ES2117279T3 - Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. - Google Patents
Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso.Info
- Publication number
- ES2117279T3 ES2117279T3 ES94919175T ES94919175T ES2117279T3 ES 2117279 T3 ES2117279 T3 ES 2117279T3 ES 94919175 T ES94919175 T ES 94919175T ES 94919175 T ES94919175 T ES 94919175T ES 2117279 T3 ES2117279 T3 ES 2117279T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- metalochene
- olephins
- catalytical
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
LA INVENCION SE REFIERE A SISTEMAS CATALIZADORES DE METALOCENO SOPORTADOS, OPCIONALMENTE POLIMERIZADOS CON MONOMEROS OLEFINICOS, PREFERIBLEMENTE ETILENO O PROPILENO, UTILES EN LA POLIMERIZACION DE ETILENO A POLIPROPILENO ISOTACTICO. EL POLIPROPILENO ISOTACTICO OBTENIDO GENERALMENTE POSEE UN PESO MOLECULAR DE APROXIMADAMENTE 100000 G/M O MAYOR, UN PUNTO DE FUNDICION DE APROXIMADAMENTE 140 GRADOS C O MAYOR Y UNA MORFOLOGIA GRANULAR. EL SISTEMA CATALIZADOR SOPORTADO POSEE GENERALMENTE UNA ACTIVIDAD CATALITICA ELEVADA, Y AL SER UTILIZADO EN UN REACTOR DE POLIMERIZACION RESULTA EN UN PROCESO CON UN BLOQUEO, DETERIORO, ETC. DEL REACTOR MINIMO O NULO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US6674093A | 1993-05-25 | 1993-05-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2117279T3 true ES2117279T3 (es) | 1998-08-01 |
Family
ID=22071387
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94919175T Expired - Lifetime ES2117279T3 (es) | 1993-05-25 | 1994-05-20 | Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP0705281B1 (es) |
JP (1) | JP3626186B2 (es) |
KR (1) | KR100314971B1 (es) |
CN (1) | CN1043474C (es) |
AU (1) | AU683899B2 (es) |
CA (1) | CA2163789C (es) |
DE (1) | DE69408989T2 (es) |
ES (1) | ES2117279T3 (es) |
FI (1) | FI114640B (es) |
NO (1) | NO308952B1 (es) |
RU (1) | RU2126017C1 (es) |
TW (1) | TW270091B (es) |
WO (1) | WO1994028034A1 (es) |
ZA (1) | ZA943595B (es) |
Families Citing this family (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW454020B (en) † | 1994-08-09 | 2001-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst |
EP0797598B1 (en) | 1994-12-15 | 2001-03-14 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
JP3071145B2 (ja) * | 1995-05-16 | 2000-07-31 | ユニベーション・テクノロジーズ・エルエルシー | 立体異性型メタロセンを用いるポリエチレンの製造 |
UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
KR100427159B1 (ko) * | 1995-07-06 | 2004-06-16 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 예비중합되고지지된메탈로센촉매계의제조방법 |
KR100254936B1 (ko) * | 1995-10-18 | 2000-05-01 | 고토 기치 | 올레핀(공)중합체 조성물과 그 제조방법 및 올레핀(공)중합용 촉매와 그 제조방법 |
DE19548288A1 (de) | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
FI104825B (fi) * | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
FI104826B (fi) * | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
EP0909279B1 (de) | 1996-07-04 | 2001-04-25 | Basf Aktiengesellschaft | Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren |
EP0928297A1 (en) * | 1996-09-24 | 1999-07-14 | Exxon Chemical Patents Inc. | Improved method for preparing supported metallocene catalyst systems |
US6245856B1 (en) | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
DE19703502A1 (de) | 1997-01-31 | 1998-08-06 | Basf Ag | Nicht selbstentzündlicher Feststoff |
EP0958313B1 (en) | 1997-02-07 | 2002-09-25 | ExxonMobil Chemical Patents Inc. | Thermoplastic elastomer compositions from branched olefin copolymers |
TW425414B (en) * | 1997-02-18 | 2001-03-11 | Chisso Corp | Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method |
DE19757563A1 (de) * | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
US6231804B1 (en) | 1997-04-02 | 2001-05-15 | Chisso Corporation | Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding |
US6143683A (en) * | 1997-04-09 | 2000-11-07 | Fina Technology, Inc. | Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms |
US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
TW504515B (en) | 1997-08-07 | 2002-10-01 | Chisso Corp | Olefin (co)polymer composition |
WO1999009076A1 (fr) | 1997-08-15 | 1999-02-25 | Chisso Corporation | Polypropylene polydisperse et procede de production associe |
CN1279694A (zh) * | 1997-10-22 | 2001-01-10 | 智索公司 | 负载型金属茂催化剂、其制备方法及烯烃聚合物的生产方法 |
