OA11947A - Reducing fischer-tropsch catalyst attrition lossesin high agitation reaction systems. - Google Patents
Reducing fischer-tropsch catalyst attrition lossesin high agitation reaction systems. Download PDFInfo
- Publication number
- OA11947A OA11947A OA1200100306A OA1200100306A OA11947A OA 11947 A OA11947 A OA 11947A OA 1200100306 A OA1200100306 A OA 1200100306A OA 1200100306 A OA1200100306 A OA 1200100306A OA 11947 A OA11947 A OA 11947A
- Authority
- OA
- OAPI
- Prior art keywords
- catalyst
- cobalt
- pbw
- alumina
- alumina support
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 294
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 76
- 238000013019 agitation Methods 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 157
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 119
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 35
- 239000007864 aqueous solution Substances 0.000 claims abstract description 32
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 32
- 230000008569 process Effects 0.000 claims abstract description 31
- 238000001354 calcination Methods 0.000 claims abstract description 16
- 230000002378 acidificating effect Effects 0.000 claims abstract description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 11
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 122
- 239000010941 cobalt Substances 0.000 claims description 122
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 122
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 60
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 46
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 40
- 239000010936 titanium Substances 0.000 claims description 33
- 229910052719 titanium Inorganic materials 0.000 claims description 33
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 31
- 239000002002 slurry Substances 0.000 claims description 27
- 229910001593 boehmite Inorganic materials 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 51
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 47
- 238000012360 testing method Methods 0.000 description 37
- 230000000694 effects Effects 0.000 description 34
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- 239000002245 particle Substances 0.000 description 27
- 239000000243 solution Substances 0.000 description 27
- 238000011068 loading method Methods 0.000 description 25
- 239000000377 silicon dioxide Substances 0.000 description 24
- ZZBAGJPKGRJIJH-UHFFFAOYSA-N 7h-purine-2-carbaldehyde Chemical compound O=CC1=NC=C2NC=NC2=N1 ZZBAGJPKGRJIJH-UHFFFAOYSA-N 0.000 description 20
- 239000000463 material Substances 0.000 description 19
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 18
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 17
- 229910002651 NO3 Inorganic materials 0.000 description 16
- 238000010438 heat treatment Methods 0.000 description 16
- 239000012018 catalyst precursor Substances 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 15
- 229910052726 zirconium Inorganic materials 0.000 description 15
- -1 aluminum alkoxide Chemical class 0.000 description 13
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 241000640882 Condea Species 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000002243 precursor Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 238000002604 ultrasonography Methods 0.000 description 10
- 239000011261 inert gas Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- 229910052681 coesite Inorganic materials 0.000 description 6
- 229910052906 cristobalite Inorganic materials 0.000 description 6
- 239000002019 doping agent Substances 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 229910052682 stishovite Inorganic materials 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 229910052905 tridymite Inorganic materials 0.000 description 6
- 229910021094 Co(NO3)2-6H2O Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000003426 co-catalyst Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- PNPIRSNMYIHTPS-UHFFFAOYSA-N nitroso nitrate Chemical compound [O-][N+](=O)ON=O PNPIRSNMYIHTPS-UHFFFAOYSA-N 0.000 description 4
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229940093928 potassium nitrate Drugs 0.000 description 3
- 235000010333 potassium nitrate Nutrition 0.000 description 3
- 239000004323 potassium nitrate Substances 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910021091 Co(NO3)26H2O Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000003637 basic solution Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000013467 fragmentation Methods 0.000 description 2
- 238000006062 fragmentation reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 2
