ES2117279T3 - Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. - Google Patents
Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso.Info
- Publication number
- ES2117279T3 ES2117279T3 ES94919175T ES94919175T ES2117279T3 ES 2117279 T3 ES2117279 T3 ES 2117279T3 ES 94919175 T ES94919175 T ES 94919175T ES 94919175 T ES94919175 T ES 94919175T ES 2117279 T3 ES2117279 T3 ES 2117279T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- metalochene
- olephins
- catalytical
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6674093A | 1993-05-25 | 1993-05-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2117279T3 true ES2117279T3 (es) | 1998-08-01 |
Family
ID=22071387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94919175T Expired - Lifetime ES2117279T3 (es) | 1993-05-25 | 1994-05-20 | Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0705281B1 (online.php) |
| JP (1) | JP3626186B2 (online.php) |
| KR (1) | KR100314971B1 (online.php) |
| CN (1) | CN1043474C (online.php) |
| AU (1) | AU683899B2 (online.php) |
| CA (1) | CA2163789C (online.php) |
| DE (1) | DE69408989T2 (online.php) |
| ES (1) | ES2117279T3 (online.php) |
| FI (1) | FI114640B (online.php) |
| NO (1) | NO308952B1 (online.php) |
| RU (1) | RU2126017C1 (online.php) |
| TW (1) | TW270091B (online.php) |
| WO (1) | WO1994028034A1 (online.php) |
| ZA (1) | ZA943595B (online.php) |
Families Citing this family (117)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW454020B (en) † | 1994-08-09 | 2001-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst |
| DE69520370T2 (de) * | 1994-12-15 | 2001-10-31 | Exxon Chemical Patents, Inc. | Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung |
| UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
| ES2182950T3 (es) * | 1995-05-16 | 2003-03-16 | Univation Tech Llc | Produccion de polietileno utilizando metalocenos estereosomericos. |
| JPH11508932A (ja) * | 1995-07-06 | 1999-08-03 | エクソン・ケミカル・パテンツ・インク | 予備重合され担持されたメタロセン触媒系の製造方法 |
| JP3176932B2 (ja) * | 1995-10-18 | 2001-06-18 | チッソ株式会社 | オレフィン(共)重合体組成物とその製造方法及びオレフィン(共)重合用触媒とその製造方法 |
| DE19548288A1 (de) | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
| FI104826B (fi) * | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
| US6225426B1 (en) * | 1996-04-10 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Process for producing polyolefin elastomer employing a metallocene catalyst |
| ATE200785T1 (de) | 1996-07-04 | 2001-05-15 | Basf Ag | Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren |
| WO1998013393A1 (en) * | 1996-09-24 | 1998-04-02 | Exxon Chemical Patents Inc. | Improved method for preparing supported metallocene catalyst systems |
| US6245856B1 (en) | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
| DE19703502A1 (de) | 1997-01-31 | 1998-08-06 | Basf Ag | Nicht selbstentzündlicher Feststoff |
| DE69809192T2 (de) | 1997-02-07 | 2003-07-24 | Exxonmobil Chemical Patents Inc., Baytown | Propylenpolymere enthaltend polyethylenmakromonomere |
| TW425414B (en) * | 1997-02-18 | 2001-03-11 | Chisso Corp | Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method |
| DE19757563A1 (de) * | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| US6231804B1 (en) | 1997-04-02 | 2001-05-15 | Chisso Corporation | Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding |
| US6143683A (en) * | 1997-04-09 | 2000-11-07 | Fina Technology, Inc. | Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms |
| US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
| TW504515B (en) | 1997-08-07 | 2002-10-01 | Chisso Corp | Olefin (co)polymer composition |
| EP1004603B1 (en) | 1997-08-15 | 2003-01-15 | Chisso Corporation | Polydisperse propylene polymer and process for producing the same |
| JP3695331B2 (ja) * | 1997-10-22 | 2005-09-14 | チッソ株式会社 | メタロセン担持型触媒およびその製造方法、ならびにオレフィン重合体の製造方法 |
| US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
| US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
| US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
