TW521075B - Process for the production of ruthenium (III) acetate solution - Google Patents
Process for the production of ruthenium (III) acetate solution Download PDFInfo
- Publication number
- TW521075B TW521075B TW086117657A TW86117657A TW521075B TW 521075 B TW521075 B TW 521075B TW 086117657 A TW086117657 A TW 086117657A TW 86117657 A TW86117657 A TW 86117657A TW 521075 B TW521075 B TW 521075B
- Authority
- TW
- Taiwan
- Prior art keywords
- solution
- rhodium
- reducing agent
- item
- iii
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract 4
- OJLCQGGSMYKWEK-UHFFFAOYSA-K ruthenium(3+);triacetate Chemical compound [Ru+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OJLCQGGSMYKWEK-UHFFFAOYSA-K 0.000 title abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 51
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 11
- 229910052703 rhodium Inorganic materials 0.000 claims description 10
- 239000010948 rhodium Substances 0.000 claims description 10
- 150000002429 hydrazines Chemical class 0.000 claims description 4
- 229910003450 rhodium oxide Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 2
- PZSJYEAHAINDJI-UHFFFAOYSA-N rhodium(3+) Chemical compound [Rh+3] PZSJYEAHAINDJI-UHFFFAOYSA-N 0.000 claims 2
- ALLIZEAXNXSFGD-UHFFFAOYSA-N 1-methyl-2-phenylbenzene Chemical group CC1=CC=CC=C1C1=CC=CC=C1 ALLIZEAXNXSFGD-UHFFFAOYSA-N 0.000 claims 1
- IHLDFUILQQSDCQ-UHFFFAOYSA-L C(C)(=O)[O-].[Ge+2].C(C)(=O)[O-] Chemical compound C(C)(=O)[O-].[Ge+2].C(C)(=O)[O-] IHLDFUILQQSDCQ-UHFFFAOYSA-L 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- CULSIAXQVSZNSV-UHFFFAOYSA-N germanium(4+) Chemical compound [Ge+4] CULSIAXQVSZNSV-UHFFFAOYSA-N 0.000 claims 1
- -1 ruthenium (III) carboxylate Chemical class 0.000 abstract description 4
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 abstract 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- BPEVHDGLPIIAGH-UHFFFAOYSA-N ruthenium(3+) Chemical compound [Ru+3] BPEVHDGLPIIAGH-UHFFFAOYSA-N 0.000 abstract 2
- RADGOBKLTHEUQO-UHFFFAOYSA-N ruthenium(4+) Chemical compound [Ru+4] RADGOBKLTHEUQO-UHFFFAOYSA-N 0.000 abstract 1
- 229960000583 acetic acid Drugs 0.000 description 14
- 239000000243 solution Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- SVOOVMQUISJERI-UHFFFAOYSA-K rhodium(3+);triacetate Chemical compound [Rh+3].CC([O-])=O.CC([O-])=O.CC([O-])=O SVOOVMQUISJERI-UHFFFAOYSA-K 0.000 description 5
- 229910001868 water Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000012362 glacial acetic acid Substances 0.000 description 3
- SJLOMQIUPFZJAN-UHFFFAOYSA-N oxorhodium Chemical compound [Rh]=O SJLOMQIUPFZJAN-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000002079 cooperative effect Effects 0.000 description 2
- XSXHWVKGUXMUQE-UHFFFAOYSA-N dioxoosmium Chemical compound O=[Os]=O XSXHWVKGUXMUQE-UHFFFAOYSA-N 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 150000003284 rhodium compounds Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- GWNAJLSPZNJDQW-UHFFFAOYSA-N [Na].[Ge] Chemical compound [Na].[Ge] GWNAJLSPZNJDQW-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- GTYNIXHTXBGGHQ-UHFFFAOYSA-N acetic acid osmium Chemical compound [Os].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O GTYNIXHTXBGGHQ-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- KZYDBKYFEURFNC-UHFFFAOYSA-N dioxorhodium Chemical compound O=[Rh]=O KZYDBKYFEURFNC-UHFFFAOYSA-N 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- LNYNHRRKSYMFHF-UHFFFAOYSA-K europium(3+);triacetate Chemical compound [Eu+3].CC([O-])=O.CC([O-])=O.CC([O-])=O LNYNHRRKSYMFHF-UHFFFAOYSA-K 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- OLQSNYOQJMTVNH-UHFFFAOYSA-N germanium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Ge+4] OLQSNYOQJMTVNH-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- KTEDZFORYFITAF-UHFFFAOYSA-K rhodium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Rh+3] KTEDZFORYFITAF-UHFFFAOYSA-K 0.000 description 1
- 230000008684 selective degradation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910009112 xH2O Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3182396P | 1996-11-26 | 1996-11-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW521075B true TW521075B (en) | 2003-02-21 |
