ATE293132T1 - Nicht koordinierende anionen für die polymerisation von olefinen - Google Patents
Nicht koordinierende anionen für die polymerisation von olefinenInfo
- Publication number
- ATE293132T1 ATE293132T1 AT99908638T AT99908638T ATE293132T1 AT E293132 T1 ATE293132 T1 AT E293132T1 AT 99908638 T AT99908638 T AT 99908638T AT 99908638 T AT99908638 T AT 99908638T AT E293132 T1 ATE293132 T1 AT E293132T1
- Authority
- AT
- Austria
- Prior art keywords
- polymerization
- cyclopentadienyl ligand
- olefin
- ethylene
- substituted
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7684198P | 1998-03-04 | 1998-03-04 | |
US7671298P | 1998-03-04 | 1998-03-04 | |
US8744598P | 1998-06-01 | 1998-06-01 | |
US8744698P | 1998-06-01 | 1998-06-01 | |
US8744798P | 1998-06-01 | 1998-06-01 | |
PCT/US1999/004751 WO1999045042A1 (en) | 1998-03-04 | 1999-03-03 | Noncoordinating anions for olefin polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE293132T1 true ATE293132T1 (de) | 2005-04-15 |
Family
ID=27536103
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT99908638T ATE293132T1 (de) | 1998-03-04 | 1999-03-03 | Nicht koordinierende anionen für die polymerisation von olefinen |
Country Status (13)
Country | Link |
---|---|
US (4) | US6291609B1 (de) |
EP (3) | EP1060198B1 (de) |
JP (2) | JP2002505353A (de) |
KR (2) | KR20010041557A (de) |
CN (2) | CN1133660C (de) |
AT (1) | ATE293132T1 (de) |
AU (3) | AU2801899A (de) |
BR (2) | BR9907754A (de) |
CA (2) | CA2319067A1 (de) |
DE (3) | DE69925114T2 (de) |
EA (2) | EA200000902A1 (de) |
ES (3) | ES2237911T3 (de) |
WO (3) | WO1999045041A1 (de) |
Families Citing this family (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
US6177527B1 (en) * | 1998-09-08 | 2001-01-23 | Union Carbide Chemical & Plastics Technology Corporation | Process for the preparation of polyethylene or polypropylene |
CN1125834C (zh) * | 1998-10-23 | 2003-10-29 | 埃克森美孚化学专利公司 | 使用桥接二茂铪的烯烃共聚方法 |
US6486088B1 (en) | 1998-10-23 | 2002-11-26 | Exxonmobil Chemical Patents Inc. | High activity carbenium-activated polymerization catalysts |
US6300433B1 (en) * | 1998-10-23 | 2001-10-09 | Exxonmobil Chemical Patents Inc. | Olefin copolymerization process with bridged hafnocenes |
TW526209B (en) * | 1999-10-21 | 2003-04-01 | Asahi Chemical Ind | Method for producing an olefin homopolymer or an olefin copolymer |
DE60021405T2 (de) * | 1999-10-22 | 2006-05-18 | Univation Technologies, LLC, Houston | Katalysatorsysteme und deren verwendung in einem polymerisationsverfahren |
US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
US6489480B2 (en) | 1999-12-09 | 2002-12-03 | Exxonmobil Chemical Patents Inc. | Group-15 cationic compounds for olefin polymerization catalysts |
US6822057B2 (en) | 1999-12-09 | 2004-11-23 | Exxon Mobil Chemical Patents Inc. | Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them |
ATE395368T1 (de) * | 1999-12-20 | 2008-05-15 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren |
US6809209B2 (en) | 2000-04-07 | 2004-10-26 | Exxonmobil Chemical Patents Inc. | Nitrogen-containing group-13 anionic compounds for olefin polymerization |
AU2001277556A1 (en) * | 2000-08-09 | 2002-02-18 | Bayer Aktiengesellschaft | Catalyst system for the polymerisation of olefins |
DE10044981A1 (de) * | 2000-09-11 | 2002-03-21 | Bayer Ag | Katalysatorsystem zur Polymerisation von Dienen |
