TW555798B - Methods and compositions for protecting polymers from UV light - Google Patents
Methods and compositions for protecting polymers from UV light Download PDFInfo
- Publication number
- TW555798B TW555798B TW088105206A TW88105206A TW555798B TW 555798 B TW555798 B TW 555798B TW 088105206 A TW088105206 A TW 088105206A TW 88105206 A TW88105206 A TW 88105206A TW 555798 B TW555798 B TW 555798B
- Authority
- TW
- Taiwan
- Prior art keywords
- article
- polymeric
- bis
- item
- patent application
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract description 21
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title description 10
- 239000006096 absorbing agent Substances 0.000 abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- -1 pentamethyl-4-hexahydropyridyl Chemical group 0.000 description 24
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 229930182556 Polyacetal Natural products 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 125000001188 haloalkyl group Chemical group 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000002466 imines Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920001470 polyketone Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- KLZYRCVPDWTZLH-UHFFFAOYSA-N 2,3-dimethylsuccinic acid Chemical compound OC(=O)C(C)C(C)C(O)=O KLZYRCVPDWTZLH-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- YXOLAZRVSSWPPT-UHFFFAOYSA-N Morin Chemical compound OC1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 YXOLAZRVSSWPPT-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- GOAJGXULHASQGJ-UHFFFAOYSA-N ethene;prop-2-enenitrile Chemical compound C=C.C=CC#N GOAJGXULHASQGJ-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000004658 ketimines Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000012701 michael addition polymerization Methods 0.000 description 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 description 1
- 235000007708 morin Nutrition 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- IGEIPFLJVCPEKU-UHFFFAOYSA-N pentan-2-amine Chemical compound CCCC(C)N IGEIPFLJVCPEKU-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920002098 polyfluorene Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- GUYXXEXGKVKXAW-UHFFFAOYSA-N prop-2-enenitrile Chemical compound C=CC#N.C=CC#N GUYXXEXGKVKXAW-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- BHZOKUMUHVTPBX-UHFFFAOYSA-M sodium acetic acid acetate Chemical compound [Na+].CC(O)=O.CC([O-])=O BHZOKUMUHVTPBX-UHFFFAOYSA-M 0.000 description 1
- JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 229960000281 trometamol Drugs 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Organic Insulating Materials (AREA)
Description
555798 A8 B8 C8 D8 六、申請專利範園 咯啶基，或環己胺，X與X1 (其可相同或不同）為氫， Ci-C20烷基’或式（Π)基圓：
