DE410351T1 - Haertbare mischungen aus brom- oder jodhaltigen fluorelastomeren und organischen peroxiden. - Google Patents
Haertbare mischungen aus brom- oder jodhaltigen fluorelastomeren und organischen peroxiden.Info
- Publication number
- DE410351T1 DE410351T1 DE199090114081T DE90114081T DE410351T1 DE 410351 T1 DE410351 T1 DE 410351T1 DE 199090114081 T DE199090114081 T DE 199090114081T DE 90114081 T DE90114081 T DE 90114081T DE 410351 T1 DE410351 T1 DE 410351T1
- Authority
- DE
- Germany
- Prior art keywords
- alkyl groups
- peroxide
- different
- same
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title 1
- 229920001971 elastomer Polymers 0.000 title 1
- 239000000806 elastomer Substances 0.000 title 1
- 229910052740 iodine Inorganic materials 0.000 title 1
- 239000011630 iodine Substances 0.000 title 1
- 150000001451 organic peroxides Chemical class 0.000 title 1
- 150000002978 peroxides Chemical class 0.000 claims abstract 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 3
- VQGABIYDHNEEEC-UHFFFAOYSA-N 3-methyl-3-(3-methylpentan-3-ylperoxy)pentane Chemical compound CCC(C)(CC)OOC(C)(CC)CC VQGABIYDHNEEEC-UHFFFAOYSA-N 0.000 claims 3
- FGHPXAKHUFZDRY-UHFFFAOYSA-N 3-ethyl-3-(3-ethylpentan-3-ylperoxy)pentane Chemical compound CCC(CC)(CC)OOC(CC)(CC)CC FGHPXAKHUFZDRY-UHFFFAOYSA-N 0.000 claims 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- -1 1,1-diethylpropyl Chemical group 0.000 claims 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 claims 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical group CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 claims 1
- LNGPDTPLWLXXEE-UHFFFAOYSA-N 3-(5,5-diethyl-3,4-dimethylheptan-3-yl)peroxy-5,5-diethyl-3,4-dimethylheptane Chemical compound CCC(CC)(CC)C(C)C(C)(CC)OOC(C)(CC)C(C)C(CC)(CC)CC LNGPDTPLWLXXEE-UHFFFAOYSA-N 0.000 claims 1
- 244000309464 bull Species 0.000 claims 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 229920001973 fluoroelastomer Polymers 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 229940102396 methyl bromide Drugs 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Claims (1)
- PATENTANS PRÜCHER-C-O-O-C-R1- (I)worin
R1 und Rg, die gleich oder voneinander verschieden sind, C2-C4-Alkylgruppen bedeuten, R3 und R4, die gleich oder voneinander verschieden sind, C1-C4-Alkylgruppen bedeuten, R2 und R5, die gleich oder voneinander verschieden sind, C1~C4-Alkylgruppen oder Phenylgruppen, die gegebenenfalls mit C1-C4-Alkylgruppen substituiert sind, bedeuten;und Bisperoxiden der allgemeinen Formel (II) ausgewählt sind:
25R8 ,11 C-R7- C -
IO O 1 I O O 1 • i"R15 Rl 2-<rF R16 R14 R10(IDworinRn C-i-Cc-Alkylen, Cn-C^-Alkenylen, C^-O-Alkinylen oder Phenylen bedeutet,Ro, Rg, R10 und R11, die gleich oder voneinander verschieden sind, C1-C3-Alkylgruppen bedeuten, R13 und R15, die gleich oder voneinander verschiedensind, C2-C4-Alylgruppen bedeuten,R12, R14, R16 und R17, die gleich oder voneinander verschieden sind, C1-C4-Alkylgruppen bedeuten, mit der Maßgabe, daß, wenn R7 Phenylen ist, R8 und R11, die gleich oder voneinander verschieden sind, C2-C4- ) Alkylgruppen bedeuten.2- Mischungen gemäß Anspruch 1, worin das Peroxid aus Bis(l,ldimethylpropyl)peroxid, Bis(1,1-diethylpropyl)peroxid, Bis(lethyl-1-methylpropyl)peroxid, 1,1-Diethylpropyl, 1-ethyl-lmethylpropylperoxid, 2,5-Dimethyl-2,5-di-t-amylperoxy-hexan und Mischungen derselben ausgewählt ist.3. Mischungen gemäß irgendeinem der Ansprüche 1 und 2, die ferner, vorzugsweise in Mengen von 0,1 bis 1 Gew.-Teil, Benzothiazol oder dessen Derivate, insbesondere Mercaptobenzothiazoldisulfid, enthalten.4- Mischungen gemäß irgendeinem der Ansprüche 1 bis 3, die, vorzugsweise in Mengen von 0,1 bis 2 Gew.-Teilen, N-Phenylmaleimid enthalten.5. Bis(1,1-diethylpropyl)peroxid.
