TW482742B - Nickel mixed hydroxide, process for the preparation thereof and the use thereof as cathode material in alkaline batteries - Google Patents
Nickel mixed hydroxide, process for the preparation thereof and the use thereof as cathode material in alkaline batteries Download PDFInfo
- Publication number
- TW482742B TW482742B TW088122374A TW88122374A TW482742B TW 482742 B TW482742 B TW 482742B TW 088122374 A TW088122374 A TW 088122374A TW 88122374 A TW88122374 A TW 88122374A TW 482742 B TW482742 B TW 482742B
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- water
- hydroxide
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 title claims abstract description 25
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 19
- 239000010406 cathode material Substances 0.000 title claims abstract description 5
- 238000000034 method Methods 0.000 title claims description 18
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 230000008569 process Effects 0.000 title description 3
- 150000004679 hydroxides Chemical class 0.000 claims abstract description 6
- 229910001868 water Inorganic materials 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 238000007254 oxidation reaction Methods 0.000 claims description 29
- 230000003647 oxidation Effects 0.000 claims description 28
- 239000000725 suspension Substances 0.000 claims description 20
- 238000011049 filling Methods 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 14
- 230000002079 cooperative effect Effects 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 10
- -1 H202 Chemical compound 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 7
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- 229910052702 rhenium Inorganic materials 0.000 claims description 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
- 241001674048 Phthiraptera Species 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims 2
- QXHPJWAXVTUDBA-UHFFFAOYSA-N 2-oxo-2-sulfanylacetic acid Chemical compound OC(=O)C(S)=O QXHPJWAXVTUDBA-UHFFFAOYSA-N 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- 238000002048 anodisation reaction Methods 0.000 claims 1
- 230000000875 corresponding effect Effects 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 125000005385 peroxodisulfate group Chemical group 0.000 claims 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- 229910001453 nickel ion Inorganic materials 0.000 abstract description 4
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000975 co-precipitation Methods 0.000 abstract description 2
- 239000000523 sample Substances 0.000 description 31
- 239000000463 material Substances 0.000 description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 25
- 239000000243 solution Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 17
- 239000000203 mixture Substances 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- 230000032683 aging Effects 0.000 description 9
- 150000001768 cations Chemical class 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 9
- 230000007935 neutral effect Effects 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 6
- 238000012856 packing Methods 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 238000007605 air drying Methods 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 239000013068 control sample Substances 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 229910052722 tritium Inorganic materials 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/32—Nickel oxide or hydroxide electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/30—Nickel accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19860143 | 1998-12-24 | ||
| DE19939025A DE19939025A1 (de) | 1998-12-24 | 1999-08-18 | Nickel-Mischydroxid, Verfahren zu dessen Herstellung und dessen Verwendung als Kathodenmaterial in alkalischen Batterien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW482742B true TW482742B (en) | 2002-04-11 |
Family
ID=26051046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW088122374A TW482742B (en) | 1998-12-24 | 1999-12-20 | Nickel mixed hydroxide, process for the preparation thereof and the use thereof as cathode material in alkaline batteries |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6849208B1 (enExample) |
| EP (1) | EP1145346B1 (enExample) |
| JP (1) | JP4590104B2 (enExample) |
| KR (1) | KR100665140B1 (enExample) |
| CN (1) | CN1192446C (enExample) |
| AU (1) | AU1979000A (enExample) |
| BR (1) | BR9916824A (enExample) |
| CA (1) | CA2356984C (enExample) |
| CZ (1) | CZ302880B6 (enExample) |
| DE (2) | DE19939025A1 (enExample) |
| TW (1) | TW482742B (enExample) |
| WO (1) | WO2000039865A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2198845C2 (ru) * | 2001-02-23 | 2003-02-20 | Открытое акционерное общество "Чепецкий механический завод" | Гидрат закиси никеля |
| CN100336265C (zh) * | 2005-06-17 | 2007-09-05 | 宜兴新兴锆业有限公司 | 高温镍氢电池 |
| US7985503B2 (en) * | 2005-06-27 | 2011-07-26 | Shenzhen Bak Battery Co., Ltd | Method for preparing spherical nickelous hydroxide which is dopped and multiple metal oxides, and lithium ion secondary battery |
| CN101267047B (zh) * | 2007-03-16 | 2010-10-06 | 深圳市力可兴电池有限公司 | 镍氢充电电池 |
| DE102007039471A1 (de) * | 2007-08-21 | 2009-02-26 | H.C. Starck Gmbh | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien |
| JP2009076430A (ja) * | 2007-08-28 | 2009-04-09 | Sanyo Electric Co Ltd | アルカリ蓄電池用負極及びアルカリ蓄電池 |
| DE102007049108A1 (de) * | 2007-10-12 | 2009-04-16 | H.C. Starck Gmbh | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien |
| WO2010120560A1 (en) * | 2009-03-31 | 2010-10-21 | Battelle Memorial Institute | Supercapacitor materials and devices |
| KR101296789B1 (ko) * | 2011-06-22 | 2013-08-14 | 한국전기연구원 | 아연계 음극 활물질의 제조방법 |
| CN102931396A (zh) * | 2012-11-05 | 2013-02-13 | 湖南丰日电源电气股份有限公司 | 一种高性能碱性电池正极材料及其制备方法 |
| CN103137962B (zh) * | 2013-03-11 | 2014-11-26 | 广东邦普循环科技有限公司 | 一种制备镍钴锰氢氧化物的方法 |
| CN106207106B (zh) * | 2016-07-12 | 2018-10-19 | 广东工业大学 | 一种α氢氧化镍的制备方法及其应用 |
| CN107512811B (zh) * | 2017-07-31 | 2020-06-23 | 四川思达能环保科技有限公司 | 球形氢氧化镍生产工艺过程废水的处理方法 |
| JP7109723B2 (ja) * | 2019-06-28 | 2022-08-01 | トヨタ自動車株式会社 | ニッケル水酸化物、正極材料、アルカリ電池、およびニッケル水酸化物の製造方法 |
| JP6916333B1 (ja) * | 2020-03-17 | 2021-08-11 | 日本碍子株式会社 | 電解質材料及び電気化学セル |
| JP6916334B1 (ja) * | 2020-03-17 | 2021-08-11 | 日本碍子株式会社 | 電気化学セル |
| JP6916332B1 (ja) * | 2020-03-17 | 2021-08-11 | 日本碍子株式会社 | 電気化学セル |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2645142B1 (fr) * | 1989-03-29 | 1991-07-12 | Centre Nat Etd Spatiales | Procede de preparation d'un hydroxyde de nickel substitue au cobalt de structure (alpha), stable en milieu alcalin et son utilisation dans un generateur electrochimique |
| US5518704A (en) * | 1993-07-06 | 1996-05-21 | Aristech Chemical Corporation | Nickel and cobalt containing hydrotalcite-like materials having a sheet-like morphology and process for production thereof |
| JP3397890B2 (ja) * | 1994-05-20 | 2003-04-21 | 三洋電機株式会社 | アルカリ蓄電池用非焼結式ニッケル極 |
| JP3443209B2 (ja) * | 1994-08-04 | 2003-09-02 | 三洋電機株式会社 | アルカリ蓄電池の非焼結式ニッケル極用活物質粉末及びその作製方法、並びに、アルカリ蓄電池用非焼結式ニッケル極及びその作製方法 |
| EP0696076B1 (en) * | 1994-08-04 | 1998-11-11 | Sanyo Electric Co., Ltd. | Active material powder for non-sintered nickel electrode, non-sintered nickel electrode for alkaline battery and process for producing the same |
| JP2802482B2 (ja) * | 1994-10-28 | 1998-09-24 | 古河電池株式会社 | アルカリ二次電池用ニッケル極 |
| DE4439989C2 (de) * | 1994-11-09 | 1997-06-19 | Starck H C Gmbh Co Kg | Mangan-haltige Nickel(II)-hydroxid-Pulver, Verfahren zu ihrer Herstellung sowie deren Verwendung |
| JPH09237630A (ja) | 1996-02-29 | 1997-09-09 | Matsushita Electric Ind Co Ltd | アルカリ蓄電池用活物質および正極 |
| JP3579545B2 (ja) | 1996-09-20 | 2004-10-20 | 株式会社田中化学研究所 | アルカリ蓄電池用水酸化ニッケル及びその製造法 |
| FR2760567B1 (fr) * | 1997-03-06 | 1999-04-16 | Alsthom Cge Alcatel | Matiere active positive pour electrode de nickel d'accumulateur a electrolyte alcalin |
| JPH10316431A (ja) * | 1997-05-14 | 1998-12-02 | Fuji Chem Ind Co Ltd | リチウムニッケル複合酸化物及びその製造方法並びにリチウム二次電池用正極活物質 |
-
1999
- 1999-08-18 DE DE19939025A patent/DE19939025A1/de not_active Withdrawn
- 1999-12-14 CZ CZ20012304A patent/CZ302880B6/cs not_active IP Right Cessation
- 1999-12-14 EP EP99963528A patent/EP1145346B1/de not_active Expired - Lifetime
- 1999-12-14 CN CNB998149780A patent/CN1192446C/zh not_active Expired - Fee Related
- 1999-12-14 DE DE59914227T patent/DE59914227D1/de not_active Expired - Lifetime
- 1999-12-14 US US09/868,995 patent/US6849208B1/en not_active Expired - Fee Related
- 1999-12-14 WO PCT/EP1999/009912 patent/WO2000039865A1/de not_active Ceased
- 1999-12-14 BR BR9916824-3A patent/BR9916824A/pt not_active Application Discontinuation
- 1999-12-14 AU AU19790/00A patent/AU1979000A/en not_active Abandoned
- 1999-12-14 KR KR1020017008099A patent/KR100665140B1/ko not_active Expired - Fee Related
- 1999-12-14 CA CA002356984A patent/CA2356984C/en not_active Expired - Fee Related
- 1999-12-14 JP JP2000591676A patent/JP4590104B2/ja not_active Expired - Fee Related
- 1999-12-20 TW TW088122374A patent/TW482742B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2356984A1 (en) | 2000-07-06 |
| WO2000039865A1 (de) | 2000-07-06 |
| JP4590104B2 (ja) | 2010-12-01 |
| DE19939025A1 (de) | 2000-06-29 |
| CN1331845A (zh) | 2002-01-16 |
| CZ302880B6 (cs) | 2012-01-04 |
| AU1979000A (en) | 2000-07-31 |
| CZ20012304A3 (cs) | 2001-11-14 |
| BR9916824A (pt) | 2001-10-16 |
| EP1145346B1 (de) | 2007-02-28 |
| JP2002533907A (ja) | 2002-10-08 |
| CA2356984C (en) | 2009-05-05 |
| EP1145346A1 (de) | 2001-10-17 |
| KR100665140B1 (ko) | 2007-01-09 |
| KR20010099941A (ko) | 2001-11-09 |
| CN1192446C (zh) | 2005-03-09 |
| US6849208B1 (en) | 2005-02-01 |
| DE59914227D1 (de) | 2007-04-12 |
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