TW302502B - - Google Patents
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- TW302502B TW302502B TW085101777A TW85101777A TW302502B TW 302502 B TW302502 B TW 302502B TW 085101777 A TW085101777 A TW 085101777A TW 85101777 A TW85101777 A TW 85101777A TW 302502 B TW302502 B TW 302502B
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- etching
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- 238000000034 method Methods 0.000 claims abstract description 26
- 238000001020 plasma etching Methods 0.000 claims abstract description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 3
- 238000005530 etching Methods 0.000 claims description 23
- 239000013078 crystal Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 230000005284 excitation Effects 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 240000007817 Olea europaea Species 0.000 claims 1
- 238000007517 polishing process Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 6
- 238000000227 grinding Methods 0.000 abstract description 3
- 235000012431 wafers Nutrition 0.000 description 22
- 239000011888 foil Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 3
- 238000001039 wet etching Methods 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003631 wet chemical etching Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/308—Chemical or electrical treatment, e.g. electrolytic etching using masks
- H01L21/3083—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/3086—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/308—Chemical or electrical treatment, e.g. electrolytic etching using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/308—Chemical or electrical treatment, e.g. electrolytic etching using masks
- H01L21/3081—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their composition, e.g. multilayer masks, materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Drying Of Semiconductors (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Weting (AREA)
- ing And Chemical Polishing (AREA)
- Dicing (AREA)
Description
經濟部中央標準局負工消費合作社印裝 SQ2502 A7 B7五、發明説明(') 本發明僳閧於在晶圓形式之半導體基板上製造高密度 積體電路之方法,其中晶圓受琢磨而變薄,以便可以切成 各別之晶片,由於琢磨過程在晶圖背面所造成之損傷區 域可再利用一種於受保護之晶圓正面上進行且在切割之 前即已進行之蝕刻而加以消除。 具有半導體組件之矽晶圓製造過程結束之後,晶圓将受 琢磨而變薄以便可切割成各別之晶片。此種琢磨過程在 晶圓背面精煉的裂缝上覆上一受干擾而處在欠張力狀況 之矽表面。若此晶圓琢磨得很薄(例如,用於晶片卡時< 2 0 0 u m ),則其可隨後藉切割而斷開或切割後因此亦很容 易折斷。干擾和張力在這裡亦具有作用,它們是由切鋸 本身在切割邊緣上産生。 為了防止不受控制且提早之斷開,晶圓背面迄今為止 一般均在數微米之濕蝕刻中進行清除,故此張力可去除 由此所造成之損傷區域。晶圓正面一般則受到厚(大約 l〇〇um)箔層之保護,箔層在晶圓邊緣必須^全不透水,使 在塗上箔層之前不需要在晶圓上另外再塗漆,否則就必 須預先另外塗漆以便在濕蝕刻中防止邊綠晶片之損顔。 但這些方法有一些重大的缺點:在背面濕蝕刻之後,化 學藥劑必須再被沖洗且晶圓須以旋轉脱水之方式使其乾 燥,這在琢磨變薄後之晶圓上會導致晶圓斷裂,此外,由 於環境保護之原因,濕化學法應盡可能避免。為了去除 切割邊綠上之張力及干擾,直到現在仍無方法可行,此乃 因濕化學之矽蝕刻藥劑亦會損傷未受保護之鋁墊(pad)。 (請先閱讀背面之注意事項再填寫本頁) .丄 、-° 本紙張又度適用中國國家標準(CNS ) A4規格(210X297公釐) A7 B7 修正 補充 五、發明説明(> ) 本發明之目的為提供本文開頭所述技g之方法以改進 上述之缺點β 此目的將藉開頭所述技藝之方法而得以逹成,即,此種蝕 刻使用蝕刻氣體中之氟化物以進行微波電漿蝕刻或高頻 激發之下游《漿蝕刻法。 本發明之進一步構造敘述在申誚專利範園各附屬項中。 本發明随後將依據實施例及唯一的圔式作詳細說明。 /圈式簡單說明如下: ‘ \J 画1在連接方式和切面上潁示一種單一晶國之蝕刻設 備以進行本發明之方法。 侬據本發明之方法,其有利之處為:以現有之霣漿蝕刻 設備,例如,Tokuda CDE7,CDE8或 Gasonics IPC即可進行 蝕刻。此外,此種新方法較便宜且對琛境有利,在有關晶 國之機械負載方面,此種新方法具有較濕化學蝕刻更不 會損傷的處理方式。 此處重要之點可明顯的由該圖(撤波方式)得知:若晶 圓正面受到箔層保護,則晶國以其面朝下之傳統方式输 送且由上受到蝕刻。當然此蝕刻装蘆是有優點的,此受 琢磨而變薄之晶圖可在其上小心地作機械上之處理,例 如其情形可能為:當拄刻設備設計成引導設備且在引入 室中此完好之支架慢慢被抽出或受到通風時,另一支架 卻在工作。 為了在晶圓背面進行矽蝕刻,有各種不同之撤波或高 頻霣漿程序以供使用,這卽可利用化學劑c f4./o2完成,亦 可利用N F 3或S F6 / 02/ N2 ( 4 0 )完成直到現在為止,绾是必 1用中國國家標準(€泌)八4規格(210/297公茇) —.--------裝------訂------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央橾準局員工消費合 經濟部中央標準局員工消費合作社印製 SQ25Q2 A7 B7五、發明説明(々) 須由多値切割開始,使電漿蝕刻方法不會由於長的蝕刻 時間而顯現不經濟性。由於本發明之蝕刻最好是在受損 傷之位置進行或沿箸應力線進行,逭和濕蝕刻不同,因此 只需很短的蝕刻時間(依據琢磨方法和蝕刻化學劑之不 同,此時間在10秒和4分鐘之間相當於大約2Q0U1D之切割) 以便吸收由晶圓或切割邊綠來之應力,前者使自身經由 測量晶圖之彎曲而受控制,一種受控制之過度蝕刻(over-etching) 最後 可修補 張力在 其端點 産生之 撕裂, 這樣可 達到所需之斷裂強度。 在化學下游蝕刻中,其以已知方式利用電漿産生室之分 割和探針以引導晶圓不會受電場或離子影键,卽實際上 産生一種純粹之化學蝕刻,以此種方式則晶圖不需另外 之正面塗漆以保護邊綠組件。對蝕刻氣體而言,若基於 箔層之防護問題而可使用正面塗漆,則在上述之短暫蝕 刻時間中,在墊(pad)中之鋁根本就不會受損傷且由於高 的f擇性,厚的氣化物/氮化物保護層只€撤受損傷。基 於同樣理由,在未受保護之晶片表面的切割邊緣亦以上 述方法進行蝕刻而受損傷。 若完全不在正面塗上箔層,則此方法亦可找出使用方式 以保護正面,這描述在德國專利申請案號P4405667.2中, 該案號包含在所掲示之各案件中,其中正面保護基本上 是利用其上流動之中性氣體而産生,此種中性氣體可防 止蝕刻氣體之粒子向前推進。 -5 - ---------f .衣------訂------i I (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨0>< 297公釐)
Claims (1)
- 302502 AS B8 C8 D8 六、申請專利範圍 ι· 一種在晶國形式之半導醱基板上製造高密度積體電路 之方法,晶圖在基板上受琢磨而變薄,以便能切斷成各 別之晶κ,在晶圓背面上由於琢磨過程所造成之損傷 區域可再利用在受保護之晶圓正面上進行之切斷之前 即已進行的蝕刻來加以去除,其特擻為, 此種蝕刻埭用蝕刻氣體中之氟化物以進行橄波霣漿蝕刻或 高頻激發之下游電漿蝕刻法。 2. 如申請專利範圍第1項之方法,其中晶圓正面俗利用其 上流動之中性氣體而受到保護》 3. 如申請專利範圍第1或第2項之方法,其中進行蝕刻直 至晶圆之切割邊緣為止。 4. 如申請專利範圍第1或第2項之方法,其中遘取蝕刻時 間使其介於1 〇秒和4分鐘之間。 5. 如申請專利範園第3項之方法,其中選取蝕刻時間使其 介於1 0秒和4分鐘之間。 (請先閱讀背面之注意事項再填寫本頁) 丄 訂 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS〉Α4規格(210Χ2ς»7公釐)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19505906A DE19505906A1 (de) | 1995-02-21 | 1995-02-21 | Verfahren zum Damage-Ätzen der Rückseite einer Halbleiterscheibe bei geschützter Scheibenvorderseite |
Publications (1)
Publication Number | Publication Date |
---|---|
TW302502B true TW302502B (zh) | 1997-04-11 |
Family
ID=7754590
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW085101777A TW302502B (zh) | 1995-02-21 | 1996-02-13 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5693182A (zh) |
EP (1) | EP0729176B1 (zh) |
JP (1) | JPH08250456A (zh) |
KR (1) | KR100424421B1 (zh) |
AT (1) | ATE217119T1 (zh) |
DE (2) | DE19505906A1 (zh) |
TW (1) | TW302502B (zh) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19535082A1 (de) | 1995-09-21 | 1997-03-27 | Henkel Ecolab Gmbh & Co Ohg | Pastenförmiges Wasch- und Reinigungsmittel |
DE19752404C1 (de) * | 1997-11-26 | 1999-08-19 | Siemens Ag | Verfahren zum Herstellen eines Kontaktflächen aufweisenden Trägerelements, das ein Trägersubstrat mit einem Halbleiterchip mit sehr geringer Dicke bildet |
DE19823904A1 (de) * | 1998-05-28 | 1999-12-02 | Wacker Siltronic Halbleitermat | Hochebene Halbleiterscheibe aus Silicium und Verfahren zur Herstellung von Halbleiterscheiben |
US6335293B1 (en) | 1998-07-13 | 2002-01-01 | Mattson Technology, Inc. | Systems and methods for two-sided etch of a semiconductor substrate |
DE19919471A1 (de) * | 1999-04-29 | 2000-11-09 | Bosch Gmbh Robert | Verfahren zur Beseitigung von Defekten von Siliziumkörpern durch selektive Ätzung |
US6372151B1 (en) | 1999-07-27 | 2002-04-16 | Applied Materials, Inc. | Storage poly process without carbon contamination |
JP2001110755A (ja) * | 1999-10-04 | 2001-04-20 | Tokyo Seimitsu Co Ltd | 半導体チップ製造方法 |
JP3368876B2 (ja) | 1999-11-05 | 2003-01-20 | 株式会社東京精密 | 半導体チップ製造方法 |
JP2003521120A (ja) * | 2000-01-26 | 2003-07-08 | トル−シ・テクノロジーズ・インコーポレイテッド | ドライエッチングを用いた半導体ウェーハのシンニング及びダイシング、並びに半導体チップの底部のエッジ及び角を丸める方法 |
TW492100B (en) * | 2000-03-13 | 2002-06-21 | Disco Corp | Semiconductor wafer processing apparatus |
JP2003007682A (ja) * | 2001-06-25 | 2003-01-10 | Matsushita Electric Ind Co Ltd | プラズマ処理装置用の電極部材 |
US7074720B2 (en) * | 2001-06-25 | 2006-07-11 | Matsushita Electric Industrial Co., Ltd. | Plasma treating apparatus, plasma treating method and method of manufacturing semiconductor device |
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JP3789802B2 (ja) * | 2001-10-19 | 2006-06-28 | 富士通株式会社 | 半導体装置の製造方法 |
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US20030129102A1 (en) * | 2002-01-08 | 2003-07-10 | Turek Alan Gerard | Exhaust emissions control devices comprising adhesive |
US6743722B2 (en) | 2002-01-29 | 2004-06-01 | Strasbaugh | Method of spin etching wafers with an alkali solution |
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JP4398686B2 (ja) * | 2003-09-11 | 2010-01-13 | 株式会社ディスコ | ウエーハの加工方法 |
JP4590174B2 (ja) * | 2003-09-11 | 2010-12-01 | 株式会社ディスコ | ウエーハの加工方法 |
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JP4937674B2 (ja) * | 2006-08-16 | 2012-05-23 | 株式会社ディスコ | ウエーハのエッチング方法 |
US8144309B2 (en) * | 2007-09-05 | 2012-03-27 | Asml Netherlands B.V. | Imprint lithography |
US20090137097A1 (en) * | 2007-11-26 | 2009-05-28 | United Microelectronics Corp. | Method for dicing wafer |
JP5320619B2 (ja) | 2009-09-08 | 2013-10-23 | 三菱電機株式会社 | 半導体装置の製造方法 |
US8802545B2 (en) | 2011-03-14 | 2014-08-12 | Plasma-Therm Llc | Method and apparatus for plasma dicing a semi-conductor wafer |
CN115732321A (zh) * | 2022-11-30 | 2023-03-03 | 深圳泰研半导体装备有限公司 | 一种晶圆刻蚀清洗设备及方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6074626A (ja) * | 1983-09-30 | 1985-04-26 | Fujitsu Ltd | ウエハー処理方法及び装置 |
JPS61112345A (ja) * | 1984-11-07 | 1986-05-30 | Toshiba Corp | 半導体装置の製造方法 |
JP2656511B2 (ja) * | 1987-11-25 | 1997-09-24 | 株式会社日立製作所 | プラズマエッチング装置 |
JPH0330326A (ja) * | 1989-06-27 | 1991-02-08 | Mitsubishi Electric Corp | 半導体製造装置 |
US5075256A (en) * | 1989-08-25 | 1991-12-24 | Applied Materials, Inc. | Process for removing deposits from backside and end edge of semiconductor wafer while preventing removal of materials from front surface of wafer |
US4946547A (en) * | 1989-10-13 | 1990-08-07 | Cree Research, Inc. | Method of preparing silicon carbide surfaces for crystal growth |
KR0142874B1 (ko) * | 1989-12-18 | 1998-08-17 | 문정환 | 반도체 실리콘 웨이퍼의 뒷면 식각장치 |
JP3084497B2 (ja) * | 1992-03-25 | 2000-09-04 | 東京エレクトロン株式会社 | SiO2膜のエッチング方法 |
US5268065A (en) * | 1992-12-21 | 1993-12-07 | Motorola, Inc. | Method for thinning a semiconductor wafer |
DE19502777A1 (de) * | 1994-02-22 | 1995-08-24 | Siemens Ag | Verfahren zur plasmaunterstützten Rückseitenätzung einer Halbleiterscheibe bei belackungsfreier Scheibenvorderseite |
-
1995
- 1995-02-21 DE DE19505906A patent/DE19505906A1/de not_active Ceased
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1996
- 1996-02-06 AT AT96101674T patent/ATE217119T1/de not_active IP Right Cessation
- 1996-02-06 DE DE59609139T patent/DE59609139D1/de not_active Expired - Lifetime
- 1996-02-06 EP EP96101674A patent/EP0729176B1/de not_active Expired - Lifetime
- 1996-02-13 TW TW085101777A patent/TW302502B/zh active
- 1996-02-16 JP JP8054166A patent/JPH08250456A/ja not_active Ceased
- 1996-02-21 US US08/604,643 patent/US5693182A/en not_active Expired - Lifetime
- 1996-02-21 KR KR1019960004025A patent/KR100424421B1/ko not_active IP Right Cessation
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DE59609139D1 (de) | 2002-06-06 |
EP0729176A2 (de) | 1996-08-28 |
US5693182A (en) | 1997-12-02 |
ATE217119T1 (de) | 2002-05-15 |
KR960032631A (ko) | 1996-09-17 |
JPH08250456A (ja) | 1996-09-27 |
DE19505906A1 (de) | 1996-08-22 |
KR100424421B1 (ko) | 2004-06-05 |
EP0729176A3 (de) | 1997-11-12 |
EP0729176B1 (de) | 2002-05-02 |
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