US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
JP2001527098A (ja) * | 1997-12-23 | 2001-12-25 | ユニベーション・テクノロジーズ・エルエルシー | アルキル置換ビスシクロペンタジエニルメタロセンを用いるスラリー重合法 |
DE19811934A1 (de) | 1998-03-19 | 1999-09-23 | Basf Ag | Ethylencopolymere mit enger Comonomerverteilung |
US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
DE69918100T2 (de) | 1998-05-13 | 2005-07-07 | Exxonmobil Chemical Patents Inc., Baytown | Propylenhomopolymere und herstellungsverfahren |
DE19821949A1 (de) | 1998-05-15 | 1999-11-18 | Basf Ag | Verfahren zur Herstellung geträgerter Katalysatoren |
DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
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BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
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EP2386584A1 (en) | 2010-05-11 | 2011-11-16 | Borealis AG | Polypropylene composition suitable for extrusion coating |
EP2603548A1 (en) | 2010-08-12 | 2013-06-19 | Borealis AG | Easy tear polypropylene film without notch |
EP2418237A1 (en) | 2010-08-12 | 2012-02-15 | Borealis AG | Easy tear polypropylene film without notch |
EP2426171A1 (en) | 2010-08-30 | 2012-03-07 | Borealis AG | Heterophasic polypropylene with high flowability and enhanced mechanical properties |
ES2645714T3 (es) | 2011-02-28 | 2017-12-07 | Borealis Ag | Composición de polipropileno adecuada para el recubrimiento por extrusión |
EP2520425B1 (en) | 2011-05-02 | 2017-11-08 | Borealis AG | Polypropylene for foam and polypropylene foam |
EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
WO2018091653A1 (en) | 2016-11-18 | 2018-05-24 | Borealis Ag | Catalyst |
KR102225972B1 (ko) * | 2016-12-06 | 2021-03-09 | 주식회사 엘지화학 | 폴리프로필렌의 제조 방법 |
CN112409515B (zh) * | 2019-08-23 | 2023-10-20 | 中国石油化工股份有限公司 | 茂金属聚丙烯催化剂的制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2091273T3 (es) * | 1990-11-12 | 1996-11-01 | Hoechst Ag | Procedimiento para la preparacion de un polimero olefinico de alto peso molecular. |
DE4119343A1 (de) * | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
JP3193110B2 (ja) * | 1992-04-15 | 2001-07-30 | 三菱化学株式会社 | プロピレン重合体の製造法 |
US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
TW294669B (es) * | 1992-06-27 | 1997-01-01 | Hoechst Ag |
-
1994
- 1994-05-20 CA CA002163789A patent/CA2163789C/en not_active Expired - Lifetime
- 1994-05-20 AU AU70413/94A patent/AU683899B2/en not_active Expired
- 1994-05-20 RU RU95122079A patent/RU2126017C1/ru active
- 1994-05-20 ES ES94919175T patent/ES2117279T3/es not_active Expired - Lifetime
- 1994-05-20 EP EP94919175A patent/EP0705281B1/en not_active Expired - Lifetime
- 1994-05-20 JP JP50080295A patent/JP3626186B2/ja not_active Expired - Lifetime
- 1994-05-20 WO PCT/US1994/005636 patent/WO1994028034A1/en active IP Right Grant
- 1994-05-20 DE DE69408989T patent/DE69408989T2/de not_active Expired - Lifetime
- 1994-05-20 CN CN94192752A patent/CN1043474C/zh not_active Expired - Lifetime
- 1994-05-20 KR KR1019950705272A patent/KR100314971B1/ko not_active IP Right Cessation
- 1994-05-24 ZA ZA943595A patent/ZA943595B/xx unknown
- 1994-06-06 TW TW083105189A patent/TW270091B/zh not_active IP Right Cessation
-
1995
- 1995-11-24 NO NO954780A patent/NO308952B1/no not_active IP Right Cessation
- 1995-11-24 FI FI955687A patent/FI114640B/fi not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE69408989T2 (de) | 1998-11-05 |
JP3626186B2 (ja) | 2005-03-02 |
FI114640B (fi) | 2004-11-30 |
AU7041394A (en) | 1994-12-20 |
AU683899B2 (en) | 1997-11-27 |
WO1994028034A9 (en) | 1999-07-29 |
NO308952B1 (no) | 2000-11-20 |
EP0705281B1 (en) | 1998-03-11 |
DE69408989D1 (de) | 1998-04-16 |
CA2163789A1 (en) | 1994-12-08 |
FI955687A (fi) | 1996-01-24 |
FI955687A0 (fi) | 1995-11-24 |
JPH08511044A (ja) | 1996-11-19 |
NO954780D0 (no) | 1995-11-24 |
WO1994028034A1 (en) | 1994-12-08 |
RU2126017C1 (ru) | 1999-02-10 |
CN1043474C (zh) | 1999-05-26 |
EP0705281A1 (en) | 1996-04-10 |
NO954780L (no) | 1996-01-15 |
TW270091B (es) | 1996-02-11 |
CA2163789C (en) | 2006-10-24 |
KR100314971B1 (ko) | 2002-07-03 |
ZA943595B (en) | 1995-12-14 |
KR960702484A (ko) | 1996-04-27 |
CN1130912A (zh) | 1996-09-11 |
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