| ES2195443T3 (es) * | 1997-12-23 | 2003-12-01 | Exxonmobil Chem Patents Inc | Procedimiento de polimerizacion de etileno en un medio de reaccion liquido. |
| DE19811934A1 (de) | 1998-03-19 | 1999-09-23 | Basf Ag | Ethylencopolymere mit enger Comonomerverteilung |
| EP1078009B1 (en) | 1998-05-13 | 2004-06-16 | ExxonMobil Chemical Patents Inc. | Propylene homopolymers and methods of making the same |
| US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
| US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
| DE19821949A1 (de) | 1998-05-15 | 1999-11-18 | Basf Ag | Verfahren zur Herstellung geträgerter Katalysatoren |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| EP1115761B1 (en) | 1998-08-26 | 2013-09-18 | ExxonMobil Chemical Patents Inc. | Branched polypropylene compositions |
| DE19949235A1 (de) | 1998-10-16 | 2000-05-11 | Chisso Corp | Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung |
| GB9826874D0 (en) | 1998-12-07 | 1999-01-27 | Borealis As | Process |
| KR100662954B1 (ko) | 1999-01-21 | 2006-12-28 | 이데미쓰 고산 가부시키가이샤 | 알파-올레핀 제조용 촉매 및 알파-올레핀의 제조 방법 |
| KR100367463B1 (ko) * | 1999-03-03 | 2003-01-14 | 주식회사 엘지화학 | 메탈로센 화합물 및 이를 이용한 올레핀 중합 |
| US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
| DE19927766A1 (de) | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
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| DE19957384A1 (de) | 1999-11-29 | 2001-05-31 | Targor Gmbh | Hochmolekulares Polypropylen mit breiter Molekulargewichtsverteilung und geringer isotaktischer Sequenzlänge |
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| CN1820543B (zh) | 2003-02-07 | 2010-11-17 | 约翰逊父子公司 | 具有发光二极管夜灯的散射器 |
| US7285608B2 (en) | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| KR101286307B1 (ko) | 2004-12-31 | 2013-07-15 | 보레알리스 테크놀로지 오와이. | 공정 |
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| US7598329B2 (en) | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
| US8034886B2 (en) | 2005-11-04 | 2011-10-11 | Ticona Gmbh | Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts |
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| EP1803743B1 (en) | 2005-12-30 | 2016-08-10 | Borealis Technology Oy | Catalyst particles |
| KR101364329B1 (ko) * | 2006-02-02 | 2014-02-18 | 바젤 폴리올레핀 게엠베하 | 프로필렌 용융 취입 수지, 이로부터 제조된 프로필렌 용융 취입 수지 섬유 및 부직포, 및 이의 제조 방법 |
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| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
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| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
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| BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
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| JP2010065068A (ja) | 2008-09-08 | 2010-03-25 | Sumitomo Chemical Co Ltd | ポリオレフィンの製造装置および製造方法 |
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| ES2359761T3 (es) | 2008-11-18 | 2011-05-26 | Borealis Ag | Copolímero aleatorio de propileno-hexeno producido en presencia de un catalizador metalocénico. |
| EP2316882A1 (en) | 2009-10-29 | 2011-05-04 | Borealis AG | Heterophasic polypropylene resin |
| ATE538173T1 (de) | 2009-10-29 | 2012-01-15 | Borealis Ag | Heterophasisches polypropylenharz mit langkettiger verzweigung |
| PL2325248T3 (pl) | 2009-11-16 | 2012-11-30 | Borealis Ag | Włókna pneumotermiczne typu melt blown z kompozycji polipropylenowych |
| EP2330136B1 (en) | 2009-12-07 | 2013-08-28 | Borealis AG | Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins |
| US8859451B2 (en) | 2009-12-18 | 2014-10-14 | Basell Polyolefine Gmbh | Process for the preparation of supported catalysts |
| EP2338920A1 (en) | 2009-12-22 | 2011-06-29 | Borealis AG | Preparation of single-site catalysts |
| EP2338921B8 (en) | 2009-12-22 | 2015-05-06 | Borealis AG | Preparation of single-site catalysts |
| KR101424366B1 (ko) | 2009-12-22 | 2014-07-31 | 보레알리스 아게 | 단일-위치 촉매 존재 하의 폴리프로필렌의 제조 |
| EP2341086A1 (en) | 2009-12-30 | 2011-07-06 | Borealis AG | Bopp-film |
| EP2341088B1 (en) | 2009-12-30 | 2012-06-20 | Borealis AG | BOPP with homogeneous film morphology |
| EP2385073A1 (en) | 2010-05-07 | 2011-11-09 | Borealis AG | Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins |
| EP2386584A1 (en) | 2010-05-11 | 2011-11-16 | Borealis AG | Polypropylene composition suitable for extrusion coating |
| EP2418237A1 (en) | 2010-08-12 | 2012-02-15 | Borealis AG | Easy tear polypropylene film without notch |
| WO2012020106A1 (en) | 2010-08-12 | 2012-02-16 | Borealis Ag | Easy tear polypropylene film without notch |
| EP2426171A1 (en) | 2010-08-30 | 2012-03-07 | Borealis AG | Heterophasic polypropylene with high flowability and enhanced mechanical properties |
| ES2645714T3 (es) | 2011-02-28 | 2017-12-07 | Borealis Ag | Composición de polipropileno adecuada para el recubrimiento por extrusión |
| EP2520425B1 (en) | 2011-05-02 | 2017-11-08 | Borealis AG | Polypropylene for foam and polypropylene foam |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
| WO2018091653A1 (en) | 2016-11-18 | 2018-05-24 | Borealis Ag | Catalyst |
| KR102225972B1 (ko) * | 2016-12-06 | 2021-03-09 | 주식회사 엘지화학 | 폴리프로필렌의 제조 방법 |
| CN112409515B (zh) * | 2019-08-23 | 2023-10-20 | 中国石油化工股份有限公司 | 茂金属聚丙烯催化剂的制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU427022A1 (ru) * | 1972-03-16 | 1974-05-05 | Способ получения карбоцепных линейных полимеров | |
| KR920006464B1 (ko) * | 1988-09-14 | 1992-08-07 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법 |
| DE3916553A1 (de) * | 1989-05-20 | 1990-11-22 | Hoechst Ag | Syndio- isoblockpolymer und verfahren zu seiner herstellung |
| DE3942364A1 (de) * | 1989-12-21 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung einer polypropylen-formmasse |
| ES2091273T3 (es) * | 1990-11-12 | 1996-11-01 | Hoechst Ag | Procedimiento para la preparacion de un polimero olefinico de alto peso molecular. |
| DE4119343A1 (de) * | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| TW300901B (online.php) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| JP3193110B2 (ja) * | 1992-04-15 | 2001-07-30 | 三菱化学株式会社 | プロピレン重合体の製造法 |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| TW294669B (online.php) * | 1992-06-27 | 1997-01-01 | Hoechst Ag |
-
1994
- 1994-05-20 DE DE69408989T patent/DE69408989T2/de not_active Expired - Lifetime
- 1994-05-20 CA CA002163789A patent/CA2163789C/en not_active Expired - Lifetime
- 1994-05-20 ES ES94919175T patent/ES2117279T3/es not_active Expired - Lifetime
- 1994-05-20 EP EP94919175A patent/EP0705281B1/en not_active Expired - Lifetime
- 1994-05-20 RU RU95122079A patent/RU2126017C1/ru active
- 1994-05-20 WO PCT/US1994/005636 patent/WO1994028034A1/en not_active Ceased
- 1994-05-20 KR KR1019950705272A patent/KR100314971B1/ko not_active Expired - Lifetime
- 1994-05-20 CN CN94192752A patent/CN1043474C/zh not_active Expired - Lifetime
- 1994-05-20 AU AU70413/94A patent/AU683899B2/en not_active Expired
- 1994-05-20 JP JP50080295A patent/JP3626186B2/ja not_active Expired - Lifetime
- 1994-05-24 ZA ZA943595A patent/ZA943595B/xx unknown
- 1994-06-06 TW TW083105189A patent/TW270091B/zh not_active IP Right Cessation
-
1995
- 1995-11-24 FI FI955687A patent/FI114640B/fi not_active IP Right Cessation
- 1995-11-24 NO NO954780A patent/NO308952B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1043474C (zh) | 1999-05-26 |
| AU683899B2 (en) | 1997-11-27 |
| CN1130912A (zh) | 1996-09-11 |
| CA2163789A1 (en) | 1994-12-08 |
| FI955687A0 (fi) | 1995-11-24 |
| WO1994028034A9 (en) | 1999-07-29 |
| JPH08511044A (ja) | 1996-11-19 |
| ZA943595B (en) | 1995-12-14 |
| JP3626186B2 (ja) | 2005-03-02 |
| WO1994028034A1 (en) | 1994-12-08 |
| DE69408989T2 (de) | 1998-11-05 |
| TW270091B (online.php) | 1996-02-11 |
| KR960702484A (ko) | 1996-04-27 |
| KR100314971B1 (ko) | 2002-07-03 |
| RU2126017C1 (ru) | 1999-02-10 |
| EP0705281B1 (en) | 1998-03-11 |
| AU7041394A (en) | 1994-12-20 |
| DE69408989D1 (de) | 1998-04-16 |
| FI114640B (fi) | 2004-11-30 |
| NO308952B1 (no) | 2000-11-20 |
| EP0705281A1 (en) | 1996-04-10 |
| NO954780D0 (no) | 1995-11-24 |
| NO954780L (no) | 1996-01-15 |
| CA2163789C (en) | 2006-10-24 |
| FI955687L (fi) | 1996-01-24 |
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