AU2002300979B2 - Stabilization of synthetic polymers - Google Patents
Stabilization of synthetic polymers Download PDFInfo
- Publication number
- AU2002300979B2 AU2002300979B2 AU2002300979A AU2002300979A AU2002300979B2 AU 2002300979 B2 AU2002300979 B2 AU 2002300979B2 AU 2002300979 A AU2002300979 A AU 2002300979A AU 2002300979 A AU2002300979 A AU 2002300979A AU 2002300979 B2 AU2002300979 B2 AU 2002300979B2
- Authority
- AU
- Australia
- Prior art keywords
- tert
- butyl
- bis
- copolymers
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920001059 synthetic polymer Polymers 0.000 title description 23
- 230000006641 stabilisation Effects 0.000 title description 7
- 238000011105 stabilization Methods 0.000 title description 7
- -1 tert-octyl Chemical group 0.000 claims description 76
- 239000000203 mixture Substances 0.000 claims description 59
- 150000001875 compounds Chemical class 0.000 claims description 55
- 229920000642 polymer Polymers 0.000 claims description 30
- 239000003381 stabilizer Substances 0.000 claims description 27
- 229920000098 polyolefin Polymers 0.000 claims description 20
- 229920000570 polyether Polymers 0.000 claims description 19
- 239000004814 polyurethane Substances 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 14
- 230000015556 catabolic process Effects 0.000 claims description 13
- 238000006731 degradation reaction Methods 0.000 claims description 13
- 229920002635 polyurethane Polymers 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 230000001590 oxidative effect Effects 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 10
- 229920005862 polyol Polymers 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
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- 230000008569 process Effects 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 239000004611 light stabiliser Substances 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 51
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- 229910052757 nitrogen Inorganic materials 0.000 description 26
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 15
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 10
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- 150000002148 esters Chemical class 0.000 description 10
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- GQBHYWDCHSZDQU-UHFFFAOYSA-N 4-(2,4,4-trimethylpentan-2-yl)-n-[4-(2,4,4-trimethylpentan-2-yl)phenyl]aniline Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1NC1=CC=C(C(C)(C)CC(C)(C)C)C=C1 GQBHYWDCHSZDQU-UHFFFAOYSA-N 0.000 description 9
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- 125000003118 aryl group Chemical group 0.000 description 9
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 9
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
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- 235000006708 antioxidants Nutrition 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000007983 Tris buffer Substances 0.000 description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 6
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 6
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 5
- 229920002396 Polyurea Polymers 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 5
- 239000012964 benzotriazole Substances 0.000 description 5
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 5
- MBAUOPQYSQVYJV-UHFFFAOYSA-N octyl 3-[4-hydroxy-3,5-di(propan-2-yl)phenyl]propanoate Chemical compound OC1=C(C=C(C=C1C(C)C)CCC(=O)OCCCCCCCC)C(C)C MBAUOPQYSQVYJV-UHFFFAOYSA-N 0.000 description 5
- 229940059574 pentaerithrityl Drugs 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- 229920006380 polyphenylene oxide Polymers 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 239000011732 tocopherol Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 4
- KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
- ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
- ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- 150000002815 nickel Chemical class 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
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- 235000019260 propionic acid Nutrition 0.000 description 1
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- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- IJRHDFLHUATAOS-DPMBMXLASA-M sodium ricinoleate Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O IJRHDFLHUATAOS-DPMBMXLASA-M 0.000 description 1
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- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- NZNAAUDJKMURFU-UHFFFAOYSA-N tetrakis(2,2,6,6-tetramethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)NC(C)(C)C1)C(C(=O)OC1CC(C)(C)NC(C)(C)C1)CC(=O)OC1CC(C)(C)NC(C)(C)C1 NZNAAUDJKMURFU-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
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- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
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- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01810876 | 2001-09-11 | ||
| EP01810876.1 | 2001-09-11 |
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| AU2002300979A1 AU2002300979A1 (en) | 2003-06-12 |
| AU2002300979B2 true AU2002300979B2 (en) | 2007-11-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002300979A Ceased AU2002300979B2 (en) | 2001-09-11 | 2002-09-11 | Stabilization of synthetic polymers |
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| EP (1) | EP1291384B1 (OSRAM) |
| JP (1) | JP4314610B2 (OSRAM) |
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| CN (1) | CN1237058C (OSRAM) |
| AR (1) | AR036500A1 (OSRAM) |
| AT (1) | ATE299911T1 (OSRAM) |
| AU (1) | AU2002300979B2 (OSRAM) |
| BR (1) | BR0203538B1 (OSRAM) |
| CA (1) | CA2401927C (OSRAM) |
| CO (1) | CO5270026A1 (OSRAM) |
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| ES (1) | ES2246008T3 (OSRAM) |
| HU (1) | HU229128B1 (OSRAM) |
| MX (1) | MXPA02008708A (OSRAM) |
| MY (1) | MY129373A (OSRAM) |
| PL (1) | PL205846B1 (OSRAM) |
| PT (1) | PT1291384E (OSRAM) |
| RU (1) | RU2286361C2 (OSRAM) |
| SG (1) | SG125905A1 (OSRAM) |
| TW (1) | TW593303B (OSRAM) |
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| BRPI0417261B1 (pt) * | 2003-12-04 | 2021-01-26 | Ciba Specialty Chemicals Holding Inc. | composição, uso e processo para estabilização de poliéter polióis, poliéster polióis e poliuretanas |
| MY145571A (en) | 2003-12-19 | 2012-02-29 | Ciba Holding Inc | Fluorocarbon terminated oligo-and poly-carbonates as surface modifiers |
| CN1976986B (zh) * | 2004-06-30 | 2011-11-16 | 西巴特殊化学品控股有限公司 | 聚醚多元醇、聚酯多元醇或者聚氨酯组合物的稳定 |
| MY139524A (en) * | 2004-06-30 | 2009-10-30 | Ciba Holding Inc | Stabilization of polyether polyol, polyester polyol or polyurethane compositions |
| US20090076198A1 (en) | 2004-10-25 | 2009-03-19 | Thomas Giesenberg | Functionalized nanoparticles |
| EP1676887B1 (en) | 2004-12-29 | 2007-05-23 | Ciba Specialty Chemicals Holding Inc. | Composition and process for improving heat and weathering stability of segmented polyurethane polymers |
| ES2322776T5 (es) * | 2005-04-19 | 2012-11-20 | Basf Se | Poliéter-polioles, poliéster-polioles y poliuretanos de bajo contenido residual de aldehídos |
| DE102007005508A1 (de) * | 2007-02-03 | 2008-08-07 | Evonik Goldschmidt Gmbh | Verfahren zur Reduktion des Trennwert-Anstiegs bei der Herstellung von No-Label-Look-Etiketten |
| RU2356728C2 (ru) * | 2007-02-21 | 2009-05-27 | Людмила Карповна Семенова | Способ изготовления плит из композиционного материала |
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| CN102348761A (zh) * | 2009-03-13 | 2012-02-08 | 巴斯夫欧洲公司 | 聚酯和聚酰胺的稳定共混物 |
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| JP7293205B2 (ja) | 2017-09-18 | 2023-06-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 添加剤混合物 |
| DE202017005179U1 (de) | 2017-10-09 | 2019-01-11 | Follmann Gmbh & Co. Kg | Beschichtungszusammensetzung, insbesondere zur Herstellung einer beschichteten Wand-, Boden und Deckenbekleidung, insbesondere zur Herstellung einer beschichteten Tapete |
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| CN111117216B (zh) * | 2019-12-19 | 2021-09-17 | 金发科技股份有限公司 | 一种聚酰胺组合物及其制备方法 |
| GB2590910A (en) | 2019-12-24 | 2021-07-14 | Si Group Switzerland Chaa Gmbh | Composition |
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| IL317161A (en) | 2022-05-24 | 2025-01-01 | Basf Se | Polycarbonate composition containing a combination of hydroxyphenyl triazines and UV absorbers |
| JP2025526164A (ja) | 2022-08-19 | 2025-08-07 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリエチレンの加工性を改善するための添加剤の使用 |
| EP4584315A1 (en) | 2022-09-07 | 2025-07-16 | Basf Se | Rheology modifying of polymers with a radical initiator and thiourethane |
| WO2024133667A1 (en) | 2022-12-21 | 2024-06-27 | Basf Se | A method for improving the processing of polyethylene |
| WO2025087886A1 (en) | 2023-10-26 | 2025-05-01 | Basf Se | Polyolefin pipe comprising a hydrotalcite mineral and a hydrazide |
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| DE19916650A1 (de) * | 1999-04-14 | 2000-10-19 | Agfa Gevaert Ag | Farbfotografisches Silberhalogenidmaterial |
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- 2002-08-09 MY MYPI20022971A patent/MY129373A/en unknown
- 2002-09-02 CO CO02077628A patent/CO5270026A1/es not_active Application Discontinuation
- 2002-09-03 ES ES02405759T patent/ES2246008T3/es not_active Expired - Lifetime
- 2002-09-03 DK DK02405759T patent/DK1291384T3/da active
- 2002-09-03 EP EP02405759A patent/EP1291384B1/en not_active Expired - Lifetime
- 2002-09-03 AT AT02405759T patent/ATE299911T1/de active
- 2002-09-03 DE DE60205071T patent/DE60205071T2/de not_active Expired - Lifetime
- 2002-09-03 PT PT02405759T patent/PT1291384E/pt unknown
- 2002-09-06 MX MXPA02008708A patent/MXPA02008708A/es active IP Right Grant
- 2002-09-06 PL PL355901A patent/PL205846B1/pl unknown
- 2002-09-06 SG SG200205419A patent/SG125905A1/en unknown
- 2002-09-09 US US10/237,313 patent/US6881774B2/en not_active Expired - Lifetime
- 2002-09-09 CA CA2401927A patent/CA2401927C/en not_active Expired - Lifetime
- 2002-09-09 KR KR1020020054145A patent/KR100849947B1/ko not_active Expired - Lifetime
- 2002-09-09 AR ARP020103402A patent/AR036500A1/es active IP Right Grant
- 2002-09-10 HU HU0202991A patent/HU229128B1/hu not_active IP Right Cessation
- 2002-09-10 RU RU2002123926/04A patent/RU2286361C2/ru not_active IP Right Cessation
- 2002-09-10 BR BRPI0203538-3A patent/BR0203538B1/pt not_active IP Right Cessation
- 2002-09-10 CN CNB021315973A patent/CN1237058C/zh not_active Expired - Lifetime
- 2002-09-11 JP JP2002265357A patent/JP4314610B2/ja not_active Expired - Lifetime
- 2002-09-11 AU AU2002300979A patent/AU2002300979B2/en not_active Ceased
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| DE19950459A1 (de) * | 1999-10-20 | 2001-04-26 | Agfa Gevaert Ag | Farbfotografisches Silberhalogenidmaterial |
Also Published As
| Publication number | Publication date |
|---|---|
| PL355901A1 (en) | 2003-03-24 |
| RU2286361C2 (ru) | 2006-10-27 |
| EP1291384B1 (en) | 2005-07-20 |
| HU229128B1 (en) | 2013-08-28 |
| HUP0202991A2 (en) | 2003-05-28 |
| CA2401927A1 (en) | 2003-03-11 |
| HU0202991D0 (OSRAM) | 2002-10-28 |
| SG125905A1 (en) | 2006-10-30 |
| DK1291384T3 (da) | 2005-09-19 |
| KR100849947B1 (ko) | 2008-08-01 |
| JP4314610B2 (ja) | 2009-08-19 |
| BR0203538B1 (pt) | 2011-09-06 |
| TW593303B (en) | 2004-06-21 |
| HUP0202991A3 (en) | 2006-02-28 |
| JP2003176417A (ja) | 2003-06-24 |
| US20030109611A1 (en) | 2003-06-12 |
| DE60205071T2 (de) | 2006-05-24 |
| US6881774B2 (en) | 2005-04-19 |
| DE60205071D1 (de) | 2005-08-25 |
| PT1291384E (pt) | 2005-11-30 |
| BR0203538A (pt) | 2003-06-03 |
| ATE299911T1 (de) | 2005-08-15 |
| CN1407005A (zh) | 2003-04-02 |
| CA2401927C (en) | 2010-08-03 |
| MXPA02008708A (es) | 2003-03-27 |
| MY129373A (en) | 2007-03-30 |
| CN1237058C (zh) | 2006-01-18 |
| ES2246008T3 (es) | 2006-02-01 |
| PL205846B1 (pl) | 2010-06-30 |
| EP1291384A1 (en) | 2003-03-12 |
| AR036500A1 (es) | 2004-09-15 |
| CO5270026A1 (es) | 2003-04-30 |
| KR20030022708A (ko) | 2003-03-17 |
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