RU2068425C1 - Вулканизирующаяся смесь на основе фторэластомера, содержащего атомы брома и/или иода в полимерной цепи - Google Patents
Вулканизирующаяся смесь на основе фторэластомера, содержащего атомы брома и/или иода в полимерной цепи Download PDFInfo
- Publication number
- RU2068425C1 RU2068425C1 SU904830797A SU4830797A RU2068425C1 RU 2068425 C1 RU2068425 C1 RU 2068425C1 SU 904830797 A SU904830797 A SU 904830797A SU 4830797 A SU4830797 A SU 4830797A RU 2068425 C1 RU2068425 C1 RU 2068425C1
- Authority
- RU
- Russia
- Prior art keywords
- peroxide
- different
- parts
- same
- alkyls
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 229920001973 fluoroelastomer Polymers 0.000 title claims abstract description 19
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 11
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title claims abstract description 11
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 229910052794 bromium Inorganic materials 0.000 title claims abstract description 11
- 229920000642 polymer Polymers 0.000 title claims abstract description 6
- 150000002978 peroxides Chemical class 0.000 claims abstract description 37
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- -1 1-ethyl-1-methylpropyl Chemical group 0.000 claims abstract description 11
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 10
- FGHPXAKHUFZDRY-UHFFFAOYSA-N 3-ethyl-3-(3-ethylpentan-3-ylperoxy)pentane Chemical compound CCC(CC)(CC)OOC(CC)(CC)CC FGHPXAKHUFZDRY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 3
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 claims abstract 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 6
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 claims description 5
- VQGABIYDHNEEEC-UHFFFAOYSA-N 3-methyl-3-(3-methylpentan-3-ylperoxy)pentane Chemical compound CCC(C)(CC)OOC(C)(CC)CC VQGABIYDHNEEEC-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- 238000004073 vulcanization Methods 0.000 abstract description 21
- 229920001971 elastomer Polymers 0.000 abstract description 13
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 abstract description 12
- 239000000806 elastomer Substances 0.000 abstract description 11
- 229910052740 iodine Inorganic materials 0.000 abstract description 7
- 239000011630 iodine Substances 0.000 abstract description 7
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract description 6
- 229940102396 methyl bromide Drugs 0.000 abstract description 6
- 231100000331 toxic Toxicity 0.000 abstract description 5
- 230000002588 toxic effect Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- KKDHWGOHWGLLPR-UHFFFAOYSA-N 1,1-bis(sulfanylidene)-3h-1,3-benzothiazole-2-thione Chemical compound C1=CC=C2S(=S)(=S)C(S)=NC2=C1 KKDHWGOHWGLLPR-UHFFFAOYSA-N 0.000 abstract 1
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 abstract 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 239000007789 gas Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 6
- 238000005481 NMR spectroscopy Methods 0.000 description 5
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 5
- 238000004949 mass spectrometry Methods 0.000 description 5
- 239000012074 organic phase Substances 0.000 description 5
- 238000004448 titration Methods 0.000 description 5
- FRDAATYAJDYRNW-UHFFFAOYSA-N 3-methyl-3-pentanol Chemical compound CCC(C)(O)CC FRDAATYAJDYRNW-UHFFFAOYSA-N 0.000 description 4
- 238000004587 chromatography analysis Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000012043 crude product Substances 0.000 description 4
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 3
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- XKIRHOWVQWCYBT-UHFFFAOYSA-N 3-ethylpentan-3-ol Chemical compound CCC(O)(CC)CC XKIRHOWVQWCYBT-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229920006027 ternary co-polymer Polymers 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- AQIXEPGDORPWBJ-UHFFFAOYSA-N pentan-3-ol Chemical compound CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- SEGIXENNYFRFKP-UHFFFAOYSA-N 2,5-dihydroperoxyhexane Chemical compound OOC(C)CCC(C)OO SEGIXENNYFRFKP-UHFFFAOYSA-N 0.000 description 1
- TUAPLLGBMYGPST-UHFFFAOYSA-N 2,5-dimethyl-2,5-bis(2-methylbutan-2-ylperoxy)hexane Chemical compound CCC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)CC TUAPLLGBMYGPST-UHFFFAOYSA-N 0.000 description 1
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 1
- BWMWVYKKWYNWMF-UHFFFAOYSA-N 3-hydroperoxy-3-methylpentane Chemical compound CCC(C)(CC)OO BWMWVYKKWYNWMF-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010060 peroxide vulcanization Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- NFJPDTZIGCKLTM-UHFFFAOYSA-N s-(1,3-benzothiazol-2-yl)thiohydroxylamine;morpholine Chemical compound C1COCCN1.C1=CC=C2SC(SN)=NC2=C1 NFJPDTZIGCKLTM-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT21277A/89 | 1989-07-24 | ||
IT8921277A IT1231174B (it) | 1989-07-24 | 1989-07-24 | Mescole vulcanizzabili di fluoroelastomeri contenenti bromo o iodio e di perossidi organici |
Publications (1)
Publication Number | Publication Date |
---|---|
RU2068425C1 true RU2068425C1 (ru) | 1996-10-27 |
Family
ID=11179417
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU904830797A RU2068425C1 (ru) | 1989-07-24 | 1990-07-23 | Вулканизирующаяся смесь на основе фторэластомера, содержащего атомы брома и/или иода в полимерной цепи |
Country Status (12)
Country | Link |
---|---|
US (1) | US5153272A (zh) |
EP (1) | EP0410351B1 (zh) |
JP (1) | JP3053849B2 (zh) |
CN (1) | CN1027377C (zh) |
AT (1) | ATE115164T1 (zh) |
AU (1) | AU630480B2 (zh) |
CA (1) | CA2021639A1 (zh) |
DE (2) | DE69014746T2 (zh) |
ES (1) | ES2066055T3 (zh) |
IT (1) | IT1231174B (zh) |
RU (1) | RU2068425C1 (zh) |
ZA (1) | ZA905741B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2539009C2 (ru) * | 2009-10-01 | 2015-01-10 | Асахи Гласс Компани, Лимитед | Сшиваемая фторкаучуковая композиция и сшитое каучуковое изделие |
Families Citing this family (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5219964A (en) * | 1989-07-10 | 1993-06-15 | Ausimont S.R.L. | Fluoroelastomers endowed with improved processability and process for preparing them |
JPH03157439A (ja) * | 1989-11-14 | 1991-07-05 | Nippon Mektron Ltd | 架橋性含フッ素エラストマー組成物 |
DE4006058A1 (de) * | 1990-02-26 | 1991-08-29 | Luperox Gmbh | Vernetzung von fluorkautschuk mittels vernetzungsinitiatoren, die keine methyl- oder phenyl-radikale bilden |
JP3046375B2 (ja) * | 1991-03-27 | 2000-05-29 | 日本油脂株式会社 | 加硫用ゴム組成物 |
US5447985A (en) * | 1993-10-28 | 1995-09-05 | Akzo Nobel N.V. | Modification of (CO)polymers with unsaturated peroxyacids |
IT1265461B1 (it) * | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
IT1269514B (it) * | 1994-05-18 | 1997-04-01 | Ausimont Spa | Fluoroelastomeri vulcanizzabili per via perossidica,particolarmente adatti per la fabbricazione di o-ring |
IT1273608B (it) * | 1995-04-28 | 1997-07-08 | Ausimont Spa | Fluoroelastomeri sostanzialmente privi di terminali polari e relativo processo di preparazione |
IT1277445B1 (it) * | 1995-08-04 | 1997-11-10 | Ausimont Spa | Composizioni vulcanizzabili di fluoroelastomeri contenenti bromo |
IT1276980B1 (it) * | 1995-10-20 | 1997-11-03 | Ausimont Spa | Composizioni fluoroelastomeriche |
IT1276979B1 (it) * | 1995-10-20 | 1997-11-03 | Ausimont Spa | Composizioni fluoroelastomeriche |
IT1302986B1 (it) * | 1997-02-11 | 2000-10-18 | Ausimont Spa | Blends di elastomeri fluorurati e acrilici |
IT1301780B1 (it) | 1998-06-23 | 2000-07-07 | Ausimont Spa | Fluoroelastomeri vulcanizzabili per via perossidica |
CN100448897C (zh) * | 1998-08-06 | 2009-01-07 | 阿克佐诺贝尔公司 | 二烷基过氧化物化合物以及用其引发化学反应的方法 |
IT1302016B1 (it) | 1998-08-11 | 2000-07-20 | Ausimont Spa | Fluoroelastomeri. |
IT1308628B1 (it) * | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
IT1308627B1 (it) | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
US7534845B2 (en) | 2000-04-21 | 2009-05-19 | Solvay Solexis S.P.A. | Fluorovinyl ethers and polymers obtainable therefrom |
IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
IT1318487B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluoroelastomeri. |
IT1318593B1 (it) | 2000-06-23 | 2003-08-27 | Ausimont Spa | Ionomeri fluorurati. |
ITMI20010384A1 (it) | 2001-02-26 | 2002-08-26 | Ausimont Spa | Membrane idrofiliche porose |
ITMI20010383A1 (it) | 2001-02-26 | 2002-08-26 | Ausimont Spa | Membrane idrofiliche porose |
ITMI20011062A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011059A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011061A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011060A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011745A1 (it) | 2001-08-09 | 2003-02-09 | Ausimont Spa | Processo per impregnare supporti |
ITMI20012164A1 (it) | 2001-10-18 | 2003-04-18 | Ausimont Spa | Fluoroelastomeri |
ITMI20012165A1 (it) | 2001-10-18 | 2003-04-18 | Ausimont Spa | Perfluoroelastomeri |
ITMI20040789A1 (it) | 2004-04-22 | 2004-07-22 | Solvay Solexis Spa | Membrane fluorurate |
ITMI20041253A1 (it) | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Gel di fluoroelastomeri |
ITMI20041252A1 (it) | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Composizioni perfluoroelastomeriche |
ITMI20041573A1 (it) | 2004-07-30 | 2006-01-31 | Solvay Solexis Spa | Fluoroelastomeri |
ITMI20041571A1 (it) | 2004-07-30 | 2004-10-30 | Solvay Solexis Spa | Perfluoroelastomeri |
ITMI20052509A1 (it) | 2005-12-28 | 2007-06-29 | Solvay Solexis Spa | Assemblati per dispositivi elettrochimici |
ITMI20052508A1 (it) | 2005-12-28 | 2007-06-29 | Solvay Solexis Spa | Processo per ottenere ccm con subgasket |
EP2014707B1 (en) * | 2007-07-12 | 2014-04-23 | Borealis Technology Oy | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
WO2009027213A1 (en) | 2007-08-29 | 2009-03-05 | Solvay Solexis S.P.A. | (per)fluoroelastomeric compositions |
KR101643423B1 (ko) | 2007-11-22 | 2016-07-27 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 가황성 플루오로엘라스토머 조성물 |
EP2065441A1 (en) | 2007-11-30 | 2009-06-03 | Solvay Solexis S.p.A. | Fluoroelastomer composition |
EP2373735B1 (en) | 2008-12-05 | 2015-04-01 | Solvay Specialty Polymers Italy S.p.A. | Vulcanized (per)fluoroelastomer sealing articles |
EP2194094A1 (en) | 2008-12-08 | 2010-06-09 | Solvay Solexis S.p.A. | (Per)fluoroelastomer composition |
CN104014250A (zh) | 2009-04-06 | 2014-09-03 | 恩特格里斯公司 | 微孔膜复合体 |
US9260543B2 (en) | 2009-12-18 | 2016-02-16 | Solvay Specialty Polymers Italy S.P.A. | Method for manufacturing fluoroelastomers |
KR101959473B1 (ko) | 2010-03-17 | 2019-03-18 | 보레알리스 아게 | 유리한 전기적 특성을 갖는 와이어 및 케이블 용도의 중합체 조성물 |
CA2792989C (en) | 2010-03-17 | 2018-08-14 | Borealis Ag | Polymer composition for w&c application with advantageous electrical properties |
KR101853987B1 (ko) | 2010-07-14 | 2018-05-02 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로 엘라스토머 조성물 |
TWI523900B (zh) | 2010-07-20 | 2016-03-01 | 首威索勒希斯股份有限公司 | 氟彈性體組合物 |
WO2012010640A1 (en) | 2010-07-22 | 2012-01-26 | Borealis Ag | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
WO2012049093A1 (en) | 2010-10-15 | 2012-04-19 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomers |
US9458272B2 (en) | 2010-12-20 | 2016-10-04 | Solvay Specialty Polymers Italy S.P.A. | Low viscosity fluoroelastomers |
EP2705061B1 (en) | 2011-05-03 | 2017-02-01 | Solvay Specialty Polymers Italy S.p.A. | Method for manufacturing fluoroelastomers |
US9688786B2 (en) | 2011-06-09 | 2017-06-27 | Solvay Specialty Polymers Italy S.P.A. | Hyperbranched fluoroelastomer additive |
US9518178B2 (en) | 2011-08-17 | 2016-12-13 | Solvay Specialty Polymers Italy S.P.A. | Milling process |
JP2015512963A (ja) | 2012-02-03 | 2015-04-30 | グリーン, ツイード テクノロジーズ, インコーポレイテッド | 急速ガス減圧耐性フルオロエラストマー組成物および成型品 |
WO2017102818A1 (en) | 2015-12-14 | 2017-06-22 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer compositions |
CN108884198A (zh) | 2016-03-11 | 2018-11-23 | 索尔维特殊聚合物意大利有限公司 | 用于固化氟弹性体组合物的多不饱和化合物 |
US20200299467A1 (en) | 2016-03-24 | 2020-09-24 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer composition |
WO2018015234A1 (en) | 2016-07-18 | 2018-01-25 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer composition |
CN106397291A (zh) * | 2016-09-08 | 2017-02-15 | 沈阳化工大学 | 一种用于高温交联的引发剂及其制备方法 |
CN109890893B (zh) | 2016-10-27 | 2022-01-28 | 索尔维特殊聚合物意大利有限公司 | 氟弹性体组合物 |
WO2019137920A1 (en) | 2018-01-10 | 2019-07-18 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer curable composition |
WO2019155073A1 (en) | 2018-02-12 | 2019-08-15 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer curable composition |
US20210252769A1 (en) | 2018-05-17 | 2021-08-19 | Solvay Specialty Polymers Italy S.P.A. | Heat-shrinkable article |
US20220002505A1 (en) | 2018-10-31 | 2022-01-06 | Solvay Specialty Polymers Italy S.P.A. | Curable composition of elastomers |
WO2021099336A1 (en) | 2019-11-22 | 2021-05-27 | Solvay Specialty Polymers Italy S.P.A. | Method for improving coefficient of friction in cured fluororubber parts |
WO2021123114A1 (en) | 2019-12-18 | 2021-06-24 | Solvay Specialty Polymers Italy S.P.A. | Base-resistant fluoroelastomer composition |
WO2024200225A1 (en) | 2023-03-27 | 2024-10-03 | Solvay Specialty Polymers Italy S.P.A. | Curable fluoroelastomer composition |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA553191A (en) * | 1958-02-11 | Hercules Powder Company | Polyethylene composition and process of cross-linking | |
US2965619A (en) * | 1953-04-03 | 1960-12-20 | Minnesota Mining & Mfg | Cross-linking of fluorinated elastomers |
DE1283520B (de) * | 1957-05-20 | 1968-11-21 | Hercules Inc | Verfahren zur Verbesserung der Eigenschaften von vernetzten AEthylenpolymerisaten |
US2999854A (en) * | 1958-07-31 | 1961-09-12 | Minnesota Mining & Mfg | Fluorinated elastomers and cross linking thereof |
NL126833C (zh) * | 1959-01-14 | |||
DE1203278B (de) * | 1963-02-01 | 1965-10-21 | Knoll Ag | Verfahren zur Herstellung von cyclischen organischen Peroxyden |
DE1208487B (de) * | 1963-02-16 | 1966-01-05 | Dynamit Nobel Ag | Verfahren zur Vernetzung von Polyolefinen |
DE1544735A1 (de) * | 1963-02-16 | 1969-07-17 | Dynamit Nobel Ag | Verfahren zur Vernetzung von Polyolefinen,wie Polyaethylen |
US3299019A (en) * | 1963-03-26 | 1967-01-17 | Du Pont | Dehydrofluorination of a copolymer of trifluoromethyl vinyl ether and tetrafluoroethylene |
US3449191A (en) * | 1964-02-03 | 1969-06-10 | Boeing Co | Polymer bonding process and product |
US3654216A (en) * | 1970-02-25 | 1972-04-04 | Us Air Force | High strength fluorocarbon elastomer compositions |
US4035565A (en) * | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
JPS5920310A (ja) * | 1982-07-27 | 1984-02-02 | Daikin Ind Ltd | 含フッ素ポリマー硬化用組成物 |
US4774293A (en) * | 1985-06-26 | 1988-09-27 | Akzo N.V. | Process for cross-linking or degrading polymers and shaped articles obtained by this process |
JPS62260807A (ja) * | 1986-05-07 | 1987-11-13 | Nippon Mektron Ltd | 含フッ素重合体の製造方法 |
IT1197929B (it) * | 1986-10-29 | 1988-12-21 | Ausimont Spa | Composizione perossidiche liquide |
JP2665947B2 (ja) * | 1988-08-03 | 1997-10-22 | 日本メクトロン株式会社 | 架橋性含フッ素エラストマー組成物 |
-
1989
- 1989-07-24 IT IT8921277A patent/IT1231174B/it active
-
1990
- 1990-07-20 ZA ZA905741A patent/ZA905741B/xx unknown
- 1990-07-20 CA CA002021639A patent/CA2021639A1/en not_active Abandoned
- 1990-07-23 EP EP90114081A patent/EP0410351B1/en not_active Expired - Lifetime
- 1990-07-23 DE DE69014746T patent/DE69014746T2/de not_active Expired - Fee Related
- 1990-07-23 US US07/555,636 patent/US5153272A/en not_active Expired - Lifetime
- 1990-07-23 ES ES90114081T patent/ES2066055T3/es not_active Expired - Lifetime
- 1990-07-23 AU AU59735/90A patent/AU630480B2/en not_active Ceased
- 1990-07-23 AT AT90114081T patent/ATE115164T1/de not_active IP Right Cessation
- 1990-07-23 DE DE199090114081T patent/DE410351T1/de active Pending
- 1990-07-23 RU SU904830797A patent/RU2068425C1/ru active
- 1990-07-24 CN CN90104818A patent/CN1027377C/zh not_active Expired - Fee Related
- 1990-07-24 JP JP2196037A patent/JP3053849B2/ja not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
Патент США N 4035565, кл. C 08 F 214/16, 1977. * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2539009C2 (ru) * | 2009-10-01 | 2015-01-10 | Асахи Гласс Компани, Лимитед | Сшиваемая фторкаучуковая композиция и сшитое каучуковое изделие |
Also Published As
Publication number | Publication date |
---|---|
EP0410351B1 (en) | 1994-12-07 |
DE69014746D1 (de) | 1995-01-19 |
ZA905741B (en) | 1991-05-29 |
CA2021639A1 (en) | 1991-01-25 |
IT8921277A0 (it) | 1989-07-24 |
AU5973590A (en) | 1991-01-24 |
DE69014746T2 (de) | 1995-04-27 |
DE410351T1 (de) | 1991-07-04 |
US5153272A (en) | 1992-10-06 |
EP0410351A1 (en) | 1991-01-30 |
ATE115164T1 (de) | 1994-12-15 |
ES2066055T3 (es) | 1995-03-01 |
CN1049019A (zh) | 1991-02-06 |
AU630480B2 (en) | 1992-10-29 |
IT1231174B (it) | 1991-11-22 |
JPH0359057A (ja) | 1991-03-14 |
CN1027377C (zh) | 1995-01-11 |
JP3053849B2 (ja) | 2000-06-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2068425C1 (ru) | Вулканизирующаяся смесь на основе фторэластомера, содержащего атомы брома и/или иода в полимерной цепи | |
US5061759A (en) | Processing-coadjuvating additives for rubbers vulcanizable by means of peroxides | |
US4564662A (en) | Fluorocarbon elastomer | |
US5026786A (en) | Perfluoropolyethers having brominated end groups and fluoroelastomers obtained therefrom | |
JP2005506391A (ja) | フルオロポリマー組成物 | |
JPH0931283A (ja) | 含フッ素エラストマー組成物 | |
WO1998054259A1 (fr) | Composition d'elastomere contenant du fluor | |
JP2002544330A (ja) | フルオロアルカンスルホニルアジドモノマーおよびその共重合体 | |
US5155282A (en) | Perfluoropolyethers having brominated end groups and fluoroelastomers obtained therefrom | |
EP0187893B1 (en) | Peroxide-curable brominated or iodinated fluoroelastomer composition containing an n,n,n',n'-tetrasubstituted 1,8-diaminonaphthalene | |
EP0373973B1 (en) | Additives for curing fluoroelastomers containing bromine or iodine | |
CA1246791A (en) | Peroxide-curable brominated fluoroelastomer composition containing an n,n,n',n'-tetrasubstituted 1,8-diaminonaphthalene | |
EP0251285B1 (en) | Curable compositions based on fluoroelastomers vulcanizable with peroxides | |
EP0607457A1 (en) | Vulcanizing fluororubber composition | |
CA1304409C (en) | Oligomeric amine and phenolic antidegradants | |
EP0506105A2 (en) | Vulcanizable rubber composition | |
JPH06331040A (ja) | オイルシール | |
US6207776B1 (en) | Peroxidic compositions | |
RU2002767C1 (ru) | Резинова смесь на основе ненасыщенного каучука | |
JPH03200850A (ja) | クロロプレンゴム加硫組成物 |