RU2126017C1 - Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения - Google Patents

Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения Download PDF

Info

Publication number
RU2126017C1
RU2126017C1 RU95122079A RU95122079A RU2126017C1 RU 2126017 C1 RU2126017 C1 RU 2126017C1 RU 95122079 A RU95122079 A RU 95122079A RU 95122079 A RU95122079 A RU 95122079A RU 2126017 C1 RU2126017 C1 RU 2126017C1
Authority
RU
Russia
Prior art keywords
group
same
metallocene
different
olefin monomer
Prior art date
Application number
RU95122079A
Other languages
English (en)
Russian (ru)
Other versions
RU95122079A (ru
Inventor
Джон Баркхардт Терри
Лоренс Бринен Джеффри
Джордж Хлатки Грегори
Шпалекк Вальтер
Винтер Андреас
Original Assignee
Эксон Кемикэл Пейтентс Инк.
Хехст Акциенгезелльшафт
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Эксон Кемикэл Пейтентс Инк., Хехст Акциенгезелльшафт filed Critical Эксон Кемикэл Пейтентс Инк.
Publication of RU95122079A publication Critical patent/RU95122079A/ru
Application granted granted Critical
Publication of RU2126017C1 publication Critical patent/RU2126017C1/ru

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
RU95122079A 1993-05-25 1994-05-20 Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения RU2126017C1 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US6674093A 1993-05-25 1993-05-25
US08/066,740 1993-05-25
US08/066.740 1993-05-25
PCT/US1994/005636 WO1994028034A1 (en) 1993-05-25 1994-05-20 Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof

Publications (2)

Publication Number Publication Date
RU95122079A RU95122079A (ru) 1998-01-10
RU2126017C1 true RU2126017C1 (ru) 1999-02-10

Family

ID=22071387

Family Applications (1)

Application Number Title Priority Date Filing Date
RU95122079A RU2126017C1 (ru) 1993-05-25 1994-05-20 Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения

Country Status (14)

Country Link
EP (1) EP0705281B1 (online.php)
JP (1) JP3626186B2 (online.php)
KR (1) KR100314971B1 (online.php)
CN (1) CN1043474C (online.php)
AU (1) AU683899B2 (online.php)
CA (1) CA2163789C (online.php)
DE (1) DE69408989T2 (online.php)
ES (1) ES2117279T3 (online.php)
FI (1) FI114640B (online.php)
NO (1) NO308952B1 (online.php)
RU (1) RU2126017C1 (online.php)
TW (1) TW270091B (online.php)
WO (1) WO1994028034A1 (online.php)
ZA (1) ZA943595B (online.php)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2205837C2 (ru) * 1996-04-10 2003-06-10 Юнироял Кемикал Компани, Инк. Способ полимеризации для получения полиолефинового эластомера, сокатализатор, образующий катион, для активации металлоценового прокатализатора, полиолефиновый эластомер
RU2392283C2 (ru) * 2005-03-23 2010-06-20 Базелль Полиолефине Гмбх Способ полимеризации олефинов
RU2431640C2 (ru) * 2006-02-02 2011-10-20 Базелль Полиолефине Гмбх Полипропиленовые пластмассы, полученные методом выдувной экструзии, пропиленовое волокно и нетканый материал из него же, а также методы их получения

