DE69408989D1 - Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung - Google Patents
Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendungInfo
- Publication number
- DE69408989D1 DE69408989D1 DE69408989T DE69408989T DE69408989D1 DE 69408989 D1 DE69408989 D1 DE 69408989D1 DE 69408989 T DE69408989 T DE 69408989T DE 69408989 T DE69408989 T DE 69408989T DE 69408989 D1 DE69408989 D1 DE 69408989D1
- Authority
- DE
- Germany
- Prior art keywords
- metalocenate
- production
- support
- catalyst system
- olefin polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US6674093A | 1993-05-25 | 1993-05-25 | |
PCT/US1994/005636 WO1994028034A1 (en) | 1993-05-25 | 1994-05-20 | Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69408989D1 true DE69408989D1 (de) | 1998-04-16 |
DE69408989T2 DE69408989T2 (de) | 1998-11-05 |
Family
ID=22071387
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69408989T Expired - Lifetime DE69408989T2 (de) | 1993-05-25 | 1994-05-20 | Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP0705281B1 (de) |
JP (1) | JP3626186B2 (de) |
KR (1) | KR100314971B1 (de) |
CN (1) | CN1043474C (de) |
AU (1) | AU683899B2 (de) |
CA (1) | CA2163789C (de) |
DE (1) | DE69408989T2 (de) |
ES (1) | ES2117279T3 (de) |
FI (1) | FI114640B (de) |
NO (1) | NO308952B1 (de) |
RU (1) | RU2126017C1 (de) |
TW (1) | TW270091B (de) |
WO (1) | WO1994028034A1 (de) |
ZA (1) | ZA943595B (de) |
Families Citing this family (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW454020B (en) † | 1994-08-09 | 2001-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst |
EP0797598B1 (de) | 1994-12-15 | 2001-03-14 | Exxon Chemical Patents Inc. | Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung |
UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
DE69623528T2 (de) * | 1995-05-16 | 2003-03-20 | Univation Technologies,Llc | Herstellung von Polyethylen unter Verwendung eines stereoisomeren Metallocens |
KR100427159B1 (ko) * | 1995-07-06 | 2004-06-16 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 예비중합되고지지된메탈로센촉매계의제조방법 |
US6156845A (en) * | 1995-10-18 | 2000-12-05 | Chisso Corporation | Polyolefin composition and method of making |
DE19548288A1 (de) | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
FI104826B (fi) | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
JP2001501987A (ja) | 1996-07-04 | 2001-02-13 | ビーエーエスエフ アクチェンゲゼルシャフト | 遷移金属担持触媒の製造方法 |
EP0928297A1 (de) * | 1996-09-24 | 1999-07-14 | Exxon Chemical Patents Inc. | Verbessertes verfahren zur herstellung von geträgerten metallocenkatalysatorsystemen |
US6245856B1 (en) | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
DE19703502A1 (de) | 1997-01-31 | 1998-08-06 | Basf Ag | Nicht selbstentzündlicher Feststoff |
CN1130406C (zh) | 1997-02-07 | 2003-12-10 | 埃克森美孚化学专利公司 | 结合有聚乙烯大分子单体的丙烯聚合物 |
TW425414B (en) * | 1997-02-18 | 2001-03-11 | Chisso Corp | Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method |
DE19757563A1 (de) * | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
WO1998044042A1 (fr) | 1997-04-02 | 1998-10-08 | Chisso Corporation | Composition (co)polymere d'olefine modifiee, procede pour preparer cette composition et produit moule de cette composition (co)polymere |
US6143683A (en) * | 1997-04-09 | 2000-11-07 | Fina Technology, Inc. | Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms |
US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
TW504515B (en) | 1997-08-07 | 2002-10-01 | Chisso Corp | Olefin (co)polymer composition |
JP4119607B2 (ja) | 1997-08-15 | 2008-07-16 | チッソ株式会社 | 多分散性プロピレン重合体およびその製造方法 |
EP1026177A4 (de) * | 1997-10-22 | 2004-12-08 | Chisso Corp | Geträgerter metallocenekatalysator, verfahren zu dessen herstellung und verfahren zur herstellung von olefinpolymeren |
US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
