TR199900589T2 - 2 heteroatom ikameli siklopentadienil i�eren metal kompleksleri ve olefin polimerizasyonu i�in i�lem. - Google Patents

2 heteroatom ikameli siklopentadienil i�eren metal kompleksleri ve olefin polimerizasyonu i�in i�lem.

Info

Publication number
TR199900589T2
TR199900589T2 TR1999/00589T TR9900589T TR199900589T2 TR 199900589 T2 TR199900589 T2 TR 199900589T2 TR 1999/00589 T TR1999/00589 T TR 1999/00589T TR 9900589 T TR9900589 T TR 9900589T TR 199900589 T2 TR199900589 T2 TR 199900589T2
Authority
TR
Turkey
Prior art keywords
metal complexes
heteroatom
heteroatom substituted
substituted cyclopentadienyl
polymerization
Prior art date
Application number
TR1999/00589T
Other languages
English (en)
Turkish (tr)
Inventor
Klosin Jerzy
William J. Kruper, Jr.
N. Nickias Peter
T.Patton Jasson
R. Wilson David
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of TR199900589T2 publication Critical patent/TR199900589T2/xx

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
TR1999/00589T 1996-08-08 1997-07-28 2 heteroatom ikameli siklopentadienil i�eren metal kompleksleri ve olefin polimerizasyonu i�in i�lem. TR199900589T2 (xx)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08

Publications (1)

Publication Number Publication Date
TR199900589T2 true TR199900589T2 (xx) 1999-07-21

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
TR1999/00589T TR199900589T2 (xx) 1996-08-08 1997-07-28 2 heteroatom ikameli siklopentadienil i�eren metal kompleksleri ve olefin polimerizasyonu i�in i�lem.

Country Status (21)

Country Link
EP (1) EP1021454A1 (xx)
JP (1) JP2000516608A (xx)
KR (1) KR20000029853A (xx)
CN (1) CN1231668A (xx)
AR (1) AR009034A1 (xx)
AU (1) AU716659B2 (xx)
BR (1) BR9711115A (xx)
CA (1) CA2262377A1 (xx)
CO (1) CO4870709A1 (xx)
CZ (1) CZ42499A3 (xx)
HU (1) HUP9904148A3 (xx)
ID (1) ID18005A (xx)
NO (1) NO990546L (xx)
NZ (1) NZ333877A (xx)
PL (1) PL331526A1 (xx)
RU (1) RU2196776C2 (xx)
SA (1) SA97180735B1 (xx)
SK (1) SK15299A3 (xx)
TR (1) TR199900589T2 (xx)
WO (1) WO1998006728A1 (xx)
ZA (2) ZA976999B (xx)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI971565A (fi) * 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
DE19809159A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
EP1177198B1 (en) 1999-04-29 2002-11-20 Dow Global Technologies Inc. Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
US6555634B1 (en) 1999-05-13 2003-04-29 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
EP1178996B1 (en) 1999-05-13 2003-03-05 Dow Global Technologies Inc. Metal complexes containing bridging heteroatom for olefin-polymerization-process
US6420299B1 (en) 1999-06-04 2002-07-16 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
CN1495188A (zh) * 1999-12-10 2004-05-12 取代的第4族金属配合物,催化剂和烯烃聚合方法
DE60109680T2 (de) 2000-01-18 2006-02-02 Basell Polyolefine Gmbh Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
WO2001053362A1 (en) * 2000-01-19 2001-07-26 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
WO2003078483A1 (en) * 2002-03-14 2003-09-25 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
CN102471408A (zh) 2009-07-28 2012-05-23 尤尼威蒂恩技术有限责任公司 使用负载型受限几何构型催化剂的聚合方法
JP5579859B2 (ja) * 2010-09-15 2014-08-27 株式会社日本触媒 熱潜在性重合開始剤として用い得る組成物
CN102101897B (zh) * 2010-12-24 2013-02-06 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
WO2015142547A1 (en) 2014-03-21 2015-09-24 Exxonmobil Chemical Patents Inc. Process to produce ethylene propylene copolymers
JP6739435B2 (ja) 2015-01-06 2020-08-12 エスシージー ケミカルズ カンパニー,リミテッド SiO2−層状複水酸化物ミクロスフェアおよびその作製方法
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
WO2018175073A1 (en) * 2017-03-23 2018-09-27 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2020174346A1 (ko) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR20200105409A (ko) 2019-02-28 2020-09-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법

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Publication number Priority date Publication date Assignee Title
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
ATE198207T1 (de) * 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene
DE4406964A1 (de) * 1994-03-03 1995-09-07 Basf Ag Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem

Also Published As

Publication number Publication date
ZA976998B (en) 1999-02-08
SK15299A3 (en) 2000-03-13
JP2000516608A (ja) 2000-12-12
PL331526A1 (en) 1999-07-19
CO4870709A1 (es) 1999-12-27
WO1998006728A1 (en) 1998-02-19
NO990546D0 (no) 1999-02-05
NZ333877A (en) 2000-08-25
CA2262377A1 (en) 1998-02-19
SA97180735B1 (ar) 2006-10-08
AU3964797A (en) 1998-03-06
HUP9904148A3 (en) 2003-03-28
BR9711115A (pt) 1999-08-17
NO990546L (no) 1999-03-29
CZ42499A3 (cs) 1999-07-14
ID18005A (id) 1998-02-19
KR20000029853A (ko) 2000-05-25
HUP9904148A2 (hu) 2000-03-28
ZA976999B (en) 1999-02-08
CN1231668A (zh) 1999-10-13
EP1021454A1 (en) 2000-07-26
RU2196776C2 (ru) 2003-01-20
AU716659B2 (en) 2000-03-02
AR009034A1 (es) 2000-03-08

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