TW309523B - - Google Patents
Download PDFInfo
- Publication number
- TW309523B TW309523B TW081107748A TW81107748A TW309523B TW 309523 B TW309523 B TW 309523B TW 081107748 A TW081107748 A TW 081107748A TW 81107748 A TW81107748 A TW 81107748A TW 309523 B TW309523 B TW 309523B
- Authority
- TW
- Taiwan
- Prior art keywords
- formula
- group
- alkyl
- compound
- same
- Prior art date
Links
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 29
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000001257 hydrogen Substances 0.000 claims abstract description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 150000001336 alkenes Chemical class 0.000 claims abstract description 10
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 9
- 230000018044 dehydration Effects 0.000 claims abstract description 6
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 6
- 125000003118 aryl group Chemical group 0.000 claims description 35
- -1 aluminum alkane Chemical class 0.000 claims description 34
- 239000007789 gas Substances 0.000 claims description 19
- 125000004429 atom Chemical group 0.000 claims description 17
- 125000005843 halogen group Chemical group 0.000 claims description 13
- 230000002079 cooperative effect Effects 0.000 claims description 12
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 7
- 125000001072 heteroaryl group Chemical group 0.000 claims description 7
- 239000003446 ligand Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 6
- 238000005727 Friedel-Crafts reaction Methods 0.000 claims description 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 125000000304 alkynyl group Chemical group 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 125000003106 haloaryl group Chemical group 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000008064 anhydrides Chemical class 0.000 claims description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000000269 nucleophilic effect Effects 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- 208000003251 Pruritus Diseases 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 claims 1
- 230000005180 public health Effects 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 4
- 239000000543 intermediate Substances 0.000 abstract description 3
- 229910052736 halogen Inorganic materials 0.000 abstract description 2
- 150000002367 halogens Chemical class 0.000 abstract description 2
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 abstract 1
- QNXSIUBBGPHDDE-UHFFFAOYSA-N indan-1-one Chemical class C1=CC=C2C(=O)CCC2=C1 QNXSIUBBGPHDDE-UHFFFAOYSA-N 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 120
- 239000000203 mixture Substances 0.000 description 76
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 37
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 27
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- 239000002904 solvent Substances 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 15
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 14
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 14
- 238000011978 dissolution method Methods 0.000 description 13
- 150000002576 ketones Chemical class 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 238000010992 reflux Methods 0.000 description 13
- 239000012074 organic phase Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000001819 mass spectrum Methods 0.000 description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 description 9
- 235000011152 sodium sulphate Nutrition 0.000 description 9
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 7
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 7
- 239000005457 ice water Substances 0.000 description 7
- 239000011261 inert gas Substances 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 101150041968 CDC13 gene Proteins 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 230000000875 corresponding effect Effects 0.000 description 6
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 6
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 238000004949 mass spectrometry Methods 0.000 description 6
- 239000000741 silica gel Substances 0.000 description 6
- 229910002027 silica gel Inorganic materials 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 5
- 239000012230 colorless oil Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000012279 sodium borohydride Substances 0.000 description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PCFLKKORMABVTC-UHFFFAOYSA-N CC1=C2C=C(C3=CC(=CC4=C3C2=C(C=C1)C=C4)C)C Chemical compound CC1=C2C=C(C3=CC(=CC4=C3C2=C(C=C1)C=C4)C)C PCFLKKORMABVTC-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 150000003254 radicals Chemical group 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXHKONLOYHBTNS-UHFFFAOYSA-N Diazomethane Chemical compound C=[N+]=[N-] YXHKONLOYHBTNS-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
- 229910000091 aluminium hydride Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 244000309464 bull Species 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 125000004399 C1-C4 alkenyl group Chemical group 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 238000005361 D2 NMR spectroscopy Methods 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- UFHGABBBZRPRJV-UHFFFAOYSA-N Hydroxysanguinarine Chemical compound C12=CC=C3OCOC3=C2C(=O)N(C)C(C2=C3)=C1C=CC2=CC1=C3OCO1 UFHGABBBZRPRJV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000004440 column chromatography Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 125000003963 dichloro group Chemical group Cl* 0.000 description 2
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- 150000005599 propionic acid derivatives Chemical class 0.000 description 2
- 150000003220 pyrenes Chemical group 0.000 description 2
- 229910052705 radium Inorganic materials 0.000 description 2
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- SDTXSEXYPROZSZ-UHFFFAOYSA-N 1,2-dibromo-2-methylpropane Chemical compound CC(C)(Br)CBr SDTXSEXYPROZSZ-UHFFFAOYSA-N 0.000 description 1
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- HLVFKOKELQSXIQ-UHFFFAOYSA-N 1-bromo-2-methylpropane Chemical compound CC(C)CBr HLVFKOKELQSXIQ-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- SDVZYNVSZLYGTL-UHFFFAOYSA-N 2-bromo-2-methylpropan-1-amine Chemical compound CC(C)(Br)CN SDVZYNVSZLYGTL-UHFFFAOYSA-N 0.000 description 1
- ZPSJGADGUYYRKE-UHFFFAOYSA-N 2H-pyran-2-one Chemical compound O=C1C=CC=CO1 ZPSJGADGUYYRKE-UHFFFAOYSA-N 0.000 description 1
- QSMSXBWWLZGOGQ-UHFFFAOYSA-N 4-bromo-4-methylpentanoyl bromide Chemical compound BrC(CCC(=O)Br)(C)C QSMSXBWWLZGOGQ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241000252073 Anguilliformes Species 0.000 description 1
- 229910014585 C2-Ce Inorganic materials 0.000 description 1
- YEUXQANUKKPZJU-UHFFFAOYSA-N CC(C)C1=CC2=C3C(=C1)C=CC4=C3C(=CC=C4)C=C2C(C)C Chemical compound CC(C)C1=CC2=C3C(=C1)C=CC4=C3C(=CC=C4)C=C2C(C)C YEUXQANUKKPZJU-UHFFFAOYSA-N 0.000 description 1
- KCBAMQOKOLXLOX-BSZYMOERSA-N CC1=C(SC=N1)C2=CC=C(C=C2)[C@H](C)NC(=O)[C@@H]3C[C@H](CN3C(=O)[C@H](C(C)(C)C)NC(=O)CCCCCCCCCCNCCCONC(=O)C4=C(C(=C(C=C4)F)F)NC5=C(C=C(C=C5)I)F)O Chemical compound CC1=C(SC=N1)C2=CC=C(C=C2)[C@H](C)NC(=O)[C@@H]3C[C@H](CN3C(=O)[C@H](C(C)(C)C)NC(=O)CCCCCCCCCCNCCCONC(=O)C4=C(C(=C(C=C4)F)F)NC5=C(C=C(C=C5)I)F)O KCBAMQOKOLXLOX-BSZYMOERSA-N 0.000 description 1
- IEEJPEUGSXSHDG-UHFFFAOYSA-N CC1=CC2=C3C(=C1)C(=CC4=C(C=CC(=C43)C=C2)C(C)C)C(C)C Chemical compound CC1=CC2=C3C(=C1)C(=CC4=C(C=CC(=C43)C=C2)C(C)C)C(C)C IEEJPEUGSXSHDG-UHFFFAOYSA-N 0.000 description 1