- GJKFIJKSBFYMQK-UHFFFAOYSA-N lanthanum(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GJKFIJKSBFYMQK-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 230000035899 viability Effects 0.000 description 2
- 229910009112 xH2O Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910008334 ZrO(NO3)2 Inorganic materials 0.000 description 1
- 229940008309 acetone / ethanol Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/316,562 US6262132B1 (en) | 1999-05-21 | 1999-05-21 | Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems |
Publications (1)
Publication Number | Publication Date |
---|---|
OA11947A true OA11947A (en) | 2006-04-13 |
Family
ID=23229572
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
OA1200100306A OA11947A (en) | 1999-05-21 | 2000-05-15 | Reducing fischer-tropsch catalyst attrition lossesin high agitation reaction systems. |
Country Status (19)
Country | Link |
---|---|
US (3) | US6262132B1 (ja) |
EP (3) | EP1187674B1 (ja) |
JP (1) | JP5048182B2 (ja) |
KR (1) | KR20020010150A (ja) |
CN (1) | CN1384771A (ja) |
AR (1) | AR024047A1 (ja) |
AT (2) | ATE530254T1 (ja) |
AU (1) | AU777852B2 (ja) |
BR (1) | BR0010831A (ja) |
CA (1) | CA2374600A1 (ja) |
CO (1) | CO5190732A1 (ja) |
DE (1) | DE60040387D1 (ja) |
EA (3) | EA200301280A1 (ja) |
GC (1) | GC0000337A (ja) |
MX (1) | MXPA01011910A (ja) |
MY (1) | MY125370A (ja) |
NO (2) | NO325478B1 (ja) |
OA (1) | OA11947A (ja) |
WO (1) | WO2000071253A2 (ja) |
Families Citing this family (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19836821A1 (de) * | 1998-08-14 | 2000-02-24 | Rwe Dea Ag | Böhmitische Tonerden und aus diesen erhältliche phasenreine, hochtemperaturstabile und hochporöse Aluminiumoxide |
US6262132B1 (en) * | 1999-05-21 | 2001-07-17 | Energy International Corporation | Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems |
DE19931204A1 (de) * | 1999-07-07 | 2001-01-18 | Rwe Dea Ag | Verfahren zur Herstellung von in organischen Lösungsmitteln dispergierbaren Metalloxiden |
US7208446B2 (en) * | 1999-08-11 | 2007-04-24 | Albemarle Netherlands B. V. | Quasi-crystalline boehmites containing additives |
JP2003507296A (ja) * | 1999-08-11 | 2003-02-25 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 添加物を含む擬結晶性ベーマイト |
JP3715482B2 (ja) * | 1999-11-04 | 2005-11-09 | エヌ・イーケムキャット株式会社 | 水素含有ガス中の一酸化炭素選択酸化触媒並びに該触媒を用いた一酸化炭素除去方法及び固体高分子電解質型燃料電池システム |
RU2252072C2 (ru) * | 1999-12-01 | 2005-05-20 | Сэсол Текнолоджи (Проприетери) Лимитед | Кобальтовые катализаторы |
IT1317868B1 (it) | 2000-03-02 | 2003-07-15 | Eni Spa | Catalizzatore a base di cobalto supportato, particolarmente utilenella reazione di fischer-tropsch. |
US6255358B1 (en) * | 2000-03-17 | 2001-07-03 | Energy International Corporation | Highly active Fischer-Tropsch synthesis using doped, thermally stable catalyst support |
AU6257901A (en) * | 2000-06-12 | 2001-12-24 | Sasol Tech Pty Ltd | Cobalt catalysts |
EP1315564A2 (en) | 2000-07-03 | 2003-06-04 | Conoco Inc. | Fischer-tropsch processes and catalysts using aluminum borate supports |
US6706661B1 (en) * | 2000-09-01 | 2004-03-16 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst enhancement |
ITMI20010478A1 (it) * | 2001-03-08 | 2002-09-08 | Inst Francais Du Petrole | Catalizzatore a base di cobalto e suo utilizzo nel processo di fischer-tropsch |
US7452844B2 (en) * | 2001-05-08 | 2008-11-18 | Süd-Chemie Inc | High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis |
BR0210813A (pt) * | 2001-10-25 | 2004-06-22 | Sasol Tech Pty Ltd | Processo para produzir um catalizador fischer-tropsch suportado |
US6706660B2 (en) * | 2001-12-18 | 2004-03-16 | Caterpillar Inc | Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems |
RU2005115063A (ru) * | 2002-10-16 | 2005-10-10 | КонокоФиллипс Кампэни (US) | Способ изготовления носителя для катализатора из стабилизированного переходного оксида алюминия (варианты), способ изготовления катализатора фишера-тропша и способ синтеза парафиновых углеводородов из синтез-газа |
WO2004035194A2 (en) * | 2002-10-16 | 2004-04-29 | Conocophillips Company | High hydrothermal stability catalyst support |
US7012104B2 (en) * | 2002-10-16 | 2006-03-14 | Conocophillips Company | Fischer-Tropsch processes and catalysts made from a material comprising boehmite |
AU2003277409C1 (en) * | 2002-10-16 | 2009-06-25 | Conocophillips Company | Fischer-Tropsch processes and catalysts using stabilized supports |
US7176160B2 (en) * | 2002-10-16 | 2007-02-13 | Conocophillips Company | Method for forming a Fischer-Tropsch catalyst using a boehmite support |
US7341976B2 (en) * | 2002-10-16 | 2008-03-11 | Conocophillips Company | Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using |
US7276540B2 (en) * | 2002-11-11 | 2007-10-02 | Conocophillips Company | Supports for high surface area catalysts |
US7067562B2 (en) * | 2002-12-20 | 2006-06-27 | Conocophillips Company | Iron-based Fischer-Tropsch catalysts and methods of making and using |
US20040127584A1 (en) * | 2002-12-31 | 2004-07-01 | Phillips Petroleum Company | Chemical vapor deposition synthesis of polymerization catalyst composition |
EP1583734A2 (en) * | 2003-04-14 | 2005-10-12 | Teva Pharmaceutical Industries Limited | Hydrogenation of imine intermediates of sertraline with catalysts |
US7045554B2 (en) * | 2003-09-03 | 2006-05-16 | Conocophillips Company | Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion |
US7163963B2 (en) * | 2003-09-08 | 2007-01-16 | Conocophillips Company | Chemically and thermally stabilized alumina for Fischer-Tropsch catalysts |
WO2005037745A1 (en) * | 2003-10-16 | 2005-04-28 | Conocophillips Company | Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same |
WO2005046855A2 (en) * | 2003-10-16 | 2005-05-26 | Conocophillips Company | Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same |
FR2862238B1 (fr) * | 2003-11-14 | 2006-11-17 | Solvay | Catalyseur a base d'alumine contenant du titane et procede en phase gazeuse utilisant un tel catalyseur |
US20050233898A1 (en) * | 2003-12-12 | 2005-10-20 | Robota Heinz J | Modified catalyst supports |
GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
US20050182145A1 (en) * | 2004-02-17 | 2005-08-18 | Conocophillips Company | Methods of reducing and loading a metal-based catalyst into a reactor |
CA2559451C (en) * | 2004-03-12 | 2010-09-14 | Saint-Gobain Ceramics & Plastics, Inc. | Spray dried alumina for catalyst carrier |
GB2416715A (en) * | 2004-07-30 | 2006-02-08 | Statoil Asa | Fischer-Tropsch catalyst |
RU2007120500A (ru) * | 2004-11-03 | 2008-12-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Зернистый катализатор, устойчивый к истиранию |
GB0510316D0 (en) * | 2005-05-20 | 2005-06-29 | Johnson Matthey Plc | Catalyst manufacture |
US20070004810A1 (en) * | 2005-06-30 | 2007-01-04 | Yong Wang | Novel catalyst and fischer-tropsch synthesis process using same |
US7915196B2 (en) * | 2005-10-07 | 2011-03-29 | Alliance For Sustainable Energy, Llc | Attrition resistant fluidizable reforming catalyst |
US7393876B2 (en) * | 2005-12-16 | 2008-07-01 | Eltron Research, Inc. | Fischer-tropsch catalysts |
US20070169412A1 (en) * | 2006-01-26 | 2007-07-26 | Georgia Tech Research Corporation | Sulfur- and alkali-tolerant catalyst |
JP3987555B1 (ja) | 2006-03-28 | 2007-10-10 | 三洋化成工業株式会社 | 粘度指数向上剤および潤滑油組成物 |
RU2436627C2 (ru) * | 2006-08-25 | 2011-12-20 | Ниппон Стил Инджиниринг Ко., Лтд. | Катализатор для производства углеводорода из синтез-газа, способ получения катализатора, способ регенерации катализатора и способ получения углеводорода из синтез-газа |
RU2326732C1 (ru) * | 2006-12-27 | 2008-06-20 | ООО "Объединенный центр исследований и разработок" | Катализатор для синтеза фишера-тропша и способ его получения |
GB2446127A (en) * | 2007-01-30 | 2008-08-06 | Gtl F1 Ag | Preparation of Fischer-Tropsch Catalysts |
US20090023822A1 (en) * | 2007-07-19 | 2009-01-22 | Tijm Peter J | Method for activating and regenerating catalyst for a fischer-tropsch synthesis reaction |
KR100885311B1 (ko) * | 2007-09-04 | 2009-02-24 | 한국화학연구원 | 피셔-트롭쉬 합성용 코발트/인-알루미나 촉매와 이의 제조방법 |
US20090143493A1 (en) * | 2007-10-04 | 2009-06-04 | Jacobus Johannes Cornelis Geerlings | Catalyst and method |
FR2926084B1 (fr) | 2008-01-04 | 2010-03-19 | Inst Francais Du Petrole | Procede ameliore de synthese fischer-tropsch par controle de la pression partielle d'eau dans la zone reactionnelle |
DE102008025307A1 (de) * | 2008-05-27 | 2009-12-03 | Süd-Chemie AG | Kobalt-Fischer-Tropsch-Katalysator |
KR100991012B1 (ko) | 2008-07-14 | 2010-10-29 | 한국화학연구원 | 저온영역에서 탄소섬유 제조가 가능한코발트/알루미늄포스페이트 촉매 및 이의 제조방법 |
KR101689356B1 (ko) | 2009-03-17 | 2016-12-23 | 가부시기가이샤 닛뽕쇼꾸바이 | 수소 제조용 촉매 및 그를 사용한 수소 제조방법, 및, 암모니아 연소용 촉매, 그의 제조방법 및 이 촉매를 사용한 암모니아 연소방법 |
GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
KR101094077B1 (ko) | 2010-02-16 | 2011-12-15 | 한국에너지기술연구원 | 금속 폼 표면에 코발트 촉매 분말이 코팅된 코발트 금속 폼 촉매의 제조방법 및 그 코발트 금속 폼 촉매, 이 코발트 금속 폼 촉매를 이용한 열매체 순환 열교환형 반응기 및 이 열매체 순환 열교환형 반응기를 이용한 피셔-트롭쉬 합성 반응에 의한 액체 연료의 생산 방법 |
WO2012020210A2 (en) | 2010-08-09 | 2012-02-16 | Gtl.F1 Ag | Fischer-tropsch catalysts |
US9156022B2 (en) | 2010-08-09 | 2015-10-13 | W. R. Grace & Co.-Conn. | Attrition resistant supports for fischer-tropsch catalyst and process for making same |
JP5795483B2 (ja) * | 2011-03-31 | 2015-10-14 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 活性化されたフィッシャー・トロプシュ合成反応用触媒および炭化水素の製造方法 |
AU2012265887B2 (en) | 2011-06-07 | 2016-12-22 | Sasol Technology (Proprietary) Limited | Process for producing at least one product from at least one gaseous reactant in a slurry bed |
CA2838462C (en) | 2011-06-07 | 2020-04-21 | Sasol Technology (Proprietary) Limited | Process for producing at least one product from at least one gaseous reactant in a slurry bed |
