PT96344B - Processo para a preparacao de catalisadores solidos e pre-polimeros para a polimerizacao de olefinas - Google Patents

Processo para a preparacao de catalisadores solidos e pre-polimeros para a polimerizacao de olefinas Download PDF

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Publication number
PT96344B
PT96344B PT96344A PT9634490A PT96344B PT 96344 B PT96344 B PT 96344B PT 96344 A PT96344 A PT 96344A PT 9634490 A PT9634490 A PT 9634490A PT 96344 B PT96344 B PT 96344B
Authority
PT
Portugal
Prior art keywords
ethylene
catalyst
particles
compound
support
Prior art date
Application number
PT96344A
Other languages
English (en)
Portuguese (pt)
Other versions
PT96344A (pt
Inventor
Jean-Claude Andre Bailly
Christine Jacqueline Chabrand
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of PT96344A publication Critical patent/PT96344A/pt
Publication of PT96344B publication Critical patent/PT96344B/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
PT96344A 1989-12-22 1990-12-21 Processo para a preparacao de catalisadores solidos e pre-polimeros para a polimerizacao de olefinas PT96344B (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8917403A FR2656315B1 (fr) 1989-12-22 1989-12-22 Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Publications (2)

Publication Number Publication Date
PT96344A PT96344A (pt) 1991-09-30
PT96344B true PT96344B (pt) 1998-06-30

Family

ID=9389118

Family Applications (1)

Application Number Title Priority Date Filing Date
PT96344A PT96344B (pt) 1989-12-22 1990-12-21 Processo para a preparacao de catalisadores solidos e pre-polimeros para a polimerizacao de olefinas

Country Status (18)

Country Link
EP (1) EP0435514B1 (fr)
JP (1) JPH04211405A (fr)
KR (1) KR910011921A (fr)
CN (1) CN1053432A (fr)
AT (1) ATE142655T1 (fr)
AU (1) AU647430B2 (fr)
CA (1) CA2032621A1 (fr)
DE (1) DE69028503T2 (fr)
ES (1) ES2091230T3 (fr)
FI (1) FI906299A (fr)
FR (1) FR2656315B1 (fr)
HU (1) HU208982B (fr)
MY (1) MY104605A (fr)
NO (1) NO176764C (fr)
PL (1) PL288413A1 (fr)
PT (1) PT96344B (fr)
SG (1) SG44342A1 (fr)
ZA (1) ZA9010047B (fr)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
EP0578838A1 (fr) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation
EP0609439B1 (fr) * 1992-05-28 1996-11-27 Idemitsu Petrochemical Co., Ltd. Procede de production de polyolefine
CA2127822A1 (fr) * 1993-07-13 1995-01-14 Yoshinori Morita Procede de polymerisation en phase gazeuse d'olefine
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
US6140432A (en) * 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
ES2135771T3 (es) * 1994-10-13 1999-11-01 Exxon Chemical Patents Inc Sistemas cataliticos de polimerizacion, su produccion y su uso.
JPH10511706A (ja) * 1994-10-13 1998-11-10 エクソン・ケミカル・パテンツ・インク 重合触媒系、それらの製造及び使用
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
JPH09309926A (ja) 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
US6187882B1 (en) * 1997-02-21 2001-02-13 Council Of Scientific & Industrial Research Process for polymerization of olefins
US5962360A (en) * 1997-03-27 1999-10-05 Council Of Scientific And Industrial Research Process for the preparation of a magnesium halide supported metallocene catalyst
EP0878483B1 (fr) * 1997-03-27 2008-03-12 Council of Scientific and Industrial Research Procédé pour la polymérisation et copolymérisation des oléfines
JP3322643B2 (ja) * 1998-10-19 2002-09-09 丸善石油化学株式会社 オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法
US6291613B1 (en) 1998-10-27 2001-09-18 Eastman Chemical Company Process for the polymerization of olefins
EP1522544B1 (fr) 1998-10-27 2008-03-12 Westlake Longview Corporation Technique de polymérisation d'olefines, polyéthylènes, films et articles produits à l'aide de ces polyéthylènes.
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6288181B1 (en) * 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
EP1194459B1 (fr) * 1999-06-25 2005-12-14 Eastman Chemical Company Procede de polymerisation d'olefines, polyolefines, et films et articles produits a partir de celles-ci
US6288182B1 (en) * 1999-10-12 2001-09-11 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization
DE19962129A1 (de) * 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
AU2003301539A1 (en) * 2002-10-23 2004-05-13 Mitsui Chemicals, Inc. Magnesium-containing carrier components and application thereof to olefin polymerization
KR102019467B1 (ko) 2015-12-23 2019-11-04 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2541683B1 (fr) * 1983-02-28 1986-05-09 Ato Chimie Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation

Also Published As

Publication number Publication date
AU6817490A (en) 1991-06-27
ATE142655T1 (de) 1996-09-15
ZA9010047B (en) 1992-08-26
JPH04211405A (ja) 1992-08-03
SG44342A1 (en) 1997-12-19
AU647430B2 (en) 1994-03-24
FR2656315B1 (fr) 1992-04-17
CN1053432A (zh) 1991-07-31
DE69028503D1 (de) 1996-10-17
EP0435514B1 (fr) 1996-09-11
EP0435514A3 (fr) 1991-07-10
MY104605A (en) 1994-04-30
HUT59424A (en) 1992-05-28
NO176764B (no) 1995-02-13
NO905440D0 (no) 1990-12-17
KR910011921A (ko) 1991-08-07
FI906299A0 (fi) 1990-12-20
PL288413A1 (en) 1992-02-10
NO176764C (no) 1995-05-24
HU208982B (en) 1994-02-28
DE69028503T2 (de) 1997-01-30
HU908439D0 (en) 1991-07-29
PT96344A (pt) 1991-09-30
CA2032621A1 (fr) 1991-06-23
ES2091230T3 (es) 1996-11-01
FI906299A (fi) 1991-06-23
FR2656315A1 (fr) 1991-06-28
NO905440L (no) 1991-06-24
EP0435514A2 (fr) 1991-07-03

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Effective date: 19910509

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Effective date: 19980327

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Effective date: 20060927