PL167905B1 - Sposób polimeryzacji a-olefin w obecnosci katalizatora PL PL PL - Google Patents
Sposób polimeryzacji a-olefin w obecnosci katalizatora PL PL PLInfo
- Publication number
- PL167905B1 PL167905B1 PL90300678A PL30067890A PL167905B1 PL 167905 B1 PL167905 B1 PL 167905B1 PL 90300678 A PL90300678 A PL 90300678A PL 30067890 A PL30067890 A PL 30067890A PL 167905 B1 PL167905 B1 PL 167905B1
- Authority
- PL
- Poland
- Prior art keywords
- catalyst component
- olefin
- polymerization
- catalyst
- propylene
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 109
- 238000000034 method Methods 0.000 title claims abstract description 46
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 81
- 150000001336 alkenes Chemical class 0.000 claims abstract description 76
- 239000010936 titanium Substances 0.000 claims abstract description 75
- 229920000642 polymer Polymers 0.000 claims abstract description 73
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 67
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 66
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000011949 solid catalyst Substances 0.000 claims abstract description 36
- 239000007787 solid Substances 0.000 claims abstract description 33
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 32
- 239000004711 α-olefin Substances 0.000 claims abstract description 27
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 58
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 54
- 238000007334 copolymerization reaction Methods 0.000 claims description 52
- 239000002904 solvent Substances 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 11
- 230000000737 periodic effect Effects 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 125000002524 organometallic group Chemical group 0.000 claims description 2
- 125000003262 carboxylic acid ester group Chemical class [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 38
- 229920000098 polyolefin Polymers 0.000 abstract description 17
- 238000009826 distribution Methods 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 54
- 239000005977 Ethylene Substances 0.000 description 54
- 229920001577 copolymer Polymers 0.000 description 48
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 28
- 230000000704 physical effect Effects 0.000 description 28
- 238000002360 preparation method Methods 0.000 description 24
- 239000007789 gas Substances 0.000 description 23
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 238000001035 drying Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000012071 phase Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 8
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 7
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical group COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 4
- -1 aromatic acid ester Chemical class 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000012685 gas phase polymerization Methods 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- IXGQUXURSKQJJI-UHFFFAOYSA-N CO[SiH2]CC1CCCCC1 Chemical compound CO[SiH2]CC1CCCCC1 IXGQUXURSKQJJI-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- PZQBWGFCGIRLBB-NJYHNNHUSA-N [(2r)-2-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1O PZQBWGFCGIRLBB-NJYHNNHUSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229940005483 opioid analgesics Drugs 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1340909A JP2940684B2 (ja) | 1989-12-29 | 1989-12-29 | オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL167905B1 true PL167905B1 (pl) | 1995-12-30 |
Family
ID=18341422
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL90300678A PL167905B1 (pl) | 1989-12-29 | 1990-12-28 | Sposób polimeryzacji a-olefin w obecnosci katalizatora PL PL PL |
| PL90300679A PL167913B1 (pl) | 1989-12-29 | 1990-12-28 | Sposób wytwarzania katalizatora polimeryzacji olefin PL PL PL |
| PL90288512A PL167899B1 (pl) | 1989-12-29 | 1990-12-28 | Sposób wytwarzania stalego skladnika katalizatora do polimeryzacji olefin PL PL PL |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL90300679A PL167913B1 (pl) | 1989-12-29 | 1990-12-28 | Sposób wytwarzania katalizatora polimeryzacji olefin PL PL PL |
| PL90288512A PL167899B1 (pl) | 1989-12-29 | 1990-12-28 | Sposób wytwarzania stalego skladnika katalizatora do polimeryzacji olefin PL PL PL |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5153158A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0435332B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2940684B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR940010963B1 (cg-RX-API-DMAC7.html) |
