DE69028503T2 - Katalysator und Prepolymer für Polyolefinherstellung - Google Patents

Katalysator und Prepolymer für Polyolefinherstellung

Info

Publication number
DE69028503T2
DE69028503T2 DE69028503T DE69028503T DE69028503T2 DE 69028503 T2 DE69028503 T2 DE 69028503T2 DE 69028503 T DE69028503 T DE 69028503T DE 69028503 T DE69028503 T DE 69028503T DE 69028503 T2 DE69028503 T2 DE 69028503T2
Authority
DE
Germany
Prior art keywords
prepolymer
solid catalyst
catalyst
contacting
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69028503T
Other languages
English (en)
Other versions
DE69028503D1 (de
Inventor
Jean-Claude Andre Bailly
Christine Jacqueline Chabrand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of DE69028503D1 publication Critical patent/DE69028503D1/de
Application granted granted Critical
Publication of DE69028503T2 publication Critical patent/DE69028503T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
DE69028503T 1989-12-22 1990-12-13 Katalysator und Prepolymer für Polyolefinherstellung Expired - Fee Related DE69028503T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8917403A FR2656315B1 (fr) 1989-12-22 1989-12-22 Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Publications (2)

Publication Number Publication Date
DE69028503D1 DE69028503D1 (de) 1996-10-17
DE69028503T2 true DE69028503T2 (de) 1997-01-30

Family

ID=9389118

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69028503T Expired - Fee Related DE69028503T2 (de) 1989-12-22 1990-12-13 Katalysator und Prepolymer für Polyolefinherstellung

Country Status (18)

Country Link
EP (1) EP0435514B1 (de)
JP (1) JPH04211405A (de)
KR (1) KR910011921A (de)
CN (1) CN1053432A (de)
AT (1) ATE142655T1 (de)
AU (1) AU647430B2 (de)
CA (1) CA2032621A1 (de)
DE (1) DE69028503T2 (de)
ES (1) ES2091230T3 (de)
FI (1) FI906299A (de)
FR (1) FR2656315B1 (de)
HU (1) HU208982B (de)
MY (1) MY104605A (de)
NO (1) NO176764C (de)
PL (1) PL288413A1 (de)
PT (1) PT96344B (de)
SG (1) SG44342A1 (de)
ZA (1) ZA9010047B (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
EP0578838A1 (de) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung
EP0609439B1 (de) * 1992-05-28 1996-11-27 Idemitsu Petrochemical Co., Ltd. Verfahren zur herstellung von polyolefin
CA2127822A1 (en) * 1993-07-13 1995-01-14 Yoshinori Morita Process for gas phase polymerization of olefin
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
US6140432A (en) * 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
ES2135771T3 (es) * 1994-10-13 1999-11-01 Exxon Chemical Patents Inc Sistemas cataliticos de polimerizacion, su produccion y su uso.
JPH10511706A (ja) * 1994-10-13 1998-11-10 エクソン・ケミカル・パテンツ・インク 重合触媒系、それらの製造及び使用
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
JPH09309926A (ja) 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
US6187882B1 (en) * 1997-02-21 2001-02-13 Council Of Scientific & Industrial Research Process for polymerization of olefins
US5962360A (en) * 1997-03-27 1999-10-05 Council Of Scientific And Industrial Research Process for the preparation of a magnesium halide supported metallocene catalyst
EP0878483B1 (de) * 1997-03-27 2008-03-12 Council of Scientific and Industrial Research Verfahren zur Polymerisation und Copolymerisation von Olefinen
JP3322643B2 (ja) * 1998-10-19 2002-09-09 丸善石油化学株式会社 オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法
US6291613B1 (en) 1998-10-27 2001-09-18 Eastman Chemical Company Process for the polymerization of olefins
EP1522544B1 (de) 1998-10-27 2008-03-12 Westlake Longview Corporation Verfahren zur Polymerisierung von Olefine; Polyethylene, und Filme, und Gegenstände damit hergestellt
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6288181B1 (en) * 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
EP1194459B1 (de) * 1999-06-25 2005-12-14 Eastman Chemical Company Verfahren für die polymerisation von olefinen; polyolefine, und filme und daraus hergestellte gegenstaende
US6288182B1 (en) * 1999-10-12 2001-09-11 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization
DE19962129A1 (de) * 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
AU2003301539A1 (en) * 2002-10-23 2004-05-13 Mitsui Chemicals, Inc. Magnesium-containing carrier components and application thereof to olefin polymerization
KR102019467B1 (ko) 2015-12-23 2019-11-04 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2541683B1 (fr) * 1983-02-28 1986-05-09 Ato Chimie Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation

Also Published As

Publication number Publication date
AU6817490A (en) 1991-06-27
ATE142655T1 (de) 1996-09-15
ZA9010047B (en) 1992-08-26
JPH04211405A (ja) 1992-08-03
SG44342A1 (en) 1997-12-19
AU647430B2 (en) 1994-03-24
FR2656315B1 (fr) 1992-04-17
CN1053432A (zh) 1991-07-31
DE69028503D1 (de) 1996-10-17
EP0435514B1 (de) 1996-09-11
EP0435514A3 (de) 1991-07-10
MY104605A (en) 1994-04-30
PT96344B (pt) 1998-06-30
HUT59424A (en) 1992-05-28
NO176764B (no) 1995-02-13
NO905440D0 (no) 1990-12-17
KR910011921A (ko) 1991-08-07
FI906299A0 (fi) 1990-12-20
PL288413A1 (en) 1992-02-10
NO176764C (no) 1995-05-24
HU208982B (en) 1994-02-28
HU908439D0 (en) 1991-07-29
PT96344A (pt) 1991-09-30
CA2032621A1 (en) 1991-06-23
ES2091230T3 (es) 1996-11-01
FI906299A (fi) 1991-06-23
FR2656315A1 (fr) 1991-06-28
NO905440L (no) 1991-06-24
EP0435514A2 (de) 1991-07-03

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee