NO322277B1 - Oksydasjonskatalysator og fremgangsmate som anvender katalysatoren - Google Patents
Oksydasjonskatalysator og fremgangsmate som anvender katalysatoren Download PDFInfo
- Publication number
- NO322277B1 NO322277B1 NO20001678A NO20001678A NO322277B1 NO 322277 B1 NO322277 B1 NO 322277B1 NO 20001678 A NO20001678 A NO 20001678A NO 20001678 A NO20001678 A NO 20001678A NO 322277 B1 NO322277 B1 NO 322277B1
- Authority
- NO
- Norway
- Prior art keywords
- ethylene
- acetic acid
- catalyst
- ethane
- oxidation
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 62
- 230000003647 oxidation Effects 0.000 title claims abstract description 19
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 92
- 239000000203 mixture Substances 0.000 claims abstract description 46
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000005977 Ethylene Substances 0.000 claims abstract description 40
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000001301 oxygen Substances 0.000 claims abstract description 23
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 23
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010955 niobium Substances 0.000 claims abstract description 12
- 239000010931 gold Substances 0.000 claims abstract description 11
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 11
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 11
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052737 gold Inorganic materials 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 8
- 239000011733 molybdenum Substances 0.000 claims abstract description 8
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000007789 gas Substances 0.000 claims description 13
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- 229910001882 dioxygen Inorganic materials 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000008246 gaseous mixture Substances 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052787 antimony Inorganic materials 0.000 abstract description 6
- 229910052748 manganese Inorganic materials 0.000 abstract description 6
- 229910052759 nickel Inorganic materials 0.000 abstract description 6
- 229910052697 platinum Inorganic materials 0.000 abstract description 6
- 229910052703 rhodium Inorganic materials 0.000 abstract description 6
- 229910052707 ruthenium Inorganic materials 0.000 abstract description 6
- 229910052804 chromium Inorganic materials 0.000 abstract description 5
- 229910052802 copper Inorganic materials 0.000 abstract description 5
- 229910052741 iridium Inorganic materials 0.000 abstract description 5
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 229910052745 lead Inorganic materials 0.000 abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 5
- 229910052710 silicon Inorganic materials 0.000 abstract description 5
- 229910052709 silver Inorganic materials 0.000 abstract description 5
- 229910052716 thallium Inorganic materials 0.000 abstract description 5
- 229910052718 tin Inorganic materials 0.000 abstract description 5
- 229910052719 titanium Inorganic materials 0.000 abstract description 5
- 229910052770 Uranium Inorganic materials 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- 229910052796 boron Inorganic materials 0.000 abstract description 4
- 229910052792 caesium Inorganic materials 0.000 abstract description 4
- 229910052791 calcium Inorganic materials 0.000 abstract description 4
- 229910052733 gallium Inorganic materials 0.000 abstract description 4
- 229910052735 hafnium Inorganic materials 0.000 abstract description 4
- 229910052738 indium Inorganic materials 0.000 abstract description 4
- 229910052701 rubidium Inorganic materials 0.000 abstract description 4
- 229910052712 strontium Inorganic materials 0.000 abstract description 4
- 229910052715 tantalum Inorganic materials 0.000 abstract description 4
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- 229910052726 zirconium Inorganic materials 0.000 abstract description 4
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- 229910052788 barium Inorganic materials 0.000 abstract description 2
- 229910052702 rhenium Inorganic materials 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000001307 helium Substances 0.000 description 6
- 229910052734 helium Inorganic materials 0.000 description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 6
- 239000010948 rhodium Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 4
- 229940010552 ammonium molybdate Drugs 0.000 description 4
- 235000018660 ammonium molybdate Nutrition 0.000 description 4
- 239000011609 ammonium molybdate Substances 0.000 description 4
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- LGDAGYXJBDILKZ-UHFFFAOYSA-N [2-methyl-1,1-dioxo-3-(pyridin-2-ylcarbamoyl)-1$l^{6},2-benzothiazin-4-yl] 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=1C2=CC=CC=C2S(=O)(=O)N(C)C=1C(=O)NC1=CC=CC=N1 LGDAGYXJBDILKZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9907704.2A GB9907704D0 (en) | 1999-04-01 | 1999-04-01 | Catalyst and process utilising the catalyst |
Publications (3)
Publication Number | Publication Date |
---|---|
NO20001678D0 NO20001678D0 (no) | 2000-03-31 |
NO20001678L NO20001678L (no) | 2000-10-02 |
NO322277B1 true NO322277B1 (no) | 2006-09-04 |
Family
ID=10850940
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20001678A NO322277B1 (no) | 1999-04-01 | 2000-03-31 | Oksydasjonskatalysator og fremgangsmate som anvender katalysatoren |
Country Status (19)
Country | Link |
---|---|
US (1) | US6333444B1 (de) |
EP (1) | EP1043064B1 (de) |
JP (1) | JP4588159B2 (de) |
KR (1) | KR100685203B1 (de) |
CN (1) | CN1128666C (de) |
AT (1) | ATE270144T1 (de) |
BR (1) | BR0001460B1 (de) |
DE (1) | DE60011832T2 (de) |
ES (1) | ES2223400T3 (de) |
GB (1) | GB9907704D0 (de) |
ID (1) | ID25432A (de) |
MY (1) | MY121466A (de) |
NO (1) | NO322277B1 (de) |
RS (1) | RS49505B (de) |
RU (1) | RU2238144C2 (de) |
SG (1) | SG84569A1 (de) |
TR (1) | TR200000876A2 (de) |
TW (1) | TW476666B (de) |
UA (1) | UA67751C2 (de) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0014584D0 (en) | 2000-06-14 | 2000-08-09 | Bp Chem Int Ltd | Apparatus and process |
GB0026242D0 (en) | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Apparatus and process |
GB0026243D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
US6841699B2 (en) * | 2001-04-25 | 2005-01-11 | Rohm And Haas Company | Recalcined catalyst |
EP1266688A3 (de) * | 2001-06-14 | 2003-07-09 | Rohm And Haas Company | Mischoxidkatalysator, der durch Gasphasenabscheidung eines Metalls dotiert wurde, und Mischoxidkatalysator, der durch Aufbringen mehrerer Schichten verschiedener Elemente mittels Gasphasenabscheidung hergestellt wurde |
RU2004115326A (ru) | 2001-10-16 | 2005-10-27 | БП Кемикэлз Лимитед (GB) | Катализатор окисления этана и способ, в котором исрользуют этот катализатор |
GB0124835D0 (en) * | 2001-10-16 | 2001-12-05 | Bp Chem Int Ltd | Catalyst and process |
TWI322709B (en) | 2001-12-04 | 2010-04-01 | Bp Chem Int Ltd | Oxidation process in fluidised bed reactor |
GB0129611D0 (en) * | 2001-12-11 | 2002-01-30 | Bp Chem Int Ltd | Process for production of styrene |
GB0223681D0 (en) * | 2002-10-10 | 2002-11-20 | Bp Chem Int Ltd | Catalyst and process |
US7718811B2 (en) | 2002-11-26 | 2010-05-18 | Ineos Europe Limited | Oxidation process in fluidised bed reactor |
UA79540C2 (uk) * | 2003-01-27 | 2007-06-25 | Бп Кемікалз Лімітед | Каталітична композиція окиснення, її одержання та спосіб селективного окиснення |
US7294734B2 (en) * | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
US7220390B2 (en) | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
TWI355292B (en) * | 2003-06-10 | 2012-01-01 | Bp Chem Int Ltd | Catalyst composition and process for the selective |
CN103537274A (zh) * | 2003-08-21 | 2014-01-29 | 英国石油化学品有限公司 | 催化剂组合物、其制备方法及用其制备乙酸和乙烯的方法 |
US20120208695A1 (en) * | 2009-11-02 | 2012-08-16 | Dow Global Technologies Llc | Supported rhodium synthesis gas conversion catalyst compositions |
CN102939154B (zh) * | 2010-04-09 | 2014-09-10 | 陶氏环球技术有限责任公司 | 用于生产混合的醇的催化剂组合物 |
CN101869845B (zh) * | 2010-06-21 | 2012-06-13 | 浙江新和成股份有限公司 | 一种用于去氢异植物醇选择性加氢合成异植物醇的催化剂 |
CN102125869B (zh) * | 2010-12-20 | 2012-12-26 | 中国石油大学(北京) | 一种乙烷选择氧化制乙醛用催化剂及其制备方法 |
CN102125833B (zh) * | 2010-12-20 | 2013-03-13 | 中国石油大学(北京) | 一种乙烷选择氧化制乙醛和乙烯用催化剂及其制备方法 |
RU2528830C1 (ru) * | 2013-07-10 | 2014-09-20 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ получения этилена |
RU2528829C1 (ru) * | 2013-07-10 | 2014-09-20 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ получения этилена |
CN106660902B (zh) * | 2014-06-30 | 2019-07-05 | 国际壳牌研究有限公司 | 烷烃氧化脱氢和/或烯烃氧化 |
WO2016001112A1 (en) | 2014-06-30 | 2016-01-07 | Shell Internationale Research Maatschappij B.V. | Treatment of a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium |
EP3026037A1 (de) * | 2014-11-26 | 2016-06-01 | Shell Internationale Research Maatschappij B.V. | Oxidative Alkendehydrierung und/oder Alkenoxydierung |
EP3933881A1 (de) | 2020-06-30 | 2022-01-05 | VEC Imaging GmbH & Co. KG | Röntgenquelle mit mehreren gittern |
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US3567772A (en) * | 1966-03-30 | 1971-03-02 | Toa Gosei Chem Ind | Process for the production of acrylic acid |
US4339355A (en) * | 1975-10-09 | 1982-07-13 | Union Carbide Corporation | Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal |
US4250346A (en) * | 1980-04-14 | 1981-02-10 | Union Carbide Corporation | Low temperature oxydehydrogenation of ethane to ethylene |
US4410752A (en) * | 1980-07-10 | 1983-10-18 | The Standard Oil Company | Process for the oxydehydrogenation of ethane to ethylene |
GB8915410D0 (en) * | 1989-07-05 | 1989-08-23 | Bp Chem Int Ltd | Chemical process |
US4568790A (en) * | 1984-06-28 | 1986-02-04 | Union Carbide Corporation | Process for oxydehydrogenation of ethane to ethylene |
US4524236A (en) * | 1984-06-28 | 1985-06-18 | Union Carbide Corporation | Process for oxydehydrogenation of ethane to ethylene |
US5162578A (en) * | 1987-06-12 | 1992-11-10 | Union Carbide Chemicals & Plastics Technology Corporation | Acetic acid from ethane, ethylene and oxygen |
DE4220859A1 (de) * | 1992-06-25 | 1994-01-05 | Basf Ag | Multimetalloxidmassen |
CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
DE19600741A1 (de) * | 1995-01-18 | 1996-07-25 | Basf Ag | Katalysator und dessen Verwendung bei der heterogenkatalytischen instationären oxidativen Dehydrierung von Alkylaromaten und Paraffinen |
DE19630832A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
GB9616573D0 (en) * | 1996-08-07 | 1996-09-25 | Bp Chem Int Ltd | Process |
DE19717076A1 (de) | 1997-04-23 | 1998-10-29 | Hoechst Ag | Katalysator und Verfahren zur katalytischen Oxidation von Ethan zu Essigsäure |
DE19717075A1 (de) | 1997-04-23 | 1998-10-29 | Hoechst Ag | Verfahren zur Herstellung von Essigsäure in einer Reaktorkaskade |
DE19745902A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
US6030920A (en) * | 1997-12-24 | 2000-02-29 | Saudi Basic Industries Corporation | Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same |
GB9807142D0 (en) * | 1998-04-02 | 1998-06-03 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
-
1999
- 1999-04-01 GB GBGB9907704.2A patent/GB9907704D0/en not_active Ceased
-
2000
- 2000-02-14 DE DE60011832T patent/DE60011832T2/de not_active Expired - Lifetime
- 2000-02-14 EP EP00301108A patent/EP1043064B1/de not_active Expired - Lifetime
- 2000-02-14 AT AT00301108T patent/ATE270144T1/de not_active IP Right Cessation
- 2000-02-14 ES ES00301108T patent/ES2223400T3/es not_active Expired - Lifetime
- 2000-02-17 US US09/506,092 patent/US6333444B1/en not_active Expired - Lifetime
- 2000-02-21 TW TW089102972A patent/TW476666B/zh not_active IP Right Cessation
- 2000-02-23 RS YU10200A patent/RS49505B/sr unknown
- 2000-02-25 SG SG200001048A patent/SG84569A1/en unknown
- 2000-03-09 KR KR1020000011780A patent/KR100685203B1/ko not_active IP Right Cessation
- 2000-03-29 BR BRPI0001460-5A patent/BR0001460B1/pt not_active IP Right Cessation
- 2000-03-30 TR TR2000/00876A patent/TR200000876A2/xx unknown
- 2000-03-30 JP JP2000094484A patent/JP4588159B2/ja not_active Expired - Fee Related
- 2000-03-31 UA UA2000031836A patent/UA67751C2/uk unknown
- 2000-03-31 ID IDP20000258D patent/ID25432A/id unknown
- 2000-03-31 RU RU2000107895A patent/RU2238144C2/ru not_active IP Right Cessation
- 2000-03-31 MY MYPI20001344A patent/MY121466A/en unknown
- 2000-03-31 CN CN00104939A patent/CN1128666C/zh not_active Expired - Fee Related
- 2000-03-31 NO NO20001678A patent/NO322277B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
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KR100685203B1 (ko) | 2007-02-22 |
ID25432A (id) | 2000-10-05 |
RU2238144C2 (ru) | 2004-10-20 |
KR20000071428A (ko) | 2000-11-25 |
GB9907704D0 (en) | 1999-05-26 |
NO20001678L (no) | 2000-10-02 |
NO20001678D0 (no) | 2000-03-31 |
BR0001460B1 (pt) | 2011-02-22 |
DE60011832D1 (de) | 2004-08-05 |
SG84569A1 (en) | 2001-11-20 |
JP2000312826A (ja) | 2000-11-14 |
UA67751C2 (uk) | 2004-07-15 |
EP1043064A3 (de) | 2001-12-19 |
JP4588159B2 (ja) | 2010-11-24 |
YU10200A (sh) | 2002-08-12 |
EP1043064B1 (de) | 2004-06-30 |
ES2223400T3 (es) | 2005-03-01 |
US6333444B1 (en) | 2001-12-25 |
RS49505B (sr) | 2006-10-27 |
TR200000876A3 (tr) | 2000-11-21 |
CN1128666C (zh) | 2003-11-26 |
TR200000876A2 (tr) | 2000-11-21 |
CN1269259A (zh) | 2000-10-11 |
TW476666B (en) | 2002-02-21 |
ATE270144T1 (de) | 2004-07-15 |
EP1043064A2 (de) | 2000-10-11 |
MY121466A (en) | 2006-01-28 |
BR0001460A (pt) | 2001-01-16 |
DE60011832T2 (de) | 2005-08-25 |
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