TW449607B - Bisphenyl-substituted triazines - Google Patents

Abstract

A description is given of biphenyl-substituted triazine compounds of the formula. The biphenyl-substituted triazine compounds, which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fibre materials, and as sunscreens for the human skin.

Description

449607 at B7 V. Description of the invention (I) The present invention relates to a bisphenyl-substituted triazine compound 'and a method for preparing these compounds. These compounds are copidinated to resist damage caused by sunlight * heat and oxygen. Organic substances * and cypresses which are used as stabilizers for hosiery substances, and are used as light stabilizers for spinning and shrinking substances and as photomasks for human skin. If it is desired to increase the photocharacteristics of a substance, especially a coating, a light stabilizer is usually required. One class of light stabilizers often used includes UV absorbers, which protect the substance by absorbing harmful rays through a color base. An important class of UV absorbers are triazine compounds, described in EP-A- 4 3 4, 6 0 8; EP-A-520,938; US-A-4,619,956; EP-A- 4 8 3, 4 8 8; EP-A- 50 0, 4 9 6; EP-A-50 2, 8 1 6 and EP-A-5Q 6,615. Some bis-resorcinols derived from these groups are described in, for example, CH-A-430,090; CH-A-484,695 US-A- 3, 2 4 9, 6 0 8; US-A-3,244,708; US -A-3,843,371 US -A- 4,826,378; EP-A-4 3 4,6 0 8; EP-A- 5 2 0, 9 3 8 68-Jiu-2,273,498 and cut '0-4-94 / 18,278 . It has been found that specific bisphenyl-substituted triazine compounds are printed in the range of 3 ◦ ◦ printed by the Consumer Cooperatives of the Central Bureau of Samples of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) to 400 nm Very high absorbance and therefore very important for organic polymers. The neo-biphenyl mono-substituted triazine 丨 b complex of the present invention has the following chemical formula: -4- This paper size is applicable to China Gujia Koufeng {CNS) A shirt sees UIOXM7 mm 44960 7 A7 B7 5 , Description of invention (说明

X) (Please read the notes on the back before filling out this page) Staff Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs

Ri is _; Ci — Cz 4 alkyl or Cs — Ci 2 ring radical, or

Ci -Cz 4 alkyl or C5 —Ci 2 cycloalkyl I which is composed of 1 to 9 years old atom, one R4 ′ — 0 R 5, one N (R 5) 2, = NR 5, = 0, − C〇N (R 5) z 1 — C 0 R 5, -C 0 0 R 5 t_〇C〇R5 >-0 C 〇 N (R s) 2, —CN, — NO2 * — SR 5 > — S 0 R 5, -S Ο z R 5,-P (0) (0 R 5) 2, morpholinyl, menidinyl, 2, 2, 6, 6-tetramethyltonidinyl, piperidine Substituted with a azinyl or N-methylzinazinyl group, or a combination thereof; and / or C i -C 2 4 alkyl or C 5 -C! -0_--NR 5---C 0 NR 5-, — C〇0-,-0C0---CH f R s)-, -C (Rs) £ _ or -CO —group base or combination thereof Interrupted; This paper size applies Chinese National Standard (CNS) A4C (210 X 297 mm) 449 60 7 A7 B7 V. Description of the invention (,) and Ri are further Cz -C2 4 alkenyl; halogen; _SR3, S 0 R 3; S 0 2 R 3; -S〇3 H; -S〇3M; or one (Please read the precautions on the back before filling this page) The group base of the following formula:

R3 is Ci — C2. Alkyl; C3 —'Ci 8 alkenyl; cs — C; 2 cycloalkyl; C7 — Ci 5 phenylalkyl • or Ce — Ci 2 aryl, which are unsubstituted or have 1 to 3 ( 31 ~ C4 alkyl substituted; R4 is unsubstituted Cs — Cl2 aryl; or Cs — aryl, which consists of 1 to 3 halogen atoms, Ci_C8 alkyl or Ci-C8 alkoxy or Substituted by its composition; C5_CS 2 cycloalkyl; unsubstituted C7 —Ci 5 —phenylalkyl; or C7 -Ci 5phenylalkyl, which has from 1 to 3 halogens on the benzene ring Atom iCi-Cs alkyl * Ci_C8 alkoxy or its composition substituted, or C2-C8 dilute; is R4; hydrogen; Ci_C24 alkyl; or a group of the following formula: Central rubbing rate of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperative

This paper is again in accordance with the Chinese National Standard (CNS) A ** grid (210X297 mm) 443607 A7 B7 V. Description of the invention (4) (Please read the notes on the back before filling this page) T is hydrogen; C8 alkyl; Cz — C8 alkyl, which is substituted via one or more hydroxyl groups or one or more fluorenyloxy groups; oxygen groups; hydroxyl groups; -CH2 CNiC!-CL8 alkoxy groups; Cs — (: 12 Cycloalkoxy; C3 ^ Cs alkenyl; C7-C9 phenylalkyl; C7-C9 phenylalkyl | It is substituted by Ci monoalkyl on the benzene ring for one, two or three times; or C ! _C3 alkylfluorenyl;

Rs to R! 5 are unrelated to each other; hydrogen; hydroxyl; -C ^ N; Ci-C2 alkyl; C!-C2. Alkoxy; C7-C2 0 phenylalkyl; C4-012 cycloalkyl; C4_cl2 cycloalkoxy; halogen: halogenated-Ci-Cs alkyl; sulfofluorenyl; carboxyl; fluorenylamino; Oxy; Ci — Ci 2 alkoxycarbonyl; amine carbonyl; 0 — Y; or 0 — Z; or Ra and R3 — and phenyl are cyclic groups | it is composed of one or more oxygen or nitrogen atoms Interrupted; M is an alkali metal; ρ is 1 or 2; q is 0 or i; r is 1 or 0; printed by the Shellfish Consumer Cooperative of the Central Government Bureau of the Ministry of Economic Affairs and if q is 0 · R i 2 and R t 3 is not a hydroxyl group; if ρ is 1, X > Y and Z are mutually independent hydrogen; C4_C5 alkyl group * which is interrupted by one or more oxygen atoms * and / or via one or Substituted by multiple hydroxyl groups; The paper scale is applicable to the CNS A4 specification (210X297 mm) 9 8 0 7 A7 V. Description of the invention (〇

-ch2-ch (oh) -ch2-nry-τ -CH2-CH (OR2) -CH2-NRY C4 — Ci 2 cycloalkyl, which is substituted by Rz; _0R2 — substituted C4 —Ci 2 cycloalkane base;

〇II c- I —CH 〇.: CH2) n OMnc

—CH NR * CH ^ Printed by the Offset Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs -CH 2-CH (-0 (CO)-R 2)-R 7 2, -C 0-NR 7-(CH z) n -R 2; C s-C12 aryl: amidino; C4-C2. Dilute group • It is unsubstituted or interrupted by one or more gas atoms; C4-Ci 2 cycloalkenyl • It is unsubstituted or substituted by one or more oxygen atoms; C3 — C2 . Alkynyl; or Cs —C! 2 cycloalkynyl; if Rz and R '2 are attached to a carbon atom, they are unrelated to each other, respectively, Rx>, and if attached to an oxygen atom, R y; η is 0 to 2 0 ; m is 0 to 2 0; -8- (Please read the precautions on the back before filling in this page)

The paper scale is applicable to the Chinese National Standard (CNS) A4 specification U10X 297 mm 9 60 7 at B7 V. Description of the invention (G) and if p is 2, Y and Z are not related to each other as above when p is 1 Defined by; and X is C 2 —Ci 2 alkylene; -C 0-(C 2 -Ci 2 alkylene) -CO-; _c〇_phenylene -C〇-; co -bisphenylene-CO- '> CO — 0 — (C 2 — Ci 2 Complex)-0 — CO —; -CO — 0 -Phenylene-0-CO —;-CO- ◦-Biphenylene -O-CO-;-- C〇-NRy-(C2-Cl2 alkylene) -NR '-CO —; -C〇 -NR' -phenylene-NR '— CO — CO — NR' — bisphenylene —NR '— C0-;- CH 2-CH (OH) -CH2-;-CHz-CH (0 R 2) — CHz —; — CH2 — CH (OH) — CH 2 —〇— D — 〇— CH2 — CH (OH) ~ CH 2 ; -CH 2-CH (0 R a)-CH 2-0-D-0-CH 2-CH (0 R 2) — CH 2-; D is C2 — C; 2 alkylene; C4 — CS. Alkylene, which is interrupted by one or more oxygen atoms; phenylene; bisphenylene or phenylene_ E _phenylene Please fill in this page again) E Yes-〇-;-S-;-S〇2 —; _CH2-;-C0 —; or —C (CH3) 2-;

Rx is hydrogen; hydroxyl; C: — C2. Alkyl; C4—Ci 2 cycloalkyl; Ci—C2 0 alkoxy; C4—C! Z cycloalkoxy; C4 —Ci 2 cycloalkyl or C4 — Ci 2 cycloalkoxy, which is via one or Interrupted by multiple oxygen atoms; CS-Ci 2 aryl; Hetero-C3 _ This paper size applies to the Chinese National Standard (CNS) A4 specification (210X29? Mm) 449 60 7 Λ7 Α7 Β7 V. Description of the invention (Ί ) (:! 2 aryl; -0 ft 2; 1 \ 11 ^ ft 2; ft 2; C 0 NRJR "; allyl; (: 2-0 2 0 alkenyl; 0-C 1 2 -ring Alkenyl, which is uninterrupted or interrupted by one or more oxygen atoms; C3_C2. An alkynyl; or cs-cl2 cycloalkynyl;

Ry is S; Jing; Ci. Carbyl; C4 — Ci z-cyclic heptyl * which is uninterrupted or interrupted by one or more oxygen atoms; Cs — Cl 2 aryl; hetero-C 3 —Ci 2 aryl; Rz; C2-C20 alkenyl; C4-1012-cycloalkenyl • it is uninterrupted * or interrupted by one or more oxygen atoms; C3-c2O-alkynyl; or 06-c [2 ring Alkynyl

Rz is a COR;-C 0 0 R /;-C 0 NR 7 R "-CO-CH = CH2;-C 0-C (C Η 3) = C Η 2 f R 'and R " do not Associated are hydrogen; Ci — CZ 0 alkyl; C4 — c5 0 alkyl; C4 — Cs 0 alkyl, which is uninterrupted or interrupted by one or more oxygen atoms; C4 — Ci £ ring Alkyl * It is printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling this page) Uninterrupted or interrupted by one or more oxygen atoms; C2-C2 0 alkenyl, which is unsubstituted or interrupted by one or more oxygen atoms; or Cs_C12 aryl; and r is 1. Group bases Rx * Ry, R 'and R " via hydroxyl groups * -N Η 2 > — NHR', one NR 'R ", halogen, Ci — -10-This paper standard is applicable to Chinese standard (CMS) A4 specification (2 [0297mm) 44960 7 α7 B7 5. Description of the invention (?) C2 0 alkyl, Cl-C2. Alkoxy, C4—Cl z cycloalkyl, C4 — Cl 2 cycloalkoxy, C 2 -C 2 alkenyl, C 4 -Ci 2 cycloalkyl, C 3 —C 2 0 alkynyl, Cs — Ci 2 cycloalkynyl , CS — Ct 2aryl, fluorenylamino, fluorenyloxy, sulfonylfluorenyl, carboxyl, (meth) propenyloxy | (meth) propenylamino,

(Please read the notes on the back before filling out this page) -COQ ^ ~ ^^-T; —CONR 'The above-mentioned group base also includes the isomer mixtures of the definition given. Alkyl can be branched or unbranched alkyl, like methyl, ethyl I propyl, isopropyl t n-butyl, sec-butyl, isobutyl, tert-butyl, 2- Ethylbutyl, n-pentyl, isopentyl, 1-methylpentyl * 1, 3-dimethylbutyl, n-yl, 1-methylhexyl, n-heptyl, isoheptyl, 1,1,3,3-tetramethylbutyl, 1-methylheptyl, 3-methylheptyl, n-octyl * 2-ethylhexyl * 1,1,3-trimethylhexyl, 1, 1, 3, 3-tetramethylpentyl, nonyl * decyl Printed by the Consumer Cooperative of the Ministry of Economic Affairs + Central Standards Bureau, undecyl, methylundecyl, dodecyl, 1, 1,3,3,5,5-hexamethylhexyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl or octadecyl. C l to C2. Alkoxy groups that can contain straight or branched bonds, such as · For example methoxy * ethoxy, propoxy | butoxy • pentoxy · hexyloxy, heptyloxy * octyloxy, iso Octyloxy | Nonyloxy, Undecyloxy · TenM 1- This paper size applies to China National Standard (CNS) A4 (2Ι0 × 297 mm)

Λ Π T ^ w «Α7 B7 V. Description of the invention (4) Dialkoxy, tetradecyloxy, or pentadecyloxy, hexadecyloxy * heptadecyloxy, octadecyloxy , Undecyloxy or eicosylamino. Phenylalkyl is a group in which an alkyl group is substituted by a phenyl group> C7-Cz. The phenyl group is, for example, benzyl, methylbenzyl, C (,, C (-dimethylbenzyl, phenylethyl) , Phenylpropyl, phenylbutyl, phenylpentyl, phenylhexyl, phenylheptyl, phenyloctyl • phenylnonyl * phenyldecyl, phenyldodecyl or phenyl Tetradecyl. Halogen is one F, one C1, one Br, or one I, preferably one F, or one C1, and one C1. C4 — Ci 2 cycloalkyl is > , Cyclopentyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cycloundecyl, cyclododecyl, especially cyclohexyl. C4 interrupted by one or more oxygen atoms Suitable examples of _Ci 2-cycloalkyl are tetrahydrofuranyl, 1-oxa-4_cyclohexyl and 1-dioxa ~ 4-cyclohexyl. The Ministry of Economic Affairs and the Central Government Bureau of Employees' Consumer Cooperatives India (Please read first Note on the back, please fill in this page again.) In the defined range of alkenyl, include allyl, isopropenyl, 2-butenyl, 3-butenyl, isobutenyl, n-152-2, 4-12 Alkenyl, 3-methyl —Butan 2 —alkenyl, n-octyl_2 —alkenyl, n — twelve — 2 — pavement, iso — twelve dilute — n — twelve — 2 — dilute and n — 18 — 4 Examples of C 2 -C is alkylfluorenyl are ethyl, propionyl, propenyl * methacryl or benzamyl.

Cb — Ci 2 cycloalkenyl gardenia is 2-cyclopentene-1 1 base, -1 2-This paper's standard is applicable to China National Standard (CNS) A4 (210 X 297 mm) 49 60 7 A7 B7 V. Description of the invention (^) 2,4-cyclopentadiene-1-yl, 2-cyclohexene-1-yl, 2-cycloheptene-1-yl or 2-cyclooctene-1-yl. Examples of C4 —Ci 2 cycloalkoxy are cyclobutoxy, cyclopentyloxy, cyclohexyloxy > cycloheptyloxy > cyclooctyloxy, cyclononyloxy, cyclodecyloxy, cyclodeca Monoalkoxy * ring + dialkoxy, especially cyclohexyloxy. Specific examples of Cs_C i 2 aryl are phenyl · naphthyl and bisphenyl 0-C3—Ci 2 aryl is preferably pyridyl · pyrimidinyl I triazinyl · pyrrolyl * pyranyl * thio Phenyl or quinolinyl. An example of a fluorene group formed by Ri i and 1 ^ 2 and a phenyl group is 3,4-didimethyldioxyphenyl group. The preferred compound of the present invention is defined by the following formula: < Please read the notes on the back before filling this page)

This paper size applies the China National Standard (CNS) Ad Grid (210X297mm) i 4 DuPont, Shellfish Consumer Cooperation, Central Bureau of the Ministry of Economic Affairs. 4 6 0 7 A7 _B7 V. Description of the invention ()

P where R 1, 乂, 丫, redundant, 1 > and 1 ′ are as defined in formula (1). Among the compounds of formula (3), the compounds defined below are preferred, wherein: X is ((C Η 2) m-C Η 2-〇-) η-R y;-(C Η 2) η- RX; -CH2 -CH (0H) -CH2 -〇- {CH2) n-Rx;

Rx is hydrogen; hydroxy; Ci—C20 alkyl; or C4—Ci 2 ring hexyl;

Ry is hydrogen; or 〇1—C2. Alkyl; or _Ci 2 cycloalkyl! M is 0 to 2; η is 0 to 2 0; ρ is 1; r is 1; and

Ri is as defined in Equation 1. -1 4- This paper is applicable to China National Standards (CMS) A4, see the standard (210X297 mm) I bundle order I. (Please read the precautions on the back before filling this page) Ministry of Economic Affairs Printed by the consumer cooperative A7 B7 V. Description of the invention (, particularly triazine compounds of the formulae (1) to (3) are: where X, Y and Z are independent of each other is hydrogen, ) i ™ CH2 -0-) n-R2;-(CH2 -CH ((CH2) Ηϋ) -0-) nR, 2;-(CH ((CH2) -R2) -CH2 -O-Jn-R ^ ;-(CH2) n-Rz; -CHz -CH (0H) _CHz -Q- (CHz) n-R2; -ch2 -CH (0R2) -CH2 ~ 0 * (CH2) nR * 2; -CHz -CH (OH)-CH2 * 〇- (CH2) n -0 R2; or -CHz -CH (ORz) -CHz -0- (Cfia) n-0 R 1 2 Other preferred compounds are compounds of the formula:

among them:

Rji is M; Ci — Cz. Heji; Ci-Cz. Burnt oxygen; or halogen;

Ri 3 is hydrogen; Ci 10 hospital base; Ci — C2 〇 gas base; -1 5-Chinese paper standard (CNS) M paper grid (210 X 297 cm) II ί-f-gen Ding I ^ 3, -11 right '(please read and read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs 449 60 7 at B7 V. Description of the invention (Λ) —C2 〇 alkoxy; or halogen; R14 is hydrogen; Ci-Czo alkyl; Ci —C2 alkoxy; or halogen; R! 5 and Ri s independently of each other is hydrogen; C! _C2 0 alkyl ; Ct _C2. Alkoxy, or halogen; r is 0 or 1; and q is 0 or 1. The most preferred compound is a compound of formula (4) |

Ri is nitrogen; Ci—C2O; radical; or Ci—C2o alkyl; R 1 3 ′ R 1 4, R 15 and R 1 S are gas; r is 0; and q is 0 or 1. The compounds of the formulae (1) to (4) are novel compounds; examples of this neofluorene compound include 2- (2-hydroxyphenyl) -4-phenyl-6- (4-bisphenyl) -1,3, 5-triazine, 2- (2,4-dihydroxyphenyl) -1,4,6-bis (4-bisphenyl) -1'3,5-triazine, 2- (2-hydroxy-1-4-hexane Oxybenzyl) -4,6-bis (4-bisphenyl) -1,3,5-triazine, 2- (2,4-dihydroxyphenyl) -4,6-bis (4-bis (Phenyl) -1,3,5-triazine, 2_ [2-hydroxy-1-4- (2-hydroxy-3-butoxydioxy) phenyl] -1,4,6-bis (4-bisphenyl)- 1 * 3, 5-triazine * 2 — (2-hydroxy-4 4-octyloxyphenyl) -4,6-bis (4-bisphenyl) -1,3,5-triazine * 2-[ 2 —Hydroxy · / -16- This paper size is applicable to China Solid State (CNS) A4 rule (210X297 mm) (Please read the precautions on the back before filling this page) Ding, Yi =-* 7 7 A7 B7 printed by China Industrial Standards Co., Ltd., Industrial Standards and Consumer Cooperatives 5. Explanation of the Invention (7) -4-(2-Hydroxy-3-Dodecyloxy-C (Phenyl) phenyl] _4.6-bis (4-bisphenyl) -1,2,3,5-triazine * 2-[2-hydroxy-4 (2-hydroxy-3-tridecyloxypropane) (Oxy) phenyl] -4,6-bis (4-bisphenyl)-1 1 3,5-triazine '2-(2-hydroxy-4-methoxyphenyl)-4-(2, 4-dimethoxyphenyl) -phenyl-6- (4-bisphenyl) -1,3,5-triazine, 2.4-bis (2-hydroxyphenyl) -6- (4-1 Biphenyl) _1, 3.5-trimethyl, 2- (2-triphenyl) -1, 4- (2-methoxyphenylhydrazone), 6- (4-bisphenyl), 1 · 3, 5 a triple voice, 2-(2-via the basic group)-4-(4-methoxymethoxy)-6-(4-bisphenyl) di 1, 3, 5-triazine; or 2 ~ ( 2-hydroxy-4,4-methoxyphenyl) -4,6-bis (4-bis-benzyl) -1,3,5-triazine. The novel compounds of formulae (1) to (4) can be prepared by various methods. For example * these compounds can be similarly described in EP-A-434, 6Q8 or in H. Brunetti and C. E. Luthi, Hel ν. Chim. Acta 55, 1566 (19 7 2) Friede 1-Crafts Additiona of Halotriazines prepared from onto appropriate phenols. These methods are then reacted in a conventional manner to obtain compounds of formulae (1) to (4). These methods and reactions are described, for example, in Ep-A ~ 434,608, page 15 *, line 11 to page 17, line i. This novel compound can also be prepared from a compound of the following formula: benzyl compound and a salicylic acid compound of formula (7) to obtain a tritherapeutic compound of formula (1) -17. A4 specifications (210X297mm t) I ^ .1 n take n 11 11 I ^ (read the precautions on the back before filling out this page) 9Λ 60 7 A7 B7 V. Description of the invention ((5)

HHaL (6)

HHal 1 (Please read the notes on the back before filling out this page) ⑺

OH

D-5 Central Bureau of Standards, Ministry of Economic Affairs β; printed by the Industrial and Consumer Cooperatives where: Η a 1 1 is halogen > XI is halogen or — 0 R 5! 1 1 R 5 is C 1 — C 3 courtyard; and R 1, R 6 R 7 R Rai R 9 R 1 ZR 1 3 »R 1 4» R! 1) The reaction of class U is described in, for example, -1 8-* R i 〇 * R 1 1 ^ 5, Q · Γ and X are as follows (EP-A-0,649,841 〇 This paper wave standard is applicable to China National Standard (CNS) Sixty-four Regulations · (210 × 297 mm) 449 60 7 A7 B7__ Description of the invention (The new amidine compound of formula (1) can be obtained by dehydrogenation of a dihydrotriazine compound of the following formula:

(Please read the notes on the back before filling out this page} Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy Ri > R 6 * R 7 * R 8 R 9 * R 1 〇 * Ri 1, R 1 2 , Rl3, Rl4 'RI5, the parent's mouth' and ^ are as defined in formula (1 >. An example of an argon-removing agent that can be used is Cl. It is known that 1 * 3 · 5-triazine can be obtained by hydrogen reaction, for example, described by Khim. Geteritsikl. Soedin. (2), pp. 350-353 (1963). Other dehydrogenation reagents that can be used in this method are: Conventional reducing agents, such as dithionite, pyrosulfate, sulfite and thiosulfite • but in this case act as oxidants. A variant of this preparation method is preferably the use of hydrogen sulfite Sodium or sodium dithionite is reacted • and this method is described in, for example, EP-A-0648,754. Dihydrotriazine of formula (8) is a novel compound * The present invention is also 9-1 9- This paper size Applicable to national standards (CNS> A4 (210X2? 7mm) A7 _ B7 V. Description of the invention (β) To neutralize the acid formed during the reaction The bases that can be used include organic and inorganic compounds, such as metal hydroxides, especially sodium hydroxide or potassium hydroxide solution; ammonia water is weak; ammonia gas; alkali gold tincture carbonate, especially sodium carbonate or potassium carbonate; acetic acid Sodium; tertiary amines * like pyrimidine or trialkylamines, especially triethylamine · N, N-dimethylcyclohexylamine, N, N-dimethylaniline; alkali amidinates, especially Sodium formate and potassium formate, or potassium tert-butyrate. The benzoxazinone of formula (10) is a neofluorene compound, and the present invention also relates to these compounds. The benzoxazine of formula (10) is Novel compounds are easily reactive. For example, salicylic acid salicylamine of the following formula undergoes an acid-catalyzed cyclization reaction: (please read the note on the back before filling this page) Order

The Central Government Bureau of the Ministry of Economic Affairs's consumer cooperation. Du Yinzhuang

This synthetic reaction can be carried out in a single reactor, by reacting ammonium salicylate and a carbonyl halide of the formula:

C (12)

Hai -21- The paper scale is remotely used by the Chinese National Cricket (CMS) Α4 Specification < 2 丨 0X29? Mm) 4f Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

A7 B7 5. Description of the invention (a) The reaction is carried out, for example, in a boiling aromatic solvent, such as xylene or methylbenzene. The reaction time is from 1 to 10 hours, preferably from 2 to 4 hours. In formulae (11) and (12), 'R 1 3' R 1 4, Ris, q, r, X and Hal are as described above. Defined by. Similar to the literature by Η · J. Kabbe, K. Eiter, and F. Μοο Πer, Liebegs Ann. Chem. 704, 140-143, (1967), and may also consist of 4-bisphenyl Hydrazine and guanidinium salt to prepare 2-amino-4,6-bis (4-bisphenyl) -1,3,5-triazine NH. 丄 N ^ N (13); then amine K hydrogen The sodium oxide solution is hydrolyzed to hydroxyl groups. Then react with the SOC to obtain a compound of formula (114) (Example 14), and then react as described in M to a compound of formula (115) (Example 15) ° This novel bisphenyl-substituted triazine compound It is a very good UV absorber. Especially its high thermal properties. Therefore, it can be used as a bonding agent for organic polymers, especially coating materials | to resist -2 2 caused by light, oxygen and heat-This paper size applies to China National Standard (CNS) A4 specifications (210X 297 Gongao ), Clothing order ---- '{Please read the notes on the back before filling this page) ^ 607

^ 607 A A7 B7 V. Description of the invention () Damage and light stabilizer for textile fiber material. Special benefits of this novel bisphenyl-substituted compound include its surprisingly high absorbance in the electromagnetic spectral range of 300 to 400 nm, and another surprising regulation is that although the novel compound has a large conjugated aromatic糸 System * but its dissolution and melting behavior is surprising. • Dissolution and melting behavior of comparative compounds similar to previous techniques. The substances stabilized by the compounds of the present invention have outstanding mouth resistance to the effects of climate and light, and have outstanding light properties to the stabilizers added. The substances that can be fixed can be, for example, oils, fats, stone, cosmetics or biocides. Particularly advantageous applications are stabilization of polymeric materials such as plastics, rubber * coatings and other coating substances, photographic substances or cobalt compounds. Examples of polymers and other baseboards that can be specified in this way are the following: 1 'Monoolefins and diolefin polymers, such as polypropylene, polyisobutylene, polybutene-1ene, poly-4_ Methylpentadiene, polyisoprene or polybutadiene, and polymers of cycloolefins * such as cyclopentene or norbornene 1 polyethylene glycol (which is selectively crosslinked), such as high High density polyethylene (HDPE), high density and high molecular weight polyethylene (HDPE-HMW), high density and ultra high molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE) | Linear Low Density Polyethylene (LL DPE), Supported Low Density Polyethylene (BLDPE). Polyolefins, that is, polymers of monoolefins • As mentioned in the previous paragraph-2 3- This paper size applies Chinese National Standard (CNS) A4 (210X 297 mm) (Please read the notes on the back first (Fill in this page again), 11 Printed by male laborers in the Central Standards Bureau of the Ministry of Economic Affairs, printed by the Central Laboratories of the Ministry of Economic Affairs, printed by the Consumers ’Cooperatives in the Central Laboratories, printed 449607 A7 B7 Ethylene and polypropylene can be produced by different methods: usually under high pressure and high temperature) 0-combination reaction * This catalyst usually contains species or 1 V b redundant to VI b or Group VIII-one or more types t are typically Oxidation of m 1 amine t fluorenyl compound alkenyl compound and —or σ — covalent 0 On these metal composite substrates I is typically activated activated magnesium or silicon oxide. This solvent is soluble or some catalyst But its white has made the type of gold sulfide alkylate in the polymerization reaction. Or metal alkyloxane *, II a 9 and / or II Ϊ A group ester tm 9 amine or silane ether is conveniently converted to P hi 1 1 ί PS > S ta η d ί a η a * Z ie S 1 e Γ ((Du P 0 η t) rmeta 1 (SS c) 3, such as y The temperature compound of polypropylene and polyisopolyethylene (such as f ρ P / PE) »Mix with different types of polyethylene V. Description of the invention (J) The monoene fluorene polymer is prepared by a special method, especially the following a) free radical reactive group polymerization (b) using a catalyst to polymerize more than one type of periodic table I Vb metals, these metals usually have the substance * halogenated tree | alcohol ester, cool | or arylate, which can be rr or can be free or fixed in

Titanium (III) chloride is insoluble in the polymer matrix, and it can be used, or an activator can be used, such as a metal halide, and the metal can be the I a element of the periodic table. The activator can be For further use, these catalysts are generally called dard Oil In-N atta), but NZ 1ocene or unilateral catalyst 2. A mixture of polymers butenes mentioned in 1), polypropylene and HDPE · PP / LDP (Such as LDPE / HD PE) 0 -2 4-This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) Central Government Standards Bureau, Ministry of Economic Affairs, Maternity and Consumer Cooperation Du printed 60 7 A7 B7 _ 5. Description of the invention (,) 3. Copolymers of mono-olefins and di-olefins and other ethylene monomers, such as * ethylene / propylene copolymers, linear low density polyethylene (LLDPE) and its warm compounds and low density polyethylene ( LDPE), propylene / butane 1-dilute copolymer, propylene / isobutylene copolymer, ethylene / butane-1 monoene copolymer, ethylene / hexene copolymer, ethylene / methylpentene copolymer, ethylene / heptene copolymer Polymer, ethylene / octene copolymer, propylene / butadiene copolymer'isobutylene / isoprene copolymer • Ethylene / alkyl acrylate copolymers' and their copolymers with carbohydrates, or ethylene / acrylic acid copolymers, and their toilet products (ionized products), and Polymers such as hexadiene, dicyclopentadiene or ethylene di-orbornene; and mixtures of the copolymers and the warm compounds of the polymers mentioned in 1) above, for example, polypropylene / ethylene-propylene Copolymer * LDPE / ethylene-vinyl acetate copolymer (EVA), LDPE / ethylene acrylic copolymer (EAA) * LLDPE / EVA-LLDPE / EAA and interlaced (a 1 ternat i ns) or scattered (rando m) Polyolefin / carbon monooxide copolymers and mixtures thereof with other polymers, for example, polyamines. 4. Hydrocarbon resins (e.g. C5 to C9), including their argonized modifiers (e.g., adhesives), and mixtures of polyolefins and starch. 5. Polystyrene, poly (P-methylstyrene), poly (α-methylstyrene). 6 'Styrene or α-methylstyrene and a copolymer of diene or an acrylic derivative, for example, styrene / butadiene * styrene / acrylonitrile' styrene shop-2 5-(Please read the Note: Please fill in this I ·) and order a. The paper size is applicable to Chinese National Standard (CNS) A4 (210X297mm) 449 60 7 A7 B7_ V. Description of the invention (/) / Alkyl methacrylate 'styrene / Butadiene / alkyl acrylate 'styrene / butadiene / alkyl methacrylate, styrene / maleic acid, styrene / acrylic acid / methacrylate; high impact of styrene copolymer Strength blends, and another polymer, such as polyacrylate, a diene polymer or an ethylene / propylene / diene terpolymer; and a block copolymer of styrene, like styrene / butadiene / benzene Ethylene'styrene / isoprene / styrene, styrene / ethylene / butene / styrene or stupid ethylene / ethylene / propylene / styrene. 7. Graft copolymers of styrene or α-methylstyrene, for example, styrene on polybutadiene, polybutadiene-styrene or polybutadiene-acrylonitrile copolymer Styrene on polybutadiene and acrylonitrile (or methacrylonitrile): styrene on polybutadiene, acrylonitrile and methacrylic acid; benzene on polybutadiene Ethylene and maleic anhydride; styrene, acrylonitrile, and maleic anhydride or melamine butadiene on polybutadiene; styrene and melamine on polybutadiene Fluorene imine; styrene and alkyl acrylate or methacrylate on polybutadiene; ethylene and acrylic eyes on ethylene / propylene / diene terpolymer; polyalkyl acrylate or polyacrylate Styrene and propylene on alkylmethacrylates; styrene and acrylonitrile on acrylate / butadiene copolymers and mixtures of copolymers listed under S), such as * Knowledge ABS ' Copolymers of MBS, AS A or AES polymers. 8. Halogen-containing polymers, such as poly (vinyl chloride) chlorinated rubber, atmospheric or vulcanized gasified polyethylene, ethylene and chlorinated ethylene copolymers, and superficially fermented paper CNS Α4 size (210X297 mm) (Please read the precautions on the back before filling in this page), ^ τ Central Standards Bureau, Ministry of Economic Affairs, Office of Consumer and Consumer Cooperation Du printed 44960 7 A7 B7 Central Ministry of Economic Affairs橾 Rubber Co-consumer Cooperative Printing Du V. Description of Invention (艸) Homo- and copolymers • Especially polymers containing halogenated vinyl compounds • For example, polyethylene gaseous compounds, polyethylene diene compounds, polyethylene Fluoride, polyethylene diene fluoride, and copolymers thereof, such as ethylene chloride / ethylene dichloride, ethylene chloride / ethylene acetate or ethylene diene copolymer / ethylene acetate copolymer. 9. Polymers made from α, / 3-cells and acids and their derivatives 'like polyacrylates and polymethacrylates; polymethacrylates' polyacrylamide and polyacrylonitrile, acrylic acid Butyl esters become shock modifiers. 10. Copolymers formed between the monomers of 9) and other non-cells and monomers, such as propylene / butadiene copolymers, acrylonitrile / alkyl acrylate copolymers, acrylonitrile / alkoxyalkanes Copolymers of acrylonitrile or acrylonitrile / ethylene halide or acrylonitrile / alkylmethacrylate / butadiene terpolymer. 1 1 · Polymers derived from unsaturated alcohols and amines or their halogenated derivatives or their acetals, such as polyethylene yeast, polyethylene acetate, polyethylene stearic acid_ • polyethylene stearates , Polyethylene maleic acid-polybutylene acetal, polyallyl peptidate or polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1 above. 1 2 · Homopolymers and copolymers of cyclic ethers * like polyolefin dienzymes, polyethylene oxides, polypropylene oxides or copolymers with dioxolane. 1 3 · Polyacetals, like polyoxymethylene and those polyoxymethylenes, which contain ethylene oxide as a conjugate * K thermoplastic polyurethane, acrylate or MB S modified polyacetal. 1 4 · Polyphenylene oxides and sulfides • and polystyrene oxides and styrene-27- ^ ------ Order --- Ipr- (Please read «Notes on the back before filling this page ) This paper size applies to China's family standard {CNS) A4 (210X297 mm) printed by the Central Government Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, printed OQ n ^ \ jt A7 _ B7____ 5. Description of the invention (λ) polymer or Polyamide mixture. 15 Polyurethane derived from hydroxy-terminated polyether, polyester or polybutadiene on one side, and aliphatic or aromatic polyisooxylate on the other side, and its precursor. 1 6 'Polymer [amines and copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent lactams * For example, polyamine 4 * polyamine 6, polyamine Amines 6/6, 6/1 0 * 6/9, 6/12 * 4/6 * 12/12, polyamines 1 1 and polyamines 12, starting from m-xylylenediamine and adipic acid Aromatic polyamines; polyamines derived from hexamethylene diamine and iso-peptides or / and p-peptides, with or without elasticity, as modifiers, for example, poly-2,4, 4-trimethylhexamethylene p-amine or poly-111-benzene isoamidine; and the above-mentioned polyamines and polyolefins, olefin copolymers, ions, or chemically bonded or grafted elastomers; or Poly-, such as block copolymers with polyethylene terephthalate, polypropylene terephthalate, or polytetramethylene glycol; and ME PDM or AB S modified polyamines or copolyamides; and in the manufacturing process (RIM Polyamine system) concentrated polyamine 0 1 7 'polyurea, polyimide, polyamido-imino and polybenzoxazole. 1 8 * Polyesters derived from dicarboxylic acids and diols and / or hydroxycarboxylic acids or equivalent lactones, such as • polyethylene terephthalate, polybutylene terephthalate, poly-1 4,4-dimethylmethanol cyclohexane terephthalate and polyhydroxybenzoate, and block copolyetheresters derived from hydroxyl-terminated polyethers; and polycarbonate modified or MBS modified Polyester. -28- This paper once again applies the national standard (CNS) A4 specification (210X297 mm) (please read the notes on the back ^ before filling in this page), ιτ A7 B7 ^, description of the invention (> ) 1 9 · Polycarbonate and polyester carbonate are cool. 20 · Polymill, polyether barrier and polyether copper. 2 1 • Crosslinked polymers derived from aldehyde on one side, phenol, urea and melamine on the other side • Like phenol / formaldehyde resin * urea / formaldehyde resin, and melamine / formaldehyde resin. 22 Dry and non-drying yeast resins. 23 · Unsaturated polyester resins derived from saturated and unsaturated dicarboxylic acids, polyhydrogenases, and K vinyl compounds as crosslinking agents, and their low-flammability halogen-containing modifiers. 24 * Crosslinked acrylic resin derived from fluorene-substituted acrylic resin, such as * epoxy acrylic resin, urethane acrylic resin or polyester acrylate 0 2 5 _ alkyd resin, polyester resin and melamine resin crosslinked Acrylic resin, urea resin, polyisocyanate or epoxy resin. 26 ‘Crosslinked epoxy resin derived from polyepoxide, such as from dioxolan or cycloaliphatic diepoxide. Printed by the Consumer Cooperatives of the Central Bureau of Procurement, Ministry of Economic Affairs (谙 Please read the precautions on the back before filling out this page) 27. Natural polymers, such as venom androgen, rubber, gelatin and their chemically modified derivatives Substances, such as astroxol acetate 'cellulose propionate and astroxol butyrate * or azeloxin ether 1 like methyl_vitamin; and turpentine and its derivatives.

28. Blends (Polyblends) of the above polymers, such as PP / E PDM, Polyamide / EPDM or ABS, PVC / EVA, PVC / ABS * PVC / MBS PC / ABS * PB -29- This paper size applies to China National Standards (CNS > A < t specifications (210X297 mm) 2 "η 7 w WW. N AI B7 V. Description of the invention (i) TP / ABS, PC / ASA-PC / PBT, PVC / CPE, PVC / acrylic resin, POM / thermoplastic PUR, PC / thermoplastic PUR, POM / acrylic resin POM / MBS, PPO / HI PS, PP0 / PA6. 6 and copolymers * PA / HDPE · PA / PP, PA / PPO, PBT / PC / ABS or PBT / PET / PC. Therefore, the present invention also relates to a composition including: A) — organic substances that are sensitive to photo-oxygen and / or thermal damage, and B) — deemed as fixed The present invention also relates to a method for stabilizing an organic substance against light, oxygen, and / or heat damage, including adding a compound of formula (1) as a stabilizer, and a compound of formula (1). Application of Stabilizing Organic Substances The amount of stabilizer used is determined by the stabilized organic substance and its intended use. Generally speaking, this novel composition includes from 0 · 0 1 to 15 parts by weight • Especially from 0. 05 to 10 parts by weight, especially from 0. 1 to 5 parts by weight although stabilizer (ingredient B) / per 100 parts by weight of ingredient (A). Economy Printed by the Ministry of Economic Affairs and Consumer Cooperatives (read the notes on the back and then fill out this page) S fixative (ingredient B) can also be a mixture of two or more novel compounds. In addition to the novel composition, In addition to I stabilizers, other S stabilizers or other additives can also be included * such as antioxidants, other light stabilizers | metal deactivators, phosphonates or phosphonates, examples are the following stabilizers: 1. Aromatizing agent 1.1. Alkylated trophenols, for example, 2,6-di-tert-butyl-1 4 -30- This paper size is commonly used in China National Standard (CNS) A4 (210 × 297 mm) 44960 7 A7 B7 printed by Shelley Consumer Cooperatives of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs 5. Description of the invention (> 1)-methylphenol, 2-butyl-1, 4-dimethylphenol, 2, 6-dione Tert-butyl-4-n-butylphenol, 2,6-di-tert-butyl-4 4-ethylphenol, 2,6_di-tert-butyl-4 4-isobutylphenol, 2 6-dicyclopentyl-4 monomethylphenol, 2- (ct-methylcyclohexyl) -4,6-dimethylol, 2,6-octacosyl-4 monomethylphenol, 2 , 4,6-tricyclohexyl, 2,6-di-tert-butyl-4 monomethoxymethylphenol, 2,6-di-nonyl-4-methylol, 2,4-di Methyl-6- (1-methyl-stilbene-1-yl) cool, 2 * 4 dimethyl-6- (1 * -methylheptadecanyl-1-yl) phenol, 2 * 4 one two one Methyl-6- (1'-methyltridecane-1'-1yl) phenol and mixtures thereof. 1 · 2 alkylthiomethylphenol, for example, 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4-dioctylthiomethyl-6-methylphenol, 2, 4-Dioctylthiomethyl-6-ethylphenol * 2, 6-122 heptylthiomethyl_4_shijiling. 1_3, hydroquinone and its alkylated hydroquinones, for example, 2 * 6_di-tert-butyl-4 4-methoxyphenol, 2,5_di-tert-butylhydroquinone Phenol, 2, di-tert-pentylhydroquinone, 2,6-di ~ phenyl-4-octadecyloxyphenol, 2,6-di-tert-butylhydroquinone, 2, 5-Di-tert-butyl-hydroxyanisole, 3,5-di-tert-butyl-4 "fennel chain * 3,5-di-tert-butyl-4-monohydroxyphenylstearic acid Ester, bis ~ (3,5-di-tert-butyl-4-hydroxyphenyl) adipate. -3 1- This paper size applies to China National Standard (CNS) A4 (2! 0 X 297 mm) ml ^ nn ^ l — ^ n Test-, HH ^ i (please read the precautions on the back before filling this page) Printed by the Central Ministry of Economic Affairs, Consumer Affairs Cooperation, Du η τ Α7 Β7 Five Description of the invention () 1 * 4 Tocopherol m > For example »a — tocopherol ♦ β — tocopherol * Ί — tocopherol δ — tocopherol and its mixture (vitamin E) 0 1 • 5 * hydroxylated thiodiphenyl Ethers »eg i 2 i 2 t — sulfur Bis (6-tert-butyl-4-methylphenol) 1 2 2 »—thiobis (4-octylphenol) t 4 > 4 t 0-thiobis (6-tert-butyl- 3 -methyl) Phenol) 1 4 > 4, thiobis (6-tert- 2-methylphenol) ί 4 t 4 1-thiobis (3 > 6-bis-sec-pentylphenol) 7 4 t 4, — Bis (2 6 —dimethyl- 4 —hydroxy) disulfide 0 1 • 6 • bisphenol i such as 1 2 > 2 t — methylenebis (6 —tert-butyl — 4 monomethyl) Phenol) f 2 1 2, —methylenebis (6-tert-butyl- 4 -ethylphenol) > 2 f 2, methylenebisC 4 —methyl-6 — (a —methylcyclohexyl) Phenol 1 2 T 2, —Methylbis (4-methyl-6-pentanylphenol) > 2 * 2, —Methylbis (6-nonyl-4—methylphenol) 2 9 2 > — Methylene bis (4 * 6-di-tert-butylphenol) i 2 t 2 r-ethylidene bis (4, 6-di-tert-butyl phenol), 2% 2 t-ethylidene from J3Z. ( 6-Uncle — Butyl — 4 — Isobutylphenol) t 2 > 2 t — Methylenebis L 6 — (a — methyl-*-ρ based) — 4 — Nonylphenol »2% 2 t — Methylbis L 6 — (a 1 a —dimethylbenzyl) 4 monoethylphenol 3 1 4 4} —methylenebis (2 i 6 —di-tert-butylphenol) r 4 4 βmethylenebis ( 6-tert-butyl-2-methylphenol) 1 ϊ 1-bis (5-tert-butyl-4 -hydroxy-2 methylphenyl) butane t 2 »6-bis (3 -tert- Butyl — 5 — methyl — 2 — hydroxy) — 4 — methylphenol t 1 t 1 3 di (5 -tert-butyl — 4 -32- (Please read the notes on the back before filling this page ) D-11 Μ This paper size is applicable to China National Standards (CNS) A4 Washing (210X297mm) Printed by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs 449607 A7 B7 V. Description of the invention (p) Monohydroxyl 2- Methylphenyl) butane, 1,1bis (5-tert-butyl-4-hydroxy-1, 2-methylphenylhydrazone), 3-η-dodecylhydrothiobutane, ethyl Diether bis [3,3-bis (3 * -tert-butyl-4'-hydroxyphenyl) butyrate], bis (3-tert-butyl-4-hydroxy-5-methyl-phenyl ) Dicyclopentanyl, bis [2- (3'-tert-butyl- 2'_hydroxy-5'_methylbenzyl) -6-tert-butyl_4-methylphenyl) p-peptidic acid Ester, 1,1-bis (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis- (3,5-di-tert-butyl-4-hydroxyphenyl) Propane, 2,2-bis- (5-tert-butyl-4, hydroxyl-1, 2-methylphenyl), 4-n-dodecylhydrothiobutane, 1,1,5,5 — Tetra- (5-tert-butyl-4-hydroxy2-methylphenyl) pentane. 1.7.0—.N— and S-benzyl compounds, such as 3,5, 3, * 5'-tetra-t-butyl-4,4'-dihydroxy-dibenzylmethyl ether | octadecane 4-methyl-4-hydroxybenzyl hydrothioacetate, tris (3,5-di-tert-butyl-4-hydroxybenzyl) amine, bis (4-tert-one Butyl-3_hydroxy_2,6-dimethylbenzylmethyl) dithio peptidate, bis (3,5-di-tert-butyl-4-hydroxybenzyl) sulfide | Isooctyl-3 * 5-di-tert-butyl-4-hydroxybenzyl hydrothioacetate. 1 · 8 · hydroxybenzyl malonate, such as octacosyl-2,2-bis- (3,5-di-tert-butyl-2-hydroxybenzyl) Sour cool, two-eight octadecyl—2-(3-tert-butyl-1 4_ -33- Chinese standard (CNS) A4 specification (210 X 297 mm), 4 t-- --I Μ, (please read the precautions on the reverse side before filling out this page) 449607 A7 B7 Printed by the Ministry of Economic Affairs of the Zhunzhenzhengong Consumer Cooperative Co., Ltd. 5. Description of the invention (y) Hydroxy-5 -methyl benzyl Radical) monomalonate, dodecylhydrothioethyl-2,2-bis- (3,5-di-tert-butyl-4-benzylbenzyl) malonate , Bis [4-mono (1,1,3,3-tetramethylbutyl) phenyl] -2 * 2-bis (3,5-di-tert-butyl-4-hydroxybenzyl) propane Diester. 1 · 9 'aromatic hydroxybenzyl compounds · For example 1,3,5-tris- (3,5-di-tert-butyl-4-hydroxybenzyl) -2 · 4 * 6-trimethyl Benzyl, 1 * 4-bis (3,5-di-tert-butyl-4-hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2 * 4 < 6-trinyl (3 * 5-di-tert-butyl-4-hydroxybenzylmethyl) phenol 0 1 · 10 · triazine compounds, such as 2,4-bis (octylhydrothio) -6-(3,5- Di-tert-butyl-4 monohydroxyanilino) -1,3,5-triazine, 2-octylhydrosulfanyl-4,6-bis (3 * 5-di-tert-butyl-4) Hydroxy-aniline) -1,3,5-triazine, 2-octylhydrothio ~ 4 * 6-bis (3,5-di-tert-butyl-4-hydroxyphenoxy) -1, 3,5-triazine, 2,4,6-tris (3,5-di-tert-butyl-4 monohydroxybenzyloxy) -1,2,3-triazine, 1,3,5-tris Mono (3,5-di-Sy-butyl_4 monohydroxybenzyl) isocyanurate, 1,3,5-tri- (4-tert-butyl-3-hydroxy-2,6 — Dimethyl benzyl Isofluurate, 2,4,6-tris (3,5-di-tert-butyl-4 4-hydroxyphenylethyl) -1,3,5-triazine, 1,3,5-tris -34 —, Booklet I ^ (Please read the precautions on the back before filling in this page) This paper size applies to China National Standards (CNS) A4 (2! 〇 × 297 mm). Industrial and consumer cooperation Du India 44960 7 Α7 Β7 V. Description of the invention (θ)-(3,5-di-tert-butyl-4-hydroxyphenylpropionamidine) hexamethylene-1,3,5-triazine , 1,3 * 5 —tris (3,5 -dicyclohexyl-4 monohydroxybenzyl) isourethane. 1 · 1 1 · benzylphosphonate, for example, dimethyl-2,5-di-tert-butyl-4 monohydroxybenzylphosphonate, diethyl_3, 5-ditert —Butyl-4—hydroxybenzyl phosphonate, octacosyl 3,5 1,2-tert-Butyl-4 4-hydroxybenzylmethyl phosphonate, octacosyl—5-tert- Calcium hydrazone of the monoethyl ester of butyl-1,4-hydroxy3-methylbenzyl monophosphonate, 3,5-di-tert-butyl-1,4-hydroxybenzyl monophosphonic acid. 1 · 1 2 · fluorenylaminophenol * For example, 4-monohydroxy 醯 lauryl tifenamine, 4-hydroxystearate tetiphenylamine, octyl-N — (3,5 —di-tert-butyl-4 —Hydroxyphenyl) carbamate. 1 · 1 3 β — (3,5 —di-tert-butyl — 4-merylbenzyl) propionic acid and mono- or poly-hydroalcohol esters, such as formazan, ethanol, stearyl, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol Diol, Pentaerythritol, Tris (hydroxyethyl) isouronic acid ester, N, N'-bis (hydroxyethyl) ethylenediamine diamine, 3-thiaundecanol, 3-thia Pentadecanol, trimethylhexanediase, tris-methyl-propane, 4-monohydroxymethyl-1 -phosphorus-2,6,7-trioxabicyclo [2.22] octane. 1 1 4 · > 3-(5-tert-butyl-4-hydrocarbyl-3-methylbenzene-3 5-This paper uses the Chinese National Standard (CNS) grid (210 × 2ί &7; 7 mm) ( (Please read the notes on the back before filling out this page)

A 449607 A7 B7 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 5. Description of the invention (A) Ester of propionic acid and single or polyhydric alcohol, such as, and methanol, ethanol, stearyl alcohol, 1, 6 _ Hexanediase, 1,9-nonane-diol, ethylene glycol, 1,2-propanediol, neopentyl diase, thiodiethylene glycol, diethylene glycol, triethylene glycol , Pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N'-bis- (hydroxyethyl) ethylenediamine diamine * 3-thiaundecanol, 3-thiadecyl alcohol Pentanease, trimethylhexanediase, trimethylolpropane, 4-monomethylol-1-phosphorus-2,6,7_trioxane [2 · 2 · 2] octane. 1 · 1 5 · / 3-(3,5-dicyclohexyl-4 monohydroxyphenyl) propionic acid and mono- or polyhydrogenated esters, such as and methanol, ethanol, stearyl alcohol, 1, 6 _Hexanediol, 1,9-nonane di-enzyme, ethylene di-enzyme, 1, 2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylfluorene glycol, triethylene glycol , Pentaerythritol, tris (hydroxyethyl) isocyanurate, Ν, Ν'-bis (hydroxyethyl) ethylenediamine diamine, 3-thio +-alkanol, 3-thiopentadecane Alkanol, trimethylhexanediol, tri-methyl alcohol propane, 4-hydroxymethyl-1 phosphorous 2,6,7-trioxabicyclo [2-2'2] octane. 1 · 16 · 3,5-di-tert. Monobutyl-4-hydroxyphenylacetic acid and mono- or polyhydric alcohols * such as formazan, ethanol, stearyl alcohol * 1, 6-hexane Diols, 1,9 monodecanediol, ethylene glycol, 1,2 propanediol * neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol | pentaerythridine Tetraol, Tris (Hydroxyethyl) isocyanurate, N, N'-Bis (Hydroxy-ethyl) Ethylene Diamine Diamine, 3 —phae + — -36- This paper is a standard Chinese national standard. Standard (CNS) Α4 specification (2Ι0χ 297 mm) (please read the precautions on the back before filling out this page), 1T 449607 Printed by the Central Government Bureau of the Ministry of Economic Affairs and Consumer Cooperatives Β7. V. Description of the invention (W) Alkalase, 3-sialpentadecanol, trimethylhexanediase * trimethylase, 3-hydroxymethyl-1, 1-phospho-2, 6, 7, 7-trioxabicyclo [2 · 2 · 2] octane. 1 · I 7 'β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate, such as N > N'-bis (3,5-di-tert-butyl- 4-Hydroxyphenylpropylammonium) hexamethylene diamine, Ν | Ν 'one bis (3,5-di-tert-butyl-4 4-hydroxyphenylpropylammonium) trimethylenediamine, Ν Ν 1 bis ( 3,5-di-tert-butyl-1, 4-hydroxy-phenylpropionamidine) hydrazine · 1'18 * ascorbic acid (vitamins < 3) 1 · 19 'amine antioxidant * For example, Ν, Ν' -dione Isopropyl-ρ -phenylene diamine, Ν, Ν '-bis-sec-butyl-ρ-Benzene diamine, Ν, Ν'-bis (1,4-dimethylpentyl) -P- Phenylenediamine Ν Ν / One bis (1 ethyl-3-methylpentyl) -ρ-phenylene diamine, Ν, Ν'_bis (1-methylheptyl) _ρ —phenylene diamine , Ν · Ν / —dicyclohexyl-ρ—phenylene diamine, Ν, Ν′—diphenyl—ρ_phenylene diamine, Ν, Ν′—bis (2-naphthyl) —ρ_phenylene Diamine, N-isopropyl-N'_phenyl-ρ-phenylene diamine, N- (1,3-dimethylbutyl) -N'-phenyl_ρ-benzene Diamine, N- (1-methylheptyl) -N'-phenyl-ρ-phenylene diamine, N-cyclohexyl-N'_phenyl-ρ-phenylene diamine, 4- (P- Tosylsulfonium) mono-diphenylamine, N * N'-dimethyl-N, N'_di-sec-butyl-ρ-phenylene diamine, diphenylamine * N-allyl diphenyl Base amine-37- This paper size applies to China National Standard (CNS) A4 (2Ι0 × 297 mm) -I mi I — ^ 1 {m · HH --- ί · ^^^ 1 I. 4 i 夂 ( Please read the precautions on the back before filling this page) 449607 A7 B7 V. Description of the invention (β) (Please read the precautions on the back before filling out this page), 4—Isopropoxydiphenylamine, N —Phenyl-1-naphthylamine * N-(4-tert-octylphenyl)-1-naphthylamine, N-phenyl-2naphthylamine, octylated diphenylamine, such as P , P'-di-tert-octyldiphenylamine, 4-a-butylaminophenol, 4-monobutylaminophenol, 4-nonanaminoaminophenol, 4-dodecylaminophenol, Octadecylaminophenol > bis (4-monomethoxyphenyl) amine * 2,6-di-tert-butyl-4-dimethylamino Phenylphenol, 2,4'-diaminodiphenyl * methane, 4 4'-diaminodiphenylmethane, Ν, Ν, Ν ', Ν'-tetramethyl-4,4'-diamine Diphenylmethane, 1,2-bis [(2-methylphenyl) amino] ethane, 1 | 2-bis (phenylamino) propane, (0-tolyl) biguanide, bis [4- — (1 /, 3'-dimethylbutyl) phenyl] limb | tert-octyl N-phenyl-1-naphthylamine > mono- and dialkylated tert-butyl / Tert-octyl dibenzyl amines, mono- and dialkylated nonyldiphenylamine mixtures, single and dialkylated dodecyldiphenylamine mixtures | mono- And dialkylated isopropyl / isohexyldiphenylamine mixtures, single and dialkylated tert-butyldiphenylamine mixtures, 2,3-dihydro-3,3-dimethyl-1 4Η—1,4-benzoxazine, phenazine * mono- and dialkylated tert-butyl benzene printed by the Ministry of Economic Affairs Bureau of Peugeot Consumer Cooperatives / tert-octylphenazine mixture I Mono- and dialkylated tert-octylpanthiazine mixture, N-allylphenothiazine, N, N, N ', N tetraphenyl -1,4-diaminobut-2-ene * N, N-bis (2, 2, 6, > 6-tetramethylmonopyridine-4 4-yl-hexamethylenediamine * bis (2, 2,6,6 -tetramethyltonidine-4 -yl) sebacate * 2 * -38- Chinese standard rubbing (CNS) A4 size (210X 297 mm) 449607 A7 B7 5 4. Description of the invention (4) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 2 * 6 1 6 — Tetramethylpiperidine — 4 — m »2 2» 6 »6 _ Tetramethylmorphine — 4 — Alcohol. 2 • UV absorber and light stabilizer 2 • 1 2 — (2 > — hydroxyphenyl) benzotriazolyl, for example% 2 — (2 f — hydroxy — 5 > monomethylphenyl) — benzene Benzyl radical 2 — (3 t, 5, — di-tert-butyl — 2 f — hydroxyphenyl) benzotriazolyl 1 2 — (5 9 — tert-butyl — 2 f — hydroxypenyl ) Benzotriazolyl 1 2 — (2 t — hydroxy — 5 t — (1 1 1 1 3 I 3 — tetramethylbutyl) benzyl) benzo — triazolyl 1 2 — (3 9 > 5 * — di-tert-butyl- 2-hydroxyphenyl)-5 -aza-benzotriazolyl) 2 — (3 f mono-tert-butyl- 2 * —hydroxy — 5 r —methylphenyl) — 5 —chloromonobenzodiyl 2 — (3 —sec-monobutyl — 5 I — tert-butyl 2 t —hydroxyphenyl) benzotriazolyl i 2 — (2, -hydroxy-4-octyloxyphenyl) benzotriazolyl 1 2 — (3; hydrazone 5, —di-tert-pentyl-2 # —hydroxyphenyl) benzotriazolyl t 2 — (3 ti 5 > — bis— (α ja —dimethylbenzyl) — 2 »— hydroxybenzyl) benzotriazolyl) 2 — (3,-tert-butyl — 2 t — hydroxy — 5 > — (2 -octyloxycarbonylethyl) phenyl) — 5 -chloro-benzotriazolyl »2-(3, —tert-butyl — 5» — [2-(2 — Ethylhexyloxy) —Ethyl] — 2, —Hydroxyphenyl) — 5 —Chloromonobenzotrivalene t 2 — ( 3 > — tert-butyl — 2 t — hydroxy — 5 > — (2-methoxycarbonylethyl) phenyl) — 5 — chlorobenzodiazolyl t 2 one (3 * one tert-one Butyl-1, 2-hydroxyl—5, 1-39- (Please read the notes on the back before filling out this page) This paper size is applicable to China Standards (CNS) A4 format {210X297 mm) 449607 A7 B7 Economy Printed by the staff of the Ministry of History and Economic Affairs of the Fifth Cooperative, V. Description of the invention Ui) (2-methoxycarbonylethyl) phenyl) benzotriazolyl, 2- (3 * -tert-butyl-1 2 ' Monohydroxy-5 '-(2-octyl-oxycarbonylethyl) phenyl) benzotrifluorenyl, 2- (3'-tert-butyl-5'-C 2-(2-ethylhexyloxy ) Furylethyl] _2'-hydroxyphenyl) benzotriazolyl, 2 ~ (3 # dodecyl-2'-hydroxy-5'-methylbenzyl) benzyl-triazolyl, And 2- (3'-tert-butyl-Z, -hydroxy-5 '-(2-isooctyloxycarbonylethyl) phenylbenzotriazolyl 2,2'-methylene-bis [4- (1,1,3,3-tetramethylbutyl) 6 —A mixture of benzotriazolyl-2-ylphenol]; 2 [3 * mono-tert-butyl-5 ′-(2-methoxycarbonylethyl) _2 ′ —hydroxy-phenyl] -2H — Cool product of benzotriazolyl and polyethylene dienzyme 300; [R — CHz CH2-C0 0 t C Η 2) 3], where R = 3 '-tert-butyl- 4'-hydroxyl _5 '— 2H ™ benzotriazolyl-2-ylphenyl. 2.2. 2-hydroxybenzophenone, for example, 4-hydroxy, 4-monomethoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2 ', 4'-trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives. 2 · 3 · Esters of substituted or unsubstituted benzoic acid | such as 4-tert-butyl-phenyl salicylate | phenyl salicylate, octylphenyl salicylate, dibenzoyl醯 Resorcinol, bis (4-tert-butylbenzidine) resorcinol, stupid methyl-resorcinol, 2,4_di-tert-butylphenyl 3,5-di-tert-one Butyl-1, 4-hydroxybenzoic acid, hexadecyl 3, 5_21, 4 0-(Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) 449607 A7 B7 Printed by Zhengong Consumer Cooperative of the Central Bureau of the Ministry of Economic Affairs 5. Description of the invention (w) tert-Butyl-4-hydroxybenzoate, octadecyl 3,5-di- Tert-butyl-4-hydroxybenzoate, 2-methyl-4,6-di-succinyl-butylphenyl 3,5-di-tert-butyl-4-hydroxy-benzoate 0 2-4. Aromatic esters, such as ethyl α-cyano- / 3, di-diphenyl acrylate, isooctyl cyano-mono, dot-di-phenyl acrylate, methyl ot-carbamate Oxycinnamic acid, methyl α-cyano-1 / ?, 3 Methyl-p ~ methoxy-cinnamate, butyl-alpha-cyano, dot-methyl-P-methoxy-cinnamate, methyl-alpha-carbomethoxy-P-methoxy Cinnamate and N-(/ 3-Carboxymethoxy- / 3-cyanovinyl) ~ 2-methyloxindole. 2.5, spicy compounds. For example, 2, 2, 1-thio-bis-one [4-((1, 1, 3, 3-tetra-methylbutyl) phenol] nickel complex] such as 1: 1 or 1: 2 Complex with or without additional reactive groups * like η-butylamine, triethylenamine or η-cyclohexyldiethylenamine, nickel dibutyldithiothiocarbamate, 4-monohydroxy _3,5_Di-tert-butyl fluorenyl knee acid monomonoxide, such as methyl or ethyl acetate, 嗣 fl bow mirror complex, such as 2-hydroxy-4 monomethylbenzene Undecyl oxime, 1-benzyl-4- 4-laurate, 5-hydroxypyrazolyl nickel complex * with or without additional reactive groups. 2. 6. Sterically hindered amines, such as bis (2,2,6,6-tetramethylmonopiperidinyl) sebacate, bis (2,2,6,6-tetramethyl) 1-methylpyridinyl) succinate, bis, -4 1-(Please read the notes on the back before filling this page) Order Λ This paper size is applicable to China National Standard (CNS) AOJL grid (2I〇X2M Mm}? ^ 44960 7 A7 B7 printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy , 2,2,6,6-Pentamethylbenzyl) η-butyl-3,5-di-tert-butyl-4 4-hydroxybenzyl malonate, 1- (2-hydroxyethyl ) -2,2,6,6-tetramethyl-1,4-monohydroxypyridine succinic acid concentrate, N, N, bis (2,2,6,6-tetramethyl-1 4- # pyridine Group) hexamethylene diamine and 4 mono-tert-octylamino-2,6-dichloro-1,3,5-triazine, tri- (2 * 2,6,6-tetramethyl-1 4 — Acryl) * four (2, 2, 6, 6-tetramethyl-4, piperidinyl)-1, 2, 3, 4- Alkane-tetracarboxylic acid ester, 1,1,-(1,2-ethanediyl) bis (3,3 < 5,5-tetramethylpiperazinone), 4-benzylhydrazine-2, 2, 6,6-tetramethylpiperidine, 4-monostearyloxy-2,2,6,6-tetramethylpiperidine • bis (1,2,2,6,6-pentamethylmethylpyridine Group)-2-η-butyl-2-(2-hydroxy- 3,5-di-di-tert-butylbenzyl) malonate, 3- η -octyl-7, 7, 9, 9 —Tetramethyl-1,3,8-triazaspiro [4'5] decane-2,4-dione, bis (1-octyloxy ~ 2, 2 > 6 * 6-tetraone Methylmeridinyl) sebacate, bis (1-octyloxy-2,2,6,6-tetramethylpiperidinyl) succinate, N, ls ^ -bis- (2,2,6,6-tetramethyl-4 piperidinyl) hexamethylene diamine and 4-morpholino_2,6 dichloro-1,3,5-triazine , 2 -Chloro ~ 4 * 6 -bis (4-a-n-butyl-amino-2,2,6,6-tetramethylpiperidinyl) -1,3,5-triazine and 1 < 2 —Bis (3-aminopropyl-42- China National Standards (CNS) 6 4 * See grid (210 × 297) (please read the notes on the back before filling out this page) Order A7 44960 7 B7 V. Description of Invention (u) Ethoxyl Group 1 Concentrate, 2-Gasto-4,6-dione (4- η-Butyloxy_1, 2, 2 * 6 * 6-Pentamethyltonpentyl) (please read the note on the back first) Please fill in this page again for matters) — 1, 3, 5-triazine and 1, 2-bis (3-aminopropylamino) ethane, 8—ethenyl—3-dodecyl-7, 7 , 9,9-tetramethyl-1,3,8-triazaspiro [4'5] decane-2,4-difluorene, 3-dodecyl-1- (2,2,6 * 6-tetramethyl-4-pyridinyl) [ftrolidine-2,5-di-, 3-dodecyl-1- 1- (1,2,2,6,6-pentamethyl-1 4 1 (Ninidyl) a mixture of pyrrolidine-2,5-difluorenyl, 4-hexadecyloxy and 4 octadecyloxy-2 * 2,6,6-tetramethylpyridine, N, N '—Bis (2,2 | 6,6_tetramethyl-1, 4-meridinyl) hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-1 Condensation products of 3,5-triazine, 1,2-bis (3-aminopropylamino) ethane and 2 * 4,6-trichloro-1,3,5-triazine and 4-monobutyl Condensation product of amino-2,2,6,6-tetramethylpyridine (CAS Reg. No. [1 3 6 5 0 4-9 6 -6]); N — (2, 2, 6, 6, 6 —Tetramethyl-1, 4-piperidinyl) -n-dodecylbutanediimide, N — ί 1 * 2 '2 * Printed by Shellfish Consumer Cooperative, Central Sample Bureau, Ministry of Economic Affairs Methyl-1, 4-Pyridinyl) _n-dodecylbutanediimide, 2-undecyl-7, 7, 9, 9, 9-tetramethyl-1_cycloundecyl-1 Monooxa-3,8-diazol-4-oxospiro [4,5] ~ \-alkane and epichlorohydrin. 2 7 · Ethylenediamine diamine, such as 4,4'-dioctyloxyoxoaniline, 2 > 2, -dioctyloxy ~ 5,5,1,2-tert-butoxy-4 3 -Standards of this paper: National Standards (CNS) Α4 size (210 X 297 mm) 449607 Α7 Β7 Duplicate work and consumption cooperation of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (d) Tifenidine, 2,2,2-docosalyloxy-5,5 * -di-tert-butoxyfluorenilanilide, 2-ethoxy-2'-ethoxyfluorenilanilide f N · N * -bis ( 3-Dimethylaminopropyl) ethylenediamine diamine, 2 monoethoxy-5'-tert-butyl-1 2'-ethoxyfluorethiline and its 2 ethylethoxy-2, ethyl A mixture of 5,4 't-butoxy-butoxyaniline * and a mixture of o- and m-methoxydisubstituted oxotetanil, and 0- and P-ethoxy-disubstituted Oxytepin aniline. 2.8.2 — (2-hydroxyphenyl) -1,3.5-triazine, such as 2,4,6_tri- (2-hydroxy_4-octyloxy-phenyl) -1,3, 5-triazine * 2-(2-hydroxy_4-octyloxyphenyl)-4 * 6-bis (2,4-dimethylbenzyl)-1,3,5-triazine, 2- (2 < 4-dihydroxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine. 2,4 ~ bis 2 -hydroxyl-4- Propyloxyphenyl) ™ 6_ (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4 monooctyloxyphenyl: 1-4 6_bis (4-monomethylphenyl) -1,3 > 5-triazine, 2- (2 ~ hydroxy-4 ~ dodecyl monooxyphenyl)-4,6-bis (2, 4-Dimethylphenyl) -1,3,5-triazine, 2- [2-hydroxy_4-mono (2-hydroxy-3 -butyloxy-propoxy) phenyl]-4 * 6 — Bis (2 * 4-dimethyl) -1 > 3 · 5-triazine, 2- [2-hydroxy-4 — (2-hydroxy-3—octyloxy-propyloxy) phenyl] 1 4 < 6 -bis (2,4-dimethyl) -1, 3, 5 —Sanxiao, 2 — 〔4 One (12 House Oxygen / + Three-44-This paper is free to use Chinese sample rate (CNS) Α4 size (210X297 mm) (Please read the precautions on the back before filling (This page) .4 49 60 7 Α7 Β7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (alkoxy-2 -hydroxypropoxy) _2 -hydroxy-phenyl] -4,6 a double ( 2 * 4-Dimethylphenyl) -1,3,5-triazine, 2- [2-hydroxy-4— (2-hydroxy-3—dodecyloxy-propoxy) phenyl] -1 4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine * 2-(2-hydroxy-4 4-hexyloxy) phenyl-4, 6-diphenyl-1 , 3,5-triazine, 2- (2-hydroxy-4 monomethoxyphenyl) -4,6-diphenyl-1,3,5-triazine, 2 * 4,6-tris [2 _Hydroxy-4— (3-butoxy—2-hydroxy-propoxy) phenyl] —1,3,5-trimethyl, 2— (2-hydroxyphenyl) —4— (4-methoxy Phenyl) -6-phenyl-1,3,5-trifluorene, 3 · metal deactivators, such as Ν, Ν'-diphenyl Ethylene bisamidine limbs, Ν_salicyl-salicylidene M, N, N'_bis (salicyl) hydrazine, Ν, Ν, bis (3,5-di-tert-butyl-4-hydroxy) Phenyl-propionamidine) hydrazine · 3-salicylamidoamino-1,2,4, triazole, bis (benzylidene) ethylenedihydrazine, hydrazine, dihydrazone, panteanilide, isopeptidyl , Bishydrazine, sebacylbisphenylhydrazine, Ν * Ν 'di-ethenylhexamethylene dihydrazide, N, N'-bis (salicyl) ethenyldihydrazide, Ν * Ν '—Bis (salicyl) monothiopropionate dihydrazine. 4 · Phosphonite and Phosphonic Acid S · For example triphenylphosphite blue, dibenzylalkyl phosphite, phenyldialkylphosphonium phosphonium, tri- (nonylphenyl) phosphite S, trilauric acid Bisphosphite, trioctadecylphosphite, di-45- This paper method applies the Chinese national standard (CNS > Α4 size (2ΙΟ × 297)) (Please read the precautions on the back before filling this page) Α. 1- ° ^ 49 8 0 7 Α7 Β7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 5. Description of the invention (θ) Stearyl pentaerythritol diphosphite 三 *-(2, di-tertiary Mono (* butylbenzyl) phosphite > diisodecylpentaerythritol diisophthalate, bis (2,4,1,2-tert-butylphenyl) pentaerythritol Phosphonium phosphate * bis (2, S-di-tert-butyl-4-methylbenzyl) phosphonium pentaerythritol diphosphite, diisodecyloxypentaerythritol diphosphite, Bis (2 < 4-di-tert-butyl- 6-methylphenyl) pentaerythritol tetrasodium diphosphite, bis (2,4,6-tri- (tert-butylphenyl) Pentaerythritol diisophthalic acid | Tristearyl sorbitol triphosphite monitor, four (2,4 one two one t-butyl phenyl) 4,4 'one biphenylene diphosphonic acid 6 -isooctyloxy-2, 4 , 8,1 0—tetra-t-butyl- 12H-diphenyl [d, s] -1,3,2-dioxophosphate, 6-fluoro_2,4,8,10—tetra-one-tert-one Butyl-12 methyl-diphenyl [d, g] — 1,3,2-dioxophosphate, bis (2,4-di-tert-butyl-6-methylphenyl) methyl phosphite * Bis (2,4-di-tert-butyl-6-methylphenyl) ethyl phosphite M. 5 · Hydroxyamine, such as N, N-dibenzylhydroxyamine, N, N-di Ethylhydroxylamine, N, N-dioctylylamine < N, N-dilaurylhydroxylamine, N, N-di (tetradecyl) hydroxylamine, N, N-di (hexadecane) ) Hydroxyamine, N, N-bis (octadecyl) hydroxyamine, N-hexadecyl-N -octadecylhydroxyamine, N -dodecyl = alkyl-N -octadecylhydroxy Amines, N, N-dialkylhydroxylamines from hydrogenated tallowamine, 06-nitrones, for example, N-benzyl-phenyl-nitrone, N- Base-46-Standards for this paper (CNS) Α4 size (ί οχ 297 mm) —. ^ Order I · ν (Please read the notes on the back before filling this page) 44960 7 α7 Α7 Β7 Imprint of the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (π)-a-methyl mononitrone, N-octyl-σ-heptyl mononitrone' N-lauryl a-!! --Amino-nitronitone 'N —h Siyuanji—α_tridecyridyl ~ nitropyrene, Ν ′ ~ * hexadecyl hexyl-1—pentadesyl-nitronitrate, Ν—octadecyl One α-seven-base group-nitrate 'N— + hexasyl-α-h seven-aid-base-nitrate, N-eighteen-base-one-α-fifteen-base-nitrate * N—seven Alkyl-α-heptadecanyl-nitronitrate, N-P octaalkyl ** α-V hexaalkyl-nitrone, derived from N, N-dialkylhydroxylamine of hydrogenated tallowamine Alas. 7. A halogenated synergist, for example, dilaurylthiodipropionate or distearylthiopropionate. 8. Suitable oxide cleaners, such as esters of 10,000-thiodipropionic acid * such as lauryl, stearyl, tetradecyl or tridecyl esters'hydrothiobenzimidazolyl or 2-hydrofluorenyl Benzozole's zinc union * zinc dibutyl dithiocarbamate 'octadecyl disulfide, five erythridine tetrazolium four (dot_dodecyl fithio) propionate union. 9 * Polyamine spike fixatives * For example, phosphonium salts combined with iodide and / or phosphorus compounds, and divalent manganese amidines. 1 0. Basic co-elixir, for example, melamine * polyvinylpyrrolidone, DM difluorene, tri-allyl fluorouric acid ester, urea derivative 1 hydrazine derivative, amine, polyamidoamine, polymer Urethane * Alkali metals or alkaline earth metals with higher fatty acids • For example, calcium stearate, zinc stearate, magnesium succinate, magnesium stearate, sodium methalate and potassium hexadecanoate, joule Antimony tea acid or tin catechin. 1 1 Nucleic acid agents, for example, inorganic substances, such as talc, metal oxides * -4 7- n I ^ nn 1111 · ^ I- ^, (Please read the notes on the back before filling this page) National Standards (CNS) A4 (210 × 297 mm) / 49607 V. Description of the invention (d) Magnesium oxide, phosphate, europium carbonate or europium sulfate, such as europium dioxide or a better alkaline earth metal; there are europium compounds, Like mono- or polycarboxylic acids and their baskets, such as 4-tert-butyl benzyl, adipic acid, diphenylacetic acid, sodium succinate, or sodium benzoate; polymeric compounds, such as ionic copolymers (Ionomers) 〇1 2, fillers and reinforcements, such as calcium carbonate, silicic acid, glass sickle, asbestos, talc • high-sensitivity clay, mica * barium sulfate, gold tin oxide and hydroxide, Carbon black * graphite, powder of wood or other natural products, or powder, synthetic Panve 1 3. Other additives, such as plasticizers, lubricants, emulsifiers, colorants, flow additives, catalysts, flow control agents, optical brighteners, fire retardants, antistatic agents, and blowing agents. 1 4. Benzofuran pyrene and indene, for example, described in US-A-4,325,863; US-A- 4,3 3 8,244, U S-A-5, 1 7 5, 3 1 3; US-A -5, 2 1 6, 0 5 2, US-A-5, 2 5 2, 6 4 3, DE-A-4, 3 1 6, 6 1 1; DE-A- 4,3 1 6,6 2 2; DE-A- 4,3 1 6,8 7 6; EP-A-0,5 8 9,8 3 9 or EP-A-0,591,102 or 3 — [4— (2 —ethoxyloxyethyl (Oxy) phenyl] ~ 5,7-di-sy-butyl-benzyfuran-2 —_, 5 'Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (Please read the precautions on the back before filling this page ) 7-Di-tert-butyl_3-[4-(2-Stearylethoxyethyl) phenyl] benzofuran-2 -fluorene, 3,3'-bis [5,7 -di Monobutyl-3- (4-([2-hydroxyethoxy] phenyl) benzylfuran_2_one], 5,7-di-tert-butyl- (4-ethylaminophenyl) Benzofuran-2-one, 3 — (4-Ethoxyl 3 '-4 8 1 Paper Size Quick Use China National Standard (CNS) A4 Specification (210X297 mm) 44960 7 A7 B7 IL * V. Description of the invention (5-dimethylphenyl) -5,7-di-tert Butyl-benzofuran ~ 2-m '3-(3,5 -dimethyl-4 -trimethylacetamidooxy) -5,7 -di-sylobutyl-benzofuran-2- Ketones. The type and amount of other stabilizers added are based on the type of substrate being stabilized and its intended use; generally from 0 to 5% by weight (depending on the polymer being determined). This novelty The post-fixing agent is particularly advantageous in which component (A) is a synthetic organic polymer, especially a thermoplastic polymer, a binder for a coating, such as a coating, or a composition of a photographic substance. Entangled thermoplastics The polymer is 1, for example, a polyolefin and a polymer containing a hetero atom on the main core. A preferred composition is that the component (A) is a heat-resistant polymer and contains nitrogen, oxygen and / or sulfur on the main core , Especially nitrogen or oxygen. Compositions in which component (A) is polyolefin, such as polyethylene or polypropylene, are also advantageous. Addition to organic polymers, such as synthetic organic * especially thermoplastic polymers, can be industrially traditional Add this new compound or any other additive. Add Can be easily carried out prior to forming or during shaping, for example, mixing and grinding ingredients, or stabilizer is added to the melt or solution of the polymer, or the compound is dissolved or dispersed in the polymer, if desired, followed by evaporation of the solvent. In the case of elastomers it can be set in the form of a latex. Another method of adding this novel compound to the polymer includes adding it before or at the same time as polymerizing the equivalent army, or before crosslinking. -49- The paper scale is free to use Chinese National Standard (CNS) A4 Washing (210X297 mm) (Please read the notes on the back before filling out this page) " Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ¾ 449607 A7 B7 Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs. 5. Description of the invention (d) The mixture of this new compound can also be added to the plastic to be stabilized. • Including these compounds M * For example Add from 2.5 to 25% by weight. This novel mixture can be easily added in the following ways:-as a milk wetting or dispersion (for example in a latex or emulsion polymer)-when mixing other ingredients or polymer mixtures as a dry mixture * direct Add to processing equipment (eg, extruder's internal mixer, etc.)-as a solution or melt. The stable polymer composition obtained by this method can be transformed into shaped articles such as fibers, films, ribbons, layers, sandwich plywood, containers, tubes, and other rotating materials such as heat Compressed, spun, extruded or shot into a shot. Therefore * the present invention is further related to the use of this new polymer composition in the preparation of shaped articles. It is also advantageous to apply to multilayer board systems. In this case, a stabilizer of formula I having a relatively high content, such as 15% by weight, although a percentage of a new aggregate survey composition tree is applied as a thin film (10 * ~ 100iim) and coated with a small amount or no Stabilized polymers of formula I on shaped articles. This application can be carried out at the same time as the basic structure is being shaped, such as co-extrusion. However, this application can also be carried out when the basic structure is ready to be shaped, such as by lamination with a film, or coating with a solution. The outer layer of the finished item has UV-if -50-(Please read the precautions on the back before filling in this f). 4- The paper scale is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 44960 7 A7 B7 V. Description of the invention (u) The function of the device, which can protect the inner articles from the damage of UV rays. The outer layer preferably contains from 5 to 15% by weight of children, especially from 5 to 10% by weight of at least the formula I tinting agent. K The polymer determined by this method has a high degree of weather resistance, which is different from the resistance of the U V vehicle. This allows it to retain its mechanical properties and its color and gloss even after a long period of outdoor use. It is also particularly advantageous to use this novel mixture comprising a compound of formula (1) as a coating dwelling agent, such as a coating. Therefore, the present invention also relates to a composition in which component A is a film-forming adhesive. The new coating composition preferably contains 0.001 to 10 parts by weight of B, especially 0.05 to 10 parts of resuspended B, especially 0.1 to 5 parts by weight of B ( A) per 100 parts by weight. Here the multilayer system can also have a higher concentration of the compound of formula I (component B) in the outer layer, for example * from i to 15 parts by weight of B, especially from 3 to 10 parts by weight, B (per 100 parts Weight of solid adhesive A) Printed by the Central Samples Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives (please read the precautions on the back before filling this page) The application of this novel bonding agent in coatings has other preventable delaminations Advantages such as peeling off the coating from the base board. This advantage is particularly important in the case of metal substrates containing multiple layers of metal substrates. Adhesive (ingredient A) is mainly any adhesive commonly used in industry, such as those described in UlUann's Encyclopedia of Industrial Chemistry, 5th E d n., Vo 1. A 1 8, pp · 3 6 8-4 2 6, VCH , Weinheint, 1991. Generally speaking, this is based on thermoplastic or thermosetting resin-5 1- The standard of this paper is applicable to the Chinese National Standard (〇 阳) 6 4 specifications (210/297 mm) A7 f 449607 B7 V. Description of the invention (Please) (Please read the notes on the back before filling this page) The film-forming adhesive I based on the film is mainly based on K thermosetting resin. Examples are enzyme resins | acrylic, polyester, phenol, melamine, epoxy and polyamino Ethyl formate resin · and mixtures thereof. The component (A) can be a cold-hardenable or hot-hardenable adhesive, and it is advantageous to add a hardening catalyst therein. The catalyst suitable for accelerating the hardening of the adhesive is described in, For example, Ullmann's Encyclopedia of

Industrial Chemistry, V o1. A 18, p. 4 6 9, V C H

Verlagsgesellschaft, tfeinhein, 1991 ° The preferred coating composition is one in which the component (A) is an adhesive containing a functional acrylic resin and a crosslinking agent. Examples of coating compositions containing specific adhesives are: 1. K cold- or heat-crosslinked enzyme resins, acrylic resins, polyesters, epoxy or melamine resins, or coatings based on these resin mixtures, may Appropriately add a hardening catalyst; 2. Two-component polyurethane coating based on hydroxy-acrylic resin> polyester or poly-resin and fatty or aromatic polyisocyanate; Central Ministry of Economic Affairs Printed by the Office of Consumer Cooperatives 3. Polyurethane, a component based on block polyisocyanate, which will release the block during baking; 4. M (poly) ketimine and fatty hydrazone or aromatic Polyisocyanate-based two-component coatings; 5. Two-component coatings based on (poly) ketimine and unsaturated acrylic resins or polyethylene glycol acetate resins or methacrylaminoglycolates物 r -52- This paper size is applicable to Chinese National Standards (CNS) A4 size {210X297 mm) 4 49 60 7 A7 B7 V. Description of the invention (punch) 6 · M containing carboxyl- or amino polyacrylate and poly Epoxy-based two-component coating; (Please read the precautions on the back before filling this page) 7 · M two-component coatings based on acrylic resin containing anhydride and a polyhydroxy or polyamine-based component; 8 · (poly) oxazole and anhydride -Two-component coating based on acrylic resin or unsaturated acrylic resin, or fatty resin or aromatic polyisocyanate; 9. Two-component coating based on unsaturated polyacrylic resin and polymalonate 10. Thermoplastic polyacrylate coatings based on thermosetting acrylic resins or acrylic resins crosslinked with etherified melamine resins respectively; 1 1, acrylic modified with siloxane or fluorine-modified An acid resin-based coating system. In addition to the components (A) and (B), the coating composition of the present invention preferably contains (as component C) a photo stabilizer, such as a sterically hindered amine and / or 2-hydroxyphenyl_2Η_ Compounds of the benzotriazole type · For example, those mentioned in the above items 2.1 and 2.6. In order to obtain the best photostability of the Central Bureau of Standards, the Ministry of Economic Affairs, the Shellfish Consumer Cooperative, printed the product B, 〇f 〇, amines and agents}} A fixed amine position A, stable light amines 6% amines Bit-2 except body 6 is the first _ _ described, of the 6 things} ': on the C 2 base such as the group t, the addition of the group coverage 2 is the formula is a work under the Dangjia Yiliguan There are few and also agents containing special agents, which must be specified separately, including the original, the original and the other}, the paper size is in accordance with the Chinese National Standard (CNS) 戍 4 grid (210X297 mm) 449607 A7 B7 V. Invention description (d)

(HALS-II)

The Ministry of Economic Affairs 'Cardholders' Association Consumer Employees Cooperative Co., Ltd. where G is hydrogen or methylr. Special ingredient (C) is better to use 100 parts by weight of solid viscous energy as ingredient (C). Ep-A -3 56,677 9 P ag es 3 A — The paragraph in the patent is deemed to have been derived using the following four-house Keatyridine-derived double (2, 2 »6 t 6 — four double (2 t 2 1 6 t 6 — Quadruple (1 t 2 i 2 * 6 i 6 Cool I < 1 i 2 1 2 1 6 t 6 3 5 — — — — — Butyl — Bis (1 — Octyloxy 2 y 2 (HALS- 川) Is hydrogen. The amount is 0. 05-5 parts by weight (based on the agent). Examples of tetraalkylpyridine derivatives are described in paragraphs -17, a) to f). This EP-part of the invention .It is particularly convenient to use methyl-pyridine-4-yl) succinate, methylpiperidine-4-yl) sebacate, -pentamethylpiperidine-4-yl) sebacate Acid-pentamethylpiperidine-4-yl) butyl (4-monohydroxybenzyl) malonate, 6,6-tetramethylmethylpyridine-4-yl_ 5 4 ~ order Read first Please fill in this page again if you need to pay attention to this page.) The paper size is universally applicable to the countries with difficulty (CNS) A4 size (210 X 297 mm) 4 49 60 7 A7 B7 V. Description of the invention (0)) Sebacate, Tetra (2,2,6,6-tetramethylpiperidin-4-yl) butane-1, 2,3,4-tetracarboxylic acid ester, tetra (1,2,2,6,6-pentamethyl) Ketoline 4 -yl) butane — 1,2,3,4 -tetracarboxylic acid ester, 2,2,4,4 -tetramethyl- 7 -oxo 3 * 20-diazine 2 1- Oxodispiro [5,1 · 11.2] pyridine, 8_ acetamidine ~ 3 —twelve-base radical _1,3, tri-B yam 7 * 7, 9, 9, 9-tetramethylspiroline [4, 5] Decane-2,4-dione, or a compound of the following formula: (Please read the precautions on the back before filling out this page) Printed by the Consumer Affairs Cooperative of the Central Government Bureau of the Ministry of Economic Affairs

R R R-NH- (CH2) 3-N- (CH2) 2-N- (CH2) 3-NH-R

-55- This paper uses the Chinese national standard (CNS) A4 (2 丨 0X 297 mm > 443607 A7 B7) V. Description of the invention (θ C, H3?? H3 N- (CH2) 3'N -(CH2) fN '(CH2) 3-N ^

R

Where R

(Please read the precautions on the back before filling out this page)

N— ο

N fj N1 4

c 3 H H • c

N (CH Η c Η c

This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 449607 A7 B7 Printed by the Shell Poverty Alleviation Cooperative of the Central Government Bureau of the Ministry of Economic Affairs 5. Description of the invention (发明)

Where m is a number from 5_50. In addition to ingredients (A) * (B) and if required (0), this coating composition can contain other ingredients, such as solvents, pigments, dyes, plasticizers * spike fixatives, thixotropic agents, dry touch Vehicle and / or flow-controlling agent. Examples of possible ingredients are those described in Ullaiann ’s Encyclopedia of industrial Chemistry, 5th Edn., V〇 1. A 18, pp. 4 2 9-4 Ή, VCH, Weinheira, 1 99 1. Possible dry or hardening catalysts are, for example, organometallic compounds, amines, amine-containing resins and / or phosphines. Examples of organic gold sulfonium compounds are metal carboxylates, especially those of Pb, Mn, Co, Zn, Zr and Cu, or metal chelating agents, especially those of metals A 1, T i and Z r, or organic Metal compounds, such as organotin compounds. Examples of metal carboxylates are the stearates of P b, Mn and Z η, the caprylates of Co, Zη and Cu, the naphthalates of Mn and Co, and the equivalent linoleates, resinates and Tall salt. Examples of metal couplers are acetopropyl- acetic acid ethyl acetate 'salicylic aldehyde, salicylic acetaldehyde oxime, o-hydroxyacetophenone and ethyl ethyl trifluoride aluminum, titanium and Chelating agents, and alkoxides of these metals. -57- This paper size is in Chinese National Standard (CNS) A4 (2 丨 0 X 297 mm) ...... I ^ ρϋ. 'FeJi n. N (Please read the notes on the back first (Fill in this page again) 449607 Printed by the China Standards Bureau of the Ministry of Economic Affairs—Industrial and Consumer Cooperatives. A7 B7 5. Description of the Invention (c) Examples of organic tin compounds are dibutyltin oxide, dibutyltin dilaurate and dibutyl. Tin dioctoate. Specific examples of amines are tertiary amines, such as tributylamine, triethanolamine, 1 N-methyldiethanolamine, N-dimethylethionylamine, N-ethylmorpholine, N-methylmorpholine and diazine. Bicyclooctane (triethylenediamine) and its salts. Others are quaternary ammonium salts, such as trimethylbenzyl ammonium. The amine-containing resin is both an adhesive and a hardening catalyst, and an example thereof is an amine-containing acrylate copolymer. The hardening catalyst can be a phosphine * such as triphenylphosphine. This novel coating composition can also be a photo-curable coating composition. In this case, the adhesive mainly includes monomer or oligomer compounds, which contain ethylene unsaturated bonds • These bonds will then be hardened by light * such as being converted into a crosslinked * polymer type. The system is UV-hardenable and usually also contains a photoinitiator. The relative system is described in the above publication, Ullmann's Encyclopedia of Industrial Chenistry, 5th Edition, Vol. A18, pages 451-453. In this photo-hardenable coating composition, the use of novel stabilizers may require the addition of sterically hindered amines. The coating composition of the present invention can be applied to any desired substrate substrate 'such as metal, wood, plastic or ceramic materials. It is preferably used as a top coat for automotive coatings. Provided that the top coating includes two layers, of which the lower layer is a dyed layer and the higher layer is undyed, the novel coating composition can be used in a lower or higher layer, or both, but more Ideal for higher layers. -58- This paper music is again applicable to the Chinese Family Standard (CNS) Α4 specification (210 × 297 mm) (please read the precautions on the back before filling this page) Order 449607 Ministry of Economic Affairs ^-Central Government Standards Bureau off-site consumption Cooperative Du printed Α7 Β7 V. Description of the invention (young) This novel coating composition can be applied to the substrate by traditional methods, such as, brushing, spraying, pouring, dipping or electrophoresis; see ϋUB a η η 's Encyclopedia of Industrial Chemistry, 5th Ed., Vo 1. A18, pp. 4 9 1-5 0 0 〇 The hardening energy of the coating (depending on the adhesive system) is performed at room temperature or elevated temperature . The coating is preferably hardened at 50 °; L50, and the powder coating is also hardened at high temperature. The coating obtained according to the method of the present invention has excellent resistance to the harmful effects of light, oxygen and heat; in particular, it is necessary to mention the good light and climatic resistance of the coating, such as the coating obtained by this method . Therefore, the present invention also relates to a coating, in particular a coating, which is stabilized against the damage caused by light, oxygen and heat by containing a novel compound of formula (1). This coating is preferably a car top coating. The present invention further relates to a method for resisting light, oxygen, and / or thermal damage based on an organic polymer-based coating of Suiding K, comprising mixing a compound of formula (1) and the coating composition, and regarding the compound of formula (1) in Application as a stabilizer for coating composition to resist damage from light, oxygen and / or heat. The coating composition of the present invention usually contains an organic solvent or a solvent mixture in which the binder is soluble. However * This coating composition can also be a ~ solution or dispersion, and the carrier can be a warm compound of organic solvent and water. The coating composition can also be a high-solids coating or a solution-free (powder coating). The pigment can be an inorganic, organic or golden tint pigment. The novel coating composition is preferably applied as a pigment-free and transparent coating. -59- National Standard (CNS) 11% (210X297 mm) of this paper standard (Please read the precautions on the back before filling out this page) Order printed by the Central Laboratories of the Ministry of Economic Affairs Manufacturing 449607 A7 B7 V. Description of the invention () It is also preferred that the coating composition be used as a top coating for the automotive industry, especially the top coating that is dyed or undyed at the end; however, it is also used for the bottom coating. possible. Preferably, the novel compound of formula (1) is used as a photographic stabilizer to resist light, especially UV light. Therefore, the present invention is also limited to photographic materials containing a compound of formula (1). The compound of the present invention can be used for all types of light-sensitive substances, for example, it can be used for colored paper * reversal paper, direct-positive color materials, and color negative film. , Color positive film (color positive filia), color reverse film. It is preferably used on a light-sensitive color substance. This substance includes an inverse base plate or forms a positive film. Furthermore, this novel compound can be combined with other UV absorbers, especially those that are dispersible in gelatin water, such as with hydroxybenzylbenzotriazole (such as US-A-4,853,471, US-A- 4,973,702, US-A- 4, 9 2 1,9 6 6 and US-A-4,9_7 3,7G1), benzophenazine, anilide, cyanopropionate, salicylate, acrylonitrile or Thiazoline. In this paper, it is more advantageous to use other oil-soluble UV grazing agents in the photographs in different phase layers containing this novel UV absorber. In particular, it is a stable photographic substance that can be successfully used in the method of class M and described in ϋS-A-4, 5 1 8, 6 8 6. Therefore, the present invention also relates to a photographic substance that includes at least one M color-sensitive, green-sensitive, and / or red-sensitive toothed silver on a support layer. * 60 ^ This paper standard applies to China National Standard (CNS) Α4 Speaking case (210 × 297 mm) -I ί--ί— HI —: si J- I! Winter; ^^ 1 ^^ 1-J-_. 1 (Please read the notes on the back before filling this page ] 44360 7 A7 B7 V. Description of the invention (π) Emulsified layer, and if necessary, a protective layer with a phase layer containing a UV absorber * and this phase layer containing a UV absorber is arranged in a silver halide emulsion layer Above, wherein the UV absorber is a compound of formula (1). In addition, the preferred photographic substance has a phase layer containing the compound of formula (1). It is on the silver halide emulsion calendar and / or on green and Between red-sensitive silver halide emulsion layers. In addition, it is advantageous for all or part of the phase layer that already contains a UV absorber to have a UV absorber mixture that is dispersible in an aqueous gelatin solution and / or other UV Absorbent • But the compound of formula (1) must be present in at least one layer. This novel substance is preferred A gelatin inner layer is contained between the silver halide emulsion layers. The preferred photographic substance is that the silver halide on the blue-sensitive, color-recording-sensitive and / or red-sensitive layer is silver bromide, which contains at least 90 moles. Ear% silver chloride. Printed by the Central Government Bureau of the Ministry of Economic Affairs and Consumer Cooperatives (please read the precautions on the back before filling out this page). The compound of formula (1) of the present invention can be used alone or with a color coupler. Add, or if other additives are used, add them to the color photographic material, the method of adding these compounds is to disperse the organic solvent to a high boiling point. It is preferable to use a solvent with a boiling point higher than 16 ου. These solvents Basic examples are peptidic acid esters, osmic acid esters, lauric acid esters, benzoic acid esters, or fatty acid esters, and also include alkylphosphonium amines and phenols. Preferred color coupling agents for the compositions of the present invention, these compounds Zongzi, other additives, such as color projection inhibitor, DIRI Yu mixture · -6 1- This paper size is applicable to China National Standard (CNS) A4 (210X297 male oysters) 449607 Cooperative Du Printing Α7 Β7 V. Description of the invention (approximately) and other light stabilizers, such as UV absorbers, phenols, europium (III) compounds, organic gold compounds, hydrogen K and awake ethers, and more details of various photographic materials The detailed information can be found from, for example, EP-A-531,258 and EP-A-520,938, and the materials cited therein. The novel bisphenyl-substituted triazine compounds of formula (1) are suitable for undyed, dyed or printed Photochemical definitions of fibrous substances • These substances include silk • leather, wool * polyamide or polyurethane, and in particular various diastereovitamin-containing diagnosing substances. Examples of these entangled substances are natural diaceae Plain fiber * like cotton * linen, jute and hemp, and also includes viscous maintenance and regenerated fibers. The preferred spun Valer material is cotton fiber. This novel bisphenyl-substituted triazine compound is also suitable for the photochemical determination of hydroxyl-containing fibers of various mixed suspects, such as the warm compounds of cotton and polyester andramide or polyamide fibers. Other preferred fields of application are blocking or reducing UV rays that pass through the above-mentioned textiles (UV-cutting) 1 and the final treatment of rhenium with this novel compound to improve the sun protection of human skin. For this purpose, a traditional dyeing method can be used to apply different compounds of the formulae (1) to (4) to the textiles, and the more advantageous application amount is 0 * 0 1 to 5% by weight. It is preferably 0.1 to 3% by weight, especially from 0.25 to 2% by weight (based on the weight of the male substance). This novel bisphenyl-substituted compound can be various Method of application to fibrous material | and fixation on it, especially the method of M aqueous solution dispersion or printing paste application. -6 2-This paper uses the Chinese Standard for Household Standards (CNS) A4 specification ( 210 X 297 mm), 4 --- ^ ---- Order ---- II (please read the notes on the back before filling this page) 449β〇7 Α7 Β7 V. Description of the invention (p) Μ formula (1) The final treatment of new compounds: Kanwei substances have an improved protective effect on the photochemical cleavage and yellowing of fibrous substances, and in the case of dyeing and maintaining substances, improve (thermal) light fixation Special emphasis must be placed on the improved photoprotective effects of the treated fibrous material, especially for short-wave UV-B The good protection effect of the thread. This can be explained by the fact that the spinning compound treated by the novel compound of formula (1) has a large increase in the sun protection factor (SPF) compared to the untreated junk. The definition of the sun protection factor is The dose of UV-protective nickel that harms the protected skin is divided by the quotient that damages the dose of UV-rays that do not protect the skin. Therefore, the sun protection factor is also an untreated fibrous substance and a dilute substance treated with a new type of compound of formula (1). Measurements that allow the transmission of UV rays. The determination of the sun protection factor of entangled substances is explained in the following documents' for example in WO 9 4/0 4515 or in J. Soc. C 0 S ni 8 t. Che ». 4 0, 1 2 7-1 3 3 (1989) and similar methods can be carried out ° The V absorbent of the present invention is further suitable for use as a photoprotectant for cosmetic preparations. Consumption by employees of the Central Bureau of the Ministry of Economic Affairs Co-operative printing (please read the note on the back before filling this page) Λ Therefore, the present invention also relates to a cosmetic preparation 'containing at least one compound of formula (1) * and a carrier or auxiliary acceptable to the cosmetic industry Agent ^ This novel cosmetic composition contains formula (1) from 0 '1 to 1 5% by weight, preferably from 0.5 to 10% by weight (calculated based on the weight of the total composition) UV absorber | and a co-coster acceptable in the cosmetics industry. -63- This paper size is applicable to Chinese National Standard (CNS) A4 standard (210 × 297 mm) 443 60 7 A7 _B7___ 5. Description of the invention (d) Cosmetics sister The finished product can be physically mixed with the novel u V absorbent and co-costing agent by conventional methods, such as simply mixing the two substances. The cosmetic preparation of the present invention can be formulated into water-soluble oil-soluble or oil-soluble emulsion * and oil-soluble oil-soluble emulsions • small-bubble dispersions of ionic or non-ionic amphoteric lipids, and colloids • solid gum sticks, or gas Sol formula. When applied to water-soluble oil-soluble or water-soluble emulsions | This cosmetically acceptable rib extender preferably contains from 5 to 50% oil phase, from 5 to 20% of emulsifiers | and from 30 to 90 % Of water. The oily phase includes any oleum suitable for use in cosmetic formulations, such as one or more hydrocarbon oils, stone oils, natural oils, silicone oils, fatty acid esters or fatty alcohols. The preferred one or more enzymes are ethanol, isopropion, malonate, adipase * glycerol and sorbitol. For the cosmetic formulations of the present invention it is possible to use any conventionally used emulsifiers * such as ethoxylated esters of one or more naturally hardened derivatives, such as polyethoxylated hydrogenated sesame oil; or silicone oil emulsifiers, like silicon Ketone polyols; unmodified or ethoxylated fatty acid soaps; ethoxylated fatty acid alcohols; unmodified or ethoxylated sorbitan esters; ethoxylated fatty acids; or monoethoxylated glycerides. Printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperative (please read the precautions on the back before filling out this page) This cosmetic formula also includes other ingredients, such as lubricants, emulsifiers, stabilizers, skin moisturizers, Color accelerators, thickeners, like xanthan, calendar retention agents, like glycerol, preservatives, or fragrances and dyes. This novel cosmetic formula protects human skin from the harmful effects of light i. At the same time, it can provide a reliable effect of skin care -64 'The paper method is universal Chinese national standard (CNS > Eight 4 Zhuge (210X297 public *) 449607 A7 B7 V. Description of the invention (u) Fruit 0 The following examples will carefully describe the subject matter of the present invention without limitation. In some examples, the 'part and percentage are M Calculated by weight; if an example refers to room temperature, it is meant to be in the range of 20-2 5C. Unless specifically mentioned 'these definitions apply to each case. Preparation Example 1 of a new amidine compound Example a ) 2-(4-bisphenyl) -4H-1,3-benzoxazine-4-M 15.07 g of salicylamide is dissolved in 30 ml of xylene (+ 1 ml of pyridine), and 21.7 g of bisphenyl-4-carbamidine nitride dissolved in 100 ml of xylene were added over 2.5 hours at a temperature of 70C. Stir the mixture at a temperature of 1 80 for about 4 hours, then evaporate to dryness, leaving 35.3 grams of an oily residue. Its chemical formula is: Printed by the Central Ministry of Economic Affairs, printed by the Shellfish Consumer Cooperative 〇

(Please read "Notes on the back side before filling out this page) (101) b) 2-(2- • hydroxyphenyl)-4-phenyl-6-(1-bis-benzene-65- ft-size paper) National Standards for Difficulties (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 449607 A7 B7 V. Description of the invention (θ) based) 1-3,5-Triazine will be formula (10 1 ) The oily residue of the compound was dissolved in 40 ml of methylcellulose at 40D, then 45-7 g of 38% benzamidine hydrochloride dissolved in methanol was added * followed by 19.6 g of 3 0% sodium hydroxide solution. Next, the mixture was stirred at a temperature of 90 ° C for about 4 hours, and after passing through 逋, 19 · 7 g of almost colorless, crystalline product was obtained: ζλ〇Η

Yield: 49% of the theoretical melting point; elemental analysis of 2 5 2 2 5 9 ΰο 〇C 2 7 Η 1 9 Ν 3 0: calculated value of C Η N 0; 8 0 .78¾ 4. 7 7% 10.47¾ 3.39 ¾ Found value 80.74¾ 4. 87¾ 10.50¾ 3.93¾ Spring example 2: _ 6 6 — This paper size is applicable to the Chinese standard Jiaxin (CNS) Α4 specification (210 × 297 mm) Dream -------- Order-- -^ (Please read the notes on the back before filling this page) 44960 7 A7 B7 V. Description of the invention (4), 16 · 15g of 2-benzyl-4H-1, 3 -benzoxazine-4- Tritium (M similar to the method of Helv. Chim. Acta 55, 1566-1599 (1972)) was dissolved in 100 ml of methanol. Then 12 '◦ g of 4-bisphenylpyridine was added, and then 1 3 * 5 grams of a 40% sodium methylate solution, and the mixture was stirred at a bath temperature of 70 ° C for 2 hours. After the filtration, 16 * 75 grams of the compound of the formula (102) was obtained. Yield ·· 8 3 · 5% Example 3: Repeat the procedure described in Example 1 b), but use 24.44 g of the compound of formula (10 1) and .17 g of 4-bisphenyl fatty hydrochloride instead of benzene Formamidine hydrogenate. After purification, 2 1 · 6 g of the following compound can be obtained: (Please read the precautions on the back before filling out this page)

Yield: 61 _ 5% Theoretical value Melting point: 262 — 265 ° C Elemental analysis of C3 3 Has 0x0 '5H2 0: -67- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 4 49 60 7 A7 B7 V. Description of the invention (C Η Calculated value: 8 1 .4 6% 4.. 9 8% 8 • 6 3% Found value: 8 1 • 3 5% 5. • 0 8% 8. .5 1% Printed by the Consumer Cooperative of the Central Bureau of Quasi-Economic Bureau of the Ministry of Economic Affairs Example 4: Dissolve 4-65 g of bisphenylphosphonium hydrogen hydride in 8-9 ml of dimethylacetamide, and then add 3 * 65 ml of a 30% sodium methylate solution of methanolic acid, 2.97 g of methyl salicylate and 10.6 ml of cyclohexane, the mixture was added to 90C in 30 minutes > and stirred at this temperature for 2 0 hours. Then cooled to 5 t: and filtered to obtain 1.05 g of pale yellow (.103) product (Reference Example 3). Yield: 2 2% of theoretical value Example 5: a) 4 65 g 4 A bisphenylphosphonium chloride was suspended in 6.7 ml of methanol, followed by the addition of 3.6 g of a 30% sodium methylate solution and 1.22 g of salicylaldehyde at a temperature of 60-64t: under Mix the mixture for 6 hours • After filtering and washing with K water and methanol, you can get 4 · 4 grams of light gray ochre with the following formula: -68- The paper ft scale applies the Chinese National Standard (CNS) Α4 specification (210 × 29 · 7 Public) Private ------ Order --- I · ν (Please read the notes on the back before filling this page) 449607 A7 _ B7 V. Description of the invention (A) (104)

Employees of the Central Bureau of Standards of the Ministry of Economic Affairs and Cooperation Du Yince C3 3 H2 5 N3 0 Elemental analysis: C Η Calculated value: 82.65¾ 5.25% Issued value: 81,40% 5.19¾ b) 4 · 8 g formula ( 104) The compound was dissolved in 35 ml of dimethylformamide | 40% sodium bisulfite aqueous solution at 3.83 ml was added. The mixture was stirred at a temperature of 4 ¾ for 6 hours, and then filtered at room temperature, and the filtered product was dried to obtain 4.62 g of a product of formula (io3) having a pale yellowish gray color (see Example 3). Yield: 9 6 · 3% of the theoretical value 莨 洌 6: (previous technique) 4 · 6 g of resorcinol was dissolved in 40 m 1 of nitrobenzene, and then 3.82 g of 2— (4 ~ bisphenyl) —4,6—dichloro—1,3,5_triazine, and then introduce 3 ′ 37 g of anhydrous aluminum trichloride * with ice cooling in between, so the temperature does not exceed 2 0 ° C, then heat the mixture to a bath temperature of 9 2 ° C, and stir at this temperature for 2 hours, cool and pour 100m H2 ◦, 90 grams of ice and 10 ml of concentrated -69- China National Standards (CNS) grid (210XM7 mm> N 0 8.76¾ 3.34 8.61% 3.85 (read the notes on the back and then fill out this page)

