RU2126017C1 - Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения - Google Patents
Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения Download PDFInfo
- Publication number
- RU2126017C1 RU2126017C1 RU95122079A RU95122079A RU2126017C1 RU 2126017 C1 RU2126017 C1 RU 2126017C1 RU 95122079 A RU95122079 A RU 95122079A RU 95122079 A RU95122079 A RU 95122079A RU 2126017 C1 RU2126017 C1 RU 2126017C1
- Authority
- RU
- Russia
- Prior art keywords
- group
- same
- metallocene
- different
- olefin monomer
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6674093A | 1993-05-25 | 1993-05-25 | |
| US08/066.740 | 1993-05-25 | ||
| US08/066,740 | 1993-05-25 | ||
| PCT/US1994/005636 WO1994028034A1 (en) | 1993-05-25 | 1994-05-20 | Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU95122079A RU95122079A (ru) | 1998-01-10 |
| RU2126017C1 true RU2126017C1 (ru) | 1999-02-10 |
Family
ID=22071387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU95122079A RU2126017C1 (ru) | 1993-05-25 | 1994-05-20 | Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0705281B1 (ref) |
| JP (1) | JP3626186B2 (ref) |
| KR (1) | KR100314971B1 (ref) |
| CN (1) | CN1043474C (ref) |
| AU (1) | AU683899B2 (ref) |
| CA (1) | CA2163789C (ref) |
| DE (1) | DE69408989T2 (ref) |
| ES (1) | ES2117279T3 (ref) |
| FI (1) | FI114640B (ref) |
| NO (1) | NO308952B1 (ref) |
| RU (1) | RU2126017C1 (ref) |
| TW (1) | TW270091B (ref) |
| WO (1) | WO1994028034A1 (ref) |
| ZA (1) | ZA943595B (ref) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2205837C2 (ru) * | 1996-04-10 | 2003-06-10 | Юнироял Кемикал Компани, Инк. | Способ полимеризации для получения полиолефинового эластомера, сокатализатор, образующий катион, для активации металлоценового прокатализатора, полиолефиновый эластомер |
| RU2392283C2 (ru) * | 2005-03-23 | 2010-06-20 | Базелль Полиолефине Гмбх | Способ полимеризации олефинов |
| RU2431640C2 (ru) * | 2006-02-02 | 2011-10-20 | Базелль Полиолефине Гмбх | Полипропиленовые пластмассы, полученные методом выдувной экструзии, пропиленовое волокно и нетканый материал из него же, а также методы их получения |
Families Citing this family (114)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW454020B (en) † | 1994-08-09 | 2001-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst |
| WO1996018661A1 (en) * | 1994-12-15 | 1996-06-20 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
| PT743324E (pt) * | 1995-05-16 | 2003-01-31 | Univation Tech Llc | Producao de polietileno usando metalocenos estereoisomericos |
| WO1997002297A1 (en) * | 1995-07-06 | 1997-01-23 | Exxon Chemical Patents Inc. | Method for producing prepolymerized, supported metallocene catalyst systems |
| DE69623308T2 (de) * | 1995-10-18 | 2002-12-19 | Chisso Corp., Osaka | Olefin(co)polymerzusammensetzung, verfahren zu dessen herstellung, katalysator for olefin(co)polymerisation und verfahren zu dessen herstellung |
| DE19548288A1 (de) | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
| FI104826B (fi) * | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
| ES2156389T3 (es) | 1996-07-04 | 2001-06-16 | Basf Ag | Procedimiento para la obtencion de catalizadores de metales de transicion soportados. |
| WO1998013393A1 (en) * | 1996-09-24 | 1998-04-02 | Exxon Chemical Patents Inc. | Improved method for preparing supported metallocene catalyst systems |
| US6245856B1 (en) | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
| DE19703502A1 (de) | 1997-01-31 | 1998-08-06 | Basf Ag | Nicht selbstentzündlicher Feststoff |