- 101100459438 Caenorhabditis elegans nac-1 gene Proteins 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical group N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 240000003537 Ficus benghalensis Species 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- CVRALZAYCYJELZ-UHFFFAOYSA-N O-(4-bromo-2,5-dichlorophenyl) O-methyl phenylphosphonothioate Chemical compound C=1C=CC=CC=1P(=S)(OC)OC1=CC(Cl)=C(Br)C=C1Cl CVRALZAYCYJELZ-UHFFFAOYSA-N 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- VOLMSPGWNYJHQQ-UHFFFAOYSA-N Pyranone Natural products CC1=C(O)C(=O)C(O)CO1 VOLMSPGWNYJHQQ-UHFFFAOYSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- CWRYPZZKDGJXCA-UHFFFAOYSA-N acenaphthalene Natural products C1=CC(CC2)=C3C2=CC=CC3=C1 CWRYPZZKDGJXCA-UHFFFAOYSA-N 0.000 description 1
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 description 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- XRWSZZJLZRKHHD-WVWIJVSJSA-N asunaprevir Chemical compound O=C([C@@H]1C[C@H](CN1C(=O)[C@@H](NC(=O)OC(C)(C)C)C(C)(C)C)OC1=NC=C(C2=CC=C(Cl)C=C21)OC)N[C@]1(C(=O)NS(=O)(=O)C2CC2)C[C@H]1C=C XRWSZZJLZRKHHD-WVWIJVSJSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- XBWRJSSJWDOUSJ-UHFFFAOYSA-L chromium(ii) chloride Chemical compound Cl[Cr]Cl XBWRJSSJWDOUSJ-UHFFFAOYSA-L 0.000 description 1
- GKIRPKYJQBWNGO-OCEACIFDSA-N clomifene Chemical compound C1=CC(OCCN(CC)CC)=CC=C1C(\C=1C=CC=CC=1)=C(\Cl)C1=CC=CC=C1 GKIRPKYJQBWNGO-OCEACIFDSA-N 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940125833 compound 23 Drugs 0.000 description 1
- 229940125961 compound 24 Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000005595 deprotonation Effects 0.000 description 1
- 238000010537 deprotonation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- GNEPOXWQWFSSOU-UHFFFAOYSA-N dichloro-methyl-phenylsilane Chemical compound C[Si](Cl)(Cl)C1=CC=CC=C1 GNEPOXWQWFSSOU-UHFFFAOYSA-N 0.000 description 1
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical class [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- KXUHSQYYJYAXGZ-UHFFFAOYSA-N isobutylbenzene Chemical compound CC(C)CC1=CC=CC=C1 KXUHSQYYJYAXGZ-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical compound N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical group 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 125000004309 pyranyl group Chemical group O1C(C=CC=C1)* 0.000 description 1
- 125000005581 pyrene group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 125000005630 sialyl group Chemical group 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
- C07C13/465—Indenes; Completely or partially hydrogenated indenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
- C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
- C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
- C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
- C07C49/67—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having two rings, e.g. tetralones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
- C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
- C07C49/675—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having three rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
- C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
- C07C2603/20—Acenaphthenes; Hydrogenated acenaphthenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4139594 | 1991-11-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW309523B true TW309523B (US07122603-20061017-C00183.png) | 1997-07-01 |
Family
ID=6446018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW081107748A TW309523B (US07122603-20061017-C00183.png) | 1991-11-30 | 1992-09-30 |
Country Status (12)
Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW294669B (US07122603-20061017-C00183.png) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| ATE177436T1 (de) * | 1992-08-15 | 1999-03-15 | Targor Gmbh | Verfahren zur herstellung von polyolefinen |
| ATE198893T1 (de) * | 1993-11-24 | 2001-02-15 | Targor Gmbh | Metallocene, verfahren zu ihrer herstellung und ihrer verwendung als katalysatoren |
| EP0668157B1 (de) | 1994-02-21 | 2003-05-21 | Basell Polyolefine GmbH | Siegelbare polyolefinische Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP3357186B2 (ja) | 1994-07-14 | 2002-12-16 | 三菱化学株式会社 | プロピレンブロック共重合体の製造法 |
| IT1273662B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
| EP0693502B1 (en) | 1994-07-22 | 1997-11-05 | Mitsubishi Chemical Corporation | Catalyst component for the polymerization of alpha-olefins and a process for preparing alpha-olefin polymers with use of same |
| IT1272924B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili |
| JP3946248B2 (ja) * | 1995-03-30 | 2007-07-18 | 出光興産株式会社 | 遷移金属化合物、オレフィン重合用触媒及びオレフィン系重合体の製造方法 |
| DE19517851A1 (de) * | 1995-05-16 | 1996-11-21 | Hoechst Ag | Organometallverbindung |
| US6787618B1 (en) | 1995-12-01 | 2004-09-07 | Basell Polypropylen Gmbh | Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms |
| US5679814A (en) * | 1995-12-11 | 1997-10-21 | Albemarle Corporation | Purification of metallocenes |
| DE19624828C1 (de) * | 1996-06-21 | 1998-03-26 | Basf Ag | Verfahren zur Herstellung substituierter Benzoindanone |
| CA2230365A1 (en) * | 1996-06-27 | 1997-12-31 | Albermarle Corporation | Production of bridged metallocene complexes and intermediates therefor |
| US5710299A (en) * | 1996-06-27 | 1998-01-20 | Albemarle Corporation | Production of bridged metallocene complexes and intermediates therefor |
| DE19634684C1 (de) * | 1996-08-28 | 1998-03-12 | Basf Ag | Verfahren zur Herstellung von Indenderivaten |
| US5760262A (en) * | 1996-09-17 | 1998-06-02 | Albemarle Corporation | Enhanced production of bridged hafnocenes |
| US5936108A (en) * | 1996-10-17 | 1999-08-10 | Albemarle Corporation | Metallocene synthesis |
| DE19729833A1 (de) * | 1997-07-11 | 1999-01-14 | Clariant Gmbh | Polypropylenwachs |
| DE19757540A1 (de) | 1997-12-23 | 1999-06-24 | Hoechst Ag | Geträgertes Katalysatorsystem zur Polymerisation von Olefinen |
| US6211300B1 (en) | 1998-04-10 | 2001-04-03 | Chisso Corporation | Propylene-ethylene block copolymer compositions and processes for production thereof |
| US6025512A (en) * | 1999-01-06 | 2000-02-15 | Univation Technologies, Llc | Pentafulvene synthesis |
| DE19962814A1 (de) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
| DE19962910A1 (de) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| US20040072975A1 (en) * | 2000-03-17 | 2004-04-15 | Jorg Schottek | Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins |
| US6846943B2 (en) | 2000-05-23 | 2005-01-25 | Chisso Corporation | Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst |
| US6635733B2 (en) * | 2000-05-23 | 2003-10-21 | Chisso Corporation | Elastomeric polypropylene |
| DE10025412A1 (de) | 2000-05-24 | 2001-11-29 | Basell Polypropylen Gmbh | Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| DE50105968D1 (de) * | 2000-08-29 | 2005-05-25 | Basell Polyolefine Gmbh | VERFAHREN ZUR HERSTELLUNG VON AlKYLVERBRÜCKTEN LIGANDSYSTEMEN UND ÜBERGANGSMETALLVERBINDUNGEN |
| DE60125408T2 (de) * | 2000-10-31 | 2007-09-27 | Akzo Nobel N.V. | Verfahren zur herstellung von 1-indanonen |
| US6548710B2 (en) | 2000-10-31 | 2003-04-15 | Akzo Nobel N.V. | Process for preparing 1-indanones |
| JP4687849B2 (ja) * | 2001-04-05 | 2011-05-25 | Ｊｘ日鉱日石エネルギー株式会社 | 高純度ジイソプロピルエーテルおよびその製法 |
| DE10126265A1 (de) | 2001-05-29 | 2002-12-05 | Basell Polyolefine Gmbh | Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte |
| US7060765B2 (en) | 2001-07-19 | 2006-06-13 | Univation Technologies, Llc | Low comonomer incorporating metallocene catalyst compounds |
| US6956088B2 (en) | 2001-07-19 | 2005-10-18 | Univation Technologies, Llc | Polyethylene films with improved physical properties |
| MXPA04000550A (es) | 2001-07-19 | 2005-02-17 | Univation Tech Llc | Sistemas catalizadores de metaloceno mixtos, conteniendo un incorporador de co-monomero pobre y un buen incorporador de co-monomero. |
| US6936675B2 (en) * | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| JP5268087B2 (ja) * | 2004-07-08 | 2013-08-21 | エクソンモービル・ケミカル・パテンツ・インク | 超臨界条件におけるポリマー製造 |
| US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
| DE602005013376D1 (de) * | 2005-08-09 | 2009-04-30 | Borealis Tech Oy | Siloxy substituierte Metallocenkatalysatoren |
| US7723448B2 (en) * | 2005-10-14 | 2010-05-25 | Basell Polyolefine Gmbh | Hybrid catalyst systems supported on magnesium halide |
| DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| JP2009530341A (ja) | 2006-03-17 | 2009-08-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物類 |
| EP2004664B1 (en) * | 2006-04-12 | 2016-12-14 | Basell Polyolefine GmbH | Metallocene compounds |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| WO2008077530A2 (en) * | 2006-12-22 | 2008-07-03 | Basell Polyolefine Gmbh | Multimodal polyethylene composition, mixed catalyst and process for preparing the composition |
| CN101652178B (zh) | 2007-03-06 | 2014-08-27 | 巴塞尔聚烯烃股份有限公司 | 铁络合物及其在聚合方法中的用途 |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| JP2010529253A (ja) * | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
| ATE554110T1 (de) * | 2007-07-27 | 2012-05-15 | Basell Polyolefine Gmbh | Katalysatorsystem zur polymerisierung von olefinischen monomeren, verfahren zur herstellung von polymeren und anhand dieses verfahrens hergestellte polymere |
| US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| ATE531776T1 (de) | 2008-02-18 | 2011-11-15 | Basell Polyolefine Gmbh | Poylmer-haftzusammensetzung |
| EP2303937B1 (en) | 2008-07-23 | 2012-08-29 | Basell Polyolefine GmbH | Method for transitioning between incompatible olefin polymerization catalyst systems |
| WO2010022941A1 (en) | 2008-08-29 | 2010-03-04 | Basell Polyolefine Gmbh | Polyethylene for injection moldings |
| RU2509782C2 (ru) | 2008-09-25 | 2014-03-20 | Базелль Полиолефине Гмбх | Ударопрочная композиция лпэнп и полученные из нее пленки |
| MX349957B (es) | 2008-09-25 | 2017-08-21 | Basell Polyolefine Gmbh | Composicion de polietileno lineal de baja dencidad (lldpe) resistente a impactos y peliculas hechas de la misma. |
| JP2012513506A (ja) | 2008-12-23 | 2012-06-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | 非適合性のオレフィン重合触媒系の間の移行を行う方法 |
| JP2011099091A (ja) | 2009-09-30 | 2011-05-19 | Sumitomo Chemical Co Ltd | エチレン系重合体の製造方法 |
| EP2513166B1 (en) | 2009-12-18 | 2017-04-05 | Basell Polyolefine GmbH | Process for the preparation of supported catalysts |
| EP2563957B1 (en) | 2010-04-30 | 2018-04-04 | Basell Polyolefine GmbH | Polymer filament or fiber |
| US9029478B2 (en) | 2011-02-07 | 2015-05-12 | Equistar Chemicals, Lp | High clarity polyethylene films |
| KR101212637B1 (ko) * | 2011-06-09 | 2012-12-14 | 에스케이종합화학 주식회사 | 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
| US9321945B2 (en) | 2011-09-30 | 2016-04-26 | Equistar Chemicals, Lp | Systems, methods and compositions for production of tie-layer adhesives |
| CN103772443A (zh) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | 一种桥联茂金属化合物及其制备方法 |
| EP2746320A1 (en) | 2012-12-20 | 2014-06-25 | Basell Polyolefine GmbH | Polyethylene composition having high mechanical properties |
| CN105593249B (zh) | 2013-10-14 | 2018-10-09 | 巴塞尔聚烯烃股份有限公司 | 耐热性提高的聚乙烯 |
| US20220389133A1 (en) | 2019-10-30 | 2022-12-08 | China Petroleum & Chemical Corporation | Metallocene compound, and preparation method therefor and application thereof |
| WO2021110769A1 (en) | 2019-12-03 | 2021-06-10 | Basell Polyolefine Gmbh | Polyethylene composition for filaments or fibers |
| US11999839B2 (en) | 2019-12-03 | 2024-06-04 | Basell Polyolefine Gmbh | Polyethylene composition for filaments or fibers |
| CN111333494B (zh) * | 2019-12-10 | 2023-07-11 | 武汉海昕药物研究有限公司 | 6-甲氧基-1-萘满酮的合成方法 |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT344153B (de) * | 1974-10-29 | 1978-07-10 | Hexachimie | Verfahren zur herstellung neuer 2-alkyl-5-indanessigsaeure- und -alkylester-derivate |
| ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US5324800A (en) * | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| US5654248A (en) * | 1986-08-26 | 1997-08-05 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefins and process for polymerization |
| US5700749A (en) * | 1986-09-24 | 1997-12-23 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
| IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| PL276385A1 (en) * | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| ATE133690T1 (de) * | 1987-04-03 | 1996-02-15 | Fina Technology | Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. |
| DE3726067A1 (de) * | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| US4931417A (en) * | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
| DE3742934A1 (de) * | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
| DE3808268A1 (de) * | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
| EP0355289A1 (en) * | 1988-07-01 | 1990-02-28 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Accelerometer |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| JP2835729B2 (ja) * | 1988-10-24 | 1998-12-14 | チッソ株式会社 | オレフィン重合体の製造方法 |
| EP0685496A1 (en) * | 1988-12-26 | 1995-12-06 | Mitsui Petrochemical Industries, Ltd. | Olefin copolymers and processes for preparing same |
| JPH02208213A (ja) * | 1989-02-07 | 1990-08-17 | Koa Oil Co Ltd | 圧縮弾性にすぐれた炭素質成形体の製造方法 |
| DE3922546A1 (de) * | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
| ATE137770T1 (de) * | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
| EP0426643B1 (en) * | 1989-10-30 | 1995-12-27 | Fina Research S.A. | Process for the preparation of metallocenes |
| ES2071086T5 (es) * | 1989-10-30 | 2002-01-16 | Fina Technology | Preparacion de catalizadores metalocenicos para polimerizacion de olefina. |
| DE69026679T3 (de) * | 1989-10-30 | 2005-10-06 | Fina Technology, Inc., Houston | Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators |
| DE3942364A1 (de) * | 1989-12-21 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung einer polypropylen-formmasse |
| JP2826362B2 (ja) * | 1990-02-13 | 1998-11-18 | 三井化学株式会社 | オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法 |
| DE59107926D1 (de) * | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| US5243001A (en) * | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
| EP0485823B1 (de) * | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
| DE59107973D1 (de) * | 1990-11-12 | 1996-08-08 | Hoechst Ag | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
| DE4104931A1 (de) * | 1991-02-18 | 1992-08-20 | Hoechst Ag | Verfahren zur herstellung substituierter indene |
| DE4119343A1 (de) * | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| DE4120006A1 (de) * | 1991-06-18 | 1992-12-24 | Basf Ag | Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen |
| DE4120009A1 (de) * | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| JP3402473B2 (ja) * | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
| TW300901B (US07122603-20061017-C00183.png) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| CA2084017C (en) * | 1991-11-30 | 2006-11-21 | Jurgen Rohrmann | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts |
| TW318184B (US07122603-20061017-C00183.png) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| DE59308494D1 (de) * | 1992-08-03 | 1998-06-10 | Targor Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| ATE177436T1 (de) * | 1992-08-15 | 1999-03-15 | Targor Gmbh | Verfahren zur herstellung von polyolefinen |
| JP3307704B2 (ja) * | 1993-02-19 | 2002-07-24 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| CA2125247C (en) * | 1993-06-07 | 2001-02-20 | Daisuke Fukuoka | Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer |
| DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| DE4436113A1 (de) * | 1994-10-10 | 1996-04-11 | Hoechst Ag | Metallocenverbindung |
-
1992
- 1992-09-30 TW TW081107748A patent/TW309523B/zh active