Families Citing this family (114)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW454020B (en) † 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
DE69520370T2 (de) * 1994-12-15 2001-10-31 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
ES2182950T3 (es) * 1995-05-16 2003-03-16 Univation Tech Llc Produccion de polietileno utilizando metalocenos estereosomericos.
JPH11508932A (ja) * 1995-07-06 1999-08-03 エクソン・ケミカル・パテンツ・インク 予備重合され担持されたメタロセン触媒系の製造方法
JP3176932B2 (ja) * 1995-10-18 2001-06-18 チッソ株式会社 オレフィン（共）重合体組成物とその製造方法及びオレフィン（共）重合用触媒とその製造方法
DE19548288A1 (de) 1995-12-22 1997-06-26 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
FI104826B (fi) * 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
ATE200785T1 (de) 1996-07-04 2001-05-15 Basf Ag Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
WO1998013393A1 (en) * 1996-09-24 1998-04-02 Exxon Chemical Patents Inc. Improved method for preparing supported metallocene catalyst systems
US6245856B1 (en) 1996-12-17 2001-06-12 Exxon Chemical Patents, Inc. Thermoplastic olefin compositions
DE19703502A1 (de) 1997-01-31 1998-08-06 Basf Ag Nicht selbstentzündlicher Feststoff
DE69809192T2 (de) 1997-02-07 2003-07-24 Exxonmobil Chemical Patents Inc., Baytown Propylenpolymere enthaltend polyethylenmakromonomere
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6231804B1 (en) 1997-04-02 2001-05-15 Chisso Corporation Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
EP1004603B1 (en) 1997-08-15 2003-01-15 Chisso Corporation Polydisperse propylene polymer and process for producing the same
JP3695331B2 (ja) * 1997-10-22 2005-09-14 チッソ株式会社 メタロセン担持型触媒およびその製造方法、ならびにオレフィン重合体の製造方法
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
ES2195443T3 (es) * 1997-12-23 2003-12-01 Exxonmobil Chem Patents Inc Procedimiento de polimerizacion de etileno en un medio de reaccion liquido.
DE19811934A1 (de) 1998-03-19 1999-09-23 Basf Ag Ethylencopolymere mit enger Comonomerverteilung
EP1078009B1 (en) 1998-05-13 2004-06-16 ExxonMobil Chemical Patents Inc. Propylene homopolymers and methods of making the same
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
DE19821949A1 (de) 1998-05-15 1999-11-18 Basf Ag Verfahren zur Herstellung geträgerter Katalysatoren
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
EP1115761B1 (en) 1998-08-26 2013-09-18 ExxonMobil Chemical Patents Inc. Branched polypropylene compositions
DE19949235A1 (de) 1998-10-16 2000-05-11 Chisso Corp Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung
GB9826874D0 (en) 1998-12-07 1999-01-27 Borealis As Process
KR100662954B1 (ko) 1999-01-21 2006-12-28 이데미쓰 고산 가부시키가이샤 알파-올레핀 제조용 촉매 및 알파-올레핀의 제조 방법
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
DE19927766A1 (de) 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
JP2003511493A (ja) * 1999-10-02 2003-03-25 ボレアリス テクノロジー オイ オレフィン重合用修飾担持触媒
WO2001032758A1 (en) 1999-11-04 2001-05-10 Exxon Chemical Patents Inc. Propylene copolymer foams and their use
DE19957384A1 (de) 1999-11-29 2001-05-31 Targor Gmbh Hochmolekulares Polypropylen mit breiter Molekulargewichtsverteilung und geringer isotaktischer Sequenzlänge
US7105690B2 (en) 2000-05-31 2006-09-12 Basell Polyolefine Gmbh Method for producing transition metal compounds and their use for the polymerization of olefins
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
DE10057009A1 (de) 2000-11-17 2002-05-29 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
DE10130229A1 (de) 2001-06-22 2003-01-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