| ES2187005T3 (es) | 1997-02-07 | 2003-05-16 | Exxonmobil Chem Patents Inc | Polimeros de propileno que incorporan macromeros de polietileno. |
| TW425414B (en) * | 1997-02-18 | 2001-03-11 | Chisso Corp | Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method |
| DE19757563A1 (de) * | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| WO1998044042A1 (en) | 1997-04-02 | 1998-10-08 | Chisso Corporation | Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding |
| US6143683A (en) * | 1997-04-09 | 2000-11-07 | Fina Technology, Inc. | Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms |
| US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
| TW504515B (en) | 1997-08-07 | 2002-10-01 | Chisso Corp | Olefin (co)polymer composition |
| WO1999009076A1 (en) | 1997-08-15 | 1999-02-25 | Chisso Corporation | Polydisperse propylene polymer and process for producing the same |
| CN1279694A (zh) * | 1997-10-22 | 2001-01-10 | 智索公司 | 负载型金属茂催化剂、其制备方法及烯烃聚合物的生产方法 |
| US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
| US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
| US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
| EP1042377A1 (en) * | 1997-12-23 | 2000-10-11 | Univation Technologies LLC | Slurry polymerization process with alkyl-substituted biscyclopentadienyl metallocenes |
| DE19811934A1 (de) | 1998-03-19 | 1999-09-23 | Basf Ag | Ethylencopolymere mit enger Comonomerverteilung |
| US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
| CA2327497A1 (en) | 1998-05-13 | 1999-11-18 | Exxon Chemical Patents, Inc. | Propylene homopolymers and methods of making the same |
| US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
| DE19821949A1 (de) | 1998-05-15 | 1999-11-18 | Basf Ag | Verfahren zur Herstellung geträgerter Katalysatoren |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| CA2341167A1 (en) | 1998-08-26 | 2000-03-09 | Exxon Chemical Patents Inc. | Branched polypropylene compositions |
| DE19949235A1 (de) | 1998-10-16 | 2000-05-11 | Chisso Corp | Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung |
| GB9826874D0 (en) | 1998-12-07 | 1999-01-27 | Borealis As | Process |
| CA2324923C (en) * | 1999-01-21 | 2009-09-15 | Idemitsu Petrochemical Co., Ltd. | Catalyst for the production of .alpha.-olefin and .alpha.-olefin production method |
| KR100367463B1 (ko) * | 1999-03-03 | 2003-01-14 | 주식회사 엘지화학 | 메탈로센 화합물 및 이를 이용한 올레핀 중합 |
| US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
| DE19927766A1 (de) | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
| AU7540700A (en) | 1999-10-02 | 2001-05-10 | Borealis Technology Oy | Modified supported catalysts for the polymerization of olefins |
| WO2001032758A1 (en) | 1999-11-04 | 2001-05-10 | Exxon Chemical Patents Inc. | Propylene copolymer foams and their use |
| DE19957384A1 (de) | 1999-11-29 | 2001-05-31 | Targor Gmbh | Hochmolekulares Polypropylen mit breiter Molekulargewichtsverteilung und geringer isotaktischer Sequenzlänge |
| US7105690B2 (en) | 2000-05-31 | 2006-09-12 | Basell Polyolefine Gmbh | Method for producing transition metal compounds and their use for the polymerization of olefins |
| GB0023662D0 (en) | 2000-09-27 | 2000-11-08 | Borealis Tech Oy | Supported catalyst |
| DE10057009A1 (de) | 2000-11-17 | 2002-05-29 | Celanese Ventures Gmbh | Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