449607 Α7 Β7 V. Description of the invention (π ΟΗ

In the HC 1 mixture printed by the Male Standards Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, followed by steam distillation and purification. 7. 38 g of pale yellow-orange powder were obtained: (105) Yield: 8 5 · 2% of theoretical value. The elements of C 2 7 Η 1 9 Ν 3 〇 4 X 1 3 3 Η 2 0 C Η Ν Η 20 Calculated value 68.5¾ 4 .6 1¾ 8.88¾ 5.06¾ Found value 68.37% 4. 58¾ 8.79¾ 5.05¾ Example 7: 2 g of the compound of formula (105) prepared in Example 6 was dissolved in 30 ml of dimethylmethane phosphonate together with 3 g of sodium carbonate, and the solution was stirred at a temperature of 50 ° C 2 Hours, after cooling, diluted with 500ml ethanol, and then washed to obtain 1.85 grams of light gray product of the following formula: -70- National Standard (CNS) A4 size (210 × 297 cm) ) (Read the notes on the back before filling in this page)

4 49607 A7 B7 V. Description of the invention (α) 0-CH, (106)

Elemental analysis of C 3 ο Η 2 S Ν 3 0 4: C Η N Calculated value: 73.31¾ ί). 13¾ 8 * 5 5¾ Found value: 73.27%. £). 15¾ 8.48¾ Example 8: Repeat Example 2 Procedure, but using 2- (2-hydroxyphenyl) _4H-1,3-benzoxazine-4afluorene instead of 2-phenyl-4H-1,3_benzoxazine-4afluorene, After purification, compounds of the following formula can be obtained: 1, Binding ---- Μ (please read the precautions on the back before filling out this page) Printed by the Central Labor Bureau of the Ministry of Economic Affairs, Consumer Cooperative (107)

The dimensions of this paper are generally in accordance with Chinese National Standards (CNS) 戍 4 (210 X 297 mm) 449 60 7 A7 B7 V. Description of the invention (θ) Yield: 8 1% Theoretical value Melting point: 289 — 290¾ C 2 7 Elemental analysis of Η 1 g Ν 3 ◦ 2: C Η Calculated value: 77.68¾ 4.59% 10.07% Found value: 77.67% 4.64% 10.04¾ Example 9: Repeat the procedure of Example 7 * but use the compound of formula (107) instead The compound of formula (105) can be obtained as follows: (Please read the precautions on the back before filling this page)

Printed by the Central Bureau of Standards of the Ministry of Economic Affairs for consumer cooperation Du Yield: 10 0%

Melting point: 228-229 ° C

Czs Hz】 N3 〇2 xl. 5H2 0 Elemental analysis: C Η N Calculated value: 7 3 3U 5.27¾ 9.16¾ This paper size applies the Chinese Enclosure Standard (CNS) ΑΊ specifications (2lOX: 297 mm) The Ministry of Economic Affairs, the Procurement Bureau staff consumption cooperation, Du printed 449607 A7 B7 V. Description of the invention (7.) Issued value: 73.U 4.5% 3.1% Actual value 1 0: Repeat the procedure of Example 2 * but use 2 — (4-methoxymethoxyphenyl) — 4H_i, 3-benzoxazine-4 monoketone instead of 2-phenyl-4H-1, 3-benzoxazine-4__. After purification, a light gray-brown compound can be obtained:

Elemental analysis of C2 s H2! N2 02:

C Η N Calculated: 77.9U 4.91% 9.74¾ Found: 77.84¾ 4.9 4 3: 9.68¾ 莨 Example 1 1: a) Repeat the procedure of Example la), but use 4-methoxysalicylamidine Substitute salicyl with amine | Residue is equal to the compound of the following formula: -7 3- This paper is again suitable for China National Standards (CNS) A4 (210X297 mm) —I Private Order Ϊ (Please read first (Notes on the back then fill out this page) 449607 A7 B7

V. Description of the invention (V (110)

b) The compound of formula (110) was further treated as described in Example 2 without further purification, and 4-bisphenylphosphonium amine hydrochloride was used instead of benzamidine hydrochloride, so that a compound of the following formula was obtained: ( 111)

Knowledge of clothing order J (please read the precautions on the back before filling this page) Elementary analysis of the consumer printing cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs, the printed yield of the society 3 4% Theoretical value C 3 4 Η 2 5 Ν 2 〇2 ： C Η N Calculated value 80.4 5% 4.96¾ 8.28¾ Found value 80 .58¾ 4.95¾ 8.18¾ Spring example 1 2: -74- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (%) 44960 7 A7 B7 V. Description of the invention (η Repeats the procedure of Example 2, but uses 2- (4-fluorofluorophenyl)-4Η-1 * 3-benzobenzoxazinone-one instead of 2-phenyl-1 4Η-1, 3-benzoxazin-4-one. After purification, compounds of the following formula can be obtained: (112)

Yield: 3 1% Theoretical value C Calculated value: 7 8.5 9 ¾ Found value: 7 8.5 7% In the step, the compound of the following formula is used instead of 2 ~ phenyl- 4H-1, 3-benzo- _ _ — 4 嗣:, winter -----order ---- i J. (Please read the back first (Please note this page, please fill in this page) Printed by the Central Government Bureau of the Ministry of Economy

〇, 0 The compound of the following formula can be obtained after purification: -75- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 44960 7 A7 B7 V. Description of the invention (M)

Yield: 72 · 6% Theoretical melting point: 240 — 242 = 0 Elemental analysis of C2 8 Hi 9 N3 〇3: C Η N 0 Calculated value: 75.49% 4.3% 9.43¾ 10.77¾ Hair value: 75.45¾ 4.36¾ 9.36¾ 10.83¾ (Please read the notes on the back before filling this page) T cyanide 4 ο, · Substitute it, 5 005 0 g gram mix into 3 ο This ear liquid is mixed up and floatable, 5 will molybdenum 漶, suspend 4 于. 5 of the permagnesium 3 is dissolved ο} mixed 0 layer has a small base P this glue} containing benzene 200 will be a pair of silicon ears < 5 and Shen Yimo into ib, and 7 Add bromine mixed 2 ^^ stupid after the 4th formula I heat. Η Jiajian refining 1 square 4 plus 9T dry period. The flow has risen. 0drop} back to the ear containing the liquid with 毫 ο ο 1 1 gram to moran to 50C residue: 6-7 'added to 1; 1; filter 4. medium 4 solution type dissolved in% over 13F1 solution Adding 2 irrigation examples Η 的 的 化 ， 1 Washing water after dripping chlorine in the paper size of the paper applies the Chinese National Standard (CNS) Α4 specifications (210 X 297 mm)

A 449607 V. Product description of the invention (Η): A7 B7

Yield 35% Theoretical value C 2 7 Η ϊ 8 Ν Ν C 1 Elemental analysis: C Η NHC 1 Calculated value: 7 7. 2 3% 4:. 3 2% 10.01¾ 8.44% Found value 7 7 .1 Q% 4: .5 1% 9.95¾ 8.13¾ (Please read the notes on the back before filling this page)

'1T 洌 1 5: λ 17.6 g (0.042 mol) of 2-chloro-46,6-bisdiphenyl_1,3,5-triazine (compound of Formula 1 14) Ministry of Suspension Economy Printed on 1 ◦ 0 ml of toluene group by the Central Government Bureau of Consumers ’Cooperative, add A 丨 C 1 3 as a catalyst, heat the mixture to 100 ° C, and add a portion of 4,7 g (0.0042) Mol) resorcinol, and then the mixture was heated at reflux temperature for 12 hours. The reaction mixture was poured into ice water. The mixture was filtered, and the residue was washed and washed with water. 145 g of the product of the following formula was obtained: -77-This paper size uses the Chinese National Standard (CNS) A4 washing grid (210X297 mm) 44960 7 A7 B7 Economy Ministry of Central Bureau of Standards, Consumer Cooperatives, Printing Policy V. Invention Description ()

0H

Yield: 70% Elemental analysis of C3 2 H2 3 Ns 02: C Η N Calculated value: SO. 3 U 4.70% 8.51¾ Hair value: 80.26¾ 4.55¾ 8,23¾ Example 16: 9 · 9 g ( 0. 02 moles) of the compound of formula (1 15) (Reference Example 15) and 3 g (0.022 moles) of potassium carbonate suspended in 50 ml of ethyl cellulose and heating the mixture to 1 ου, and K droplets were added in 3.6 g (0.022 mol) of hexane bromide, and the mixture was stirred at a temperature of 110 ° C for 2 hours. As the mixture was cooled, the product precipitated. The mixture was filtered and the residue was filtered and washed with K water to obtain the product of the following formula: 7 8 ~ This paper size applies the Chinese National Standard (CNS) A4 washing grid (210 X 297 mm) II — — ^^^^ 1 1 ϊ— 一 Ί I ^^^ 1 n ^ i «I. 丨., Λ (Please read the note on the back before filling this page) 449607 A7 B7 V. Description of the invention ((116)

Yield: 69%. Melting point: 176 — 178C Elemental analysis of C3 9 H3 5 N3 〇2: C Η Calculated value: 8K083: 6.11¾ Found value: 80.91¾ 6.28¾ N .27¾ .14¾ I. ~~ " Order J ^ (Please read the precautions on the back before filling out this page) Example of printed spring of the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 17: 8-5 grams (0 items (refer to Example 1 5 based epoxypropyl ether and 0 0172 moles) compound of formula (115), 3.4 grams (0 '025 moles) of butadiene 5 grams (0.014 moles) of ethyltribenzylphosphonium bromide suspended in 2 ◦ ◦ ml In xylene • Heat the mixture under circulating current for 17 hours, distill out the xylene, and recrystallize the residue to obtain -79- This paper size is in accordance with Chinese Standard (CNS) A4 (210X 297 mm) 44960 7 Α7 Β7

Yield: 6 1% Melting point: 156 — 158¾ Order

Elemental analysis of C Η Ν 3 ◦ 4:

C Η Calculated value: Hair value: 77.02¾ 76.78¾ 5.98¾ .97% N .7 4¾.7 2¾ Example of printing by the Central Bureau of Standards of the Ministry of Economy and Industry and Consumer Cooperatives 1 8: 23 + 2 grams (0 · 047 mol ) Of the compound of formula (115) (Reference Example 15) and 7.2 g (◦ · 052 mol) of potassium carbonate suspended in 100 ml of ethyl cellulose > Heat the mixture to 1 1 0 ° C | In the form of M droplets, 10 g (0 052 mol) of 1-bromooctane was added. Search and mix the mixture for 3 hours at 80 ° -80 This paper size is applicable to the national standard (CNS) A4 specification (2 [0 X 297 cm) ^ 49607 A7 B7 V. Description of the invention (舛 When cooling the mixture, The product precipitated out. The mixture was filtered and the residue was combined with gram 3 3? -I to obtain the washable water K.

Rate point melting% 7 4 P ο 6 1 I 8 5 1 ^ 1 i ^ i ^^^ 1 d.— In r ^ nm -i —I-n ^^^ 1 ^^^ 1 II 1 ^ ^ n 1 ^ 1 {Please read the notes on the back before filling in this page) 9 1—I Example printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

C ο 5 .ί \ 1 gram example 1 fact.

C ο / | \ gram 6 ο 5 ears 1 mo 1 8 (2 formula ◦ of *) ο-M 5 6 1—I ο gram 8 6 and the suspension of the compound 'bromide-based mixed benzene three Isopropyl group} Propyloxane 6 group 1 alkane ο I ο Substitute formula 3 under 2 grams 8 kun. V / · Heat 9 can be flowed down, and regressed in the layer Benzylsilicone in two, the solvent is completely soluble ο lose 5 rounds 1 steamed in 'floating time this paper size is applicable to China National Standards (CNS) A4 specifications (210 X 29? Mm) 4 49 60 7 V. Invention Explanation (·? 1 Compound: Α7 Β7 (119)

Isomeric mixtures (please read the notes on the back before filling this page) Employees' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Yield: 81% Melting point: 80-88 ： Example 20: 22, 2 g (0.045 Moore) of 2-(2 4 -dihydroxyphenyl) _4,6 -bisdiphenyl_1,3,5 hydrazine (equivalent to formula (115)) | and 6.8 g (〇.〇5 萁) Ear) potassium carbonate was suspended in 150 ml of ethyl cellulose, and the mixture was heated to 110 ° C. and K droplets were added in a manner of 1 · 9g (◦ '〇5mol) of 1_ bromine Decane. The mixture was stirred at a temperature of 110 ° C for 12 hours. As the mixture was cooled, the product precipitated. After filtering the mixture and recrystallizing the residue, 8 g of a compound of the following formula can be obtained: -82- The paper size is in accordance with the standard of Chinese paper mills {CNS) A4 (210X297 mm) 44960 7 A7 B7 V. Description of the invention (π ) (120)

(Please read the notes on the back before filling this page) (Yield 28%-Melting point: 1 5 4-157 ...). Elemental analysis (%) C Η Calculated value 8 1.48 6.84 8.63 Found value; 8 1.41 6.74 6.62 Printed example 21 by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 21: 10 g (0.016 mol) of 2-(2 -hydroxyl- 4-(2-Hydroxy-3_butoxypropoxy) phenyl) -4,6-dibisphenyl-1,3,5-triazine (equivalent to formula 16)), dissolved in 100 ml In a mixture of xylene isomers, heat it to 120P, and then add 4.7 g (0 '0352 mol) of hexamethylene chloride as a droplet, and add 5 drops of pyridine. The mixture was stirred at a temperature of 12 0 3C for 12 hours, the warm mixture was cooled, and the water phase was washed with M water and then dried with Ms S04. After evaporating off the solvent, the paper scale of -83- is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 4 49 60 7 A7 B7 V. Description of the invention () The residue is chromatographed on silica gel to obtain 8. 6 grams of a compound of the formula:

It is resinous (yield 74%). Elemental analysis (96.) C 计算 Calculated value: 76.54 6.56 5.82 Found value: 76.27 6.66 5.30 (Please read the notes on the back before filling this page) Example 22 printed by the Standards Bureau Consumer Cooperative: 2 '3 g (0.025 mol) of a compound of formula (1 15) and 5-18 g (0.0375 mol) of potassium carbonate suspended in 150 ml In ethyl cellulose, the mixture was heated to 110 and 9 · 35 g (0.0375 mol) of 1-dodecane bromide was added. The temperature mixture was stirred at a temperature of 1 1 ◦ ° C 1 2 For hours, the product precipitated out as the mixture was cooled. Filter the mixture • Recrystallize the residue • Get 6 · 3 grams of the compound of the following formula: _ 8 4 _ This paper ruler is applicable to China National Standard (CNS) A4 (210X 297 mm) 449607 A7 B7

V. Description of the invention (A (122) (yield 38%, melting point: 143-146C) elemental analysis (%) (please read the precautions on the back before filling this page) C 计算 N calculated value: 81.66 7.16¾ 6.35 found Values: 8 1.66 7.33 6.21 Revised Example 23: Formula (10 1) Benzozine hydrazone was reacted with the following substituted benzamidine as described in Example 1: a) Reaction with 3-aminobenzidine :

A Printed by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs, W NH W, Ν, 一 ~ / Ν 、,

The compound of the following formula can be obtained by HCI: 85- This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 44360 7 A7 B7

NH, V. Description of the invention (Magic (123a) Melting point: 297-298C. Elemental analysis of C2 8 Η2 〇Ν4〇2 (Please read the notes on the back before filling this page) Calculated value: Found value: C Η Ν 0 75 .66 4.54 1 2. 6 7. 2 75 • 65 4.65 12 · 57 7.13

, TT b) and methyl 4-monoaminobenzoate of the following formula k 〇W HC-0 /-^ ΓΛ ΝΗ κ > <) \ ~ f ΝΗ, printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A compound of the following formula can be obtained: -8 6 _ This paper scale is applicable to the Chinese garden house standard rate (CNS) A4 (2l0X297mm) λ η εο 7 Α7 Β7 5. Description of the invention (shake S '3 2

CH ο 8 9 τ—I point melting

2 C Z Η

Analyze the element 〇 of P 3 ο 〇 ο 3 2 N ο

The value of C Η Ν ο is calculated to be 2 groups of benzene} diol-Mo 4 9 (1 I ο bis • -ο 6 / _ \ g 4 4 I 9 group: benzene 4 group 2 hydroxy group 2-2 1 4 3 (Please read the notes on the back before filling out this page) Kerr 6 Mo. 1 2 2, ο ο a {kilk 1 1 liter 6 milliliter and ο potassium ο acid 1 carbon in,-.浮 耳 挂 莫 晓 9 三 1-ο 5., Ο Cooperative Du printed by employees of the China Prospective Bureau of the Ministry of Economic Affairs ο Silicon-· ο Remaining in the product 1 property ο Residual type}. The mixture is filtered through %% of the structure; the last 7 radicals are 4 octane, {hr gram ester is small 3 octane 2. The acid 1 6 alkane is pentatized and the temperature can be reduced, the bromine is stirred out, the layer is stirred 2 gum

The size of this paper applies the Chinese National Standard (CNS) A4 specification (210X: 297 mm) 44960 7 Α7 Β7 V. Description of the invention u?) 1 Η — N MR spectrum and this chemical formula are compatible. Elemental analysis of C 4 Η 3 7 Ν 3〇4: Calculated value of C Η 78.2 7 6 .7 1 5.95 Found value: 7 9 Λ 5 7 .18 5. 1 δ (Please read the precautions on the back before (Fill in this page) Application example printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Example 2 5: 2—Finishing the final coating (FINISH) The test compound is dissolved in 20-30 grams of Solvesso® 150 , And tested in a transparent coating with the following product:

Synthacryl® SC 3031 2 7.51 Synthacry 1 ® SC 3 7 0 2 23.34 Maprenal® 6503 2 7.29 Butyl acetate / butanol (37/8) 4,33 Isobutanol 4.87 Solvesso® 1504 2.72 Crystal Oil K-30 8.74 Equalization assistant Agent Baysilon® MAS 1.20 -88- This paper size applies to Chinese National Standard (CNS) A4 scale (2! 0 X 297 mm) 443 60 7 A7 B7 V. Description of the invention (1 0 0 0 0 g 1 5% The test compound is added to the clear coating (calculated based on the solid content of the varnish). Some other varnish samples were prepared * which, in addition to this new compound, contained 1% of a compound of the formula: (125)

HX

0 I C

0 (CH2) e--C

CH, (calculated based on the solid content of the coating compound). For comparison, a transparent overlay without light stabilizer was used. The transparent coating KSolvesso® 10Q was diluted to spray and spray viscosity, and spray-applied to a prepared aluminum plate (Unipr Ue Epoxy, ^ -Golden base coating), baked at 1 30C for 30 Minutes, a dry film with a thickness of 40-50wm is obtained. These samples K were subjected to weathering tests in the following ways: (Please read the precautions on the back before filling out this page) The Ministry of Economic Affairs printed the acrylic resin, Hoechst AG; 65% solution of toluene / butanol (26: 9) 2 Acrylic acid ester, Hoechst 46; 75% solution dissolved in 30] ^ 655〇 @ 100 3 Melamine resin, Hoechst AG; Soluble in isobutanol 5 of 5 5% solution 4 aromatic hydrocarbon mixture, boiling point range 1 8 2 — 2 0 3 t: (-89- This paper size is applicable to Chinese Standards (CNS) A4 (210X 297 mm)

----- «J 449607 A7 B7 V. Description of the invention (Η)

Solvesso® 150) or 1 6 l ·-1 7 8 (Solvesso® 100); manufacturer: E s s ο

5 1% solution in Solvesso® i5〇 * Manufacturer: Bayer AG. UVC 0 N ® A tias Co or 〇rati ο η weather-resistant instrument (UVB-31 3 lamps) 'period of 8 hours of irradiation, and 4 Condensation at 50 ° C. .QUV®Q-Panel weather-resistant instrument (UVA-340 lamp-high intensity), with a period of 70 C irradiation for 8 hours and condensation for 4 hours. Measure the * face gloss of the sample (20 ° gloss * DIiH753). Compounds used: Compounds of formula (1 1 6) (Example 16) Compounds of formula (119) (Example 19) Compounds of formula (1 2 1) (Example 2 1) Results: Table 1: at 0, 1 2 0 0 hours at u 20 ° after weathering in VC 0 N (UVB-3 1 3), printed by member of the Central Bureau of the Ministry of Economic Affairs of the Ministry of Economics and Consumer Affairs, Du printed (please read the precautions on the back before filling this page) Triazine 0 12 0 0 m 8 7 7 0 Compound of formula (1 1 6) 8 8 8 4 -90- This paper size is applicable to China National Standards (CNS > A4 size (210X297 mm) bu 44960 7 A7 B7 V. Description of the invention (type) Compounds of formula (119) of 1.5% 85 8 7 Compounds of formula (121) of 87.5% 87 86 Table 2: UVCON (UVB- 3i3) The combination of 20 ° gloss didiphenyltriazine and Tinuvin 2 9 2 (HALS) after weathering 0 12 0 0 (Please read the precautions on the back before filling this page) 7 7 0 1% compound of formula (125) 87 76 1 · 5% compound of formula (1 16) / 1% of compound of formula (125) 87 82 1 '5% compound of formula (1 19) / 1% Compound of formula (125) 87 84 1 5% 121) compound / formula 1% (125) 8786

、 1T Imprint of Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Table 3: 20 ° after weathering in 00-4 (high strength) at 0, 1 200 hours, single gloss, double dibenzyl triazine, 0 12 0 0 Undeding 8 7 6 0 -91 ^ The paper scale is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) 44960 7 A7 B7 V. Description of the invention (η) 1.5% of the compound of formula (116) 88 89 1 · 5% compound of formula (119) 85 88 1 · 5% compound of formula (121) 87 90 Table 4: After weathering in QUV-A (high strength) 2 at 0,120 hours ◦ ° Glossy bisdiphenyltriazine and: combination of Finuvin 2 9 2 (HALS) 0 12 0 0 Unstable 87 60 1% compound of formula (125) 87 84 1 · 5% compound of formula (116) / 1% compound of formula (125) 87 9 0 1 · 5% compound of formula (1 19) / 1% compound of formula (125) 87 90 1 · 5% compound of formula (121) / 1% formula (125 ) Compound 87 90 Printed by Shellfish Consumer Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) The results in Tables 1 to 4 show that the samples stabilized by the present invention are more stable than the unstabilized comparative samples. Have better Hou stability example 26: Application of 10 grams of polycarbonate powder (Lex an 115) in polycarbonate, stirring and dissolving in 50 grams -92- This paper size applies to China National Standard (CNS) A4 size (210X297) (%) 44360? A7 B7 V. Description of the invention (The temperature of the methyl chloride in room temperature * The process takes several hours. At the same time, 0 _ 2 grams of UV absorber * equivalent to 0. 2% concentration of additives These solutions were cast into thin films with a thickness of 20 wm. These films were exposed to Atlas Weatherometer C165 * Blackboard temperature was 6 3C, and relative humidity was 6 0T: Timed measurement of the tint of samples * It is used Yellowing index (YI * method is DIN6167). Table 5 shows the exposure time until the yellowing index is 7. Further exposure of the film > to make it shattered, which can be determined by the degree of film cracking and exposure to the shattering site The required time is also listed in Table 5. Table 5: Exposure time (hours) to yellowing index of 7 and fragmentation ), 4- Ding--0

Y 7 Broken Work Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed no 2% formula (1 2 6) compound 2% formula (1 ◦ 2) The compound uses the following UV absorber a)-a compound of the following formula: 9 9 0 10 0 0 k 3 2 0 2 4 8 0 -93- 4 0 5 7 6 0 6 0 The paper wave size is applicable to the Chinese National Standard (CNS) A4 size (210 X 297 mm) 44960 7 Α7 Β7 Economy Consumer Co-operation of the Central Bureau of Standards of the People's Republic of China Du Yin 袈 5. Description of Invention (Gas |)

b) Example lb) A compound of formula (102). Jin Example 27: Polycarbonate was mixed with 0.3% UV absorber of formula (102), and the mixture was processed into granules using a two-roll extruder, with a melting temperature of 275¾ and a rate of 25rpm. Injection molding this particle (24〇 / 300t: / 75bar), a layer of 67x43 X 2mm can be obtained. This layer is exposed to the Atlas Weatherometer C165 (as in Example 25). Table 6 shows the time required until the yellowing index reaches 20 (measured by Y I «D I N 6 1 6 7). Table 6: The exposure time required until the yellowing index (Υ ί) is 1 0 * 1 5, 2 0 UV absorber exposure time (hours) Υ I = 10 15 2 0 -94- This paper size is applicable to Chinese countries 橾Rate (CNS) A4 Washing (210 X 297 mm) · * 4 (I order I (please read the notes on the back before filling out this page) 44960 7 Α7 Β7 Shellfish consumer cooperation cooperation of the Central Standards Bureau of the Ministry of Economic Affairs Sincerity 5. Explanation of the invention (γ) No 3 7 5 6 9 5 9 4 0 Compound of formula (1 ◦ 2) 116 0 1 6 0 0 3 9 5 0 Example 2 8: 10 g of polycarbonate powder (Lexan 115) Dissolve in 50 grams of methylene nitride at room temperature, and the process takes several hours. At the same time, 0.2 grams of UV absorbent of formula (1 16) is also added, which is equivalent to 0.2% Additives. Pour these solutions into 20 / im thick films. Expose these films to Atlas Weatherometer C165 with a blackboard temperature of 6 3 and a cabinet pair of 60. The timing of the sample's discoloration is determined by The yellowing index (ΥΙ, method is DIN6167) is used. Table 7 shows the difference between the yellowing index after 500 and 10 hours and the beginning (△ Υ I) Table 7: ΔΥΙ 5 after UV absorber exposure. Hours 1 0 0 0 hours without 2 '2 7 · 12% Formula (1 1 6) Compound 0 · 5 1 · 1 This paper size is applicable to China's furniture industry Standard (CNS> A4 specification (210 X 297 mm) — '^ Order i " (Please read the notes on the back before filling out this page) 449S0 7 A7 B7 V. Description of the invention (〇) Example 28: Cosmetic application ( 120) Suspension of compound Biphenyl-triazine UV absorbent of formula (120) 3 g C8-Cl2-fatty alcohol polyglycoside 2.4 g sodium chloride 1 g xanthan gum 0.5 g

B r ο η ο ρ ο 1 0.15S Preparation of 93 grams of deionized water. 40 grams of UV absorber. · 20 grams of lipase polysaccharide and 40 grams of water are mixed together, and a ball Grind by a grinder (Drais). The diameter of the particles thus ground will be less than 1 and the remaining ingredients mentioned above will be suspended and mixed with the paste. The results of measuring the sun protection factor (S P F) > and the light floor qualitative * are shown in Table 8. Printed by the Central Labor Bureau of the Ministry of Economic Affairs, Consumer Cooperatives (please read the precautions on the back, and then fill out this page) Table 1 0 Concentration Sunshine Protection Factor *) Light 镲 Qualitative 〃) Formula (120) 3% 19-7 1400 Compound hours *) Measured by Difey and Robson method -96 " This paper size applies Chinese National Standards (CNS > A4 par (210X297 mm) 449607 A7 B7 V. Description of the invention ㈠d) **) in ethanol solution · MDS5 light photochemical decomposition in half the time is high and the stability of the light is high, there is a low degree of concentration and quality. The digital display is a fruit protection and protection of Guangyang (please read the precautions on the back before filling this page) i. Order > Printed by the Central Government Standards Bureau, Ministry of Economic Affairs, Zhengong Consumer Cooperatives, the paper size is general t country national standard ( CNS) A4 (210 X 297 mm)

Claims (1)

4496, The I A8 B8 C3 D8 λ p «1 __________ 衲 charge *; the scope of the patent application is the substitution of i-Hydrazine III with i-phenylbenzene and IHHI species RR ”\-0 9 in which 4; C's .1 substituted group is taken as oxygen Η 4 ο 2 IC -K I and 1 C; the said oxygen ο by-is; its hydrogen is the radical 1 oxygen R垸 CC 4 -------- Order --------- line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs H ο Substituting for I;-ο, S group R oxo ο alkane o S 3 -1 c ICC c or R group ◦ oxygen group C alkane C or cyclic-2 or C1 / 1 / (0 Η (C r Ηc Η C τ Η The size of this paper is applicable to the national standard (CNS) A4 (210 X 297 mm) A8 B8 C3 D8 4 4 9 6 0 7 6. Application scope of patent where T is Η or Ci-C4 alkyl; Rs is氲 or Ci _Ci 2 alkyl; or cyclohexyl or methylcyclohexyl; Rt i and 61 2 are hydrogen, which are mutually exclusive; hydroxyl; one CN; Ci — C4 alkoxy; Ci-C4 alkoxycarbonyl ; Amine carbonyl; or Ri 1 and & 1 2 together form a cyclic countervailing group with phenyl, and is interrupted by one or two lysyl oxygen atoms; q is 0 or 1; and if Q is 0, Ri and Ri 2 are not hydroxyl groups; but do not include the compound fluorene 2- (2-hydroxyphenyl) -4-phenyl-6- (bisphenyl) _1,3'5-triazine. 2 'A compound of formula (1) as claimed in item 1 of the patent scope, wherein Q is 103. A method for preparing a compound of formula (1) as described in item 1 of the patent scope, where Q is 1, including reaction The benzamidine compound of the following formula (5) or (S), and the salicylic acid compound of formula (7), (please read the precautions of S before filling this page) 4 -------- Order ---------- · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) 44960 7 A8 B8 C8 D8 Where: H a i is halogen; is halogen or an ORi; Rs is (: [—Cs alkyl;. &Amp; R i, Ri t and R12 are as defined in item 1 of the patent application range 0 4 A method for preparing a compound tree of formula (1) as described in item 1 of the scope of patent application, which comprises dehydrogenation reaction of a dihydrotriazine compound of the following formula (please read the precautions on the back before filling this page) ------- Order -------- II. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs η This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public love) ^ 9607 AS BS C8 D8 patent application scope where R ij R ii, R i 2 and q are as described in the first patent application Definer. 5 · A method for preparing a compound of formula (1) as described in item 1 of the patent application scope, which includes the preparation of benzoxazinone of the following formula and benzamidine of formula (6) (Please fill in this page for matters) (6) 〇 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs NH. NH HHai, R ί 2 and Q. If the scope of the patent application is under item 1, the paper size in this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 4 49 6 0 7, AS B8 C8 D8 Patent application As defined by the range, Ha 1 i is halogen. S · —Dihydrazine triazine compound toughness (8) Among them, R i > RI 1 2 and Q are the ones defined in the item of patent scope 圔 Mi (please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs A method for preparing a compound of formula (8) of formula 6 in the patent application scope, wherein q is 1, including reaction of a benzamidine compound of formula (5) or (6) and a mole of formula (S) α-Hydroxybenzaldehyde: This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 449607 A8 B8 C3 D8 Patent Application Scope (5) HHa /, (S) NH. HHa / ·, NH ⑼ OH I 0 where R !, Ri 1 and ruler 12 are as defined in item 1 of the patent application garden, and H a 1 t is halogen. 8 · —A benzoxazine 嗣 ^ 1 —1 ^ 1 I nn 1 n I-I-ί---- 1 ^ 1 nn I-一-" Jt nn afa (I (Please read first Note on the back? Matters need to be filled out on this page) This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 public love) Printed by the Economic and Intellectual Property Bureau Employee Consumer Cooperatives AS 44960 7 § \ D8 VI. Application scope of patents among which R i-R 1 1, Ri2 and q is as defined in item 1 of the scope of patent application. 9 * A method for preparing a dish such as the formula (10) of the patent scope M8, which combines the toughness method, including cyclizing the following formula of salicylamine with an acid catalyst in an aromatic solvent And carbonyl hafnium halide Ψ n a 丨 represents the insect atom, and Ri 1 Ri i and Ri 2 are as defined in item 1 of the patent application scope. 1 0 · —seeds, including: A) — organic substances that are sensitive to oxygen and / or heat loss, and B) from 0 '〇i to 15 parts by weight (A) as stable The paper size of the agent applies to China National Standard (CNS) A4 (210 X 297 male 1)-^ · -------! I ------ ^ I, (Please read the precautions on the back first (Fill in this page again) AS 449007 S D8 6. The scope of patent application is for compounds in any one of item i or 2 of the scope of patent application. (Please read the notes on the reverse side before filling out this page) 1 1 茆 The composition of item 10 of the scope of patent application, in addition to ingredients (A) and (B) potential * In addition to one or more other stabilizers or other additives . 1 2 The composition of item 10 of the patent application scope includes a synthetic amidine polymer as an ingredient (A). 1 3 * If the composition of item 10 in the scope of patent application * includes a thermoplastic polymer, coating adhesive or photographic substance as the equivalent (A) The composition of the item includes a coated fluorene adhesive as component (A), and one or more selected from sterically hindered amines and / or 2-hydroxyphenyl-2 fluorene-benzotriazole as other components. Stabilizer for type light stabilizer. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 15 · —Methods for protecting the textiles and maintaining the quality factor of the sun dragon f , Or water-soluble-organically dissolved to the sterilizing substance * and then fix the compound. 16 — A variety of cosmetic preparations, including at least one Chinese national standard (CNS) A4 specification (210 X 297 mm) as the paper size of the patent application model 44960 7 A8 B8 C8 D8 The item that can be used in the previous product is the makeup item Σ and the first item. Fan Guang Xiangli's 1 renminbi in the siege of the siege, such as person 2, is used to 7 with 11 ο first agent _ help, ------------- 3Ί- ------- Order · --------- (Please read the precautions on the back before filling out this page) Printed on paper standards of the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, this paper applies Chinese national standards (CNS ) A4 specification (210 X 297 mm) Application date fJr f l. Case No./Roro A Class I Type _k_ (The above columns are filled by this Office) '--- ~ ----- A4 C4 449607 Weng Jin Patent Specification Chinese Invention New Name English Name Nationality Biphenyl-Substituted Triazines Biohenvl-substituted triazines Inventor 1. Ian. John Boileau 2. Jurgen Kasci 3. George Mez Grid 4. Dieter Reine 5. Pasco Hiots 1. United Kingdom 2. 4. Germany 3. France 5. Houses and residences in Switzerland 1. 4312 Magden, Switzerland, 27 Budenstad 2 Germany 79 丨 04, Schlaisburg, 30 Red Arch Road 3. France 6848Q Monach, No. 228 Heilang Road 4. Germany 734Q Camden, No. 10 Wolf Trail 5. Switzerland 1 7 2 3 Mary, All Mongolia Tower Order No. 6 (Name) Ciba Specialty Chemicals Holding Co., Ltd., Ministry of Economic Affairs, China Bureau of Standards, Bureau of Economic and Social Affairs, Consumer Cooperation. Tu α 1, Applicant Nationality Residence, Residence (Office) Representative Name No. 141, Klebe Street, Ernst 1. Ernst Atter Hale, 2. Hans-Petter Wittling This paper is sized for the Chinese National Standard (CNS) Α4 (2ΙΟχ 297) (Wide) 4496, the present I A8 B8 C3 D8 λ p «1 __________ 衲 charge *; the scope of patent application for the substitution of the compound hydrazine three is substituted by the i-phenylbenzene formula IHHI species RR ”\-0 9 in which 4; C's .1 substituted group is taken as oxygen Η 4 ο 2 IC -K I and 1 C; the said oxygen ο by-is; its hydrogen is the radical 1 oxygen R垸 CC 4 -------- Order --------- line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs H ο Substituting for I;-ο, S group R oxo ο alkane o S 3 -1 c ICC c or R group ◦ oxygen group C alkane C or cyclic-2 or C1 / 1 / (0 Η (C r Ηc Η C τ Η This paper size is applicable to the national standard (CNS) A4 (210 X 297 mm)