WO2003000744A1 (en) 2001-06-22 2003-01-03 Borealis Technology Oy Metallocene catalysts containing an idenyl moiety substituted at the 4-, 5-, 6- or 7-position by a siloxy or germyloxy group
EP1421090B1 (en) 2001-06-29 2014-03-26 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
DE60137638D1 (de) 2001-12-19 2009-03-26 Borealis Tech Oy Herstellung von geträgerten Katalysatoren für die Olefinpolymerisation
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
CN100424107C (zh) * 2002-01-31 2008-10-08 三菱化学株式会社 基于丙烯的软质树脂组合物
DE10208252A1 (de) 2002-02-26 2003-09-04 Celanese Ventures Gmbh Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
DE10213191A1 (de) 2002-03-23 2003-10-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
AU2003233542B2 (en) 2002-05-13 2009-03-05 S.C. Johnson & Son, Inc. Coordinated emission of fragrance, light, and sound
US6884749B2 (en) * 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
CN1820543B (zh) 2003-02-07 2010-11-17 约翰逊父子公司 具有发光二极管夜灯的散射器
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
KR101286307B1 (ko) 2004-12-31 2013-07-15 보레알리스 테크놀로지 오와이. 공정
US7643734B2 (en) 2005-03-31 2010-01-05 S.C. Johnson & Son, Inc. Bottle eject mechanism
US7589340B2 (en) 2005-03-31 2009-09-15 S.C. Johnson & Son, Inc. System for detecting a container or contents of the container
US7281811B2 (en) 2005-03-31 2007-10-16 S. C. Johnson & Son, Inc. Multi-clarity lenses
USD541922S1 (en) 2005-03-31 2007-05-01 S.C. Johnson & Son, Inc. Diffuser
USD542400S1 (en) 2005-03-31 2007-05-08 S.C. Johnson & Son, Inc. Diffuser
US7232869B2 (en) 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US7598329B2 (en) 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
EP1803743B1 (en) 2005-12-30 2016-08-10 Borealis Technology Oy Catalyst particles
ATE421760T1 (de) 2006-07-10 2009-02-15 Borealis Tech Oy Elektrischer isolierfilm
PT2208749E (pt) 2006-07-10 2016-03-04 Borealis Tech Oy Películas de polipropileno orientadas biaxialmente
DE602006008470D1 (de) 2006-08-25 2009-09-24 Borealis Tech Oy Geblasene Polypropylenfolie
EP1967547A1 (en) 2006-08-25 2008-09-10 Borealis Technology OY Extrusion coated substrate
ATE427330T1 (de) 2006-08-25 2009-04-15 Borealis Tech Oy Polypropylenschaumstoff
EP1903579B1 (en) 2006-09-25 2010-03-24 Borealis Technology Oy Coaxial cable
ATE424424T1 (de) 2006-12-28 2009-03-15 Borealis Tech Oy Verfahren zur herstellung von verzweigtem polypropylen
DE602007001873D1 (de) 2007-05-08 2009-09-17 Borealis Tech Oy Folie zur elektrischen Isolierung
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
JP5598856B2 (ja) 2007-10-25 2014-10-01 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー
EP2235071A2 (en) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
EP2203486B9 (en) 2007-10-25 2012-08-01 Lummus Novolen Technology Gmbh Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
EP2363433B1 (en) 2007-12-17 2018-02-07 Borealis Technology OY Heterophasic polypropylene with high flowability and excellent low temperature impact properties
ATE457323T1 (de) 2007-12-18 2010-02-15 Borealis Tech Oy Heterophasisches polypropylen mit hoher schlagfestigkeit
EP2113541A1 (en) 2008-04-28 2009-11-04 Borealis AG Adhesive propylene polymer composition suitable for extrusion coating of paper substrates
EP2133389A1 (en) 2008-06-12 2009-12-16 Borealis AG Polypropylene composition
US20100036068A1 (en) 2008-08-08 2010-02-11 Sumitomo Chemical Company, Limited Hydrogenation catalyst and process for producing olefin polymer
US7960486B2 (en) 2008-08-08 2011-06-14 Sumitomo Chemical Company, Limited Process for producing olefin polymer
US7897705B2 (en) 2008-08-08 2011-03-01 Sumitomo Chemical Company, Limited Process for producing olefin polymer
KR100992715B1 (ko) 2008-08-21 2010-11-05 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법 및 그를 이용한 폴리올레핀 중합체 제조방법
JP2010065068A (ja) 2008-09-08 2010-03-25 Sumitomo Chemical Co Ltd ポリオレフィンの製造装置および製造方法
EP2184301A1 (en) 2008-11-07 2010-05-12 Borealis AG Process for the preparation of a hafnium catalyst system
WO2010052264A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
ES2359761T3 (es) 2008-11-18 2011-05-26 Borealis Ag Copolímero aleatorio de propileno-hexeno producido en presencia de un catalizador metalocénico.
EP2316882A1 (en) 2009-10-29 2011-05-04 Borealis AG Heterophasic polypropylene resin
ATE538173T1 (de) 2009-10-29 2012-01-15 Borealis Ag Heterophasisches polypropylenharz mit langkettiger verzweigung
PL2325248T3 (pl) 2009-11-16 2012-11-30 Borealis Ag Włókna pneumotermiczne typu melt blown z kompozycji polipropylenowych
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
US8859451B2 (en) 2009-12-18 2014-10-14 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
EP2338920A1 (en) 2009-12-22 2011-06-29 Borealis AG Preparation of single-site catalysts
EP2338921B8 (en) 2009-12-22 2015-05-06 Borealis AG Preparation of single-site catalysts
KR101424366B1 (ko) 2009-12-22 2014-07-31 보레알리스 아게 단일-위치 촉매 존재 하의 폴리프로필렌의 제조
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
EP2341088B1 (en) 2009-12-30 2012-06-20 Borealis AG BOPP with homogeneous film morphology
EP2385073A1 (en) 2010-05-07 2011-11-09 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
EP2386584A1 (en) 2010-05-11 2011-11-16 Borealis AG Polypropylene composition suitable for extrusion coating
EP2418237A1 (en) 2010-08-12 2012-02-15 Borealis AG Easy tear polypropylene film without notch
WO2012020106A1 (en) 2010-08-12 2012-02-16 Borealis Ag Easy tear polypropylene film without notch
EP2426171A1 (en) 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
ES2645714T3 (es) 2011-02-28 2017-12-07 Borealis Ag Composición de polipropileno adecuada para el recubrimiento por extrusión
EP2520425B1 (en) 2011-05-02 2017-11-08 Borealis AG Polypropylene for foam and polypropylene foam
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
WO2018091653A1 (en) 2016-11-18 2018-05-24 Borealis Ag Catalyst
KR102225972B1 (ko) * 2016-12-06 2021-03-09 주식회사 엘지화학 폴리프로필렌의 제조 방법
CN112409515B (zh) * 2019-08-23 2023-10-20 中国石油化工股份有限公司 茂金属聚丙烯催化剂的制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU427022A1 (ru) * 1972-03-16 1974-05-05 Способ получения карбоцепных линейных полимеров
EP0363029B1 (en) * 1988-09-14 1994-08-03 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
EP0433990B1 (de) * 1989-12-21 1995-04-19 Hoechst Aktiengesellschaft Verfahren zur Herstellung einer Polypropylen-Formmasse
RU94019418A (ru) * 1991-09-12 1995-12-20 Басф Аг Катализаторная система на основе металлоцена, способ ее получения и способ получения полимеров алкенов с 2 - 10 атомами углерода
EP0485822B1 (de) * 1990-11-12 1996-07-03 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines hochmolekularen Olefinpolymers
EP0399347B1 (de) * 1989-05-20 1996-08-14 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Syndio-Isoblockpolymeren
EP0530647B1 (de) * 1991-08-26 1998-01-28 Hoechst Aktiengesellschaft Metallocene, diese enthaltende Katalysatoren und Verfahren zur Herstellung eines Olefinpolymers unter Verwendung dieser Katalysatoren