| DE60238256D1 (de) | 2001-06-22 | 2010-12-23 | Borealis Tech Oy | Metallocenkatalysatoren mit einer in 4-, 5-, 6- oder 7-stellung mit siloxy oder germyloxy substitutierten indenylgruppe |
| DE10130229A1 (de) | 2001-06-22 | 2003-01-02 | Celanese Ventures Gmbh | Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
| JP2005522406A (ja) | 2001-06-29 | 2005-07-28 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン及び該メタロセン由来の触媒組成物 |
| EP1323747A1 (en) | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| ES2321806T3 (es) | 2001-12-19 | 2009-06-12 | Borealis Technology Oy | Produccion de catalizadores soportados para la polimerizacion de olefinas. |
| CN100424107C (zh) * | 2002-01-31 | 2008-10-08 | 三菱化学株式会社 | 基于丙烯的软质树脂组合物 |
| DE10208252A1 (de) | 2002-02-26 | 2003-09-04 | Celanese Ventures Gmbh | Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
| DE10213191A1 (de) | 2002-03-23 | 2003-10-02 | Celanese Ventures Gmbh | Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
| WO2003098971A1 (en) | 2002-05-13 | 2003-11-27 | S.C. Johnson & Son, Inc. | Coordinated emission of fragrance, light, and sound |
| US6884749B2 (en) * | 2002-10-17 | 2005-04-26 | Equistar Chemicals L.P. | Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof |
| ES2403514T3 (es) | 2003-02-07 | 2013-05-20 | S.C. Johnson & Son, Inc. | Difusor con iluminación nocturna de LED (diodo emisor de luz) |
| US7285608B2 (en) | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| ES2366651T3 (es) | 2004-12-31 | 2011-10-24 | Borealis Technology Oy | Procedimiento para preparar un catalizador sólido para la polimerización de olefinas. |
| US7643734B2 (en) | 2005-03-31 | 2010-01-05 | S.C. Johnson & Son, Inc. | Bottle eject mechanism |
| US7589340B2 (en) | 2005-03-31 | 2009-09-15 | S.C. Johnson & Son, Inc. | System for detecting a container or contents of the container |
| USD541922S1 (en) | 2005-03-31 | 2007-05-01 | S.C. Johnson & Son, Inc. | Diffuser |
| USD542400S1 (en) | 2005-03-31 | 2007-05-08 | S.C. Johnson & Son, Inc. | Diffuser |
| US7281811B2 (en) | 2005-03-31 | 2007-10-16 | S. C. Johnson & Son, Inc. | Multi-clarity lenses |
| US7232869B2 (en) | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
| DE102005052654A1 (de) * | 2005-11-04 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren |
| US7598329B2 (en) | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
| US8034886B2 (en) | 2005-11-04 | 2011-10-11 | Ticona Gmbh | Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts |
| EP1803743B1 (en) | 2005-12-30 | 2016-08-10 | Borealis Technology Oy | Catalyst particles |
| ATE421760T1 (de) | 2006-07-10 | 2009-02-15 | Borealis Tech Oy | Elektrischer isolierfilm |
| ES2558256T3 (es) | 2006-07-10 | 2016-02-02 | Borealis Technology Oy | Películas de polipropileno orientadas biaxialmente |
| DE602006008470D1 (de) | 2006-08-25 | 2009-09-24 | Borealis Tech Oy | Geblasene Polypropylenfolie |
| EP1900764B1 (en) | 2006-08-25 | 2009-04-01 | Borealis Technology Oy | Polypropylene foam |
| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
| DE602006013137D1 (de) | 2006-09-25 | 2010-05-06 | Borealis Tech Oy | Koaxiales Kabel |
| ES2322186T3 (es) | 2006-12-28 | 2009-06-17 | Borealis Technology Oy | Proceso para la fabricacion de polipropileno ramificado. |
| DE602007001873D1 (de) | 2007-05-08 | 2009-09-17 | Borealis Tech Oy | Folie zur elektrischen Isolierung |
| BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
| US8299287B2 (en) | 2007-10-25 | 2012-10-30 | Lammus Novolen Technology GmbH | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