256. Bis(1-ethyl-I-methylpropyl)peroxid.7. 1, 1-Diethylpropyl- 1-ethyl- 1-methylpropyl- peroxid. 8.2,5-Dimethyl-2,5-di-t-amylperoxy-hexan.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT8921277A IT1231174B (it) | 1989-07-24 | 1989-07-24 | Mescole vulcanizzabili di fluoroelastomeri contenenti bromo o iodio e di perossidi organici |
Publications (1)
Publication Number | Publication Date |
---|---|
DE410351T1 true DE410351T1 (de) | 1991-07-04 |
Family
ID=11179417
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69014746T Expired - Fee Related DE69014746T2 (de) | 1989-07-24 | 1990-07-23 | Härtbare Mischungen aus brom- oder jodhaltigen Fluorelastomeren und organischen Peroxiden. |
DE199090114081T Pending DE410351T1 (de) | 1989-07-24 | 1990-07-23 | Haertbare mischungen aus brom- oder jodhaltigen fluorelastomeren und organischen peroxiden. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69014746T Expired - Fee Related DE69014746T2 (de) | 1989-07-24 | 1990-07-23 | Härtbare Mischungen aus brom- oder jodhaltigen Fluorelastomeren und organischen Peroxiden. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5153272A (de) |
EP (1) | EP0410351B1 (de) |
JP (1) | JP3053849B2 (de) |
CN (1) | CN1027377C (de) |
AT (1) | ATE115164T1 (de) |
AU (1) | AU630480B2 (de) |
CA (1) | CA2021639A1 (de) |
DE (2) | DE69014746T2 (de) |
ES (1) | ES2066055T3 (de) |
IT (1) | IT1231174B (de) |
RU (1) | RU2068425C1 (de) |
ZA (1) | ZA905741B (de) |
Families Citing this family (70)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5219964A (en) * | 1989-07-10 | 1993-06-15 | Ausimont S.R.L. | Fluoroelastomers endowed with improved processability and process for preparing them |
JPH03157439A (ja) * | 1989-11-14 | 1991-07-05 | Nippon Mektron Ltd | 架橋性含フッ素エラストマー組成物 |
DE4006058A1 (de) * | 1990-02-26 | 1991-08-29 | Luperox Gmbh | Vernetzung von fluorkautschuk mittels vernetzungsinitiatoren, die keine methyl- oder phenyl-radikale bilden |
JP3046375B2 (ja) * | 1991-03-27 | 2000-05-29 | 日本油脂株式会社 | 加硫用ゴム組成物 |
US5447985A (en) * | 1993-10-28 | 1995-09-05 | Akzo Nobel N.V. | Modification of (CO)polymers with unsaturated peroxyacids |
IT1265461B1 (it) * | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
IT1269514B (it) | 1994-05-18 | 1997-04-01 | Ausimont Spa | Fluoroelastomeri vulcanizzabili per via perossidica,particolarmente adatti per la fabbricazione di o-ring |
IT1273608B (it) * | 1995-04-28 | 1997-07-08 | Ausimont Spa | Fluoroelastomeri sostanzialmente privi di terminali polari e relativo processo di preparazione |
IT1277445B1 (it) * | 1995-08-04 | 1997-11-10 | Ausimont Spa | Composizioni vulcanizzabili di fluoroelastomeri contenenti bromo |
IT1276979B1 (it) * | 1995-10-20 | 1997-11-03 | Ausimont Spa | Composizioni fluoroelastomeriche |
IT1276980B1 (it) * | 1995-10-20 | 1997-11-03 | Ausimont Spa | Composizioni fluoroelastomeriche |