其中R,表示氫，（VC3羥烷基，烷基，羥基，或 烴氧基；R2表示氫’ Ci-Cg烷基，或苄基；R3與R4 (其 可相同或不同）為CrCs烷基，苄基.，或苯乙基，或可 形成Cs-Ca環烷基；Z為直鏈或分支鍵c2-C2〇伸烷基， 或經一或多個氧基、硫基、或 基團，其中R5為氫，CkCzo烷基，或式（11)基團阻斷之 直鏈或分支鏈Cz-Czo伸烷基；Cs-C丨〇伸環烧基，
本纸張尺度適用中國國家標準(CNS) A4規格(210X 297公釐) 555798
8 8 8 8 A B c D 申請專利範園
-·或
C6-C12伸芳基，或C8-C丨4伸芳烧基；η為大於1之整 數；且Υ為鹵原子，CrC8烷基胺，二（CrC8)烷基胺， 叶匕洛咬基，嗎淋代，環己胺，或 X1
X —N —Z —N — Η 其中X、X1及Ζ係如前述定義；其限制條件為X與 X1當中之一或二者均係式（II)基團。 6.根據申請專利範圍第5項之組合物，其中X與X1可相 同或不同，且係為式（II)基團，其中R.為嗎啉代或辛基 C57863CZ201405C.doc 本纸張尺度適用中國國家標準(CNS) A4規格(210X 297公釐） 555798 A8 68 C8 D8 六、申請專利範圍
胺，R1為Η或CH3，R2為Η，R3與R4為CH3，Z為 C0H丨2，且Y為嗎η林代，辛基胺，或 X X1
I I —Ν — Ζ — Ν ——Η 其中Χ’Χ1，及Ζ如前述定義。 根據申請專利範圍第1項之組合物，其中該HALS係 選自下列所組成之群組： (1) 雙（1-辛氧基-2,2,6,6-四曱基-4-六..氫吡啶基）癸二酸 酯； (2) 具有4-羥基-2,2,6,6-四曱基-1-六氫吡啶乙醇之琥王白 酸二甲酯聚合物； (3) 具有4-經基-2,2,6,6-四曱基-1-六氫p比咬乙醇之琥珀 酸二甲酯聚合物與具有2,4,6-三氯-1，3,5-三'•井及 2,4,4-三乙基-1，2-戊胺之Ν,Ν1-雙（2,2,6,6-四曱基-4- 六氫吡啶基）-1,6-己二胺之聚合物之摻合物； ⑷ 1，3,5-三畊-2,4,6-三胺，N，N"，[1，2-乙二基雙[[[(4,6_. 雙[丁基（1，2,2,6,6-五曱基-4-六氫p比咬基）胺基]_ 13,5-三 _ -2-基]亞胺基]-3.，1-丙二基]]-雙[n_，n·'-二 丁基-N’，N"-雙（1，2,2,6,6-五曱基·4-六氫吨咬基.）， 1，3,5-三畊-2,4,6-三胺，Ν，Ν，，，[1，2-乙二基雙[[[(4,6_ 雙[丁基（1-環己氧基-2,2,6,6-四甲基-4-六氫ρ比咬基） CS7863CZ20l40SC.doc 本紙張尺度適用中國國家標準(CNS) Α4規格(210X 297公釐) 装 訂 線 555.798 A8 B8 C8 D8 六 申請專利範圍 胺基]-1，3,5-三喷-2-基]亞胺基]-3,1-丙二基]]-雙 [N、N"-二丁基 _Νι，Ν"_ 雙（1，2,2,6,6·五甲基-4-六氫吡 啶基），1，3,5-三畊-2,4,6-三胺，Ν，：ΝΤ[ 1，2-乙二基雙 [[[(4,6-雙[丁基（1，2,2,6,6-五曱基-4-六氫吡啶基）胺 基]-2-基]亞胺基]_3，1-丙二基]]-雙[Ν，，Ν，，-二丁基-Ν'，Ν"-雙（l，2,2,6,6-五曱基-4-六氫吡啶基）； (5) 具有2,4,6-三氣-1，3,5-三畊與2,4,4-三甲基-1,2-五胺 之Ν，Ν'-雙（2,2,6,6-四曱基-4-六氫吡啶基）-1，6-己二 胺聚合物； (6) 聚-曱基丙基-3·氧基_(4( 2,2,6,6-四曱基）六氫吡啶 基）矽氧烷； (7) 聚-甲基丙基-3-氧基（4(1，2,2,6,6-五曱基）六氫吡啶 基）矽氧烷； (8) 四甲基-7-噚-3,20-重氮-21-嗣基-二螺（5,1，11，12)正廿 一烷與環氧氣丙烷反應之聚烷基-1-哼-重氮螺癸烷 產物；及 (9) 具有 2,4,6-三氣-l，3,5-三畊之 1，3-丙二胺，Ν，Ν"-1，2-乙二基雙-聚合物與Ν- 丁基-2,2,6,6-四甲基-4-六氫吡 啶胺之反應產物。 根據申請專利範圍第1項之組合物，其中該三畊光吸 收劑係具式（III): 本纸張尺度適用中國国家標準(CNS) Α4規格(210X297公«) 555798 A8 B8 C8 D8 中請專利範園
中A’B及C各為芳香族化合物，一或多個A、B 及C係經與該三畊環連接之鄰位羥基取代，且R1至 R9各係為選自氫，羥基，烷基，烷氧基，磺基’羧 基’鹵素，鹵烷基及醯胺基。 9·根據申請專利範圍第8項之組合物.，其中該三畊光吸 .· · 收劑係具式（IV):
線 其中Rio，R_n，R12及可相同或不同，且個別選自 氫，羥基’烷基，烷氧基，磺基，羧基’鹵素’鹵烷 基及醯胺基，而R14為氫或Cl至Cl8烷基。 1〇_根據申請專利範圍第9項之組合物，其中，R" » R 2及R13為Η或CH3，且R14為氫，C6H13，或 C8H17。 II.根據申請專利範圍第8項之組合物，其中該三B井光吸 收劑係選自 CS7863CZ20M0SC.doc 本纸張尺度適用中國國家標準(CNS) A4規格(210X297公爱) 555798 A8 B8 C8 D8 申請專利範園 2-(4,6-二苯基-1，3,5-三p井-2-基）-5-(己基）氧基-盼， 2-(4-((2-羥基-3-十二烷氧基丙基）-氧基-2-羥笨基 4.6- 雙（2,4-二甲基苯基）-1，3,5-三岍， 2- ( 4- (( 2-經基-3-十三炫氧基丙基）-氧基-2-經笨基） 4.6- 雙（2,4-二甲基苯基）-1,3,5-三哨·，及 2- ( 4- ( ( 2-羥基-3-異辛氧基丙基）-氧基-2-羥苯基）_4,6_ 雙（2,4-二曱基苯基）-1,3,5-三畊。 12.根據申請專利範圍第2項之組合物，其中铱聚合物質 係選自聚烯烴，聚醋，聚醚，聚酮，聚醯胺，天然咬 合成橡膠，聚胺基甲酸酯，聚苯乙烯，耐衝擊聚笨乙 烯，聚丙烯酸酯，聚甲基丙烯酸酯，聚縮醛，聚丙歸 腈，聚丁二烯，聚苯乙烯，ABS (丙烯腈丁二歸笨乙 烯），SAN (苯乙烯丙烯腈），ASA (丙烯酸苯乙綿丙缔 腈），纖維素醋酸丁酸酯，纖維素聚合物，聚醞亞胺， 聚醯胺酿亞胺，聚醚醯亞胺，聚苯基硫醚，PP〇 (對聚 苯氧），聚颯，聚醚颯，聚氣乙烯，聚碳酸酯，聚_ , 脂肪族聚酮，熱塑性TPU (熱塑性聚胺基曱酸乙錯. 合物’經胺基樹脂交聯之聚丙烯酸酯或聚酯，經聚異 氰酸酯交聯之聚酯或聚丙烯酸醋，酚/甲醛，尿素/甲酸 或蜜胺/甲醛樹脂，乾燥或非乾燥酸醇樹脂，酸醇樹 月旨，聚酯樹脂’經蜜胺樹脂交聯之丙烯酸樹脂，尿素 樹脂’異氰酸酯樹脂，異氰尿酸酯，胺基甲酸輯.，或 CS7863C220l40SC.(ioc 本紙張尺度適用中國國家標準(CNS) A4規格(210X 297公爱) 裝 訂 線