| CN101910216A (zh) | 2007-10-25 | 2010-12-08 | 鲁姆斯诺沃伦技术公司 | 柄型金属茂化合物的外消旋选择性合成、柄型金属茂化合物、含有该化合物的催化剂、通过使用该催化剂制备烯烃聚合物的方法和烯烃均聚物及共聚物 |
| EP2235071A2 (en) | 2007-10-25 | 2010-10-06 | Novolen Technology Holdings, C.V. | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers |
| EP2075284B1 (en) | 2007-12-17 | 2013-05-29 | Borealis Technology OY | Heterophasic polypropylene with high flowability and excellent low temperature impact properties |
| ES2337195T5 (es) | 2007-12-18 | 2013-03-01 | Borealis Technology Oy | Polipropileno heterofásico con elevadas propiedades de impacto |
| EP2113541A1 (en) | 2008-04-28 | 2009-11-04 | Borealis AG | Adhesive propylene polymer composition suitable for extrusion coating of paper substrates |
| EP2133389A1 (en) | 2008-06-12 | 2009-12-16 | Borealis AG | Polypropylene composition |
| US7897705B2 (en) | 2008-08-08 | 2011-03-01 | Sumitomo Chemical Company, Limited | Process for producing olefin polymer |
| US7960486B2 (en) | 2008-08-08 | 2011-06-14 | Sumitomo Chemical Company, Limited | Process for producing olefin polymer |
| US20100036068A1 (en) | 2008-08-08 | 2010-02-11 | Sumitomo Chemical Company, Limited | Hydrogenation catalyst and process for producing olefin polymer |
| KR100992715B1 (ko) | 2008-08-21 | 2010-11-05 | 삼성토탈 주식회사 | 폴리올레핀 중합용 촉매의 제조방법 및 그를 이용한 폴리올레핀 중합체 제조방법 |
| JP2010065068A (ja) | 2008-09-08 | 2010-03-25 | Sumitomo Chemical Co Ltd | ポリオレフィンの製造装置および製造方法 |
| EP2184301A1 (en) | 2008-11-07 | 2010-05-12 | Borealis AG | Process for the preparation of a hafnium catalyst system |
| EP2355927B1 (en) | 2008-11-07 | 2015-03-04 | Borealis AG | Solid catalyst composition |
| PL2186834T3 (pl) | 2008-11-18 | 2011-06-30 | Borealis Ag | Statystyczny kopolimer propylenu-heksenu produkowany w obecności katalizatora metalocenowego |
| EP2316882A1 (en) | 2009-10-29 | 2011-05-04 | Borealis AG | Heterophasic polypropylene resin |
| EP2319885B1 (en) | 2009-10-29 | 2011-12-21 | Borealis AG | Heterophasic polypropylene resin with long chain branching |
| EP2325248B1 (en) | 2009-11-16 | 2012-05-16 | Borealis AG | Melt blown fibers of polypropylene compositions |
| EP2330136B1 (en) | 2009-12-07 | 2013-08-28 | Borealis AG | Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins |
| EP2513166B1 (en) * | 2009-12-18 | 2017-04-05 | Basell Polyolefine GmbH | Process for the preparation of supported catalysts |
| EP2338920A1 (en) | 2009-12-22 | 2011-06-29 | Borealis AG | Preparation of single-site catalysts |
| WO2011076443A1 (en) | 2009-12-22 | 2011-06-30 | Borealis Ag | Preparation of polypropylene in the presence of a single-site catalyst |
| EP2338921B8 (en) | 2009-12-22 | 2015-05-06 | Borealis AG | Preparation of single-site catalysts |
| EP2341088B1 (en) | 2009-12-30 | 2012-06-20 | Borealis AG | BOPP with homogeneous film morphology |
| EP2341086A1 (en) | 2009-12-30 | 2011-07-06 | Borealis AG | Bopp-film |
| EP2385073A1 (en) | 2010-05-07 | 2011-11-09 | Borealis AG | Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins |
| EP2386584A1 (en) | 2010-05-11 | 2011-11-16 | Borealis AG | Polypropylene composition suitable for extrusion coating |
| EP2418237A1 (en) | 2010-08-12 | 2012-02-15 | Borealis AG | Easy tear polypropylene film without notch |
| EP2743293B1 (en) | 2010-08-12 | 2016-11-30 | Borealis AG | Easy tear polypropylene film without notch |
| EP2426171A1 (en) | 2010-08-30 | 2012-03-07 | Borealis AG | Heterophasic polypropylene with high flowability and enhanced mechanical properties |