US7053153B2 (en) | 2000-12-04 | 2006-05-30 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions |
US20020107343A1 (en) * | 2001-02-08 | 2002-08-08 | Mitsui Chemicals, Inc. | Ethylene polymer, preparation process thereof and molded articles of the same |
JP5156167B2 (ja) * | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
AU2002315077A1 (en) | 2001-06-20 | 2003-01-08 | Exxonmobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
US7332551B2 (en) * | 2001-12-13 | 2008-02-19 | Exxonmobil Chemical Patents Inc. | Partially fluorinated naphthyl-based borates |
US8318993B2 (en) | 2002-03-05 | 2012-11-27 | Exxonmobil Research And Engineering Company | Lubricant blend composition |
US20030236177A1 (en) * | 2002-03-05 | 2003-12-25 | Wu Margaret May-Som | Novel lubricant blend composition |
US6756455B2 (en) * | 2002-05-31 | 2004-06-29 | Equistar Chemicals, Lp | High-temperature solution process for polyolefin manufacture |
US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
AU2003270780A1 (en) * | 2002-09-20 | 2004-04-08 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
EP1552520B1 (de) * | 2002-10-15 | 2012-02-29 | LG Electronics, Inc. | Aufzeichnungsmedium mit einer datenstruktur zur verwaltung der wiedergabe mehrerer darauf aufgezeichneter grafikströme und aufzeichnungs- und wiedergabeverfahren und vorrichtungen |
AU2003302033A1 (en) | 2002-10-15 | 2004-06-15 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
JP2004149673A (ja) | 2002-10-30 | 2004-05-27 | Mitsui Chemicals Inc | エチレン系ワックスの製造方法 |
US7091282B2 (en) * | 2003-05-15 | 2006-08-15 | Bridgestone Corporation | Composition containing ethylene/propylene/diene copolymer and polyalkylene/olefin copolymer |
US7456021B2 (en) * | 2004-01-16 | 2008-11-25 | Exxonmobil Chemical Patents Inc. | Analysis method |
US7217676B2 (en) * | 2004-01-16 | 2007-05-15 | Exxon Mobil Chemical Patents Inc. | Hydrophobization and silica for supported catalyst |
EP1727838B1 (de) * | 2004-03-24 | 2013-04-17 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von ethylen-mischpolymeren und danach hergestellte mischpolymere; zusammensetzungen und elektrische vorrichtungen, die derartige mischpolymere enthalten |
BRPI0513057A (pt) * | 2004-07-08 | 2008-04-22 | Exxonmobil Chem Patents Inc | produção de polìmero em condições supercrìticas |
GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
WO2007067307A1 (en) * | 2005-12-06 | 2007-06-14 | Exxonmobil Chemical Patents Inc. | Ethylene elastomer compositions |
EP1994065A1 (de) * | 2006-03-02 | 2008-11-26 | Exxonmobil Chemical Patents Inc. | Verfahren zur herstellung von propylencopolymeren |
EP2024403B1 (de) | 2006-05-17 | 2014-09-17 | Dow Global Technologies LLC | Verfahren zur polymerisierung einer polyolefinlösung und polymer |
US8143352B2 (en) * | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
US7943711B2 (en) * | 2007-05-14 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Ethylene elastomer compositions |
WO2008150572A1 (en) * | 2007-06-04 | 2008-12-11 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
EP2195349B1 (de) * | 2007-09-13 | 2012-07-11 | ExxonMobil Research and Engineering Company | In-line-verfahren zur herstellung von weichgemachten polymeren und weichgemachten polymerblends |
EP2201042B1 (de) * | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line-mischen von weichmachern mit einem basispolymer |
JP5623912B2 (ja) * | 2007-11-09 | 2014-11-12 | ユニバーシティー オブ メリーランド,カレッジ パーク | リビング配位連鎖移動重合によるポリオレフィンの調製プロセス |
US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
EP2231779B1 (de) * | 2007-12-20 | 2012-06-06 | ExxonMobil Research and Engineering Company | In-line-verfahren zur herstellung von pelletstabilen polyolefinen |
CN103254513B (zh) * | 2007-12-20 | 2015-08-26 | 埃克森美孚研究工程公司 | 全同立构聚丙烯和乙烯-丙烯共聚物的共混物 |
US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
EP2103634A1 (de) | 2008-03-20 | 2009-09-23 | ExxonMobil Chemical Patents Inc. | Herstellung propylen-basierter polymere |
US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
US8283428B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
US8283419B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
US8399725B2 (en) * | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
US8022154B2 (en) * | 2008-11-06 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Ethylene polymers, their production and use |
SG182318A1 (en) | 2010-01-14 | 2012-08-30 | Exxonmobil Chem Patents Inc | Processes and apparatus for continuous solution polymerization |
US8425847B2 (en) | 2010-01-14 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
SG182320A1 (en) | 2010-01-22 | 2012-08-30 | Exxonmobil Chem Patents Inc | Ethylene copolymers, methods for their production, and use |
JP5574916B2 (ja) * | 2010-10-26 | 2014-08-20 | 三井化学株式会社 | オレフィン重合体の製造方法 |
CA2819467C (en) * | 2010-12-03 | 2019-06-18 | Dow Global Technologies Llc | Processes to prepare ethylene-based polymer compositions |
BR112014026599A2 (pt) | 2012-04-26 | 2017-07-18 | Mitsui Chemicals Inc | processo para a produção de polímero de olefina |
US9952276B2 (en) | 2013-02-21 | 2018-04-24 | Advantest Corporation | Tester with mixed protocol engine in a FPGA block |
US10162007B2 (en) | 2013-02-21 | 2018-12-25 | Advantest Corporation | Test architecture having multiple FPGA based hardware accelerator blocks for testing multiple DUTs independently |
US11009550B2 (en) | 2013-02-21 | 2021-05-18 | Advantest Corporation | Test architecture with an FPGA based test board to simulate a DUT or end-point |
US10161993B2 (en) | 2013-02-21 | 2018-12-25 | Advantest Corporation | Tester with acceleration on memory and acceleration for automatic pattern generation within a FPGA block |
US9810729B2 (en) | 2013-02-28 | 2017-11-07 | Advantest Corporation | Tester with acceleration for packet building within a FPGA block |
US8916659B1 (en) | 2013-10-31 | 2014-12-23 | Exxonmobil Chemical Patents Inc. | Process and apparatus for continuous solution polymerization |
JP2015147862A (ja) * | 2014-02-06 | 2015-08-20 | 東ソー株式会社 | ポリエチレン系重合体製造用触媒及びそれを用いてなるポリエチレン系重合体の製造方法 |
EP2995631A1 (de) | 2014-09-12 | 2016-03-16 | Borealis AG | Verfahren zur Herstellung von Pfropfcopolymeren auf einem Polyolefinrückgrat |
US9630994B2 (en) * | 2014-11-03 | 2017-04-25 | University Of Washington | Polypeptides for use in self-assembling protein nanostructures |
CN107108777B (zh) | 2014-11-12 | 2021-02-05 | 埃克森美孚化学专利公司 | 增塑剂的纯化及其在聚合物生产方法和装置中的用途 |
CN104672358B (zh) * | 2015-01-22 | 2016-10-19 | 大连理工大学 | 一种催化极性乙烯基单体聚合的催化体系 |
WO2016204874A1 (en) | 2015-06-15 | 2016-12-22 | Exxonmobil Chemical Patents Inc. | Process for continuous solution polymerization |
US9926443B2 (en) | 2015-11-09 | 2018-03-27 | Exxonmobil Chemical Patents Inc. | Propylene-based elastomers for roofing compositions and methods for preparing the same |
WO2017082999A1 (en) | 2015-11-09 | 2017-05-18 | Exxonmobil Chemical Patents Inc. | Propylene-based elastomers for roofing compositions and methods for preparing the same |
US9487653B2 (en) | 2015-12-08 | 2016-11-08 | Exxonmobil Chemical Patents Inc. | Process of making crosslinked polyolefin polymer blends and compositions prepared thereof |
SG11201802756QA (en) | 2015-12-16 | 2018-06-28 | Exxonmobil Chemical Patents Inc | Low crystalline polymer compositions |
CA3018952C (en) | 2016-03-31 | 2023-06-27 | Exxonmobil Chemical Patents Inc. | Low crystalline polymer compositions prepared in a dual reactor |
WO2018022263A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Polymerization processes using high molecular weight polyhydric quenching agents |
WO2018160300A1 (en) | 2017-02-28 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized epdm |
US20190135960A1 (en) * | 2017-11-07 | 2019-05-09 | Nova Chemicals (International) S.A. | Process to manufacture ethylene interpolymer products |
US10995166B2 (en) * | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
KR101918484B1 (ko) * | 2017-11-15 | 2019-01-31 | 금호폴리켐 주식회사 | 탄성 공중합체 제조용 촉매 조성물 및 이를 이용한 에틸렌 및 알파-올레핀 또는 에틸렌, 알파-올레핀 및 비공액 디엔을 포함하는 탄성 공중합체의 제조 방법 |
US11466149B2 (en) | 2018-07-23 | 2022-10-11 | Exxonmobil Chemical Patents Inc. | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom |
CN112703210B (zh) | 2018-07-23 | 2022-10-28 | 埃克森美孚化学专利公司 | 制备双峰橡胶、热塑性硫化橡胶和由其制成的制品 |
SG11202102663QA (en) | 2018-09-19 | 2021-04-29 | Exxonmobil Chemical Patents Inc | Devolatilization processes |
US20200172715A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Chemical Patents Inc. | Blends of Cyclic Olefin Copolymers and Films Prepared Therefrom |
US10976361B2 (en) | 2018-12-20 | 2021-04-13 | Advantest Corporation | Automated test equipment (ATE) support framework for solid state device (SSD) odd sector sizes and protection modes |
WO2020167399A1 (en) | 2019-02-11 | 2020-08-20 | Exxonmobil Chemical Patents Inc. | Biphasic polymerization processes and ethylene-based polyolefins therefrom |
US11137910B2 (en) | 2019-03-04 | 2021-10-05 | Advantest Corporation | Fast address to sector number/offset translation to support odd sector size testing |
US11237202B2 (en) | 2019-03-12 | 2022-02-01 | Advantest Corporation | Non-standard sector size system support for SSD testing |
US10884847B1 (en) | 2019-08-20 | 2021-01-05 | Advantest Corporation | Fast parallel CRC determination to support SSD testing |
WO2021126443A2 (en) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Solution polymerization process for making high-density polyethylene long-chain branching |
WO2022005634A1 (en) | 2020-07-02 | 2022-01-06 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same |
US11186662B1 (en) * | 2020-07-14 | 2021-11-30 | Chevron Phillips Chemical Company Lp | Metallocene catalyst systems with chemically-treated solid oxides for producing ethylene-based plastomers and elastomers |
CN116209683A (zh) * | 2020-08-10 | 2023-06-02 | 埃克森美孚化学专利公司 | 向聚合反应器递送非芳族溶液的方法 |
WO2023097161A1 (en) | 2021-11-23 | 2023-06-01 | Exxonmobil Chemical Patents Inc. | Plants and processes for forming polymers |