環氧樹脂，衍生自脂肪族，環脂肪族，雜環或芳香族 縮水甘油化合物之交聯環氧樹脂（其經酸酐或胺交 聯），聚矽氧烷，麥可（Michael)加成聚合物，胺，具有 活化不飽和與亞曱基化合物之嵌段胺，具有活化不飽 和與亞甲基化合物之酮亞胺，與不飽和丙烯酸聚乙醯 乙酸酯樹脂組合之聚酮亞胺，輻射可固化組合物，環 氧蜜胺樹脂’有機染料，化粧品產物，以纖維素為主 之紙調配物，照像軟片紙，油墨，及其摻合物。 13. 根據申請專利範圍第2項之組合物，其中該聚合物質 為聚稀烴均聚物，共聚物，或三聚物。 14. 根據申請專利範圍第13項之組合物，其中該聚合物質 為聚乙烯或聚丙烯之均聚物，共聚物，或三聚物。 15. 根據申5月專利範圍第1 4項之組合物，其中該聚乙烯或 聚丙稀係在一或多種齊.格勒-納他（Ziegler_Natta)觸媒存 在下進行聚合反應之產物。 16. 根據申請專利範圍第14項之組合物，其令該聚乙烯或 聚丙烯係在一或多種單部位觸媒存在下進行聚合反應 之產物。 17. 根據申請專利範圍第14項之奴合物，其中該聚乙稀或 聚丙稀係在齊格勒-納他觸媒及一或多種單部位觸媒皆 存在下進行琅合反應之產物。 吸根據申請專利範圍第2項之組合物，其中該聚合.物質 -8 - C57S63C2201405C,doc 本纸張尺度通用中國国家標準(CNS) A4規格(21〇X 297公釐) 555798
A BCD 螫 六、申請專利範圍 係選自聚醯胺，聚酯，聚縮醛，及聚胺基曱酸酯。' 19. 根據申請專利範圍第18項之組合物，其中該HALS 與三畊光吸收劑之重量比為自5:1至10:1。 20. 根據申請專利範圍第1 8項之組合物，其中該HALS與 三p井光吸收劑之重量比為自6:1至7.5:1。 裝 訂 線 C57S63CZ20l405Cdoc 本纸張尺度適用中國國家標準(CNS) A4規格(210X297公釐)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/070,627 US6051164A (en) | 1998-04-30 | 1998-04-30 | Methods and compositions for protecting polymers from UV light |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW555798B true TW555798B (en) | 2003-10-01 |
Family
ID=22096447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW088105206A TW555798B (en) | 1998-04-30 | 1999-04-01 | Methods and compositions for protecting polymers from UV light |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6051164A (zh) |
| EP (2) | EP1080147B2 (zh) |
| JP (2) | JP2002513832A (zh) |
| KR (1) | KR100608439B1 (zh) |
| CN (1) | CN1154685C (zh) |
| AT (1) | ATE282061T1 (zh) |
| AU (1) | AU740494B2 (zh) |
| BR (1) | BR9910062B1 (zh) |
| CA (1) | CA2330422C (zh) |
| DE (1) | DE69921806T3 (zh) |
| ES (2) | ES2233030T5 (zh) |
| IL (2) | IL139348A0 (zh) |
| NO (1) | NO319839B1 (zh) |
| PT (2) | PT1500675E (zh) |
| RU (1) | RU2222560C2 (zh) |
| TW (1) | TW555798B (zh) |
| WO (1) | WO1999057189A1 (zh) |
| ZA (1) | ZA993008B (zh) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69931792T2 (de) * | 1999-12-01 | 2007-05-16 | Chi Mei Optoelectronics Corp. | UV absorbierender Film und Verwendung als Schutzfolie |
| US6468609B2 (en) | 1999-12-01 | 2002-10-22 | Agfa-Gevaert | UV-absorbing film and its use as protective sheet |
| CO5231248A1 (es) * | 2000-07-26 | 2002-12-27 | Ciba Sc Holding Ag | Articulos transparentes de polimero de baja consistencia |
| US6777470B2 (en) * | 2001-05-29 | 2004-08-17 | Sunoco, Inc. (R&M) | Polyolefin additive packages for producing articles with enhanced stain resistance |
| US7297409B2 (en) | 2001-10-12 | 2007-11-20 | Sabic Innovative Plastics Ip Bv | Multilayer, weatherable compositions and method of manufacture thereof |
| EP1302309B2 (en) * | 2001-10-12 | 2016-09-07 | SABIC Innovative Plastics IP B.V. | Multi-layer, weatherable compositions and method of manufacture thereof |
| US6630527B2 (en) | 2001-10-19 | 2003-10-07 | General Electric Company | UV stabilized, impact modified polyester/polycarbonate blends, articles, and methods of manufacture thereof |
| US7090926B2 (en) * | 2001-11-09 | 2006-08-15 | General Electric Company | Multi-layer, weatherable compositions and method of manufacture thereof |
| WO2003054083A1 (de) * | 2001-12-20 | 2003-07-03 | Ami - Agrolinz Melamine International Gmbh | Additiv zur inhibierung von photolytischen abbaureaktionen in aminoplasten |
| AT411452B (de) * | 2001-12-20 | 2004-01-26 | Agrolinz Melamin Gmbh | Uv-resistenter, thermohärtbarer aminoplastverbund, dessen herstellung und verwendung |
| DE10233848A1 (de) * | 2002-07-22 | 2004-02-19 | Agrolinz Melamin Gmbh | Additiv zur Inhibierung von photolytischen Abbaureaktionen in Aminoplasten |
| US7482397B2 (en) * | 2003-01-13 | 2009-01-27 | Eastman Chemical Company | Polycarbonate compositions |
| US20040143041A1 (en) * | 2003-01-13 | 2004-07-22 | Pearson Jason Clay | Polyester compositions |
| US7297735B2 (en) * | 2003-03-05 | 2007-11-20 | Eastman Chemical Company | Polycarbonate compositions |
| US7070683B2 (en) * | 2003-02-13 | 2006-07-04 | Ppg Industries Ohio, Inc. | Electrodepositable coating compositions and processes related thereto |
| US20040183053A1 (en) * | 2003-03-20 | 2004-09-23 | Pearson Jason Clay | Process for the preparation of a hindered amine light stabilizer salt |
| US20050277713A1 (en) * | 2003-03-05 | 2005-12-15 | Pearson Jason C | Polymer blends |
| BRPI0407952A (pt) * | 2003-03-05 | 2006-03-07 | Eastman Chem Co | composição polimérica |
| US20040192813A1 (en) * | 2003-03-20 | 2004-09-30 | Pearson Jason Clay | Polymer compositions containing an ultraviolet light absorbing compound |
| US20040180994A1 (en) * | 2003-03-05 | 2004-09-16 | Pearson Jason Clay | Polyolefin compositions |
| US7338992B2 (en) * | 2003-03-05 | 2008-03-04 | Eastman Chemical Company | Polyolefin compositions |
| ATE390460T1 (de) * | 2003-03-05 | 2008-04-15 | Eastman Chem Co | Polymerblends |
| EP1338622A3 (en) * | 2003-03-14 | 2003-09-10 | Ciba SC Holding AG | Stabilizer mixtures |
| CN1875061A (zh) * | 2003-11-04 | 2006-12-06 | Cytec技术有限公司 | 紫外稳定添加剂组合物 |
| US20070161741A1 (en) * | 2003-12-09 | 2007-07-12 | Mitsui Chemicals, Inc. | Resin composition for reflector plate and reflector plate |
| US7582690B2 (en) * | 2004-11-19 | 2009-09-01 | Eastman Chemical Company | Stabilized aliphatic polyester compositions |
| ATE478915T1 (de) * | 2005-04-07 | 2010-09-15 | Cytec Tech Corp | Zusammensetzungen und verfahren zur verhinderung des lichtzerfalls zyklischer olefin-copolymere |
| ITMI20052067A1 (it) * | 2005-10-28 | 2007-04-29 | 3V Sigma Spa | Composizione per la stabilizzazione di polimeri sintetici |
| US20070174972A1 (en) * | 2005-11-14 | 2007-08-02 | Invista North America S.A R.I. | Spandex having enhanced whiteness, and fabrics and garments comprising the same |
| RU2424256C2 (ru) * | 2006-08-04 | 2011-07-20 | Плейтекс Продактс, Инк. | Изделия с хорошей смазываемостью, аппликатор тампона, ствол и плунжер аппликатора тампона |
| US20080306188A1 (en) * | 2007-06-06 | 2008-12-11 | Impact Composite Technology, Ltd. | Novel UV inhibitors and stabilizers, derived from a biomass feedstock source, for thermoplastic and thermosetting resins |
| CN102292397B (zh) | 2009-01-19 | 2014-12-10 | 巴斯夫欧洲公司 | 有机黑色颜料及其制备 |
| JP5556395B2 (ja) * | 2009-08-28 | 2014-07-23 | Ｊｓｒ株式会社 | 液晶配向剤、液晶配向膜、液晶表示素子 |
| GB0915687D0 (en) | 2009-09-08 | 2009-10-07 | Dupont Teijin Films Us Ltd | Polyester films |
| EP2569378B1 (en) * | 2010-05-14 | 2014-10-01 | FUJIFILM Imaging Colorants Limited | Printing process, polymer and ink |
| KR20130100954A (ko) * | 2010-06-14 | 2013-09-12 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 장기간 옥외 노출 저항성 폴리에스테르 복합 구조체 및 그의 제조 방법 |
| JP2012134445A (ja) * | 2010-12-01 | 2012-07-12 | Fujifilm Corp | 保護フィルム |
| JP2012116113A (ja) * | 2010-12-01 | 2012-06-21 | Fujifilm Corp | 保護フィルム |
| KR102025299B1 (ko) * | 2010-12-13 | 2019-09-25 | 사이텍 테크놀러지 코포레이션 | 가공 첨가제 및 회전 성형에서의 이의 용도 |
| US11267951B2 (en) | 2010-12-13 | 2022-03-08 | Cytec Technology Corp. | Stabilizer compositions containing substituted chroman compounds and methods of use |
| GB2488787A (en) * | 2011-03-07 | 2012-09-12 | Dupont Teijin Films Us Ltd | Stabilised polyester films |
| JP6010108B2 (ja) * | 2011-04-01 | 2016-10-19 | スリーエム イノベイティブ プロパティズ カンパニー | トリアジン系紫外線吸収剤を含むフィルム |
| TWI454604B (zh) * | 2011-12-27 | 2014-10-01 | Ind Tech Res Inst | 分散性染料組成物、聚酯纖維材料的染色方法以及染色後的聚酯纖維材料 |
| EP2647664A1 (en) * | 2012-04-04 | 2013-10-09 | Cytec Technology Corp. | Method for stabilizing polyolefin films against UV degradation |
| GB201310837D0 (en) | 2013-06-18 | 2013-07-31 | Dupont Teijin Films Us Ltd | Polyester film -IV |
| CN103289296A (zh) * | 2013-06-21 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | 高耐候性阻燃abs复合材料 |
| GB201317551D0 (en) | 2013-10-03 | 2013-11-20 | Dupont Teijin Films Us Ltd | Co-extruded polyester films |
| EP3137540A1 (en) * | 2014-05-01 | 2017-03-08 | Cytec Industries Inc. | Stabilizing compositions for stabilizing materials against ultraviolet light and thermal degradation |
| MY182679A (en) | 2014-06-24 | 2021-01-29 | Dow Global Technologies Llc | Polyolefin photovoltaic backsheet comprising a stabilized polypropylene layer |
| KR101630161B1 (ko) * | 2014-07-25 | 2016-06-14 | 한국화학연구원 | 열안정성이 우수한 탄성 폴리우레탄의 중합 방법 및 이로부터 제조된 탄성 폴리우레탄 중합체 |
| CA2968381C (en) | 2014-11-20 | 2023-10-17 | Cytec Industries Inc. | Stabilizer compositions and methods for using same for protecting polymeric organic materials from uv light and thermal degradation |
| CN106589514B (zh) * | 2015-10-20 | 2020-03-24 | 天罡新材料（廊坊）股份有限公司 | 一种光稳定剂组合物母粒及其制备方法和应用 |
| EP3470465A4 (en) * | 2016-06-09 | 2020-04-15 | Adeka Corporation | RESIN COMPOSITION |
| US20200002493A1 (en) * | 2017-02-24 | 2020-01-02 | Solvay Specialty Polymers Usa, Llc | Uv-stabilizer solution for treating the surface layer of a polymer article |
| WO2018155396A1 (ja) | 2017-02-27 | 2018-08-30 | 東ソー株式会社 | 熱可塑性ポリウレタン樹脂組成物、および該樹脂組成物を用いた成形体 |
| JP7110606B2 (ja) | 2017-02-27 | 2022-08-02 | 東ソー株式会社 | 熱可塑性ポリウレタン樹脂組成物、および該樹脂組成物を用いた成形体 |
| MX2019011625A (es) | 2017-03-28 | 2019-12-05 | Basf Se | Mezcla fotoestabilizante. |
| CN110709455A (zh) * | 2017-06-26 | 2020-01-17 | Sabic环球技术有限责任公司 | Uv和热稳定的阻燃玻璃填充的聚合物组合物和由其制成的增强制品 |
| JP7169109B2 (ja) * | 2017-08-02 | 2022-11-10 | 花王株式会社 | ポリマーエマルション |
| EP3578599A1 (en) | 2018-06-08 | 2019-12-11 | Cytec Industries Inc. | Granular stabilizer compositions for use in polymer resins and methods of making same |
| KR102602854B1 (ko) * | 2018-06-05 | 2023-11-16 | 주식회사 동진쎄미켐 | 폴리이미드 조성물 및 이를 이용하여 제조한 자외선 안정성이 우수한 폴리이미드 필름 |
| CN111253655A (zh) * | 2019-12-23 | 2020-06-09 | 浙江瑞堂塑料科技股份有限公司 | 一种高耐候聚乙烯复合材料及其制备方法 |
| CN111690257A (zh) * | 2020-07-02 | 2020-09-22 | 中国地质大学（北京） | 耐紫外辐照无色透明聚酰亚胺薄膜及其制备方法和应用 |
| US20220411646A1 (en) | 2021-06-29 | 2022-12-29 | Cytec Industries Inc. | Compositions and methods for protecting coatings from the deleterious effects of exposure to uv-c light |
| AU2022429675A1 (en) | 2022-01-01 | 2024-07-04 | Cytec Industries Inc. | Polymer compositions having densification accelerators and rotational molding processes for making hollow articles therefrom |
| WO2024083872A1 (en) | 2022-10-18 | 2024-04-25 | Cytec Industries Inc. | Synergistic stabilizer compositions and methods for using same for protecting organic materials from uv light and thermal degradation |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL302933A (zh) * | 1963-01-24 | |||
| US4331586A (en) * | 1981-07-20 | 1982-05-25 | American Cyanamid Company | Novel light stabilizers for polymers |
| JPS58113236A (ja) * | 1981-12-28 | 1983-07-06 | Tounen Sekiyu Kagaku Kk | ポリオレフイン組成物 |
| JPS61113649A (ja) * | 1984-11-07 | 1986-05-31 | Adeka Argus Chem Co Ltd | 耐光性の改善された高分子材料組成物 |
| US4619956A (en) * | 1985-05-03 | 1986-10-28 | American Cyanamid Co. | Stabilization of high solids coatings with synergistic combinations |
| US4929653A (en) * | 1987-07-13 | 1990-05-29 | The Bf Goodrich Company | Stabilized pigmented polypropylene fiber resistant to gas fade |
| SG49847A1 (en) * | 1989-12-05 | 1999-07-20 | Ciba Sc Holding Ag | Stabilized organic material |
| US5786477A (en) * | 1989-12-26 | 1998-07-28 | Cytec Technology Corp. | Stabilization of high solids coatings with liquid compositions of triazine UV absorbers |
| CN1040006C (zh) † | 1990-03-23 | 1998-09-30 | 中国科学院长春应用化学研究所 | 耐候性聚乙烯薄膜的制备方法 |
| DE59107052D1 (de) * | 1990-03-30 | 1996-01-25 | Ciba Geigy Ag | Lackzusammensetzungen |
| DK0483488T3 (da) * | 1990-10-29 | 1997-04-01 | Cytec Tech Corp | Synergistiske ultravioletabsorberende sammensætninger indeholdende hydroxyaryltriaziner og tetraalkylpiperidiner |
| US5190710A (en) * | 1991-02-22 | 1993-03-02 | The B. F. Goodrich Company | Method for imparting improved discoloration resistance to articles |
| US5200443A (en) * | 1991-03-29 | 1993-04-06 | Kimberly-Clark Corporation | Radiation stabilized fabric having improved odor characteristics containing an hindered amine compound |
| US5244947A (en) * | 1991-12-31 | 1993-09-14 | Kimberly-Clark Corporation | Stabilization of polyolefin nonwoven webs against actinic radiation |
| ATE175731T1 (de) * | 1994-09-30 | 1999-01-15 | Ciba Geigy Ag | Stabilisierung von pigmentierten fasern mit einer synergistischen mischung von uv-absorber und gehindertem amin |
| TW401437B (en) † | 1995-02-10 | 2000-08-11 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
| GB9515048D0 (en) | 1995-07-22 | 1995-09-20 | Ciba Geigy Ag | Sunscreen compositions |
| CH692739A5 (de) * | 1996-03-26 | 2002-10-15 | Ciba Sc Holding Ag | Polymerzusammensetzungen enthaltend 2-Hydroxyphenyl-1,3,5-triazine als UV-Absorber sowie neue 2-Hydroxyphenyl-1,3,5-triazine |
| JP3932144B2 (ja) † | 1996-07-05 | 2007-06-20 | 株式会社Ａｄｅｋａ | トリアジン系化合物、それからなる紫外線吸収剤及びそれを含む高分子材料組成物 |
| US5840788A (en) * | 1997-06-20 | 1998-11-24 | Acushnet Company | Ultraviolet light resistant urethane top coat for golf balls |
| US5844026A (en) * | 1997-06-30 | 1998-12-01 | Ciba Specialty Chemicals Corporation | N,N',N''-tris{2,4-bis Hydrocarbyloxy-2,2,6,6-tetra-methylpiperidin-4-yl)alkylamino!-s-triazin-6-yl}-3,3'-ethylenediiminodipropylamines, their isomers and bridged derivatives and polymer compositions stabilized therewith |
-
1998
- 1998-04-30 US US09/070,627 patent/US6051164A/en not_active Expired - Lifetime
-
1999
- 1999-03-30 CN CNB998056596A patent/CN1154685C/zh not_active Ceased
- 1999-03-30 PT PT40779779T patent/PT1500675E/pt unknown
- 1999-03-30 EP EP99914266A patent/EP1080147B2/en not_active Expired - Lifetime
- 1999-03-30 IL IL13934899A patent/IL139348A0/xx active IP Right Grant
- 1999-03-30 BR BRPI9910062-2A patent/BR9910062B1/pt not_active IP Right Cessation
- 1999-03-30 AU AU32153/99A patent/AU740494B2/en not_active Expired
- 1999-03-30 RU RU2000130235/04A patent/RU2222560C2/ru active
- 1999-03-30 PT PT99914266T patent/PT1080147E/pt unknown
- 1999-03-30 CA CA002330422A patent/CA2330422C/en not_active Expired - Lifetime
- 1999-03-30 ES ES99914266T patent/ES2233030T5/es not_active Expired - Lifetime
- 1999-03-30 AT AT99914266T patent/ATE282061T1/de active
- 1999-03-30 KR KR1020007011989A patent/KR100608439B1/ko not_active IP Right Cessation
- 1999-03-30 WO PCT/US1999/006862 patent/WO1999057189A1/en active IP Right Grant
