代替ガスケット材料 |
| US8168718B2 (en) * | 2005-12-09 | 2012-05-01 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate adhesive compositions |
| US7645832B2 (en) * | 2006-03-08 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Use of metal oxides and salts to enhance adhesion to steels |
| US8071220B2 (en) | 2006-07-21 | 2011-12-06 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates having improved adhesion to polar substrates |
| US7687575B2 (en) * | 2006-08-03 | 2010-03-30 | Equistar Chemicals, Lp | Propylene elastomer-containing adhesive blends |
| US7790809B2 (en) * | 2006-08-28 | 2010-09-07 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates with advantageous adhesion to polar substrates |
| US8056584B2 (en) * | 2006-09-25 | 2011-11-15 | Veyance Technologies, Inc. | Kink, crush, and burst resistant flexible hose construction |
| US8557393B2 (en) | 2006-10-31 | 2013-10-15 | Exxonmobil Chemical Patents Inc. | Adhesive thermoplastic vulcanizates |
| US7951871B2 (en) * | 2006-11-10 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Curing rubber by hydrosilation |
| EP2094537B1 (en) * | 2006-12-06 | 2013-02-27 | Dow Corning Corporation | Airbag and process for its assembly |
| US8575275B2 (en) * | 2007-09-11 | 2013-11-05 | Dow Global Technologies Llc | Compositions and articles prepared therefrom |
| US10023776B2 (en) * | 2007-12-21 | 2018-07-17 | Saint-Gobain Performance Plastics Corporation | Preparation of a self-bonding thermoplastic elastomer using an in situ adhesion promoter |
| WO2009143090A2 (en) * | 2008-05-22 | 2009-11-26 | Dow Corning Corporation | Process and composition for fabricating non-sewn seams |
| US8247494B2 (en) * | 2009-11-23 | 2012-08-21 | Exxonmobil Chemical Patents Inc. | Thermoset compositions with dispersed thermoplastic resin therein and process for making them |
| WO2015003752A1 (en) * | 2013-07-12 | 2015-01-15 | Datwyler Pharma Packaging Belgium Nv | A part consisting of a material and a method of manufacturing such part and a method of radiation sterilisation of such part |
| EP3079906A1 (en) | 2013-12-12 | 2016-10-19 | Firestone Building Products Co., LLC | Highly loaded thermoplastic membranes with improved mechanical properties |
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| KR101575458B1 (ko) | 2014-03-07 | 2015-12-07 | 현대자동차주식회사 | 압출성형용 폴리올레핀-천연섬유 복합재 조성물 |
| PL3134590T3 (pl) | 2014-04-25 | 2022-08-16 | Firestone Building Products Company, Llc | Przywierający system pokrycia dachowego z termoplastyczną membraną pokrycia dachowego |
| EP3172270B1 (en) | 2014-07-23 | 2022-06-15 | Firestone Building Products Company, LLC | Thermoplastic roofing membranes for fully-adhered roofing systems |
| DE102014214858B4 (de) * | 2014-07-29 | 2017-05-18 | Mehler Engineered Products Gmbh | Verwendung einer Haftmischung |
| US11242684B2 (en) | 2015-02-06 | 2022-02-08 | Firestone Building Products Company, Llc | Thermoplastic roofing membranes for fully-adhered roofing systems |
| EP3397478A1 (en) | 2015-12-31 | 2018-11-07 | Firestone Building Products Co., LLC | Polyolefin thermoplastic roofing membranes with improved burn resistivity |
| US10121342B2 (en) * | 2016-12-07 | 2018-11-06 | Tyco Fire & Security Gmbh | Security tag with stain prevention pads |
| DE112016007517A5 (de) * | 2016-12-13 | 2019-09-19 | Actega Ds Gmbh | Thermoplastische Vulkanisate |
| WO2019199486A1 (en) | 2018-04-10 | 2019-10-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizale compositions |
| WO2020033462A1 (en) | 2018-08-08 | 2020-02-13 | Firestone Building Products Company, Llc | Thermoplastic roofing membranes adapted for adhesion to polar adhesives |
| CN112512794A (zh) | 2018-08-10 | 2021-03-16 | 三井化学株式会社 | 复合结构体及电子设备用壳体 |
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| CN115322455B (zh) * | 2022-09-02 | 2023-09-15 | 湖北工业大学 | 一种改性涤纶短纤维复合天然橡胶减振材料及其制备方法 |
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| US4130535A (en) | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
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| US4957968A (en) * | 1988-08-09 | 1990-09-18 | Monsanto Company | Adhesive thermoplastic elastomer blends |
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-
1998
- 1998-12-22 US US09/218,002 patent/US6503984B2/en not_active Expired - Lifetime
-
1999
- 1999-10-22 MX MXPA01006403A patent/MXPA01006403A/es unknown
- 1999-10-22 CA CA002356249A patent/CA2356249A1/en not_active Abandoned
- 1999-10-22 KR KR1020017007866A patent/KR20010099873A/ko not_active Ceased
- 1999-10-22 PL PL99350330A patent/PL350330A1/xx not_active Application Discontinuation
- 1999-10-22 AU AU11300/00A patent/AU757959B2/en not_active Ceased
- 1999-10-22 JP JP2000589617A patent/JP2002533510A/ja active Pending
- 1999-10-22 CN CN99814946A patent/CN1331724A/zh active Pending
- 1999-10-22 BR BR9916405-1A patent/BR9916405A/pt not_active IP Right Cessation
- 1999-10-22 DE DE69937690T patent/DE69937690T2/de not_active Expired - Lifetime
- 1999-10-22 AT AT99955123T patent/ATE380218T1/de not_active IP Right Cessation
- 1999-10-22 EP EP99955123A patent/EP1144502B1/en not_active Expired - Lifetime
- 1999-10-22 IL IL14384599A patent/IL143845A0/xx unknown
- 1999-10-22 CZ CZ20012311A patent/CZ20012311A3/cs unknown
- 1999-10-22 WO PCT/US1999/024725 patent/WO2000037553A1/en not_active Ceased
- 1999-10-27 TW TW088118575A patent/TW579381B/zh not_active IP Right Cessation
- 1999-12-20 MY MYPI99005595A patent/MY133756A/en unknown
-
2002
- 2002-11-05 US US10/287,845 patent/US6776997B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| IL143845A0 (en) | 2002-04-21 |
| CA2356249A1 (en) | 2000-06-29 |
| PL350330A1 (en) | 2002-12-02 |
| DE69937690T2 (de) | 2008-10-30 |
| WO2000037553A1 (en) | 2000-06-29 |
| EP1144502A4 (en) | 2002-08-21 |
| AU757959B2 (en) | 2003-03-13 |
| CN1331724A (zh) | 2002-01-16 |
| AU1130000A (en) | 2000-07-12 |
| BR9916405A (pt) | 2001-09-04 |
| US20030119988A1 (en) | 2003-06-26 |
| US6503984B2 (en) | 2003-01-07 |
| JP2002533510A (ja) | 2002-10-08 |
| KR20010099873A (ko) | 2001-11-09 |
| MY133756A (en) | 2007-11-30 |
| EP1144502A1 (en) | 2001-10-17 |
| US20020010265A1 (en) | 2002-01-24 |
| MXPA01006403A (es) | 2002-06-04 |
| US6776997B2 (en) | 2004-08-17 |
| CZ20012311A3 (cs) | 2001-11-14 |
| ATE380218T1 (de) | 2007-12-15 |
| DE69937690D1 (de) | 2008-01-17 |
| EP1144502B1 (en) | 2007-12-05 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |