CO4870709A1 - Complejo de metal que contienen ciclopentadienilo sustituido por heteroatomo en la posicion 2, y proceso de polimeriza- cion de olefina - Google Patents

Complejo de metal que contienen ciclopentadienilo sustituido por heteroatomo en la posicion 2, y proceso de polimeriza- cion de olefina

Info

Publication number
CO4870709A1
CO4870709A1 CO97045592A CO97045592A CO4870709A1 CO 4870709 A1 CO4870709 A1 CO 4870709A1 CO 97045592 A CO97045592 A CO 97045592A CO 97045592 A CO97045592 A CO 97045592A CO 4870709 A1 CO4870709 A1 CO 4870709A1
Authority
CO
Colombia
Prior art keywords
hydrocarbyl
hydrocarbylamino
substituted
hydrocarbyloxy
group
Prior art date
Application number
CO97045592A
Other languages
English (en)
Inventor
Jerzy Klozin
William J Kruper Jr
Peter N Nickias
Jasson T Patton
David R Wilson
Original Assignee
Doe Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Doe Chemical Company filed Critical Doe Chemical Company
Publication of CO4870709A1 publication Critical patent/CO4870709A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Abstract

Un complejo de metal que corresponde a la fórmula:en donde M es un metal a partir de uno de los altos Grupos 3 a 13 de la Tabla Periódica de los Elementos, los lantaniuros o actiniuros, que está en el estado de oxidación formal +2, +3 o +4, y que está enlazado con p a un grupo ciclopentadienilo (CP), que es un grupo de ligado enlazado con p deslocalizado ciclo que tiene 5 sustituyentes: (RA )j -T, en donde j es cero, 1 ó 2; RB ; RC ; RD y Z; en donde RA , RB , RC y RD son grupos R; y en donde: T es un heteroátomo que se enlaza covalentemente al anillo de Cp, y a RA cuando j es 1 ó 2, y cuando j es O, T es F, Cl, Br ó I; cuando j es 1, T es O ó S, ó N ó P; y RA tiene un doble enlace con T; cuando j es 2, T es N ó P; y en donde: RA , independientemente en cada presentación, es hidrógeno, ó es un grupo que tiene de 1 a 80 átomos que no son de hidrógeno, que es hidrocarbilo, hidrocarbilsilio, hidrocarbilo sustituido por halógeno, hidrocarbilo sustituido por hidrocarbiloxi, hidrocarbilo sustituido por hidrocarbilamino, hidrocarbilsilihidrocarbilo, hidrocarbilamino, di(hidrocarbil)amino, hidrocarbiloxi, estando cada RA opcionalmente sustituido por uno o más grupos que, independientemente en cada presentación, son hidrocarbiloxi, hidrocarbilsiloxi, hidrocarbilsililamino, di(hidrocarbilsilil)amino, hidrocarbilamino, di(hidrocarbil)amino, di(hidrocarbil)fosfino, hidrocarbilsulfido, hidrocarbilo, hidrocarbilo sustituido por halógeno, hidrocarbilo sustituido por hidrocarbiloxi, hidrocarbilo sustituido por hidrocarbilamino, hidrocarbilsililo o hidrocarbilsililhidrocarbilo que tiene de 1 a 20 átomos que no son de hidrógeno, o un grupo que no interfiera que tenga de 1 a 20 átomos que no sean hidrógeno; y ...
CO97045592A 1996-08-08 1997-08-08 Complejo de metal que contienen ciclopentadienilo sustituido por heteroatomo en la posicion 2, y proceso de polimeriza- cion de olefina CO4870709A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08

Publications (1)

Publication Number Publication Date
CO4870709A1 true CO4870709A1 (es) 1999-12-27

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
CO97045592A CO4870709A1 (es) 1996-08-08 1997-08-08 Complejo de metal que contienen ciclopentadienilo sustituido por heteroatomo en la posicion 2, y proceso de polimeriza- cion de olefina

Country Status (21)

