RU2009136169A - Фотополимерная композиция и ее применение для изготовления голографических сред - Google Patents

Фотополимерная композиция и ее применение для изготовления голографических сред Download PDF

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RU2009136169A
RU2009136169A RU2009136169/28A RU2009136169A RU2009136169A RU 2009136169 A RU2009136169 A RU 2009136169A RU 2009136169/28 A RU2009136169/28 A RU 2009136169/28A RU 2009136169 A RU2009136169 A RU 2009136169A RU 2009136169 A RU2009136169 A RU 2009136169A
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photopolymer composition
composition according
component
molecular weight
groups
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RU2515991C9 (ru
RU2515991C2 (ru
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Марк-Штефан ВАЙЗЕР (DE)
Марк-Штефан ВАЙЗЕР
Томас РЕЛЛЕ (DE)
Томас РЕЛЛЕ
Фридрих-Карл БРУДЕР (DE)
Фридрих-Карл БРУДЕР
Томас ФЭККЕ (DE)
Томас ФЭККЕ
Деннис ХЕНЕЛЬ (DE)
Деннис ХЕНЕЛЬ
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Байер МатириальСайенс АГ (DE)
Байер Матириальсайенс Аг
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Abstract

1. Фотополимерная композиция, включающая трехмерно-сшитые органические полимеры А) или их предшественники в качестве матрицы, а также соединения В), содержащие группы, которые при действии актиничного излучения реагируют с ненасыщенными соединениями с этиленовыми фрагментами с образованием полимеров (радиационно-отверждаемые группы) и которые растворены в этой матрице или находятся в ней в распределенном состоянии, а также компонент С), представляющий собой, по меньшей мере, один фотоинициатор, отличающаяся тем, что плотность полимерной сшивки органического полимера, выраженная через среднюю молекулярную массу МC двух сегментов, соединенных полимерными мостиками, составляет величину, по меньшей мере, 2685 г/моль. ! 2. Фотополимерная композиция по п.1, отличающаяся тем, что значения МC лежат в области от 7500 до 55000 г/моль. ! 3. Фотополимерная композиция по п.1, отличающаяся тем, что величина Q, равная отношению молекулярной массы MC к среднечисленной молекулярной массе MMo для соединений B), больше чем 3,30. ! 4. Фотополимерная композиция по п.1, отличающаяся тем, что соотношение Q больше чем 10,00. ! 5. Фотополимерная композиция по п.1, отличающаяся тем, что трехмерно-сшитые органические полимеры содержат уретановые группы. ! 6. Фотополимерная композиция по п.1, отличающаяся тем, что трехмерно-сшитые органические полимеры компонента A) образованы из изоцианатного компонента a) и реакционноспособного по отношению к изоцианатам компонента b). ! 7. Фотополимерная композиция по п.1, отличающаяся тем, что компонент А) включает изоцианатный компонент a) и реакционноспособный по отношению к изоцианатам компонент b). ! 8. Фотополимерная композ�

Claims (14)

1. Фотополимерная композиция, включающая трехмерно-сшитые органические полимеры А) или их предшественники в качестве матрицы, а также соединения В), содержащие группы, которые при действии актиничного излучения реагируют с ненасыщенными соединениями с этиленовыми фрагментами с образованием полимеров (радиационно-отверждаемые группы) и которые растворены в этой матрице или находятся в ней в распределенном состоянии, а также компонент С), представляющий собой, по меньшей мере, один фотоинициатор, отличающаяся тем, что плотность полимерной сшивки органического полимера, выраженная через среднюю молекулярную массу МC двух сегментов, соединенных полимерными мостиками, составляет величину, по меньшей мере, 2685 г/моль.
2. Фотополимерная композиция по п.1, отличающаяся тем, что значения МC лежат в области от 7500 до 55000 г/моль.
3. Фотополимерная композиция по п.1, отличающаяся тем, что величина Q, равная отношению молекулярной массы MC к среднечисленной молекулярной массе MMo для соединений B), больше чем 3,30.
4. Фотополимерная композиция по п.1, отличающаяся тем, что соотношение Q больше чем 10,00.
5. Фотополимерная композиция по п.1, отличающаяся тем, что трехмерно-сшитые органические полимеры содержат уретановые группы.
6. Фотополимерная композиция по п.1, отличающаяся тем, что трехмерно-сшитые органические полимеры компонента A) образованы из изоцианатного компонента a) и реакционноспособного по отношению к изоцианатам компонента b).
7. Фотополимерная композиция по п.1, отличающаяся тем, что компонент А) включает изоцианатный компонент a) и реакционноспособный по отношению к изоцианатам компонент b).
8. Фотополимерная композиция по п.6, отличающаяся тем, что компонент а) включает полиизоцианаты на основе HDI с изоциануратными и/или иминооксадиазиндионовыми структурами или преполимеры с NCO-функциональностью от 2 до 5 с аллофанатными и/или уретановыми структурами на основе HDI и/или TMDI и простых полиэфир-, сложных полиэфир- и/или поликарбонатполиолов.
9. Фотополимерная композиция по п.6, отличающаяся тем, что компонент b) включает полипропиленоксиды, полиэтиленоксиды и/или их комбинации в форме статистических или блок-сополимеров и/или блок-сополимеры вышеназванного вида, которые дополнительно содержат в качестве мономерных структурных единиц тетрагидрофуран, бутиленоксид или ε-капролактон, причем ОН-функциональность составляет от 1,5 до 6, а среднечисленная молекулярная масса составляет от 200 до 18000 г/моль.
10. Фотополимерная композиция по п.1, отличающаяся тем, что используемые в компоненте В) соединения имеют показатель преломления nD 20 больше чем 1,54.
11. Фотополимерная композиция по одному из пп.1-10, отличающаяся тем, что используемые в компоненте B) соединения в качестве радиационно-отверждаемых групп содержат акрилатные и/или метакрилатные группы.
12. Среда, подходящая для записи визуальных голограмм, которая может быть получена из фотополимерной композиции по одному из пп.1-11.
13. Применение среды по п.12 для записи визуальных голограмм или для изготовления оптических элементов, картинок, изображений.
14. Способ облучения среды по п.12, при котором записывающий мономер селективно полимеризуется под действием актиничного излучения.
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