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
JP3193110B2 (ja) * 1992-04-15 2001-07-30 三菱化学株式会社 プロピレン重合体の製造法
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
TW294669B (online.php) * 1992-06-27 1997-01-01 Hoechst Ag

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU427022A1 (ru) * 1972-03-16 1974-05-05 Способ получения карбоцепных линейных полимеров
EP0363029B1 (en) * 1988-09-14 1994-08-03 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
EP0399347B1 (de) * 1989-05-20 1996-08-14 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Syndio-Isoblockpolymeren
EP0433990B1 (de) * 1989-12-21 1995-04-19 Hoechst Aktiengesellschaft Verfahren zur Herstellung einer Polypropylen-Formmasse
EP0485822B1 (de) * 1990-11-12 1996-07-03 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines hochmolekularen Olefinpolymers
EP0530647B1 (de) * 1991-08-26 1998-01-28 Hoechst Aktiengesellschaft Metallocene, diese enthaltende Katalysatoren und Verfahren zur Herstellung eines Olefinpolymers unter Verwendung dieser Katalysatoren
RU94019418A (ru) * 1991-09-12 1995-12-20 Басф Аг Катализаторная система на основе металлоцена, способ ее получения и способ получения полимеров алкенов с 2 - 10 атомами углерода

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2205837C2 (ru) * 1996-04-10 2003-06-10 Юнироял Кемикал Компани, Инк. Способ полимеризации для получения полиолефинового эластомера, сокатализатор, образующий катион, для активации металлоценового прокатализатора, полиолефиновый эластомер
RU2392283C2 (ru) * 2005-03-23 2010-06-20 Базелль Полиолефине Гмбх Способ полимеризации олефинов
RU2431640C2 (ru) * 2006-02-02 2011-10-20 Базелль Полиолефине Гмбх Полипропиленовые пластмассы, полученные методом выдувной экструзии, пропиленовое волокно и нетканый материал из него же, а также методы их получения

Also Published As

Publication number Publication date
CN1043474C (zh) 1999-05-26
AU683899B2 (en) 1997-11-27
CN1130912A (zh) 1996-09-11
CA2163789A1 (en) 1994-12-08
FI955687A0 (fi) 1995-11-24
WO1994028034A9 (en) 1999-07-29
JPH08511044A (ja) 1996-11-19
ZA943595B (en) 1995-12-14
JP3626186B2 (ja) 2005-03-02
ES2117279T3 (es) 1998-08-01
WO1994028034A1 (en) 1994-12-08
DE69408989T2 (de) 1998-11-05
TW270091B (online.php) 1996-02-11
KR960702484A (ko) 1996-04-27
KR100314971B1 (ko) 2002-07-03
EP0705281B1 (en) 1998-03-11
AU7041394A (en) 1994-12-20
DE69408989D1 (de) 1998-04-16
FI114640B (fi) 2004-11-30
NO308952B1 (no) 2000-11-20
EP0705281A1 (en) 1996-04-10
NO954780D0 (no) 1995-11-24
NO954780L (no) 1996-01-15
CA2163789C (en) 2006-10-24
FI955687L (fi) 1996-01-24

Similar Documents

Publication Publication Date Title
EP0705281B1 (en) Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
AU651915B2 (en) Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
JP4167254B2 (ja) アリール置換インデニル誘導体をリガンドとして含んだメタロセンの合成のための中間体およびその使用方法
AU651914B2 (en) Process for the preparation of a high molecular weight olefin polymer
RU2142466C1 (ru) Металлоцены, содержащая их каталитическая система, способ полимеризации олефинов, полиолефин, формованное изделие
RU2144539C1 (ru) Металлоцены, содержащая их каталитическая система, способ получения полиолефинов, полиолефин
US5830821A (en) Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
AU640286B2 (en) Process for the preparation of a high molecular weight olefin polymer
AU665811B2 (en) Catalyst for the polymerization of olefins, process for its preparation and its use
HUP0003603A2 (hu) Olefinek polimerizációjában alkalmazható metallocének és katalizátorok
JP4017202B2 (ja) 有機金属化合物
WO1996000243A1 (en) Polymerization catalyst systems, their production and use
US5932669A (en) Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
US5945367A (en) Metallocenes with silyl-substituted bridges and their use for olefin polymerization
CA2219652A1 (en) Metallocenes containing partially hydrogenated p-ligands
AU656834B2 (en) Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof
US6391817B1 (en) Method for producing a prepolymerized catalyst
JP2000191715A (ja) ポリオレフィン製造