TW200640954A - - Google Patents
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- Publication number
- TW200640954A TW200640954A TW95114296A TW95114296A TW200640954A TW 200640954 A TW200640954 A TW 200640954A TW 95114296 A TW95114296 A TW 95114296A TW 95114296 A TW95114296 A TW 95114296A TW 200640954 A TW200640954 A TW 200640954A
- Authority
- TW
- Taiwan
- Prior art keywords
- polymer structure
- absorbing polymer
- moisture absorbing
- weight
- value
- Prior art date
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- 229920000642 polymer Polymers 0.000 claims abstract description 211
- 238000000034 method Methods 0.000 claims abstract description 100
- 150000001875 compounds Chemical class 0.000 claims abstract description 68
- 150000001450 anions Chemical class 0.000 claims abstract description 35
- 239000002131 composite material Substances 0.000 claims abstract description 34
- 239000000758 substrate Substances 0.000 claims abstract description 26
- -1 formed bodies Substances 0.000 claims abstract description 25
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 9
- 239000006260 foam Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 229910001868 water Inorganic materials 0.000 claims description 44
- 238000004132 cross linking Methods 0.000 claims description 20
- 239000002250 absorbent Substances 0.000 claims description 17
- 230000002745 absorbent Effects 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 13
- 238000006386 neutralization reaction Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000003630 growth substance Substances 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 230000002538 fungal effect Effects 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000005022 packaging material Substances 0.000 claims description 3
- 239000003566 sealing material Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 239000004035 construction material Substances 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 239000000969 carrier Substances 0.000 claims 2
- 239000013543 active substance Substances 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 19
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 43
- 239000000178 monomer Substances 0.000 description 37
- 239000000243 solution Substances 0.000 description 31
- 239000012530 fluid Substances 0.000 description 26
- 239000000203 mixture Substances 0.000 description 26
- 239000003431 cross linking reagent Substances 0.000 description 24
- 239000000499 gel Substances 0.000 description 17
- 239000002253 acid Substances 0.000 description 16
- 238000006116 polymerization reaction Methods 0.000 description 16
- 238000002156 mixing Methods 0.000 description 15
- 150000002500 ions Chemical class 0.000 description 13
- 229920001223 polyethylene glycol Polymers 0.000 description 13
- 239000000017 hydrogel Substances 0.000 description 12
- 239000002202 Polyethylene glycol Substances 0.000 description 11
- 238000010998 test method Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 229920003169 water-soluble polymer Polymers 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 239000011859 microparticle Substances 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000010954 inorganic particle Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000010298 pulverizing process Methods 0.000 description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 150000001412 amines Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920006037 cross link polymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- KVIPHDKUOLVVQN-UHFFFAOYSA-N ethene;hydrate Chemical group O.C=C KVIPHDKUOLVVQN-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 230000002706 hydrostatic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002715 modification method Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920005594 polymer fiber Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000000611 regression analysis Methods 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- BGKZULDOBMANRY-UHFFFAOYSA-N sulfanyl prop-2-enoate Chemical compound SOC(=O)C=C BGKZULDOBMANRY-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- OTIXUSNHAKOJBX-UHFFFAOYSA-N 1-(aziridin-1-yl)ethanone Chemical compound CC(=O)N1CC1 OTIXUSNHAKOJBX-UHFFFAOYSA-N 0.000 description 1
- WJQZZLQMLJPKQH-UHFFFAOYSA-N 2,4-dichloro-6-methylphenol Chemical compound CC1=CC(Cl)=CC(Cl)=C1O WJQZZLQMLJPKQH-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- UHBKLFLAVYCZEP-UHFFFAOYSA-N 2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound OCCOCCOCCOCCOCCOCCOC(=O)C=C UHBKLFLAVYCZEP-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ASVKKRLMJCWVQF-UHFFFAOYSA-N 3-buten-1-amine Chemical compound NCCC=C ASVKKRLMJCWVQF-UHFFFAOYSA-N 0.000 description 1
- XBZOSMWIVFTITF-UHFFFAOYSA-N 3-methoxyindol-2-one Chemical compound COC=1C(N=C2C=CC=CC=12)=O XBZOSMWIVFTITF-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- UHIIHYFGCONAHB-UHFFFAOYSA-N 4,6-dimethyl-1,3-dioxan-2-one Chemical compound CC1CC(C)OC(=O)O1 UHIIHYFGCONAHB-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OVDQEUFSGODEBT-UHFFFAOYSA-N 4-methyl-1,3-dioxan-2-one Chemical compound CC1CCOC(=O)O1 OVDQEUFSGODEBT-UHFFFAOYSA-N 0.000 description 1
- JLLYLQLDYORLBB-UHFFFAOYSA-N 5-bromo-n-methylthiophene-2-sulfonamide Chemical compound CNS(=O)(=O)C1=CC=C(Br)S1 JLLYLQLDYORLBB-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- POOWCUWFCXSKBI-UHFFFAOYSA-N C(C=C)(=O)N(C)C1C=CC2=CC=CC=C12 Chemical compound C(C=C)(=O)N(C)C1C=CC2=CC=CC=C12 POOWCUWFCXSKBI-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229940126639 Compound 33 Drugs 0.000 description 1
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 102000016736 Cyclin Human genes 0.000 description 1
- 108050006400 Cyclin Proteins 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
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- 206010021639 Incontinence Diseases 0.000 description 1
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- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- WYGBHCSVNDTUKK-UHFFFAOYSA-N prop-1-ene Chemical group CC=C.CC=C.CC=C WYGBHCSVNDTUKK-UHFFFAOYSA-N 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
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- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- YFHICDDUDORKJB-UHFFFAOYSA-N trimethylene carbonate Chemical compound O=C1OCCCO1 YFHICDDUDORKJB-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005018922A DE102005018922A1 (de) | 2005-04-22 | 2005-04-22 | Mit Polykationen oberflächenbehandeltes wasserabsorbierendes Polymergebilde |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200640954A true TW200640954A (https=) | 2006-12-01 |
| TWI405776B TWI405776B (zh) | 2013-08-21 |
Family
ID=36972863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095114296A TWI405776B (zh) | 2005-04-22 | 2006-04-21 | 以聚陽離子表面處理之水份吸收聚合物結構 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20080280128A1 (https=) |
| EP (1) | EP1915182B1 (https=) |
| JP (1) | JP5275023B2 (https=) |
| CN (1) | CN101184514A (https=) |
| AT (1) | ATE435667T1 (https=) |
| BR (1) | BRPI0610043A2 (https=) |
| DE (2) | DE102005018922A1 (https=) |
| TW (1) | TWI405776B (https=) |
| WO (1) | WO2006111403A1 (https=) |