US20130105440A1 (en) | 2011-11-01 | 2013-05-02 | Az Electronic Materials Usa Corp. | Nanocomposite negative photosensitive composition and use thereof |
WO2014020507A2 (en) * | 2012-08-02 | 2014-02-06 | Sasol Technology (Proprietary) Limited | Catalysts |
JP5919145B2 (ja) * | 2012-09-03 | 2016-05-18 | 新日鉄住金エンジニアリング株式会社 | 合成ガスから炭化水素を製造する触媒の製造方法、合成ガスから炭化水素を製造する方法、及び触媒の再生方法 |
EP2898947A4 (en) * | 2012-09-21 | 2016-10-05 | Jx Nippon Oil & Energy Corp | FISCHER-TROPSCH SYNTHESIS CATALYST, PROCESS FOR PRODUCING THE SAME, AND PROCESS FOR PRODUCING HYDROCARBONS |
RU2669372C2 (ru) * | 2013-07-24 | 2018-10-11 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения хлорсодержащего катализатора, полученный катализатор и его использование |
KR101373823B1 (ko) | 2013-10-22 | 2014-03-11 | 한국에너지기술연구원 | 선택적 합성오일 생성을 위한 피셔-트롭쉬 반응용 금속 구조체 기반 코발트계 촉매 및 그 제조 방법, 이 금속 구조체 기반 코발트계 촉매를 이용한 선택적 합성 오일 제조 방법 |
US9358526B2 (en) | 2013-11-19 | 2016-06-07 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
US9180436B1 (en) | 2013-11-19 | 2015-11-10 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
PL3071538T3 (pl) | 2013-11-20 | 2021-09-06 | Lummus Technology Llc | Katalizator izomeryzacji podwójnego wiązania olefiny o wysokiej odporności na zatrucie |
AU2015366160B2 (en) * | 2014-12-19 | 2020-04-16 | Bp P.L.C. | Process for preparation of a supported cobalt-containing Fischer-Tropsch synthesis catalyst |
US10010877B2 (en) * | 2016-06-14 | 2018-07-03 | Chevron U.S.A. Inc. | Stable support for Fischer-Tropsch catalyst and methods for making and using |
EP3513872A1 (en) * | 2018-01-22 | 2019-07-24 | SASOL Germany GmbH | Catalyst support comprising homogeneously distributed titanium dioxide and method for production |
CN110368983A (zh) * | 2018-04-13 | 2019-10-25 | 株式会社模范 | 一种合成气合成航空煤油用催化剂的制备方法以及由此得到的催化剂和其应用 |
US11376567B2 (en) * | 2019-12-05 | 2022-07-05 | GM Global Technology Operations LLC | Methods for preparing catalytic systems |
Family Cites Families (138)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2735802A (en) | 1956-02-21 | jahnig | ||
US799378A (en) * | 1904-08-20 | 1905-09-12 | Harold James Hedderwick | Life-boat. |
US2393909A (en) | 1945-04-02 | 1946-01-29 | Standard Oil Co | Chemical reaction with fluidized solids |
US2540109A (en) | 1946-05-15 | 1951-02-06 | Phillips Petroleum Co | Process for reactivating catalysts |
US2635110A (en) | 1946-11-26 | 1953-04-14 | Texas Co | Regeneration of hydrocarbon synthesis catalysts |
US2515245A (en) | 1947-06-11 | 1950-07-18 | Standard Oil Dev Co | Process of regenerating a fluidized fischer-tropsch catalyst |
US2544574A (en) | 1947-09-25 | 1951-03-06 | Stanolind Oil & Gas Co | Catalyst regeneration |
US2605234A (en) | 1947-12-01 | 1952-07-29 | Phillips Petroleum Co | Regeneration of a carbonized fischer-tropsch catalyst |
US2608568A (en) | 1948-04-12 | 1952-08-26 | Phillips Petroleum Co | Regeneration of catalyst |
US2661338A (en) | 1948-12-13 | 1953-12-01 | Phillips Petroleum Co | Regeneration of a fischer-tropsch reduced iron catalyst |
US2598186A (en) | 1948-12-20 | 1952-05-27 | Phillips Petroleum Co | Process for use of spent fischertropsch catalyst for manufacture of carbon monoxide-hydrogen synthesis gas |
US2620313A (en) | 1949-06-01 | 1952-12-02 | Standard Oil Dev Co | Regeneration of fluidized iron oxide catalyst |
US2632015A (en) | 1949-06-29 | 1953-03-17 | Stanolind Oil & Gas Co | Regeneration of hydrocarbon synthesis catalyst by treatment with ethanol |
US2662912A (en) | 1950-07-28 | 1953-12-15 | Standard Oil Dev Co | Hydrocarbon synthesis reaction |
US2775607A (en) | 1952-11-17 | 1956-12-25 | Rheinpreussen Ag | Reactivation of catalysts |
US2852350A (en) | 1952-12-27 | 1958-09-16 | Rheinpreussen Ag Fur Bergbau A | Carbon monoxide hydrogenation synthesis reactors |
GB799378A (en) * | 1954-12-24 | 1958-08-06 | Houdry Process Corp | Method of preparing attrition resistant alumina particles |
US3351567A (en) * | 1963-12-19 | 1967-11-07 | Universal Oil Prod Co | Production of attrition-resistant alumina catalyst |
US3617517A (en) | 1969-06-23 | 1971-11-02 | Cities Service Oil Co | Hydroforming catalyst |
US3669904A (en) | 1970-05-28 | 1972-06-13 | Air Prod & Chem | Particles featuring gamma alumina |
US3853789A (en) * | 1971-03-26 | 1974-12-10 | J Warthen | Preparation of macroporous alumina extrudates |
US3943052A (en) | 1973-08-16 | 1976-03-09 | Exxon Research & Engineering Co. | Regeneration procedure |
FR2245408B1 (ja) * | 1973-09-04 | 1981-03-27 | Norton Co | |
US3966586A (en) | 1974-07-31 | 1976-06-29 | Mobil Oil Corporation | Method for upgrading heavy petroleum type stocks |
US4090949A (en) | 1974-07-31 | 1978-05-23 | Mobil Oil Corportion | Upgrading of olefinic gasoline with hydrogen contributors |