Country Link
EP (1) EP1021454A1 (es)
JP (1) JP2000516608A (es)
KR (1) KR20000029853A (es)
CN (1) CN1231668A (es)
AR (1) AR009034A1 (es)
AU (1) AU716659B2 (es)
BR (1) BR9711115A (es)
CA (1) CA2262377A1 (es)
CO (1) CO4870709A1 (es)
CZ (1) CZ42499A3 (es)
HU (1) HUP9904148A3 (es)
ID (1) ID18005A (es)
NO (1) NO990546L (es)
NZ (1) NZ333877A (es)
PL (1) PL331526A1 (es)
RU (1) RU2196776C2 (es)
SA (1) SA97180735B1 (es)
SK (1) SK15299A3 (es)
TR (1) TR199900589T2 (es)
WO (1) WO1998006728A1 (es)
ZA (2) ZA976998B (es)

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FI971565A (fi) * 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
DE19809159A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
DE60000831T2 (de) 1999-04-29 2003-08-28 Dow Global Technologies Inc Bis(n,n-dihydrocarbylamino)-substituierte cyclopentadiene und diese enthaltende metallkomplexe
AU3764600A (en) 1999-05-13 2000-12-05 Dow Chemical Company, The Di- and tri-heteroatom substituted indenyl metal complexes
WO2000069870A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
CA2368112A1 (en) 1999-06-04 2000-12-14 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
ES2379243T3 (es) * 1999-12-10 2012-04-24 Dow Global Technologies Llc Complejos de metal del grupo 4 sustituidos, catalizadores y procedimiento de polimerización de olefinas
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
DE60109680T2 (de) 2000-01-18 2006-02-02 Basell Polyolefine Gmbh Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
EP1248806A1 (en) * 2000-01-19 2002-10-16 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
WO2003078483A1 (en) * 2002-03-14 2003-09-25 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
WO2011017092A1 (en) 2009-07-28 2011-02-10 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
CN103249755A (zh) * 2010-09-15 2013-08-14 株式会社日本触媒 可作为热潜在性聚合引发剂使用的组合物
CN102101897B (zh) * 2010-12-24 2013-02-06 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
JP6355815B2 (ja) 2014-03-21 2018-07-11 エクソンモービル・ケミカル・パテンツ・インク エチレンプロピレンコポリマーを製造する方法
KR20170103887A (ko) 2015-01-06 2017-09-13 에스씨지 케미컬스 컴퍼니, 리미티드. SiO2-층상 이중 수산화물 마이크로스피어 및 이들의 제조 방법
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
CN110612313A (zh) * 2017-03-23 2019-12-24 埃克森美孚化学专利公司 催化剂体系及其制备和使用方法
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR20200105409A (ko) 2019-02-28 2020-09-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2020174346A1 (ko) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법

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Also Published As

Publication number Publication date
HUP9904148A2 (hu) 2000-03-28
EP1021454A1 (en) 2000-07-26
CN1231668A (zh) 1999-10-13
JP2000516608A (ja) 2000-12-12
ID18005A (id) 1998-02-19
RU2196776C2 (ru) 2003-01-20
ZA976998B (en) 1999-02-08
KR20000029853A (ko) 2000-05-25
BR9711115A (pt) 1999-08-17
SK15299A3 (en) 2000-03-13
CA2262377A1 (en) 1998-02-19
AU3964797A (en) 1998-03-06
NO990546L (no) 1999-03-29
NO990546D0 (no) 1999-02-05
CZ42499A3 (cs) 1999-07-14
ZA976999B (en) 1999-02-08
NZ333877A (en) 2000-08-25
SA97180735B1 (ar) 2006-10-08
WO1998006728A1 (en) 1998-02-19
HUP9904148A3 (en) 2003-03-28
PL331526A1 (en) 1999-07-19
AU716659B2 (en) 2000-03-02
AR009034A1 (es) 2000-03-08
TR199900589T2 (xx) 1999-07-21

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