Family
ID=21861602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086117657A TW521075B (en) | 1996-11-26 | 1997-11-25 | Process for the production of ruthenium (III) acetate solution |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US5886204A (https=) |
| EP (1) | EP0844251B1 (https=) |
| JP (1) | JP3999320B2 (https=) |
| KR (1) | KR100536791B1 (https=) |
| CN (1) | CN1279012C (https=) |
| AR (1) | AR010654A1 (https=) |
| BR (1) | BR9705903A (https=) |
| CA (1) | CA2222119C (https=) |
| DE (1) | DE69714384T2 (https=) |
| ID (1) | ID18998A (https=) |
| MY (1) | MY117386A (https=) |
| NO (1) | NO975429L (https=) |
| NZ (1) | NZ329244A (https=) |
| RU (1) | RU2184119C2 (https=) |
| SA (1) | SA98190044B1 (https=) |
| TW (1) | TW521075B (https=) |
| UA (1) | UA56134C2 (https=) |
| ZA (1) | ZA9710220B (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100406534B1 (ko) * | 2001-05-03 | 2003-11-20 | 주식회사 하이닉스반도체 | 루테늄 박막의 제조 방법 |
| JP5293930B2 (ja) * | 2007-03-22 | 2013-09-18 | Ｊｓｒ株式会社 | 化学気相成長材料及び化学気相成長方法 |
| DE102007014914B4 (de) * | 2007-03-26 | 2013-09-12 | Heraeus Precious Metals Gmbh & Co. Kg | Katalytisch hochwirksame Edelmetall-Carboxylat-Verbindungen von Ir, Ru, Rh, Pd, Pt und Au |
| KR101526633B1 (ko) * | 2008-03-17 | 2015-06-05 | 제이에스알 가부시끼가이샤 | 디루테늄 착체 및 화학 기상 성장의 재료 및 방법 |
| CN115141093A (zh) * | 2022-06-28 | 2022-10-04 | 浙江微通催化新材料有限公司 | 一种醋酸钌的制备方法 |
| CN115536520A (zh) * | 2022-11-02 | 2022-12-30 | 金川集团股份有限公司 | 一种醋酸钌的制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1405592A (en) * | 1971-08-11 | 1975-09-10 | Johnson Matthey Co Ltd | Compounds of ruthenium |
| JPS63315509A (ja) * | 1987-06-17 | 1988-12-23 | Hitachi Ltd | 蒸発缶の硝酸液処理システム |
| RU2033442C1 (ru) * | 1991-07-08 | 1995-04-20 | Институт неорганической химии СО РАН | Способ разделения металлов платиновой группы |
-
1997
- 1997-11-12 DE DE69714384T patent/DE69714384T2/de not_active Expired - Lifetime
- 1997-11-12 ZA ZA9710220A patent/ZA9710220B/xx unknown
- 1997-11-12 EP EP97309107A patent/EP0844251B1/en not_active Expired - Lifetime
- 1997-11-13 US US08/969,664 patent/US5886204A/en not_active Expired - Lifetime
- 1997-11-21 JP JP32179597A patent/JP3999320B2/ja not_active Expired - Lifetime
- 1997-11-24 KR KR1019970062382A patent/KR100536791B1/ko not_active Expired - Lifetime
- 1997-11-24 NZ NZ329244A patent/NZ329244A/xx unknown
- 1997-11-25 TW TW086117657A patent/TW521075B/zh active
- 1997-11-25 UA UA97115644A patent/UA56134C2/uk unknown
- 1997-11-25 CA CA002222119A patent/CA2222119C/en not_active Expired - Lifetime
- 1997-11-26 RU RU97120622/04A patent/RU2184119C2/ru active
- 1997-11-26 BR BR9705903A patent/BR9705903A/pt not_active Application Discontinuation
- 1997-11-26 ID IDP973767A patent/ID18998A/id unknown
- 1997-11-26 AR ARP970105554A patent/AR010654A1/es unknown
- 1997-11-26 NO NO975429A patent/NO975429L/no unknown
- 1997-11-26 CN CNB971257523A patent/CN1279012C/zh not_active Expired - Lifetime
- 1997-11-26 MY MYPI97005717A patent/MY117386A/en unknown
-
1998
- 1998-05-05 SA SA98190044A patent/SA98190044B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SA98190044B1 (ar) | 2006-05-13 |
| KR19980042700A (ko) | 1998-08-17 |
| KR100536791B1 (ko) | 2006-04-21 |
| JPH10168027A (ja) | 1998-06-23 |
| BR9705903A (pt) | 1999-05-18 |
| CN1279012C (zh) | 2006-10-11 |
| UA56134C2 (uk) | 2003-05-15 |
| MY117386A (en) | 2004-06-30 |
| ZA9710220B (en) | 1999-05-12 |
| NZ329244A (en) | 1999-02-25 |
| CA2222119C (en) | 2007-01-30 |
| EP0844251B1 (en) | 2002-07-31 |
| EP0844251A1 (en) | 1998-05-27 |
| CN1191858A (zh) | 1998-09-02 |
| US5886204A (en) | 1999-03-23 |
| AR010654A1 (es) | 2000-06-28 |
| MX9709135A (es) | 1998-09-30 |
| JP3999320B2 (ja) | 2007-10-31 |
| NO975429L (no) | 1998-05-27 |
| CA2222119A1 (en) | 1998-05-26 |
| RU2184119C2 (ru) | 2002-06-27 |
| NO975429D0 (no) | 1997-11-26 |
| ID18998A (id) | 1998-05-28 |
| DE69714384T2 (de) | 2002-11-14 |
| DE69714384D1 (de) | 2002-09-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GD4A | Issue of patent certificate for granted invention patent |