KR20240005309A (ko) | 2022-07-05 | 2024-01-12 | 한화토탈에너지스 주식회사 | 신규한 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물 및 이를 이용한 에틸렌 및 α-올레핀의 공중합체의 제조방법 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
DE3751694T2 (de) | 1987-04-03 | 1996-08-01 | Fina Technology | Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke. |
US4931417A (en) | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
DE3907964A1 (de) | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
DE3916555A1 (de) | 1989-05-20 | 1990-11-22 | Hoechst Ag | Verfahren zur herstellung von ethylenpolymeren |
DE3922546A1 (de) | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
US5801113A (en) * | 1990-06-22 | 1998-09-01 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
JP3117231B2 (ja) | 1991-03-11 | 2000-12-11 | 三井化学株式会社 | 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法 |
US5571880A (en) | 1991-05-09 | 1996-11-05 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process |
EP0702030B1 (de) | 1991-05-27 | 2001-03-21 | TARGOR GmbH | Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung |
US5710224A (en) | 1991-07-23 | 1998-01-20 | Phillips Petroleum Company | Method for producing polymer of ethylene |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
KR100311244B1 (ko) | 1993-02-22 | 2001-12-15 | 가지와라 야스시 | 에틸렌/α-올레핀공중합체의제조방법 |
US6313240B1 (en) | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
DE4333128A1 (de) | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
KR100420432B1 (ko) | 1995-03-10 | 2004-07-23 | 다우 글로벌 테크놀로지스 인크. | 지지된촉매및이를이용한중합방법 |
US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
WO1997014698A1 (en) | 1995-10-18 | 1997-04-24 | The Dow Chemical Company | Synthesis of perfluoroaryl-substituted compounds |
PT863919E (pt) * | 1995-11-27 | 2001-04-30 | Grace W R & Co | Catalisador sobre suporte contendo um activador imobilizado que forma catioes |
WO1997022639A1 (en) | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
US5856256A (en) * | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
JPH1060034A (ja) | 1996-06-14 | 1998-03-03 | Mitsui Petrochem Ind Ltd | オレフィン重合用触媒およびオレフィンの重合方法 |
EP0906343B1 (de) | 1996-06-17 | 2001-04-18 | Exxon Chemical Patents Inc. | Olefinpolymerisationkatalysatorsysteme von gemischten übergangsmetalen |
ATE202365T1 (de) | 1996-08-13 | 2001-07-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
US5783512A (en) * | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
WO1999006412A1 (en) | 1997-08-01 | 1999-02-11 | The Dow Chemical Company | Perfluoronaphthyl substituted boron containing catalyst activator |
DE19808254A1 (de) | 1998-02-27 | 1999-09-02 | Aventis Res & Tech Gmbh & Co | Chemische Verbindung |
-
1999
- 1999-03-03 AU AU28018/99A patent/AU2801899A/en not_active Abandoned
- 1999-03-03 ES ES99908638T patent/ES2237911T3/es not_active Expired - Lifetime
- 1999-03-03 ES ES99909821T patent/ES2239439T3/es not_active Expired - Lifetime
- 1999-03-03 EP EP99908638A patent/EP1060198B1/de not_active Expired - Lifetime
- 1999-03-03 US US09/261,637 patent/US6291609B1/en not_active Expired - Lifetime
- 1999-03-03 DE DE69925114T patent/DE69925114T2/de not_active Expired - Lifetime
- 1999-03-03 WO PCT/US1999/004750 patent/WO1999045041A1/en active IP Right Grant
- 1999-03-03 CN CNB998035696A patent/CN1133660C/zh not_active Expired - Lifetime
- 1999-03-03 BR BR9907754-0A patent/BR9907754A/pt not_active IP Right Cessation