| EP2492293B1 (en) | 2011-02-28 | 2017-09-20 | Borealis AG | Polypropylene composition suitable for extrusion coating |
| ES2648254T3 (es) | 2011-05-02 | 2017-12-29 | Borealis Ag | Polipropileno para espuma y espuma de polipropileno |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
| WO2018091653A1 (en) | 2016-11-18 | 2018-05-24 | Borealis Ag | Catalyst |
| KR102225972B1 (ko) * | 2016-12-06 | 2021-03-09 | 주식회사 엘지화학 | 폴리프로필렌의 제조 방법 |
| CN112409515B (zh) * | 2019-08-23 | 2023-10-20 | 中国石油化工股份有限公司 | 茂金属聚丙烯催化剂的制备方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU427022A1 (ru) * | 1972-03-16 | 1974-05-05 | Способ получения карбоцепных линейных полимеров | |
| EP0363029B1 (en) * | 1988-09-14 | 1994-08-03 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| EP0433990B1 (de) * | 1989-12-21 | 1995-04-19 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung einer Polypropylen-Formmasse |
| RU94019418A (ru) * | 1991-09-12 | 1995-12-20 | Басф Аг | Катализаторная система на основе металлоцена, способ ее получения и способ получения полимеров алкенов с 2 - 10 атомами углерода |
| EP0485822B1 (de) * | 1990-11-12 | 1996-07-03 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
| EP0399347B1 (de) * | 1989-05-20 | 1996-08-14 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines Syndio-Isoblockpolymeren |
| EP0530647B1 (de) * | 1991-08-26 | 1998-01-28 | Hoechst Aktiengesellschaft | Metallocene, diese enthaltende Katalysatoren und Verfahren zur Herstellung eines Olefinpolymers unter Verwendung dieser Katalysatoren |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4119343A1 (de) * | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| JP3193110B2 (ja) * | 1992-04-15 | 2001-07-30 | 三菱化学株式会社 | プロピレン重合体の製造法 |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| TW294669B (ref) * | 1992-06-27 | 1997-01-01 | Hoechst Ag |
-
1994
- 1994-05-20 KR KR1019950705272A patent/KR100314971B1/ko not_active Expired - Lifetime
- 1994-05-20 DE DE69408989T patent/DE69408989T2/de not_active Expired - Lifetime
- 1994-05-20 AU AU70413/94A patent/AU683899B2/en not_active Expired
- 1994-05-20 EP EP94919175A patent/EP0705281B1/en not_active Expired - Lifetime
- 1994-05-20 ES ES94919175T patent/ES2117279T3/es not_active Expired - Lifetime
- 1994-05-20 RU RU95122079A patent/RU2126017C1/ru active
- 1994-05-20 CA CA002163789A patent/CA2163789C/en not_active Expired - Lifetime
- 1994-05-20 WO PCT/US1994/005636 patent/WO1994028034A1/en not_active Ceased
- 1994-05-20 CN CN94192752A patent/CN1043474C/zh not_active Expired - Lifetime
- 1994-05-20 JP JP50080295A patent/JP3626186B2/ja not_active Expired - Lifetime
- 1994-05-24 ZA ZA943595A patent/ZA943595B/xx unknown
- 1994-06-06 TW TW083105189A patent/TW270091B/zh not_active IP Right Cessation
-
1995
- 1995-11-24 FI FI955687A patent/FI114640B/fi not_active IP Right Cessation
- 1995-11-24 NO NO954780A patent/NO308952B1/no not_active IP Right Cessation
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU427022A1 (ru) * | 1972-03-16 | 1974-05-05 | Способ получения карбоцепных линейных полимеров | |
| EP0363029B1 (en) * | 1988-09-14 | 1994-08-03 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| EP0399347B1 (de) * | 1989-05-20 | 1996-08-14 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines Syndio-Isoblockpolymeren |
| EP0433990B1 (de) * | 1989-12-21 | 1995-04-19 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung einer Polypropylen-Formmasse |
| EP0485822B1 (de) * | 1990-11-12 | 1996-07-03 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
| EP0530647B1 (de) * | 1991-08-26 | 1998-01-28 | Hoechst Aktiengesellschaft | Metallocene, diese enthaltende Katalysatoren und Verfahren zur Herstellung eines Olefinpolymers unter Verwendung dieser Katalysatoren |
| RU94019418A (ru) * | 1991-09-12 | 1995-12-20 | Басф Аг | Катализаторная система на основе металлоцена, способ ее получения и способ получения полимеров алкенов с 2 - 10 атомами углерода |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2205837C2 (ru) * | 1996-04-10 | 2003-06-10 | Юнироял Кемикал Компани, Инк. | Способ полимеризации для получения полиолефинового эластомера, сокатализатор, образующий катион, для активации металлоценового прокатализатора, полиолефиновый эластомер |
| RU2392283C2 (ru) * | 2005-03-23 | 2010-06-20 | Базелль Полиолефине Гмбх | Способ полимеризации олефинов |
| RU2431640C2 (ru) * | 2006-02-02 | 2011-10-20 | Базелль Полиолефине Гмбх | Полипропиленовые пластмассы, полученные методом выдувной экструзии, пропиленовое волокно и нетканый материал из него же, а также методы их получения |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3626186B2 (ja) | 2005-03-02 |
| CN1043474C (zh) | 1999-05-26 |
| CA2163789C (en) | 2006-10-24 |
| EP0705281A1 (en) | 1996-04-10 |
| TW270091B (ref) | 1996-02-11 |
| FI955687A0 (fi) | 1995-11-24 |
| NO954780D0 (no) | 1995-11-24 |
| ES2117279T3 (es) | 1998-08-01 |
| EP0705281B1 (en) | 1998-03-11 |
| CN1130912A (zh) | 1996-09-11 |
| KR960702484A (ko) | 1996-04-27 |
| JPH08511044A (ja) | 1996-11-19 |
| KR100314971B1 (ko) | 2002-07-03 |
| DE69408989T2 (de) | 1998-11-05 |
| AU683899B2 (en) | 1997-11-27 |
| FI955687L (fi) | 1996-01-24 |
| FI114640B (fi) | 2004-11-30 |
| ZA943595B (en) | 1995-12-14 |
| NO308952B1 (no) | 2000-11-20 |
| NO954780L (no) | 1996-01-15 |
| AU7041394A (en) | 1994-12-20 |
| CA2163789A1 (en) | 1994-12-08 |
| WO1994028034A9 (en) | 1999-07-29 |
| WO1994028034A1 (en) | 1994-12-08 |
| DE69408989D1 (de) | 1998-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2126017C1 (ru) | Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения | |
| AU651915B2 (en) | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts | |
| JP4167254B2 (ja) | アリール置換インデニル誘導体をリガンドとして含んだメタロセンの合成のための中間体およびその使用方法 | |
| AU651914B2 (en) | Process for the preparation of a high molecular weight olefin polymer | |
| RU2142466C1 (ru) | Металлоцены, содержащая их каталитическая система, способ полимеризации олефинов, полиолефин, формованное изделие | |
| RU2144539C1 (ru) | Металлоцены, содержащая их каталитическая система, способ получения полиолефинов, полиолефин | |
| US5830821A (en) | Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands | |
| AU640286B2 (en) | Process for the preparation of a high molecular weight olefin polymer | |
| HUP0003603A2 (hu) | Olefinek polimerizációjában alkalmazható metallocének és katalizátorok | |
| JP4017202B2 (ja) | 有機金属化合物 | |
| WO1996000243A1 (en) | Polymerization catalyst systems, their production and use | |
| US5932669A (en) | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts | |
| US5945367A (en) | Metallocenes with silyl-substituted bridges and their use for olefin polymerization | |
| CA2219652A1 (en) | Metallocenes containing partially hydrogenated p-ligands | |
| AU656834B2 (en) | Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof | |
| US6391817B1 (en) | Method for producing a prepolymerized catalyst | |
| JP2000191715A (ja) | ポリオレフィン製造 |