PL205846B1 - Kompozycja do stabilizacji termoplastycznego polimeru, sposób stabilizacji termoplastycznego polimeru i zastosowanie związków benzofuran-2-onu - Google Patents

Info

Publication number

PL205846B1

PL205846B1 PL355901A PL35590102A PL205846B1 PL 205846 B1 PL205846 B1 PL 205846B1 PL 355901 A PL355901 A PL 355901A PL 35590102 A PL35590102 A PL 35590102A PL 205846 B1 PL205846 B1 PL 205846B1

Authority

PL

Poland

Prior art keywords

tert

butyl

bis

copolymers

hydroxy

Prior art date

2001-09-11

Links

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• 229920000642 polymer Polymers 0.000 title description 34
• 230000006641 stabilisation Effects 0.000 title description 8
• 150000001875 compounds Chemical class 0.000 claims abstract description 50
• 239000003381 stabilizer Substances 0.000 claims abstract description 29
• 230000015556 catabolic process Effects 0.000 claims abstract description 12
• 238000006731 degradation reaction Methods 0.000 claims abstract description 12
• 230000001590 oxidative effect Effects 0.000 claims abstract description 10
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 9
• 239000001257 hydrogen Substances 0.000 claims abstract description 9
• -1 tert-octyl Chemical group 0.000 claims description 94
• 239000000203 mixture Substances 0.000 claims description 62
• 229920000098 polyolefin Polymers 0.000 claims description 21
• 229920000570 polyether Polymers 0.000 claims description 19
• 229920001169 thermoplastic Polymers 0.000 claims description 18
• 239000004814 polyurethane Substances 0.000 claims description 15
• 239000000654 additive Substances 0.000 claims description 14
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• 238000000034 method Methods 0.000 claims description 10
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• 150000003077 polyols Chemical class 0.000 claims description 10
• 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 9
• 238000012545 processing Methods 0.000 claims description 8
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 7
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 6
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
• 239000002530 phenolic antioxidant Substances 0.000 claims description 6
• 230000000087 stabilizing effect Effects 0.000 claims description 5
• 239000004611 light stabiliser Substances 0.000 claims description 4
• 229920001059 synthetic polymer Polymers 0.000 abstract description 13
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 2
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• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
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• 125000003118 aryl group Chemical group 0.000 description 7
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• 150000002148 esters Chemical class 0.000 description 6
• 229920001519 homopolymer Polymers 0.000 description 6
• 239000000314 lubricant Substances 0.000 description 6
• 239000000178 monomer Substances 0.000 description 6
• MBAUOPQYSQVYJV-UHFFFAOYSA-N octyl 3-[4-hydroxy-3,5-di(propan-2-yl)phenyl]propanoate Chemical compound OC1=C(C=C(C=C1C(C)C)CCC(=O)OCCCCCCCC)C(C)C MBAUOPQYSQVYJV-UHFFFAOYSA-N 0.000 description 6
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
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• 239000000047 product Substances 0.000 description 6
• 125000000217 alkyl group Chemical group 0.000 description 5
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 5
• 239000012964 benzotriazole Substances 0.000 description 5
• 229920001971 elastomer Polymers 0.000 description 5
• 239000012948 isocyanate Substances 0.000 description 5
• ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 5
• 238000004519 manufacturing process Methods 0.000 description 5
• 238000000465 moulding Methods 0.000 description 5
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• 238000006116 polymerization reaction Methods 0.000 description 5
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• 239000000126 substance Substances 0.000 description 5
• 150000005846 sugar alcohols Polymers 0.000 description 5
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• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
• ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 description 4
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
• 229920000877 Melamine resin Polymers 0.000 description 4
• 229920002396 Polyurea Polymers 0.000 description 4
• 229920005830 Polyurethane Foam Polymers 0.000 description 4
• 239000002253 acid Substances 0.000 description 4
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
• 125000001931 aliphatic group Chemical group 0.000 description 4
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• 239000003446 ligand Substances 0.000 description 4
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