US3988263A (en) | 1974-10-02 | 1976-10-26 | Union Oil Company Of California | Thermally stable coprecipitated catalysts useful for methanation and other reactions |
US4102978A (en) * | 1975-11-10 | 1978-07-25 | Norton Company | Process for producing alumina catalyst carriers |
US4088671A (en) | 1976-03-19 | 1978-05-09 | Gulf Research & Development Company | Conversion of synthesis gas using a cobalt-ruthenium catalyst |
DD128777A1 (de) | 1976-03-26 | 1977-12-07 | Inst Francais Du Petrole | Verfahren zur veredelung von ausstroemenden stoffen aus fischer-tropsch-syntheseverfahren oder aehnlichen syntheseverfahren |
US4089811A (en) | 1976-11-01 | 1978-05-16 | Texaco Inc. | Preparation of catalyst support |
US4079072A (en) | 1976-11-15 | 1978-03-14 | Phillips Petroleum Company | Methanation process |
US4179408A (en) * | 1977-03-25 | 1979-12-18 | W. R. Grace & Co. | Process for preparing spheroidal alumina particles |
US4279830A (en) | 1977-08-22 | 1981-07-21 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors |
US4218388A (en) | 1977-12-22 | 1980-08-19 | Shell Oil Company | Process for preparing hydrocarbons from gasification of coal |
US4208191A (en) | 1978-05-30 | 1980-06-17 | The Lummus Company | Production of pipeline gas from coal |
JPS5527830A (en) * | 1978-08-15 | 1980-02-28 | Chiyoda Chem Eng & Constr Co Ltd | Production of alumina carrier |
US4207208A (en) | 1978-12-18 | 1980-06-10 | Mobil Oil Corporation | Method for regeneration and activity improvement of syngas conversion catalyst |
FR2449474A1 (fr) * | 1979-02-26 | 1980-09-19 | Rhone Poulenc Ind | Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs |
US4219445A (en) | 1979-02-26 | 1980-08-26 | Phillips Petroleum Company | Methanation of carbon monoxide over tungsten carbide-containing alumina catalyst for methanation of carbon monoxide |
US4260518A (en) | 1979-05-15 | 1981-04-07 | University Of Delaware | Process for the regeneration of metallic catalysts |
US4252736A (en) | 1979-06-01 | 1981-02-24 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors |
US4235754A (en) | 1979-08-10 | 1980-11-25 | Mobil Oil Corporation | Cracking catalyst |
NL8001342A (nl) | 1980-03-06 | 1980-07-31 | Shell Int Research | Werkwijze voor het uitvoeren van katalytische omzettingen. |
US4548912A (en) | 1980-04-14 | 1985-10-22 | Ashland Oil, Inc. | Microspherical catalysts |
NL8003313A (nl) | 1980-06-06 | 1982-01-04 | Shell Int Research | Werkwijze voor de bereiding van middeldestillaten. |
US5244648A (en) * | 1980-12-23 | 1993-09-14 | Rhone-Poulenc Industries | Process for the preparation of alumina agglomerates |
US4379134A (en) * | 1981-02-13 | 1983-04-05 | Union Carbide Corporation | Process of preparing high purity alumina bodies |
NL8101447A (nl) | 1981-03-24 | 1982-10-18 | Shell Int Research | Werkwijze voor de bereiding van koolwaterstoffen uit koolstofhoudend materiaal. |
US4585798A (en) | 1981-10-13 | 1986-04-29 | Gulf Research & Development Company | Synthesis gas conversion using ruthenium-promoted cobalt catalyst |
US4605676A (en) | 1981-10-13 | 1986-08-12 | Chevron Research Company | Synthesis gas conversion using ROR-activated catalyst |
US4493905A (en) | 1981-10-13 | 1985-01-15 | Gulf Research & Development Company | Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel |
US4413064A (en) * | 1981-10-13 | 1983-11-01 | Gulf Research & Development Company | Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel |
US4729981A (en) | 1981-10-13 | 1988-03-08 | Shell Internationale Research Maatschappij B.V. | ROR-activated catalyst for synthesis gas conversion |
US4565831A (en) | 1981-12-16 | 1986-01-21 | Exxon Research And Engineering Co. | Process for producing aromatic hydrocarbons from carbon monoxide and water |
US4477595A (en) | 1982-03-31 | 1984-10-16 | Exxon Research And Engineering Co. | Liquid hydrocarbon synthesis using supported ruthenium catalysts |
US4606811A (en) | 1982-07-29 | 1986-08-19 | Ashland Oil, Inc. | Combination process for upgrading reduced crude |
ATE21340T1 (de) | 1982-11-22 | 1986-08-15 | Shell Int Research | Verfahren zur herstellung eines fischer-tropsch- katalysators, der auf diese weise hergestellte katalysator und seine verwendung zur herstellung von kohlenwasserstoffen. |
US4476245A (en) * | 1982-11-29 | 1984-10-09 | Atlantic Richfield Company | Preparative process for alkaline earth metal, aluminum-containing spinels |
US4523047A (en) | 1982-12-01 | 1985-06-11 | Mobil Oil Corporation | Process for syngas conversions to liquid hydrocarbon products utilizing ZSM-45 zeolite |
US4423265A (en) | 1982-12-01 | 1983-12-27 | Mobil Oil Corporation | Process for snygas conversions to liquid hydrocarbon products |
