TW406104B - A mixture containing three different monodispers block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials - Google Patents

Abstract

Compounds of the formula (I) in which the polydispersity Mw/Mn is 1; n is 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 or 15; the radicals R1 are for example hydrogen or C1-C8alkyl; R2 is for example C2-C12alkylene; the radicals A are independently of one another -OR3, -N(R4)(R5) or a group of the R3, R4 and R5, which are identical or different, are for example hydrogen or C1-C18alkyl, or -N(R4)(R5) is additionally a group of the formula with Y being -O-, -CH2-, -CH2CH2- or >N-CH3; X is -O- or >N-R6; R6 is for example hydrogen or C1-C18alkyl; R is preferably a group of the formula and the radicals B have independently of one another one of the definitions given for A; with the proviso that in the individual recurrent units of the formula (I), each of the radicals B, R, R1 and R2 has the same or a different meaning. The indicated compounds are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.

Description

A7 V. Description of the invention (40610¾ The present invention relates to a 6, 6-tetramethyl monoorganic light spike fixing agent, is a synthetic polymer, and Guan Ming relates to a mixture in which three different blocks are copolymerized into a polymer M 2 has been disclosed in, for example, U_A-4, 3 3 1 1 42; US-A-4 7,223 and EP- The present invention relates to a single special block oligomer having 2, 2 4 — Piperidinyl, the present invention also relates to its use as a thermal stabilizer and an oxidation stabilizer, especially to organic substances that are stabilized by this. Furthermore, the present invention has a narrow molecular weight distribution and has at least a substance, and Its preparation method. 2,6,6-tetramethylpiperidine derivative stable 5-A-4'086 * 204; US 586; US-A-4 * 335 * 2, 234,707; EP-A- 35 A-377, 324 ° Specific compounds of formula (I): A.

· Ν · I Printed by the Central Standards Bureau of the Ministry of Economy

A (I) where the polydispersity Mw / Mn is 1; n is 3, 4, 5, 6 * 7, 8, 9, 10, 11, 12 1 3, 1 4 or 1 5; -6- This paper size applies Chinese National Standard (CNS) A4 specification (210'〆297 mm) —-.—------ installation ------ order l · -----: line (please first Read the notes on the back and fill in this page) A7 B7 Reactive groups Ri are independent of hydrogen, Ci -Cs alkyl 'C2 ~ C8 via radicals' —CHz CN 'C3 — Cs dilute' C3 —Cs Alkynyl, C7-C9 phenylalkyl, which is unsubstituted or substituted on the phenyl via 1 * 2 or 3 Ci-10 alkyl; or C1-C8 pentyl; R2 is C2 — cl2 alkylene group, C4-(: 12 alkenyl group, Cs, Cs — C7 cycloalkane one two (Ci — C4 alkanyl (C5-C7 cycloalkylene), phenylene di (Ci — C4 comprehensive ) Or C4-Ci 2 heald, which is composed of 1, 4-C 7 cycloalkylene C 1-C 4 -C 4 alkylene) or C 4-C, 2 morphazine diyl, 10— or > 1 ^ — Xi, 乂 1 is (: 1— <: 12 phenyl or (Ci_Ci 2alkoxy) carbonyl, or has one of the definitions of R # under M, but does not include hydrogen; or R2 Formula (a), (b) or (c) of Qunji: Ministry of Economic Affairs Bureau HIGHLAND central standard rate of consumer cooperatives printing equipment

—CH | —CH—CH ^ 01 c = o I This paper size applies Chinese National Standard (CNS) A4 (210X297mm) gutter (please read the precautions on the back before filling this page) ⑻ (b) A7 B7 406Ϊ04 V. Description of the invention (⑹ m is 2 or 3; X2 is 〇1—Ci 8 alkyl group, Cs—Ci 2 cycloalkyl group> It is unsubstituted or via 1, 2 or 3 C i — C 4 alkyl substituted; phenyl, which is unsubstituted or substituted via 1, 2 or 3 Ci —C 4 alkyl or Ci — C 4 alkoxy; C 7-C 9 phenyl alkyl, which is unsubstituted Substituted or substituted on phenyl via 1, 2 or 3 Ci—C4 alkyl groups; and X3 reactive groups that are not related to each other are C2-Ci 2 alkylene groups; reactive groups A that are unrelated to each other are one 0R3, -N (R 4) (RS) or the group basis of the following formula (II): 丨 丨 .——.---------------- l · Order —----- line (please (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

(II) -8 This paper size is in accordance with Chinese National Standard (CNS) A4 specification (2 丨 0 X 297 mm) 5. Description of the invention (Li 610 4 A7 B7 R 3, R4 and Rs are the same or different, they are hydrogen , Ci — C! 8 alkyl, Cs-Ci 2 cycloalkyl, which is unsubstituted or substituted via 1, 2 or 3 Ci — C4 alkyl; C3 — Cs alkenyl, phenyl, which is Unsubstituted or substituted via 1,2, or 3 (: 1-C4 alkyl or Ci-C4 alkoxy; C7-Cs phenylalkyl, which is unsubstituted or via 1, 2, or 3 Each 〇1-C4 alkyl group is substituted on a phenyl group; tetrahydrofuranyl or C2-C4 alkyl group, which is at the 2, 3 or 4 position via mono-OH, -Cs alkoxy, di (Ci- C4 alkyl) amino or a group of the formula (III):

Y N- (III) Y is —◦ —, — CH2 —, — CH2 CHz ~ or > N-C Η 3, or -N (R 4) (R 5) is also a group base X of formula (III) Yes-0 — $ > N — Rs; -----: -------- install -------- ^ order h ----- line (please read the precautions on the back before filling this page ) Poly-alkyl, C3-Cl8 alkenyl, C5-Ci 2-cycloalkyl, which are unsubstituted or substituted with 1, 2 or 3 Ci-C4 alkyl groups; C7 —C9 phenylalkyl, which is unsubstituted or substituted on the phenyl via 1, 2 or 3 Ci —C4 alkyl groups; tetrahydrofuranyl, a group group of formula (IV) below, 9- this paper Standards are applicable to China National Standard (CNS) A4 specifications (210X297 mm) i A7 Employee Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs

, 4WM 5. Description of the invention (<)

Or C2—C4 alkyl, which is substituted at the 2 * 3 or 4 position by —0Η Ci—Cs alkoxy, bis (Ci—C4 alkyl) amino or a group of formula (III); R has one of the definitions of Rs; and the reactive groups B are unrelated to each other as defined by A above; its limitation is that in each repeated unit of formula (I), each B, R, and 1 ^ 2 have the same Or different definitions. In the repeating unit of formula (I), the reactive group R and the reactive group of formula

Can have a scattered or block distribution. Examples of alkyl groups containing not more than 18 carbon atoms are methyl, ethyl, propyl, isopropyl, butyl, 2-butyl, isobutyl, tert-butyl, pentyl, 2-pentyl , Hexyl, heptyl, octyl, 2-ethylhexyl, tert-octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl And octadecyl. C2 — Cs hydroxyalkyl and C2 substituted by —〇H — C4 -1 0- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) --.-- ^ ----- pack- ----- ^ Order ------ line (please read the precautions on the back before filling this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 --406104-V. Description of Invention An example of an alkyl group is 2-hydroxyethyl. Via Ci-Cs alkoxy, preferably C2-C4 alkyl substituted by Ci-C4 alkoxy, especially methoxy or ethoxy Example 2-methoxyethyl, 2-ethoxyethyl Group, 3-methoxypropyl, 3-ethoxypropyl, 3-butoxypropyl, 3-octyloxypropyl and 4-monomethoxybutyl. Via a bis (Cl-C4 alkyl) amino group, preferred examples of C2-C4 alkyl substituted by dimethylamino or diethylamino are 2-dimethylaminoethyl, 2-diethyl Aminoaminoethyl, 3-dimethylaminopropyl, 3-diethylaminopropyl, 3-dibutylaminopropyl and 4-diethylaminobutyl. The group base of formula (I I I) is preferably:

A preferred example of a C2 — (: 4 alkyl group substituted by a group of formula (III) is a group of the formula: V_ / N— ~ (CH4r ~ ο The group of the following formula is particularly preferred: 0 -11- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ----- ^ ----- installation ------ ^ order l · ----- line (please read the back first Please pay attention to this page, please fill in this page) A7 40β1Π4 B7_ printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (j) Examples of alkoxy groups containing no more than 8 carbon atoms are methoxy, ethoxy, and propoxy Group, isopropoxy, butoxy, isobutoxy, pentyloxy, isopentyloxy, hexyloxy, heptyloxy or octyloxy. Unsubstituted or via 1, 2 or 3 C ^ Examples of Cs-Ci 2 cycloalkoxy substituted with a C 4 alkyl group are cyclopentamidine, methylcyclopentyl, dimethylcyclopentyl, cyclohexyl, methylcyclohexyl, dimethylcyclohexyl, Trimethylcyclohexyl, tert-butylcyclohexyl, cyclooctyl, cyclodecyl and cyclododecyl. Unsubstituted or substituted cyclohexyl is preferred. It contains no more than 18 carbon atoms An example of alkenyl is allyl , 2-Methylallyl, butenyl, undecenyl, and octadecenyl. Among them, alkenyl having a saturated carbon atom at the first position is preferred, and allyl is particularly preferred. Examples of alkynyl are 2-butynyl. Examples of phenyl substituted by 1, 2 or 3 C! -C4 alkyl or Ci-C4 alkoxy are methylphenyl, dimethylphenyl, tris Methylphenyl, tert-butylphenyl, di-tert-butylphenyl, 3,5-di-tert-butyl-4 -methylbenzyl, methoxyphenyl, ethoxyphenyl And butoxyphenyl. Examples of C7-C9phenylalkyl, unsubstituted or substituted on phenyl via 1, 2 or 3 Ci_C4 alkyl are benzyl, methylbenzyl, dimethyl Benzyl, trimethylbenzyl, tert-butylbenzyl and 2-phenylethyl. Benzyl is preferred. Amidino (aliphatic, cycloaliphatic or aromatic) containing no more than 12 carbon atoms Fan series) Examples are methylamido * ethylamyl, propylamyl, butylamyl, pentam-12- This paper size applies to China National Standard (CNS) A4 (210X297 mm)!-! ^ ----- ----- hirl · ----- line (Please read the precautions on the back first (Fill in this page) A7 406104 B7 V. Description of the invention ((Γ) 1,2,4-fluorenyl, hexyl, heptyl, octylfluorenyl and benzamidine are preferred. B (C i — C! 2 alkoxy) ethoxycarbonyl, propoxycarbonyl, butoxycarbonyl, heptyloxycarbonyl, octyloxycarbonyl, undecyloxycarbonyl and ten containing no more than 12 carbon atoms, trimethyl Supports four, four, five, and twelve. R 2 is, for example, C 2, especially C 2 -C 6 alkylene, C 4 -C! 2 ethylenic examples. Cs -C 7 cycloalkylene examples. Bases in oxazine diyl, and benzamidine. Ci — C8 fluorenyl is particularly preferred. Examples of carbonyl are methoxycarbonyl, oxycarbonyl, pentoxycarbonyl, hexylcarbonyl, nonoxycarbonyl, decoxydialkoxycarbonyl. Examples of the alkylene group are ethylene, propylene, hexamethylene, octamethyl, decamethyl-C8 alkylene or C4-C8 alkyl, preferably hexamethylene. For 3-hexene. For the ring itself. Example of a broken C4 2 alkylene (Please read the precautions on the back before filling this page) -9

-CH, CH0—N Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs.

Examples of Ci 2 alkylene are 3-oxopentane-1,5-diyl, 4-monoheptane-1,7-diyl, 3,6-dioxaoctane-1, 8-12 Base, 4,7-dioxadecane-1, 10-diyl, 4,9-dioxadodecane-1, 12-diyl, 3, 6, 9-trioxane-1 3 Paper size applies Chinese National Standard (CNS) A4 specification (210X297mm> 406104 b7) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (OM 1 1 Eleven Institutes 1 $ 1 1 — 2 bases and 4 S 7 > 1 0 —Trioxatridecane 1 1 | — 1 9 1 3 Diyl 0 1 1 Interrupted by> N — X C 4 — C 1 2 Examples of alkylene are 1 1 1 '— C Η 2 C Η ZC Η 2 — N (X 1) — C Η 2 C Η ZO_N Read back I side (XX) — C Η ZC Η Zn C Η ZO -9 9 Especially: Winter 1 I _ C Η 2 C Η 2 C Η 2 — N (C Η 3) — C Η 2 C Η 2 — Event 1 1 N (C Η 3) — C Η Zn C Η 2 C Η Z — 0 Refill 1 Write 1 C 5 — C 7 The example of the circle courtyard support (C 1 — C 4 courtyard support) is IS3 m This page has been supported by the second support 0 1 Examples of 1 C 1 — c 4 academic diene (C 5 — C 7 cycloalkane) are methyl 1 I dicyclohexyl and isopropylidene dicyclohexylene 0 1 1 · order phenylene di (C 1 1 An example of C 4 is phenylene dimethyl OR, preferably hydrogen C 1 —CX 0 or cyclohexyl or —. Group bases of formula (1 1 IV), especially group bases of formula (IV) 0 1 | Reactive group R 1 is preferably MC 1-C 4 fluorenyl allyl 1 linear i benzyl or ethenyl 0 hydrogen and methyl are particularly preferred 0 i trans OPg fluorenyl B is preferred Is N — (2) 2 > 6 6 — tetramethylammonium 1 1 pyridine — 4 monoyl] butylamino group N — (1 f 2 2 6 6-penta-1 I methylmorphine — 4 —yl) butylaminodibutylamino »1 9 1 3 1 1) 3-tetramethylbutylamino or 4-morpholinyl 0 1 1 1 The variable η is preferably 3» 4 > 5 > 6 9 7 9 8 9 9 * 1 0 1 9 1 1 i 1 2 or 1 3 e.g. 3 »4 t 5 6 ί 7 8 $ 9 1 9 1 0 or 1 1 and 3 9 4 f 5 > 6 9 7 8 or 9) Especially 3 1 I-14 1 1 1 This paper size applies to Chinese National Standard (CNS) A4 specification (210X29? mm) A7 B7-; 4Ό61M 5. Description of the invention (/ p ), 5 or 7 ° Polydispersity represents the molecular weight distribution of the polymer compound. In the present invention, the degree of polydispersity is the ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mη). A value of Mw / Mn of 1 means monodisperse, only one molecular weight, and no molecular weight distribution. Preferred spring embodiments of the present invention pertain to a compound of formula (I), wherein: η is 3, 4, 5 * 6, 7, 8, 9, 10, 11, 12, or 13; the reactive groups R! Are not related to each other. Are hydrogen, C〗 -Cs alkyl, _CH2 CN, C3 — Cs dilute, C7 — Cs phenyl alkyl, which are unsubstituted or have 1, 2, or 3 C on the phenyl! — C4 alkyl substituted; or C i -C 8 fluorenyl; R 2 is C 2-Cl 2 alkylene, CS — C ·? Cycloalkane, Cs — C 7 cyclopentadiene (Cl — C 4 fluorene), Cl — Burned diene (cs —C7 cycloalkylene) or phenylene di (Ci -C4 alkylene); printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, R6 is hydrogen, Ci — c18 alkyl, cs — cl2 cycloalkyl, Is unsubstituted or substituted via 1, 2 or 3 Ci-C4 alkyl groups; C7 ~ C9 phenylalkyl, which is unsubstituted or substituted by 1 '2 or 3 Ci-C4 Alkyl substituted; tetrahydrofuranyl, a group of formula (IV) or a C2_C4 alkyl group, which is in the 2, 3 or 4 position by a 10H, C!-C8 alkoxy group, di (Ci -C4 alkyl) -1 5-This paper size applies to China National Standard (CNS) A4 specification (210X297 C) A7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ------ rrt〇6104 ---- V. Description of the Invention (//) Substituted by an amino group or a group of formula (III); and R is a formula ( IV) The group base. Preferred compounds of formula (I,) are: wherein R2 is C2-C10 alkylene, cyclohexylene, cyclohexylene di (C! -C4 alkylene), Ci-C4 alkylene dicyclohexylene or benzene Dialkyl (Ci-C 4 alkylene); R 3 ′ and Rs (same or different) are hydrogen, C! -Ci 2 alkyl * Cs —C7 cycloalkyl, which is unsubstituted or via 1, 2 or 3 Ci-C4 alkyl substituted; C3-Ci 2 alkenyl, phenyl, which is unsubstituted or substituted via 1, 2 or 3 (: 1-C4 alkyl; benzyl, which Is unsubstituted or substituted by a Ci-C4 alkyl group on a benzyl group; tetrahydrofuranyl or C2-C3 alkyl group, which is in the 2 or 3 position by a 10H, Ci-C4 alkoxy group , A di (Ci-C4 alkyl) amino group or a group of the formula (III) is substituted; or -N (R 4) (Rs) is another group of the formula (III), and Re is hydrogen, Ci — C12 alkyl, Cs — C7 cycloalkyl, which is unsubstituted or substituted via 1, 2 or 3 C i -C 4 alkyl; benzyl, which is unsubstituted or is substituted by phenyl 1, 2 or 3 Ci ~ C4 alkyl substituted; tetrahydrofuranyl, a group of formula (IV) or Cz-C3 Group, which is substituted at the 2 or 3 position by mono-OH, Ci ~ C4 alkoxy, di (Cz_C4 alkyl) amino or a group of formula (III). Particularly preferred compounds of formula (I) are Among them: -16- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) ----- ^ ----- installation ------- order ------- (Please read the notes on the back before filling in this page) 406104 B7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (丨 > 0 R 2 is C 2 _ c S alkylene; R4 and Rs (same or different) are hydrogen * Ci-C8 alkyl, cyclohexyl, which is unsubstituted or substituted via methyl; C3-C8 alkenyl, phenyl, which is unsubstituted or Substituted via a methyl group; benzyl, tetrahydrocarbyl, or C2-C3 alkyl at the 2 or 3 position by monoOH, Ci-C4 alkoxy, dimethylamino, diethylamine Or 4-morpholinyl; or N (R4) (Rs) is additionally 4-morpholinyl; and R6 is hydrogen * Ci-Cs alkyl, cyclohexyl, which is unsubstituted or via Methyl substituted; benzyl'tetrahydrofuranyl * of formula (IV) Group or C2-C3 alkyl, substituted at the 2 or 3 position by mono-OH, Ci-C4 alkoxy, dimethylamino, diethylamino or 4-morpholinyl. Particularly advantageous The compound of formula (I) is: wherein: η is 3, 5 or 7; the fluorenyl groups Ri are independently related to hydrogen or methyl; R2 is C2 to Cs; the reactive groups A are independent to each other. N (R4) (R5) or a group of formula (II); R4 and Chi 5 (same or different) are hydrogen, Ci—Cs alkyl, 2 monohydroxyethyl or 2-methoxyethyl or 1 N (R4) (Rs) is another 4-morpholinyl group; X is〉 N-R s; -17- (Please read the precautions on the back before filling this page) This paper size applies Chinese National Standard (CNS) A4 Specification (2 丨 0x297 mm) A7406104 B7 \ — / η) ί_— / __ \ Explain that the first five and the combination of \ 1 »/ 〇X are one of the formula 1 meaning eight Αchemicals in the fixed substance Such as 丨 •, TX base with alkane formula 4 Bm 6μ C phase is good I don't differ 1 mutual CBS is radical and its 6 should be R reverse

A N ·

: N

N -1 R

AI (Please read the notes on the back before filling this page) The Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs printed η, A, B, R, Ri and {? 2 with the above definitions, and B has the same as B The definition is: (1) B is different from B, and (2) each reactive group B > R, Ri and R2 have the same definition in each repeated unit. Preferred compounds of the formula (X) are: wherein η is 3, 5 or 7; the reactive groups Ri are independently related to hydrogen or methyl; R 2 is C 2 -C 6 alkylene; reactive groups A and B are (Which is the same) is -N (R4) (R5) R4 and Rs (same or different) are hydrogen > C, -C8 alkyl * 2 monohydroxyethyl or 2-methoxyethyl or -N (R4) (Rs) is another 4-morpholinyl group; B is a group group of formula (II), Ri is as defined above; this paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A74M1G4-^-V. Description of the invention (/ #) X is > N-R s; R6 is Cl-C4 courtyard; R! Is as defined above; its limitation is that each reactive group B, R, Ri and 1 ^ 2 has the same definition in each repeated unit formula. A preferred embodiment of the present invention is a mixture containing at least three different compounds of formula (I) * preferably formula (X), which only varies with the value of η, and the mixture has a polydispersity M w / Μ η values 1 · 1 to 1 · 7, such as 1 · 1 to 1 · 65, 1 · 1 to 1 · 6, 1. 1 to 1. 55, 1 '1 to 1 · 5, preferably 1 · 1 to 1 1 · 45 or 1 · 1 to 1 · 40, especially 1 · 1 to 1 · 35 7 IX to '5 6 IX · ♦ 1 × 1 to 5 sons 1 case · It'—I its, 5 η 6 Μ . \ 1 W to Μ 5 degrees 1 scattered.

τ ± 1X 1X a

A

Is another special best ’than ο, 4 5. ♦ 1 1 to 5 5 1 1 ♦» 1 1 or:,,. 5 5 5 packs 5 4 3 things)-· * Combine a 1X 1 ± IX XI to to 丨 LQLOLO style 1 1 1 Compared

1N binding line (please read the precautions on the back before filling this page)

N

/ Ya B

N

N-R

This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 5. Description of the invention (/ ^) AQU04 A7 B7 t >) Formula (lb), and

> 1 N > CH3 ch3 1 5 丨 γ 丨

• A (lb) c) compounds of formula (I c)

(lc) Eight, eight, only one, and only one and two feet 2 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs are the same in formulas (1 &), (lb) and (I c), and as defined above, And the ratio of the compounds of formulae (la) and (Ib) and (Ic) is 2: 1 · 5: 1 to 2: 0.5: 0.05, especially 2: 1: 0.5 to 2: 0 · 5: 0.08 Or 2: 0,75: 0.3 to 2: 0,5: 0-08 ° The compound of formula (la) is preferably equivalent to the compound of formula (X a): -20- This paper size applies Chinese national standards ( CNS) A4 specification (210X 297 mm) -----; ----- installation ----- order -------- line (please read the precautions on the back before filling this page) 406104-5. Description of the invention (/ ^)

A

A type N. • Β · Ν ·

: N .Β *

R2-H3CH3C

A X / IV Formula 1 is better than the equivalent compound (please read the precautions on the back before filling this page)

-Load I, ιτ

A L (xb Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs and

The compounded \ 1 / C X / tv formula is better than the current compounded compound \ — »C This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm)

V. Description of the invention G A- ΝγΝ Β * A · A- 406104 A7 B7 Ν-1¾-

R ρρ I on the basis of κR into chR, γ 1 Β H3Cy ^ N ^ CH3 Ri f 7rA N ~ N (Xc) Β * The mixture shown may additionally contain a compound of formula (I d), such as a compound of formula (X d) , Ν,, Ν, (Id) Ν 丫 Ν Β Ν ·

CH, Ν 丫 Ν Β * binding line (please read the notes on the back before filling out this page) Printed by the consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs

A (Xd) and / or a compound of formula (I e) -22- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 406104 a? B7 V. Description of the invention (I 丨)

B

Β le) --------- 装 — (Please read the notes on the back before filling this page)

R some 9 these 2 8 A- SU in the common knowledge is the combination of materials ο 5 2 2 4 4 4 I A- 5 U and 8 rh The best mix is better than the total, from% to 5 phases. / Ίν ο% to 5%. Ο ο 3 to 8% or 8% or 5% of the deposit. Goods ο Combine to the Central Bureau of Standards of the Ministry of Economic Affairs employee consumption Cooperatives printed instructions. } In the calculation formula, it is said that the compound of the compound is the compound of the compound, the compound of the compound, the compound of the compound, the compound of the compound, and the compound of the compound. The combination of one thing and one's compound QCJ -Ml ,. Special b This paper size is applicable to Chinese National Standard (CNS) A4 specification (2 丨 0'〆297 mm) 5. Description of the invention (/ 406104 A7 B7 mutual Irrelevant ones are hydrogen or methyl;

The reactive group RR 2 is a group group of CA and B ((II), R i is as defined above; R 4 and R 2 -C 6 alkylene; the same or different) is n (r4) (r5) or Hydroxyethyl 5 (same or different) is hydrogen, Ci—C8 alkyl, 2- or 2-methoxyethyl, or N (R4) (Rs) is additionally 4-monomorpholinyl; X is > NR s; R6 is Cl — C4 alkyl; and R is a group radical of formula (IV), and Ri is as defined above. Another particularly preferred mixture is a compound in which three different compounds of formula (I) correspond to formulae (X a), (X b) and (X c), wherein the reactive group RR 2 is a C 2 -C s alkane The unrelated ones are hydrogen or methyl respectively; A and B * (same or different) are a N (R4) (Rs), or a group-based gutter of type (II) (please read the note on the back first) Please fill in this page again for details) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (same or different) is hydrogen, Ci ~ C8 alkyl, 2 monohydroxyethyl or 2-methoxyethyl, or N (R4) (Rs) is another 4 and B is a morpholinyl; (II) a group base, R i is as defined above; X is> N-R 6; Rs is Cl 104 alkyl; and -24- This paper size applies to China National Standard (CNS) A4 (210X 297 mm)

A7 --4Μ4Λ4 —— ^-V. Description of the invention (W) R is a group group of formula (IV) 'Rt is as defined above; it is limited to each reactive group B of each repeating unit in this chemical formula * R, Rt and only 2 have the same definition. A and B meters (same or different) are preferably a group of N (Ci — Cs alkyl) 2 or the following formula: A and B meters are particularly the same and are N (Ci — Cs alkyl) 2) Another preferred embodiment of the present invention is a method for preparing a mixture of different compounds of formula (I) having the above-mentioned polydispersity and including at least three different compounds of formula (I). (Please read the notes on the back before filling out this page) Printed by the Department of Economics, Central Bureau of Standards, Consumer Cooperation

B reacts with a compound of formula (B) -2 5-

This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) Α7 4tQ61Q4 87 V. Description of invention (/!)

Order (please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 2) Make the compound of formula (C) and the compound of formula (B) react at a reaction ratio of 1: 2 to 1: 3, preferably 1: 2 to 1: 2'5, especially 1: 2, a mixture comprising at least three different compounds of formula (D) is obtained, where η is 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, or 15, or 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, or 12, preferably 3, 4, 5 , 6, 7, 8, 9, 10 or 11, or preferably 3, 4, 5, 6, 7, 8 or 9, especially 3, 5 and 7; -26- This paper size applies to Chinese national standards (CNS) A4 specifications (210X297 mm) A7 V. Invention Day

Η-Ν-R2 R

Ya

(D) 3) reacting the mixture obtained in 2) with a compound of formula (E):

(E) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs The reaction ratio is about stoichiometric ratio, and the desired mixture can be obtained. The reactions 1) to 3) are performed in the presence of an organic solvent and an inorganic base. A particularly preferred embodiment of the present invention relates to a method for preparing a mixture having the polydispersity shown above and comprising at least three different compounds of formula (X), including the reactions 1) to 3) described above, but it is limited to using a formula ( E to) compounds

A (E *) -27- This paper size applies to Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) IIIII nnn I ^ III n line (Please read the precautions on the back before filling this page) Α7406104_ Economy Member of the Central Standards Bureau of the Ministry of Consumers, Co-production of Du Du, V. Invention Description (1) Substitute the compound of formula (E). Examples of suitable organic solvents are toluene, xylene 'trimethylbenzene, cumene, diisopropylbenzene, and mainly organic ketones which are insoluble in water, such as methyl ethyl ketone and methyl isobutyl ketone . Xylene is preferred. Examples of inorganic bases are sodium hydroxide 'potassium hydroxide' sodium carbonate and potassium carbonate. Sodium hydroxide is preferred. Reaction 1) is performed, for example, at a temperature of 401 to 70 t: ', preferably 50 to 601. Reaction 2) is carried out, for example, at a temperature of 110 ° C to 180 ° C, preferably 1401 to 160C. The reaction 3) is carried out, for example, at a temperature of 110C to 180C, preferably from 140 to 1601. Possible by-products are the compounds of formulae (1d) and (1e) above. The compound of formula (A) can be prepared, for example, by using cyanuric chloride and a compound of formula B-fluorene in a stoichiometric reaction in the presence of an organic solvent and an inorganic base. Furthermore, compounds of formula (E) or (E to) can be obtained, for example, by reacting monocyanuric chloride and compounds of formulas A — Η and B — 或 or compounds of B m — Η, M — stoichiometry and organic solvents. Reaction in the presence of an inorganic base 0 It is appropriate to use the above reactions 1) to 3) to prepare the same solvents for the compounds of formula (A) and (E) or (E), and the same inorganic base. The starting material used in the above method is conventional. * In its uncommercial one. 2 8 · --.--: -----. See II (Please read the precautions on the back before filling this page) Order Ni! This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 406104 A7 B7 V. Description of the invention cyf) (Please read the precautions on the back before filling this page) In the case of production, K can be similar Prepared according to the method 'for example some starting materials of formula (B) are described in WO-A-95 / 2 1 157, US-A-4,316,837 and US-A-4,74 3 * 6 8 8 ° An embodiment of the invention is also a mixture obtained from the method described above. The intermediate of formula (D) is novel and is another embodiment of the present invention. In addition, the present invention relates to a mixture containing at least three different compounds of formula (D), which changes with the value of η, and the mixture has a polydispersity Mw / Mnl · 1 to 1 · 7. The preferred embodiments of the variable η and the reactive groups R, Ri, R 2 and B of the compound of the above formula (I) are also related to the intermediate of the formula (D). The compound of formula (I) or (D) having a polydispersity Mw / Mn of 1 can be prepared step by step. Some representative examples of this step are shown below: The Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (I) is a compound of formula (I), where R is a group group of formula (IV), and η is 3, which is convenient According to the reaction mechanism I-1, a compound of formula (F) is obtained by reacting a compound of formula (E) with a large excess of a compound of formula (B). The molar ratio of the compound of formula (E) to the compound of formula (B) is, for example, 1: 4. Reaction mechanism I-1 1: -29- This paper size applies the Chinese National Standard (CNS) ΑΊ specifications (210 × 297 mm) A7 406104 π 5. Description of the invention (<).

Next, the compound of formula (F) can be combined with the compound of formula (C), and the reaction ratio is stoichiometric to obtain the desired compound (described in the reaction mechanism I I -2). Responsive Agency II-12: Ordering (please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs -30- This paper size applies to Chinese National Standard (CNS) A4 specifications (2〗 0 × 297 Mm) A7406104 b7 V. Description of the invention (β)

R, R, (F)

R, R, (C)

Printed bags of employees of cooperative bureaus of the Central Standards Bureau of the Ministry of Economic Affairs II) Compounds of formula (I), where R is a group group of formula (IV), and n is 4, which can be conveniently based on the reaction mechanism II _ 1, which is represented by reaction formula (F ) Compound and a compound of formula (A) * The reaction ratio is a stoichiometric ratio to obtain a compound of formula (G). Reaction mechanism II ~ 1: -3 1- This paper size applies Chinese National Standard (CNS) A4 specification (210X297mm)-; --.----- ^ .----- 1T --- ---- i (Please read the notes on the back before filling this page) __4061Π4Five 'invention description (/)) B7 -N— r2 —NH I ^ Chl3 H3C ^ 〇zCH3 I, ch3 h3c' I \ ch3 1 (F) 1 R, +

Cl—I iP " c,

B ㈧

Cl (G) The compound of formula (G) can then be reacted with a large excess of the compound of formula (B) to obtain a compound of formula (VII) (shown in reaction mechanism I I-2). The reaction ratio of the compound of the formula (G) and the compound of the formula (B) may be, for example, 1: 4. Responsive Agency II-12:! I n Ordering (please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs -32- This paper size applies to Chinese National Standard (CNS) A4 specifications 210X297 mm) 406104 A7 B7

Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (Η) Next, the compound of formula (Η) can be reacted with the compound of formula (A) in a stoichiometric ratio to obtain a compound of formula (K) (based on the reaction mechanism II-3) ° Reaction mechanism II _ 3: -33- This paper size applies Chinese National Standard (CNS) A4 (210X 297mm) 406104 A7 B7 V. Description of the invention (> 1 I?

-N- H3C

-R2-N

CH, T il-N ΝγΝ R H3C

CH3 H3C h3c R, R

ch3 h3c

CH, H3C? CH, H.c ^ CH 'CH3 H3C ’Fly, CH3H3CT, CH, (H)

(A)

-HCL

A

I — gutter (please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (K) III) —Compounds of formula (I), where R is a group of formula (IV) -34 -This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X 297 mm) 406104 A7 B7 5. The explanation base of the invention, η is 5, it is convenient to react the compound of formula (式) and compound of formula (C), the reaction ratio Is a stoichiometric ratio to obtain a compound of formula (L) NΗ 2 A ~ f Ίϊ

(Η)

Printed by CI Consumers Cooperative, Central Bureau of Standards

35- This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) Thread setting (please read the precautions on the back before filling this page) A7 A7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 40M64-^- V. Description of the invention (\ I) Reverse reactions 1) to III) are, for example, in an organic solvent, such as toluene, xylene, and xylene, and in the presence of an inorganic base, such as sodium hydroxide, at a temperature of K l 〇t to 180 ° C, preferably from 401 ° to 160 °. When the compound of formula (I) is equal to the compound of formula (X), the relative compounds of formula (xa), (Xb) and (Xc) can be similar to the above reaction mechanism, and a compound of formula (E to) is used instead of the compound of formula (E) Prepared. The intermediate of formula (D), wherein η is, for example, 3, and has a polydispersity Mw / Mn value of 1, which can be prepared, for example, by reacting a compound of formula (C) and a compound of formula (B), the reaction ratio is 1: 1 〇 to 1: 50, preferably 1: 20 to 1: 40, especially 1: 2 to 1: 35. This reaction can be performed, for example, in an organic solvent or only in the presence of an inorganic base. The solvent and / or excess of the reactant of formula (B) can be removed by distillation under appropriate conditions; examples of organic solvents are toluene, xylene, trimethylbenzene, isopropylbenzyl and diisopropylbenzene. Xylene is preferred. Examples of inorganic bases are sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate. Sodium hydroxide is preferred. This reaction can be carried out at a temperature of 1 1 OC to 1 80 ° F, preferably 1 40 ° C to 16 0 ° F. The compound of formula (I) and the above-mentioned mixture having a narrow molecular weight distribution are very effective for modifying the light, heat and oxidation resistance of organic substances, especially synthetic polymers and copolymers. Especially low pigment interaction and good color can be observed in polypropylene, especially polypropylene fibers. -36- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 mm) IIIIIIII Pack IIII order-II line (please read the precautions on the back before filling this page) 5 406104 A7 B7, invention description can Examples of stabilized organic substances are: polymers of mono- and di-olefins, for example, polypropylene butadiene-1, polymethyl-4-methylpentane-1, polyisobutylene, or polyisobutylene Tabletene (Uncrosslinked high molecular weight MDP Ethylene (ene, poly, polyiso-ortho-ortho-linked or densified and ultra-high ethylene (density poly (please read the precautions on the back before filling this page)) Central Standard of the Ministry of Economic Affairs Printed by the Bureau's consumer cooperatives, polybutylene η 〇) the amount of polyethylene E) LL statutes a) b) more than gold, and / or materials available, chlorine insoluble, diene, rb 〇, such as polymer Vinylene (Η, low-density DPE, polyolefin monoolefins are prepared freely for one week, these halides are arylated to free titanium (for polymerization or to make TT rm ΛιΆ and cycloolefin rue high density)(HD D Ρ Ε Degree polyethyl), branch, that is, polymer, special polymer catalysts on the periodic table of metal link, fermented esters, its state or III boundary with activated PE--U pinene (L bond is low-density, monoene, especially the following compound (catalyst poly IV b often has, ester, but 71 is fixed at), aluminum, and this agent, typical compounds, such as polyethylene ((HD Ρ E Η MW), MW), medium D Ρ Ε), degree of polyethylene (the polymer of hydrocarbon is polyethylene and the method: it is usually in the high-pressure reaction, this cyclopentene is cross-linked), high density polymer Linear low BLD Ρ Ε, as mentioned in the previous paragraph, polypropylene can be divided by different squares V b

V One or more ethers, amines, alkane- or co-substrates, catalysts or silicon oxides. These catalysts can be metal pressure and high temperature catalysts usually Ib or V type, canonical compounds, valence. This type is in. These touch themselves under polyalkylate) ° Types containing one or group III are oxyalkylene compounds and some gold sulfide composite activated magnesium chloride media can be dissolved or combined in the reaction, metal hydride -37 This paper is applicable to China National Standard (CNS) A4 specification (21〇 < 297 mm) 406104 A7 B7 _ V. Description of the invention (V ^ l) (Please read the notes on the back before filling this page) Halides, metal alkyl oxides or metal alkyl oxane, the gold halide may be an element of Group Ia, IIa, and / or IIIA of the periodic table, and the activator may further be ester, ether, amine or silane Convenient modification of ether. These catalysts are generally called Phi 1 1 ps * Stan dard 0 i 1 Indiana, Ziegler (-N atta) * TNZ (DuPont) 'metal locene or single-sided catalyst (SSC). 2 * A mixture of polymers mentioned in 1), for example, a mixture of polypropylene and polyisobutylene, a mixture of polypropylene and polyethylene (for example, PP / HDPE * PP / LDPPE), and a mixture of different types of polyethylene (for example, LDPE / HDPE). Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

3. Copolymers of mono- and diolefins, or copolymers with other ethylene monomers, such as ethylene / propylene copolymers, linear low density polyethylene (LL DPE) and mixtures thereof and low density polyethylene (LDPE), Propylene / Butene-1 ~ ene copolymer * propylene / isobutylene copolymer, ethylene / butane-1-ene copolymer, ethylene / hexene copolymer, ethylene / methylpentene copolymer, ethylene / heptene copolymer, ethylene / Octene copolymers, propylene / butadiene copolymers, isobutylene / isoprene copolymers, ethylene / alkyl acrylate copolymers, and their copolymers with carbon monoxide, or ethylene / acrylic copolymers Compounds, and their salts (ionized compounds) and terpolymers of ethylene, propylene, and monodiene, such as hexadiene, dicyclopentadiene, or ethylenedi-orbornene; and the copolymer And the mixture of polymers mentioned in 1) above, for example, polypropylene / ethylene-propylene copolymer, LDPE -38- This paper size applies to China National Standard (CNS) A4 (210X29 * 7 mm) 5 406104 B ?

Description of the invention) / ethylene-ethylene-acrylic acid copolymer PE / EAA acetate copolymer (EVA), LDPE / ethylene (EAA), LLDPE / EVA, LLD and interlaced (a 1 ternat i ng) or scattered m) polyolefin / Carbon monooxide copolymers and mixtures thereof, for example, polyamides. Resins (such as C s-C 9), including their hydrogenation modifiers, and mixtures of polyolefins and starch. Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs (please read the notes on the back before filling this page) (ra polymer 4 · carbonaceous (5 · polyethylene) 6 · benzene polymer, / alkyl ethylene / , Styrene ethylenic strength diene polyblock co-diene / ethylene 7. styrene butadiene-acrylonitrile (nd 0 formed hydride such as gum styrene 0 ethylene or for example, methacrylic butadiene / Acrylic mixtures or polymers, / styrene / propylene ethylene or benzonitrile copolymers or methyl-propylene, poly (cx-styrenate, / alkylenenitrile / monomethylstyrene) styrene and / Butadiene, styrene / butyl methacrylate, and another polymer—ethylene such as styrene, styrene / styrene (—vinyl vinyl, physical acetonitrile) / propylene / diene / butadiene ethylene / Vinylene. Styrene based on polybutadiene styrene; diene or styrene dienes /, phenethyl; benzene, such as olefin trimer / styrene / butene polybutadiene on polybutadiene -39- polymethylmethacrylic acid derivative / acrylonitrile, alkyl propane Olefin / cis-butene ethylene copolymer, polyacrylic acid compound; co-styrene ester with styrene, styrene / styrene or copolymer, high impact ester of phthalic anhydride, monoethylene / isoprene Copolymers, for example, styrene and polystyrene on polystyrene or polybutadiene. Acrylonitrile and this paper size apply Chinese National Standard (CNS) A4 (210X297 mm) 406i04 at B7 Printed by Shelley Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention C 1 1 I Methacrylic acid styrene and maleic anhydride 1 1 1 on polybutadiene > on polybutadiene % Of ethylene acrylonitrile and maleic anhydride or maleic 1 I diene diimide on polybutadiene styrene and maleimide 9 Please read 1 I first on poly butadiene Styrene and alkyl acrylate or methacrylic acid; Read back 1 1 ethylene / propylene / di 4 > y hoof dimer Styrene and acrylonitrile on polyalkyl note 1 I means 1 I styrene and acrylonitrile on acrylate or polyalkylmethacrylate; in propylene matter 1 I then 1 1 acrylate / butadiene copolymerization Physical stylene and acrylonitrile and listed in 6 fill 1 co-manuscript) mixtures of item polymers such as the conventional ABS Μ Β SAS page • --- 1 1 A or AES polymer copolymer mixture 0 1 1 8 Halogen-containing polymers like polychlorinated chlorinated rubber 9 1 1 Aerated or vulcanized chlorinated polyethylene iyS. M Ethylene and chlorinated ethylene copolymers Epichlorohydrin I Homogeneous and copolymers especially halogen-containing Polymers of ethylene compounds such as 9 polyvinyl chloride polyethylene diene chloride polyethylene fluoride polyethylene 1 1 diene fluoride and its copolymers like ethylene chloride / ethylene diene Compound 1 1 f Ethylene chloride / ethylene acetate or ethylene dichloride / ethylene acetate 1 linear copolymer 〇1 I 9 Polymer made from a β-unsaturated acid and its derivative 1 1 1 Image Polyacrylic acid, polymethacrylic acid, polymethacrylic acid, polypropylene, 1 1 Ammonium amine and polyacrylonitrile butyl acrylate become impact modifier 0 1 1 1 0 9) between monomers and other unsaturated army Copolymers such as acrylonitrile / butadiene copolymers acrylonitrile / alkyl acrylate 1 1 I ester copolymers acrylonitrile / oxyalkyl acrylate or acrylonitrile / vinyl halide 1 1 copolymer Or acrylonitrile / alkyl methacrylate / butadiene__ · polymer 0 1 1-40-1 1 This paper size applies to China National Standard (CNS) A4 size (210X297 mm) 406104 V. Description of the invention (Ί Α7 Β7 Central Standard of the Ministry of Economic Affairs Printed by the local shellfish consumer cooperative 1 1, a polymer derived from an unsaturated enzyme and an amine or a halogenated derivative thereof or an acetal thereof, for example, polyethylene yeast, polyvinyl acetate, polyethylene stearic acid Esters, polyethylene benzoates, polyethylene maleates, polyethylene butylenes, polyallyl peptides or polyallyl melamines; and those mentioned in point 1 above Copolymer of olefins. 1 2 * Homopolymers and copolymers of cyclic ethers, such as polynicotinyl glycol, polyethylene oxide, polypropylene oxide, or copolymers thereof with dioxypropylene ethers. 1 3 · Polyacetals, like polyoxymethylene and those polyoxymethylenes, which contain ethylene oxide as a co-monomer, modified polyacetals with thermoplastic polyurethane, acrylate or MBS. 1 4 · Polyphenylene oxides and sulfides, and mixtures of polystyrene oxides and phenethyl polymers or polyamides. 1 5 'Polyurethane derived from hydroxyl-terminated polyether, polyester or polybutadiene on one side, and aliphatic or aromatic polyisofluorate on the other side, and its precursors. 16. Polyamines and copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent lactams, such as polyamine 4, polyamine 6, polyamine 6 / 6, 6/10, 6/9, 6/12, 4/6, 12/12, Polyamine 1 1, Polyamide 12 * Aromatic polymer starting from m-xylylenediamine and adipic acid Amidoamine; polyamidoamine derived from hexamethylene diamine and isopeptidic acid or / and peptidic acid, with or without elastomer as a modifier, for example, poly-2, 4, 4--3 Methylhexamethylene peptidylamine or poly-m-phenylene isopeptide amide; and the above-mentioned polyamines and polyolefins, -4 1- This paper size is applicable to the Chinese National Standard (CNS) M specification (21〇X 297 (Mm) I n " —Order — — — — — (Please read the notes on the back before filling this page) A7 B7 (V)) 406104 V. Description of the invention Olefin copolymer, ionization, or chemical knotting Or grafted elastomers; or polyethers, such as block copolymers with polyethylene glycol, polypropylene glycol, or polytetramethylene glycol; and ME PDM or ABS modified polyamides or copolyamides ; And in the preparation process (RI M polyamide System) Polyammine condensed in the system 〇 17 · Polyurea, polyimide, polyimide-imide and polybenzimidazole. 1 8 * Polyesters derived from dicarboxylic acids and dienzymes and / or hydroxycarboxylic acids or equivalent lactones, such as polyethylene terephthalate, polybutene parapeptide, poly-1 4,4-Dimethylolcyclohexyl peptidate and polyhydroxy stearic acid ester, and block copolyetherester derived from hydroxyl terminated polyether; and M polycarbonate modified or MB S modified Polyester. 1 9 · Polycarbonate and polyester carbonate. 2 ◦ polymill, polyether mill and polyetherketone. 2 1 * Crosslinked polymer derived from aldehyde on one side, phenol, urea and melamine on the other side * Like phenol / formaldehyde resin * urea / formaldehyde resin, and melamine / formaldehyde resin. 2 2 · Dry and non-drying enzyme resins. 23. Unsaturated polyester resins derived from saturated and unsaturated dicarboxylic acids, polyhydrogenases, and M ethylene compounds as crosslinking agents, and their low-flammability halogen-containing modifiers. 2 4. Cross-linked acrylic resin derived from substituted acrylate, for example, epoxy acrylic resin, urethane acrylic resin or polyester acrylate-42- This paper size applies to Chinese National Standard (CNS) A4 specifications ( 2 丨 〇'〆297mm) III Packing — I nn .f I n line (Please read the notes on the back before filling this page) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 40fi104 Printed by the Bureau ’s Consumer Cooperatives 5. Description of the invention (> (Γ) — 1 1 2 5 * Alkyd resin polyester resin and melamine resin cross acrylic resin 1 1 I 9 Urea resin polyisofluorate or TWI ring Oxygen resin 〇1 2 6 * Cross-linked epoxy resin derived from aliphatic cycloaliphatic 9 heterocyclic ring or aromatic oxypropane group, such as bisphenol A and bisphenol F Read back 1 I side I The product obtained by oxypropane ether can be traditionally hardened Crosslinking> Anhydride or Note 1 1 Amine (can be in the presence or absence of accelerator) Λ Matter 1 item 1 2 7 days m Polymers such as cellulose rubber > Gelatin and its chemistry and refill 1 Synthetic modified derivatives such as cellulose vinegar, cellulose acetate, cellulose acetate, cellulose acetate, and cellulose ethers such as methylcellulose and pine 1 1 I 2 8 Blends (Polyblends) of the above polymers, such as PP / E1.% ΤPPDMPolyamine / EPDM or ABSPP VC / EVA, 1PP VC / ABSPVC / ΜBSBSC / ABSPB 1 1 Τ P / ABSPC / ASAPC / PB BT VC / 1 1 CP Ε PVC / acrylate P 0 Μ / thermoplastic PURP 1 line C / thermoplastic PURP 0 Μ / acrylate P 0 Μ / Μ BS 1 I ♦ P Ρ 0 / Η IPSP Ρ 0 / PA 6 ♦ 6 and copolymerization »P 1 1 A / Η DP Ε PA / P Ρ PA / Ρ Ρ 0, Ρ Β Τ / 1 1 PC / ABS or PBT / Ρ Ε T / PC 〇1 | 2 9 days Is a pure compound or a mixture of the compounds 1 1 9 for example »mineral oil 9 animal and vegetable fats 9 oils and waxes 1 1 1 * or M synthetic ester-based oils i fats and waxes (like > acid esters 9 Adipate 1 1 Ester Phosphate I Triphenyl "" Ester "and synthetic esters and mineral oils of any weight 1 1-43-1 1 This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) 6ο 4 4ο

A B7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. I I. Description of the invention) 1 1 I Mixtures are typically those used as rotating compositions and 1 1 aqueous emulsions of this substance 0 1 1 please 1 3 0 Aqueous emulsions of natural or synthetic rubbers such as styrene carboxylic acid / Read 1 | t # 1 Butadiene copolymers m latex or emulsion 0 back 1 The present invention also relates to ___. Note 1 for light, heat or oxidation. I means organic matter that is sensitive to degradation and at least one compound of formula (I). Preferred items 1 I and 1 | are compounds of formula (X where the polydispersity MW / M Π 1 but The book 1 is limited to the sum of compounds of formula (I) in this composition. Degree M W / Ν4 η is 1 to 1 7 For example 1 to 1 6 5 1 to 1 1 | 1 6 1 to 1 5 5 1 to 1 5 1 to 1 4 5 1 1 1 to 1 4 or 1 to 1 3 5 This invention further relates to a composition comprising an organic substance that is sensitive to light, heat, or oxidative degradation and at least a compound of formula (I) 9 1 1 I is preferably a compound of formula (X) which is Variable η changes the composition 1 1 The composition has a polydispersity MW / Mη = 1 1 to 1 7 or 1 1 1 line to 1 5 * 1 is limited to the sum of 1 I in which the compound of formula (I) is present in the composition The polydispersity MW / Mη is 1 1 to 1 7 or 1 1 1 1 I to 1 5 0 1 1 The organic substance is preferably a synthetic polymer, and more particularly, the above 1 1 group is selected. Olefins are preferred. Polyethylene and polypropylene are particularly preferred. 0 1 I Another embodiment of the present invention The method of degradation caused by light, heat 1 1 1 or oxidation includes adding to the organic substance 1 1 less a compound of formula (I), preferably a compound of formula (X) 1 which has 1 1-44-1 1 The size of this paper applies to China National Standard (CNS) A4 (210X297 mm). The consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs, printed by A7 _____ 406104 ---- V. Description of the invention (0⑴ Polydispersity M w / Μ η = 1 ' However, the compound f of the formula (I) exists here. The total polydispersity Mw / Mn in the final product is between 1 and 1.7, preferably 1 to 1.5 'or 1 to 1.4. 1 to 1.35 0 The compound of formula (I) or its mixture can be used in various proportions (depending on the nature of the stabilized substance, the end use and the presence of other additives). In general, it is appropriate to use, for example, from 0.01 to 5% by weight of the compound of formula (I) or a mixture thereof (relative to the weight of the stabilized substance), preferably from 0.5 to 1%. The compound of formula (I) or a mixture thereof can be added, for example, simultaneously or after the substance is polymerized or cross-linked *. Furthermore, they can be added to the polymeric substance as a pure substance or as a coating in paraffin, oil or polymer. In general, the compound of formula (I) or a mixture thereof can be added to the polymer material in various ways, such as dry mixing in the form of powder, or lyophilization or suspension, or wet mixing in the form of M precursor; in these operations, The polymer can be applied in the form of powder, granules, dissolve, suspend, or latex. The compound of the formula (I) or a mixture of which is stable can be used for the preparation of models, films, ribbons, single minerals, fibers, surface coatings and the like. If desired, other conventional additives suitable for synthetic polymers, such as antioxidants, UV absorbers, nickel stabilizers, pigments, fillers, plasticizers, corrosion inhibitors and metal deactivators can also be added to formula (I ) Chemical combination (please read the precautions on the back before filling this page) -Packing-, 1T thread paper size is applicable to China National Standard (CNS) Α4 specification (210 × 297 mm) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs104 A7 B7 5. Description of the Invention (+1) or organic substances in mixtures thereof. Specific examples of this traditional additive are: 1 * Antioxidant: 1'1 'alkylated monophenols, for example, 2,6-di-tert-butyl-4 methylol, 2-butyl-4,6 —Dimethylphenol, 2,6-di-tert-butyl-4-n-butylphenol, 2,6-di-tert-butyl-4—ethylphenol, 2,6-di-tert- — Butyl-4-isobutylphenol, 2,6-dicyclopentyl-4 monomethylphenol, 2 ~ (α-methylcyclohexyl) _4, 6-dimethylphenol, 2,6-di Octadecyl 4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-tert-butyl-4-methoxymethylphenol, 2,6-di-nonyl 4-Methylphenol, 2,4-Dimethyl-6- (17-methylundecane-1-yl) phenol, 2,4-Dimethyl-6- (1-methyldecat Yard-1, 1-base), 2,4-Di-methyl-6- (1'-methyltridecane-1'-yl) phenol and mixtures thereof. 1 · 2 · Alkylthiomethylphenol, for example, 2,4-dioctylthiomethyl-6-tert-butylphenol * 2, 4-dioctylthiomethyl-6-methylphenol, 2 , 4-dioctylthiomethyl-6-ethylphenol, 2,6-diododecylthiomethyl-4 nonylphenol. 1 * 3, hydroquinone and its alkylated hydroquinones, for example, 2,6-di-tert-butyl-4 4-methoxyphenol, 2,5-di-tert-butylhydroquinone Diphenol, 2,5-di-tert-pentylhydroquinone, 2,6-di-t-benzyl-4-octadecyloxyphenol, 2,6-di-tert-butylhydroquinone. -46- This paper is inferior to Chinese National Standard (CNS) A4 (210X297mm). I I line (please read the precautions on the back before filling this page) Printed A7 by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs B7 V. Description of the invention (Appleol, 2,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyanisole, 3,5-dione Tert-butyl-4 monohydroxyphenylstearate, bis (3,5-di-tert-butyl-4hydroxyphenyl) adipate. 1 · 4 · tocopherol, for example, α —Tocopherol, Θ —tocopherol, tocopherol, δ —tocopherol and its mixture (vitamin E). 1 · 5 · hydroxylated thiodiphenyl ether, for example, 2, 2 'monothiobis (6-tertiary Butyl-4 (methylcool), 2 2 * —thiobis (4-octylphenol), 4,4 'monothiobis (6-tert-butyl-3-methylol), 4, 4' monothiobis (6-tert-2-methyl) Phenol), 4,4 'monothiobis (3,6-bis-sec-pentylphenol) * 4,4'-bis (2,6-dimethyl-4 4-hydroxyphenyl) disulfide 1 · 6. Alkylene bisphenols, for example, 2,2'-methylenebis (6-tert-butyl-4-methylphenol), 2,2'_methylenebis (6-tert-butyl) —4 —ethylphenol), 2, 2 ′ monomethylbis [4 monomethyl-6- {α-methylcyclohexyl) phenol], 2, 2 ′ monomethylbis (4-methyl-6 _Cyclohexylphenol), 2, 2 'monomethylbis (6-nonyl_4-monomethylphenol), 2, 2' monomethylbis (4,6-di-tert-butylphenol), 2 , 2'-ethylidene bis (4,6-di-tert-butylphenol), 2, 2'-ethylidene bis (6-tert-butyl-4-isobutylphenol), 2,2 'one Methylbis [6_ (ot —methylbenzyl) -4 4-nonylphenol], 2, 2′-methylbis [6 — (a, oc — dimethylbenzyl) -4—nonylphenol] , 4,4 'one armor (2,6 —Di-tert-butyl phenol) -4 7-This paper size applies to China National Standard (CNS) A4 specification (210 '乂 297 mm) Approval for clothing line (please read the precautions on the back first) (Fill in this page) 406104 A7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (t / j) 1 1 I ♦ 4 4, Monomethylbis (6 — tert-butyl — 2 — methylphenol) t 1 1 1 y 1 bis (5-tert-butyl- 4-hydroxy-2- 2-methylphenyl) but 1 1 please 1 1 burn 2 6 — m (3 mono-tert-butyl-5-methyl — 2 — hydroxybenzyl 1 base) — 4 — methylphenol 1 1 3 — —di (5 —tert-butyl — 4) Read back 1 — hydroxy — 2 — methylphenyl) Butan 1 1 — Bis (5-tert-butyl-note 1 I means 1 I group—4—hydroxy-2—methylphenyl) — 3 — η—dodecyl hydrogen sulfur matters 1 I Re 1 I-Butaneethylene Diether Bis [3 3 —Bis (3 -tert-butyl-4) Fill in 1 book, monohydroxyphenyl) butyrate] Bis (3 -tert-butyl-4 -hydroxy Page 1 | — 5 —methyl-phenyl) dicyclopentanebis [2 — (3, — tert-butyl 1 1 — 2, —hydroxy — 5 t — methylbenzyl) — 6 — tert-butyl — 4 1 1 —methylphenyl) terephthalate 1 1 —bis — (3 5 —dimethyl order I — 2 —hydroxyphenyl) butane 2 2 —bis — (3 5 —di — tert — Butyl — 4 — hydroxyphenyl) Glycolin 2 2 — bis — (5 — tertiary — 1 1 butyl — 4 — mesityl — 2 — methylphenyl) — 4 — η — dodecyl hydrogen 1 1 Thiobutane 1 1 5 5 — tetra- (5-tert-butyl- 4-1 linear hydroxyl 2-methylphenyl) pentyl 0 1 I 1 7 0 — N — and S-benzyl compounds For example 3 5 1 1 1 3, 5 — Tetra-tert-butyl— 4 4 t —dihydroxy-dibenzoyl 1 1 yl ether octadecyl — 4 —hydroxy-3 35 —dimethylbenzyl hydrogen sulfide 1 1 (3 5 — Di-tert-butyl — 4 —hydroxybenzyl 1 I) amine bis (4 —tert-butyl — 3 —hydroxy — 2 6 —dimethyl 1 1 benzyl) dithio — Para-peptide bis (3 5 —di-tert-butyl 1 1 ~ 4 —hydroxybenzyl) sulfide j isooctyl — 3 5 di-tert-butyl 1 1-48-1 1 Applicable to this paper size China National Standard (CNS) A4 specification (210X297 mm) A7 B7 ^ 06104 5. Inventive base-4 monohydroxybenzyl hydrothioacetate. (Please read the precautions on the back before filling out this page) 1 · 8 · Hydroxybenzyl malonate, such as octacosyl-2,2—bis- (3,5_bis-tert-one Butyl mono-2-hydroxybenzyl) -malonate, dioctadecyl mono-2-(3-tert-butyl-4 4-hydroxy_5-methylphenylmethyl) monomalonate , Dodecyl hydrosulfanyl ethyl-2,2-bis (3,5-di-tert-butyl-1,4-tribenzylbenzyl) malonate, bis- [4 一 (1 , 1,3,3-tetramethylbutyl) phenyl] -2,2-bis (3,5-di-tert-butyl-4-hydroxybenzyl) malonate. 1 · 9 · Aromatic hydroxybenzyl compounds · For example 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) -2,4,6-trimethyl Phenylbenzene, 1,4-bis (3,5-di-tert-butyl-4-hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2,4,6-trione ( 3,5-di-tert-butyl-4 4-hydroxybenzyl) phenol η 1 · 10 · triazine compounds, such as 2,4-bis (octylhydrosulfanyl) —6— (3,5-di —Tert-butyl-4-hydroxybenzylamino) —1 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, 3,5-triazine, 2-octylhydrothio-4,6-bis (3,5 —Di-tert-butyl-4—controller—aniline) —1,3,5-triazine, 2-octylhydrothio—4,6-bis (3,5-di-tert-butyl) -4-monohydroxyphenoxy) -1,3,5-triazine, 2,4,6-tris (3,5-di-tert-butyl-4-hydroxyphenoxy) -1, 2, 3 —Triazine, 1, 3, 5 — Trinity (3, 5 — Di-tert-butyl — 49-) This paper size applies to China National Standard (CNS) Α4 Specification (21 0 × 297 mm) A7 B7 Printed bags of employees' cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention 1 II-based 4-hydroxybenzyl.) Isocyanurate t 1 > 3 f 5 — — (1 1 1 4 — tert-butyl — 3 — hydroxy — 2 > 6 — di-methylbenzyl) iso 1 I Please 1 1 fluorouric acid m 9 2 4 > 6 — tri (3 9 5 — di-tert- — Butyl—— 4 Read 1 —Hydroxyphenylethyl) — 1 > 3 9 5 —Diazine, 1 9 3 9 5 — Second reading — 1 — (3 5 — Di-tert-butyl — 4 —Hydroxyphenylpropionamidine — — Note to Phoenix 1 I means 1 I — 1 3 5 —diazine 9 1 3 5 one three — (3 f 5 — — * IS —m Matter 1 I then 1 I Hexyl — 4 — Hydroxybenzyl) isocyanurate 0% 1% pack 1 1 1 benzylphosphonate such as dimethyl-2 1 5 _ Two pages 1 I tert-butyl-4 4-hydroxybenzyl phosphonate diethyl-3) 5-di 1 1 tert-butyl-4 4-hydroxybenzyl phosphonate 28 Radical 3 5 1 1 bis-tert-butyl-4 hydroxybenzyl phosphonate octadecyl-1 butyl 5 -tert-butyl butyl 4 -hydroxy3-methylbenzyl monophosphonic acid Esters 3 I 5 —Di-tert-butyl-4—Hydroxybenzyl—monoethyl ester of phosphonic acid 1 1 Calcium salt 0 1 1 1 1 2 Amidinoaminophenols such as 4_hydroxy 醯 lauryl tanilide 1 Line 4 —Hydroxystearate, aniline octyl — N — (3 5 — di 1 I — tert-butyl — 4 — hydroxyphenyl) carbamate 0 1 1 1 1 1 3 β — (3 5 — Di-tert-butyl — 4 —hydroxyphenyl 1 1) Propionic acid and mono- or poly-hydroalcohol esters »such as and methanol, ethanol stearyl 1 1 Alcohol 1 6 — Hexanediase 1 9 — Nonanediol Ethylene Glycol> 1 I 1 2 — Propanediol Neopentyl Glycol Thiodiethylene Glycol t Diethylene 1 1 Ethylene Glycol Triethylene glycol pentaerythritol tri- (hydroxyethyl) iso-1 1 fluorourate Ν Ν > — bis (hydroxyethyl) ethylenediamine diamine 9 3 — warm 1 1-50-1 1 This paper size applies to China National Standard (CNS) A4 (210X297 mm) 40 1 6 o4

7 7 AB Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention. 1 1 I Eleven-house fermentation 3 — pentadecanol trimethylhexanediol ♦ HI — methyl alcohol 1 1 1 propane 4 — Hydroxymethyl — 1 — phosphorus — 2 > 6 > 7 — trioxobicyclic C 1 I please 1 I 2 2 2] octane 0 first 1 1 1 4 β — (5 — tert-butyl — 4 — Hydroxy — 3 —methylbenzene reads back 1 side I) esters of propionic acid and mono- or polyhydric alcohols such as > and methanol i ethanol octadecine 1 I means 1 I alcohol 1 6 — hexanediol 1 9 — Nonane — Diethylene glycol diethylene glycol 1 I True 1 1 Alcohol 1 9 2 — Glycolin neopentyl glycol thiodiethylene glycol) Introduction 1 Diethylene glycol diethylene glycol five Erythritol bis (hydroxyethyl page s__ ^ 1 I) isofluuric acid Ν Ν, — bis- (hydroxyethyl) ethylenediamine diamine 1 1 9 3 — thiaundecanol 3 — warm pentadecanol trimethylhexanodiol J 1 1 Tris-methyl alcohol propane 4 —Hydroxymethyl — 1 —Phosphorus — 2 6 7 — Order I Dioxo IS m C 2 2 2 Octane 0 1 1 5 β — (3 5 — Dicyclohexyl — 4 — Hydroxyphenyl) Propyl 1 1 acid and mono- or poly-hydro alcohol esters such as and methanol ethanol stearyl alcohol 1 1 1 6 — hexanediol 1 9 — nonanediol ethylene glycol 1 > 1 silk 2 — Propanediol neopentyl glycol thiodiethylene difermentation diethylene di 1 I alcohol diethylene glycol pentaerythritol tri — (hydroxyethyl) isocyanurate 1 1 I acid ester N Ν * One bis (hydroxyethyl) ethylenediamine diamine 3 One thia 11 1 1 Alcohol 3 — thiopentadecyl dimethyl hexanediol di — methyl alcohol prop 1 1 alkane 4 — hydroxymethyl — 1 — Phosphorus 2 6 7 — trioxane C 2 1 I 2 2] octane Γ, 1 1 1 1 6 3 > 5 — di-tert-butyl-4 4-hydroxyphenylacetic acid 1 1 and mono- or polyhydric alcohol Ester such as and methanol ethanol stearyl alcohol 1 9 1 1-51-1 1 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (^) 6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol , Triethylene glycol, pentaerythritol, tri- (hydroxyethyl) isofluorourate-N »N f —bis (hydroxymonoethyl) ethylenediamine, 3-thiaundecanol , 3-BI pentadecanol, trimethylhexanediol, trimethyl alcohol propane, 4 monohydroxymethyl-1 monophosphoryl 2,6,7-trioxabicyclo [2 * 2 · 2] octyl alkyl. 1 · 17 · Call ammonium (3,5-di-tert-butyl-1,4-hydroxyphenyl) propionic acid, such as N, N'-bis (3,5-di-tert-butyl-1 4 monohydroxybenzyl propyl hydrazone) hexamethylene diamine, Ν, Ν 'bis (3,5-di-tert-butyl-4-hydroxyphenylpropyl hydrazine) trimethylenediamine, Ν, Ν'-bis (3,5-di-tert-butyl-4 4-hydroxy-phenylpropionamidine) hydrazine. 1 * 1 8 · Ascorbic acid (vitamin C) 1 · 1 9. Amine antioxidants, for example, N, N′-diisopropyl-P-phenylene diamine, N, N′-di-sec-butyl _ρ —phenylene diamine, Ν, Ν′—bis (1,4 dimethylpentyl) —P—phenylhydrazine diamine, Ν, Ν′—bis (1-ethyl-3-methylpentyl) Group) -ρ-phenylene diamine, Ν, Ν '-bis (1-methylheptyl) -d-benzyl diamine, Ν, Ν'-dicyclohexyl-ρ-phenylene diamine, N, Ν'-diphenyl-ρ-phenylene diamine, Ν, Ν'-bis (2-naphthyl) -ρ-phenylene diamine * Ν-isopropyl-N'-phenyl-ρ-phenylene Diamine, Ν— (1,3-dimethylbutyl) -N'-phenyl-d-phenylene diamine, NR This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm)- -: ------- ^ ------ ΐτ _------ # (Please read the notes on the back before filling out this page) __406104 b7_ V. Description of the invention d) One (1 One A Heptyl) -N'-phenyl-ρ-phenylenediamine, N-cyclohexyl-N'-phenyl-ρ-phenylenediamine, 4- (P-toluenesulfonyl) Mono-diphenylamine, N, N'-dimethyl-N, N'-di-sec-monobutyl-P-phenylenediamine, diphenylamine, N-allyl diphenylamine, 4 Monoisopropoxydiphenylamine, N-phenyl-1M-based amine, N- (4-tert-octylphenyl) _1-Ceylamine, N-phenyl ~ 2-naphthylamine, Octylated diphenylamines, such as ρ, P′-di-Syctyldiphenylamine, 4-n-butylaminophenol, 4-butylfluorenylaminophenol, 4-nonaniminophenol , 4-dodecylaminoaminophenol, 4 octamethylaminoaminophenol, bis (4-monomethoxyphenyl) amine, 2,6-di-tert-butyl-4-dimethylamine Methylphenol, 2,4'-diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, Ν, Ν, Ν ', Ν' -tetramethyl-1,4,4 '- Diaminodiphenylmethane, 1,2-bis [(2-methylphenyl) amino] ethane, 1,2-bis (phenylamino) propane, (0-tolyl) biguanide ， Double [4 — (1 '· 3 / —The Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics of the People's Republic of China, Yinfan (Please read the precautions on the back before reading Write this page) Butyl) phenyl] amine, tertiary mono-octyl N-phenyl-1 mononaphthylamine, mono- and dialkylated tert-butyl / tert-octyl diphenylamine Mixtures * single and dialkylated nonyldiphenylamine mixtures, single and dialkylated dodecyldiphenylamine mixtures, single and dialkylated isopropyl / isohexyl dibenzyl Amine mixtures, mono- and dialkylated tert-butyldiphenylamine mixtures, 2,3-dihydro-3,3-dimethyl-1,4,4-benzothiazine, phenothiazine , Single and dialkylated tert-butyl / tert-octylphenothiazine mixtures, mono- and dialkylated tert-octyl phenothiazine ~ 5 3-This paper size applies to Chinese National Standard (CNS) Α4 Specifications (210X29 * 7mm) A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (with 1 1 1 I thiazine mixture t N — allylphenantrazine N > N 9 N 9 N / — 1 1 1 tetraphenyl — 1 9 4 — diaminobutane — 2 —ene> N f N — bis (2 i / —V 1 I 2 f 6 > 6 tetramethyl one Pyridine — 4 monoyl ^-methylene diamine 9 bis (see 1 2 9 2 9 6 9 6 — tetramethylpiperidine — 4 —yl) sebacate 2 9 glutamate 1 surface 2 »6 9 6 — Tetramethylmeridine — 4 — Xing 9 2 > 2 6 * 6 — Note of Four 1 I means 1 I methylpiperidine — 4 — alcohol 0 matter 1 I 1 I 2 * UV absorber and light stabilizer Fill in 1 book 2 1 2 — (2 -m phenyl) benzotriazolyl, for example 2 pages 1 I — (2 t —hydroxy-5, —methylphenyl) —benzotriazolyl 2 1 1 (3 f 5 * — di-tert-butyl — 2 f — hydroxyphenyl) benzotri 1 1 oxazolyl 2 — (5 t — tert-butyl — 2 t — hydroxyphenyl) benzotriol I Oxazolyl 2 mono (2, —hydroxy — 5 t mono (1 1 3 3 — tetramethylbutyl) phenyl) benzo —triazolyl 2 — (3 f 9 5 — —di 1 1 —tert-butyl — 2 —hydroxyphenyl) — 5 — chloro —benzotriazolyl 1 1) 2 — (3 > — tert-butyl — 2 9 —hydroxyl — 5 , Monomethylphenyl 1-line) — 5 —chloro-benzodiazolyl 2 — (3 1 —sec-butyl-5 1 |, —tert-butyl-2, —hydroxyphenyl) benzo Triazolyl 2 — (2 1 1 > — hydroxyl-1 4 t — octyloxyphenyl) benzodiawyl) 2 — (3 t 1 1 5 y — di-tert-pentyl — 2, monohydroxybenzene Benzotriazolyl t 2 1 1 — (3 * 9 5 > — bis — (a 9 α —dimethylbenzyl) — 2, 1 I — hydroxyphenyl) benzotriazolyl 2 — (3 9 —tert-butyl — 2, 1 1 —hydroxy — 5 r — (2 —octyloxycarbonylethyl) phenyl) — 5 —chlorine 1 1-monobenzotriazolyl »2 — ( 3 t — tert-butyl — 5 9 — [2 — 1 1-54-1 1 This paper is for China Standard (CNS) A4 specification (2 丨 0 > < 297 mm) 4〇61〇 | 7 V. Description of the invention (P) (2-ethylhexyloxy) -ethyl] -2'-hydroxyphenyl) 5-chloro-benzotriazolyl, 2- (3'-tert-butyl-1 2'-hydroxy-5 '-(2-methoxycarbonylethyl) benzyl) -5-chloro-1 Benzotriazolyl, 2- (3'-tert-butyl- 2'-hydroxy-5 '-(2-methoxycarbonylethyl) phenyl) benzotriazolyl, 2- (3'- Tert-butyl-2'-hydroxy-5 '— (2-octyl monooxycarbonylethyl) phenyl) benzotriazolyl, 2- (3'-tert-butyl-5'-[2- (2-ethylhexyloxy) carbonylethyl] -2'-hydroxyphenyl) benzotriazolyl, 2- (3 * -dodecyl-2'-hydroxy-5'-methylphenyl) Benzo-triazolyl, and 2- (3'-tert-butyl- 2'-hydroxy-5 '-(2-isooctyloxycarbonylethyl) phenylbenzotriazolyl 2,2'- Methylene bis [4- — (1,1,3,3-tetramethylbutyl) — 6 —benzotriazolyl — 2 — Phenol] mixture; 2-[3'-tert-butyl-5 '-(2-methoxycarbonylethyl) -2, -hydroxy-phenyl] -2H-benzotriazolyl and polyethylene di An esterification product of alcohol 300, where R = 3'-tert-butyl- 4'-hydroxy-5'-2H-benzotriazolyl-2-ylphenyl. Printed bags for employees' cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 2 · 2 · 2 -Hydroxybenzophenone * For example, 4-hydroxy, 4-methoxy, 4-octyl Oxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2 ', 4'-trihydroxy and 2'-hydroxy-4,4'_dimethoxy derivatives . 2 · 3 · Ester of substituted or unsubstituted benzoic acid, such as 4-tert-butyl-phenylsalicylate, phenylsalicylate, octylbenzylsalicylate, this paper size applies China National Standard (CNS) A4 specification (210X297 mm) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 406104 --- 5. Description of the invention (r)) Dibenzopyrene resorcinol, bis (4 — Tert-butylbenzidine) resorcinol * benzidine resorcinol, 2,4-di-tert-butylbenzyl 3,5-di-tert-butyl-4-hydroxybenzoate Hexadecyl 3,5-di-tert-butyl-4 monohydroxybenzoate, octadecyl 3,5-di-tert-butyl-4 4-hydroxybenzoate, 2-methyl -4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4 -hydroxy-benzoate 0 2 · 4 ♦ Aromatic esters, such as ethylfluoro- / 3 , YS-diphenyl acrylate, isooctyl α-cyano-yS, / 3-di-phenyl acrylate, methyl α-carbomethoxycinnamate, methyl "-fluoro-1 / 3 , / 3-methyl-p-methoxy-cinnamate, butyl α-cyano / 3, dot-methyl-P-methoxy-cinnamate * methylcarbmethoxy-P-methoxycinnamate and N-(/?-carbmethoxy- / 3-cyanovinyl) -2 methyl indole. 2 · 5 · Nickel compounds. For example, a nickel compound of 2,2'-thio-bis-one [4-((1,1,3,3-tetra-methylbutyl) phenol], such as 1: 1 or 1 : 2 complex with or without additional reactive groups, such as η-butylamine, triethanolamine or η-cyclohexyldiethylenamine, nickel dibutyldithiocarbamate, 4-monohydroxy Nickel salts of monoalkyl esters of 3,5-di-di-tert-butylbenzylphosphonic acid, such as methyl or ethyl esters, and nickel complexes of ketoxime, such as 2-hydroxy-4-methylphenyl Undecyl ketone oxime, 1-phenyl-1, 4-lauryl-5-hydroxypyrazolyl nickel complex, with or without additional reactive groups. -56- This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) III binding III binding-II line (please read the precautions on the back before filling this page) 40610 ^ 7 V. Description of the invention (l : V) 2 · 6 · Sterically hindered amines, such as bis (2,2,6,6-tetramethylmonofluorinyl) sebacate, bis (2,2,6,6— Tetramethyl-tonidinyl) succinate, bis (1,2,2,6,6-pentamethylpyridinyl) sebacate, bis (1,2,2,6,6-5) Methylpiperidinyl) η-butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate, 1- (2-hydroxyethyl), 2,6,6-tetrakis Concentrate of methyl 4-hydroxypiperidine succinic acid, N, N'-bis (2,2,6,6-tetramethyl-4-nonidyl) hexamethylene di-amine and 4-tert-one Octylamino-2,6-dichloro-1,3,5-triazine, tri- (2,2,6,6-tetramethyl-4-piperidinyl), four (2,2, 6,6—Tetramethyl-1—4-pyridinyl) —1,2,3,4-butane-tetracarboxylic acid ester, 1,1 'Mono (1,2-ethanediyl) bis (3,3,5 > 5-tetramethylpiperazine hydrazone), 4-benzylhydrazone-2,2,2,6,6-tetramethylpiperidine , 4-stearylmethyloxy-2 * 2,6,6-tetramethylpiperidine, bis (1,2,2,6,6-pentamethylmethylpyridinyl) -2-η-butyl 1 2-(2-Hydroxy-3,5-Di-tert-butylbenzyl) malonate printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) esters, 3 — η —octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro [4 · 5] decane-2,4-bis-, bis (1-octyl Oxy-2,2,6,6-tetra-methylpiperidinyl) sebacate, bis (1-octyloxy-2,2,6,6-tetramethylpiperidinyl) butane Concentrate of the acid ester, N, N'-bis- (2,2,6,6-tetramethyl-4 piperidinyl) hexamethylenediamine and 4-morpholino-2,6-5 paper Standards apply to China National Standard (CNS) Α4 specifications (21 × 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. A7 _ _406104 b7___ V. Description of the invention (jr))-Concentrate of dichloro-1,3,5_triazine, 2-chloro-4 '6-bis (4-η-butyl-amino-2,2 , 6,6-Tetramethylpiperidinyl) -Concentrate of 1,3,5-triazine and 1,2-bis (3-aminopropylamino) -ethane, 2-chloro-4,6 —Bis (4-n—butylamino—1 ′ 2 ′ 2 * 6,6—pentamethylnehydrazine) —1,3,5-triazine and 1,2—bis— (3-aminopropyl Aminoamino) ethane, 8-ethenyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro [4.5] decane-1 2'4-dione, 3-dodecyl-1— (2,2,6 * 6-tetramethyl-4 piperidinyl) Krolidin-2,5-dione, 3-dodecyl Alkyl 1- (1,2,2,6,6-pentamethyl-4, 4-pentyl) alkane-2,5-dihydrazone, 4-hexadecyloxy and 4 octadecyloxy A mixture of 2,2-, 6,6-tetramethylpyridine, Ν, Ν7 —bis— (2, 2,6,6—tetramethyl-1—4-pyridyl) hexamethylenediamine and 4-ring Hexylamino Condensation product of 2,6-dichloro-1,3,5-diazine, 1 * 2-bis (3-aminopropylamino) ethane and 2, 4,6-trichloro-1,3 Condensation products of 1,5-triazine and 4-monobutylamino-2,2,6,6-tetramethylmethylpyridine (C AS Reg. No. [136504-96-6]); N — (2, 2,6,6-tetramethyl-4-piperidinyl) -n-dodecyl succinimide, N- (1,2,2,6,6-pentamethyl-4_piperidine ) -N-dodecyl butane diimide, 2-undecyl-7,7,9,9-tetramethyl-1 2-cycloundecyl-1-oxa-3,8 —Two acryl 4 —oxo 〔4,5〕 -58- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 cm) III ^ 1111 n line (Please read the precautions on the back before filling this page ) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs __40610487_ V. Description of the Invention (/ y) Undecane and epichloromethane. 2.7. Ethylenediamine diamine, such as 4,4'-dioctyloxyoxopanidine, 2,2'-dioctyloxy-5,5'-di-tert-butoxy-fluorene Tefaniline, 2,2'-docosalyloxy-5,5 't-di-tert-butoxyfluortanilide, 2-ethoxy-2'-ethoxyxanthiline, N, N' One bis (3-dimethylaminopropyl) ethylenedifluorene diamine, 2-monoethoxy-5-tert-butyl-2, monoethoxyaniline and its 2-ethoxy_2 ' Mixtures of monoethyl-5,4'-di-tert-butoxyanilide and mixtures of ortho- and meta-methoxydisubstituted oxotetanil, and ◦- and P-ethoxy One or two substituted oxotetanil. 2.8.2 — (2-hydroxyphenyl) _1,3 · 5-triazine, such as 2,4,6-trione (2-hydroxy-4 4-octyloxy-phenyl) —1, 3, 5 —Triazine, 2- (2-hydroxy-4—octyloxyphenyl) —4,6-bis (2,4-dimethylphenyl) —1,3,5—triazine, 2-— 2,4-dihydroxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2,4-bis (2-hydroxy-1-4-propyl) Oxyphenyl) -6- (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4-octyloxyphenyl) -4 * 6- Bis (4-monomethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4dodecylmonooxyphenyl) -4,6-bis (2,4, two (Methylphenyl) -1,3,5-triazine, 2- [2-hydroxy-4 — (2-hydroxy-3 —butyloxy monopropoxy) phenyl] — 4,6-bis (2 , 4-dimethyl) -1, 3, This paper size applies to Chinese National Standard (CNS) A4 specification (210 X29 "? mm) gutter (please read the precautions on the back first) (Fill in this page) 406104 b7 A7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention 1 1 I 5 — Triazine 2 — r 2 — Hydroxy — 4 — (2 — Hydroxy — 3 — Octyl 1 1 1 Oxygen Monopropyloxy) phenyl] 4f 6 —bis (2, 4 —dimethylλ—s 1 |) a 1 3 5 _ triazineί 2 a C 4 a (dodecyloxy / Thirteen please read I (oxyl 2 — hydroxypropoxy) — 2 — hydroxy — phenyl] — 4 1 6 Read back 1 I — Bis (2 4 — dimethylphenyl) — 1 3 9 5 — Triazine * 2 — Note I means 1 I [2 — hydroxy — 4 — (2 — hydroxy — 3 — dodecyloxy-propoxy matter 1 | 1 1) phenyl] — 4 6 — Bis (2 4 — dimethylphenyl) — 1 > 3 Filled with 1 hydrazine writing »5 Tris 2 * — (2 hydroxy-4 4-hexyloxy) phenyl-4 * Page, _, 1 1 6 — diphenyl — 1 3 5 — triazine 2 — (2 — hydroxy — 4 — 1 1 methoxyphenyl) ~ 4 6 — diphenyl — 1 3 5 — triazine 2 1 1 > 4 6 -tri-C 2 -hydroxy- 4-(3 _ butoxy_ 2 _ hydroxy 1-propoxy) phenyl] — 1 3 5 — triazine 2 — (2 — hydroxy I phenyl ) — 4 — (4 —methoxyphenyl) — 6 —phenyl — 1 3 9 1 1 5 monodiazine Q 1 1 3 metal deactivator such as N 9 N 9 diphenylethylenediamine diamine 1 1 Line 1 IN —Salicyl — Ν, ~ Salicyl m hydrazine NN t — Bis (salicyl) hydrazine 9 N 9 Ν, —bis (3 9 5 —di-tert-butyl — 4 —hydroxyl 1 1-phenylphenyl—propanyl) hydrazine> 3—Salicyl-JMS-based amino— 1 2) 4 —-* 1 1azole 9 bis (benzylidene) ethanedihydrazine—hydrazine 9 dihydrazine t 醯Taniline 1 I 9 isofluorenyl > dihydrazine 9 decanedion bisphenylfluorene Hydrazine 9 N i N > — Di 1 I — Ethyl hexamethylene dihydrazide dihydrazine > N »N t — Bis (salicyl) hydrazine 1 1 Di 2 hydrazine hydrazine Ν 9 N > — Bi (Salicinyl) — Thiopropanyl dihydrazone 1 1 Hydrazine 0 1 1-60-1 1 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) ^ 06104 B7_ V. Description of the invention (丄 1) 4 'Phosphites and phosphonates such as triphenylphosphite, diphenylalkylphosphite, phenyldialkylphosphite, tri- (nonylphenyl) phosphite, trilauric acid Diphosphite, tris-octadecylphosphite, distearylpentaerythritol diphosphite, tris (2,4-di-tert-butylphenyl) phosphite, di Isodecyl pentaerythritol diphosphite, bis (2,4-di-tert-butylphenyl) pentaerythritol tetraphosphite, bis (2,6-di-tert-butyl) -4 monomethylphenyl) pentaerythritol diphosphite, diisodecyloxy pentaerythritol diphosphite , Bis (2,4-di-tert-butyl-6-methylphenyl) pentaerythritol tetraphosphite, bis (2,4,6-tri- (tert-butylphenyl) Pentaerythritol diphosphite, tristearyl sorbitol triphosphite, four (2,4 t-butyl-butylphenyl) 4,4'-biphenylene diphosphonate, 6 —Isooctyloxy-2,4,8 * 1 ◦—Tetra-tert-butyl-12H-diphenyl [d, g] —1,3,2—Phosphorus dioxin Employees ’Central Standards Bureau Consumption Cooperative printed poly (Please read the notes on the back before filling this page), 6-Fluoro-1,2,4,8,1 0-Tetra-tert-butyl- 1 2 Methyl-diphenyl [d, g] -1, 3, 2-dioxophosphate, bis (2,4,1,2-tert-butyl-6-methylphenyl) methylphosphite, bis (2,4,2-tert-butyl- 6-methylphenyl) ethyl phosphite. 5. Hydroxylamine, for example, N, N-dibenzylhydroxylamine, N, N-diethylhydroxylamine, N, N-dioctylhydroxylamine, N, N-dilaurylhydroxylamine, N, N —Di (tetradecyl) hydroxylamine, N, N —di (hexadecyl) hydroxylamine, N, N —di (octadecyl) hydroxylamine, N —hexadecyl—N —octadecyl Alkylhydroxylamine, N —ten t alkyl —N — -61- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 406104 ) Octadecylhydroxylamine * 1 ^ 1 from hydrogenated tallowamine > N-dialkylhydroxylamine 06. Nitrones, for example, N-benzyl-ot-phenyl-nitrile, N-ethyl -Α_methyl-nitrazine 'N_octyl-ot-heptyl-nitrazine' N -lauryl-a-undecyl mononitrone, N-decyltetraalkyl-a-thirteen Alkyl mononitrate, N—hexadecyl-a—pentadecyl mononitrone, N—octadecyl—a—heptadecanyl nitrone—N—hexadecyl—a—ten ir Yuan Ji Ni Ni, N_18 Yuan Ji Ji 15 Yuan Ji Ni, N — Heptadecyl-1a —Heptadecyl-nitronone 'N--Heptadecyl ~ cx--Hexaalkyl-Nitrofluorene * Derived from hydrogenated tallowamine N′N ~ dialkylhydroxylamine Of nitrone. 7. A thiosynergist, for example, dilaurylthiodipropionate or distearylthiopropionate. 8. Peroxide cleaners * such as in the case of esters of thiodipropionic acid, such as lauryl, stearyl, tetradecyl or tridecyl, hydrothiobenzimidazole or 2-hydrothio Zinc salt of benzimidazole, zinc dibutyldithiocarbamate, octacosyl disulfide, pentaerythritol tetraol (four-dodecyl hydrogenthio) propionate. 9. Polyamide stabilizers, such as copper salts combined with iodide and / or phosphorus compounds, and salts of divalent manganese. 10 * Basic co-stabilizers, such as melamine, polyvinylpyrrolidine, dicyandiamide, tri-allyl fluorourate, urea derivatives, hydrazine derivatives, amines, polyamidoamines , Polyurethane, Alkali or Alkaline Earth Metal Salts with Higher Fatty Acids This paper is sized for China National Standard (CNS) A4 (210X297 mm) I — III — II Order — Line Please fill in this page for further information) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 406104 A7 _B7 _ V. Description of invention (j ^ f), for example, calcium stearate, zinc stearate, magnesium succinate, stearin Magnesium acid, sodium ricinole and potassium hexadecanoate, antimony pyrocatechuate or tin pyrocatechuate. 1 1 Nucleic acid agents, for example, inorganic substances, like talc, metal oxides, like titanium oxide or magnesium oxide, phosphates, carbonates or sulfates of preferred alkaline earth metals; organic compounds, like mono- or polycarboxylic acids and Its salts, such as 4-tert-butylbenzyl, adipic acid, diphenylacetic acid, sodium succinate, or sodium benzoate; polymeric compounds, such as ionic copolymers (ionomers) -1 2 · Filling and reinforcing agents, such as calcium carbonate, silicate, glass fiber, asbestos, talc, high-sensitivity clay, mica, barium sulfate, gold oxide and hydroxide, carbon black, graphite, wood powder and Or other natural product powders or fibers, synthetic fibers. 1 3 • Other additives, such as plasticizers, lubricants, emulsifiers, pigments, flow additives, catalysts, flow control agents, optical brighteners, fire retardants, antistatic agents, and blowing agents. 1 4 · Benzofuranone and indolinone, for example, described in US-A- 4,3 2 5,8 6 3; US-A- 4,3 38,2 4 4, US-A-5, 175,313; US-A- 5,2 1 6, 0 5 2, ϋS-A-5, 2 5 2, 6 4 3, DE-A-4,316,611; DE-A- 4,3 1 6,6 2 2; DE-A-4, 3 1 6, 8 7 6; EP-A-0, 5 8 9, 8 3 9 or EP-A- 0, 5 9 1, 1 0 2 or 3— [4— (2 — Acetyloxyethoxy) benzyl] -5,7-di-tert-butyl-benzofuran-2- 2--5,7-di-tert-butyl-1 3-[4-(2 — Stearyl-oxyethoxy) phenyl] benzofuran-2-one, 3,3'-bis [5,7 -di-63- This paper is in accordance with China National Standard (CNS) A4 (210 × 297) Li) (Please read the notes on the back before filling in this page)

, 1T Printed by the Consumer Cooperatives of the Central Bureau of Quasi-Staff of the Ministry of Economic Affairs 406104 V. Description of the invention ], 5 > 7-di-tert-butyl-3- (4-ethoxyphenyl) benzofuran-2-fluorene, 3- (4-ethylacetoxy-3,5-dimethyl Phenyl) -5,7-di-tert-butyl-benzofuran- 2 -pyrene, 3-(3,5-dimethyl-4,4-dimethylethyloxy) -5 * 7 — Di-tert-butyl-benzofuran-2 Compounds of formula (I) or mixtures thereof can also be used as stabilizers for most conventional substances in the field of photocopying and other photocopying techniques, especially for light buildings. Dosage, as described in Research Disclosure 1990, 31429 (pp. 4-4 to 48). The weight ratio of the compound of the formula (I) or a mixture thereof to the conventional additives is from 1: 0.5 to 1: 5. Compounds of formula (I) or mixtures thereof are particularly suitable for stabilizing dyed polyolefins, especially polypropylene. The above descriptions and comments of the compounds of formula (I) and mixtures thereof for stabilizing organic substances also apply to intermediates of formula (D) and mixtures thereof. The present invention illustrates the following examples in more detail. Unless otherwise specified, all percentages are calculated by K weight. GPC (Gel Permeation Chromatography) is an analytical step used to separate molecules of different sizes to obtain the average molecular weight (Mw, Mn) or the distribution of the molecular weight of the polymer. This technique is well-known and described in, for example, Μ 〇 〇dem Size-Exclusion Liquid Chr〇fflatography, / by WW Yan -6 4-This paper size applies the Chinese National Standard (CNS) A4 specification (2! 0X297 mm) (Please read the notes on the back before filling this page) -9 Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs ___u06104 B7_ V. Description of the invention (^ et a 1. by J. Wii 1 ey & S on s, edited by N · Y., USA, 1 9 7 9,

Pages 4-8, 249-283 and 315-340 ° The narrower molecular weight distribution is characterized by the closer the polydispersity (Mw / Mn) to 1 〇 The GPC shown in the following example is a M device with Perkin-Elmer RI LC 3 0 and ® Perki η-E 1 mer furnace GPC chromatography of ® Perkin-E 1 mer LC 2 50 was performed. All analyses were performed at 45C using three column PLGEL 3wm, which was E300mm._x7. 5mm ί.d. (provided by Polymers Laboratories Ltd. Shropshire U.K.). Tetrahydroenan was used as the eluent (flow rate 0.40 ml / min), and the sample was dissolved in tetrahydrofuran (2%) (% w / v). In the structural formulas exemplified under K, η ′ represents that there are repeating units in the molecule, and the resulting product is not uniform. These products are characterized by a number average molecular weight Mn and a polydispersity Mw / ^ 4n. Examples 1, 2, 5, 6, and 10 * Especially the products of Example 10 relate to preferred embodiments of the present invention. Example 1: Preparation of the compound of the following formula: -65- The paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) --1 --.----- 1 ------ 1T- -----. ^ (Please read the notes on the back before filling this page) A7 406104 B7 V. Description of Invention Q 1)

(Please read the precautions on the back before filling out this page) A solution, including 74.3 g (0.35 mol) of N- (2, 2, 6, 6-tetramethyl-1, 4-meridinyl) Mono-n-butylamine is dissolved in 50 ml of water * It is slowly added at 0 ° C to a solution containing 64.5 g (0.35 mol) of fluorourethane in 500 ml of xylene. Keep this temperature during the addition and for the next 1 hour. After 2 hours at room temperature, cool the reaction mixture to 0 ° C, add an aqueous solution containing 14.7 g (0.368 mol) of sodium hydroxide in 50 ml, at 1/2 hour at 0 υ and After 2 hours at room temperature * Separate this aqueous solution and add 69 · 2 grams (0 * 1 75 mol) of N printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs «N y — double (2, 2, 6, 6 —Tetramethyl-4-nonidyl) — 1,6-hexanediamine. Heat the mixture to 50 and hold the ore for 1 hour > Add 4 8 g (0.35 mol) of powdered potassium carbonate and heat to 60 C for 4 hours. After washing with M water, the organic phase was concentrated under vacuum at 60-70 ° C / 10m b a r, and 250 ml of xylene could be recovered. -66- This paper size applies to Chinese National Standards (CNS) A4 (210X297 mm) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ), Ν, Ν'—bis (2,2,6'6-tetramethyl-1, 4-? ® group) -1'6-hexanediamine, and heat the mixture to 1 501 for 2 hours and then cool And 14 g (.35 mol) of powdered arsenic was added. The mixture was reheated to 14 'M azeotropically to remove SB residual water, and heated at 16 0 P for 4 hours. Cooled to 60 After ° C, the mixture was diluted with 300 ml of xylene, filtered, and washed three times with 100 ml of oxalase. ° Concentrated in a vacuum and 60Ό / 1 mb a 1 'concentration · shrink' added 78 · 7 grams (0.147 mole) of 2-chloro-4'6-bis [N-(2,2,6,6-tetramethyl-1,4-pyridyl) -n-butylamino) -1, 3, 5_ triazine. ‘Heat the mixture to 14 ° C. for 3 hours’ and then add 5.9 g (.147 mol) of powdered sodium hydroxide while refluxing the mixture and azeotropically removing the reaction water. Heat the mixture to 160C for 4 hours, add another 5 * 9 grams (0.147 mol) of powdered sodium hydroxide, and heat to 160 υ for 2 hours. After cooling to 6 ° t: After that, the mixture was diluted with 300 ml of xylene 'and filtered, and concentrated under vacuum at 140 ° / 1 mbar. After drying, a solid is obtained, m · p * (me 11 ing po int) = 1 6 6-1 7 0 ¾ ° Μη (measured by GPC) = 3360 g / mol -67- (Please read the back first Please pay attention to this page and fill in this page) • The size of the paper is customized for Chinese national standard (CNS) μ size (210X297 mm) 406104 A7 B7 V. Description of the invention (1 ^) Mw / Mn = l · 18 Figure GPC chart analysis of 1 shows a monochromatic spectrum. Example 2: Preparation of a compound of the formula:

CH, CH, (Please read the notes on the back before filling out this page) -Packing. And from 4 · 3 g (0 · 1 · 43 mol). Formaldehyde was dissolved in 16 ml of a 2% (w / v) sodium hydroxide aqueous solution and slowly added to a solution containing 11 g Compound 1 was dissolved in a solution of 50 ml of xylene, and simultaneously heated to 110 ° C, water was added, and the reaction water was removed by azeotropic method. The mixture was then cooled to 70-80 ° C and a solution containing 4 g of sodium hydroxide in 20 ml of water was added at a temperature of 30-80 ° C. The aqueous layer was separated, and the water dried mixture was azeotropically separated. After evaporation under vacuum (140t; / lmbar), you can get a _ 6 8 1 This paper size is applicable to China National Standard (CMS) A4 specifications (210X297 mm)

αΓ *

406104 Α7 Β7 V. Description of the invention β product, m · ρ · 184—190 ° C. M η (measured by GPC) = 3650 g / mol Mw / Mn = 1-20 The analysis of the G PC chart of Fig. 2 shows a monochromatic spectrum. Examples 3 to 6: According to the procedure of Example 1, using the appropriate reactants under the same reaction conditions, the compound of formula (I) can be obtained:

Tr * η, (I) Approval for clothing (please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 69 This paper size applies to China National Standard (CNS) Α4 specifications (210 × 297) %) Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, Yin Ju 406104 A? B7 V. Number of Examples of Inventions AB R1 r2 Mn Mw / Mn mp (° C) (GPC Analysis) 3 1 1 -H-(CH2) 6- 2450 1.21 152-159 Λ Λ (Figure 3) 4 1 1 -ch3-(CH2) 6- 2770 1.20 180-187 Λ Λ (Figure 4) 5 (C4H9) 2N- (C4h9) 2n- -H _ (CH2) 6_ 3870 1.16 85-95 (Figure 5) 6 (C4H9) 2N- (C4H9) 2N- -ch3-(CH2) 6- 4060 1.16 98-106 (Figure 6) 6 / bis -rH —rH -H _ (CH2) 6 * · 3340 1.18 115-125 h3c «c-ch3 T2 H3C " C-CH3 ch3 h3c-c-ch3? HZ H3C-C-CH3 ch3 (Figure 6 / bis) (Please read the precautions on the back before filling in this Page)-installed.

、 1T -70- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) Α7 Β7 406104 V. Description of the invention (i) Example 7: Preparation of compound of the following formula:

Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs a) Preparation of Ν, Ν '-Dibutyl-N, N', N "-Trinity (2, 2, 6, 6-tetramethyl-1-piperidinyl) )-[6-(2,2,6,6-tetramethyl-1 4 imidimidinylamino) -hexyl]-[-1 1 * 3,5] -triazine-2,4,6-tri Amine-soluble, including 53 < 5 grams (0 * 1 mole) of 2-chloro-4,6-bis [N ~ (2, 2, 6, 6, 6-tetramethyl-1, 4-benzyl) —N-butylamino] -1,3,5-triazine was dissolved in 25 ml of xylene, and it was slowly added to a mixture containing 157.9 g (0,4 moles) at reflux temperature. Ν, Ν'-bis (2,2,6,6-tetramethyl-1,4-pyridyl) -1,6-hexanediamine was dissolved in 250 ml of a solution of xylene. -7 1- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm) A7 406104 V. Description of the invention (0) After adding, add 8 grams (0.2 Molar) of sodium hydroxide and heat Warm the mixture to reflux temperature for 8 hours. (Please read the precautions on the back before filling this page) Then filter the mixture and concentrate the concentrated solution under vacuum (140 ° C / lm bar). Excess N, N '— double (2, 2, 6, 6 —Tetramethyl—4-pyridyl) —1,6-hexane was removed under vacuum (190f / 0-2mbar). The obtained solid was dissolved in 200 ml of xylene, washed with M water 4 times (50 ml), and dried with MNa 2 SO 4. After filtration, the xylene was evaporated under vacuum (140Ό / lOmbar), and after drying, a product with a γπ · ρ · of 67-72 υ was obtained. Analysis of C53 H103 Ni i: Calculated value: C = 71, 17%; H = 11, 61%; N = 17-22% Found value: C = 70, 47%; H = 11 · 49%; N = 17 -09% Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs b) Preparation of Ν, Ν'-bis [4 — [(2,2,6,6 —tetramethyl_4 monopyridyl) —butylamino ] -6-chloro- [1,3,5] -triazine-2-yl] -N, N'-bis (2,2,6,6-tetramethyl-4-piperidinyl) _1,6 —Hexanediamine in a mixture containing 36.03 g (0.1 mol) of 2,4-dichloro-6 — [(2,2,6,6—tetramethyl-1—4-pyridyl) — Ding-72- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (1) 1 1 I-based amino group] — [1 > 3} 5] — Triazine dissolved in 2000 ml-· toluene 1 1 1 solution was added with 1 9 * 7 g (0 * 0 5 mol) of NN / 1 1 — double (2 »2 6 9 6 — Tetramethyl — 4 monopyridyl) — 1 6 Please read I-hexanediamine 0 Read the back 1 side I add the radon mixture to 50 V for 1 hour 9 and add 15 2 g (Note 1 010 1 Moore) of powdered potassium carbonate 9 and reheat to 60 V 4 small matters 1 I re 1 I 0 0 Fill 1 cold nest, but the mixture was washed twice with 50 ml of water and washed twice. Page ___- 1 I The organic phase was dried over sodium carbonate 9 filtered and evaporated under vacuum (1 1 I 1 0 0 / 1 0 mba Γ) 0 1 1 Available after drying— * Melting point 1 〇〇— 1 0 ° C solid 〇 Order analysis has m Chlorine I Calculated value 6 8 0% 1 1 I Found value 6 7 8% 1 1 1 1 Embroidery C) Preparation of compound 1 I * above solution contains 3 5 7 g (0 0 4 mol) of step a) 1 1 | prepared compound and 2 0 8 g (0 0 2 mol)Step b 1 1) The compound obtained is dissolved in 2000 ml of dimethyl pen and heated to a reflux temperature of 1 1 for 3 hours. 0 1 I To the mixture is added 3 2 g (0 8 mol) of powder. 1 | Sodium hydroxide and adding 埶 to reflux temperature M azeotropically remove the reaction water 0 1 1 Heat the mixture in a closed vessel for 14 hours to cool and ifff. M filter 0 1 I-73-1 1 1 Standard General Ningguo National Standard CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (^) Organic solution K water (50 ml) was washed three times, and M sodium carbonate dried Filtered and evaporated under vacuum (140 C / lmbai '). After drying, a product with m · p · 150-155 ° C can be obtained

Analysis of Cl6 1 H3 0 6 H3 6: Calculated: C = 70.54%; H = 11.18%; N = 18-28% Found: C = 70.34%; H = 11.10%; N = 1 8 0 6% ° Example 8: Preparation of compounds of the formula CA c4h,

a) Preparation of the compound of the following formula: -7 4 ~ This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) gutter (please read the precautions on the back before filling this page) 4qH〇4 V. Description of the invention Γ c4h9 HX CHq

Ν ·

Η (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs—I—a solution containing 20 grams (0 · 022 mol) of Example 7 a) And 8.1 g (0.022 mole) of 2,4-dichloro-6-[[(2,2,6,6-tetramethyl-1,4-pentidyl) -butylamino]]-a The 1,3,5-triazine was dissolved in 100 ml of xylene and heated to 41 hours. Add 3 ♦ 1 g (0.022 mol) of powdered potassium carbonate and heat the mixture to 60 ° C for 2 hours and 80 ° C for 1 hour and cool to room temperature. 34.7 g (0.088 mol) of N, N'-bis (2,2,6,6-tetramethyl-4-imidinyl) -1,6-hexanediamine and 0 * were added 88 grams (0.022 mol) of powdered hydroxide 75 This paper is sized to the Chinese National Standard (CNS) A4 (210X 297 mm) M 406104 B7 5. Description of the invention (⑺ :) Sodium. Heat the mixture to reflux temperature for 15 hours. Remove the reaction water azeotropically (please read the precautions on the back before filling in this page). ○ After cooling, filter the mixture and wash the organic solution with ethylene glycol (50 ml) three times, and Wash with K water (50 ml) three times. The organic solution was then dried with sodium sulfate, filtered, and evaporated under vacuum (14 υ / 0 · 1 m b a r). A solid product of m · p · 1 1 ◦-1 151 can be obtained. Analysis of C93H17sN2o: Calculated value: C = 70.85%; H = 11.38%; N = 17-77% Found value: C = 70 · 34%; H = 1 '26%; N = 17-52% b ) Preparation of the compound of the above formula: a solution printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, which contains 10 grams (0. 0063 moles) of the compound prepared in step a) and 3.3 grams (0. 003 15 moles) Ear) Example 7b) The compound prepared in Example 7b) was dissolved in 10 ml of trimethylbenzene, heated under reflux for 3 hours, and 1.75 g (0. 0 13 mol) of powdery carbonic acid was added. Potassium. Heat the mixture to reflux temperature for 24 hours, remove the reaction water by azeotropy. 0 Cool the reaction mixture, filter and evaporate under vacuum (1 40 t / This paper size applies to China National Standards (CNS) A4 specifications (210X 297). (Centi) 406104 A7 B7 V. Description of the invention (7 M 0 · 1 mbar). The obtained solid product] 71, 〇, 176 — 1 8 3.0. Analysis of C242 H4 5SNS4: Calculated value: C 2 70 · 50%; Η = 11 · 15%; N = 18 * 35% found value: C = 70.46%; H = 11 · 17%; N = 18-21% Example 9: Preparation of the compound of the following formula: Consumption by employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by a cooperative

a) Preparation of compounds of the following formula: -77- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) Description of invention Η

Η 3 (Please read the notes on the back before filling out this page) -9 Consumers 'cooperation with the Central Bureau of Standards of the Ministry of Economic Affairs to print a solution, including 8 g (◦' 005 mole) of the compound 8a) And 1.83 g (◦ * 0 0 5 mol) of 2,4-dichloro-6 — [(2,2,6,6—tetramethyl-1, 4-isopropylidene) -butylamino ] [1 * 3,5] -triazine was dissolved in 100 ml of xylene and heated to 40 to 1 hour. After adding 1.4 g (0.01 mol) of powdered potassium carbonate, the mixture was heated to 60 ° C for 2 hours and 80 ° C for 1 hour. 7.9 g (0.02 mol) of N, Ny-bis (2,2,6,6-tetramethyl-1,4-pentidinyl) -1,6-hexanediamine and 0.4 were added Grams (0.01 mol) of powdery sodium hydroxide, and the mixture was heated at reflux for 4 hours, during which the reaction water was removed azeotropically. Then filter the mixture, organic solution M glycol (3 ◦ ml) and -78- This paper size applies Chinese National Standard (CNS) A4 specifications (2! 0'〆297 mm) A7 B7 V. Description of the invention) Water ( 50 ml) wash and irrigate three times. After drying over sodium sulfate and filtering, the organic solution was dried under vacuum (140 ° C / lmbar). After drying, a solid product can be obtained. Analysis of m · p · 143-147 〇cl3 3 Hz S3 N2 9: Calculated value: C = 70.73%; H = 11 · 29%; N = 17-98¾ Found value: C = 70 * 68%; H = 11 · 25%; N = 17-88¾ b) a solution of the compound of the formula above, including 9.5 g (0.004 mol) of the compound prepared in step a) above and 2 * 2 g (0. 002 1 mol) The compound prepared in Example 7 b) was dissolved in 100 ml of xylene and heated at reflux temperature for 1 hour. Add 1.2 grams (◦ · 0084 mol) of powdered potassium carbonate printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page), and heat the mixture under reflux for 16 hours to The reaction water was removed azeotropically. The temperature was then raised to 180 ° C for 10 hours and the mixture was concentrated to 50 ml. Next, the mixture was cooled, washed three times with K water (30 ml), and dried with K sodium sulfate. After filtration, the organic solution was concentrated under vacuum (140 TJ / 0 · 1 -7 9- this paper size applies Chinese National Standard (CNS) A4 specifications (210 × 297 mm) 5 406104, description of the invention 0 A7 B7 m b a r). After drying, a solid product can be obtained, m, p * 180-184 〇C322 Hs〇SN72 Analysis: Calculated value: C = 70'49%; H = 11.13%; N = 18-38¾ Found value: C = 7〇. 03%; H = 1 1. 01%; N = Heart 18-21% Example 1 0: Preparation of the compound of the formula:, N, (Please read the precautions on the back before filling this page) cn n — Η Yin Ju N—'hN —— (called a Ν ′ nvn ^ P > [\ ch3 ^ c ^ TjL · HjC ^ N ^ CK, Η, Ο ^ Ν I Η

Ν 一 叫 一 Ν CH, KjC ^ 'N' 'CHj κρ ^ Ν

Η Η Ν ^ Ν a solution containing 74.3 g (0.35 mol) of N— (2,2,6,6—tetramethyl-1—4-pyridinyl) -n-butylamine soluble— 80- The paper scale is in accordance with the Chinese national standard (CNS M4 specification (21 × 297 mm) 406104 A7 B7 V. Description of the invention (eg) In 50 ml of water, add it slowly to a volume containing 64 · 5 g ( (Please read the precautions on the back before filling this page) 〇 '35mole) Fluorouric chloride is dissolved in 50 ml of xylene, the temperature is 0 ° C, keep this temperature when adding, and then Hold for 1 hour. After 2 hours at room temperature, cool the mixture to 0 ° C, and add 14.7 g (0.368 mol) of sodium hydroxide in 50 ml of water to dissolve the water. At 0 ° C 1 / 2 hours, and after another 2 hours at room temperature, separate the aqueous solution and add 69 * 2 g (0 * 175 mol) of N, N, -bis (2,2,6,6-tetramethyl-1 4-Nanidinyl) -1,6-hexanediamine. Heat the mixture to 50 for 1 hour, add 48.4 g (0.35 mol) of powdered potassium carbonate, and heat to 60 g. 4 hours After washing with M water, the organic phase layer was under vacuum at M60-70 ° C / 1 mbar concentration > 250 ml of xylene was recovered during the addition. 138 * 1 g (0 * 35 mole) of N was added N′—bis (2,2,6,6—tetramethyl-1—4-pyridinyl) —1,6—Hexanediamine, a consumer cooperative of employees of the Central Standards Bureau of the Ministry of Economic Affairs, and heating the mixture to 15 Cool for 0 2 hours, and add 14 g (0.35 mol) of powdered sodium hydroxide. Heat the mixture to 140 ° C for another 4 hours, during which time the residual water is removed by azeotropy, and again at 16 Heat for 4 hours at 0 C. After cooling to 60 ° C, K 3 0 ◦ ml of dimethylbenzene diluted mixture is filtered and washed with K 1 ◦ 0 ml of ethylene glycol three times. _ 8 1 _ This paper size applies to China Standard (CNS) A4 specification (210X 297 mm) 406104 A7 B7 V. Description of the invention (I) After concentrating under vacuum and 601/1 Omb ar, add 54 * 4 grams (0.147 mol) of 2 — Chloro-4,6-bis- (dibutylamino) -1,3,5-triazine. Heat the mixture to 14 0 t: 3 hours, then add 20 · 3 g (〇 · 1 4 7 Mol ) Powdered potassium carbonate, the mixture was heated under reflux, and the reaction water was removed azeotropically. The mixture was heated to 16 0 υ for 4 hours, and then 20 · 3'g (0 · 147 mole) of powdered potassium carbonate was added, and Reheat to 16o 2 hours. After cooling to 60 ° C, the mixture M 300 ml of xylene was diluted, filtered and concentrated under vacuum at KK 140 ° C / 1 m b a r. A solid product was obtained after drying, m · p · = 130-136 ° C. Μ η (G Ρ C) = 2830 g / mol Mw / " Mn = l · 22 Figure 7 shows a chart of GPC analysis. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Example 1 1: Preparation of the compound of the following formula:

406104 A7 B7 V. Description of the invention (# Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy A) 2 * 4 —Bis [bis ((2-hydroxyethyl) -amino group] _6 —Nitrogen- [1, 3, 5] Monotriazine synthesis is maintained at 0-5 ^ 0, 92.9 grams (0.5 mole) of cyanuric chloride is slowly added to a solution containing 100 ml of acetone in 920 ml of water , Cooled to 0 ° C, and then slowly added 105.1 grams (1 mole) of diethanolamine to the reaction mixture, while maintaining the temperature at about 5 υ. Stir the solution for 1/2 hour at a temperature of 5-10 ° C, and slowly add a solution containing 63 · 6 g (◦ · 6 mol) of Na2C03 in 7000 ml of water, and heat the solution to 45 ° F, and maintained at this temperature for 4 hours. The mixture was then filtered, the resulting solid M was washed twice with water, and dried in a vacuum oven (100 ° C / 1 m b a r). After drying, the resulting product was a white solid with a melting point of 1 46-1 4 7 ° C. Ci! Hz. Analysis of Ns〇4 C1: Calculated value: C 1 = 1 1 · 0 2% Hair value: (: 1 = 11.00% (Please read the precautions on the back before filling this page) This paper size is applicable to China Standard (CNS) A4 specification (2 丨 0'〆297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7___ V. Description of the invention d) B) Under Ot: one will contain 74.3 grams (0 35 mol) of N- (2,2,6'6-tetramethyl-1,4 ##)-n-butylamino group dissolved in 5 ◦ml of water slowly added to a solution containing 64 · 5 grams (0.35 moles) of cyanuric chloride is dissolved in a solution of 500 ml of xylene, and it is kept at this temperature during the addition, and it is kept for another hour. After 2 hours at room temperature, the mixture was cooled to 0 t, and a solution of 14.7 g (0.368 mol) of sodium hydroxide in 50 ml of water was added. After 1/2 hour at 0 ° C and another 2 hours at room temperature, the aqueous solution was separated and 69.2 g (0 175 mol) of N'N'-bis- [2, 2, 6, 6 -Tetramethyl-4-pyridinyl] -1,6-hexanediamine, heat the mixture to 50 ° C for 1 hour, add 48 '4 g (.35 mol) of powdered potassium carbonate, and heat to 60 ° C for 4 hours. After washing with M water, the organic phase layer was concentrated under vacuum at M60 0-70C / 100 mb a r, and 250 ml of xylene could be recovered. Add 138,1 g (0.35 mole) of N, N'-bis ~ [2,2,6,6-tetramethyl-4-piperidinyl] -1,6-hexanediamine, and heat the mixture Cool to 15 ° C for 2 hours, cool and add 14 g (35 mol) of sodium hydroxide in powder form. The mixture was heated to 1 4 ◦ Ό for 4 hours, and the remaining reaction water was removed azeotropically ′ and then kept at 160 t for another 4 hours. After cooling to 60 ° C, the mixture was diluted with 300 ml of xylene -84- This paper is commonly used in China Standard (CNS) A4 (210X297 mm) --1-: ----- Packing ----- l · Ordering ------- Silk (please read the precautions on the back before filling this page) A7 B7 V. Description of the invention (P), filtration and K 2 0 ml Wash with alcohol three times. After concentration under vacuum at 60 ° C / 10 mbar, 4 7 · 3 g (0,14 7 mol) of 2,4-bis- [bis- (2-hydroxyethyl) -amino group ] -6-chloro- [1,3,5] triazine. Heat the mixture to 140 ° C for 1 hour, cool to room temperature, and add a solution of 14 g (0.35 mol) of sodium hydroxide in 50 ml of water, then heat the mixture to 95 ° C for 4 hours, cooled to room temperature, and the aqueous layer was separated. The organic phase layer M was washed and washed once with water, and the residual water was removed azeotropically. After concentration under vacuum (200 ° C / 12 ′ 3mbar), a yellow product was obtained with a melting point of 155-51.6. Mn (GPC) = 2852 g / mol Mw / Mn = 1 · 48 G P C The analysis chart is shown in FIG. 8. Threading (Please read the notes on the back before filling out this page) Yin Fan, a Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Example 1 2: Preparation of a compound of the following formula:

406104 V. Description of the invention (Q1) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A) 2,4 one pair one [bis one (2-methoxyethyl) -amino group] — 6 —chloro — [1, 3,5] Synthesis of monotriazine According to the procedure described in Example 1 1 A), 9 2 · 2 g (0.5 mole) of fluorourethane and 133.2 g (1 mole) were used. Mono- [2-methoxyethyl] -amine is reacted in a solution containing 100 ml of acetone and 92 ml of water. After evaporation of the acetone / water mixture, the resulting resinous compound was crystallized from ethanol. The product was a white solid with a puppet point of 40 to 4 ° C. C! S Η 2 s Analysis of N 5 0 4 C 1: Calculated value: C1 = 9 * 38% Found value: C 1 = 9 · 4 2% B) According to the procedure of Example 1 1 B, use an appropriate amount of appropriate The reactant can obtain the desired product, which is a white solid with a melting point of 1 3 to 1 53 υ. Μη (G P C) = 3017 g / mol Mw / Mn = l · 35 G P C Analytical spectrum is shown in FIG. 9. Example D: Preparation of the compound of the following formula: -86- The paper size is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) 406104 Α7 Β7 V. Description of the invention ( y >)

Λ, ya-• Ν 1 Ν Ν

h3c

H3CH3C

NIH chch. 3

NIH

ca-NIH 2 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs at 2, 50 milli (0 · medium. Then add a 50 milli 6 9 · 2, 6, heat 0 · 3 6 0 ° C recycling 2 ot, a solution containing 74 '3 g (0 * 35 6, 6 -tetramethyl-4 4-meridinyl) in one liter of water, slowly added to 35 mol under stirring) cyanuric chloride dissolved in After 500 milliseconds, stir the mixture at room temperature for 2 hours, in an aqueous solution containing 14.7 g (0.368 mol) of water, and then separate the aqueous solution from mol) N-(2 n-butylamine dissolved in a solution containing 6 After 4.5 g of a solution of xylene was cooled to 0 υ, sodium hydroxide was dissolved in the phase layer * 2 g (0.175 mol) of Ν, Ν'-bis- [2,, 6-tetramethyl A mixture of 4- (4-pyridinyl) -1,6-hexanediamine to 50 ° C for 1 hour, then 5 moles) of powdery anhydrous carbonic acid for 4 hours. After washing and filling with water, 50 ml of xylene) was concentrated, and N * N'-bis- [2,4-piperidinyl] -1,6-hexanediamine 0 υ 2 was added with 5 mol). After 8 hours, add 28 grams (0. Sodium oxide, and heat the mixture under reflux for 8 hours-87-, and then add 4 8 · 4 grams (potassium, and heat the mixture to a minimum of the organic phase layer (into 138. 1 grams (3, 2, 6, 6-tetramethyl one. After heating the adduct to 1 4 70 mol) of powdery hydrogen, the reaction water is azeotropically removed. Add (Please read the precautions on the back before filling this page ) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm). Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 406104 A7 B7. 5. Description of the invention (^) 2,500 ml of xylene, and then filter the mixture. The solution was concentrated under vacuum (14.0 ° C / 1 mbar), and excess N, N'-double-one [2, 2, 6, 6] was removed under vacuum (1 90 ° C / 0, 2mbar). 6-tetramethyl-4-piperidinyl] -1,6-hexanediamine. The obtained solid was dissolved in xylene, washed with M water (50 ml) four times, and dried over Na 2 SO 4 After dysprosium, the xylene solvent was evaporated under vacuum (140C / 10mbar), and after drying, a product was obtained with a melting point of 1 3 0 -1 3 8 ° C. Fractions; · '%% 2 2 5 2 ο% 9 Ν · 2 · 15 0 7. 7 1 -I 7 II Η c 1 C 4:: G value 1 Calculated C Calculated D Example

N-Η ο ο

% 4 5 7 rH N% 6 4 r-H 1I II Η Ν% 8 4 1-_ 1 II Η The prepared compound is ib

This paper size applies Chinese National Standard (CNS) A4 specification (210 > < 297mm) Staple (please read the precautions on the back before filling this page) 406104 A7 B7 V. Description of the invention (#) at 0 ° C , One containing 74.3 grams (0 * 35 moles) N — (2 (please read the precautions on the back before filling out this page), 2, 6, 6 —tetramethyl_4—imididyl) —one A solution of monobutylamine in 50 ml of water was slowly added with stirring to a solution containing 64 · 5 g (35 · mol) cyanuric chloride in 500 ml of xylene. Then stir the mixture at room temperature for 2 hours. After cooling to 0 ° C, add 1 4 * 7 grams (0 · 368 mol) of argon sodium dissolved in 5 ◦ of water to dissolve it. The aqueous phase was then separated, and 69'2 g (0 * 175 mol) of N, N'-bis- [2, 2, 6, 6, 6-tetramethyl-4-piperidinyl] -1, 6- Hexanediamine, the mixture was heated to 50 ° C for 1 hour, then 48.8 g (0.35 mol) of powdered anhydrous potassium carbonate was added, and the mixture was heated to 60 t: 4 hours. After washing with K water, the organic layer was concentrated to a minimum amount (recovering 250 ml of xylene), and 138.1 g (3 * 5 moles) of Ν, Ν 'one pair one [2, 2, 6 , 6-tetramethyl-4-imididyl] -1,6-hexanediamine. After the consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs, Du printed, after heating the mixture to 1 4 0 υ for 2 hours, add 28 g (0.70 mol) of powdery sodium hydroxide and heat the mixture under reflux for 8 hours. Water was removed azeotropically. The mixture was then cooled to 6 ° C, K 3 0 ml of xylene was diluted and filtered. Next, this solution M 100 ml of ethylene glycol was washed three times, and then condensed under vacuum (1 40 ° C / 1 mbar), and after drying, the paper standard of this paper applies Chinese National Standard (CNS) A4 Specification (210X 297 mm) 4 3 ° C.

Mn (GPC) = 2555 g / mole Mw / Mn = l · The analysis chart of 25 G P C is shown in Figure D-1. Examples D — 2 to D — 5: Follow the steps of Example D — 1 to use each stylist (please read the precautions on the back before filling this page)

Number of printed examples of employees' cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Rt r2 B Melting point (° C) Mn Mw / Mn D-2 -Η-(CH2) 6- CH, CH. 1 3 1 3 H3C-C-CH2-C —NH— ch3 ch3 97-105 2631 1.28 D-3 -Η-(CH2) 6- CH, 1 3 H3C-〇-NH — ch3 121-128 2475 1.34 D-4 -Η-(CH2) 6- r ~ \ —N 0 v_y 125-130 2340 1.24 D-5 -Η-(CH2) 6- -N (C4H9) 2 68-72 2773 1.20 -90-

R

This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention (shirt) Examples of GPC analysis maps of D-2 to D-5 are as follows Figures D-2 to D-5. Example I: Photostabilization of polypropylene fibers 2.5 g of stabilizer of Table 1, 1 g of tris (2,4-di-butylphenyl) phosphite, 1 g of monoethyl 3 ' 5-di-tert-butyl-4-hydroxybenzyl-calcium phosphate, 1 g of calcium stearate and 2.5 g of titanium dioxide in a slow mixer and 1,000 g of polypropylene powder ( Has a melt index = 12 g / 10 minutes, measured at 2 30 ° C and 2. 16 kg) mixed. Extrude the mixture at 200-230C to obtain polymer pellets, which are then converted into fibers (Pilot-Sumirago (VAK 11. a 1 y)) using a pilot-type device, and under the following conditions Next operation:

Extrusion temperature: 230 — 245 ° C -91- This paper size is applicable to Chinese National Standard (CNS) A4 (210X297mm) I n III nn II Order IIII line (Please read the precautions on the back before filling this page ) Delete i w-, ^-V. Description of the invention)

Extrusion head temperature: 2 5 5-2 6 0 ° C Stretching ratio: 1: 3 · 5 Linear density: 1 1 denier / filament The fiber prepared in this way is fixed on a white board, and the temperature is at 6 6 WR Weather-O-Meter (ASTM D2565-85) was exposed, and the blackboard temperature was 6 3 Ό. After the sample has been exposed for various times, the residual toughness is measured using a constant speed tensiometer, and then the time required for exposure to half the initial toughness (Ts.) Is calculated. For comparison, another sample was prepared and exposed as described above, but without the stabilizer of the present invention. The results are listed in the table. Ts 〇 (hours) 2 5 0 2 10 0 19 5 0 19 9 0 18 2 0 19 0 0 2 2 10 (Please read the notes on the back first) Refill this page) Stabilizer without stabilizer Example 1 Compound Example 2 Compound Example 3 Compound Example 4 Compound Example 5 Compound Example 1 0 Compound This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) Central Standard of the Ministry of Economic Affairs Bureau Consumer Consumption Cooperative Printing Poly A7 V. Explanation of the Invention (Example II) * Interaction of pigments in polypropylene test boards 5. 625 grams of stabilizer of Table 2, 13.500 grams of Pigment Blue 15 " Flush " (50% blended in polyethylene) and 25.75 grams of polypropylene powder (having a melt index of approximately 14, measured at 230 and 21.6 kg) were added to a Haake internal mixer (Room temperature) (Haake Buchler Rheochord System 40, using 60 c c 3 pieces of Rheomixei with crooked knife). The rotation speed of the crooked wheel knife is 5 RPM (revolutions per minute). A 5 kg ladle is used to seal the bowl mouth. The temperature rises to 180 ° F and is maintained at 180 ° C. The total time is 30 minutes. The mixture is removed after 30 minutes at 180 ° C and cooled to room temperature. The resulting mixture is called a concentrate and needs to be reused. 0.90 g of this concentrate, 3.600 g of titanium dioxide " Flush " (50% mixture / polyethylene), and 40.500 g of polypropylene powder (having a melt index of about 14, in 2 3 0 〇 and 2 · 16 kg) Add to a ® HAAKE mixing bowl-shaped container, the temperature is 1 60Ό, the twisted knife is rotated by K20RPM, and a 5 kg ladle is used to seal the bowl. It rises to 170, and R PM rises to 1.25. The total time is 30 minutes. The molten mixture was removed at 1 70 ° C, transferred to a hand-operated tool (room temperature) and formed into a circular test plate with a diameter of 1 mm x 25 mm. The resulting mixture was called 〃letdown〃, and this test plate was called 〃letdown test Board ". -93- This paper size applies to Chinese National Standard (CNS) A4 (210 × 297 mm) I 111 n 1 I 11 i — Order — 111 I ^ (Please read the precautions on the back before filling this page)

Delta E 0 · 3 0 · 4 .06104 B7_ 5. Description of the invention: Up color difference, measure delta E (CIE color difference equation) including the stabilizer sample let down test board of Table 2 and stabilizer-free letdown test board. This measurement was made using Applied Color Systems

Spectrophotometer Model CS-5 (USA) was performed. The measurement parameters were 4 00 — 7 00 nm — scanning, small area inspection, reaction, honey light D 6 5, 10 degree observation. The above method conditions simulate the manufacture of pigments and stabilizer concentrates (parents) and subsequent let-down (dilution) into the final plastic article. Higher delta E values represent pigment aggregation and poor dispersion. A delta E value of 0 · 5 or less cannot be seen by the eyes. Table 2 Stabilizer Example 1 Compound Example 1 0 Compound Example III: Light-stabilizing effect of polypropylene tape 1 g of each of the compounds listed in Table 3, 1 g of three [2,4-di-tert-butylphenyl] Phosphite, 5 grams of pentaerythritol tetra [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] and 1 gram of calcium stearate in a pressure mixer and neutralized 1 0 0 0 grams of polypropylene powder (with a melt index of 2 · 1, measured at 230 P and 2 '16 kg-9 4 ~ This paper size applies to Chinese National Standard (CNS) A4 size (210X297 mm)) I stapler (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 3: Τ 5 0 (hours) 5 0 0 2 9 2 0 2 6 0 0 -95- a406104 B7 V. Description of the invention (p)) Mixing ° The mixture is extruded at 200-220 ¾ to obtain a polymer pellet * which is then converted into an extension band with a thickness of 50 «m * and 2 · 5 mm wide (for semi-industrial tape devices) (®Leonard-Sumirago (VA)-Italy), operating conditions are : Extrusion temperature: 210 — 2301C Extrusion head temperature: 240 — 26〇υ Extension ratio: 1: 6 The resulting ribbon is fixed on a white board, and W-Weather-0-Meter 65WR (ASTM D 2 5 6 5-8 5) Exposure, blackboard temperature is 6 3 ° C. Measure the residual toughness (using a constant-speed tensiometer), and measure the toughness of the sample at an indefinite time. From this, the time required to reach half the initial toughness (T50) can be calculated. For comparison, another tape without the stabilizer of the present invention was prepared and exposed under the same conditions. The results are listed in Table 3. Table Stabilizers No Stabilizers Example 1 Compound Example 1 0 Compound This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) — — — — — — I equipment — — I order — silk (Please read the precautions on the back before filling out this page) 5. Description of the invention (, /) A7 B7 Example IV: Antioxidant effect of polypropylene test board 1g each of the compounds listed in Table 4 and 1g stearic acid Calcium was mixed in a slow mixer with 100 g of polypropylene powder (having a melt index of 4.3, measured at 230 and 2.16 kg). Extrude the mixture twice (200-220f) to obtain a polymer pellet, which was then converted to a 1 mm thick test plate (6 minutes) by a K-die at 230C. Then use DIN 5 3 4 5 1 to punch the test board. The test block obtained is exposed to a powerful circulating air oven and the temperature is maintained. 1 3 The time is 180 hours (hours) when printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. ). The results are listed in Table 4. Table Stabilizers No Stabilizers Example 1 Compound Example 1 0 Compound is folded to view the test block to determine the time required to crack 4: Time to crack (hours) 2 5 0 15 6 0 14 9 0 Example V: Polypropylene test panel aging in the oven 5 g of each compound listed in Table 5, 1 g of tris [2,4 t-butyl-butylphenyl] phosphite, 1 g of pentaerythritol tetra [ 3— (3, -96- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) I n DII f I silk (please read the precautions on the back before filling this page)) 406104 B7 V. Description of the invention (/ ≫) 5-Di-tert-butyl-4-hydroxyphenyl) propionate] and 1 g of calcium stearate are mixed in a slow mixer with 1000 g of polypropylene powder (With a melt index of 2 * 1, measured at 2 3 0 ° C and 2 * 16 kg) 0 The mixture is extruded twice at 200-220C to obtain pellets of the polymer, and then the K compression die is converted to 2 Transformed into a 1 mm thick test plate at 30 ° C (6 minutes). Then exposed to a powerful circulating air furnace for 7 days, the temperature was maintained at 120 ° C, and after exposure in the furnace, the yellowing finger of the test board was measured according to ASTM D 19 2 5 ® MINOLTA CR 210 colorimeter (MINOLTA -Japan) Receive (YI). The results are shown in Table 5. table 5 :

Stabilizer YI Example 1 Compound 2 2 · 1 ◦ Example 1 0 Compound 2 1 · 1 0 Batch of two-tongue green (please read the precautions on the back before filling out this page) Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Yindan-97 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 1 '· 4 miscellaneous 1 detailed illustration Brief description Figure 1 is the GPC chromatogram of the compound of Example 1; Figure 2 is the GPC chromatogram of the compound of Example 2 Figure 3 is the GPC chromatogram of the compound of Example 3; Figure 4 is the GPC chromatogram of the compound of Example 4; Figure 5 is the GPC chromatogram of the compound of Example 5; Figure 6 is the GPC chromatogram of the compound of Example 6; Figure 6 / bis is the GPC chromatogram of the compound of Example 6 / bis; Figure 7 is the GPC chromatogram of the compound of Example 10; Figure 8 is the GPC chromatogram of the compound of Example 11; Figure 9 is the GPC chromatogram of the compound of Example 12 Figure D-1 is the GPC chromatogram of the compound of Example D-1; Figure D-2 is the GPC chromatogram of the compound of Example D-2; Figure D-3 is the GPC chromatogram of the compound of Example D-3; Figure D-4 is the GPC chromatogram of the compound of Example D-4; Figure D-5 is the GPC chromatogram of the compound of Example D-5. 406104

Brief Description of the Drawings:

Fig. 1 is the chromatogram of GPC of the compound of Example 1;

Fig. 2 is the chromatogram of GPC of the compound of Example 2;

Fig. 3 is the chromatogram of GPC of the compound of Example 3;

Fig. 4 is the chromatogram of GPC of the compound of Example 4;

Fig. 5 is the chromatogram of GPC of the compound of Example 5;

Fig. 6 is the chromatogram of GPC of the compound of Example 6;

Fig. 6 / bis is the chromatogram of GPC of the compound of Example 6 / bis; Fig. 7 is the chromatogram of GPC of the compound of Example 10;

Fig. 8 is the chromatogram of GPC of the compound of Example 11;

Fig. 9 is the chromatogram of GPC of the compound of Example 12;

Fig. D-1 is the chromatogram of GPC of the compound of Example D-1; Fig. D-2 is the chromatogram of GPC of the compound of Example D-2; Fig. D-3 is the chromatogram of GPC of the compound of Example D-3; Fig. D-4 is the chromatogram of GPC of the compound of Example D-4; Fig. D-5 is the chromatogram of GPC of the compound of Example D-5.

Claims (1)

Male port 4 0 1 6 o 4 8 8 8 8 ABCD patent application scope 1 · A mixture * includes at least three different formulas (la)-(lb) and (Ic), or formulas (Xa), (Xb) and ( Xc) a monodisperse compound having a polydispersity Mw / Mn value of 1 · 1 to 1 · 7: Ν · Iπ FV CH, CHi (la) (Please read the notes on the back before filling this page), -'Λ · A- · Ν · I R (lb) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ⑽ Among the formulas (la), (lb), and (Ic), A, B, R -1 _ This paper size applies the Chinese National Standard (CNS) A4 specification (2 丨 0〆297 public envy) 406104 8 8 8 8 ABCD, Rt and R2 are the same and are defined as follows, and the ratio of the compound of formula (I a): (I b): (Ic) is 2: 1.5: 1 to 2: 0 · 5: 0 · 0 5; 1 Order.-"-(Please read the precautions on the back before filling in this page) This paper size uses the Chinese National Standard (CNS) A4 specification (210X297 mm) 6. Application for patent scope 406lOd __ 6. Application for patent The range where A, B, R, Ri * R2 is defined as follows, B comes with (2,: to 0) 1 and a: X 5 B (. Such as the formula 1 b ο X: 2 as an example compared物 合 化) ο C. X ο / 1. *: 5 ί and} system b limit X hLX / ί \ But in 'X 2', (Yuan 5 and Shan 'cover B is more than a different rice ) BC} group a should be X inverse (where formula 1 is in each, R c AR is in base, should be tvj should be B inverse to R inverse; the basic meaning of hydrogen is the same as the two separate R phases and not 1 Mutual R 1 R / V Ν-is; C0 of the branched branch is closed C phase 1 No 2 Mutual 1 or 5 R (Please read the precautions on the back before filling this page) VI / Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperative, C Hydrogen is the same or the same phase as / \ — / IV 5 R and 4 R 2 groups or 6.1 I groups R 1 € ZINCS group 4 > is a hydroxyl group Yes Yes e Yes_ Outer XRR 4 CV 4 R / VNI or Ethyloxymethyl; Alkyl 8C 5 R 2 In addition, this paper uses Chinese National Standard (CNS) A4 specifications (210X297 mm) ) 4〇〇104 8 8 8 8 8 ABCD Anti-base B is not related to each other as defined in A. 2 * As a mixture of item 1 in the scope of patent application, the mixture has a polydispersity Mw / Mn value of 1 * 1 to 1.5. 3 · If the mixture of item 1 in the scope of patent application, where A and B meters (same or different) is a N (Cl-C8 alkyl) 2 or the group group of the following formula: (Please read the precautions on the back first (Fill in this page again) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs H3c ch3 h, c ch3 -4-This paper; using the Chinese National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs _§__ 6. Scope of patent application 4 · If you apply The mixture of item 1 in the patent, wherein Ri is hydrogen, R2 is hexamethylene, A and B are dibutylamine, and B is N— (2, 2, 6, 6—tetramethyl-4 piperidinyl). ) Monobutylamine, and the product is 2,2,6,6-tetramethyl- 4-piperidinyl. 5 · —A method for preparing a mixture as described in item 1 of the scope of the patent application, including: 1) Compounding a compound of formula (A) * in a stoichiometric ratio aa \ 1 / reaction product \ 1 / B / fv formula-and Η N1R Wuhehua \ — / C yf \ Formula 1 To the paper size of this paper, use Chinese National Standard (CNS) A4 (210X297 mm) --------- t ------ ΐτ- -----. ^ a-(Please read the notes on the back before filling out this page) (B) 4 Correction 04. Patent application scope α 0 18 \-, 1 is divided into single cases} than D (^ 7 the formula and the contract are not changed,} species 3 Β three are {valued formulas containing η 'one one, and. To the material is combined, mixed Should} be reversed to C} group < (Please read the precautions on the back before filling this page)% Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Employee Cooperative Co-operative Printed Type 1 and Mixed Material \ J · 2 Self-contained and Unified Application} The size of this paper is applicable to China National Standards (CNS) A4it (210X297) Α8 Β8 C8 D8 Scope of patent application cb (Ε) Cl N N. -A (E *) Day * (Reverse ratio is the stoichiometric ratio), the mixture can be obtained as in the scope of patent application item 1; 1) to 3) the reaction is in an organic solvent, and It is performed in the presence of an inorganic base. 6 * — a composition, including a synthetic 'polymer that is sensitive to degradation caused by light, heat or oxidation, and a range of 0. 0 1 to 5% by weight (relative to the weight of the synthetic polymer) as claimed in the patent application Mixture of item 1. ----- ^ ----- 1% ------ Order · ------ 0 •-»(Please read the notes on the back before filling out this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs The paper size printed by the consumer cooperative is applicable to the Chinese National Standard (CNS) A4 (210X297 mm)