- 1992-11-27 CA CA002084016A patent/CA2084016C/en not_active Expired - Lifetime
- 1992-11-27 JP JP31910192A patent/JP3290218B2/ja not_active Expired - Fee Related
- 1992-11-27 ZA ZA929215A patent/ZA929215B/xx unknown
- 1992-11-27 AT AT92120289T patent/ATE219494T1/de not_active IP Right Cessation
- 1992-11-27 EP EP92120289A patent/EP0545304B1/de not_active Expired - Lifetime
- 1992-11-27 AU AU29727/92A patent/AU655088B2/en not_active Ceased
- 1992-11-27 ES ES92120289T patent/ES2177523T3/es not_active Expired - Lifetime
- 1992-11-27 DE DE59209962T patent/DE59209962D1/de not_active Expired - Lifetime
- 1992-11-28 KR KR1019920022688A patent/KR100322976B1/ko not_active IP Right Cessation
- 1992-11-30 RU RU92004483/04A patent/RU2103250C1/ru not_active IP Right Cessation
-
1995
- 1995-06-05 US US08/462,588 patent/US5852142A/en not_active Expired - Lifetime
- 1995-06-05 US US08/464,459 patent/US6051522A/en not_active Expired - Lifetime
- 1995-06-05 US US08/462,587 patent/US5840948A/en not_active Expired - Lifetime
-
1997
- 1997-07-10 US US08/890,942 patent/US5929264A/en not_active Expired - Lifetime
-
2001
- 2001-12-12 JP JP2001379159A patent/JP3434288B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2177523T3 (es) | 2002-12-16 |
| EP0545304B1 (de) | 2002-06-19 |
| RU2103250C1 (ru) | 1998-01-27 |
| JP3290218B2 (ja) | 2002-06-10 |
| CA2084016A1 (en) | 1993-05-31 |
| US5929264A (en) | 1999-07-27 |
| US5852142A (en) | 1998-12-22 |
| ZA929215B (en) | 1993-05-27 |
| CA2084016C (en) | 2004-06-22 |
| US6051522A (en) | 2000-04-18 |
| AU655088B2 (en) | 1994-12-01 |
| EP0545304A1 (de) | 1993-06-09 |
| JP2002226405A (ja) | 2002-08-14 |
| KR100322976B1 (ko) | 2002-05-01 |
| US5840948A (en) | 1998-11-24 |
| ATE219494T1 (de) | 2002-07-15 |
| JPH06206890A (ja) | 1994-07-26 |
| DE59209962D1 (de) | 2002-07-25 |
| JP3434288B2 (ja) | 2003-08-04 |
| KR930009968A (ko) | 1993-06-21 |
| AU2972792A (en) | 1993-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW309523B (US07122603-20061017-C00183.png) | ||
| JP5578473B2 (ja) | アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー | |
| JP2007505947A (ja) | 特定の置換パターンを有する有機遷移金属化合物、ビスシクロペンタジエニル配位子組成物、触媒組成物、及ポリオレフィンの製造法 | |
| Flores et al. | (N, N'-Dimethyl-p-toluamidinato) trichlorotitanium: Synthesis, Structure, and Polymerization Catalysis | |
| JP6033322B2 (ja) | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 | |
| Görl et al. | The combination of mononuclear metallocene and phenoxyimine complexes to give trinuclear catalysts for the polymerization of ethylene | |
| JP2001510846A (ja) | メタロセンの製造 | |
| EP0920403A1 (en) | Process for preparing cyclopentadienyl compounds | |
| JP5237966B2 (ja) | 有機アルカリ金属化合物および有機遷移金属化合物の製造方法 | |
| Ma et al. | Steric and electronic effects of the R in IndTiCl2 (OR) catalysts on the syndiospecific polymerization of styrene | |
| Foster et al. | Synthesis and polymerization behavior of tetrahydro-2-methylbenzindenyltitanium and zirconium compounds | |
| EP4206182A1 (en) | Ester compound | |
| JP6596027B2 (ja) | インデンの合成のための方法 | |
| US20060052620A1 (en) | Preparation of substituted indenes | |
| US7199274B2 (en) | Preparation of substituted indenes | |
| Abdelbagi et al. | Unbridged 1-and 2-substituted bis (silylindenyl) zirconium (IV) and hafnium (IV) dichloride complexes as catalyst precursors for ethylene polymerization | |
| Rimkus et al. | Di-and trinuclear zirconium complexes as catalysts for ethylene polymerization | |
| JPH04124191A (ja) | 有機ケイ素化合物 | |
| WO2021198509A1 (en) | Process for producing a biphenyl metallocene complex | |
| JPH1180264A (ja) | アレニルオキシメチルナフタレン、その製法およびそれより得られた重合体 | |
| KR20220114945A (ko) | 극성 비닐기를 가진 단량체의 부가중합용 촉매 및 이를 이용한 극성 비닐기를 가진 단량체의 중합체 제조방법 | |
| JP2022518564A (ja) | メタロセンを製造するためのプロセス | |
| KR100676302B1 (ko) | 안사-메탈로센 화합물의 제조방법 | |
| JPH01233253A (ja) | アリールオキシアレン化合物の製造法 | |
| El-Zoghbi | Synthesis of new zirconium complexes |