- 1999-03-03 CA CA002319067A patent/CA2319067A1/en not_active Abandoned
- 1999-03-03 KR KR1020007009741A patent/KR20010041557A/ko active IP Right Grant
- 1999-03-03 WO PCT/US1999/004751 patent/WO1999045042A1/en active IP Right Grant
- 1999-03-03 DE DE69924712T patent/DE69924712T2/de not_active Expired - Lifetime
- 1999-03-03 AT AT99908638T patent/ATE293132T1/de not_active IP Right Cessation
- 1999-03-03 US US09/261,627 patent/US6262202B1/en not_active Expired - Fee Related
- 1999-03-03 EP EP99909821A patent/EP1064311B1/de not_active Expired - Lifetime
- 1999-03-03 AU AU28942/99A patent/AU742900B2/en not_active Ceased
- 1999-03-03 EA EA200000902A patent/EA200000902A1/ru unknown
- 1999-03-03 JP JP2000534582A patent/JP2002505353A/ja not_active Withdrawn
- 1999-03-04 BR BR9907924-0A patent/BR9907924A/pt not_active IP Right Cessation
- 1999-03-04 EA EA200000901A patent/EA200000901A1/ru unknown
- 1999-03-04 DE DE69902362T patent/DE69902362T2/de not_active Expired - Lifetime
- 1999-03-04 WO PCT/US1999/004672 patent/WO1999045040A1/en active IP Right Grant
- 1999-03-04 AU AU30678/99A patent/AU741842B2/en not_active Ceased
- 1999-03-04 CN CN99803010A patent/CN1128823C/zh not_active Expired - Fee Related
- 1999-03-04 US US09/263,510 patent/US6218488B1/en not_active Expired - Lifetime
- 1999-03-04 KR KR1020007009738A patent/KR100554775B1/ko not_active IP Right Cessation
- 1999-03-04 CA CA002318246A patent/CA2318246A1/en not_active Abandoned
- 1999-03-04 ES ES99912265T patent/ES2181408T3/es not_active Expired - Lifetime
- 1999-03-04 EP EP99912265A patent/EP1062254B1/de not_active Expired - Lifetime
- 1999-03-04 JP JP2000534581A patent/JP2002505352A/ja not_active Withdrawn
-
2001
- 2001-07-10 US US09/902,125 patent/US6559253B2/en not_active Expired - Lifetime
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE293132T1 (de) | Nicht koordinierende anionen für die polymerisation von olefinen | |
ATE284421T1 (de) | Verbrückte hafnocenen für die copolymerisation von olefinen | |
BR0014119A (pt) | Catalisadores de polimerização ativados por carbênio de atividade elevada | |
CA2345628A1 (en) | Bridged metallocenes for olefin copolymerization | |
US5434115A (en) | Process for producing olefin polymer | |
RU2001113443A (ru) | Способ сополимеризации олефинов с применением гафноценов с мостиковыми связями | |
ATE247676T1 (de) | Stickstoff-enthaltende anionische komplexe der gruppe 13 für olefinpolymerisation | |
JP2002528463A5 (de) | ||
RU2001113445A (ru) | Связанные мостиками металлоцены для сополимеризации олефинов | |
RU2405791C2 (ru) | Способ получения ультравысокомолекулярных полимеров с использованием специальных мостиковых металлоценовых катализаторов | |
JPS61228003A (ja) | α−オレフインポリマ−およびその製法 | |
KR101646178B1 (ko) | 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법 | |
KR101645611B1 (ko) | 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법 | |
EP1392738B1 (de) | Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester | |
ATE327241T1 (de) | Für polymerisationskatalysatoren geeignete carbenium-kationische komplexe | |
JP3893674B2 (ja) | 重合用触媒 | |
JP3325719B2 (ja) | エチレン重合体の製造法 | |
US6531554B2 (en) | Metallocycle metallocenes and their use | |
KR102018535B1 (ko) | 올레핀 중합 촉매 및 이를 이용하여 중합된 올레핀계 중합체 | |
KR960029351A (ko) | 메탈로센 담지 촉매 및 그 제조방법 그리고 이를 이용한 이중 분자량 분포를 갖는 중합체의 제조방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |