ES2133888T3 - Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno. - Google Patents

Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno.

Info

Publication number
ES2133888T3
ES2133888T3 ES96200514T ES96200514T ES2133888T3 ES 2133888 T3 ES2133888 T3 ES 2133888T3 ES 96200514 T ES96200514 T ES 96200514T ES 96200514 T ES96200514 T ES 96200514T ES 2133888 T3 ES2133888 T3 ES 2133888T3
Authority
ES
Spain
Prior art keywords
ethylene
polymerization
procedure
catalytic
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96200514T
Other languages
English (en)
Inventor
Olivier Lhost
Nicola Zandona
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Manufacturing Belgium NV
Solvay SA
Original Assignee
Solvay Polyolefins Europe Belgium SA
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay Polyolefins Europe Belgium SA, Solvay SA filed Critical Solvay Polyolefins Europe Belgium SA
Application granted granted Critical
Publication of ES2133888T3 publication Critical patent/ES2133888T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SOLIDO CATALITICO PARA LA (CO)POLIMERIZACION DE ETILENO QUE COMPRENDE UN SOPORTE INORGANICO, UN METALOCENO DE UN METAL DE TRANSICION, UN AGENTE IONIZANTE Y UN COMPUESTO DE UN METAL DEL GRUPO VIB DE LA TABLA PERIODICA. PROCEDIMIENTO DE PREPARACION DE TAL SOLIDO CATALITICO SEGUN EL CUAL SE PREPARA, EN UNA PRIMERA ETAPA, UN SOLIDO QUE COMPRENDE UN SOPORTE INORGANICO Y UN COMPUESTO DE UN METAL DEL GRUPO VIB Y SE INCORPORA, EN UNA SEGUNDA ETAPA, UN COMPUESTO A BASE DE UN METALOCENO DE METAL DE TRANSICION Y UN COMPUESTO A BASE DE UN AGENTE IONIZANTE. SISTEMA CATALITICO PARA LA (CO)POLIMERIZACION DE ETILENO OBTENIDO POR PUESTA EN CONTACTO DEL SOLIDO CATALITICO CITADO CON UN COMPUESTO ORGANOMETALICO. PROCEDIMIENTO DE POLIMERIZACION DE OLEFINAS EN EL QUE SE UTILIZA ESTE SISTEMA.
ES96200514T 1995-03-13 1996-02-28 Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno. Expired - Lifetime ES2133888T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE9500216A BE1009186A3 (fr) 1995-03-13 1995-03-13 Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.

Publications (1)

Publication Number Publication Date
ES2133888T3 true ES2133888T3 (es) 1999-09-16

Family

ID=3888842

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96200514T Expired - Lifetime ES2133888T3 (es) 1995-03-13 1996-02-28 Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno.

Country Status (13)

Country Link
US (1) US6013595A (es)
EP (1) EP0733650B1 (es)
JP (1) JPH08259618A (es)
KR (1) KR960034232A (es)
CN (1) CN1156729A (es)
AT (1) ATE179995T1 (es)
BE (1) BE1009186A3 (es)
BR (1) BR9600991A (es)
CA (1) CA2170805A1 (es)
DE (1) DE69602391T2 (es)
ES (1) ES2133888T3 (es)
RU (1) RU2162091C2 (es)
TW (1) TW368506B (es)

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Publication number Priority date Publication date Assignee Title
BE1010715A3 (fr) * 1996-10-25 1998-12-01 Solvay Copolymere d'ethylene et d'au moins une alpha-olefine et procede pour son obtention.
GB9712663D0 (en) 1997-06-16 1997-08-20 Borealis As Process
NO980552D0 (no) * 1998-02-09 1998-02-09 Borealis As Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
NO981631L (no) * 1998-04-08 1999-10-11 Borealis As Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne
US6465385B1 (en) 1999-02-12 2002-10-15 Sunoco, Inc. (R&M) Zwitterionic polymerization catalyst
US6653254B1 (en) * 1999-02-22 2003-11-25 Fina Technology, Inc Ziegler-Natta catalyst with metallocene for olefin polymerization
US6355594B1 (en) * 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6750302B1 (en) * 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
KR100377287B1 (ko) * 2000-05-29 2003-03-26 삼성종합화학주식회사 에틸렌 중합 방법
EP1368119A4 (en) * 2001-01-16 2010-11-03 Exxonmobil Chem Patents Inc POLYMERIZATION PROCESS WITH MIXED CATALYST COMPOSITIONS
US7381778B2 (en) 2002-06-06 2008-06-03 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7192901B2 (en) * 2004-10-27 2007-03-20 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7223823B2 (en) * 2002-06-06 2007-05-29 Exxon Mobil Chemical Patents Inc. Catalyst system and process
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
US7151145B1 (en) * 2005-07-13 2006-12-19 Equistar Chemicals, Lp Process for narrowing short-chain branching distribution in two-step ethylene polymerizations and products
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
US8258246B2 (en) * 2008-01-31 2012-09-04 Fina Technology, Inc. Preparation of supported chromium catalyst and polymerization process
CA2713042C (en) 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
CA2740755C (en) 2011-05-25 2019-01-15 Nova Chemicals Corporation Chromium catalysts for olefin polymerization
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
KR101483247B1 (ko) 2013-04-23 2015-01-16 주식회사 엘지화학 폴리올레핀 중합용 촉매의 제조 방법 및 폴리올레핀 제조방법
CA2870027C (en) 2014-11-07 2022-04-26 Matthew Zaki Botros Blow molding composition and process
CN107434831B (zh) * 2016-05-27 2020-02-18 中国石油化工股份有限公司 铬系催化剂组分及其制备方法和铬系催化剂
US10391226B2 (en) * 2017-02-07 2019-08-27 International Business Machines Corporation Air bubble removal from extracorporeal blood via chemical entrapment of nitrogen
MX2022012093A (es) 2020-04-07 2022-10-13 Nova Chem Int Sa Polietileno de alta densidad para articulos rigidos.
CN113804785B (zh) * 2021-09-16 2023-03-21 杭州普洛赛斯检测科技有限公司 一种气相色谱-质谱联用检测尿素的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4424139A (en) * 1982-03-30 1984-01-03 Phillips Petroleum Company Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
NO172242C (no) * 1988-04-26 1993-06-23 Showa Denko Kk Fremgangsmaate for fremstilling av etylenpolymerer
EP0513380B2 (en) * 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Process for producing olefinic polymer
CA2060019A1 (en) * 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
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BE1006880A3 (fr) * 1993-03-01 1995-01-17 Solvay Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
JP3423378B2 (ja) * 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system

Also Published As

Publication number Publication date
EP0733650B1 (fr) 1999-05-12
DE69602391D1 (de) 1999-06-17
US6013595A (en) 2000-01-11
CA2170805A1 (fr) 1996-09-14
EP0733650A1 (fr) 1996-09-25
TW368506B (en) 1999-09-01
JPH08259618A (ja) 1996-10-08
KR960034232A (ko) 1996-10-22
DE69602391T2 (de) 1999-12-16
ATE179995T1 (de) 1999-05-15
CN1156729A (zh) 1997-08-13
RU2162091C2 (ru) 2001-01-20
BR9600991A (pt) 1997-12-30
BE1009186A3 (fr) 1996-12-03

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