IT1302986B1 (it) * | 1997-02-11 | 2000-10-18 | Ausimont Spa | Blends di elastomeri fluorurati e acrilici |
IT1301780B1 (it) | 1998-06-23 | 2000-07-07 | Ausimont Spa | Fluoroelastomeri vulcanizzabili per via perossidica |
JP2002522576A (ja) * | 1998-08-06 | 2002-07-23 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ジアルキルパーオキサイド化合物及び該化合物を化学反応を開始するために使用する方法 |
IT1302016B1 (it) | 1998-08-11 | 2000-07-20 | Ausimont Spa | Fluoroelastomeri. |
IT1308627B1 (it) | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
IT1308628B1 (it) | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
IT1318487B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluoroelastomeri. |
US7534845B2 (en) | 2000-04-21 | 2009-05-19 | Solvay Solexis S.P.A. | Fluorovinyl ethers and polymers obtainable therefrom |
IT1318593B1 (it) | 2000-06-23 | 2003-08-27 | Ausimont Spa | Ionomeri fluorurati. |
ITMI20010383A1 (it) | 2001-02-26 | 2002-08-26 | Ausimont Spa | Membrane idrofiliche porose |
ITMI20010384A1 (it) | 2001-02-26 | 2002-08-26 | Ausimont Spa | Membrane idrofiliche porose |
ITMI20011062A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011060A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011059A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011061A1 (it) | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011745A1 (it) | 2001-08-09 | 2003-02-09 | Ausimont Spa | Processo per impregnare supporti |
ITMI20012164A1 (it) | 2001-10-18 | 2003-04-18 | Ausimont Spa | Fluoroelastomeri |
ITMI20012165A1 (it) | 2001-10-18 | 2003-04-18 | Ausimont Spa | Perfluoroelastomeri |
ITMI20040789A1 (it) | 2004-04-22 | 2004-07-22 | Solvay Solexis Spa | Membrane fluorurate |
ITMI20041253A1 (it) | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Gel di fluoroelastomeri |
ITMI20041252A1 (it) * | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Composizioni perfluoroelastomeriche |
ITMI20041571A1 (it) | 2004-07-30 | 2004-10-30 | Solvay Solexis Spa | Perfluoroelastomeri |
ITMI20041573A1 (it) | 2004-07-30 | 2006-01-31 | Solvay Solexis Spa | Fluoroelastomeri |
ITMI20052509A1 (it) | 2005-12-28 | 2007-06-29 | Solvay Solexis Spa | Assemblati per dispositivi elettrochimici |
ITMI20052508A1 (it) | 2005-12-28 | 2007-06-29 | Solvay Solexis Spa | Processo per ottenere ccm con subgasket |
EP2014707B1 (de) * | 2007-07-12 | 2014-04-23 | Borealis Technology Oy | Modifizierte Polymerzusammensetzungen, Modifikationsverfahren und Wirkstoffe zur Erzeugung freier Radikale für I.A.-Draht und Kabelanwendungen |
US8242210B2 (en) | 2007-08-29 | 2012-08-14 | Solvay Solexis S.P.A. | (Per)fluoroelastomeric compositions |
WO2009065895A1 (en) | 2007-11-22 | 2009-05-28 | Solvay Solexis S.P.A. | Vulcanisable fluoroelastomeric compositions |
EP2065441A1 (de) | 2007-11-30 | 2009-06-03 | Solvay Solexis S.p.A. | Fluorelastomerzusammensetzung |
EP2373735B1 (de) | 2008-12-05 | 2015-04-01 | Solvay Specialty Polymers Italy S.p.A. | Dichtungsartikel aus vulkanisiertem (per)fluorelastomer |
EP2194094A1 (de) | 2008-12-08 | 2010-06-09 | Solvay Solexis S.p.A. | (Per)fluorelastomer-Zusammensetzung |
WO2010117845A2 (en) | 2009-04-06 | 2010-10-14 | Entegris, Inc. | Non-dewetting porous membranes |
JP5614551B2 (ja) * | 2009-10-01 | 2014-10-29 | 旭硝子株式会社 | 架橋性フッ素ゴム組成物および架橋ゴム物品 |
US9260543B2 (en) | 2009-12-18 | 2016-02-16 | Solvay Specialty Polymers Italy S.P.A. | Method for manufacturing fluoroelastomers |
US10208196B2 (en) | 2010-03-17 | 2019-02-19 | Borealis Ag | Polymer composition for W and C application with advantageous electrical properties |
KR20130016285A (ko) | 2010-03-17 | 2013-02-14 | 보레알리스 아게 | 유리한 전기적 특성을 갖는 와이어 및 케이블 용도의 중합체 조성물 |
KR101853987B1 (ko) | 2010-07-14 | 2018-05-02 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로 엘라스토머 조성물 |
TWI523900B (zh) | 2010-07-20 | 2016-03-01 | 首威索勒希斯股份有限公司 | 氟彈性體組合物 |
KR20130143003A (ko) | 2010-07-22 | 2013-12-30 | 보레알리스 아게 | 예를 들어, 와이어 및 케이블 어플리케이션을 위한 개질된 중합체 조성물, 개질 공정 및 자유 라디칼 생성제 |
WO2012049093A1 (en) | 2010-10-15 | 2012-04-19 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomers |
JP6333554B2 (ja) | 2010-12-20 | 2018-05-30 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | 低粘度フルオロエラストマー |
WO2012150256A1 (en) | 2011-05-03 | 2012-11-08 | Solvay Specialty Polymers Italy S.P.A. | Method for manufacturing fluoroelastomers |
JP6017550B2 (ja) | 2011-06-09 | 2016-11-02 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | 超分岐フルオロエラストマー添加剤 |
WO2013023983A1 (en) | 2011-08-17 | 2013-02-21 | Solvay Specialty Polymers Italy S.P.A. | Milling process |
WO2013116868A1 (en) | 2012-02-03 | 2013-08-08 | Greene, Tweed Of Delaware, Inc. | Rapid gas decompression-resistant fluoroelastomer compositions and molded articles |
CN108603001B (zh) | 2015-12-14 | 2021-03-12 | 索尔维特殊聚合物意大利有限公司 | 氟弹性体组合物 |
CN108884198A (zh) | 2016-03-11 | 2018-11-23 | 索尔维特殊聚合物意大利有限公司 | 用于固化氟弹性体组合物的多不饱和化合物 |
WO2017162656A1 (en) | 2016-03-24 | 2017-09-28 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer composition |
JP7005590B2 (ja) | 2016-07-18 | 2022-01-21 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | フルオロエラストマー組成物 |
CN106397291A (zh) * | 2016-09-08 | 2017-02-15 | 沈阳化工大学 | 一种用于高温交联的引发剂及其制备方法 |
US10899917B2 (en) | 2016-10-27 | 2021-01-26 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer composition |
WO2019137920A1 (en) | 2018-01-10 | 2019-07-18 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomer curable composition |
KR20200120925A (ko) | 2018-02-12 | 2020-10-22 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로엘라스토머 경화성 조성물 |
EP3794047A1 (de) | 2018-05-17 | 2021-03-24 | Solvay Specialty Polymers Italy S.p.A. | Wärmeschrumpfbarer artikel |
CN112912438B (zh) | 2018-10-31 | 2023-06-13 | 索尔维特殊聚合物意大利有限公司 | 弹性体的可固化组合物 |
WO2021099336A1 (en) | 2019-11-22 | 2021-05-27 | Solvay Specialty Polymers Italy S.P.A. | Method for improving coefficient of friction in cured fluororubber parts |
WO2021123114A1 (en) | 2019-12-18 | 2021-06-24 | Solvay Specialty Polymers Italy S.P.A. | Base-resistant fluoroelastomer composition |
WO2024200225A1 (en) | 2023-03-27 | 2024-10-03 | Solvay Specialty Polymers Italy S.P.A. | Curable fluoroelastomer composition |
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CA553191A (en) * | 1958-02-11 | Hercules Powder Company | Polyethylene composition and process of cross-linking | |
US2965619A (en) * | 1953-04-03 | 1960-12-20 | Minnesota Mining & Mfg | Cross-linking of fluorinated elastomers |
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US2999854A (en) * | 1958-07-31 | 1961-09-12 | Minnesota Mining & Mfg | Fluorinated elastomers and cross linking thereof |
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JPS62260807A (ja) * | 1986-05-07 | 1987-11-13 | Nippon Mektron Ltd | 含フッ素重合体の製造方法 |
IT1197929B (it) * | 1986-10-29 | 1988-12-21 | Ausimont Spa | Composizione perossidiche liquide |
JP2665947B2 (ja) * | 1988-08-03 | 1997-10-22 | 日本メクトロン株式会社 | 架橋性含フッ素エラストマー組成物 |
-
1989
- 1989-07-24 IT IT8921277A patent/IT1231174B/it active
-
1990
- 1990-07-20 CA CA002021639A patent/CA2021639A1/en not_active Abandoned
- 1990-07-20 ZA ZA905741A patent/ZA905741B/xx unknown
- 1990-07-23 AT AT90114081T patent/ATE115164T1/de not_active IP Right Cessation
- 1990-07-23 ES ES90114081T patent/ES2066055T3/es not_active Expired - Lifetime
- 1990-07-23 AU AU59735/90A patent/AU630480B2/en not_active Ceased
- 1990-07-23 EP EP90114081A patent/EP0410351B1/de not_active Expired - Lifetime
- 1990-07-23 DE DE69014746T patent/DE69014746T2/de not_active Expired - Fee Related
- 1990-07-23 DE DE199090114081T patent/DE410351T1/de active Pending
- 1990-07-23 RU SU904830797A patent/RU2068425C1/ru active
- 1990-07-23 US US07/555,636 patent/US5153272A/en not_active Expired - Lifetime
- 1990-07-24 JP JP2196037A patent/JP3053849B2/ja not_active Expired - Fee Related
- 1990-07-24 CN CN90104818A patent/CN1027377C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AU5973590A (en) | 1991-01-24 |
EP0410351A1 (de) | 1991-01-30 |
IT8921277A0 (it) | 1989-07-24 |
ATE115164T1 (de) | 1994-12-15 |
ZA905741B (en) | 1991-05-29 |
CA2021639A1 (en) | 1991-01-25 |
JP3053849B2 (ja) | 2000-06-19 |
JPH0359057A (ja) | 1991-03-14 |
EP0410351B1 (de) | 1994-12-07 |
IT1231174B (it) | 1991-11-22 |
ES2066055T3 (es) | 1995-03-01 |
US5153272A (en) | 1992-10-06 |
DE69014746T2 (de) | 1995-04-27 |
DE69014746D1 (de) | 1995-01-19 |
RU2068425C1 (ru) | 1996-10-27 |
CN1027377C (zh) | 1995-01-11 |
AU630480B2 (en) | 1992-10-29 |
CN1049019A (zh) | 1991-02-06 |
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