SK284098B6 - Použitie polyesterovej disperzie na obaľovanie granúl hnojiva, granuly hnojiva, spôsob ich prípravy a ich použitie - Google Patents
Použitie polyesterovej disperzie na obaľovanie granúl hnojiva, granuly hnojiva, spôsob ich prípravy a ich použitie Download PDFInfo
- Publication number
- SK284098B6 SK284098B6 SK358-99A SK35899A SK284098B6 SK 284098 B6 SK284098 B6 SK 284098B6 SK 35899 A SK35899 A SK 35899A SK 284098 B6 SK284098 B6 SK 284098B6
- Authority
- SK
- Slovakia
- Prior art keywords
- mixture
- copolyester
- weight
- fertilizer granules
- acid
- Prior art date
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 74
- 239000006185 dispersion Substances 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 title abstract description 3
- 229920000229 biodegradable polyester Polymers 0.000 title 1
- 239000004622 biodegradable polyester Substances 0.000 title 1
- 229920001634 Copolyester Polymers 0.000 claims abstract description 64
- 229920000728 polyester Polymers 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 80
- 239000008187 granular material Substances 0.000 claims description 55
- 238000000576 coating method Methods 0.000 claims description 33
- 239000011248 coating agent Substances 0.000 claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 29
- -1 aromatic carboxylic acids Chemical class 0.000 claims description 25
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 17
- 125000001931 aliphatic group Chemical group 0.000 claims description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 12
- 239000004970 Chain extender Substances 0.000 claims description 11
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000002689 soil Substances 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 4
- 230000004720 fertilization Effects 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 14
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 13
- 230000003472 neutralizing effect Effects 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 11
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 9
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000001361 adipic acid Substances 0.000 description 8
- 235000011037 adipic acid Nutrition 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 7
- 235000015097 nutrients Nutrition 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 6
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
- 239000000155 melt Substances 0.000 description 6
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 5
- 150000001414 amino alcohols Chemical class 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 5
- 239000004310 lactic acid Substances 0.000 description 5
- 235000014655 lactic acid Nutrition 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 3
- 229920003232 aliphatic polyester Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229920002988 biodegradable polymer Polymers 0.000 description 2
- 239000004621 biodegradable polymer Substances 0.000 description 2
- 238000006065 biodegradation reaction Methods 0.000 description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 150000003217 pyrazoles Chemical class 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- CZAUMIGWDFREBR-UHFFFAOYSA-N (6-methyl-2-oxo-1,3-diazinan-4-yl)urea Chemical compound CC1CC(NC(N)=O)NC(=O)N1 CZAUMIGWDFREBR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- MWZJGRDWJVHRDV-UHFFFAOYSA-N 1,4-bis(ethenoxy)butane Chemical compound C=COCCCCOC=C MWZJGRDWJVHRDV-UHFFFAOYSA-N 0.000 description 1
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- RKDVKSZUMVYZHH-UHFFFAOYSA-N 1,4-dioxane-2,5-dione Chemical compound O=C1COC(=O)CO1 RKDVKSZUMVYZHH-UHFFFAOYSA-N 0.000 description 1
- JOSFJABFAXRZJQ-UHFFFAOYSA-N 1,6-bis(ethenoxy)hexane Chemical compound C=COCCCCCCOC=C JOSFJABFAXRZJQ-UHFFFAOYSA-N 0.000 description 1
- PVBLJPCMWKGTOH-UHFFFAOYSA-N 1-aminocyclohexan-1-ol Chemical compound NC1(O)CCCCC1 PVBLJPCMWKGTOH-UHFFFAOYSA-N 0.000 description 1
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- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
- GZZLQUBMUXEOBE-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,6-diol Chemical compound OCCC(C)CC(C)(C)CO GZZLQUBMUXEOBE-UHFFFAOYSA-N 0.000 description 1
- BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 description 1
- YRTNMMLRBJMGJJ-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diol;hexanedioic acid Chemical compound OCC(C)(C)CO.OC(=O)CCCCC(O)=O YRTNMMLRBJMGJJ-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- KKKKCPPTESQGQH-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-yl)-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=NCCO1 KKKKCPPTESQGQH-UHFFFAOYSA-N 0.000 description 1
- QEEZSWGDNCHFKC-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-ylmethyl)-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CC1=NCCO1 QEEZSWGDNCHFKC-UHFFFAOYSA-N 0.000 description 1
- WVXLLHWEQSZBLW-UHFFFAOYSA-N 2-(4-acetyl-2-methoxyphenoxy)acetic acid Chemical compound COC1=CC(C(C)=O)=CC=C1OCC(O)=O WVXLLHWEQSZBLW-UHFFFAOYSA-N 0.000 description 1
- KFNAHVKJFHDCSK-UHFFFAOYSA-N 2-[2-(4,5-dihydro-1,3-oxazol-2-yl)ethyl]-4,5-dihydro-1,3-oxazole Chemical compound N=1CCOC=1CCC1=NCCO1 KFNAHVKJFHDCSK-UHFFFAOYSA-N 0.000 description 1
- VOGDKZZTBPDRBD-UHFFFAOYSA-N 2-[2-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=CC=C1C1=NCCO1 VOGDKZZTBPDRBD-UHFFFAOYSA-N 0.000 description 1
- HMOZDINWBHMBSQ-UHFFFAOYSA-N 2-[3-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=CC(C=2OCCN=2)=C1 HMOZDINWBHMBSQ-UHFFFAOYSA-N 0.000 description 1
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- LQGKDMHENBFVRC-UHFFFAOYSA-N 5-aminopentan-1-ol Chemical compound NCCCCCO LQGKDMHENBFVRC-UHFFFAOYSA-N 0.000 description 1
- SUTWPJHCRAITLU-UHFFFAOYSA-N 6-aminohexan-1-ol Chemical compound NCCCCCCO SUTWPJHCRAITLU-UHFFFAOYSA-N 0.000 description 1
- HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 description 1
- IWHLYPDWHHPVAA-UHFFFAOYSA-N 6-hydroxyhexanoic acid Chemical compound OCCCCCC(O)=O IWHLYPDWHHPVAA-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 101100285389 Arabidopsis thaliana HLS1 gene Proteins 0.000 description 1
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- 244000005700 microbiome Species 0.000 description 1
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
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- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/37—Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19640269A DE19640269A1 (de) | 1996-09-30 | 1996-09-30 | Verwendung einer wäßrigen Dispersion eines biologisch abbaubaren Polyesters zur Umhüllung von Düngemittelgranulaten |
| PCT/EP1997/005352 WO1998014413A1 (de) | 1996-09-30 | 1997-09-29 | Verwendung einer wässrigen dispersion eines biologisch abbaubaren polyesters zur umhüllung von düngemittelgranulaten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SK35899A3 SK35899A3 (en) | 2000-03-13 |
| SK284098B6 true SK284098B6 (sk) | 2004-09-08 |
Family
ID=7807420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK358-99A SK284098B6 (sk) | 1996-09-30 | 1997-09-29 | Použitie polyesterovej disperzie na obaľovanie granúl hnojiva, granuly hnojiva, spôsob ich prípravy a ich použitie |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6413292B1 (enExample) |
| EP (1) | EP0931036B1 (enExample) |
| JP (1) | JP2001507326A (enExample) |
| KR (1) | KR20000048714A (enExample) |
| CN (1) | CN1113048C (enExample) |
| AT (1) | ATE193004T1 (enExample) |
| AU (1) | AU737144B2 (enExample) |
| CA (1) | CA2267349A1 (enExample) |
| CZ (1) | CZ296874B6 (enExample) |
| DE (2) | DE19640269A1 (enExample) |
| ES (1) | ES2148943T3 (enExample) |
| GR (1) | GR3033576T3 (enExample) |
| MY (1) | MY126366A (enExample) |
| NZ (1) | NZ334783A (enExample) |
| PL (1) | PL188969B1 (enExample) |
| PT (1) | PT931036E (enExample) |