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| TWI529181B (zh) * | 2005-02-28 | 2016-04-11 | 贏創德固賽有限責任公司 | 以可更新原料為基之吸水聚合物結構及其生產的方法 |
| DE102005018924A1 (de) * | 2005-04-22 | 2006-10-26 | Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserten Absorptionseigenschaften |
| DE102005055497A1 (de) * | 2005-11-18 | 2007-05-31 | Stockhausen Gmbh | Geruchsbindende superabsorbierende Zusammensetzung |
| JP2009528412A (ja) * | 2006-02-28 | 2009-08-06 | エフォニック ストックハウゼン ゲーエムベーハー | 優れた吸収性及び保持性を有する生分解性超吸収性ポリマー組成物 |
| BRPI0711452B8 (pt) | 2006-04-21 | 2021-06-22 | Evonik Degussa Gmbh | processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, uso da estrutura polimérica absorvente de água ou uso do compósito e uso de um sal |
| EP2012843B1 (de) | 2006-04-21 | 2021-10-27 | Evonik Operations GmbH | Wasserabsorbierendes polymergebilde mit verbesserter permeabilität und absorption unter druck sowie verfahren zur herstellung |
| DE102006019157A1 (de) * | 2006-04-21 | 2007-10-25 | Stockhausen Gmbh | Herstellung von hochpermeablen, superabsorbierenden Polymergebilden |
| DE102006039205A1 (de) * | 2006-08-22 | 2008-03-20 | Stockhausen Gmbh | Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung |
| DE102007007203A1 (de) * | 2007-02-09 | 2008-08-14 | Evonik Stockhausen Gmbh | Wasserabsorbierendes Polymergebilde mit hoher Ammoniak-Bindekapazität |
| US7816426B2 (en) * | 2007-07-16 | 2010-10-19 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having color stability |
| US8846565B2 (en) * | 2007-07-27 | 2014-09-30 | Basf Se | Water-absorbing polymeric particles and method for the production thereof |
| DE102007045724B4 (de) * | 2007-09-24 | 2012-01-26 | Evonik Stockhausen Gmbh | Superabsorbierende Zusammensetzung mit Tanninen zur Geruchskontrolle, Verfahren zu deren Herstellung und Verwendung |
| DE102007053619A1 (de) * | 2007-11-08 | 2009-05-20 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserter Farbstabilität |
| TWI455973B (zh) * | 2008-03-05 | 2014-10-11 | Evonik Degussa Gmbh | 用於氣味控制的具有水楊酸鋅的超吸收性組合物 |
| US8647528B2 (en) * | 2008-03-07 | 2014-02-11 | Nippon Shokubai Co., Ltd. | Water absorbing agent and production method thereof |
| US20110034603A1 (en) * | 2008-04-25 | 2011-02-10 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt)-based water-absorbent resin and method for producing same |
| DE102008030712A1 (de) | 2008-06-27 | 2009-12-31 | Construction Research & Technology Gmbh | Zeitverzögerte superabsorbierende Polymere |
| CN102124039B (zh) | 2008-09-16 | 2013-04-24 | 株式会社日本触媒 | 吸水性树脂的制造方法和通液性提高方法 |
| EP2204431A1 (de) | 2008-12-18 | 2010-07-07 | Basf Se | Verfahren zur Blockierung unterirdischer Formationen |
| WO2010090324A1 (ja) | 2009-02-06 | 2010-08-12 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂およびその製造方法 |
| EP2471846B1 (en) | 2009-08-27 | 2016-12-21 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt) water absorbent resin and method for producing same |
| WO2011034146A1 (ja) | 2009-09-16 | 2011-03-24 | 株式会社日本触媒 | 吸水性樹脂粉末の製造方法 |
| JP5731390B2 (ja) | 2009-09-30 | 2015-06-10 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂およびその製造方法 |
| EP2527391B1 (en) | 2010-01-20 | 2023-08-09 | Nippon Shokubai Co., Ltd. | Method for producing water absorbent resin |
| EP2535369B1 (en) | 2010-02-10 | 2021-03-24 | Nippon Shokubai Co., Ltd. | Process for producing water-absorbing resin powder |
| JP5632906B2 (ja) | 2010-03-12 | 2014-11-26 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| WO2011115221A1 (ja) | 2010-03-17 | 2011-09-22 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| EP2371869A1 (en) | 2010-03-30 | 2011-10-05 | Evonik Stockhausen GmbH | A process for the production of a superabsorbent polymer |
| EP3115382B1 (en) | 2010-04-07 | 2019-07-10 | Nippon Shokubai Co., Ltd. | Method for producing water absorbent polyacrylic acid (salt) resin powder, and water absorbent polyacrylic acid (salt) resin powder |
| BR112012027406B1 (pt) | 2010-04-26 | 2021-02-09 | Nippon Shokubai Co., Ltd. | resina absorvedora de água tipo ácido poliacrílico (sal), material sanitário e método para produzir a referida resina |
| US20130043384A1 (en) | 2010-04-26 | 2013-02-21 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt), polyacrylic acid (salt)-based water-absorbing resin, and process for producing same |
| EP2565219B1 (en) | 2010-04-27 | 2018-06-27 | Nippon Shokubai Co., Ltd. | Method for producing polyacrylic acid (salt)-based water absorbent resin powder |
| EP2700667B1 (en) | 2011-04-20 | 2017-08-09 | Nippon Shokubai Co., Ltd. | Process and apparatus for producing water-absorbable resin of polyacrylic acid (salt) type |
| DE102011086516A1 (de) | 2011-11-17 | 2013-05-23 | Evonik Degussa Gmbh | Superabsorbierende Polymere mit schnellen Absorptionseigenschaften sowieVerfahren zu dessen Herstellung |
| BR112014013308A2 (pt) | 2011-12-30 | 2017-06-13 | Evonik Corp | polímero superabsorvente com reticulador |
| US8420567B1 (en) | 2011-12-30 | 2013-04-16 | Evonik Stockhausen, Llc | Process for superabsorbent polymer and crosslinker composition |
| KR102125105B1 (ko) | 2012-08-01 | 2020-06-19 | 가부시키가이샤 닛폰 쇼쿠바이 | 폴리아크릴산(염)계 흡수성 수지의 제조 방법 |
| JP6096199B2 (ja) | 2012-08-27 | 2017-03-15 | 株式会社日本触媒 | 粒子状吸水剤及びその製造方法 |
| EP2952537B1 (en) | 2013-01-29 | 2021-10-27 | Nippon Shokubai Co., Ltd. | Water-absorbable resin material and method for producing same |
| US9302248B2 (en) | 2013-04-10 | 2016-04-05 | Evonik Corporation | Particulate superabsorbent polymer composition having improved stability |
| CN107936189B (zh) | 2013-08-28 | 2021-06-01 | 株式会社日本触媒 | 聚丙烯酸(盐)系吸水性树脂粉末及其制品 |
| EP3040361B1 (en) | 2013-08-28 | 2019-06-19 | Nippon Shokubai Co., Ltd. | Gel grinding device, and method for producing a polyacrylic acid (polyacrylate) superabsorbent polymer powder |
| CN106132534B (zh) | 2014-03-31 | 2020-06-19 | 株式会社日本触媒 | 颗粒状吸水剂及其制造方法 |
| CN113301989B (zh) | 2019-01-11 | 2024-06-14 | 株式会社日本触媒 | 吸水剂和吸水剂的制造方法 |
| WO2023096283A1 (ko) * | 2021-11-24 | 2023-06-01 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
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-
2005
- 2005-04-22 DE DE102005018922A patent/DE102005018922A1/de not_active Withdrawn
-
2006
- 2006-04-21 WO PCT/EP2006/003695 patent/WO2006111403A1/de not_active Ceased
- 2006-04-21 BR BRPI0610043-0A patent/BRPI0610043A2/pt not_active IP Right Cessation
- 2006-04-21 EP EP06724499A patent/EP1915182B1/de not_active Expired - Lifetime
- 2006-04-21 AT AT06724499T patent/ATE435667T1/de active
- 2006-04-21 TW TW095114296A patent/TWI405776B/zh not_active IP Right Cessation
- 2006-04-21 JP JP2008507012A patent/JP5275023B2/ja not_active Expired - Fee Related
- 2006-04-21 US US11/912,241 patent/US20080280128A1/en not_active Abandoned
- 2006-04-21 CN CNA2006800187399A patent/CN101184514A/zh active Pending
- 2006-04-21 DE DE502006004195T patent/DE502006004195D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0610043A2 (pt) | 2010-05-25 |
| EP1915182A1 (de) | 2008-04-30 |
| DE502006004195D1 (de) | 2009-08-20 |
| JP5275023B2 (ja) | 2013-08-28 |
| WO2006111403A1 (de) | 2006-10-26 |
| US20080280128A1 (en) | 2008-11-13 |
| DE102005018922A1 (de) | 2006-10-26 |
| ATE435667T1 (de) | 2009-07-15 |
| TWI405776B (zh) | 2013-08-21 |
| EP1915182B1 (de) | 2009-07-08 |
| JP2008536988A (ja) | 2008-09-11 |
| CN101184514A (zh) | 2008-05-21 |
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