ES2117065T3 - Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo. - Google Patents

Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo.

Info

Publication number
ES2117065T3
ES2117065T3 ES93105333T ES93105333T ES2117065T3 ES 2117065 T3 ES2117065 T3 ES 2117065T3 ES 93105333 T ES93105333 T ES 93105333T ES 93105333 T ES93105333 T ES 93105333T ES 2117065 T3 ES2117065 T3 ES 2117065T3
Authority
ES
Spain
Prior art keywords
olefins
polymerization
catalyst
procedure
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93105333T
Other languages
English (en)
Inventor
Hans-Friedrich Dr Herrmann
Bernd Dr Bachmann
Bernhard Dr Hierholzer
Walter Dr Spaleck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Targor GmbH
Original Assignee
Targor GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6455689&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2117065(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Targor GmbH filed Critical Targor GmbH
Application granted granted Critical
Publication of ES2117065T3 publication Critical patent/ES2117065T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

LA PRESENTE INVENCION CONCIERNE A UN CATALIZADOR PORTADOR, PARA LA POLIMERIZACION DE OLEFINAS, OBTENIBLE POR TRANSFORMACION DEL PRODUCTO DE REACCION, FORMADO A PARTIR DE UN ALUMINOXANO Y AL MENOS UN METALOCENO, CON UN PORTADOR POLIMERO MICROPOROSO.
ES93105333T 1992-04-01 1993-03-31 Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo. Expired - Lifetime ES2117065T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4210780 1992-04-01

Publications (1)

Publication Number Publication Date
ES2117065T3 true ES2117065T3 (es) 1998-08-01

Family

ID=6455689

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93105333T Expired - Lifetime ES2117065T3 (es) 1992-04-01 1993-03-31 Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo.

Country Status (13)

Country Link
US (2) US20020013217A1 (es)
EP (1) EP0563917B1 (es)
JP (1) JP3944247B2 (es)
KR (1) KR100269057B1 (es)
AT (1) ATE167198T1 (es)
AU (1) AU665811B2 (es)
CA (1) CA2093056A1 (es)
DE (1) DE59308657D1 (es)
ES (1) ES2117065T3 (es)
FI (1) FI112233B (es)
NO (1) NO302237B1 (es)
RU (1) RU2111219C1 (es)
ZA (1) ZA932305B (es)

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TW298593B (es) * 1993-02-12 1997-02-21 Hoechst Ag
AU683899B2 (en) * 1993-05-25 1997-11-27 Exxon Chemical Patents Inc. Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
FI96866C (fi) * 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
DE4344672C1 (de) * 1993-12-27 1995-06-14 Basf Ag Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation
AU694765B2 (en) * 1994-03-01 1998-07-30 Mobil Oil Corporation Olefin polymerization catalysts
FR2717816B1 (fr) * 1994-03-23 1996-04-26 Atochem Elf Sa Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
DE59503827D1 (de) * 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
ATE207085T1 (de) * 1994-06-24 2001-11-15 Exxonmobil Chem Patents Inc Polymerisationskatalysatorsystem, ihre herstellung und verwendung
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
US7153909B2 (en) * 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
ATE199732T1 (de) 1994-12-15 2001-03-15 Exxon Chemical Patents Inc Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
IT1272923B (it) * 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
WO1996035729A1 (en) * 1995-05-09 1996-11-14 Fina Research S.A. Process for preparing and using a supported metallocene-alumoxane catalyst
US5587439A (en) * 1995-05-12 1996-12-24 Quantum Chemical Corporation Polymer supported catalyst for olefin polymerization
TW338046B (en) * 1995-06-29 1998-08-11 Ciba Sc Holding Ag Process for the preparation of stabilized olefin polymers
DE19548288A1 (de) * 1995-12-22 1997-06-26 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
DE19621969A1 (de) * 1996-05-31 1997-12-04 Basf Ag Verfahren zur Herstellung von kristallinen Polymerisaten durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen
GB9613814D0 (en) * 1996-07-02 1996-09-04 Bp Chem Int Ltd Supported polymerisation catalysts
DE19630451C1 (de) * 1996-07-27 1998-01-08 Solvay Deutschland Verfahren zur Herstellung von porösen Polymerkugeln und deren Verwendung
US6136742A (en) * 1996-09-24 2000-10-24 Exxon Chemical Patents, Inc. Metallocene catalyst systems
CN1231678A (zh) * 1996-09-24 1999-10-13 埃克森化学专利公司 制备载体上的金属茂催化剂体系的改进方法
US6180736B1 (en) 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
CA2292733A1 (en) * 1997-06-05 1998-12-10 Exxon Chemical Patents, Inc. Polymeric supported catalysts for olefin polymerization
DE19805118A1 (de) * 1998-02-09 1999-09-09 Bayer Ag Neue polymerisationsinitiierende geträgerte Systeme zur ionischen Polymerisation von konjugierten Dienen und zur Copolymerisation dieser mit weiteren Monomeren in Suspensions- oder Gasphasenverfahren
DE19813657A1 (de) * 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP1085025A1 (en) * 1999-02-04 2001-03-21 Idemitsu Petrochemical Co., Ltd. Catalyst for olefin polymerization, process for producing the same, and process for producing olefin polymer
US6281155B1 (en) 1999-11-19 2001-08-28 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
KR100416471B1 (ko) * 1999-12-30 2004-01-31 삼성아토피나주식회사 폴리머 중합용 신규 메탈로센 담지촉매
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US7074736B2 (en) 2000-10-31 2006-07-11 Rohm And Haas Company Hydrozirconated matrix and process for polyolefin production
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US7005487B2 (en) * 2002-07-02 2006-02-28 Basell Poliolefine Italia S.R.L. Catalyst system for the polymerization of olefins
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Also Published As

Publication number Publication date
EP0563917B1 (de) 1998-06-10
FI112233B (fi) 2003-11-14
US5942586A (en) 1999-08-24
FI931423A0 (fi) 1993-03-30
US20020013217A1 (en) 2002-01-31
JPH0625348A (ja) 1994-02-01
AU665811B2 (en) 1996-01-18
NO931243D0 (no) 1993-03-31
ZA932305B (en) 1993-10-18
NO931243L (no) 1993-10-04
KR100269057B1 (ko) 2000-10-16
KR930021658A (ko) 1993-11-22
AU3559893A (en) 1993-10-07
ATE167198T1 (de) 1998-06-15
CA2093056A1 (en) 1993-10-02
DE59308657D1 (de) 1998-07-16
JP3944247B2 (ja) 2007-07-11
EP0563917A1 (de) 1993-10-06
FI931423L (fi) 1993-10-02
NO302237B1 (no) 1998-02-09
RU2111219C1 (ru) 1998-05-20

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