- 1999-03-30 JP JP2000547154A patent/JP2002513832A/ja not_active Withdrawn
- 1999-03-30 DE DE69921806T patent/DE69921806T3/de not_active Expired - Lifetime
- 1999-03-30 ES ES04077977.9T patent/ES2444366T3/es not_active Expired - Lifetime
- 1999-03-30 EP EP04077977.9A patent/EP1500675B1/en not_active Expired - Lifetime
- 1999-04-01 TW TW088105206A patent/TW555798B/zh not_active IP Right Cessation
- 1999-04-29 ZA ZA9903008A patent/ZA993008B/xx unknown
-
2000
- 2000-10-27 NO NO20005413A patent/NO319839B1/no not_active IP Right Cessation
- 2000-10-30 IL IL139348A patent/IL139348A/en not_active IP Right Cessation
-
2008
- 2008-11-04 JP JP2008283044A patent/JP5422174B2/ja not_active Expired - Lifetime
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW555798B (en) | Methods and compositions for protecting polymers from UV light | |
| TWI228525B (en) | UV stabilized composition | |
| US4629752A (en) | Substituted oxo-piperazinyl-triazines and UV light stabilized compositions | |
| RU2000130235A (ru) | Способы и композиции для защиты полимеров от уф излучения | |
| JP3635317B2 (ja) | 有機材料の安定剤としての２，２，６，６−テトラメチルピペリジル基を含有するブロックオリゴマー | |
| US7294714B2 (en) | Highly compatible hydroxyphenyltriazine UV-absorbers | |
| CN1334287A (zh) | 低厚度的透明聚合物制品 | |
| JP2011517716A (ja) | エポキシ樹脂用の硬化剤としての、末端アミノ基を有する高分岐のポリマー及びオリゴマー | |
| TW200408668A (en) | Synergistic combinations of UV absorbers for pigmented polyolefins | |
| US20190390040A1 (en) | Ultraviolet absorbing compound and applications thereof | |
| TW491872B (en) | Block oligomers containing l-hydrocarbyloxy-2,2,6,6-tetramethyl-4- piperidyl groups as stabilizers for lower polyolefin | |
| US20160333170A1 (en) | Polyacetal resin composition and resin molded article | |
| DE50008800D1 (de) | Verfahren zur bioziden Ausrüstung von Kunststoffen | |
| TW296384B (zh) | ||
| GB2345485A (en) | Sterically hindered amines as stabilisers to actinic radiation in polymers | |
| TW589341B (en) | Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials | |
| EP1871828B1 (en) | Compositions and method for preventing the photodecomposition of cyclic olefin copolymers | |
| TW539711B (en) | Stabilizer mixtures | |
| KR20110089414A (ko) | 신규한 방법 | |
| JPH11502524A (ja) | ホルムアルデヒドを含まない１，３，５−トリアジンを基とする架橋剤 | |
| TW449607B (en) | Bisphenyl-substituted triazines | |
| TW406104B (en) | A mixture containing three different monodispers block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials | |
| GB2382348A (en) | Transparent polyolefin film comprising hydroxyphenyl triazine UV absorber | |
| JPH06329910A (ja) | 半導体封止用樹脂組成物 | |
| JP2014005385A (ja) | ポリアセタール樹脂組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GD4A | Issue of patent certificate for granted invention patent | ||
| MK4A | Expiration of patent term of an invention patent |