| SK (1) | SK284098B6 (enExample) |
| TW (1) | TW450949B (enExample) |
| UA (1) | UA49925C2 (enExample) |
| WO (1) | WO1998014413A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE254846T1 (de) | 1998-08-05 | 2003-12-15 | Basf Ag | Bodengranulate mit kontrollierter wirkstofffreisetzung (cr-bodengranulate) |
| US6217630B1 (en) * | 1999-05-03 | 2001-04-17 | Cargill, Incorporated | Conditioned fertilizer product, method for conditioning fertilizer, and method for using conditioned fertilizer product |
| US6582637B1 (en) * | 1999-05-05 | 2003-06-24 | Agronomic Growth Industries Ltd. | Compost granulation method |
| JP2002105295A (ja) * | 2000-10-02 | 2002-04-10 | Teijin Chem Ltd | 熱可塑性樹脂組成物 |
| DE10221704A1 (de) | 2001-06-05 | 2003-01-23 | Compo Gmbh & Co Kg | Düngemittel mit verzögerter Freisetzung und Verfahren zu dessen Herstellung |
| DE10336387A1 (de) * | 2003-08-06 | 2005-03-03 | Basf Ag | Biologisch abbaubare Polyestermischung |
| DE102004013537A1 (de) * | 2004-03-19 | 2005-10-06 | Compo Gmbh & Co. Kg | Düngemittel mit biologisch abbaubarer Hülle |
| ES2336491T3 (es) * | 2005-12-22 | 2010-04-13 | Basf Se | Formulaciones para el tratamiento desinfectante de semillas a base de un poliester biodegradable parcialmente aromatico. |
| CN100351214C (zh) * | 2006-02-22 | 2007-11-28 | 华南农业大学 | 一种利用潲水油为膜材原料制备的包膜肥料 |
| US7785553B2 (en) * | 2007-03-14 | 2010-08-31 | University Of Kentucky Research Foundation | Reducing explosive potential of ammonium nitrate |
| DK2150600T3 (en) * | 2007-04-25 | 2018-07-16 | Compass Minerals Manitoba Inc | APPLICATION OF SURGIFICANT TO PROMOTE THE INTAKE OF MICRO-NUTRIENTS |
| US8192520B2 (en) * | 2009-10-05 | 2012-06-05 | Specialty Fertilizer Products, Llc | Enhanced fertilizer products with polymer adjuvants |
| US7686863B1 (en) | 2009-10-05 | 2010-03-30 | Specialty Fertilizer Products, Llc | Gypsum fertilizer products with polymer adjuvants |
| CN102718598B (zh) * | 2012-07-03 | 2015-01-14 | 常州大学 | 一种肥料用缓释型可生物降解防结块的包膜材料及其应用 |
| US9145340B2 (en) | 2012-08-13 | 2015-09-29 | Verdesian Life Sciences, Llc | Method of reducing atmospheric ammonia in livestock and poultry containment facilities |
| US9961922B2 (en) | 2012-10-15 | 2018-05-08 | Verdesian Life Sciences, Llc | Animal feed and/or water amendments for lowering ammonia concentrations in animal excrement |
| US11254620B2 (en) | 2013-08-05 | 2022-02-22 | Verdesian Life Sciences U.S., Llc | Micronutrient-enhanced polymeric seed coatings |
| TW201522390A (zh) | 2013-08-27 | 2015-06-16 | 特級肥料產品公司 | 聚陰離子聚合物 |
| WO2015035031A1 (en) | 2013-09-05 | 2015-03-12 | Verdesian Life Sciences, Llc | Polymer-boric acid compositions |
| WO2015179687A1 (en) | 2014-05-21 | 2015-11-26 | Verdesian Life Sciences, Llc | Polymer soil treatment compositions including humic acids |
| CA2946202C (en) | 2014-05-22 | 2022-06-21 | Verdesian Life Sciences, Llc | Polymeric compositions |
| US20160185682A1 (en) * | 2014-12-31 | 2016-06-30 | Dow Agrosciences Llc | Nitrification inhibitor compositions and methods for preparing the same |
| CN104926497A (zh) * | 2015-06-15 | 2015-09-23 | 安徽释乐补控释肥有限公司 | 一种含对苯聚酯多元醇的缓释肥包衣材料及其制备工艺 |
| ES2906324T3 (es) | 2016-02-29 | 2022-04-18 | Michelman Inc | Dispersión hidrolíticamente estable de base acuosa de un polímero biodegradable |
| IL247302B (en) | 2016-08-16 | 2019-03-31 | Technion Res & Dev Foundation | Systems for releasing materials based on polymer emulsions |
| EP3479693A1 (en) | 2017-11-01 | 2019-05-08 | Everris International B.V. | Sulfide containing polyester coatings for agrochemical composition |
| CN109988049A (zh) * | 2019-05-15 | 2019-07-09 | 华南农业大学 | 一种改土促根型悬浮肥及其制备方法 |
| JP7029210B1 (ja) | 2021-10-19 | 2022-03-03 | 株式会社Tbm | 肥料粒子 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5688454A (en) * | 1979-12-21 | 1981-07-17 | Toyobo Co Ltd | Aqueous dispersion |
| JPH0635363B2 (ja) * | 1985-09-10 | 1994-05-11 | 日本合成化学工業株式会社 | 被覆農薬 |
| JP3088108B2 (ja) * | 1990-02-09 | 2000-09-18 | 高松油脂株式会社 | ポリエステル樹脂水分散液 |
| JPH0597561A (ja) | 1991-04-22 | 1993-04-20 | Nippon Steel Corp | 遅効型肥料 |
| US5211985A (en) * | 1991-10-09 | 1993-05-18 | Ici Canada, Inc. | Multi-stage process for continuous coating of fertilizer particles |
| JP3291077B2 (ja) | 1993-07-21 | 2002-06-10 | 旭化成株式会社 | 分解速度の異なる被膜材よりなる多層被覆粒状肥料 |
| JPH0733577A (ja) | 1993-07-21 | 1995-02-03 | Asahi Chem Ind Co Ltd | ポリ−ｌ−乳酸膜よりなる被覆粒状肥料 |
| JPH07309689A (ja) * | 1994-05-12 | 1995-11-28 | Dainippon Ink & Chem Inc | 緩効性肥料及びその製造方法 |
| JPH07315976A (ja) | 1994-05-26 | 1995-12-05 | Chisso Corp | 分解性被膜被覆粒状肥料 |
| JPH082989A (ja) | 1994-06-16 | 1996-01-09 | Shimadzu Corp | 生分解性高分子被膜を有する層状肥料 |
| JP3395375B2 (ja) * | 1994-06-24 | 2003-04-14 | 東洋紡績株式会社 | 塗料用樹脂組成物 |
| JP2642874B2 (ja) | 1994-07-11 | 1997-08-20 | 工業技術院長 | 被覆肥料の製造方法およびその製品 |
| DE19500757A1 (de) * | 1995-01-13 | 1996-07-18 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| DE19505186A1 (de) * | 1995-02-16 | 1996-10-31 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| DE19521502A1 (de) | 1995-06-13 | 1996-12-19 | Basf Ag | Umhüllte Düngemittelgranulate |
| JPH09132305A (ja) * | 1995-11-06 | 1997-05-20 | Murata Mach Ltd | 自動倉庫の侵入検出装置 |
| DE69731623D1 (de) * | 1996-04-23 | 2004-12-23 | Ipsen Mfg Ireland Ltd | Saure Polymilchsäure Polymere |
-
1996
- 1996-09-30 DE DE19640269A patent/DE19640269A1/de not_active Withdrawn
-
1997
- 1997-09-29 PT PT97910391T patent/PT931036E/pt unknown
- 1997-09-29 US US09/269,335 patent/US6413292B1/en not_active Expired - Fee Related
- 1997-09-29 AU AU47795/97A patent/AU737144B2/en not_active Ceased
- 1997-09-29 SK SK358-99A patent/SK284098B6/sk not_active IP Right Cessation
- 1997-09-29 EP EP97910391A patent/EP0931036B1/de not_active Expired - Lifetime
- 1997-09-29 CZ CZ0109799A patent/CZ296874B6/cs not_active IP Right Cessation
- 1997-09-29 WO PCT/EP1997/005352 patent/WO1998014413A1/de not_active Ceased
- 1997-09-29 CA CA002267349A patent/CA2267349A1/en not_active Abandoned
- 1997-09-29 AT AT97910391T patent/ATE193004T1/de active
- 1997-09-29 ES ES97910391T patent/ES2148943T3/es not_active Expired - Lifetime
- 1997-09-29 DE DE59701736T patent/DE59701736D1/de not_active Expired - Lifetime
- 1997-09-29 CN CN97180231A patent/CN1113048C/zh not_active Expired - Fee Related
- 1997-09-29 NZ NZ334783A patent/NZ334783A/en unknown
- 1997-09-29 UA UA99042443A patent/UA49925C2/uk unknown
- 1997-09-29 JP JP51621998A patent/JP2001507326A/ja active Pending
- 1997-09-29 PL PL97332500A patent/PL188969B1/pl not_active IP Right Cessation
- 1997-09-29 KR KR1019990702678A patent/KR20000048714A/ko not_active Withdrawn
- 1997-09-30 MY MYPI97004571A patent/MY126366A/en unknown
- 1997-09-30 TW TW086114226A patent/TW450949B/zh not_active IP Right Cessation
-
2000
- 2000-05-31 GR GR20000401271T patent/GR3033576T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SK35899A3 (en) | 2000-03-13 |
| CA2267349A1 (en) | 1998-04-09 |
| TW450949B (en) | 2001-08-21 |
| EP0931036A1 (de) | 1999-07-28 |
| PL332500A1 (en) | 1999-09-13 |
| AU737144B2 (en) | 2001-08-09 |
| KR20000048714A (ko) | 2000-07-25 |
| AU4779597A (en) | 1998-04-24 |
| WO1998014413A1 (de) | 1998-04-09 |
| CN1113048C (zh) | 2003-07-02 |
| DE19640269A1 (de) | 1998-04-02 |
| PT931036E (pt) | 2000-11-30 |
| JP2001507326A (ja) | 2001-06-05 |
| US6413292B1 (en) | 2002-07-02 |
| MY126366A (en) | 2006-09-29 |
| DE59701736D1 (de) | 2000-06-21 |
| EP0931036B1 (de) | 2000-05-17 |
| ES2148943T3 (es) | 2000-10-16 |
| ATE193004T1 (de) | 2000-06-15 |
| CZ296874B6 (cs) | 2006-07-12 |
| NZ334783A (en) | 2000-02-28 |
| CZ109799A3 (cs) | 1999-07-14 |
| PL188969B1 (pl) | 2005-05-31 |
| GR3033576T3 (en) | 2000-09-29 |
| UA49925C2 (uk) | 2002-10-15 |
| CN1239470A (zh) | 1999-12-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Patent lapsed due to non-payment of maintenance fees |
Effective date: 20100929 |