HUP9904148A2 - 2-es Helyzetben heteroatommal szubsztituált ciklopentadienilcsoportot tartalmazó fémkomplexek és eljárás olefinek polimerizálására - Google Patents

2-es Helyzetben heteroatommal szubsztituált ciklopentadienilcsoportot tartalmazó fémkomplexek és eljárás olefinek polimerizálására

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Publication number
HUP9904148A2
HUP9904148A2 HU9904148A HUP9904148A HUP9904148A2 HU P9904148 A2 HUP9904148 A2 HU P9904148A2 HU 9904148 A HU9904148 A HU 9904148A HU P9904148 A HUP9904148 A HU P9904148A HU P9904148 A2 HUP9904148 A2 HU P9904148A2
Authority
HU
Hungary
Prior art keywords
atoms
stone
complexes
atom
catalyst
Prior art date
Application number
HU9904148A
Other languages
English (en)
Inventor
Jerzy Klosin
William J. Kruper
Peter N. Nickias
Jasson T. Patton
David R. Wilson
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of HUP9904148A2 publication Critical patent/HUP9904148A2/hu
Publication of HUP9904148A3 publication Critical patent/HUP9904148A3/hu

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Abstract

A találmány 2-es helyzetben heterőatőmmal szűbsztitűáltciklőpentadienilcsőpőrtőt tartalmazó fémkőmplexekre ilyen kőmplexekelőállításáhőz felhasználható ligandűmőkra, valamint ilyen fémkőmp-lexeket tartalmazó pőlimerek előállítását célzó őlefinpőlimerizácóskatalizátőrőkra vőnatkőzik. A találmány szerinti fémkőmplexek (II)általánős képletében - M jelentése Ti, Zr vagy Hf, - j jelentése 1vagy 2, - T jelentése O, S, N vagy P, - az RA szűbsztitűensekjelentése - egymástól függetlenül - hidrőgénatőmtól eltérő 1-80 atőmőttartalmazó hidrőkarbilcsőpőrt, - RB, RW, RX, RY és RZ jelentése -egymástól függetlenül - hidrőgénatőm vagy hidrőgénatőmtól eltérő 1-80atőmőt tartalmazó hidrőkarbilcsőpőrt, - Z jelentése kétvegyértékűmőlekűlarész, amely bórt vagy az elemek periódűsős rendszerének 14.csőpőrtjába tartőzó elemet, tővábbá nitrőgénatőmőt, főszfőratőmőt,kénatőmőt vagy őxigénatőmőt főglal magában, - X jelentése legfeljebb60 atőmős, aniőnős vagy di-aniőnős ciklűsős ligandűmcsőpőrt, - az X'szűbsztitűensek jelentése - egymástól függetlenül - semleges Lewis-bázist megkötő, legfeljebb 20 atőmős vegyület, - p jelentése 0, 1 vagy2. A találmány szerinti őlefinpőlimerizációs katalizátőr-rendszerekfémkőmplexet tartalmazó katalizátőrkőmpőnensből és aktiválótárskatalizátőrt magában főglaló társkatalizátőr-kőmpőnensbőlkészülnek. ŕ
HU9904148A 1996-08-08 1997-07-28 2-heteroatom substituted cyclopentadienyl containing metal complexes and process for olefin polymerization HUP9904148A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08
PCT/US1997/013171 WO1998006728A1 (en) 1996-08-08 1997-07-28 2-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Publications (2)

Publication Number Publication Date
HUP9904148A2 true HUP9904148A2 (hu) 2000-03-28
HUP9904148A3 HUP9904148A3 (en) 2003-03-28

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9904148A HUP9904148A3 (en) 1996-08-08 1997-07-28 2-heteroatom substituted cyclopentadienyl containing metal complexes and process for olefin polymerization

Country Status (21)

Country Link
EP (1) EP1021454A1 (hu)
JP (1) JP2000516608A (hu)
KR (1) KR20000029853A (hu)
CN (1) CN1231668A (hu)
AR (1) AR009034A1 (hu)
AU (1) AU716659B2 (hu)
BR (1) BR9711115A (hu)
CA (1) CA2262377A1 (hu)
CO (1) CO4870709A1 (hu)
CZ (1) CZ42499A3 (hu)
HU (1) HUP9904148A3 (hu)
ID (1) ID18005A (hu)
NO (1) NO990546L (hu)
NZ (1) NZ333877A (hu)
PL (1) PL331526A1 (hu)
RU (1) RU2196776C2 (hu)
SA (1) SA97180735B1 (hu)
SK (1) SK15299A3 (hu)
TR (1) TR199900589T2 (hu)
WO (1) WO1998006728A1 (hu)
ZA (2) ZA976998B (hu)

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FI971565A (fi) * 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
DE19809159A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
DE60000831T2 (de) 1999-04-29 2003-08-28 Dow Global Technologies Inc Bis(n,n-dihydrocarbylamino)-substituierte cyclopentadiene und diese enthaltende metallkomplexe
AU3764600A (en) 1999-05-13 2000-12-05 Dow Chemical Company, The Di- and tri-heteroatom substituted indenyl metal complexes
WO2000069870A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
CA2368112A1 (en) 1999-06-04 2000-12-14 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
ES2379243T3 (es) * 1999-12-10 2012-04-24 Dow Global Technologies Llc Complejos de metal del grupo 4 sustituidos, catalizadores y procedimiento de polimerización de olefinas
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
DE60109680T2 (de) 2000-01-18 2006-02-02 Basell Polyolefine Gmbh Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
EP1248806A1 (en) * 2000-01-19 2002-10-16 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
WO2003078483A1 (en) * 2002-03-14 2003-09-25 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
WO2011017092A1 (en) 2009-07-28 2011-02-10 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
CN103249755A (zh) * 2010-09-15 2013-08-14 株式会社日本触媒 可作为热潜在性聚合引发剂使用的组合物
CN102101897B (zh) * 2010-12-24 2013-02-06 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
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KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
CN110612313A (zh) * 2017-03-23 2019-12-24 埃克森美孚化学专利公司 催化剂体系及其制备和使用方法
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR20200105409A (ko) 2019-02-28 2020-09-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2020174346A1 (ko) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법

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Also Published As

Publication number Publication date
EP1021454A1 (en) 2000-07-26
CN1231668A (zh) 1999-10-13
JP2000516608A (ja) 2000-12-12
CO4870709A1 (es) 1999-12-27
ID18005A (id) 1998-02-19
RU2196776C2 (ru) 2003-01-20
ZA976998B (en) 1999-02-08
KR20000029853A (ko) 2000-05-25
BR9711115A (pt) 1999-08-17
SK15299A3 (en) 2000-03-13
CA2262377A1 (en) 1998-02-19
AU3964797A (en) 1998-03-06
NO990546L (no) 1999-03-29
NO990546D0 (no) 1999-02-05
CZ42499A3 (cs) 1999-07-14
ZA976999B (en) 1999-02-08
NZ333877A (en) 2000-08-25
SA97180735B1 (ar) 2006-10-08
WO1998006728A1 (en) 1998-02-19
HUP9904148A3 (en) 2003-03-28
PL331526A1 (en) 1999-07-19
AU716659B2 (en) 2000-03-02
AR009034A1 (es) 2000-03-08
TR199900589T2 (xx) 1999-07-21

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