US4863890A (en) | 1983-09-09 | 1989-09-05 | Berol Kemi Ab | Process for preparing a ruthenium-promoted, halogen-containing nickel and/or cobalt catalyst and a catalyst prepared by the process |
US4507400A (en) | 1983-09-28 | 1985-03-26 | Standard Oil Company (Indiana) | Cadmium- and thorium-containing catalyst |
US4605678A (en) | 1984-03-12 | 1986-08-12 | Mobil Oil Corporation | Separation of catalyst from slurry bubble column wax and catalyst recycle |
US4568663A (en) | 1984-06-29 | 1986-02-04 | Exxon Research And Engineering Co. | Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis |
US4595703A (en) | 1984-06-29 | 1986-06-17 | Exxon Research And Engineering Co. | Preparation of hydrocarbons from synthesis gas |
US4567205A (en) | 1984-06-29 | 1986-01-28 | Exxon Research And Engineering Co. | Ruthenium catalysts, and use thereof for Fischer-Tropsch synthesis |
CA1256090A (en) | 1984-10-04 | 1989-06-20 | Willibrord A. Van Erp | Catalyst containing cobalt |
JPS61111140A (ja) | 1984-11-06 | 1986-05-29 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
US4686313A (en) | 1984-12-31 | 1987-08-11 | Mobil Oil Corporation | Low nitrogen iron-containing Fischer-Tropsch catalyst and conversion of synthesis gas therewith |
US4717702A (en) | 1985-04-26 | 1988-01-05 | Shell Internationale Research Maatschappij Bv | Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst |
US4788222A (en) | 1985-05-20 | 1988-11-29 | Exxon Research And Engineering Company | Method for the production of hydrocarbons using iron-carbon-based catalysts |
US4619910A (en) | 1985-06-05 | 1986-10-28 | Air Products And Chemicals, Inc. | Catalyst for selective conversion of synthesis gas and method of making the catalyst |
US4670472A (en) | 1985-06-05 | 1987-06-02 | Air Products And Chemicals, Inc. | Fischer-Tropsch process |
US4673993A (en) | 1986-01-09 | 1987-06-16 | Mccaughey Michael P | Method for synchronizing a tape recorder to a computer under program control |
US4684756A (en) | 1986-05-01 | 1987-08-04 | Mobil Oil Corporation | Process for upgrading wax from Fischer-Tropsch synthesis |
US5504118A (en) | 1986-05-08 | 1996-04-02 | Rentech, Inc. | Process for the production of hydrocarbons |
US5324335A (en) | 1986-05-08 | 1994-06-28 | Rentech, Inc. | Process for the production of hydrocarbons |
US4822824A (en) | 1986-07-02 | 1989-04-18 | Exxon Research And Engineering Company | Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis |
GB8623233D0 (en) | 1986-09-26 | 1986-10-29 | British Petroleum Co Plc | Syngas conversion catalyst |
US4908341A (en) | 1986-12-04 | 1990-03-13 | Mobil Oil Corp. | Method for reactivating spent catalyst by contact with one or more aromatic compounds |
US4738939A (en) | 1987-06-29 | 1988-04-19 | Exxon Research And Engineering Company | Regeneration and reactivation of reforming catalysts while passivating iron scale carryover from the regenerator circuit to the reactors |
US4874732A (en) * | 1987-07-13 | 1989-10-17 | Uop | Cobalt Fischer-Tropsch catalysts having improved selectivity |
JPS6438142A (en) * | 1987-08-04 | 1989-02-08 | Kansai Coke & Chemicals | Catalyst for synthesizing hydrocarbon |
US4801573A (en) * | 1987-10-23 | 1989-01-31 | 501 Den Norske Stats Oljeslenskap A.S. | Catalyst for production of hydrocarbons |
US4880763A (en) | 1987-10-23 | 1989-11-14 | Den Norske Stats Olijeselskap A.S. | Catalyst for production of hydrocarbons |
US5036032A (en) | 1988-03-25 | 1991-07-30 | Exxon Research And Engineering Company | Selective catalysts and their preparation for catalytic hydrocarbon synthesis |
US5037791A (en) * | 1988-07-28 | 1991-08-06 | Hri, Inc. | Porous metal oxide supported carbon-coated catalysts and method for producing same |
US4872970A (en) | 1988-09-23 | 1989-10-10 | Exxon Research And Engineering Company | Reactivation of iridium-containing catalysts |
US4910227A (en) | 1988-10-11 | 1990-03-20 | Air Products And Chemicals, Inc. | High volumetric production of methanol in a liquid phase reactor |
US5140050A (en) | 1988-11-23 | 1992-08-18 | Exxon Research And Engineering Co. | Titania catalysts, their preparation, and use in Fischer-Tropsch synthesis |
US4992406A (en) | 1988-11-23 | 1991-02-12 | Exxon Research And Engineering Company | Titania-supported catalysts and their preparation for use in Fischer-Tropsch synthesis |
US5102851A (en) | 1988-12-28 | 1992-04-07 | Den Norske Stats Oljeselskap A.S. | Supported catalyst for hydrocarbon synthesis |
US4978689A (en) | 1989-03-17 | 1990-12-18 | Mobil Oil Corp. | Conversion of synthesis gas to liquid hydrocarbons |
US5070064A (en) | 1989-08-07 | 1991-12-03 | Exxon Research And Engineering Company | Catalyst pretreatment method |
US5028634A (en) | 1989-08-23 | 1991-07-02 | Exxon Research & Engineering Company | Two stage process for hydrocarbon synthesis |
US5102852A (en) | 1989-12-28 | 1992-04-07 | Chevron Research And Technology Company | Catalyst system for removal of calcium from a hydrocarbon feedstock |
US5157054A (en) | 1990-04-04 | 1992-10-20 | Exxon Research And Engineering Company | Catalyst fluidization improvements (C-2546) |
US5348982A (en) | 1990-04-04 | 1994-09-20 | Exxon Research & Engineering Co. | Slurry bubble column (C-2391) |
GB9010075D0 (en) * | 1990-05-04 | 1990-06-27 | Shell Int Research | Process for the preparation of alumina based extrudates |
US5258411A (en) | 1990-10-15 | 1993-11-02 | Exxon Research And Engineering Co. | Activation conditions to maximize the HCS activity of supported cobalt catalysts (OP-3706) |
US5116800A (en) | 1990-12-11 | 1992-05-26 | Allied-Signal Inc. | High durability and exhuast catalyst with low hydrogen sulfide emissions |
JPH04317742A (ja) * | 1991-04-15 | 1992-11-09 | Cosmo Sogo Kenkyusho:Kk | 炭化水素油の水素化処理用触媒組成物及びその製造方法 |
US5334570A (en) * | 1991-07-25 | 1994-08-02 | Corning Incorporated | Pore impregnated catalyst device |
US5206202A (en) | 1991-07-25 | 1993-04-27 | Corning Incorporated | Catalyst device fabricated in situ and method of fabricating the device |
US5162284A (en) | 1991-08-05 | 1992-11-10 | Exxon Research And Engineering Co. | Copper promoted cobalt-manganese spinel catalyst and method for making the catalyst for Fischer-Tropsch synthesis |
US5248701A (en) | 1991-08-05 | 1993-09-28 | Exxon Research And Engineering Company | Substituted cobalt catalysts for Fischer-Tropsch synthesis |
GB9203959D0 (en) | 1992-02-25 | 1992-04-08 | Norske Stats Oljeselskap | Method of conducting catalytic converter multi-phase reaction |
GB9203958D0 (en) | 1992-02-25 | 1992-04-08 | Norske Stats Oljeselskap | Catalytic multi-phase reactor |
US5334790A (en) | 1992-02-26 | 1994-08-02 | Catalytica | Process and catalyst for partially hydrogenating aromatics to produce cycloolefins |
US5411927A (en) | 1992-08-14 | 1995-05-02 | Council Of Scientific & Industrial Research | Process of preparing composite catalysts for production of synthesis gas by oxidative conversion of methane or natural gas |
US5292705A (en) | 1992-09-24 | 1994-03-08 | Exxon Research & Engineering Co. | Activation of hydrocarbon synthesis catalyst |
US5283216A (en) | 1992-09-24 | 1994-02-01 | Exxon Research And Engineering Company | Rejuvenation of hydrocarbon synthesis catalyst |
IT1255710B (it) | 1992-10-01 | 1995-11-10 | Snam Progetti | Procedimento integrato per produrre olefine da miscele gassose contenenti metano |
CA2105940C (en) | 1992-10-05 | 2001-12-25 | Robert M. Koros | Bubble column, tube side slurry process and apparatus |
US5252613A (en) | 1992-12-18 | 1993-10-12 | Exxon Research & Engineering Company | Enhanced catalyst mixing in slurry bubble columns (OP-3723) |
US5268344A (en) | 1992-12-18 | 1993-12-07 | Exxon Research & Engineering Company | Draft tube for catalyst rejuvenation and distribution |
US5288673A (en) | 1992-12-18 | 1994-02-22 | Exxon Research And Engineering Company | Temperature control in draft tubes for catalyst rejuvenation |
US5382748A (en) | 1992-12-18 | 1995-01-17 | Exxon Research & Engineering Co. | Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means |
US5260239A (en) | 1992-12-18 | 1993-11-09 | Exxon Research & Engineering Company | External catalyst rejuvenation system for the hydrocarbon synthesis process |
US5461022A (en) | 1992-12-31 | 1995-10-24 | Sandia Corporation | Thin film hydrous metal oxide catalysts |
US5356845A (en) | 1993-05-11 | 1994-10-18 | Exxon Research And Engineering Company | Process for the reactivation of nickel-alumina catalysts |
US5527473A (en) | 1993-07-15 | 1996-06-18 | Ackerman; Carl D. | Process for performing reactions in a liquid-solid catalyst slurry |
GB2281224B (en) | 1993-08-24 | 1998-02-11 | Norske Stats Oljeselskap | Solid/liquid slurry treatment apparatus and catalytic multi-phase reactor |
US5498638A (en) | 1994-04-29 | 1996-03-12 | Exxon Research & Engineering Co. | Staged hydrocarbon synthesis process |
US5484757A (en) | 1994-06-02 | 1996-01-16 | Norton Chemical Process Products Corp. | Titania-based catalyst carriers |
US5639798A (en) | 1994-12-15 | 1997-06-17 | Wexford P.A. Syncrude Limited Partnership | Process and catalyst for production of hydrocarbons |
US5780381A (en) * | 1994-12-15 | 1998-07-14 | Syncrude Technology Inc. | Cobalt/molybdenum/zirconium catalyst for Fischer-Tropsch synthesis |
US5648312A (en) | 1994-12-29 | 1997-07-15 | Intevep, S.A. | Hydrogenation catalyst with improved attrition resistance and heat dissipation |
US5591689A (en) * | 1995-06-23 | 1997-01-07 | Phillips Petroleum Company | Preparation of isomerization catalyst composition |
US5939350A (en) * | 1997-02-10 | 1999-08-17 | Energy International Corporation | Processes and catalysts for conducting fischer-tropsch synthesis in a slurry bubble column reactor |
GB2322633A (en) * | 1997-02-28 | 1998-09-02 | Norske Stats Oljeselskap | Fischer-Tropsch reactor |
IT1292462B1 (it) * | 1997-07-03 | 1999-02-08 | Agip Petroli | Composizione catalitica utile nel processo di fischer-tropsch |
US5905094A (en) * | 1997-10-21 | 1999-05-18 | Exxon Research And Engineering Co. | Slurry hydrocarbon synthesis with reduced catalyst attrition and deactivation |
US6365544B2 (en) * | 1998-05-22 | 2002-04-02 | Conoco Inc. | Fischer-Tropsch processes and catalysts using fluorided alumina supports |
EP1203061B1 (en) * | 1998-05-27 | 2005-07-13 | Sasol Technology (UK) Limited | Improved fischer-tropsch activity for "non-promoted" cobalt-on-alumina catalysts |
IT1301801B1 (it) * | 1998-06-25 | 2000-07-07 | Agip Petroli | Procedimento per la preparazione di idrocarburi da gas di sintesi |
US6262132B1 (en) * | 1999-05-21 | 2001-07-17 | Energy International Corporation | Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems |
US6100304A (en) * | 1999-05-26 | 2000-08-08 | Energy International Corportion | Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis |
-
1999
- 1999-05-21 US US09/316,562 patent/US6262132B1/en not_active Expired - Lifetime
-
2000
- 2000-05-15 CA CA002374600A patent/CA2374600A1/en not_active Abandoned
- 2000-05-15 EP EP00932431A patent/EP1187674B1/en not_active Expired - Lifetime
- 2000-05-15 EA EA200301280A patent/EA200301280A1/ru unknown
- 2000-05-15 DE DE60040387T patent/DE60040387D1/de not_active Expired - Lifetime
- 2000-05-15 JP JP2000619549A patent/JP5048182B2/ja not_active Expired - Lifetime
- 2000-05-15 AU AU50154/00A patent/AU777852B2/en not_active Expired
- 2000-05-15 BR BR0010831-6A patent/BR0010831A/pt not_active Application Discontinuation
- 2000-05-15 EP EP05023736A patent/EP1661618B1/en not_active Expired - Lifetime
- 2000-05-15 WO PCT/US2000/013282 patent/WO2000071253A2/en not_active Application Discontinuation
- 2000-05-15 KR KR1020017014880A patent/KR20020010150A/ko not_active Application Discontinuation
- 2000-05-15 AT AT05023736T patent/ATE530254T1/de not_active IP Right Cessation
- 2000-05-15 EA EA200301283A patent/EA005389B1/ru not_active IP Right Cessation
- 2000-05-15 CN CN00810518A patent/CN1384771A/zh active Pending
- 2000-05-15 MX MXPA01011910A patent/MXPA01011910A/es not_active Application Discontinuation
- 2000-05-15 OA OA1200100306A patent/OA11947A/en unknown
- 2000-05-15 AT AT00932431T patent/ATE409521T1/de not_active IP Right Cessation
- 2000-05-15 EA EA200101226A patent/EA004578B1/ru not_active IP Right Cessation
- 2000-05-15 EP EP05023618.1A patent/EP1666141B1/en not_active Expired - Lifetime
- 2000-05-17 MY MYPI20002168A patent/MY125370A/en unknown
- 2000-05-19 AR ARP000102459A patent/AR024047A1/es not_active Application Discontinuation
- 2000-05-19 CO CO00036871A patent/CO5190732A1/es not_active Application Discontinuation
- 2000-05-21 GC GCP2000667 patent/GC0000337A/en active
-
2001
- 2001-04-27 US US09/844,379 patent/US6740621B2/en not_active Expired - Lifetime
- 2001-11-21 NO NO20015685A patent/NO325478B1/no not_active IP Right Cessation
-
2004
- 2004-05-21 US US10/851,379 patent/US7011809B2/en not_active Expired - Lifetime
-
2006
- 2006-10-27 NO NO20064922A patent/NO332801B1/no not_active IP Right Cessation
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
OA11947A (en) | Reducing fischer-tropsch catalyst attrition lossesin high agitation reaction systems. | |
JP2003500188A5 (ja) | ||
JP4933014B2 (ja) | ドープされ熱的に安定な触媒担体を用いた高活性なフィッシャー−トロプシュ合成 | |
EP0370757B1 (en) | Titania-containing catalysts, their preparation and use in Fischer-Tropsch synthesis | |
EP0482753B1 (en) | Methanol synthesis catalyst | |
US4977126A (en) | Process for the preparation of surface impregnated dispersed cobalt metal catalysts | |
EP1203061B1 (en) | Improved fischer-tropsch activity for "non-promoted" cobalt-on-alumina catalysts | |
US6271432B2 (en) | Fischer-tropsch activity for non-promoted cobalt-on-alumina catalysts | |
US6191066B1 (en) | Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts | |
US20070105963A1 (en) | Catalyst for Fischer-Tropsch Synthesis and Process for Producing Hydrocarbons | |
EP2473273A1 (en) | Fischer-tropsch catalysts | |
JP2001500058A (ja) | フィッシャー―トロプシュ触媒及び炭化水素の製造方法 | |
AU764183B2 (en) | Improved fischer-tropsch activity for "non-promoted" cobalt-on-alumina catalysts | |
JPS62132545A (ja) | ルテニウム触媒及びフイツシヤ−トロプシユ合成のためのその使用法 | |
EA043038B1 (ru) | Способ фишера-тропша, катализатор на подложке для синтеза фишера-тропша и его применение | |
EA042792B1 (ru) | Способ фишера-тропша | |
EP0453674A1 (en) | Process for the preparation of surface impregnated dispersed cobalt metal catalysts and hydrocarbon synthesis using said catalysts |