| CN (2) | CN1038685C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE151782T1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2033404C (cg-RX-API-DMAC7.html) |
| CZ (1) | CZ283582B6 (cg-RX-API-DMAC7.html) |
| DE (2) | DE435332T1 (cg-RX-API-DMAC7.html) |
| DK (1) | DK0435332T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2031800T3 (cg-RX-API-DMAC7.html) |
| GR (2) | GR920300075T1 (cg-RX-API-DMAC7.html) |
| MY (1) | MY105326A (cg-RX-API-DMAC7.html) |
| PL (3) | PL167905B1 (cg-RX-API-DMAC7.html) |
| RU (1) | RU2092495C1 (cg-RX-API-DMAC7.html) |
| TW (1) | TW201763B (cg-RX-API-DMAC7.html) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0461268B1 (en) * | 1989-12-28 | 1998-05-27 | Idemitsu Petrochemical Co., Ltd. | Process for producing olefin polymerization catalyst and polyolefin |
| IT1246614B (it) | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| US5470812A (en) * | 1991-11-06 | 1995-11-28 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
| US6291384B1 (en) | 1991-11-06 | 2001-09-18 | Mobil Oil Corporation | High activity catalyst prepared with alkoxysilanes |
| US5939348A (en) * | 1991-11-06 | 1999-08-17 | Mobil Oil Corporation | Catalyst for the manufacture of polythylene with a narrow molecular weight distribution |
| FR2689133A1 (fr) * | 1992-03-27 | 1993-10-01 | Atochem Elf Sa | Catalyseur de polymérisation des oléfines, son procédé d'obtention. |
| US5308818A (en) * | 1992-06-08 | 1994-05-03 | Fina Technology, Inc. | Catalyst system for the polymerization of olefins |
| JP3156213B2 (ja) * | 1993-02-23 | 2001-04-16 | 日石三菱株式会社 | ポリオレフィンの製造方法 |
| US5376743A (en) * | 1993-03-11 | 1994-12-27 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of sticky polymers |
| US5518973A (en) * | 1993-10-15 | 1996-05-21 | Exxon Chemical Patents Inc. | Titanium trichloride catalyst system for polymerizing olefins |
| DE69415829T2 (de) * | 1993-11-18 | 1999-05-20 | Mobil Oil Corp., Fairfax, Va. | Katalysatorzusammensetzung für die copolymerisation von ethylen |
| US6034189A (en) * | 1994-05-19 | 2000-03-07 | Mitsui Petrochemical Industries, Ltd. | Solid titanium catalyst component for olefin polymerization, process for preparation of the same, olefin polymerization catalyst and process for olefin polymerization |
| TW412546B (en) * | 1994-05-19 | 2000-11-21 | Mitsui Petrochemical Ind | Solid titanium catalyst component for olefin polymerization, process for preparation of the same, olefin polymerization catalyst and process for olefin polymerization |
| IT1275867B1 (it) * | 1995-03-07 | 1997-10-24 | Enichem Elastomers | Procedimento per l'ottenimento di copolimeri elastomerici etilene- propilene ad alta purezza e distribuzione dei pesi molecolari |
| US5849655A (en) * | 1996-12-20 | 1998-12-15 | Fina Technology, Inc. | Polyolefin catalyst for polymerization of propylene and a method of making and using thereof |
| US6100351A (en) * | 1997-01-07 | 2000-08-08 | Huntsman Polymers Corporation | Olefin polymerization process and products thereof |
| US5948720A (en) * | 1997-01-07 | 1999-09-07 | Huntsman Polymers Corporation | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof |
| US6864207B2 (en) * | 1997-01-28 | 2005-03-08 | Fina Technology, Inc. | Ziegler-Natta catalyst for polyolefins |
| US6930071B2 (en) * | 1997-01-28 | 2005-08-16 | Fina Technology, Inc. | Ziegler-natta catalyst for polyolefins |
| US6080818A (en) * | 1997-03-24 | 2000-06-27 | Huntsman Polymers Corporation | Polyolefin blends used for non-woven applications |
| TR199902842T1 (xx) * | 1998-03-23 | 2000-09-21 | Montell Technology Company Bv | Olefinlerin polimerizasyonu i�in �nceden polimerize edilmi� kataliz�r elemanlar. |
| EP1094083A3 (en) * | 1999-10-19 | 2001-12-12 | Idemitsu Petrochemical Co., Ltd. | Catalyst for olefin polymerization, method for producing olefin polymer, and olefin polymer |
| US6358372B1 (en) | 2000-07-11 | 2002-03-19 | Union Carbide Chemicals & Plastics Technology Corporation | Method of reducing formation of precipitates in solvent recovery system |
| CN100564400C (zh) | 2001-05-29 | 2009-12-02 | 联合碳化化学及塑料技术有限责任公司 | 烯烃聚合催化剂组合物和制备方法 |
| US6825146B2 (en) * | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| MY136330A (en) * | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| KR100530795B1 (ko) * | 2001-12-26 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합 방법 |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| AU2003245297A1 (en) * | 2002-06-14 | 2003-12-31 | Union Carbide Chemicals And Plastics Technology Corporation ; | Catalyst composition and polymerization process using mixtures of electron donors |
| US7276463B2 (en) * | 2002-09-11 | 2007-10-02 | Japan Polypropylene Corporation | Polymerization catalyst for α-olefins and process for production of α-olefin polymers therewith |
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| JPS5634709A (en) † | 1979-08-31 | 1981-04-07 | Mitsui Petrochem Ind Ltd | Gas phase polymerization or copolymerization of olefin |
| JPS6042806B2 (ja) * | 1979-12-26 | 1985-09-25 | 日石三菱株式会社 | 共重合体の製造方法 |
| JPS56133303A (en) * | 1980-03-22 | 1981-10-19 | Chisso Corp | Production of alpha-olefin polymer |
| US4410671A (en) * | 1980-08-12 | 1983-10-18 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| US4326988A (en) * | 1980-08-12 | 1982-04-27 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| US4325837A (en) * | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| JPS5898315A (ja) * | 1981-12-07 | 1983-06-11 | Chisso Corp | ポリオレフイン共重合体の粉体流動性改良法 |
| EP0099774B2 (fr) * | 1982-06-24 | 1995-03-22 | BP Chimie Société Anonyme | Procédé pour la polymérisation et la copolymérisation des alpha-oléfines en lit fluidisé |
| FR2541683B1 (fr) * | 1983-02-28 | 1986-05-09 | Ato Chimie | Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme |
| CA1284549C (en) † | 1986-09-26 | 1991-05-28 | Fathi David Hussein | Process for the polymerization of propylene |
| ATE201216T1 (de) † | 1987-02-02 | 2001-06-15 | Fina Technology | Verfahren zur verbesserung der effektivität eines prepolymerisierten katalysators |
| FR2629461B1 (fr) * | 1988-03-31 | 1993-05-07 | Bp Chimie Sa | Catalyseur de (co)polymerisation du propylene, supporte sur des particules spheriques de chlorure de magnesium et enrobe par du polypropylene, et procedes de preparation |
| FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
-
1989
- 1989-12-29 JP JP1340909A patent/JP2940684B2/ja not_active Expired - Lifetime
-
1990
- 1990-12-27 MY MYPI90002271A patent/MY105326A/en unknown
- 1990-12-27 US US07/634,737 patent/US5153158A/en not_active Expired - Lifetime
- 1990-12-27 TW TW079110903A patent/TW201763B/zh active
- 1990-12-28 RU SU904894186A patent/RU2092495C1/ru not_active IP Right Cessation
- 1990-12-28 AT AT90125706T patent/ATE151782T1/de not_active IP Right Cessation
- 1990-12-28 PL PL90300678A patent/PL167905B1/pl unknown
- 1990-12-28 ES ES90125706T patent/ES2031800T3/es not_active Expired - Lifetime
- 1990-12-28 DE DE199090125706T patent/DE435332T1/de active Pending
- 1990-12-28 EP EP90125706A patent/EP0435332B2/en not_active Expired - Lifetime
- 1990-12-28 DK DK90125706.3T patent/DK0435332T3/da active
- 1990-12-28 PL PL90300679A patent/PL167913B1/pl unknown
- 1990-12-28 PL PL90288512A patent/PL167899B1/pl unknown
- 1990-12-28 CA CA002033404A patent/CA2033404C/en not_active Expired - Fee Related
- 1990-12-28 DE DE69030489T patent/DE69030489T3/de not_active Expired - Lifetime
- 1990-12-29 CN CN90110256A patent/CN1038685C/zh not_active Expired - Lifetime
- 1990-12-29 KR KR1019900022415A patent/KR940010963B1/ko not_active Expired - Fee Related
- 1990-12-29 CZ CS906942A patent/CZ283582B6/cs not_active IP Right Cessation
-
1992
- 1992-10-08 GR GR92300075T patent/GR920300075T1/el unknown
-
1997
- 1997-05-02 GR GR970400965T patent/GR3023309T3/el unknown
- 1997-07-04 CN CN97113747A patent/CN1174204A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CZ283582B6 (cs) | 1998-05-13 |
| PL167899B1 (pl) | 1995-12-30 |
| DE435332T1 (de) | 1992-09-03 |
| DE69030489T2 (de) | 1997-09-04 |
| CZ694290A3 (en) | 1996-07-17 |
| ATE151782T1 (de) | 1997-05-15 |
| GR920300075T1 (en) | 1992-10-08 |
| CN1052870A (zh) | 1991-07-10 |
| DE69030489T3 (de) | 2006-03-16 |
| PL167913B1 (pl) | 1995-12-30 |
| EP0435332B2 (en) | 2005-08-10 |
| CA2033404A1 (en) | 1991-06-30 |
| JPH03203908A (ja) | 1991-09-05 |
| ES2031800T1 (es) | 1993-01-01 |
| EP0435332B1 (en) | 1997-04-16 |
| US5153158A (en) | 1992-10-06 |
| KR910011920A (ko) | 1991-08-07 |
| ES2031800T3 (es) | 1997-09-16 |
| EP0435332A3 (en) | 1992-02-26 |
| KR940010963B1 (ko) | 1994-11-21 |
| TW201763B (cg-RX-API-DMAC7.html) | 1993-03-11 |
| CA2033404C (en) | 1995-09-05 |
| DK0435332T3 (da) | 1997-05-12 |
| JP2940684B2 (ja) | 1999-08-25 |
| PL288512A1 (en) | 1991-09-09 |
| MY105326A (en) | 1994-09-30 |
| RU2092495C1 (ru) | 1997-10-10 |
| GR3023309T3 (en) | 1997-08-29 |
| CN1038685C (zh) | 1998-06-10 |
| CN1174204A (zh) | 1998-02-25 |
| DE69030489D1 (de) | 1997-05-22 |
| EP0435332A2 (en) | 1991-07-03 |
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