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WO1999032531A1 (en) * | 1997-12-23 | 1999-07-01 | Univation Technologies Llc | Slurry polymerization process with alkyl-substituted biscyclopentadienyl metallocenes |
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DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
CN1167718C (zh) | 1998-08-26 | 2004-09-22 | 埃克森美孚化学专利公司 | 支化聚丙烯组合物 |
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EP2385073A1 (de) | 2010-05-07 | 2011-11-09 | Borealis AG | Katalysatoren |
EP2386584A1 (de) | 2010-05-11 | 2011-11-16 | Borealis AG | Polypropylenzusammensetzung, die zur Extrusionsbeschichtung geeignet ist |
EP2603548A1 (de) | 2010-08-12 | 2013-06-19 | Borealis AG | Leicht abziehbare polypropylenfolie ohne kerbstelle |
EP2418237A1 (de) | 2010-08-12 | 2012-02-15 | Borealis AG | Leicht abziehbarer Polypropylen-Film ohne Nocke |
EP2426171A1 (de) | 2010-08-30 | 2012-03-07 | Borealis AG | Heterophasisches Polypropylen mit großer Fließfähigkeit und verbesserten mechanischen Eigenschaften |
EP2492293B1 (de) | 2011-02-28 | 2017-09-20 | Borealis AG | Polypropylenzusammensetzung, die zur Extrusionsbeschichtung geeignet ist |
EP2520425B1 (de) | 2011-05-02 | 2017-11-08 | Borealis AG | Polypropylen für schaumstoff und polypropylenschaumstoff |
EP2573091A1 (de) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen |
WO2018091653A1 (en) | 2016-11-18 | 2018-05-24 | Borealis Ag | Catalyst |
KR102225972B1 (ko) * | 2016-12-06 | 2021-03-09 | 주식회사 엘지화학 | 폴리프로필렌의 제조 방법 |
CN112409515B (zh) * | 2019-08-23 | 2023-10-20 | 中国石油化工股份有限公司 | 茂金属聚丙烯催化剂的制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE59107973D1 (de) * | 1990-11-12 | 1996-08-08 | Hoechst Ag | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
DE4119343A1 (de) * | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
JP3193110B2 (ja) * | 1992-04-15 | 2001-07-30 | 三菱化学株式会社 | プロピレン重合体の製造法 |
US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag |
-
1994
- 1994-05-20 WO PCT/US1994/005636 patent/WO1994028034A1/en active IP Right Grant
- 1994-05-20 KR KR1019950705272A patent/KR100314971B1/ko not_active IP Right Cessation
- 1994-05-20 DE DE69408989T patent/DE69408989T2/de not_active Expired - Lifetime
- 1994-05-20 JP JP50080295A patent/JP3626186B2/ja not_active Expired - Lifetime
- 1994-05-20 ES ES94919175T patent/ES2117279T3/es not_active Expired - Lifetime
- 1994-05-20 CN CN94192752A patent/CN1043474C/zh not_active Expired - Lifetime
- 1994-05-20 AU AU70413/94A patent/AU683899B2/en not_active Expired
- 1994-05-20 EP EP94919175A patent/EP0705281B1/de not_active Expired - Lifetime
- 1994-05-20 CA CA002163789A patent/CA2163789C/en not_active Expired - Lifetime
- 1994-05-20 RU RU95122079A patent/RU2126017C1/ru active
- 1994-05-24 ZA ZA943595A patent/ZA943595B/xx unknown
- 1994-06-06 TW TW083105189A patent/TW270091B/zh not_active IP Right Cessation
-
1995
- 1995-11-24 NO NO954780A patent/NO308952B1/no not_active IP Right Cessation
- 1995-11-24 FI FI955687A patent/FI114640B/fi not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1130912A (zh) | 1996-09-11 |
WO1994028034A9 (en) | 1999-07-29 |
JP3626186B2 (ja) | 2005-03-02 |
NO954780L (no) | 1996-01-15 |
WO1994028034A1 (en) | 1994-12-08 |
KR960702484A (ko) | 1996-04-27 |
TW270091B (de) | 1996-02-11 |
ZA943595B (en) | 1995-12-14 |
NO954780D0 (no) | 1995-11-24 |
KR100314971B1 (ko) | 2002-07-03 |
FI955687A (fi) | 1996-01-24 |
DE69408989T2 (de) | 1998-11-05 |
EP0705281A1 (de) | 1996-04-10 |
JPH08511044A (ja) | 1996-11-19 |
RU2126017C1 (ru) | 1999-02-10 |
FI114640B (fi) | 2004-11-30 |
ES2117279T3 (es) | 1998-08-01 |
NO308952B1 (no) | 2000-11-20 |
CA2163789A1 (en) | 1994-12-08 |
AU683899B2 (en) | 1997-11-27 |
EP0705281B1 (de) | 1998-03-11 |
FI955687A0 (fi) | 1995-11-24 |
CN1043474C (zh) | 1999-05-26 |
CA2163789C (en) | 2006-10-24 |
AU7041394A (en) | 1994-12-20 |
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